JP7011900B2 - Textile products and their manufacturing methods - Google Patents
Textile products and their manufacturing methods Download PDFInfo
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- JP7011900B2 JP7011900B2 JP2017102375A JP2017102375A JP7011900B2 JP 7011900 B2 JP7011900 B2 JP 7011900B2 JP 2017102375 A JP2017102375 A JP 2017102375A JP 2017102375 A JP2017102375 A JP 2017102375A JP 7011900 B2 JP7011900 B2 JP 7011900B2
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/04—Compacting
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/18—Separating or spreading
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
- D06M15/295—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing fluorine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2139—Coating or impregnation specified as porous or permeable to a specific substance [e.g., water vapor, air, etc.]
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Coloring (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Description
本発明は、セルロース撥水繊維を含む繊維集合体とその製造方法及びこれを用いた繊維製品に関する。 The present invention relates to a fiber aggregate containing cellulose water-repellent fibers, a method for producing the same, and a fiber product using the same.
スポーツ衣料、夏用衣料など多量に汗をかくときに着用する衣料には撥水処理をした繊維衣料が使用される。この用途に使用される多くの衣料は、ポリエステルなどの合成繊維衣料を使用し、撥水処理して速乾性を高めたものである。特許文献１には、撥水処理したポリエステル短繊維束と、撥水処理していない木綿紡績糸を合撚し、木綿紡績糸を撥水処理したポリエステル繊維で被覆した糸とし、スポーツ衣料などに使用することが提案されている。引用文献２には、芯に撥水処理した木綿を配置し、鞘に撥水処理していない天然繊維を配置した紡績糸が提案されている。引用文献３には、木綿などの繊維を染色時に撥水処理することが提案されている。引用文献４には、経糸にインジゴ染色した木綿糸を配置し、緯糸にポリエステル糸と高収縮糸を配置し、緯糸二重組織によるデニム生地が提案されている。 Water-repellent textile clothing is used for clothing such as sports clothing and summer clothing that is worn when sweating a lot. Many garments used for this purpose use synthetic fiber garments such as polyester and are water repellent to improve quick-drying. In Patent Document 1, a water-repellent polyester staple fiber bundle and a non-water-repellent cotton spun yarn are twisted together to form a yarn in which the cotton spun yarn is coated with a water-repellent polyester fiber, which is used for sports clothing and the like. It is proposed to use. Cited Document 2 proposes a spun yarn in which water-repellent cotton is arranged in a core and natural fibers which are not water-repellent are arranged in a sheath. Cited Document 3 proposes to treat fibers such as cotton with water repellent treatment at the time of dyeing. Cited Document 4 proposes a denim fabric having an indigo-dyed cotton yarn on the warp, a polyester yarn and a highly shrinkable yarn on the weft, and a double weft structure.
しかし、前記従来技術は、耐久性のある撥水性セルロース繊維を得るには問題があり、撥水性セルロース繊維を防染に使用することは検討されてこなかった。さらに、特許文献４のようなインジゴ染色木綿糸は、色移りの問題があった。 However, the above-mentioned prior art has a problem in obtaining a durable water-repellent cellulose fiber, and the use of the water-repellent cellulose fiber for resist dyeing has not been studied. Further, the indigo dyed cotton yarn as in Patent Document 4 has a problem of color transfer.
本発明は、前記従来の問題を解決するため、耐久性のある撥水性があり、防染に使用することができ、かつ色移りの問題の無いセルロース撥水繊維を含む繊維集合体とその製造方法及び繊維製品を提供する。 In order to solve the above-mentioned conventional problems, the present invention comprises a fiber aggregate containing cellulose water-repellent fibers, which has durable water repellency, can be used for resist dyeing, and has no problem of color transfer, and its production. Providing methods and textile products.
本発明の繊維製品は、セルロース撥水繊維を含む繊維集合体と、撥水処理されていない繊維集合体から形成された繊維製品であり、前記セルロース撥水繊維を含む繊維集合体は、綿（わた）、繊維束及び糸から選ばれる少なくとも一つの状態で撥水剤がセルロース繊維表面に架橋された状態で固着されており、前記繊維製品は反物染色され、前記撥水処理されていない繊維集合体は染色され、前記セルロース撥水繊維を含む繊維集合体は染色されていないことを特徴とする。 The textile product of the present invention is a fiber product formed from a fiber aggregate containing cellulose water-repellent fibers and a fiber aggregate not treated with water-repellent treatment, and the fiber aggregate containing the cellulose water-repellent fibers is cotton ( The water repellent is fixed to the surface of the cellulose fiber in a state of being crosslinked to the surface of the cellulose fiber in at least one state selected from the cotton), the fiber bundle and the thread, and the fiber product is dyed with a cloth and the non-water repellent treated fiber. The aggregate is dyed, and the fiber aggregate containing the cellulose water-repellent fiber is not dyed.
