JP7179664B2 - detergent composition - Google Patents
detergent composition Download PDFInfo
- Publication number
- JP7179664B2 JP7179664B2 JP2019065334A JP2019065334A JP7179664B2 JP 7179664 B2 JP7179664 B2 JP 7179664B2 JP 2019065334 A JP2019065334 A JP 2019065334A JP 2019065334 A JP2019065334 A JP 2019065334A JP 7179664 B2 JP7179664 B2 JP 7179664B2
- Authority
- JP
- Japan
- Prior art keywords
- detergent composition
- foam
- sodium
- present
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 20
- 239000003599 detergent Substances 0.000 title claims description 14
- -1 acyl glycine salt Chemical class 0.000 claims description 9
- 239000002280 amphoteric surfactant Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 4
- 125000005354 acylalkyl group Chemical group 0.000 claims description 3
- 239000000845 maltitol Substances 0.000 claims description 3
- 235000010449 maltitol Nutrition 0.000 claims description 3
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 claims description 3
- 229940035436 maltitol Drugs 0.000 claims description 3
- 239000006260 foam Substances 0.000 description 26
- 239000011734 sodium Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 230000014759 maintenance of location Effects 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 235000004279 alanine Nutrition 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- GLSRFBDXBWZNLH-UHFFFAOYSA-L disodium;2-chloroacetate;2-(4,5-dihydroimidazol-1-yl)ethanol;hydroxide Chemical compound [OH-].[Na+].[Na+].[O-]C(=O)CCl.OCCN1CCN=C1 GLSRFBDXBWZNLH-UHFFFAOYSA-L 0.000 description 3
- 229960001484 edetic acid Drugs 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- IXOCGRPBILEGOX-UHFFFAOYSA-N 3-[3-(dodecanoylamino)propyl-dimethylazaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)CS([O-])(=O)=O IXOCGRPBILEGOX-UHFFFAOYSA-N 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 2
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- 150000007514 bases Chemical class 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229940083542 sodium Drugs 0.000 description 2
- HVFAVOFILADWEZ-UHFFFAOYSA-M sodium;2-[2-(dodecanoylamino)ethyl-(2-hydroxyethyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCN(CCO)CC([O-])=O HVFAVOFILADWEZ-UHFFFAOYSA-M 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- YNCPXBIZAPNQIJ-UHFFFAOYSA-N 1h-imidazole;sodium Chemical compound [Na].C1=CNC=N1 YNCPXBIZAPNQIJ-UHFFFAOYSA-N 0.000 description 1
- DMQQXDPCRUGSQB-UHFFFAOYSA-N 2-[3-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCCN(CC(O)=O)CC(O)=O DMQQXDPCRUGSQB-UHFFFAOYSA-N 0.000 description 1
- HVYJSOSGTDINLW-UHFFFAOYSA-N 2-[dimethyl(octadecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O HVYJSOSGTDINLW-UHFFFAOYSA-N 0.000 description 1
- AMRBZKOCOOPYNY-QXMHVHEDSA-N 2-[dimethyl-[(z)-octadec-9-enyl]azaniumyl]acetate Chemical compound CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)CC([O-])=O AMRBZKOCOOPYNY-QXMHVHEDSA-N 0.000 description 1
- LLAZLZZZFXWUOA-UHFFFAOYSA-N 2-hydroxyethyl 2-aminopropanoate Chemical compound CC(N)C(=O)OCCO LLAZLZZZFXWUOA-UHFFFAOYSA-N 0.000 description 1
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- 240000006890 Erythroxylum coca Species 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- QGCUAFIULMNFPJ-UHFFFAOYSA-N Myristamidopropyl betaine Chemical compound CCCCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O QGCUAFIULMNFPJ-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- JWGGSJFIGIGFSQ-UHFFFAOYSA-N N-dodecanoylglycine Chemical class CCCCCCCCCCCC(=O)NCC(O)=O JWGGSJFIGIGFSQ-UHFFFAOYSA-N 0.000 description 1
