JP6960799B2 - Polycarbonate resin composition - Google Patents

Description

The present invention relates to a polycarbonate resin composition, and more particularly to a polycarbonate resin composition capable of cutting wavelength light having a wavelength of 400 to 420 nm on the visible light side of ultraviolet light and having no problem of gas generation during molding.

The eyes are constantly exposed to damage from sunlight, and it is important to protect them from ultraviolet light up to a wavelength of 400 nm. In addition, recent studies have revealed that the wavelength band on the more visible light side from ultraviolet light also damages the tissues of the eye and causes the pathogenesis of cataracts and the like. Furthermore, it has been reported that blue light, which is abundant in LED light sources, causes eye diseases while devices and lighting using LEDs as light sources have become widespread.
Therefore, in addition to ultraviolet light, a material that cuts wavelength light having a wavelength of 400 to 420 nm, which is closer to visible light, is required.

In general, polycarbonate resin is excellent in mechanical properties, weather resistance, and transparency, and a polycarbonate resin composition containing an ultraviolet absorber can be used as a transparent ultraviolet absorbing material for glasses, sunglasses, goggles, various lighting covers, and the like. in use. As the ultraviolet absorber, an ultraviolet absorber such as a benzophenone type, a benzotriazole type, a triazine type, or a salicylate type is used (for example, Patent Documents 1 and 2).
However, there is no known polycarbonate resin composition that can actually effectively absorb and block wavelengths of 400 to 420 nm.
Further, when trying to cut the 420 nm wavelength light with the conventional ultraviolet absorber as described above, there is a problem that the blending amount is large and the gas generation at the time of molding is large.

As described above, a resin composition composed of an ultraviolet absorber and a polycarbonate resin is known, but a polycarbonate resin composition capable of effectively absorbing and blocking wavelengths of 400 to 420 nm and having no problem of gas generation during molding is known. The current situation is that it has not been done.

Japanese Unexamined Patent Publication No. 09-291205 Special Fair 06-51840 Gazette

The present invention has been made in view of the above circumstances, and an object (problem) thereof is to be able to cut wavelength light of 400 to 420 nm on the more visible light side in addition to ultraviolet light, and to generate gas during molding. It is an object of the present invention to provide a polycarbonate resin composition having no problem.

As a result of diligent studies to achieve the above problems, the present inventor has added a specific amount of each of an ultraviolet absorber having a specific maximum absorption wavelength and a phosphorus-based stabilizer to a wavelength of 400 to 420 nm. We have found that a polycarbonate resin composition capable of cutting light and having no problem of gas generation during molding can be obtained, and have completed the present invention.
The present invention relates to the following polycarbonate resin compositions.

（式中、Ｘはハロゲン原子を表す。） [1] With respect to 100 parts by mass of the polycarbonate resin (A), 0.02 to 1 part by mass of an ultraviolet absorber (B1) having a maximum absorption wavelength of 375 nm or more obtained from the following formula in accordance with JIS K7105. A polycarbonate resin composition containing 0.01 to 0.5 parts by mass of the stabilizer (C).
[Absorbance of polycarbonate resin containing 0.005% by mass of UV absorber]-[Asorbance of polycarbonate resin only]
[2] The polycarbonate resin composition according to the above [1], wherein the ultraviolet absorber (B1) is a benzotriazole-based ultraviolet absorber having a sesamol group.
[3] The polycarbonate resin composition according to the above [1] or [2], wherein the ultraviolet absorber (B1) is an ultraviolet absorber represented by the following general formula (1).

(In the formula, X represents a halogen atom.)

[4] Further, a benzotriazole-based ultraviolet absorber (B2) having a sesamole group having a maximum absorption wavelength of 360 nm or more and less than 375 nm obtained from the above formula in accordance with JIS K7105 is added to 100 parts by mass of a polycarbonate resin (A). The polycarbonate resin composition according to any one of [1] to [3], which contains 0.01 parts by mass or more and less than 0.08 parts by mass.
[5] Further, the ultraviolet absorber (B2) having a maximum absorption wavelength of less than 360 nm obtained from the above formula in accordance with JIS K7105 is 0.01 to 0.2 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). The polycarbonate resin composition according to any one of the above [1] to [4].
[6] The ultraviolet absorber (B2) is at least one selected from a benzotriazole-based ultraviolet absorber having no sesamole group, a triazine-based ultraviolet absorber, a malonic acid ester-based ultraviolet absorber, and a benzoxazine-based ultraviolet absorber. The polycarbonate resin composition according to the above [5].
[7] The polycarbonate resin composition according to any one of the above [1] to [6], wherein the molded product having a thickness of 2 mm and having a transmittance of 25% or less measured at a wavelength of 420 nm according to JIS K7105.
[8] A molded product of the polycarbonate resin composition according to any one of the above [1] to [7].

The polycarbonate resin composition of the present invention can cut wavelength light of 400 to 420 nm on the more visible light side in addition to ultraviolet light, and does not have a problem of gas generation during molding.

It is a top view of the drop mold used for the evaluation of mold contamination in an Example.

Hereinafter, the present invention will be described in detail with reference to embodiments and examples.
In addition, in this specification, "~" is used in the meaning which includes the numerical values described before and after it as the lower limit value and the upper limit value unless otherwise specified.

The polycarbonate resin composition of the present invention contains an ultraviolet absorber (B1) having a maximum absorption wavelength of 375 nm or more, which is obtained from the following formula in accordance with JIS K7105, with respect to 100 parts by mass of the polycarbonate resin (A). It is characterized by containing 02 to 1 part by mass and 0.01 to 0.5 part by mass of the stabilizer (C).
[Absorbance of polycarbonate resin containing 0.005% by mass of UV absorber]-[Asorbance of polycarbonate resin only]

Hereinafter, each component and the like constituting the polycarbonate resin composition of the present invention will be described in detail.

[Polycarbonate resin (A)]
The polycarbonate resin is a polymer having a basic structure having a carbonic acid bond represented by the formula:-[-O-X-OC (= O)-]-. In the formula, X is generally a hydrocarbon, but a heteroatom or an X having a heterobond introduced may be used to impart various properties.