本発明の繊維製品の製造方法は、前記のセルロース撥水繊維を含む繊維製品の製造方法であって、綿（わた）、繊維束及び糸から選ばれる少なくとも一つの繊維集合体に撥水剤を付着させ、乾燥後、加熱キュアすることにより撥水剤をセルロース繊維表面に架橋させた繊維集合体と、撥水処理されていない繊維集合体から繊維製品を形成して反物とし、その後、前記反物を染色処理し、前記撥水処理されていない繊維集合体は染色し、前記セルロース撥水繊維を含む繊維集合体は防染により染色しない繊維製品を得ることを特徴とする。 The method for producing a textile product of the present invention is the method for producing a textile product containing the above-mentioned cellulose water-repellent fiber, in which a water-repellent agent is applied to at least one fiber aggregate selected from cotton, a fiber bundle and a thread . After adhering, drying, and heat-curing , a fiber product is formed from a fiber aggregate in which a water-repellent agent is crosslinked on the surface of a cellulose fiber and a fiber aggregate that has not been treated with water-repellent treatment to form a cloth. It is characterized in that a cloth is dyed, the non-water-repellent fiber aggregate is dyed, and the fiber aggregate containing the cellulose water-repellent fiber is dye-proof to obtain an undyed fiber product .
本発明の繊維製品は、前記のセルロース撥水繊維を含む繊維集合体を含む繊維製品であることを特徴とする。 The textile product of the present invention is characterized by being a fiber product containing a fiber aggregate containing the above-mentioned cellulose water-repellent fiber.
本発明は、綿（わた）、繊維束、糸及び生機から選ばれる少なくとも一つであり、撥水剤がセルロース繊維表面に架橋された状態で固着されているセルロース撥水繊維を含む繊維集合体とすることにより、耐久性があり、かつ防染に使用することができるセルロース撥水繊維を含む繊維集合体とその製造方法及び繊維製品を提供できる。この撥水繊維は、スポーツ衣料、夏用衣料など多量に汗をかくときに着用する衣料に好適である。また、前記撥水繊維は後染の際の防染作用があることから、特定の糸（例えば緯糸）は本発明の糸を使用し、他の糸（例えば経糸）は通常の木綿糸を使用して１００％の木綿織物とした後、木綿繊維に好適な染色（例えば反応性染色）をすることができ、染色においては通常の木綿糸のみが染色され、撥水処理した糸は染色されないことから、一例として、後染デニム調の生地を得ることができる。この生地は堅牢度が優れており、例えば色移り等の問題はない。 The present invention is at least one selected from cotton, fiber bundles, threads and raw materials, and is a fiber aggregate containing cellulose water-repellent fibers in which a water-repellent agent is fixed to the surface of the cellulose fibers in a crosslinked state. Therefore, it is possible to provide a fiber aggregate containing cellulose water-repellent fiber, which is durable and can be used for dye resistance, a method for producing the same, and a fiber product. This water-repellent fiber is suitable for clothing worn when sweating a large amount, such as sports clothing and summer clothing. Further, since the water-repellent fiber has a resist dyeing effect at the time of post-dyeing, the thread of the present invention is used for a specific thread (for example, a weft), and a normal cotton thread is used for another thread (for example, a warp). After making 100% cotton fabric, suitable dyeing (for example, reactive dyeing) can be applied to the cotton fiber, and in the dyeing, only normal cotton yarn is dyed, and the water-repellent treated yarn is not dyed. Therefore, as an example, a resist-dyed denim-like fabric can be obtained. This fabric has excellent fastness, and there is no problem such as color transfer.
