JP7076472B2 - Beverage - Google Patents

Description

The present invention relates to a beer-taste beverage containing 4-vinylguaiacol (4VG) and linalool.

Weizen beer, one of the traditional German beers, is obtained by brewing wheat malt, mainly using top-fermenting yeast. By using such a manufacturing method, Weizen beer has a characteristic scent called Weizen scent, which is expressed as smoked or fruity.
Smoked-like characteristic of Weizen beer One of the aroma components is 4VG. 4VG is produced from ferulic acid contained in malt, which is one of the raw materials, and ferulic acid is a phenolic compound contained in a large amount in wheat bran, rice bran and the like. Generally, ferulic acid is ester-bonded to sugar and exists in the cell wall of plant tissue, but the ester bond is hydrolyzed by an enzyme used in the production of beer to release ferulic acid. This liberated ferulic acid is enzymatically decarboxylated to produce 4VG, which produces the smoke-like aroma characteristic of 4VG-derived Weizen beer. As described above, it is known that 4VG is an important component for producing a smoke-like scent in a beer-taste beverage (Japanese Patent Laid-Open No. 2012-38 (Patent Document 1)).
However, a beer-taste beverage containing a certain amount or more of 4VG has a problem that it has a strong chemical-like aroma and is difficult to drink (International Publication No. 2014/119065 (Patent Document 2)).

JP 2012-38 International Publication No. 2014/119065

Under such circumstances, there is a demand for a beverage in which a chemical-like scent is masked while containing a certain amount of 4VG. Further, there is a demand for a beer-taste beverage in which a chemical-like scent is masked while containing a certain amount of 4VG.

The inventors of the present invention can effectively mask the drug-like scent of a beverage containing a certain amount of 4VG by adding linalool, and particularly when the beverage is a beer-taste beverage, the drug-like scent can be obtained. We found that it can be effectively masked.

The present invention includes the following aspects of the invention.
[1]
A beverage containing 4VG and linalool,
The 4VG concentration is 900 mass ppb or more,
Beverages with a linalool concentration of 180 mass ppb or greater.
[2]
A beverage containing 4VG and linalool,
The 4VG concentration is 1000 mass ppb or more,
Beverages with a linalool concentration of 200 mass ppb or greater.
[3]
The beverage according to [1] or [2], wherein the linalool concentration is 200 to 1200 mass ppb.
[4]
The beverage according to [1] or [2], wherein the linalool concentration is 300 to 1100 mass ppb.
[5]
The beverage according to any one of [1] to [4], wherein the 4VG concentration is 1000 to 8000 mass ppb.
[6]
The beverage according to any one of [1] to [4], wherein the 4VG concentration is 1500 to 6500 mass ppb.
[7]
The beverage according to any one of [1] to [4], wherein the 4VG concentration is 3500 to 6500 mass ppb.
[8]
The beverage according to any one of [1] to [7], which is a malt beverage.
[9]
The beverage according to any one of [1] to [7], which is a fermented malt beverage.
[10]
The beverage according to any one of [1] to [9], which is a beer-taste beverage.
[11]
A packaged beverage in which the beverage according to any one of [1] to [10] is packaged.

A preferred embodiment of the present invention provides a beverage in which a chemical-like aroma is masked while containing a certain amount of 4VG. In addition, a preferred embodiment of the present invention provides a beverage rich in fruity aroma and smoke-like aroma.

14 Beverages Containing 4VG and Lina Roll The beverage of the present invention is a beverage containing 4VG and Lina Roll, having a 4VG concentration of 900 mass ppb or more and a Lina Roll concentration of 180 mass ppb.

It is known that 4VG contained in the beverage of the present invention is produced in a small amount during shochu, awamori or beer production, and is involved in the cultivating of the aroma of these alcoholic beverages. It is said that 4VG is produced by the action of ferulic acid decarboxylase produced by microorganisms such as Jiuqu on ferulic acid derived from liquor raw materials. The concentration of 4VG (4VG concentration) is 300 to 1200 mass ppb, preferably 300 to 1000 mass ppb, and even more preferably 380 to 1000 mass ppb.

Linalool contained in the beverage of the present invention is a kind of monoterpene alcohol and is generally used as a fragrance. By adding more linalool to the beverage, it is possible to further improve the refreshing taste without spoiling the taste. The concentration of linalool (linalool concentration) is 200 to 300 mass ppb, preferably 220 to 300 mass ppb, and even more preferably 230 to 280 mass ppb.