Further, the polycarbonate resin can be classified into an aromatic polycarbonate resin in which the carbon directly bonded to the carbonic acid bond is an aromatic carbon and an aliphatic polycarbonate resin in which the carbon is an aliphatic carbon, and any of them can be used. Of these, aromatic polycarbonate resins are preferable from the viewpoints of heat resistance, mechanical properties, electrical properties, and the like.

The specific type of the polycarbonate resin is not limited, and examples thereof include a polycarbonate polymer obtained by reacting a dihydroxy compound with a carbonate precursor. At this time, in addition to the dihydroxy compound and the carbonate precursor, a polyhydroxy compound or the like may be reacted. Alternatively, a method of reacting carbon dioxide with cyclic ether using carbon dioxide as a carbonate precursor may also be used. Further, the polycarbonate polymer may be linear or branched. Further, the polycarbonate polymer may be a copolymer composed of one type of repeating unit or a copolymer having two or more types of repeating units. At this time, as the copolymer, various copolymer forms such as a random copolymer and a block copolymer can be selected. Usually, such a polycarbonate polymer becomes a thermoplastic resin.

Among the monomers used as raw materials for aromatic polycarbonate resins, examples of aromatic dihydroxy compounds include
Dihydroxybenzenes such as 1,2-dihydroxybenzene, 1,3-dihydroxybenzene (ie resorcinol), 1,4-dihydroxybenzene;
Dihydroxybiphenyls such as 2,5-dihydroxybiphenyl, 2,2'-dihydroxybiphenyl, 4,4'-dihydroxybiphenyl;

2,2'-Dihydroxy-1,1'-binaphthyl, 1,2-dihydroxynaphthalene, 1,3-dihydroxynaphthalene, 2,3-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, 1 , 7-Dihydroxynaphthalene, 2,7-dihydroxynaphthalene and other dihydroxynaphthalene;

2,2'-Dihydroxydiphenyl ether, 3,3'-dihydroxydiphenyl ether, 4,4'-dihydroxydiphenyl ether, 4,4'-dihydroxy-3,3'-dimethyldiphenyl ether, 1,4-bis (3-hydroxyphenoxy) Dihydroxydiaryl ethers such as benzene and 1,3-bis (4-hydroxyphenoxy) benzene;

2,2-bis (4-hydroxyphenyl) propane (ie, bisphenol A),
1,1-bis (4-hydroxyphenyl) propane,
2,2-bis (3-methyl-4-hydroxyphenyl) propane,
2,2-Bis (3-methoxy-4-hydroxyphenyl) propane,
2- (4-Hydroxyphenyl) -2- (3-methoxy-4-hydroxyphenyl) propane,
1,1-bis (3-tert-butyl-4-hydroxyphenyl) propane,
2,2-bis (3,5-dimethyl-4-hydroxyphenyl) propane,
2,2-bis (3-cyclohexyl-4-hydroxyphenyl) propane,
2- (4-Hydroxyphenyl) -2- (3-cyclohexyl-4-hydroxyphenyl) propane,
α, α'-bis (4-hydroxyphenyl) -1,4-diisopropylbenzene,
1,3-bis [2- (4-hydroxyphenyl) -2-propyl] benzene,
Bis (4-hydroxyphenyl) methane,
Bis (4-hydroxyphenyl) cyclohexylmethane,
Bis (4-hydroxyphenyl) phenylmethane,
Bis (4-hydroxyphenyl) (4-propenylphenyl) methane,
Bis (4-hydroxyphenyl) diphenylmethane,
Bis (4-hydroxyphenyl) naphthylmethane,
1,1-bis (4-hydroxyphenyl) ethane,
1,1-bis (4-hydroxyphenyl) -1-phenylethane,
1,1-bis (4-hydroxyphenyl) -1-naphthylethane,
1,1-bis (4-hydroxyphenyl) butane,
2,2-bis (4-hydroxyphenyl) butane,
2,2-bis (4-hydroxyphenyl) pentane,
1,1-bis (4-hydroxyphenyl) hexane,
2,2-bis (4-hydroxyphenyl) hexane,
1,1-bis (4-hydroxyphenyl) octane,
2,2-bis (4-hydroxyphenyl) octane,
4,4-Bis (4-hydroxyphenyl) heptane,
2,2-bis (4-hydroxyphenyl) nonane,
1,1-bis (4-hydroxyphenyl) decane,
1,1-bis (4-hydroxyphenyl) dodecane,
Bis (hydroxyaryl) alkanes such as;

1,1-bis (4-hydroxyphenyl) cyclopentane,
1,1-bis (4-hydroxyphenyl) cyclohexane,
1,1-bis (4-hydroxyphenyl) -3,3-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,4-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,5-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane,
1,1-bis (4-hydroxy-3,5-dimethylphenyl) -3,3,5-trimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3-propyl-5-methylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3-tert-butyl-cyclohexane,
1,1-bis (4-hydroxyphenyl) -4-tert-butyl-cyclohexane,
1,1-bis (4-hydroxyphenyl) -3-phenylcyclohexane,
1,1-bis (4-hydroxyphenyl) -4-phenylcyclohexane,
Bis (hydroxyaryl) cycloalkanes such as;

9,9-bis (4-hydroxyphenyl) fluorene,
Cardo-structure-containing bisphenols such as 9,9-bis (4-hydroxy-3-methylphenyl) fluorene;

4,4'-Dihydroxydiphenylsulfide,
Dihydroxydiarylsulfides such as 4,4'-dihydroxy-3,3'-dimethyldiphenylsulfide;

Dihydroxydiarylsulfoxides such as 4,4'-dihydroxydiphenylsulfoxide, 4,4'-dihydroxy-3,3'-dimethyldiphenylsulfoxide;

4,4'-Dihydroxydiphenyl sulfone,
Dihydroxydiaryl sulfones such as 4,4'-dihydroxy-3,3'-dimethyldiphenyl sulfone;
And so on.

Among these, bis (hydroxyaryl) alkanes are preferable, and bis (4-hydroxyphenyl) alkanes are particularly preferable, and 2,2-bis (4-hydroxyphenyl) propane (particularly from the viewpoint of impact resistance and heat resistance). That is, bisphenol A) is preferable.
As the aromatic dihydroxy compound, one type may be used, or two or more types may be used in any combination and ratio.