- UEYROBDNFIWNST-UHFFFAOYSA-N N-octadecanoylglycine Chemical class CCCCCCCCCCCCCCCCCC(=O)NCC(O)=O UEYROBDNFIWNST-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- PCHDVNKJIYLQOC-UHFFFAOYSA-N [Cl-].C[NH+]1C=NCC1.OCCC(=O)OCCCCCCCCCCCCCCCCC Chemical compound [Cl-].C[NH+]1C=NCC1.OCCC(=O)OCCCCCCCCCCCCCCCCC PCHDVNKJIYLQOC-UHFFFAOYSA-N 0.000 description 1
- GWVPJQDUGPKIOI-UQKRIMTDSA-N [Na].CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O Chemical compound [Na].CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O GWVPJQDUGPKIOI-UQKRIMTDSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 235000008957 cocaer Nutrition 0.000 description 1
- ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 1
- 229940047648 cocoamphodiacetate Drugs 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 229940065856 cocoyl glycinate Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000003074 decanoyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C(*)=O 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229940047642 disodium cocoamphodiacetate Drugs 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229960004585 etidronic acid Drugs 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229940091855 sodium lauraminopropionate Drugs 0.000 description 1
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
- LLKGTXLYJMUQJX-UHFFFAOYSA-M sodium;3-[2-carboxyethyl(dodecyl)amino]propanoate Chemical compound [Na+].CCCCCCCCCCCCN(CCC(O)=O)CCC([O-])=O LLKGTXLYJMUQJX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、泡質が良好で、泡持ちに優れる洗浄料組成物に関する。 TECHNICAL FIELD The present invention relates to a detergent composition having good foam quality and excellent foam retention.
従来より、洗浄料として、種々の商品が開発されており、特に界面活性剤を基剤とするものは、低刺激でありながら、良好な洗浄力を有するため、洗顔料や全身洗浄料等に用いられている（特許文献１）。しかし、泡質及び泡持ちに関しては問題があった。 Various products have been developed as cleansers, especially those based on surfactants, which are mild yet have good detergency, and are therefore suitable for facial cleansers and body cleansers. is used (Patent Document 1). However, there were problems with foam quality and foam retention.
本発明は、泡質が良好で、泡持ちに優れる洗浄料組成物を提供することを課題とする。 An object of the present invention is to provide a detergent composition having good foam quality and excellent foam retention.
本発明は、
下記（Ａ）～（Ｄ）を含有する洗浄料組成物
（Ａ）アシルグリシン塩
（Ｂ）アシルアルキル中性アミノ酸塩
（Ｃ）両性界面活性剤
（Ｄ）マルチトール
を提供する。
The present invention
Provided is a detergent composition containing the following (A) to (D): (A) acylglycine salt (B) acylalkyl neutral amino acid salt (C) amphoteric surfactant (D) maltitol.
本発明の洗浄料組成物は、泡質が良好で、泡持ちに優れるという効果を発揮する。 The cleansing composition of the present invention exhibits an effect of good foam quality and excellent foam retention.
以下本発明を実施するための形態を説明する。 A mode for carrying out the present invention will be described below.
本発明の洗浄料組成物は、使用する部位により、洗髪料、洗顔料、ボディ洗浄料等の用途に用いることができる。 The cleansing composition of the present invention can be used for applications such as hair cleansing, facial cleansing, and body cleansing, depending on the site to be used.
本発明に用いられるアシルグリシン塩としては、ココイルグリシン塩，ラウロイルグリシン塩，ミリストイルグリシン塩，ステアロイルグリシン塩等が挙げられる。ココイルグリシン塩を用いることが好ましい。塩を形成する塩基性化合物としては、ナトリウム，カリウム，アルギニン，リシン，ジエタノールアミン，トリエタノールアミン等が挙げられ、ナトリウム，カリウムがより好ましい。 Acylglycinates used in the present invention include cocoylglycinates, lauroylglycinates, myristoylglycinates, stearoylglycinates and the like. Cocoyl glycinate is preferably used. Examples of basic compounds that form salts include sodium, potassium, arginine, lysine, diethanolamine and triethanolamine, with sodium and potassium being more preferred.
