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JP7158764B2 - Method for producing calcium hydroxide powder for washing fruits and vegetables and method for washing fruits and vegetables using the calcium hydroxide powder - Google Patents
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JP7158764B2 - Method for producing calcium hydroxide powder for washing fruits and vegetables and method for washing fruits and vegetables using the calcium hydroxide powder - Google Patents

Method for producing calcium hydroxide powder for washing fruits and vegetables and method for washing fruits and vegetables using the calcium hydroxide powder Download PDF

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JP7158764B2
JP7158764B2 JP2021036733A JP2021036733A JP7158764B2 JP 7158764 B2 JP7158764 B2 JP 7158764B2 JP 2021036733 A JP2021036733 A JP 2021036733A JP 2021036733 A JP2021036733 A JP 2021036733A JP 7158764 B2 JP7158764 B2 JP 7158764B2
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calcium hydroxide
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博康 今平
進 苅部
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Description

本発明は、青果洗浄用の水酸化カルシウム粉末製造方法及びその水酸化カルシウム粉末を用いた青果洗浄方法に関する。 TECHNICAL FIELD The present invention relates to a method for producing calcium hydroxide powder for washing fruits and vegetables, and a method for washing fruits and vegetables using the calcium hydroxide powder.

従来、カット野菜、果物等の青果を殺菌洗浄するために、水酸化カルシウム水溶液が用いられている(例えば、特許文献1参照)。水酸化カルシウム水溶液は、次亜塩素酸ナトリウム水溶液等の塩素系殺菌剤に比較して、野菜本来の食感、味、風味等の低下を招き難く、また、塩素系殺菌剤に特有の不快臭がない。 Conventionally, an aqueous calcium hydroxide solution has been used to sterilize and wash fruits and vegetables such as cut vegetables and fruits (see, for example, Patent Document 1). Compared to chlorine-based disinfectants such as sodium hypochlorite aqueous solutions, calcium hydroxide aqueous solutions are less likely to cause deterioration of the original texture, taste, flavor, etc. of vegetables, and also have an unpleasant odor peculiar to chlorine-based disinfectants. There is no

特開2011-67161号公報JP 2011-67161 A

ここで、青果洗浄用の水酸化カルシウム水溶液の原料となる水酸化カルシウム粉末は、食品添加物規格を満たしているものを使用する必要があるが、高純度で粒子が微細な高品質の水酸化カルシウム粉末を安定的に供給するのは難しいという問題があった。 Here, the calcium hydroxide powder, which is the raw material for the calcium hydroxide aqueous solution for washing fruits and vegetables, must meet the standards for food additives. There was a problem that it was difficult to stably supply calcium powder.

本発明は、上記問題点に鑑みてなされたものであり、青果洗浄用の高品質な水酸化カルシウム粉末製造方法及びその水酸化カルシウム粉末を用いた青果洗浄方法を提供することを課題とする。 The present invention has been made in view of the above problems, and an object of the present invention is to provide a method for producing high-quality calcium hydroxide powder for washing fruits and vegetables, and a method for washing fruits and vegetables using the calcium hydroxide powder.

上記課題を解決するために、
本発明の青果洗浄用の水酸化カルシウム粉末製造方法は、
炭酸カルシウムを土中炉で焼成することにより、硬焼生石灰を生成する硬焼生石灰生成工程と、
前記硬焼生石灰生成工程において生成された硬焼生石灰に加水処理を行うことにより、水酸化カルシウム粉末を生成する水酸化カルシウム粉末生成工程と、
前記水酸化カルシウム粉末生成工程において生成された水酸化カルシウム粉末を集塵する水酸化カルシウム粉末集塵工程と
を備えたことを特徴とする。
In order to solve the above problems,
The method for producing calcium hydroxide powder for washing fruits and vegetables of the present invention comprises:
a hard-burned quicklime generating step for generating hard-burned quicklime by firing calcium carbonate in an underground furnace;
a calcium hydroxide powder generating step for generating calcium hydroxide powder by subjecting the hard-burned quicklime generated in the hard-burned quicklime-generating step to water treatment;
and a calcium hydroxide powder dust collection step for collecting the calcium hydroxide powder generated in the calcium hydroxide powder generation step.

本発明によれば、微細な高品質の水酸化カルシウム粉末を製造することができる。 According to the present invention, fine, high-quality calcium hydroxide powder can be produced.

上記発明において、
前記硬焼生石灰生成工程において、前記焼成する期間は3日間であることを特徴とする。
In the above invention,
In the hard-burned quicklime generating step, the burning period is three days.

本発明によれば、焼締りが進み、硬焼生石灰といわれる中間物質を生成することができる。 According to the present invention, densification proceeds and an intermediate substance called hard-burned quicklime can be produced.

上記発明において、
前記水酸化カルシウム粉末集塵工程において、
前記水酸化カルシウム粉末生成工程で生成された水酸化カルシウム粉末のうち、噴霧飛散した水酸化カルシウム粉末を集塵することを特徴とする。
In the above invention,
In the calcium hydroxide powder dust collection step,
Among the calcium hydroxide powder produced in the calcium hydroxide powder producing step, the calcium hydroxide powder sprayed and scattered is collected.

本発明によれば、噴霧飛散した微細で重量が軽い粉末を集塵することで、平均粒径10μの高品質な水酸化カルシウム粉末を製造することができる。 According to the present invention, high-quality calcium hydroxide powder having an average particle size of 10 μm can be produced by collecting the sprayed and scattered fine, light powder.

本発明の青果洗浄方法は、
上記水酸化カルシウム粉末製造方法により製造された水酸化カルシウム粉末を水に添加して、水酸化カルシウム飽和水溶液を生成する工程と、
前記水酸化カルシウム飽和水溶液で青果を3秒~3分間処理する工程と
を備えたことを特徴とする。
The fruit and vegetable washing method of the present invention comprises:
adding the calcium hydroxide powder produced by the calcium hydroxide powder production method to water to produce a calcium hydroxide saturated aqueous solution;
and a step of treating fruits and vegetables with the calcium hydroxide saturated aqueous solution for 3 seconds to 3 minutes.

この特徴によれば、高品質の水酸化カルシウム飽和水溶液を用いて、3秒~3分間という短時間で効率的に青果を洗浄することができる。 According to this feature, fruits and vegetables can be efficiently washed in a short time of 3 seconds to 3 minutes using a high-quality saturated aqueous solution of calcium hydroxide.

本発明の実施形態に係る青果洗浄用の水酸化カルシウム粉末の製造及び青果洗浄工程図である。FIG. 2 is a process diagram of producing a calcium hydroxide powder for washing fruits and vegetables and washing fruits and vegetables according to an embodiment of the present invention.

以下、本発明の実施形態について、図面を参照して詳細に説明する。 BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

図1は、本発明の実施形態に係る青果洗浄用の水酸化カルシウム粉末の製造及び青果洗浄工程図である。図1を参照して、まず、青果洗浄用の水酸化カルシウム粉末の製造工程を説明する。 FIG. 1 is a production process diagram of a calcium hydroxide powder for washing fruits and vegetables and washing fruits and vegetables according to an embodiment of the present invention. First, with reference to FIG. 1, the manufacturing process of calcium hydroxide powder for washing fruits and vegetables will be described.

まず、原料となる炭酸カルシウムを土中炉で数日間焼成することにより、硬焼生石灰を生成する(行程S1)。ここで、原料となる炭酸カルシウムは、純度の高い石灰石を用いる。また、炭酸カルシウムを土中炉で焼成する期間は3日間程度の長い期間が好ましい。このように炭酸カルシウムを土中炉で長い期間焼成することで、機械式焼成炉で数時間程度焼成するのに比較して、内部まで分解反応が進行し、結晶が成長合体することで容積が減少し、嵩密度が増大する。 First, calcium carbonate, which is a raw material, is fired in an underground furnace for several days to produce hard-burned quicklime (step S1). Here, limestone with high purity is used as calcium carbonate as a raw material. Moreover, the period for baking calcium carbonate in an earthen furnace is preferably a long period of about three days. By firing calcium carbonate in an underground furnace for a long period of time in this way, compared to firing in a mechanical firing furnace for several hours, the decomposition reaction progresses to the inside, and the crystals grow and coalesce, increasing the volume. decreases and the bulk density increases.

次に、工程S1で生成された硬焼生石灰に加水処理を行う(工程S2)。これにより、高熱暴爆が生じ、微細な水酸化カルシウム粉末が生成される。 Next, the hard burnt quicklime produced in step S1 is subjected to water treatment (step S2). This causes a high thermal explosion and produces fine calcium hydroxide powder.