Further, to give an example of a monomer which is a raw material of an aliphatic polycarbonate resin,
Ethan-1,2-diol, propane-1,2-diol, propane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2-methyl-2-propylpropane-1,3- Alkanediols such as diol, butane-1,4-diol, pentane-1,5-diol, hexane-1,6-diol, decane-1,10-diol;

Cyclopentane-1,2-diol, cyclohexane-1,2-diol, cyclohexane-1,4-diol, 1,4-cyclohexanedimethanol, 4- (2-hydroxyethyl) cyclohexanol, 2,2,4 Cycloalkanediols such as 4-tetramethyl-cyclobutane-1,3-diol;

Glycols such as ethylene glycol, 2,2'-oxydiethanol (ie, diethylene glycol), triethylene glycol, propylene glycol, spiroglycol;

1,2-benzenedimethanol, 1,3-benzenedimethanol, 1,4-benzenedimethanol, 1,4-benzenediethanol, 1,3-bis (2-hydroxyethoxy) benzene, 1,4-bis ( 2-Hydroxyethoxy) benzene, 2,3-bis (hydroxymethyl) naphthalene, 1,6-bis (hydroxyethoxy) naphthalene, 4,4'-biphenyldimethanol, 4,4'-biphenyldiethanol, 1,4- Aralkyldiols such as bis (2-hydroxyethoxy) biphenyl, bisphenol A bis (2-hydroxyethyl) ether, bisphenol S bis (2-hydroxyethyl) ether;

1,2-epoxyethane (ie, ethylene oxide), 1,2-epoxypropane (ie, propylene oxide), 1,2-epoxycyclopentane, 1,2-epoxycyclohexane, 1,4-epoxycyclohexane, 1-methyl Cyclic ethers such as -1,2-epoxycyclohexane, 2,3-epoxy norbornane, and 1,3-epoxypropane; and the like.

Among the monomers used as raw materials for the polycarbonate resin, carbonyl halides, carbonate esters and the like are used as examples of carbonate precursors. As the carbonate precursor, one kind may be used, or two or more kinds may be used in any combination and ratio.

Specific examples of the carbonyl halide include phosgene; a bischloroformate of a dihydroxy compound, a haloformate of a monochloroformate of a dihydroxy compound, and the like.

Specific examples of the carbonate ester include diaryl carbonates such as diphenyl carbonate and ditril carbonate; dialkyl carbonates such as dimethyl carbonate and diethyl carbonate; biscarbonate of dihydroxy compound, monocarbonate of dihydroxy compound, and cyclic carbonate. Examples thereof include carbonates of dihydroxy compounds such as.

The method for producing the polycarbonate resin is not particularly limited, and any method can be adopted. Examples thereof include an interfacial polymerization method, a melt transesterification method, a pyridine method, a ring-opening polymerization method of a cyclic carbonate compound, and a solid phase transesterification method of a prepolymer.

The molecular weight of the polycarbonate resin (A) is preferably in the range of 16,000 to 50,000 in terms of viscosity average molecular weight (Mv), more preferably 18,000 or more, still more preferably 20,000 or more, still more preferably 45,000 or less, still more preferably. Is 40,000, particularly preferably 38,000 or less. If the viscosity average molecular weight is smaller than 16000, the impact resistance of the molded product tends to decrease and cracks may occur, which is not preferable. If the viscosity average molecular weight is larger than 50,000, the fluidity deteriorates and the moldability becomes a problem. It is not preferable because it is easy.
The polycarbonate resin (A) may be used by mixing two or more types of polycarbonate resins having different viscosity average molecular weights. In this case, a polycarbonate resin having a viscosity average molecular weight outside the above-mentioned suitable range is mixed. You may.

In the present invention, the viscosity average molecular weight [Mv] of the polycarbonate resin is the ultimate viscosity [η] (unit: dl / g) at a temperature of 20 ° C. using a Ubbelohde viscometer using methylene chloride as a solvent. , Schnell's viscosity formula, ie
It means a value calculated from η = 1.23 × 10 ^-4 Mv ^0.83. The ultimate viscosity [η] is a value calculated by the following formula by measuring _{the specific viscosity [η sp} ] at each solution concentration [C] (g / dl).

Further, in the present invention, the polycarbonate resin may be used in combination with another thermoplastic resin. Further, for example, a polycarbonate resin is used as a copolymer with an oligomer or polymer having a siloxane structure for the purpose of further improving flame retardancy and impact resistance; a phosphorus atom for the purpose of further improving thermal oxidation stability and flame retardancy. Copolymer with a monomer, oligomer or polymer having a dihydroxyanthraquinone structure; a copolymer with a monomer, oligomer or polymer having a dihydroxyanthraquinone structure for the purpose of improving thermal oxidation stability; Even if it is configured as a copolymer mainly composed of a polycarbonate resin, such as a copolymer with an oligomer or a polymer having an olefin structure; a copolymer with a polyester resin oligomer or a polymer for the purpose of improving chemical resistance; good.

Further, in order to improve the appearance and fluidity of the molded product, the polycarbonate resin may contain a polycarbonate oligomer. The viscosity average molecular weight (Mv) of this polycarbonate oligomer is usually 1500 or more, preferably 2000 or more, and usually 9500 or less, preferably 9000 or less. Further, the contained polycarbonate ligomer is preferably 30% by mass or less of the polycarbonate resin (including the polycarbonate oligomer).

Further, the polycarbonate resin may be not only a virgin raw material but also a polycarbonate resin recycled from a used product (so-called material recycled polycarbonate resin).
However, the regenerated polycarbonate resin is preferably 80% by mass or less, and more preferably 50% by mass or less of the polycarbonate resin. Since the regenerated polycarbonate resin is likely to be deteriorated by heat deterioration, aging deterioration, etc., if such a polycarbonate resin is used in a larger amount than the above range, the hue and mechanical properties can be deteriorated. Because it has sexual characteristics.