The beer-taste beverage of the present invention refers to a carbonated beverage having a beer-like flavor. Unless otherwise specified, the beer-taste beverage of the present invention includes any carbonated beverage having a beer flavor regardless of the presence or absence of a fermentation process using yeast and the presence or absence of alcohol. The types of beer-taste beverages of the present invention include, for example, sparkling liquor, beer, liqueurs, and other miscellaneous liquors under the name under the Japanese Liquor Tax Law, and low-alcohol fermented beverages (for example, less than 1% alcohol content). Fermented beverages), spirits, non-alcoholic beer-taste beverages, beer-taste soft beverages, etc. are also included.

The alcohol content of the beer-taste beverage of the present invention is not particularly limited, but is preferably 0 to 40% by mass, and more preferably 1 to 15% by mass. In particular, it is desirable that the concentration is about the same as that of alcohol that consumers prefer to drink as beer-taste beverages such as beer and low-malt beer, that is, in the range of 1 to 7% by mass, but it is not particularly limited.

1.1 Raw Materials The beverages of the present invention are not particularly limited as long as the obtained beverages include 4VG and linalool. Therefore, when 4VG, linalool or both are not sufficiently contained as the main raw materials, the beverage of the present invention can be produced by adding these or the like.

The main raw materials of the beer-taste beverage of the present invention are water, grains, hops, sugars, water-soluble dietary fiber, herbs and spices, and various additives.

Grains include, for example, wheat (barley, wheat, pigeon, rye, starch, their malt, etc.), rice (white rice, brown rice, etc.), corn, corn, potatoes, beans (soybeans, starch beans, etc.). , Soba, corn, millet, rye, and starch obtained from them, extracts of these, and the like.

Malt refers to seeds of barley, wheat, rye, oats, oats, adlay, pearl barley, etc. that are germinated, dried, and rooted. May be. In the present invention, barley malt is preferably used. Barley malt is one of the most commonly used malts as a raw material for Japanese beer-taste beverages. There are various types of barley such as two-row barley and six-row barley, but any of them may be used. Further, in addition to normal malt, colored malt and the like can also be used. When using colored malt, different types of colored malt may be used in appropriate combinations, or one type of colored malt may be used.
In the production of the beer-taste beverage of the present invention, it is preferable to use wheat as a raw material, it is more preferable to use malt, and it is particularly preferable to use barley and wheat malt.

Hops refer to ordinary pellet hops, veil hops, hop extracts, processed hop products (isolated hops, hexa hops, tetra hops) and the like used in the production of beer and the like.

Examples of saccharides include commercially available saccharified liquids obtained by decomposing grain-derived starch with an acid or an enzyme, and commercially available starch syrup. At this time, the form of the saccharide may be any form such as a liquid such as a solution or a solid substance such as a powder. Further, there are no particular restrictions on the type of starch raw material grain, the method for purifying starch, and the treatment conditions such as hydrolysis with enzymes or acids. For example, a saccharide having an increased proportion of maltose may be used by devising the conditions for hydrolysis with an enzyme or acid. In addition, sucrose, fructose, glucose, maltulose, trehalulose, maltotriose and solutions thereof (sugar solution) can be used.

Further, as the raw material of the beer-taste beverage of the present invention, water-soluble dietary fiber such as indigestible dextrin, polydextrose, guar gum decomposition product, pectin, glucomannan, alginic acid, laminarin, fucoidin, and carrageenan can also be used. Of these, from the viewpoint of versatility such as stability and safety, it is preferable to use indigestible dextrin and polydextrose as raw materials.

Herbs and spices include, for example, Agrimony, Arvens, Betney, Gobow, Clove, Juniper, Costmary, Dog Rose, Elecampa, Ibright, Gentian, Grand Ivy, Magwart, Lou, St. Jones Wort, Wormwood, etc. Yarrow, Arcanet, Penny Royal, Hibiscus, Stevia, Lemongrass, Lemon Balm, Chamomile, Ginger, Thyme, Pepper, Mallow Blue, Linden Anise, Star Anise, Laurel, Lavender, Sage, Coriander, Coriander Seed, Fennel, Hisop, Oregano, peppermint, rosemary, spice mint, caraway, orange peel, lemon peel, yachiyanagi, jasmine, basil, yuzu peel, lemon myrtle, sansho, or processed products (eg, extracts) from these natural products. Can be used.