配合量としては洗浄料組成物全量に対し、１～７０質量％が好ましく、より好ましくは３～５０質量％である。 The blending amount is preferably 1 to 70% by mass, more preferably 3 to 50% by mass, based on the total amount of the detergent composition.
本発明に用いられるアシルアルキル中性アミノ酸塩のアシル基としては、オクタノイル，デカノイル，ラウロイル，ミリストイル，パルミトイル，ステアロイル，オレオイル等が挙げられ、ラウロイルがより好ましい。アルキル基としては、メチル，エチル，プロピル，イソプロピル等が挙げられ、エチルがより好ましい。中性アミノ酸としてはグリシン，アラニン等が挙げられ、アラニンがより好ましい。塩を形成する塩基性化合物としては、ナトリウム，カリウム，アルギニン，リシン，ジエタノールアミン，トリエタノールアミン等が挙げられ、ナトリウム，カリウムがより好ましい。たとえば、ラウロイルメチルアラニンＮａ，ココイルメチルアラニンＮａ，ヤシ油脂肪酸アシルメチルアラニンＮａ等が挙げられる。 The acyl group of the acylalkyl neutral amino acid salt used in the present invention includes octanoyl, decanoyl, lauroyl, myristoyl, palmitoyl, stearoyl, oleoyl and the like, with lauroyl being more preferred. Examples of alkyl groups include methyl, ethyl, propyl, and isopropyl, with ethyl being more preferred. Examples of neutral amino acids include glycine and alanine, with alanine being more preferred. Examples of basic compounds that form salts include sodium, potassium, arginine, lysine, diethanolamine and triethanolamine, with sodium and potassium being more preferred. Examples thereof include sodium lauroylmethylalanine, sodium cocoylmethylalanine, sodium coconut oil fatty acid acylmethylalanine, and the like.
配合量としては洗浄料組成物全量に対し、０．１～１０質量％が好ましい。 The blending amount is preferably 0.1 to 10% by mass based on the total amount of the detergent composition.
本発明に用いられる両性界面活性剤としては、通常の化粧料に用いられる両性界面活性剤であれば特に制限されずに使用することができ、１種を単独でもしくは２種以上を併用して用いることができる。 As the amphoteric surfactant used in the present invention, any amphoteric surfactant that is commonly used in cosmetics can be used without particular limitation, and one type can be used alone or two or more types can be used in combination. can be used.
かかる両性界面活性剤としては、オレイルベタイン，（カプリル／カプラミド）プロピルベタイン，コカミドプロピルヒドロキシスルタイン，コカミドプロピルベタイン，ココアンホ酢酸Ｎａ，ココアンホジ酢酸２Ｎａ，ココアンホプロピオン酸Ｎａ，ココベタイン，ステアリルベタイン，パーム核脂肪酸アミドエチルヒドロキシエチルアミノプロピオン酸Ｎａ，パーム核脂肪酸アミドプロピルベタイン，ヒドロキシアルキル（Ｃ１２，１４）ヒドロキシエチルアラニン，ヘプタデシルヒドロキシエチルカルボキシラートメチルイミダゾリニウムクロリド／ヘプタデシルビスヒドロキシエチルイミダゾリニウム，ミリスタミドプロピルベタイン，ラウラミドプロピルヒドロキシスルタイン，ラウラミドプロピルベタイン，ラウラミノプロピオン酸Ｎａ，ラウリミノジプロピオン酸Ｎａ，ラウリルヒドロキシスルタイン，ラウリルベタイン，ラウロアンホ酢酸Ｎａ等が挙げられる。 Such amphoteric surfactants include oleyl betaine, (capryl/capramido)propyl betaine, cocamidopropyl hydroxysultaine, cocamidopropyl betaine, sodium cocoamphoacetate, disodium cocoamphodiacetate, sodium cocoamphopropionate, cocobetaine, stearyl betaine. , palm kernel fatty acid amidoethyl hydroxyethyl aminopropionate Na, palm kernel fatty acid amidopropyl betaine, hydroxyalkyl (C12,14) hydroxyethyl alanine, heptadecyl hydroxyethyl carboxylate methylimidazolinium chloride/heptadecyl bishydroxyethyl imidazol sodium, myristamidopropyl betaine, lauramidopropyl hydroxysultaine, lauramidopropyl betaine, sodium lauraminopropionate, sodium lauriminodipropionate, laurylhydroxysultaine, laurylbetaine, sodium lauroamphoacetate and the like.