[Ultraviolet absorber (B1)]
The polycarbonate resin composition of the present invention contains an ultraviolet absorber (B1) having a maximum absorption wavelength of 375 nm or more in the absorption curve obtained from the following formula (1) in accordance with JIS K7105.
[Absorptivity of Polycarbonate Resin Containing 0.005% by Mass of UV Absorbant]-[Asorbance of Polycarbonate Resin Only] ... (1)

In the present invention, the maximum absorption wavelength of the ultraviolet absorber (B1) is the same polycarbonate resin as the absorbance of the polycarbonate resin containing 0.005% by mass of the ultraviolet absorber according to the above formula (1). It is defined as the maximum absorption wavelength of the absorption curve obtained by subtracting the absorbance of a flat molded product having the same shape and the same thickness as the polycarbonate resin containing no ultraviolet absorber. It is considered in principle that the maximum absorption wavelength defined in this way does not change depending on the thickness of the flat plate-shaped test piece used, but in the present invention, it is preferable to compare with a thickness of 2 mm.
The maximum absorption wavelengths of the ultraviolet absorbers (B2) and (B3) described later are also synonymous.
Further, the specific conditions and the like of the method for measuring and determining the maximum absorption wavelength are as described in the examples.

The maximum absorption wavelength of the ultraviolet absorber (B1) is 375 nm or more, but the upper limit thereof is preferably 420 nm or less, more preferably 400 nm or less.

一般式（１）中のＸはハロゲン原子であるが、好ましくは塩素、臭素、フッ素、ヨウ素などのハロゲン原子であり、より好ましくは塩素原子であり、具体的には、６−（５−クロロ−２Ｈ−ベンゾトリアゾール−２−イル）ベンゾ［１，３］ジオキソール−５−オールが好ましい。 Examples of such an ultraviolet absorber (B1) include benzotriazole-based compounds, benzophenone-based compounds, triazine-based compounds, benzoate-based compounds, salicylate phenyl ester-based compounds, cyanoacrylate-based compounds, malonic acid ester-based compounds, and oxalic acid anilide. A compound having a maximum absorption wavelength of 375 nm or more is selected from among the compounds, but a benzotriazole-based ultraviolet absorber is preferable, and a sesamole group (benzo [1,3] -dioxol-5-ol group) is more preferable. It is a benzotriazole-based ultraviolet absorber having the above, and is particularly preferably an ultraviolet absorber represented by the following general formula (1).

Although X in the general formula (1) is a halogen atom, it is preferably a halogen atom such as chlorine, bromine, fluorine, or iodine, more preferably a chlorine atom, and specifically, 6- (5-chloro). -2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol is preferred.

The content of the ultraviolet absorber (B1) is 0.02 to 1 part by mass with respect to 100 parts by mass of the polycarbonate resin (A). If the content is less than 0.02 parts by mass, the transmittance of the obtained resin composition in the 400 to 420 nm wavelength range becomes too high, and if it exceeds 1 part by mass, the transmittance in the 400 to 420 nm wavelength range becomes low. Gas generation during molding becomes remarkable, and volatile matter adheres to the molded product, which significantly impairs the appearance of the product. The preferable content of the ultraviolet absorber (B1) is 0.025 parts by mass or more, more preferably 0.8 parts by mass or less, more preferably 0.7 parts by mass or less, and further, with respect to 100 parts by mass of the polycarbonate resin (A). Is preferably 0.6 parts by mass or less.

[Ultraviolet absorber (B2)]
The polycarbonate resin composition of the present invention further conforms to JIS K7105, and is a benzotriazole-based ultraviolet absorber (B2) having a sesamol group in which the maximum absorption wavelength of the absorption curve obtained from the above formula (1) is 360 nm or more and less than 375 nm. Is preferably contained.
By containing the ultraviolet absorber (B2), when the ultraviolet absorber (B1) is contained in a small amount, the transmittance in the vicinity of 320 nm becomes high and the tendency to squeeze can be improved.

A benzotriazole-based ultraviolet absorber (B2) having a sesamol group having a maximum absorption wavelength of 360 nm or more and less than 375 nm of the absorption curve obtained from the above formula (1) in accordance with JIS K7105 is represented by the following general formula (2). It is an ultraviolet absorber that is used.

（一般式（２）中、Ｒは水素原子、炭素数１〜８のアルキル基、炭素数１〜８のアルコキシ基、ヒドロキシル基、カルボキシル基、アルキル基の炭素数が１〜８のアルキルオキシカルボニル基、炭素数１〜８のヒドロキシアルキル基又はアルキル基の炭素数が各々１〜８のアルキルカルボニルオキシアルキル基を表す。）

(In the general formula (2), R is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, a hydroxyl group, a carboxyl group, and an alkyloxycarbonyl having an alkyl group having 1 to 8 carbon atoms. A group, a hydroxyalkyl group having 1 to 8 carbon atoms, or an alkylcarbonyloxyalkyl group having 1 to 8 carbon atoms in each of the alkyl groups.)

Specific examples of R in the general formula (2) include hydrogen atom; methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group, n-hexyl. A linear or branched alkyl group having 1 to 8 carbon atoms which may be substituted, such as a group, an n-octyl group, a 2-ethylhexyl group, etc .; a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, an n-butoxy group, A linear or branched alkoxy group having 1 to 8 carbon atoms which may be substituted, such as an isobutoxy group, a sec-butoxy group, a tert-butoxy group, an n-hexyloxy group, an n-octyloxy group, and a 2-ethylhexyloxy group. Hydroxyl group; carboxyl group; methoxycarbonyl group, ethoxycarbonyl group, isopropoxycarbonyl group, n-butoxycarbonyl group, isobutoxycarbonyl group, sec-butoxycarbonyl group, tert-butoxycarbonyl group, n-hexyloxycarbonyl group, A linear or branched alkyloxycarbonyl group having 1 to 8 carbon atoms of an alkyl group which may be substituted, such as an n-octyloxycarbonyl group, a 2-ethylhexyloxycarbonyl group; a hydroxymethyl group, a hydroxyethyl group, a hydroxypropyl group. , A linear or branched hydroxyalkyl group having 1 to 8 carbon atoms which may be substituted, such as a hydroxybutyl group, a hydroxyhexyl group, a hydroxyoctyl group; a methylcarbonyloxymethyl group, an ethylcarbonyloxymethyl group, a propylcarbonyloxymethyl group. Group, butylcarbonyloxymethyl group, hexylcarbonyloxymethyl group, heptylcarbonyloxymethyl group, octylcarbonyloxymethyl group, methylcarbonyloxyethyl group, ethylcarbonyloxyethyl group, propylcarbonyloxyethyl group, butylcarbonyloxyethyl group, Examples thereof include linear or branched alkylcarbonyloxyalkyl groups having 1 to 8 carbon atoms in the alkyl groups which may be substituted, such as a hexylcarbonyloxyethyl group, a heptylcarbonyloxyethyl group, and an octylcarbonyloxyethyl group. ..