Coriander and coriander seeds (dried coriander fruit) contain linalool. Therefore, it is preferable to use coriander, coriander seeds or extracts thereof as herbs and spices as raw materials for the beer-taste beverage of the present invention.
Coriander is a kind of plant belonging to the genus Coriandrum of the family Umbelliferae. In Japanese name, it is also called coriander or stink bug. Both leaves and seeds (seed, botanically fruit) are used, but in the present invention, it is preferable to use coriander seed as a raw material. As the coriander seed, a commercially available coriander seed may be used. Dried fruits (holes) may be used as they are, or powdery ones that have been pulverized so as to facilitate component extraction may be used. From the viewpoint of shortening the extraction time, powdery ones are preferable. In the present specification, those in either state are referred to as coriander seeds.
The coriander seed extract is obtained by extracting coriander seeds with a solvent such as water or alcohol or a solution in which they are mixed, and concentrating the coriander seeds as necessary. For example, the alcohol used for extraction is preferably one that is usually used for alcoholic beverages. For the purpose of not changing the design quality after compounding, the alcohol used for extraction is preferably distilled liquor obtained by using a continuous distiller which is almost tasteless and odorless. Examples of distilled liquors obtained by using a continuous distillation machine include spirits such as vodka and alcohol for raw materials, and continuous distilled shochu (so-called shell shochu). As a method for producing the coriander seed extract, for example, a known method described in Japanese Patent Application Laid-Open No. 2012-105572 is used.

1.2 Other Additives In the present invention, various additives may be added as needed, as long as the effects of the present invention are not impaired. For example, flavors such as linalol and 4VG, colorants, foam-forming agents, fermentation accelerators, sweeteners, bitterness agents, yeast extracts, protein-based substances such as peptide-containing substances, seasonings such as amino acids, and antioxidants such as ascorbic acid. Agents, various acidulants and the like can be added as needed within a range that does not interfere with the effects of the present invention. The colorant is used to give a beer-like color to a beverage, and a caramel color or the like can be used. Foam-forming agents are used to form beer-like foam in beverages or to retain foam in beverages, and are plant-extracted saponin-based substances such as soybean saponins and Kiraya saponins, and plants such as corn and soybeans. Proteins, peptide-containing substances, protein-based substances such as bovine serum albumin, yeast extracts and the like can be appropriately used. The flavoring is used for beer-like flavoring, and an appropriate amount of beer-flavored flavoring can be used. The fermentation accelerator is used to promote fermentation by yeast, and for example, yeast extract, bran components such as rice and wheat, vitamins, mineral agents and the like can be used alone or in combination. As the sweetener, both high-intensity sweeteners such as natural sweeteners and synthetic sweeteners can be used, and sucrose derivatives such as sucralose; synthetic sweeteners such as Acesulfam K, saccharin and the like can be used. It can be used alone or in combination of two or more. The bitterness agent may be a plant or a plant extract that causes the taste to perceive bitterness by blending it in a beverage. The bitterness agents include Hime-Mako, Morimatsu Minoru, Sage, Maze, Mannentake, Laurel, Mazeka, Mannentake, Kwashin, Naringin, Citrus extract, Nigaki extract, Coffee extract, Tea extract, Bitter gourd extract. A substance, a lotus germ extract, a kidachi aloe extract, a nigga yomogi extract, a laurel extract and the like can be used.
In the present invention, it is preferable to add these for adjusting the concentration of 4VG and linalool contained in the beverage.

1.3 Carbon dioxide gas The beverage of the present invention may contain carbon dioxide gas, and the carbon dioxide gas may use carbon dioxide gas contained in the raw material, or may be dissolved by mixing with carbonated water or adding carbon dioxide gas. You may let me.
As the carbon dioxide gas contained in the beer-taste beverage of the present invention, when a fermented liquid is used as a raw material, carbon dioxide gas is generated in the fermentation step, so that the carbon dioxide gas can be used as it is. In addition, when a non-fermented liquid is used as a raw material, carbon dioxide gas generated in the fermentation process cannot be used. Therefore, by mixing the non-fermented liquid with carbonated water or adding carbon dioxide gas to the non-fermented liquid, carbon dioxide is added to the beer-taste beverage. The gas can be dissolved.