綿（わた）、繊維束、糸又は生機等の繊維集合体は、従来、撥水処理することはあまり行われてこなかった。その理由は、綿（わた）や繊維束で撥水処理すると、繊維の滑り性が変化し、紡績しにくくなると思われていたからである。また、糸や生機で撥水処理すると、染色できなくなるか又は染色しにくくなる問題があり、良質な製品は得られないと思われていた。しかし、本発明者らは、従来問題があるとされていた綿（わた）、繊維束、糸又は生機等の繊維集合体を撥水処理すると、意外にも広い製品展開ができることがわかり、本発明を完成させるに至った。また、セルロース繊維は親水性繊維であり、従来、撥水処理することはあまり行われてこなかった。しかし、反物染色前のセルロース繊維を撥水処理すると、これもまた広い製品展開ができることがわかった。 Conventionally, fiber aggregates such as cotton, fiber bundles, threads, and raw machines have not been subjected to water-repellent treatment. The reason is that it was thought that water-repellent treatment with cotton or fiber bundles would change the slipperiness of the fibers and make it difficult to spin. Further, when the water-repellent treatment is performed with a thread or a raw machine, there is a problem that dyeing becomes impossible or difficult to dye, and it has been thought that a good quality product cannot be obtained. However, the present inventors have found that a surprisingly wide range of product development can be achieved by water-repellent treatment of fiber aggregates such as cotton, fiber bundles, threads or raw materials, which have been considered to have problems in the past. The invention was completed. In addition, cellulose fibers are hydrophilic fibers, and water-repellent treatment has not been performed so much in the past. However, it was found that the water-repellent treatment of the cellulose fibers before dyeing the cloth also enables a wide range of product development.
本発明のセルロース撥水繊維を含む繊維集合体は、綿（わた）、繊維束、糸及び生機から選ばれる少なくとも一つであり、撥水剤がセルロース繊維表面に架橋された状態で固着されている。前記において、綿（わた）は開繊綿であっても未開繊綿であってもよい。繊維束はウェブ、スライバー等である。糸は粗糸、紡績糸等である。生機は織り上がった織物又は編み上がった編物等である。綿（わた）及び繊維束で撥水剤を架橋させた場合は、カード等で開繊するのが好ましい。開繊或いは開繊から粗糸までの工程においては、他の繊維と混紡することもできる。糸及び生機で撥水剤を架橋させた場合は、撥水繊維の後染の際の防染作用を生かした用途に有用である。本発明の繊維集合体は、反物染色前の状態の段階で撥水処理するのが好ましい。 The fiber aggregate containing the cellulose water-repellent fiber of the present invention is at least one selected from cotton, fiber bundles, threads and raw materials, and the water-repellent agent is fixed to the surface of the cellulose fiber in a state of being crosslinked. There is. In the above, the cotton may be opened or unopened cotton. The fiber bundle is a web, a sliver, or the like. The yarn is a crude yarn, a spun yarn, or the like. The raw machine is a woven fabric or a knitted fabric. When the water repellent is crosslinked with cotton and a bundle of fibers, it is preferable to open the fibers with a curd or the like. In the process from opening or opening to blister yarn, it can be blended with other fibers. When the water repellent is crosslinked with a thread and a raw machine, it is useful for applications that make use of the resist dyeing effect during post-dyeing of water repellent fibers. The fiber aggregate of the present invention is preferably water-repellent at the stage before dyeing the cloth.
本発明においては、撥水剤はセルロース繊維表面に架橋された状態で固着されている。架橋は、撥水剤と架橋剤とを混合した水溶液又は水分散液をセルロース繊維表面に付着させ、熱キュア等により、セルロース繊維表面に強固に一体化された状態をいう。後の染色や洗濯では撥水性は維持される。このため、反物染色した場合は、撥水剤が架橋されたセルロース繊維部分は染色されず、防染として機能する。 In the present invention, the water repellent is fixed to the surface of the cellulose fiber in a crosslinked state. Cross-linking refers to a state in which an aqueous solution or an aqueous dispersion in which a water-repellent agent and a cross-linking agent are mixed is adhered to the surface of the cellulose fiber and is firmly integrated with the surface of the cellulose fiber by heat curing or the like. Water repellency is maintained in later dyeing and washing. Therefore, when the cloth is dyed, the cellulose fiber portion cross-linked with the water repellent agent is not dyed and functions as resist dyeing.
セルロース繊維は、天然セルロース繊維及び再生セルロース繊維から選ばれる少なくとも一つであるのが好ましく、さらに好ましくは天然セルロース繊維である。天然セルロース繊維としては、木綿、麻等があり、再生セルロース繊維としては、普通レーヨン、ベンベルクレーヨン、溶剤型レーヨン、リヨセル等がある。なお、本発明は、夾雑物や汚れを除去するための精錬漂白工程が必要となる天然セルロース繊維の場合において特に有効である。 The cellulose fiber is preferably at least one selected from natural cellulose fiber and regenerated cellulose fiber, and more preferably natural cellulose fiber. Natural cellulose fibers include cotton, linen and the like, and regenerated cellulose fibers include ordinary rayon, bembel crayon, solvent-based rayon, lyocell and the like. The present invention is particularly effective in the case of natural cellulose fibers that require a refining bleaching step for removing impurities and stains.