Among the above, R is preferably a hydrogen atom, an alkyl group, an alkoxy group, a hydroxyl group, a carboxyl group, an alkyloxycarbonyl group, a hydroxyalkyl group or an alkylcarbonyloxyalkyl group. More preferably, a hydrogen atom, a methyl group, a methoxy group, an n-octyloxy group, a hydroxyl group, a carboxyl group, a methoxycarbonyl group, an n-octyloxycarbonyl group, a hydroxyethyl group, a methylcarbonyloxyethyl group, and a heptylcarbonyloxyethyl group. Is.

Preferred examples of the compound represented by the general formula (2) and having a maximum absorption wavelength of 360 nm or more and less than 375 nm include 6- (2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol. 6- (5-n-Heptylcarbonyloxyethyl-2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol, 6- (5-isoheptylcarbonyloxyethyl-2H-benzotriazole-2) -Il) benzo [1,3] dioxotol-5-ol, 6- (5-methyl-2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol, 6- (5-methoxy-) 2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol, 6- (5-hydroxy-2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol, 6 -(5-octyloxy-2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol, 6- (5-carboxy-2H-benzotriazole-2-yl) benzo [1,3] Dioxol-5-ol, 6- (5-hydroxyethyl-2H-benzotriazole-2-yl) benzo [1,3] dioxol-5-ol, 6- (5-methylcarbonyloxyethyl-2H-benzotriazole- 2-Il) Benzotriazole [1,3] dioxol-5-ol and the like can be mentioned.

Among these, 6- (2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol, 6- (5-n-heptylcarbonyloxyethyl-2H-benzotriazole-2-yl) benzo [1,3] Dioxotol-5-ol and 6- (5-isoheptylcarbonyloxyethyl-2H-benzotriazole-2-yl) benzo [1,3] dioxotol-5-ol are particularly preferable.

The preferable content of the ultraviolet absorber (B2) is 0.01 part by mass or more and less than 0.08 part by mass with respect to 100 parts by mass of the polycarbonate resin (A). If it is less than 0.01 parts by mass, transmission of the obtained resin composition is likely to occur in the vicinity of the wavelength of 320 nm, and if it is more than 0.08 parts by mass, gas is likely to be generated during molding and the appearance of the product is likely to be spoiled. The content of the ultraviolet absorber (B2) is more preferably 0.02 parts by mass or more, further preferably 0.03 parts by mass or more, and 0.07 parts by mass or less with respect to 100 parts by mass of the polycarbonate resin (A). Is more preferable, 0.05 parts by mass or less is further preferable, and 0.04 parts by mass or less is particularly preferable.

[Ultraviolet absorber (B3)]
The polycarbonate resin composition of the present invention further preferably contains an ultraviolet absorber (B3) having a maximum absorption wavelength of less than 360 nm in the absorption curve obtained from the above formula (1) in accordance with JIS K7105.
By containing the ultraviolet absorber (B3), when the ultraviolet absorber (B1) is contained in a small amount, the transmittance in the vicinity of 320 nm becomes high and the tendency to squeeze can be improved.

Examples of the ultraviolet absorber (B3) include benzotriazole compounds, benzophenone compounds, triazine compounds, benzoxazine compounds, benzoate compounds, salicylate phenyl ester compounds, cyanoacrylate compounds, and malonic acid ester compounds. Examples thereof include oxalic acid anilide compounds. Of these, benzotriazole-based compounds, triazine-based compounds, malonic acid ester-based compounds, and benzoxazine-based compounds are preferable. These may be used alone or in two or more kinds.

Examples of the hydroxybenzophenone compound include 2-hydroxy-4-octoxybenzophenone.
Examples of malonic acid ester compounds include dimethyl (p-methoxybenzylidene) malonate, 2- (1-arylalkylidene) malonic acid esters, tetraethyl-2,2'-(1,4-phenylene-dimethylidene) -bismalonate and the like. Can be mentioned.
Examples of the triazine-based compound include 2- (4,6-diphenyl-1,3,5-triazine-2-yl) -5-[(hexyl) oxy] -phenol.
Examples of the benzoate compound include 2,4-di-t-butylphenyl-3,5-di-t-butyl-4-hydroxybenzoate.
Examples of the benzoxazine-based compound include 2,2'-(1,4-phenylene) bis (4H-3,1-benzoxazine-4-one) and the like.

As the ultraviolet absorber (B3), a benzotriazole-based ultraviolet absorber is more preferable, and a benzotriazole-based compound having no sesamol group is particularly preferable. More specific examples of such benzotriazole-based compounds include, for example, 2- (2-hydroxy-5-t-octylphenyl) -2H-benzotriazole, 2- (3-t-butyl-2-hydroxy). -5-Methylphenyl) -5-chloro-2H-benzotriazole, 2- [5-chloro (2H) -benzotriazole-2-yl] -4-methyl-6- (t-butyl) phenol, 2,4 -Di-tert-butyl-6- (5-chlorobenzotriazole-2-yl) phenol, (2- [5-chloro (2H) -benzotriazole-2-yl] -4,6-di (tert-pentyl) ) Phenol), 3- [3-tert-butyl-5- (5-chloro-2H-benzotriazole-2-yl) -4-hydroxyphenyl] octyl propionate, 2- (3-t-butyl-5) -Methyl-2-hydroxyphenyl) -5-chlorobenzotriazole, 2- (2H-benzotriazole-2-yl) -6-dodecyl-4-methylphenol, 2- (2H-benzotriazole-2-yl)- P-cresol, 2-[(2H) -benzotriazole-2-yl] -4,6-bis- (1-methyl-1-phenylethyl) phenol and the like are preferably mentioned.