次に、工程S2において生成された水酸化カルシウム粉末のうち、噴霧飛散した水酸化カルシウム粉末を集塵する(行程S3)。これにより、平均粒径約10μの微細で高品質な水酸化カルシウム粉末を集塵することができる。 Next, of the calcium hydroxide powder produced in step S2, the sprayed and scattered calcium hydroxide powder is collected (step S3). As a result, fine, high-quality calcium hydroxide powder having an average particle size of about 10 μm can be collected.

次に、工程S3で生成された水酸化カルシウム粉末を用いて、青果の洗浄処理を行う。具体的には、まず、水に工程S3で生成された水酸化カルシウム粉末を添加して、水酸化カルシウム飽和水溶液を生成する(工程S4)。ここで、水の温度は0~35℃が好ましい。水酸化カルシウム飽和水溶液は、温度25℃において、水酸化カルシウム濃度が0.17質量%、pHは12.4となる。 Next, using the calcium hydroxide powder produced in step S3, fruits and vegetables are washed. Specifically, first, the calcium hydroxide powder produced in step S3 is added to water to produce a calcium hydroxide saturated aqueous solution (step S4). Here, the temperature of water is preferably 0 to 35°C. A calcium hydroxide saturated aqueous solution has a calcium hydroxide concentration of 0.17% by mass and a pH of 12.4 at a temperature of 25°C.

当該水酸化カルシウム飽和水溶液に除菌対象の青果を浸漬する(工程S5)。ここで、処理時間、すなわち、水酸化カルシウム飽和水溶液に青果を浸漬する時間は、当該水酸化カルシウム飽和水溶液が強アルカリ性で除菌力が高いため、短時間(3秒~3分間)で十分であり、効率的に青果の洗浄処理を行うことができる。 Fruits and vegetables to be sterilized are immersed in the calcium hydroxide saturated aqueous solution (step S5). Here, the treatment time, that is, the time for immersing fruits and vegetables in the saturated calcium hydroxide aqueous solution is short (3 seconds to 3 minutes) because the saturated calcium hydroxide aqueous solution is strongly alkaline and has high sterilization power. Therefore, it is possible to efficiently wash fruits and vegetables.

表1には、上記製造方法で製造された水酸化カルシウム粉末と一般的な農業用消石灰との、除菌力の比較データを示す。表1における試験結果の表上段の数値の単位はLog10乗であり、表下段の数値は表上段の数値を実数化し%表示したものである。上記製造方法で製造された水酸化カルシウム粉末を用いた場合は、99.99%までウイルスを略完全に不活性化することができ、ウイルスを完全に不活性化することができない消石灰に比較して、高い除菌力が示されている。

Figure 0007158764000001
また、表2は、上記製造方法で製造された水酸化カルシウム粉末を用いて青果物を除菌した場合、食中毒防止に有効であることを示す資料である。
試験ウイルスは、主要な食中毒菌(黄色ブドウ球菌、大腸菌、腸管大腸菌O157、サルモネラ、ノロウイルス代替ネコカリシウイルス)であり、試験結果のAは各細菌やウイルスを直接的に作用させた試験であり、Bは有機物で汚染された環境を想定しアルブミン5%を加えての試験である。試験結果の各表の下欄に示すように、全ての試験ウイルスを100.00%まで完全に不活性化することができ、高い除菌力が示されている。
Figure 0007158764000002
Table 1 shows comparison data of the sterilization power between the calcium hydroxide powder produced by the above production method and common agricultural slaked lime. In Table 1, the unit of numerical values in the upper part of the table of the test results is Log10 X power, and the numerical values in the lower part of the table are expressed as percentages by converting the numerical values in the upper part of the table into real numbers. When using the calcium hydroxide powder produced by the above production method, viruses can be almost completely inactivated to 99.99%, compared to slaked lime, which cannot completely inactivate viruses. It has been shown to have high sterilizing power.
Figure 0007158764000001
Further, Table 2 is data showing that the calcium hydroxide powder produced by the above production method is effective in preventing food poisoning when fruits and vegetables are sterilized.
The test viruses are major food-poisoning bacteria (Staphylococcus aureus, Escherichia coli, enteric Escherichia coli O157, salmonella, norovirus-alternative feline calicivirus), and test result A is a test in which each bacterium or virus acts directly. B is a test in which 5% albumin is added assuming an environment polluted with organic matter. As shown in the lower column of each test result table, all test viruses could be completely inactivated up to 100.00%, indicating high sterilizing power.
Figure 0007158764000002

以上説明したように、上記製造方法により、青果洗浄用の微細な高品質の水酸化カルシウム粉末を製造することができ、当該水酸化カルシウム粉末を用いて、安全かつ短時間で青果の洗浄処理を行うことができる。 As described above, by the above-described production method, a fine, high-quality calcium hydroxide powder for washing fruits and vegetables can be produced, and the calcium hydroxide powder can be used to wash fruits and vegetables safely and in a short time. It can be carried out.

Claims (3)

青果洗浄用の水酸化カルシウム粉末製造方法であって、
炭酸カルシウムを土中炉で焼成することにより、硬焼生石灰を生成する硬焼生石灰生成工程と、
前記硬焼生石灰生成工程において生成された硬焼生石灰に加水処理を行うことにより、水酸化カルシウム粉末を生成する水酸化カルシウム粉末生成工程と、
前記水酸化カルシウム粉末生成工程において生成された水酸化カルシウム粉末のうち、噴霧飛散した水酸化カルシウム粉末を集塵する水酸化カルシウム粉末集塵工程と
を備えたことを特徴とする青果洗浄用の水酸化カルシウム粉末製造方法。
A method for producing calcium hydroxide powder for washing fruits and vegetables, comprising:
a hard-burned quicklime generating step for generating hard-burned quicklime by firing calcium carbonate in an underground furnace;
a calcium hydroxide powder generating step for generating calcium hydroxide powder by subjecting the hard-burned quicklime generated in the hard-burned quicklime-generating step to water treatment;
and a calcium hydroxide powder dust collection step for collecting sprayed and scattered calcium hydroxide powder among the calcium hydroxide powder generated in the calcium hydroxide powder generation step. Calcium oxide powder manufacturing method.
前記硬焼生石灰生成工程において、前記焼成する期間は3日間であることを特徴とする
請求項1に記載の青果洗浄用の水酸化カルシウム粉末製造方法。
2. The method for producing calcium hydroxide powder for washing fruits and vegetables according to claim 1, wherein in said hard-burned quicklime generating step, said burning period is 3 days.
請求項1又は2に記載の水酸化カルシウム粉末製造方法により製造された水酸化カルシウム粉末を水に添加して、水酸化カルシウム飽和水溶液を生成する工程と、
前記水酸化カルシウム飽和水溶液で青果を3秒~3分間処理する工程と
を備えたことを特徴とする青果洗浄方法
A step of adding calcium hydroxide powder produced by the method for producing calcium hydroxide powder according to claim 1 or 2 to water to produce a calcium hydroxide saturated aqueous solution;
a step of treating fruits and vegetables with the saturated aqueous solution of calcium hydroxide for 3 seconds to 3 minutes;
A method for washing fruits and vegetables, comprising:
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006096593A (en) 2004-09-29 2006-04-13 Ryoko Lime Industry Co Ltd Method for producing light granular slaked lime and light granular slaked lime obtained by this method
JP2008079579A (en) 2006-09-29 2008-04-10 Nisshin Seifun Group Inc Method for sterilizing vegetables and fruits
JP2018119291A (en) 2017-01-24 2018-08-02 有限会社小川節夫研究所 Coating agent for building interior and interior surface coating method
JP2019189471A (en) 2018-04-18 2019-10-31 尊司 大山 Manufacturing method of food additives and antibacterial/disinfecting/sterilizing materials using calcium components in hard water
JP2020083741A (en) 2018-11-30 2020-06-04 株式会社プラスラボ Shell burned product

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006096593A (en) 2004-09-29 2006-04-13 Ryoko Lime Industry Co Ltd Method for producing light granular slaked lime and light granular slaked lime obtained by this method
JP2008079579A (en) 2006-09-29 2008-04-10 Nisshin Seifun Group Inc Method for sterilizing vegetables and fruits
JP2018119291A (en) 2017-01-24 2018-08-02 有限会社小川節夫研究所 Coating agent for building interior and interior surface coating method
JP2019189471A (en) 2018-04-18 2019-10-31 尊司 大山 Manufacturing method of food additives and antibacterial/disinfecting/sterilizing materials using calcium components in hard water
JP2020083741A (en) 2018-11-30 2020-06-04 株式会社プラスラボ Shell burned product

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