本発明においては、コカミドプロピルベタイン、ココアンホ酢酸Ｎａ、ココアンホジ酢酸Ｎａ、ココアンホプロピオン酸Ｎａ、ラウロアンホ酢酸Ｎａから選択される１種又は２種以上を用いることが効果の観点から好ましく、さらにはコカミドプロピルベタイン及びココアンホ酢酸Ｎａから選択される１種又は２種を用いることが好ましい。 In the present invention, it is preferable to use one or more selected from cocamidopropyl betaine, sodium cocoamphoacetate, sodium cocoamphodiacetate, sodium cocoamphopropionate, and sodium lauroamphoacetate from the viewpoint of effect, and further coca It is preferable to use one or two selected from midopropyl betaine and sodium cocoamphoacetate.
配合量としては洗浄料組成物全量に対し１～２０質量％、好ましくは１～１５質量％である。１質量％未満では充分な泡質改善効果が得られず、２０質量％を超えると結晶の析出などの問題を生じるので好ましくない。 The blending amount is 1 to 20% by mass, preferably 1 to 15% by mass, based on the total amount of the detergent composition. If it is less than 1% by mass, a sufficient effect of improving foam quality cannot be obtained, and if it exceeds 20% by mass, problems such as precipitation of crystals occur, which is not preferable.
本発明に用いられるマルチトールは、グルコースとソルビトールが結合した二糖類の糖アルコールである。市販の、マルビット（物産フードサイエンス株式会社製）、粉末マビット（株式会社林原生物化学研究所製）等を用いることもできる。 The maltitol used in the present invention is a disaccharide sugar alcohol in which glucose and sorbitol are bound. Marbit (manufactured by Bussan Food Science Co., Ltd.), powder Mavit (manufactured by Hayashibara Biochemical Laboratory Co., Ltd.), etc., which are commercially available, can also be used.
配合量としては洗浄料組成物全量に対して、０．０１～３０質量％、好ましくは０．１～２５質量％であり、さらに好ましくは０．１～２０質量％である。 The blending amount is 0.01 to 30% by mass, preferably 0.1 to 25% by mass, more preferably 0.1 to 20% by mass, based on the total amount of the detergent composition.
本発明の洗浄料組成物は本発明の効果を損なわない範囲で多価アルコールを配合することができる。多価アルコールとしては、グリセリン，ポリグリセリン，1,3-ブチレングリコール，プロピレングリコール，イソプレングリコール，ポリエチレングリコール，ソルビトール，キシリトール等が挙げられる。 The detergent composition of the present invention may contain a polyhydric alcohol within a range that does not impair the effects of the present invention. Polyhydric alcohols include glycerin, polyglycerin, 1,3-butylene glycol, propylene glycol, isoprene glycol, polyethylene glycol, sorbitol, xylitol and the like.
本発明の洗浄料組成物はキレート剤を配合することができる。キレート剤は、特に限定されないが、エデト酸（エチレンジアミン四酢酸（ＥＤＴＡ））、エチレンジアミンヒドロキシエチル三酢酸、ジヒドロキシエチルエチレンジアミン二酢酸、1,3-プロパンジアミン四酢酸、ジエチレントリアミン五酢酸、トリエチレンテトラミン六酢酸、ニトリロ三酢酸、ヒドロキシエチルイミノ二酢酸、ヒドロキシエタンジホスホン酸、それらの塩等が挙げられ、１種または２種以上を適宜組み合わせて配合することができる。 The detergent composition of the present invention may contain a chelating agent. Chelating agents include, but are not limited to, edetic acid (ethylenediaminetetraacetic acid (EDTA)), ethylenediaminehydroxyethyltriacetic acid, dihydroxyethylethylenediaminediacetic acid, 1,3-propanediaminetetraacetic acid, diethylenetriaminepentaacetic acid, and triethylenetetraminehexaacetic acid. , nitrilotriacetic acid, hydroxyethyliminodiacetic acid, hydroxyethanediphosphonic acid, salts thereof, and the like, and one or two or more of them may be appropriately combined.