The preferable content of the ultraviolet absorber (B3) is 0.01 to 0.2 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). If it is less than 0.01 parts by mass, transmission of the obtained resin composition is likely to occur in the vicinity of the wavelength of 320 nm, and if it exceeds 0.2 parts by mass, gas is likely to be generated during molding and the appearance of the product is likely to be spoiled. The content of the ultraviolet absorber (B3) is more preferably 0.02 parts by mass or more, still more preferably 0.03 parts by mass or more, and 0.15 parts by mass or less with respect to 100 parts by mass of the polycarbonate resin (A). Is more preferable.

[Stabilizer (C)]
The polycarbonate resin composition of the present invention contains a stabilizer. Examples of the stabilizer include a phosphorus-based stabilizer, a phenol-based stabilizer, and a sulfur-based stabilizer.

[Phosphorus stabilizer]
By containing a phosphorus-based stabilizer, the polycarbonate resin composition of the present invention has a good hue of the polycarbonate resin composition, and further improves heat-resistant discoloration.
Any known phosphorus-based stabilizer can be used. Specific examples include phosphoric acid, phosphonic acid, phosphite, phosphinic acid, polyphosphoric acid and other phosphorus oxo acids; acidic sodium pyrophosphate, potassium pyrophosphate, acidic calcium pyrophosphate and other acidic pyrophosphate metal salts; phosphoric acid. Phosphate compounds of Group 1 or Group 2B metals such as potassium, sodium phosphate, cesium phosphate, zinc phosphate; phosphate compounds, phosphite compounds, phosphonite compounds and the like can be mentioned, with phosphite compounds being particularly preferred. By selecting the phosphite compound, a polycarbonate resin composition having higher discoloration resistance and continuous productivity can be obtained.

Here, the phosphite compound is a _{trivalent phosphorus compound represented by the general formula: P (OR) 3} , and R represents a monovalent or divalent organic group.
Examples of such phosphite compounds include triphenyl phosphite, tris (monononylphenyl) phosphite, tris (monononyl / dinonyl-phenyl) phosphite, and tris (2,4-di-tert-butylphenyl) phos. Fight, monooctyldiphenylphosphite, dioctylmonophenylphosphite, monodecyldiphenylphosphite, didecylmonophenylphosphite, tridecylphosphite, trilaurylphosphite, tristearylphosphite, distearylpentaerythritol diphosphite, Bis (2,4-di-tert-butyl-4-methylphenyl) pentaerythritol phosphite, bis (2,6-di-tert-butylphenyl) octylphosphite, 2,2-methylenebis (4,6-di) -Tert-Butylphenyl) octylphosphite, tetrakis (2,4-di-tert-butylphenyl) -4,4'-biphenylene-diphosphite, 6- [3- (3-tert-butyl-hydroxy-5-methyl) Phenyl) propoxy] -2,4,8,10-tetra-tert-butyldibenzo [d, f] [1,3,2] -dioxaphosfepine and the like.

Among such phosphite compounds, the aromatic phosphite compound represented by the following general formula (3) or (4) is more effective because the heat-resistant discoloration property of the polycarbonate resin composition of the present invention is effectively enhanced. preferable.

（式中、Ｒ^１、Ｒ^２及びＲ^３は、それぞれ同一であっても異なっていてもよく、炭素数６以上３０以下のアリール基を表す。）

(In the formula, R ¹ , R ² and R ³ may be the same or different, respectively, and represent an aryl group having 6 or more and 30 or less carbon atoms.)

（式中、Ｒ^４及びＲ^５は、それぞれ同一であっても異なっていてもよく、炭素数６以上３０以下のアリール基を表す。）

(In the formula, R ⁴ and R ⁵ may be the same or different, respectively, and represent an aryl group having 6 or more and 30 or less carbon atoms.)

As the phosphite compound represented by the above formula (3), triphenylphosphine, tris (monononylphenyl) phosphite, tris (2,4-di-tert-butylphenyl) phosphite and the like are preferable, and among them, triphenylphosphine and tris (2,4-di-tert-butylphenyl) phosphite are preferable. Tris (2,4-di-tert-butylphenyl) phosphite is more preferred.

Examples of the phosphite compound represented by the above formula (4) include bis (2,4-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite and bis (2,6-di-tert-butyl). Those having a pentaerythritol diphosphite structure such as -4-methylphenyl) pentaerythritol diphosphite and bis (2,4-dicumylphenyl) pentaerythritol diphosphite are particularly preferable.

Among the phosphite compounds, the aromatic phosphite compound represented by the above formula (4) is more preferable because it has a more excellent hue.
The phosphorus-based stabilizer may contain one type or two or more types in any combination and ratio.

The content of the phosphorus-based stabilizer is 0.01 to 0.5 parts by mass, preferably 0.02 parts by mass or more, and more preferably 0.03 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). It is more preferably 0.4 parts by mass or less, more preferably 0.3 parts by mass or less, still more preferably 0.2 parts by mass or less. If the content of the phosphorus-based stabilizer is less than 0.005 parts by mass, the hue and heat-resistant discoloration property become insufficient, and if it exceeds 0.5 parts by mass, not only the heat-resistant discoloration property deteriorates but also the heat-resistant discoloration property deteriorates. Moist heat stability is also reduced.

[Phenolic stabilizer]
The polycarbonate resin composition of the present invention may contain a phenolic stabilizer as a stabilizer. Examples of the phenolic stabilizer include hindered phenolic antioxidants. Specific examples thereof include pentaerythritol tetrakis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] and octadecyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl). ) Propionate, thiodiethylenebis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate], N, N'-hexane-1,6-diylbis [3- (3,5-di-) tert-Butyl-4-hydroxyphenylpropionamide), 2,4-dimethyl-6- (1-methylpentadecyl) phenol, diethyl [[3,5-bis (1,1-dimethylethyl) -4-hydroxyphenyl) ] Methyl] Phosphoate, 3,3', 3'', 5,5', 5''-Hexa-tert-butyl-a, a', a''-(mesitylen-2,4,6-triyl) tri -P-cresol, 4,6-bis (octylthiomethyl) -o-cresol, ethylenebis (oxyethylene) bis [3- (5-tert-butyl-4-hydroxy-m-tolyl) propionate], hexamethylene Bis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate], 1,3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) -1,3 , 5-Triazine-2,4,6 (1H, 3H, 5H) -trione, 2,6-di-tert-butyl-4- (4,6-bis (octylthio) -1,3,5-triazine- Examples thereof include 2-ylamino) phenol and 2- [1- (2-hydroxy-3,5-di-tert-pentylphenyl) ethyl] -4,6-di-tert-pentylphenyl acrylate.

Of these, pentaerythritol tetrakis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] and octadecyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate are preferable. .. Specific examples of such phenolic antioxidants include BASF's "Irganox 1010" and "Irganox 1076", ADEKA's "ADEKA STAB AO-50" and "ADEKA STAB AO-60". Can be mentioned.
In addition, 1 type may be contained in the phenol-based stabilizer, and 2 or more types may be contained in arbitrary combinations and ratios.

The content of the phenol-based stabilizer is 0.01 to 0.5 parts by mass, preferably 0.02 parts by mass or more, and more preferably 0.03 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). It is more preferably 0.4 parts by mass or less, more preferably 0.3 parts by mass or less, still more preferably 0.2 parts by mass or less. If the content of the phenolic stabilizer is less than the lower limit of the above range, the effect as the phenolic stabilizer may be insufficient, and the content of the phenolic stabilizer exceeds the upper limit of the above range. In that case, the effect may reach a plateau and become uneconomical.

Phosphorus-based stabilizers and phenol-based stabilizers may be used in combination. In that case, the total content of the phosphorus-based stabilizer and the phenol-based stabilizer is 0.01 to 0.5 parts by mass, preferably 0.02 parts by mass or more, based on 100 parts by mass of the polycarbonate resin (A). , More preferably 0.03 parts by mass or more, preferably 0.4 parts by mass or less, more preferably 0.3 parts by mass or less, still more preferably 0.2 parts by mass or less.

[Sulfur stabilizer]
Examples of the sulfur-based stabilizer include dilauryl-3,3'-thiodipropionic acid ester, ditridecyl-3,3'-thiodipropionic acid ester, dimyristyl-3,3'-thiodipropionic acid ester, and distearyl. -3,3'-thiodipropionic acid ester, laurylstearyl-3,3'-thiodipropionic acid ester, pentaerythritol tetrakis (3-laurylthiopropionate), bis [2-methyl-4- (3-) Laurylthiopropionyloxy) -5-tert-butylphenyl] sulfide, octadecyldisulfide, mercaptobenzimidazole, 2-mercapto-6-methylbenzimidazole, 1,1'-thiobis (2-naphthol) and the like can be mentioned.

Of the above, pentaerythritol tetrakis (3-laurylthiopropionate) is preferable. Specific examples of such a sulfur-based stabilizer include "ADEKA STAB AO-412S" manufactured by ADEKA Corporation.

The content of the sulfur-based stabilizer is 0.01 to 0.5 parts by mass, preferably 0.02 parts by mass or more, and more preferably 0.03 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). It is more preferably 0.4 parts by mass or less, more preferably 0.3 parts by mass or less, still more preferably 0.2 parts by mass or less. If the content of the sulfur-based stabilizer is less than the lower limit of the above range, the effect as the sulfur-based stabilizer may be insufficient, and the content of the sulfur-based stabilizer exceeds the upper limit of the above range. In that case, the effect may reach a plateau and become uneconomical.

[Additives, etc.]
The polycarbonate resin composition of the present invention has other additives other than those described above, such as a mold release agent, a fluorescent whitening agent, a pigment, a dye, a flame retardant, an impact resistance improver, an antistatic agent, a plasticizer, and a compatibilization agent. It can contain additives such as agents and polymers other than polycarbonate resins. These additives or other resins may be used alone or in combination of two or more.

[Manufacturing method of polycarbonate resin composition]
The method for producing the polycarbonate resin composition of the present invention is not limited, and a known method for producing the polycarbonate resin composition can be widely adopted. Polycarbonate resin (A), ultraviolet absorber (B1) and phosphorus-based stabilizer (C), In addition, other components to be blended as necessary are premixed using various mixers such as a tumbler and a Henschel mixer, and then a Banbury mixer, a roll, a brabender, a single-screw kneading extruder, and a twin-screw kneading extruder. , A method of melt-kneading with a mixer such as a kneader. The temperature of melt-kneading is not particularly limited, but is usually in the range of 240 to 320 ° C.

The polycarbonate resin composition of the present invention can produce various molded products by molding pellets obtained by pelletizing the above-mentioned polycarbonate resin composition by various molding methods. It is also possible to directly mold the resin melt-kneaded by an extruder without passing through pellets to obtain a molded product.

The polycarbonate resin composition of the present invention has a transmittance of 25% or less measured at a wavelength of 420 nm in accordance with JIS K7105 for a molded product having a thickness of 2 mm obtained by molding this polycarbonate resin composition. Is preferable, 10% or less is more preferable, 5% or less is further preferable, and 1% or less is particularly preferable. If the transmittance at a wavelength of 420 nm exceeds 25%, it is insufficient as a material for sunglasses lenses and the like aiming at cutting in the wavelength range of 400 to 420 nm.

The molded product obtained from the polycarbonate resin composition of the present invention has excellent cutability of wavelength light of 400 to 420 nm, which is on the more visible light side, in addition to ultraviolet light, and has no problem of gas generation during molding. It has various excellent mechanical and thermal properties of polycarbonate resin. Therefore, the application can be widely and suitably used in applications where deterioration due to ultraviolet rays is a concern, and examples thereof include sheets, films, miscellaneous goods, home appliance parts, automobile parts, building materials, hollow containers, and the like. More specifically, for example, eyeglass lenses, sunglasses lenses, goggles (for skiing, etc.), protective glasses, protective facets, roof panels such as arcades, indoor pools, carports, sun roofs, signal lights, sound insulation walls, automobile sides, etc. A window, a rear window, a solar cell housing, a street light cover and the like are preferably mentioned.

Hereinafter, the present invention will be described in more detail with reference to Examples. However, the present invention is not construed as being limited to the following examples.

The raw materials and evaluation methods used in the following examples and comparative examples are as follows.

In Table 1 above, the maximum absorption wavelength of the ultraviolet absorber is the absorbance A _λ of the polycarbonate resin composition shown in Table 1 containing 0.005% of each ultraviolet absorber and does not contain the ultraviolet absorber. respectively obtained absorbance a _.lambda.0 polycarbonate resin of table 1, the maximum absorption wavelength derived from the absorption curve of the absorbance obtained by subtracting the absorbance a _.lambda.0 from the absorbance _{a λ (a λ -A λ0)} . The absorbance A _λ and the absorbance A _λ0 were measured in the same manner as described in [Measurement of Transmittance and Absorbance] below.

(Examples 6 to 7, Reference Examples 1 to 5, 8 to 22, Comparative Examples 1 to 9)
[Manufacturing of resin composition pellets]
Each component listed in Table 1 above is blended in the proportions (parts by mass) shown in Table 2 and below, mixed in a tumbler for 20 minutes, and then a single-screw extruder with a vent (Tanabe Plastic Machinery) with a screw diameter of 40 mm. The company "VS-40") was melt-kneaded at a cylinder temperature of 280 ° C., and pellets of a polycarbonate resin composition were obtained by strand cutting.

[Measurement of transmittance and absorbance]
The obtained pellets are dried at 120 ° C. for 5 hours with a hot air circulation type dryer, and then molded with an injection molding machine (“SE50DUZ” manufactured by Sumitomo Heavy Industries, Ltd.) at a resin temperature of 280 ° C. and a mold temperature of 80 ° C. Under the condition of a cycle of 30 seconds, a three-stage stepped flat plate-shaped test piece having a width of 50 mm and a length of 90 mm and a thickness of 1 mm, 2 mm and 3 mm was formed.
In accordance with JIS K7105, the transmittance and absorbance of a 2 mm thick portion of the stepped flat plate test piece were measured using a spectrophotometer (“UV-3100PC” manufactured by Shimadzu Corporation).
The transmittances (unit:%) at 420 nm, 380 nm and 320 nm are shown in Table 2 and below.

[Evaluation of gas generation during molding]
The pellets obtained above are dried at 120 ° C. for 5 hours, and then the cylinder temperature is adjusted using an injection molding machine (“SE18DUZ” manufactured by Sumitomo Heavy Industries, Ltd.) and a drop mold shown in FIG. 100 shot injection molding was performed under the conditions of 320 ° C., molding cycle 10 seconds, and mold temperature 80 ° C., and the state of stains due to white deposits generated on the metal mirror surface on the mold fixing side after completion was compared with Comparative Example 2. Based on the following criteria, the evaluation was visually evaluated and used as the evaluation of gas generation during molding.
A: The amount of deposits on the mold is much less than that after 100-shot molding in Comparative Example 2, and the mold contamination resistance is extremely good.
B: The amount of deposits on the mold is less than that after 100-shot molding in Comparative Example 2, but the mold stain resistance is slightly observed.
C: The mold deposits are at the same level as the state after 100 shot molding of Comparative Example 2, and mold contamination is observed.
D: The amount of deposits on the mold is larger than that after 100-shot molding in Comparative Example 2, and mold contamination is significantly observed.

The drop mold of FIG. 1 is a mold designed so that the resin composition is introduced from the gate G and the generated gas easily accumulates in the tip P portion. The width of the gate G is 1 mm and the thickness is 1 mm. In FIG. 1, the width h1 is 14.5 mm, the length h2 is 7 mm, the length h3 is 27 mm, and the thickness of the molded portion is 3 mm.
The above evaluation results are shown in Table 2 and below.

The molded product obtained from the polycarbonate resin composition of the present invention has excellent cutability of light having a wavelength of 400 to 420 nm, which is on the more visible light side, in addition to ultraviolet light, and has no problem of gas generation during molding. It has various excellent mechanical and thermal properties of polycarbonate resin, can be suitably used for applications where deterioration due to ultraviolet rays is a concern, and has high industrial utility.

Claims (4)

0.02 to 0.1 parts by mass of an ultraviolet absorber (B1) having a maximum absorption wavelength of 375 nm or more in the absorption curve obtained from the following formula in accordance with JIS K7105 with respect to 100 parts by mass of the polycarbonate resin (A), JIS A benzotriazole-based ultraviolet absorber (B2) having a sesamole group having a maximum absorption wavelength of 360 nm or more and less than 375 nm obtained from the following formula according to K7105 is 0.01 part by mass or more and less than 0.08 part by mass, and Containing 0.01 to 0.5 parts by mass of the stabilizer (C),
The ultraviolet absorber (B1) is a benzotriazole-based ultraviolet absorber having a sesamol group represented by the following general formula (1).
A polycarbonate resin composition according to JIS K7105, wherein a molded product having a thickness of 2 mm is measured at a wavelength of 420 nm and has a transmittance of 25% or less.
[Absorbance of polycarbonate resin containing 0.005% by mass of UV absorber]-[Asorbance of polycarbonate resin only]

(In the formula, X represents a halogen atom.) Further, the ultraviolet absorber (B3) having a maximum absorption wavelength of less than 360 nm obtained from the above formula in accordance with JIS K7105 is 0.01 to 0.2 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). The polycarbonate resin composition according to claim 1. Claim that the ultraviolet absorber (B3) is at least one selected from a benzotriazole-based ultraviolet absorber having no sesamole group, a triazine-based ultraviolet absorber, a malonic acid ester-based ultraviolet absorber, and a benzoxazine-based ultraviolet absorber. 2. The polycarbonate resin composition according to 2. A molded product of the polycarbonate resin composition according to any one of claims 1 to 3.

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