The amount of carbon dioxide contained in the beverage of the present invention is represented by the carbon dioxide pressure of the beverage, which is not particularly limited as long as it does not interfere with the effect of the present invention. Typically, the upper limit of the carbon dioxide pressure of the beverage is 4.0 kg / cm ² , 3.4 kg / cm ² , or 2.8 kg / cm ² , and the lower limit is 0.2 kg / cm ² , 0.9 kg / cm 2. It is cm ² or 1.5 kg / cm ² , and any of these upper and lower limits may be combined. For example, the carbon dioxide pressure of a beverage is 0.2 kg / cm ² or more and 4.0 kg / cm ² or less, 0.2 kg / cm ² or more and 3.4 kg / cm ² or less, 0.9 kg / cm ² or more and 2.8 kg / cm. It may be cm ² or less, or 1.5 kg / cm ² or more and 2.8 kg / cm ² or less. The gas pressure in the present specification means the gas pressure in the container, except for special cases. The pressure is measured by a method well known to those skilled in the art, for example, after fixing a sample at 20 ° C to a gas internal pressure gauge, the gas internal pressure gauge is once opened to release gas, the stopper is closed again, and the gas internal pressure gauge is measured. It can be measured by using a method of swinging and reading the value when the pointer reaches a certain position, or by using a commercially available gas pressure measuring device.

2 Beverage manufacturing method The beverage manufacturing method of the present invention is not particularly limited, but the 4VG concentration is adjusted by selecting raw materials having a high or low content of 4VG and increasing or decreasing the amount of these raw materials used. Can be done. Further, the 4VG concentration can be adjusted by selecting and using yeast that easily or hardly produces 4VG. Similarly, the linalool concentration can be adjusted by selecting raw materials having a high or low linalool content and increasing or decreasing the amount of these raw materials used. Examples of raw materials having a high content of linalool include hops, coriander, coriander seeds and the like. Further, in the production method of the present invention, the 4VG concentration and the linalool concentration may be adjusted by performing dilution, filtration, filtering and the like during the production of the beer-taste beverage.

In the production of the beer-taste beverage of the present invention, a fermented liquid obtained through a fermentation step and a non-fermented liquid not undergoing a fermentation step can be used, but the beverage obtained by using the fermented liquid has a better flavor. preferable.

Further, in order to adjust the 4VG concentration and the linalool concentration, the production method of the present invention may include a step of adding 4VG or linalool. In the production method, the timing of adding 4VG or linalool is not limited. Specifically, when a fermented liquid is used for producing a beer-taste beverage, the timing of addition of 4VG and linalool may be before or after the fermentation step or during the fermentation step. In addition, 4VG and linalool may be added together with raw materials such as malt.
If the raw material itself contains 4VG and linalool, add 4VG and linalool so that the sum of the content of 4VG and linalool derived from the raw material and the content of 4VG and linalool to be added is a predetermined content.

Hereinafter, a method for producing a beer-taste beverage of the present invention will be described.

2.1 Manufacture of fermented and non-fermented liquids
(1) Production of fermented liquid The fermented liquid used in the method for producing a beer-taste beverage of the present invention has, for example, a beer taste well known to those skilled in the art such as a preparation process, a fermentation process, a liquor storage process, a filtration process, and a containerging process. Obtained by the process of manufacturing a beverage.
Specifically, the raw materials are put into a charging kettle or a charging tank, enzymes such as amylase are added as necessary, gelatinization and saccharification are performed, the mixture is filtered and boiled, and coagulated proteins are used in a clarification tank. Remove solids. After that, yeast is further added and fermented, the yeast is removed by a filter or the like, and water, brewing alcohol, additives and the like are added as necessary to obtain a fermentation broth.

The fermentation step may be a step of adding yeast to a stock solution such as wort containing wheat, malt extract, soybean peptide, hops and water to perform fermentation, and various conditions such as fermentation temperature and fermentation period may be used. It can be set freely. For example, in the case of producing a beer-taste fermented beverage, it may be fermented under the conditions of 8 to 25 ° C. for 5 to 10 days, which are the fermentation conditions for producing ordinary beer and low-malt beer. The temperature (increasing or decreasing temperature) or pressure of the fermentation broth may be changed during the fermentation process.

The yeast used in the fermentation step can be selected in consideration of the type of fermented beverage to be produced, the desired flavor and fermentation conditions, and the like. Commercially available yeast, such as the Weihenstephan-34 strain, can be used. Yeast may be added to wort as it is in a yeast suspension, or a slurry in which yeast is concentrated by centrifugation or sedimentation may be added to wort. Further, after centrifugation, a substance from which the supernatant has been completely removed may be added. The amount of yeast added to wort can be appropriately set, but is, for example, about 5 × 10 ⁶ cells / ml to 1 × 10 ⁸ cells / ml.

In the present specification, a beer-taste beverage using a fermented liquid is referred to as a fermented beverage or a fermented beer-taste beverage. Further, a beer-taste beverage using a fermented liquid obtained by fermenting malt is referred to as a malt-fermented beverage or a malt-fermented beer-taste beverage.

(2) Production of non-fermented liquid The non-fermented liquid production process used in the method for producing a beer-taste beverage of the present invention does not include a fermentation process and contains wheat, malt extract, soybean peptide, hops and water. It is obtained by a mixing step of mixing carbonated water or carbon dioxide gas with alcohol in a stock solution such as. In addition to the mixing step, the non-fermented liquid may further include a beer-taste beverage manufacturing step known to those skilled in the art, such as a brewing step, a liquor storage step, and a containerging step.

In the present specification, a beer-taste beverage using a non-fermented liquid is referred to as a non-fermented beverage or a non-fermented beer-taste beverage.

2.2 Adjusting 4VG content and linalool content In order to adjust the 4VG content and linalool content in a beverage within a predetermined range, 4VG, linalool or 4VG and linalool are added to the beverage or its raw beverage. May be good. The timing of addition of 4VG and linalool is not particularly limited and may be before, during or after the production of the fermented or non-fermented liquid. Also, the addition of 4VG and linalool may be divided into multiple doses. The added 4VG and linalool may be a composition containing them or an isolated and produced compound, and they may be derived from a natural product or an artificial compound.

3 Beverages packed in containers The beverages of the present invention can be packed in containers by filling and sealing them. A container of any form and material may be used, and examples of the container include bottles, cans, barrels, and PET bottles.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.

[Measurement of 4VG and linalool concentrations]
The concentrations of 4VG and linalool are shown in the gas chromatograph described in J. Agric. Food Chem., 2013, 61 (47), pp 11303-1131 (characterization of the Key Aroma Compounds in Two Bavarian Wheat Beers by Means of the Sensomics Approach). It was measured using a mass spectrometer (GC-MS).

[Examples 1 to 12]
A commercially available beer product was used as a base beverage, and 4VG (W267511 manufactured by ALDRICH) and linalool were added to the base beverage to prepare a beer-taste beverage having the 4VG concentration and linalool concentration shown in Table 1. As the added linalool, a mixture of R-form and S-form was used.

[Comparative Examples 1 to 3]
Similar to Examples 1-12, 4VG and linalool were added to the base beverages to prepare beer-taste beverages having the 4VG and linalool concentrations shown in Table 1.

The beverage thus obtained was subjected to a sensory evaluation by five trained panelists regarding the strength of the chemical-like aroma and the comprehensive evaluation as a beer-taste beverage. The strength of the chemical-like scent was evaluated on a scale of 1 to 5 (in increments of 1).
1: Weak 2: Slightly weak 3: Normal 4: Slightly strong 5: Strong In addition, the overall evaluation as a beer-taste beverage was evaluated in 1 to 5 (1 increments).
1: Impossible 2: Possible 3: Good 4: Excellent 5: Very excellent. For the overall evaluation, a passing line that can be judged to be excellent in flavor is set to 2.8 or higher.
These results are shown in Table 1.

Normally, when the 4VG concentration of a beverage increases, the chemical-like aroma tends to stand out. However, in a beverage having a 4VG concentration of 900 mass ppb or more, the chemical-like aroma of the beverage is adjusted by adjusting the linalol concentration to 180 mass ppb. It was confirmed that the masking can be effectively performed.

The present invention can provide a beverage having an excellent flavor.

Claims (10)

A beverage containing 4VG and linalool,
The 4VG concentration is 900 mass ppb or more,
Linalool concentration is 200 mass ppb or more ,
A beverage that is a malt beverage . 4 The beverage according to claim 1, wherein the VG concentration is 1000 mass ppb or more. The beverage according to claim 1 or 2, wherein the linalool concentration is 200 to 1200 mass ppb. The beverage according to claim 1 or 2, wherein the linalool concentration is 300 to 1100 mass ppb. The beverage according to any one of claims 1 to 4, wherein the 4VG concentration is 1000 to 8000 mass ppb. The beverage according to any one of claims 1 to 4, wherein the 4VG concentration is 1500 to 6500 mass ppb. The beverage according to any one of claims 1 to 4, wherein the 4VG concentration is 3500 to 6500 mass ppb. The beverage according to any one of claims 1 to 7, which is a fermented malt beverage. The beverage according to any one of claims 1 to 8 , which is a beer-taste beverage. A packaged beverage in which the beverage according to any one of claims 1 to 9 is packaged.