剤型としては、液状、ペースト状、固形を問わないが、液状が好ましい。 The dosage form may be liquid, paste or solid, but liquid is preferred.
洗浄料組成物は固形のものをそのまま又は泡吐出容器、エアゾール容器、ポンプ容器、チューブ容器、ボトル容器、ジャー容器等の容器に充填して用いる。泡吐出容器を用いることが好ましい。 The solid detergent composition is used as it is or after being filled into a container such as a foam discharge container, an aerosol container, a pump container, a tube container, a bottle container or a jar container. It is preferred to use a foam dispenser.
泡吐出容器とは泡吐出機構を備えた容器のことであり、泡吐出容器内に充填された洗浄料組成物と、空気とを混合して多孔質膜体を通過させることにより泡沫状に吐出することができる容器のことである。 A foam discharge container is a container equipped with a foam discharge mechanism, and the detergent composition filled in the foam discharge container is mixed with air and passed through a porous membrane to be discharged in the form of foam. It is a container that can be
泡吐出容器内部の多孔質膜体は、１００～４００メッシュが好ましい。 The porous membrane inside the foam discharge container is preferably 100 to 400 mesh.
本発明の洗浄料組成物には、上述の必須成分の他に、本発明の効果を損ねない範囲で、更にその他の成分を配合することができる。かかる成分としては、上記以外のアニオン界面活性剤、ノニオン界面活性剤、カチオン界面活性剤、エタノール、イソプロパノール、ブタノール等のアルコール類、カルボキシビニルポリマー、メチルセルロース、ポリエチレングリコール、ポリオキシエチレンポリオキシプロピレン共重合体等の高分子化合物、スクワラン、流動パラフィン、シリコーン油、ラノリン誘導体、脂肪酸、高級アルコール、ポリエーテル変性シリコーン等の過脂肪剤、パール化剤、香料、色素、紫外線吸収剤、酸化防止剤、殺菌剤、抗炎症剤、防腐剤等を配合することができる。 In addition to the essential components described above, the detergent composition of the present invention may further contain other components within a range that does not impair the effects of the present invention. Such components include anionic surfactants other than the above, nonionic surfactants, cationic surfactants, alcohols such as ethanol, isopropanol and butanol, carboxyvinyl polymers, methylcellulose, polyethylene glycol, polyoxyethylene-polyoxypropylene copolymers. Polymer compounds such as coalescence, squalane, liquid paraffin, silicone oil, lanolin derivatives, fatty acids, higher alcohols, hyperfatting agents such as polyether-modified silicone, pearlizing agents, fragrances, pigments, UV absorbers, antioxidants, sterilization agents, anti-inflammatory agents, antiseptics and the like can be incorporated.
本発明の洗浄料組成物の泡質及び泡持ちについて、以下の通り評価を行った。 The foam quality and foam retention of the detergent composition of the present invention were evaluated as follows.
[評価]
専門パネラー２名により、洗浄料組成物の泡質及び泡持ちについて評価を行った。
[evaluation]
Two expert panelists evaluated the foam quality and foam retention of the cleansing compositions.
[評価方法]
表１に示した処方を用いて洗浄料組成物を調製し、吐出口側１５０メッシュ、吸い口側１００メッシュの多孔質膜体を備えた泡吐出容器に充填、吐出させ、泡質及び泡持ちの評価を行った。泡持ちについては吐出してから３０分後の泡の状態を評価した。評価結果は下記の基準を用いて合議により判定した。
[Evaluation method]
A cleansing composition was prepared using the formulation shown in Table 1, filled into a foam-discharging container equipped with a porous membrane of 150 mesh on the discharge port side and 100 mesh on the suction port side, and discharged. was evaluated. For foam retention, the state of foam 30 minutes after ejection was evaluated. Evaluation results were determined by consensus using the following criteria.