本発明のセルロース撥水繊維を含む繊維集合体は２０質量％以上、好ましくは３５質量％以上、さらに好ましくは５０質量％以上であれば、本発明の作用効果を達成できる。したがって、８０質量％以下、好ましくは６５質量％以下、さらに好ましくは５０質量％以下の範囲でさらに他の繊維を含んでもよい。他の繊維としては、セルロース繊維以外の繊維、撥水処理していないセルロース繊維等を含む。 When the fiber aggregate containing the cellulose water-repellent fiber of the present invention is 20% by mass or more, preferably 35% by mass or more, and more preferably 50% by mass or more, the action and effect of the present invention can be achieved. Therefore, other fibers may be contained in the range of 80% by mass or less, preferably 65% by mass or less, and more preferably 50% by mass or less. Other fibers include fibers other than cellulose fibers, cellulose fibers that have not been treated with water repellent, and the like.
撥水剤はフッ素系撥水剤が好ましい。とくに加熱キュアタイプのものが耐久性の点で好ましい。さらに、フッ素系撥水剤とともに架橋剤を併用し、セルロース繊維表面にフッ素系撥水剤を架橋して固着させるのが好ましい。架橋剤としてはウレタン系架橋剤、アクリル系架橋剤が挙げられるが、ウレタン系架橋剤が特に好ましい。このような撥水剤としては、例えば日華化学社製、商品名“ＮＫガードＳ－０９”等があり、架橋剤としては例えば日華化学社製、商品名“ＮＫアシストＶ”等がある。 The water repellent is preferably a fluorine-based water repellent. In particular, a heated cure type is preferable in terms of durability. Further, it is preferable to use a cross-linking agent together with the fluorine-based water repellent agent to cross-link and fix the fluorine-based water repellent agent on the surface of the cellulose fiber. Examples of the cross-linking agent include urethane-based cross-linking agents and acrylic-based cross-linking agents, but urethane-based cross-linking agents are particularly preferable. Examples of such a water repellent agent include, for example, Nicca Chemical Co., Ltd., trade name "NK Guard S-09", and examples of the cross-linking agent include Nicca Chemical Co., Ltd., trade name "NK Assist V". ..
撥水剤としてフッ素系撥水剤を用いる場合、フッ素含有率は０．０１～１．４質量％であるのが好ましい。さらに好ましくは０．１～１．０質量％であり、とくに好ましくは０．２～０．７質量％である。前記の範囲であれば、防染性は実用的に十分である。なお、フッ素含有率は、撥水処理した綿（ワタ）等について蛍光Ｘ線分析装置により検出された元素のトータル和を１００とした場合の、フッ素元素の割合として測定する。 When a fluorine-based water repellent is used as the water repellent, the fluorine content is preferably 0.01 to 1.4% by mass. It is more preferably 0.1 to 1.0% by mass, and particularly preferably 0.2 to 0.7% by mass. Within the above range, the resist dyeing property is practically sufficient. The fluorine content is measured as the ratio of fluorine elements when the total sum of the elements detected by the fluorescent X-ray analyzer for water-repellent cotton or the like is 100.
本発明の繊維製品は、前記のセルロース撥水繊維を含む。一例として、繊維製品は後染デニム調生地である。この生地は経糸に通常の木綿紡績糸を配置し、緯糸に本発明の撥水処理した木綿紡績糸を配置して織物にした後、後染（反物染色）すると経糸は染まり、緯糸は染まらないことからデニム調生地が得られる。他の例としては、デニム調生地以外の交織品、交編品、或いは部分的に本発明の撥水処理した木綿紡績糸を配置した生地がある。部分的に本発明の撥水処理した木綿紡績糸を配置した生地は、白抜き模様とすることもできる。本発明の紡績糸を使用した織編物は、後染めにより染色が可能であり、しかも全体として撥水性を有するものとなる。本発明においては、綿染め、糸染めの後に撥水処理してもよい。 The textile product of the present invention contains the above-mentioned cellulose water-repellent fiber. As an example, textile products are post-dyed denim-like fabrics. In this fabric, ordinary cotton spun yarn is placed on the warp, and the water-repellent cotton spun yarn of the present invention is placed on the weft to make a woven fabric, and then the warp is dyed and the weft is not dyed. From this, a denim-like fabric can be obtained. Other examples include mixed woven and mixed knitted fabrics other than denim-like fabrics, or fabrics in which the partially water-repellent treated cotton spun yarn of the present invention is arranged. The fabric in which the water-repellent treated cotton spun yarn of the present invention is partially arranged can also have a white pattern. The woven and knitted fabric using the spun yarn of the present invention can be dyed by post-dyeing and has water repellency as a whole. In the present invention, water repellent treatment may be performed after cotton dyeing and yarn dyeing.
本発明のセルロース撥水繊維を含む繊維集合体の製造方法は、下記の工程を含む。
（１）綿（わた）、繊維束、糸及び生機から選ばれる少なくとも一つの繊維集合体に撥水剤を付着させる工程。
繊維集合体に撥水剤を付着させる方法は、含浸、スプレー、パディング等の方法がある。撥水剤は水に分散させて付着させるのが好ましい。これにより均一付着できる。
（２）乾燥後、加熱キュアすることにより撥水剤をセルロース繊維表面に架橋させる工程。
乾燥と加熱キュアは連続した加熱乾燥機で処理してもよい。また、加熱キュア条件は、温度１５０～１９０℃、時間２～２０分が好ましい。この場合、セルロース繊維を熱により傷めないようにするのが好ましい。
The method for producing a fiber aggregate containing a cellulose water-repellent fiber of the present invention includes the following steps.
(1) A step of adhering a water repellent agent to at least one fiber aggregate selected from cotton, fiber bundles, threads and raw materials.
As a method for adhering a water repellent agent to the fiber aggregate, there are methods such as impregnation, spraying, and padding. The water repellent agent is preferably dispersed and adhered to water. This allows uniform adhesion.
(2) A step of cross-linking a water repellent agent to the surface of a cellulose fiber by heating and curing after drying.
Drying and heating cure may be processed in a continuous heat dryer. The heating cure conditions are preferably a temperature of 150 to 190 ° C. and a time of 2 to 20 minutes. In this case, it is preferable to prevent the cellulose fibers from being damaged by heat.
綿（わた）又は繊維束で撥水剤をセルロース繊維表面に架橋させた場合は、開繊処理するのが好ましい。撥水処理により繊維同士が収束する場合もあるからである。 When the water repellent is crosslinked on the surface of the cellulose fiber with cotton or a fiber bundle, it is preferable to carry out a fiber opening treatment. This is because the fibers may converge with each other due to the water repellent treatment.
以下図面を用いて説明する。図１は本発明の一実施形態の撥水繊維の製造方法を示す工程図である。セルロース繊維の原綿をまず混綿し、カード機により開繊し、ウェブを形成し、次いで練条工程でスライバー（繊維束)とする。その後、撥水剤と架橋剤の水分散液に含浸させ、絞り、乾燥後、加熱キュアリングして撥水剤をセルロース繊維表面に撥水剤を架橋させ固着する。その後、再度混綿し、カード機に掛け開繊したウェブとし、練条工程でスライバーとし、粗紡工程、精紡工程により紡績糸とする。得られた紡績糸は織物又は編物にする。織物又は編物は、一例として前記撥水処理した紡績糸と、撥水処理していない通常の紡績糸とを交織する。このようにして染色すると、撥水処理していない通常の紡績糸は染まるが、撥水処理した紡績糸は染まらず、不均一染色物が得られる。このような不均一染色物はデニム調生地として有用である。前記において、繊維束の状態で撥水剤を付与するのは、連続処理が可能で、物質操作（マテリアル ハンドリング）も便利であるからである。 This will be described below with reference to the drawings. FIG. 1 is a process diagram showing a method for producing a water-repellent fiber according to an embodiment of the present invention. Cellulose fiber raw cotton is first mixed, opened with a card machine to form a web, and then made into a sliver (fiber bundle) in the kneading process. Then, it is impregnated with an aqueous dispersion of a water repellent and a cross-linking agent, squeezed, dried, and then heat-cured to cross-link the water-repellent agent on the surface of the cellulose fiber and fix it. After that, the cotton is mixed again, the web is hung on a card machine to make a web, the sliver is made in the kneading process, and the spun yarn is made by the roving process and the spinning process. The obtained spun yarn is made into a woven fabric or a knitted fabric. As an example, the woven fabric or knitted fabric is obtained by interweaving the water-repellent treated spun yarn and a normal spun yarn that is not water-repellent treated. When dyed in this manner, the normal spun yarn not treated with water repellent is dyed, but the spun yarn treated with water repellent is not dyed, and a non-uniform dyed product is obtained. Such non-uniform dyed products are useful as denim-like fabrics. In the above, the reason why the water repellent is applied in the state of the fiber bundle is that continuous treatment is possible and material handling (material handling) is also convenient.
以下実施例を用いて本発明を具体的に説明する。なお、本発明は下記の実施例に限定されるものではない。 Hereinafter, the present invention will be specifically described with reference to examples. The present invention is not limited to the following examples.
（実施例１）
＜原綿＞
原綿としてエジプト綿を使用した。
＜撥水綿（わた）の製造＞
図１に示す製造方法により撥水綿（わた）を製造した。フッ素系撥水剤として日華化学社製、商品名“ＮＫガードＳ－０９”を２０リットル、ウレタン系架橋剤として日華化学社製、商品名“ＮＫアシストＶ”を４リットル、浸透剤としてハンツマン社製、商品名“ＩＮＶＡＤＩＮＥ６５０”を１リットル使用し、これに水を加えて２００リットルとした。この薬液にスライバーを含浸させ、マングルで絞り、乾燥後１７０℃で１０分間加熱キュアリングし、撥水剤（架橋剤込み）を架橋させた。当該撥水綿を、株式会社リガク製蛍光Ｘ線分析装置（ＺＳＸ１００ｅ：ＥＺスキャン法）を用いてフッ素含有率を測定したところ０．４質量％であった。
＜紡績糸の製造＞
その後、図１に示すように混綿工程に戻し、開繊したウェブとし、練条工程でスライバーとし、粗紡工程、精紡（リング精紡）工程により紡績糸とした。得られた紡績糸は英式番手７番であった。撥水綿（わた）の紡績工程通過性は、通常の木綿と変わらなかった。
＜織物の製造＞
経糸に英式番手７.２番（単糸）の通常の紡績糸を配置し、緯糸に前記撥水綿で製造した紡績糸（英式番手７番、単糸）を配置した経糸密度６５本/inch、緯糸密度４０本/inch、織物組織３／１綾織の生地を製織した。得られた生地を常法に従い、毛焼き、糊抜き、精練、漂白し、シルケット加工を行った。その後、常法に従い反応性染料を含浸、発色固着させ、柔軟剤を付けて仕上処理を行い、経糸が染まったデニム調の生地が得られた。この生地の仕上げ質量（目付）は３８０ｇ／ｍ2であった。撥水綿（わた）の織物～染色工程通過性は、通常の木綿と変わらなかった。なお、デニム調生地の裏面側には、緯糸である撥水紡績糸が出現するが、裏面側から綿の場合と同様の装置・方法を用いてフッ素含有率を測定したところ０．３質量％であった。
＜評価＞
得られた生地は木綿糸１００％使いであり、風合いも良好であった。この生地をＪＩＳ Ｌ０００１：２０１４(記号番号１４１)に規定されている方法で水洗い洗濯２０回の洗濯試験をしたが、色落ち、色移りはなかった。また、洗濯堅牢度試験（ＪＩＳＬ０８４４：２０１１ Ａ－２号）では、木綿生地の一般的な反物染色（例えばアルカリスチーミング法）と同程度であり、変退色４－５級、汚染４－５級という結果となった。経糸を糸段階でインジゴ染色したデニム生地と比較すると堅牢度は良好であり、特に摩擦堅牢度（ＪＩＳＬ０８４９：２０１３ II形法）は、一般的なインジゴ染色したデニム生地の場合、乾燥２級（タテ方向）、湿潤１級（タテ方向）であるが、本実施例品は、乾燥４－５級（タテ方向）、湿潤２級（タテ方向）という良好な結果となった。
(Example 1)
<Raw cotton>
Egyptian cotton was used as the raw cotton.
<Manufacturing of water-repellent cotton>
Water-repellent cotton was manufactured by the manufacturing method shown in FIG. Nicca Chemical Co., Ltd. as a fluorine-based water repellent, 20 liters of product name "NK Guard S-09", Nicca Chemical Co., Ltd. as a urethane-based cross-linking agent, 4 liters of product name "NK Assist V", as a penetrant 1 liter of the product name "INVADINE650" manufactured by Huntsman Co., Ltd. was used, and water was added to the product to make 200 liters. This chemical solution was impregnated with a sliver, squeezed with a mangle, dried, and then heated and cured at 170 ° C. for 10 minutes to crosslink the water repellent (including the crosslinking agent). The fluorine content of the water-repellent cotton was measured by using a fluorescent X-ray analyzer (ZSX100e: EZ scanning method) manufactured by Rigaku Co., Ltd. and found to be 0.4% by mass.
<Manufacturing of spun yarn>
Then, as shown in FIG. 1, it was returned to the cotton-blending process to obtain an opened web, a sliver in the kneading process, and a spun yarn by a crude spinning process and a spinning (ring spinning) step. The obtained spun yarn had an English-style count of 7. The spinning process passability of water-repellent cotton was the same as that of normal cotton.
<Manufacturing of textiles>
A normal spun yarn with an English count of 7.2 (single yarn) is placed on the warp, and a spun yarn (English count 7, single yarn) manufactured with the water-repellent cotton is placed on the warp with a warp density of 65. Weaving / inch, weft density 40 / inch, woven structure 3/1 twill weave. The obtained dough was hair-baked, deglued, scoured, bleached, and mercerized according to a conventional method. Then, according to a conventional method, a reactive dye was impregnated, the color was fixed, and a softener was applied for finishing treatment to obtain a denim-like fabric in which warps were dyed. The finishing mass (weight) of this dough was 380 g / m 2 . The woven fabric-dyeing process passability of water-repellent cotton was the same as that of normal cotton. Water-repellent spun yarn, which is a warp and weft, appears on the back side of the denim-like fabric, but when the fluorine content was measured from the back side using the same equipment and method as for cotton, it was 0.3% by mass. Met.
<Evaluation>
The obtained fabric was made of 100% cotton yarn and had a good texture. This fabric was washed with water and washed 20 times by the method specified in JIS L0001: 2014 (symbol number 141), but no discoloration or color transfer was observed. In addition, in the washing fastness test (JISL0844: 2011 A-2), it is comparable to general cloth dyeing of cotton fabric (for example, alkaline steaming method), discoloration and fading 4-5 grade, and contamination 4-5 grade. The result was that. The fastness is better than the indigo-dyed denim fabric at the warp stage, and the friction fastness (JISL0849: 2013 II method) is particularly high in the case of general indigo-dyed denim fabric. (Direction) and wet grade 1 (vertical direction), but the product of this example gave good results of dry grade 4-5 (vertical direction) and wet grade 2 (vertical direction).
本発明の生地は、デニム調生地、スポーツ衣料、夏用衣料などにも適用できる。また、靴、帽子、バック、カーテン、ソファーカバー等に用いることもできる。 The fabric of the present invention can also be applied to denim-like fabrics, sports clothing, summer clothing and the like. It can also be used for shoes, hats, bags, curtains, sofa covers and the like.
Claims (9)
前記セルロース撥水繊維を含む繊維集合体は、綿（わた）、繊維束及び糸から選ばれる少なくとも一つの状態で撥水剤がセルロース繊維表面に架橋された状態で固着されており、
前記繊維製品は反物染色され、前記撥水処理されていない繊維集合体は染色され、前記セルロース撥水繊維を含む繊維集合体は染色されていないことを特徴とする繊維製品。 It is a fiber product formed from a fiber aggregate containing cellulose water-repellent fiber and a fiber aggregate not treated with water-repellent treatment.
The fiber aggregate containing the cellulose water-repellent fiber is fixed in a state where the water-repellent agent is crosslinked to the surface of the cellulose fiber in at least one state selected from cotton, fiber bundle and thread.
The textile product is characterized in that the textile product is dyed with a cloth, the fiber aggregate not treated with water repellent is dyed, and the fiber aggregate containing the cellulose water repellent fiber is not dyed.
綿（わた）、繊維束及び糸から選ばれる少なくとも一つの繊維集合体に撥水剤を付着させ、乾燥後、加熱キュアすることにより撥水剤をセルロース繊維表面に架橋させた繊維集合体と、
撥水処理されていない繊維集合体から繊維製品を形成して反物とし、
その後、前記反物を染色処理し、前記撥水処理されていない繊維集合体は染色し、前記セルロース撥水繊維を含む繊維集合体は防染により染色しない繊維製品を得ることを特徴とする繊維製品の製造方法。 The method for producing a textile product containing the cellulose water-repellent fiber according to any one of claims 1 to 6.
A fiber aggregate in which a water repellent agent is attached to at least one fiber aggregate selected from cotton, a fiber bundle, and a thread, dried, and then heat-cured to crosslink the water repellent agent on the surface of the cellulose fiber.
A textile product is formed from a fiber aggregate that has not been treated with water repellent to form a piece of cloth.
After that, the cloth is dyed, the non-water repellent fiber aggregate is dyed, and the fiber aggregate containing the cellulose water repellent fiber is dyed to obtain a fiber product which is not dyed. Manufacturing method.
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| EP18805454.8A EP3633098A4 (en) | 2017-05-24 | 2018-05-21 | Fiber assembly including cellulose water-repelent fiber, method for manufacturing same, and fiber product |
| US16/615,726 US20200173065A1 (en) | 2017-05-24 | 2018-05-21 | Fiber assembly including cellulose water-repellent fiber, method for manufacturing same, and fiber product |
| CN201880033299.7A CN110678601B (en) | 2017-05-24 | 2018-05-21 | Fiber assembly containing cellulose water-proof fiber, method for producing same, and fiber product |
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| JP2009197386A (en) | 2006-09-28 | 2009-09-03 | Hiroshi Miyamoto | Method for processing fiber material |
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| JPS6075678A (en) | 1983-09-30 | 1985-04-30 | 旭硝子株式会社 | Water and oil repellent process of fabric |
| JPH03269185A (en) * | 1990-03-16 | 1991-11-29 | Miki Riken Kogyo Kk | Production of cloth product of melange pattern |
| JPH0482980A (en) * | 1990-07-24 | 1992-03-16 | Kanebo Ltd | Production of fiber structure of multicolor dyed front and back surfaces |
| JPH04272247A (en) | 1991-02-22 | 1992-09-29 | Gunze Ltd | Production of spun yarn |
| JPH0533234A (en) | 1991-07-19 | 1993-02-09 | Toyobo Co Ltd | Spun yarn having low wet feeling |
| US5824614A (en) * | 1997-04-24 | 1998-10-20 | Basf Corporation | Articles having a chambray appearance and process for making them |
| JPH11302970A (en) * | 1998-04-17 | 1999-11-02 | Toray Ind Inc | Method for producing water-repellent fiber structure |
| WO2002027088A2 (en) * | 2000-09-29 | 2002-04-04 | Cotton Incorporated | Cellulosic substrates with reduced absorbent capacity having the capability to wick liquids |
| JP4262927B2 (en) * | 2001-07-16 | 2009-05-13 | 倉敷紡績株式会社 | Cellulose fibers with excellent oil repellency, antifouling properties and water absorption |
| JP4082980B2 (en) * | 2002-10-22 | 2008-04-30 | 花王株式会社 | Disposable diapers |
| JP2008517178A (en) * | 2004-10-22 | 2008-05-22 | ゴア エンタープライズ ホールディングス，インコーポレイティド | Fabric and manufacturing method thereof |
| US10221506B2 (en) | 2010-02-26 | 2019-03-05 | Sanko Tekstil Isletmeleri San. Ve Tic. A.S. | Method of making woven fabric that performs like a knitted fabric |
| CN102505251A (en) * | 2011-09-22 | 2012-06-20 | 东华大学 | Breathable pure cotton yarn-dyed fabric and method of producing same |
| CN104674543A (en) * | 2013-12-02 | 2015-06-03 | 广东德美精细化工股份有限公司 | Water-proof finishing process of cotton knitted fabric through dyeing and finishing at low temperature |
| WO2016007830A2 (en) * | 2014-07-11 | 2016-01-14 | Vf Jeanswear, L.P. | Jade-containing fiber, yarn, and moisture wicking, cooling fabric |
| CN105369624A (en) * | 2015-12-28 | 2016-03-02 | 苏州迈塔斯芯片科技有限公司 | Fluorine-containing finishing agent for hydrophobic and oleophobic fabric and preparation method of fluorine-containing finishing agent |
| CN105862478B (en) * | 2016-04-22 | 2018-10-26 | 常州旭荣针织印染有限公司 | Cellulose fiber knitted object resisting printing technique |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2009197386A (en) | 2006-09-28 | 2009-09-03 | Hiroshi Miyamoto | Method for processing fiber material |
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| US20200173065A1 (en) | 2020-06-04 |
| CN110678601A (en) | 2020-01-10 |
| EP3633098A4 (en) | 2021-02-17 |
| EP3633098A1 (en) | 2020-04-08 |
| WO2018216650A1 (en) | 2018-11-29 |
| TW201908557A (en) | 2019-03-01 |
| CN110678601B (en) | 2022-08-02 |
| TWI772427B (en) | 2022-08-01 |
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