[評価基準]泡質、泡持ち
◎：非常に良い
△：少し悪い
×：悪い
[Evaluation criteria] Foam quality, foam retention ◎: Very good △: Slightly bad ×: Bad
表１に示した通り、本発明の実施例１では泡質及び泡持ちにおいて良好な結果が得られた。 As shown in Table 1, in Example 1 of the present invention, good results were obtained in terms of foam quality and foam retention.
Claims (1)
（Ａ）アシルグリシン塩
（Ｂ）アシルアルキル中性アミノ酸塩
（Ｃ）両性界面活性剤
（Ｄ）マルチトール A detergent composition containing the following (A) to (D).
(A) acyl glycine salt (B) acyl alkyl neutral amino acid salt (C) amphoteric surfactant (D) maltitol
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019065334A JP7179664B2 (en) | 2019-03-29 | 2019-03-29 | detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019065334A JP7179664B2 (en) | 2019-03-29 | 2019-03-29 | detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2020164445A JP2020164445A (en) | 2020-10-08 |
| JP7179664B2 true JP7179664B2 (en) | 2022-11-29 |
Family
ID=72717203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019065334A Active JP7179664B2 (en) | 2019-03-29 | 2019-03-29 | detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP7179664B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7838958B2 (en) * | 2021-12-28 | 2026-04-01 | 株式会社コーセーホールディングス | composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002256298A (en) | 2001-03-02 | 2002-09-11 | Kanebo Ltd | Detergent composition |
| JP2012251074A (en) | 2011-06-03 | 2012-12-20 | Mikimoto Pharmaceut Co Ltd | Liquid detergent |
| JP2018002608A (en) | 2016-06-28 | 2018-01-11 | 紀伊産業株式会社 | Method for producing granula skin cleanser composition |
-
2019
- 2019-03-29 JP JP2019065334A patent/JP7179664B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002256298A (en) | 2001-03-02 | 2002-09-11 | Kanebo Ltd | Detergent composition |
| JP2012251074A (en) | 2011-06-03 | 2012-12-20 | Mikimoto Pharmaceut Co Ltd | Liquid detergent |
| JP2018002608A (en) | 2016-06-28 | 2018-01-11 | 紀伊産業株式会社 | Method for producing granula skin cleanser composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2020164445A (en) | 2020-10-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4696507B2 (en) | Cleaning composition | |
| JP4527655B2 (en) | Cleaner composition in former container | |
| JP7501373B2 (en) | Low viscosity liquid cleaner | |
| JP2010241909A (en) | Cleaning composition | |
| JP5490388B2 (en) | Liquid detergent composition in former container | |
| EP3563828B1 (en) | Article for skin cleansing agent | |
| JP2012533532A (en) | Compositions and methods | |
| JPWO2005078039A1 (en) | Thickening composition | |
| JP2012107147A (en) | Liquid cleaning agent composition contained in foamer container | |
| JP7758416B2 (en) | Liquid skin cleanser composition | |
| JP7179664B2 (en) | detergent composition | |
| JP7049938B2 (en) | Cleaning fee | |
| JP7247710B2 (en) | personal care composition | |
| JPH083585A (en) | Detergent composition | |
| JP5745945B2 (en) | Foam discharge type water-based gel skin cleanser | |
| JP4448373B2 (en) | Cleaning composition | |
| JP3711576B2 (en) | Non-gas former composition | |
| JP3194401B2 (en) | Creamy detergent composition | |
| CA3238164A1 (en) | Personal care compositions | |
| JP5603599B2 (en) | Cleaner in former container | |
| US20210283034A1 (en) | Cleansing material composition | |
| JP7778998B2 (en) | Cleaning agent for filling foam containers | |
| JP7833797B2 (en) | Hair cosmetic composition | |
| JPH06264091A (en) | Detergent composition | |
| JP2026009247A (en) | Liquid skin cleanser composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20210906 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20220525 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20220607 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20221115 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20221116 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7179664 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |