Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP7200494B2 - Wet-laid non-woven fabric for filters - Google Patents
[go: Go Back, main page]

JP7200494B2 - Wet-laid non-woven fabric for filters - Google Patents

Wet-laid non-woven fabric for filters Download PDF

Info

Publication number
JP7200494B2
JP7200494B2 JP2018068385A JP2018068385A JP7200494B2 JP 7200494 B2 JP7200494 B2 JP 7200494B2 JP 2018068385 A JP2018068385 A JP 2018068385A JP 2018068385 A JP2018068385 A JP 2018068385A JP 7200494 B2 JP7200494 B2 JP 7200494B2
Authority
JP
Japan
Prior art keywords
wet
average fiber
nonwoven fabric
laid nonwoven
dtex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2018068385A
Other languages
Japanese (ja)
Other versions
JP2019177349A (en
Inventor
健人 高見
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Priority to JP2018068385A priority Critical patent/JP7200494B2/en
Priority to PCT/JP2019/012395 priority patent/WO2019188923A1/en
Priority to EP19777006.8A priority patent/EP3777991A4/en
Priority to US17/040,655 priority patent/US20210016213A1/en
Priority to CN201980023208.6A priority patent/CN111971105A/en
Publication of JP2019177349A publication Critical patent/JP2019177349A/en
Application granted granted Critical
Publication of JP7200494B2 publication Critical patent/JP7200494B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Filtering Materials (AREA)
  • Nonwoven Fabrics (AREA)
  • Paper (AREA)

Description

本発明は、付着した異物の除去に優れたフィルター用湿式不織布に関するものである。 TECHNICAL FIELD The present invention relates to a wet-laid nonwoven fabric for filters, which is excellent in removing adhering foreign matter.

近年、空調用、エアコン用、自動車用フィルター等の分野において、濾材の高性能化、多様化の要請が急激に高まっている。使用によりフィルターに付着した異物は容易には除去できないため、フィルターの再利用は難しい状況にある。フィルターの再利用に関しては、例えば吸引ノズルを用いた粉塵除去方法がある(特許文献1)。 In recent years, in the fields of air conditioners, air conditioners, automobile filters, and the like, there has been a rapid increase in demand for higher performance and diversification of filter media. It is difficult to reuse the filter because the foreign matter adhering to the filter cannot be easily removed during use. Regarding the reuse of filters, there is a dust removal method using a suction nozzle, for example (Patent Document 1).

特開2014-136475号公報JP 2014-136475 A

しかしながら、吸引ノズルを使用して異物を除去すると、フィルターが変形し、性能が十分に回復しないといった問題がある。 However, when the foreign matter is removed using the suction nozzle, there is a problem that the filter is deformed and the performance is not sufficiently recovered.

そこで本発明は、上記課題に鑑みなされ、その目的は、付着した異物を容易に除去でき、再利用可能なフィルター用湿式不織布を提供することにある。 Accordingly, the present invention has been made in view of the above problems, and an object of the present invention is to provide a reusable wet-laid nonwoven fabric for filters, from which adhering foreign matter can be easily removed.

本発明者らは鋭意検討した結果、以下に示す手段により、上記課題を解決できることを見出し、本発明に到達した。すなわち本発明は以下の通りである。
(1)ビニロン、ポリエステル、及びポリビニルアルコールから構成され、通気の上流側に配置される面の表面粗さ(SMD)が2.7μm以下であるフィルター用湿式不織布。
(2)通気の上流側に配置される面の平均摩擦係数(MIU)が0.15以下である(1)に記載のフィルター用湿式不織布。
(3)前記ポリビニルアルコールを10~20重量%含有している(1)または(2)に記載のフィルター用湿式不織布。
(4)繊維長30mm以下の繊維から成ることを特徴とする(1)~(3)のいずれか1つに記載のフィルター用湿式不織布。
(5)ポリアクリル酸エステルを0.001~0.1重量%含有している(1)~(4)のいずれか1つに記載のフィルター用湿式不織布。
(6)(1)~(5)のいずれか1つに記載のフィルター用湿式不織布を用いたフィルター。
As a result of intensive studies, the inventors of the present invention have found that the above problems can be solved by means shown below, and have completed the present invention. That is, the present invention is as follows.
(1) A wet-laid nonwoven fabric for filters, which is composed of vinylon, polyester, and polyvinyl alcohol, and has a surface roughness (SMD) of 2.7 μm or less on the surface located on the upstream side of ventilation.
(2) The wet-laid nonwoven fabric for filters according to (1), wherein the average friction coefficient (MIU) of the surface arranged on the upstream side of ventilation is 0.15 or less.
(3) The wet-laid nonwoven fabric for filters according to (1) or (2), which contains 10 to 20% by weight of the polyvinyl alcohol.
(4) The wet-laid nonwoven fabric for filters according to any one of (1) to (3), which is made of fibers having a fiber length of 30 mm or less.
(5) The wet-laid nonwoven fabric for filters according to any one of (1) to (4), containing 0.001 to 0.1% by weight of polyacrylate.
(6) A filter using the wet-laid nonwoven fabric for filters according to any one of (1) to (5).

本発明のフィルター用湿式不織布は、通気の上流側に配置される面が平坦であるため、簡易に異物を除去できる。そのため、本発明のフィルター用湿式不織布を用いたフィルターの清掃を容易にすることができる。 Since the wet-laid nonwoven fabric for filters of the present invention has a flat surface arranged on the upstream side of ventilation, foreign substances can be easily removed. Therefore, cleaning of the filter using the wet-laid nonwoven fabric for filters of the present invention can be facilitated.

以下、本発明の実施形態について詳細に説明する。
本実施形態の湿式不織布は、ビニロン、ポリエステル、及びポリビニルアルコールから構成され、前記ポリビニルアルコールを10~20重量%含有しており、通気の上流側に配置される面の表面粗さ(SMD)が2.7μm以下であり、フィルターに用いられる。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, embodiments of the present invention will be described in detail.
The wet-laid nonwoven fabric of the present embodiment is composed of vinylon, polyester, and polyvinyl alcohol, and contains 10 to 20% by weight of the polyvinyl alcohol. It is 2.7 μm or less and is used for filters.

本明細書において表面粗さとは、カトーテック製摩擦感テスター(KES-SE)による評価において、表面の凹凸データの平均偏差を示すSMDの値である。SMDの値が大きくなるに従い、表面が粗く、凹凸性を有していることを示す。 The term "surface roughness" as used herein refers to an SMD value that indicates the average deviation of surface unevenness data as evaluated by a Kato Tech friction tester (KES-SE). As the SMD value increases, it indicates that the surface is rougher and has unevenness.

本実施形態の湿式不織布は、通気の上流側に配置される面の表面粗さ(SMD)が2.7μm以下である。2.7μmよりも大きいと、付着した異物が表面の凹凸性により除去し難い。 The wet-laid nonwoven fabric of this embodiment has a surface roughness (SMD) of 2.7 μm or less on the surface arranged on the upstream side of ventilation. If it is larger than 2.7 μm, it is difficult to remove the adhering foreign matter due to the unevenness of the surface.

本明細書において平均摩擦係数とは、カトーテック製摩擦感テスター(KES-SE)による評価において測定される表面の滑り度合いの平均摩擦係数(MIU)の値である。MIUの値が小さくなるに従い、表面が滑り易いことを示す。 The average friction coefficient as used herein is the value of the average friction coefficient (MIU) of the degree of slippage of the surface measured in the evaluation by Kato Tech Co., Ltd.'s friction tester (KES-SE). A smaller MIU value indicates a slippery surface.

本実施形態の湿式不織布は、通気の上流側に配置される面の平均摩擦係数を示すMIUが0.15である。0.15よりも大きいと、付着した異物が表面の摩擦により除去し難い。 The wet-laid nonwoven fabric of this embodiment has an MIU of 0.15, which indicates the average coefficient of friction of the surface arranged on the upstream side of ventilation. When it is larger than 0.15, it is difficult to remove adhering foreign matter due to surface friction.

本実施形態の湿式不織布を構成する繊維の平均繊維径は、1~100μmが好ましく、5~50μmがより好ましい。構成繊維の平均繊維径が1μmよりも小さいと、繊維間の空隙も狭くなり、空気中の塵埃がカバー層上に堆積し、通気抵抗が急上昇する。構成繊維の平均繊維径が100μmよりも大きいと、異物を除去し難くなる。 The average fiber diameter of the fibers constituting the wet-laid nonwoven fabric of this embodiment is preferably 1 to 100 μm, more preferably 5 to 50 μm. If the average fiber diameter of the constituent fibers is less than 1 μm, the gaps between the fibers become narrow, dust in the air accumulates on the cover layer, and the ventilation resistance rises sharply. If the average fiber diameter of the constituent fibers is greater than 100 µm, it becomes difficult to remove foreign matter.

本実施形態の濾材の不織布Bを構成する繊維の繊維長は30mm以下が好ましい。繊維長が30mmよりも大きいと、繊維が厚み方向に配向しやすくなり、表面粗さが大きくなる。 The fiber length of the fibers constituting the nonwoven fabric B of the filter medium of this embodiment is preferably 30 mm or less. If the fiber length is longer than 30 mm, the fibers tend to be oriented in the thickness direction, resulting in increased surface roughness.

本実施形態の湿式不織布は、厚みが0.1~3.0mmであることが好ましい。厚みが0.1mmよりも小さいと地合いの問題が生じる。厚みが3.0mmよりも大きいとフィルター全体の厚みが大き過ぎ、フィルターをプリーツ状にした場合に構造抵抗が大きくなり、結果としてフィルター全体での通気抵抗が高くなり過ぎ、実用上問題がある。 The wet-laid nonwoven fabric of this embodiment preferably has a thickness of 0.1 to 3.0 mm. If the thickness is less than 0.1 mm, formation problems arise. If the thickness is more than 3.0 mm, the overall thickness of the filter is too large, and when the filter is pleated, the structural resistance increases.

本実施形態の湿式不織布は、目付量が10~100g/mであることが好ましく、20~80g/mがより好ましい。目付が10g/m未満であれば地合いが悪くなる。目付が100g/mを越えると、厚みが大きくなり、フィルターに用いる際にプリーツ加工時の構造抵抗が大きくなる。 The wet-laid nonwoven fabric of the present embodiment preferably has a basis weight of 10 to 100 g/m 2 , more preferably 20 to 80 g/m 2 . If the basis weight is less than 10 g/m 2 , the texture is poor. If the weight per unit area exceeds 100 g/m 2 , the thickness increases and the structural resistance increases during pleating when used for filters.

本実施形態の湿式不織布を構成する繊維構造体の素材は、ビニロン、ポリエステル、及びポリビニルアルコールから構成されている。ここで、ポリビニルアルコールを10~20重量%含有しているのが好ましい。10%未満であると、湿式不織布の腰強度が弱く、更には表面平滑性が得られにくい。20重量%よりも多いと、通気抵抗が上がってしまう。 The material of the fibrous structure constituting the wet-laid nonwoven fabric of this embodiment is composed of vinylon, polyester, and polyvinyl alcohol. Here, it is preferable to contain 10 to 20% by weight of polyvinyl alcohol. If it is less than 10%, the wet-laid nonwoven fabric will have low stiffness, and it will be difficult to obtain surface smoothness. If it is more than 20% by weight, the ventilation resistance will increase.

本実施形態の湿式不織布は、ポリアクリル酸エステルは0.001~0.1重量%含有していることが好ましい。0.001%未満であると、表面平滑性及び表面滑り性が向上せず、0.1重量%よりも多くなると、通気抵抗が上がってしまう。 The wet-laid nonwoven fabric of this embodiment preferably contains 0.001 to 0.1% by weight of polyacrylate. If it is less than 0.001% by weight, the surface smoothness and surface slipperiness will not be improved, and if it is more than 0.1% by weight, the ventilation resistance will increase.

本実施形態の湿式不織布は、公知の湿式抄紙法により公知の抄紙機で製造することが可能である。 The wet-laid nonwoven fabric of the present embodiment can be produced by a known wet-laid papermaking method using a known paper machine.

以下に実施例を示し、本発明をより具体的に説明するが、本発明は実施例に記載されたものに限定されない。まず、実施例および比較例で用いた湿式不織布の物性の測定方法について説明する。 EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to those described in the examples. First, the method for measuring the physical properties of the wet-laid nonwoven fabrics used in Examples and Comparative Examples will be described.

[表面凹凸性]
評価はカトーテック製、摩擦感テスター(KES-SE)にて評価を行う。テーブルに固定した試料(不織布)を1mm/sの速度で、10gfの荷重をかけながら、接触子を掃引させ、検出された表面凹凸データの平均偏差を表面粗さ(SMD)の値とする。
[Surface unevenness]
The evaluation is performed using a friction tester (KES-SE) manufactured by Kato Tech. The sample (nonwoven fabric) fixed on the table is swept at a speed of 1 mm/s while applying a load of 10 gf, and the average deviation of the detected surface unevenness data is taken as the surface roughness (SMD) value.

[平均摩擦係数]
評価はカトーテック製、摩擦感テスター(KES-SE)にて評価を行う。テーブルに固定した試料を1mm/sの速度で、25gfの荷重をかけながら、接触子を掃引させ、検出された平均摩擦係数(MIU)を算出する。
[Average coefficient of friction]
The evaluation is performed using a friction tester (KES-SE) manufactured by Kato Tech. The sample fixed on the table is swept with a load of 25 gf at a speed of 1 mm/s, and the detected average coefficient of friction (MIU) is calculated.

[異物除去性]
15cm角のサイズに試料を切り取り、JIS15種粉塵を5m/minにて負荷させ、通気抵抗がベースよりも50Paアップした時点で負荷を止める。試料に捕集された粉塵量を重量にて評価する。そして15cm角の試料を机上に対して垂直に治具に設置し、高さ10cmのところから10回落とす。最後に試料の重量を測り、試料から落ちた重量を確認する。試料から落ちた重量が付着量の7割であれば、異物除去性能は良好である(○)との判定とする。
[Foreign matter removal]
A sample of 15 cm square was cut and loaded with JIS class 15 dust at 5 m 3 /min. The amount of dust collected on the sample is evaluated by weight. Then, a 15 cm square sample is placed on a jig perpendicularly to the desk and dropped 10 times from a height of 10 cm. Finally, the sample is weighed to determine the weight that has fallen off the sample. If the weight dropped from the sample is 70% of the adhered amount, it is determined that the foreign matter removing performance is good (○).

参考例1〕
ビニロン繊維(17dtex、平均繊維長12mm、平均繊維径40μm)、ビニロン繊維(7dtex、平均繊維長10mm、平均繊維径25μm)、ビニロン繊維(2.2dtex、平均繊維長6mm、平均繊維径15μm)ポリエステル繊維(0.6dtex、平均繊維長5mm、平均繊維径8μm)、ポリエステル繊維(2.2dtex、平均繊維長5mm、平均繊維径15μm)、PVA繊維(1.1dtex、平均繊維長3mm、平均繊維径10μm)を、26:31.25:5.25:11.25:11.25:15の重量比で混繊し、パルパーで水中に分散させ、湿式抄紙用原液を調整した。
この湿式抄紙用原液を短網式抄紙法にて抄紙して湿潤ウェッブをつくり、その後プレスローラーで軽く絞り140℃で回転乾燥ドラムにて乾燥し、目付40g/m2、厚み0.3mmの実施例1の湿式不織布を得た。
[ Reference Example 1]
Vinylon fiber (17 dtex, average fiber length 12 mm, average fiber diameter 40 μm), vinylon fiber (7 dtex, average fiber length 10 mm, average fiber diameter 25 μm), vinylon fiber (2.2 dtex, average fiber length 6 mm, average fiber diameter 15 μm) polyester Fiber (0.6 dtex, average fiber length 5 mm, average fiber diameter 8 μm), polyester fiber (2.2 dtex, average fiber length 5 mm, average fiber diameter 15 μm), PVA fiber (1.1 dtex, average fiber length 3 mm, average fiber diameter 10 μm) were mixed at a weight ratio of 26:31.25:5.25:11.25:11.25:15 and dispersed in water with a pulper to prepare a stock solution for wet papermaking.
This wet papermaking stock solution is made into paper by a short-mesh papermaking method to form a wet web, which is then lightly squeezed with a press roller and dried with a rotary drying drum at 140°C to obtain a basis weight of 40 g/m2 and a thickness of 0.3 mm. A wet-laid nonwoven fabric of No. 1 was obtained.

〔実施例2〕
ビニロン繊維(7dtex、平均繊維長10mm、平均繊維径25μm)、ビニロン繊維(2.2dtex、平均繊維長6mm、平均繊維径15μm)、ポリエステル繊維(0.6dtex、平均繊維長5mm、平均繊維径8μm)、ポリエステル繊維(2.2dtex、平均繊維長5mm、平均繊維径15μm)、PVA繊維(1.1dtex、平均繊維長3mm、平均繊維径10μm)を、51:7.6:16.2:16.2:9の重量比で混繊し、更にポリアクリル酸エステルを投入した繊維重量に対して0.05%となるように測り、パルパーで水中に分散させ、湿式抄紙用原液を調整した。
この湿式抄紙用原液を短網式抄紙法にて抄紙して湿潤ウェッブをつくり、その後プレスローラーで軽く絞り140℃で回転乾燥ドラムにて乾燥し、目付30g/m、厚み0.2mmの実施例2の湿式不織布を得た。
[Example 2]
Vinylon fiber (7 dtex, average fiber length 10 mm, average fiber diameter 25 μm), vinylon fiber (2.2 dtex, average fiber length 6 mm, average fiber diameter 15 μm), polyester fiber (0.6 dtex, average fiber length 5 mm, average fiber diameter 8 μm ), polyester fiber (2.2 dtex, average fiber length 5 mm, average fiber diameter 15 μm), PVA fiber (1.1 dtex, average fiber length 3 mm, average fiber diameter 10 μm), 51: 7.6: 16.2: 16 Fibers were mixed at a weight ratio of 2:9, and polyacrylic acid ester was weighed to be 0.05% based on the weight of the fibers added, and dispersed in water with a pulper to prepare a stock solution for wet papermaking.
This wet papermaking stock solution is made into paper by a short-mesh papermaking method to form a wet web, which is then lightly squeezed with a press roller and dried with a rotary drying drum at 140° C. to obtain a basis weight of 30 g/m 2 and a thickness of 0.2 mm. A wet-laid nonwoven of Example 2 was obtained.

〔実施例3〕
ビニロン繊維(7dtex、平均繊維長10mm、平均繊維径25μm)、ビニロン繊維(2.2dtex、平均繊維長6mm、平均繊維径15μm)ポリエステル繊維(0.6dtex、平均繊維長5mm、平均繊維径8μm)、ポリエステル繊維(2.2dtex、平均繊維長5mm、平均繊維径15μm)、PVA繊維(1.1dtex、平均繊維長3mm、平均繊維径10μm)を、45:7.6:16.2:16.2:15の重量比で混繊し、更にポリアクリル酸エステルを投入した繊維重量に対して0.05%となるように測り、パルパーで水中に分散させ、湿式抄紙用原液を調整した。
この湿式抄紙用原液を短網式抄紙法にて抄紙して湿潤ウェッブをつくり、その後プレスローラーで軽く絞り140℃で回転乾燥ドラムにて乾燥し、目付30g/m、厚み0.2mmの実施例3の湿式不織布を得た。
[Example 3]
Vinylon fiber (7 dtex, average fiber length 10 mm, average fiber diameter 25 μm), vinylon fiber (2.2 dtex, average fiber length 6 mm, average fiber diameter 15 μm) polyester fiber (0.6 dtex, average fiber length 5 mm, average fiber diameter 8 μm) , polyester fiber (2.2 dtex, average fiber length 5 mm, average fiber diameter 15 μm), PVA fiber (1.1 dtex, average fiber length 3 mm, average fiber diameter 10 μm), 45:7.6:16.2:16. Fibers were mixed at a weight ratio of 2:15, and polyacrylic ester was weighed so as to be 0.05% based on the weight of the fibers added, and dispersed in water with a pulper to prepare a stock solution for wet papermaking.
This wet papermaking stock solution is made into paper by a short-mesh papermaking method to form a wet web, which is then lightly squeezed with a press roller and dried with a rotary drying drum at 140° C. to obtain a basis weight of 30 g/m 2 and a thickness of 0.2 mm. A wet-laid nonwoven of Example 3 was obtained.

参考例2
ビニロン繊維(7dtex、平均繊維長10mm、平均繊維径25μm)、ビニロン繊維(2.2dtex、平均繊維長6mm、平均繊維径15μm)ポリエステル繊維(0.6dtex、平均繊維長5mm、平均繊維径8μm)、ポリエステル繊維(2.2dtex、平均繊維長5mm、平均繊維径15μm)、PVA繊維(1.1dtex、平均繊維長3mm、平均繊維径10μm)を、39:7.6:16.2:16.2:21の重量比で混繊し、パルパーで水中に分散させ、湿式抄紙用原液を調整した。
この抄紙用原液を短網式抄紙法にて抄紙して湿潤ウェッブをつくり、その後プレスローラーで軽く絞り140℃で回転乾燥ドラムにて乾燥し、目付30g/m2、厚み0.2mmの実施例4の湿式不織布を得た。
[ Reference example 2 ]
Vinylon fiber (7 dtex, average fiber length 10 mm, average fiber diameter 25 μm), vinylon fiber (2.2 dtex, average fiber length 6 mm, average fiber diameter 15 μm) polyester fiber (0.6 dtex, average fiber length 5 mm, average fiber diameter 8 μm) , polyester fiber (2.2 dtex, average fiber length 5 mm, average fiber diameter 15 μm), PVA fiber (1.1 dtex, average fiber length 3 mm, average fiber diameter 10 μm), 39:7.6:16.2:16. The fibers were mixed at a weight ratio of 2:21 and dispersed in water with a pulper to prepare a stock solution for wet papermaking.
This stock solution for papermaking is made into paper by a short-mesh papermaking method to form a wet web, which is then lightly squeezed with a press roller and dried with a rotary drying drum at 140° C. to achieve a basis weight of 30 g/m 2 and a thickness of 0.2 mm. of the wet-laid nonwoven fabric was obtained.

〔実施例5〕
ビニロン繊維(7dtex、平均繊維長10mm、平均繊維径25μm)、ビニロン繊維(2.2dtex、平均繊維長6mm、平均繊維径15μm)ポリエステル繊維(0.6dtex、平均繊維長5mm、平均繊維径8μm)、ポリエステル繊維(2.2dtex、平均繊維長5mm、平均繊維径15μm)、PVA繊維(1.1dtex、平均繊維長3mm、平均繊維径10μm)を、45:7.6:16.2:16.2:15の重量比で混繊し、更にポリアクリル酸エステルを投入した繊維重量に対して0.15%となるように測り、パルパーで水中に分散させ、湿式抄紙用原液を調整した。
この湿式抄紙用原液を短網式抄紙法にて抄紙して湿潤ウェッブをつくり、その後プレスローラーで軽く絞り140℃で回転乾燥ドラムにて乾燥し、目付30g/m、厚み0.2mmの実施例5の湿式不織布を得た。
[Example 5]
Vinylon fiber (7 dtex, average fiber length 10 mm, average fiber diameter 25 μm), vinylon fiber (2.2 dtex, average fiber length 6 mm, average fiber diameter 15 μm) polyester fiber (0.6 dtex, average fiber length 5 mm, average fiber diameter 8 μm) , polyester fiber (2.2 dtex, average fiber length 5 mm, average fiber diameter 15 μm), PVA fiber (1.1 dtex, average fiber length 3 mm, average fiber diameter 10 μm), 45:7.6:16.2:16. Fibers were mixed at a weight ratio of 2:15, and polyacrylic acid ester was weighed so as to be 0.15% with respect to the fiber weight added, and dispersed in water with a pulper to prepare a stock solution for wet papermaking.
This wet papermaking stock solution is made into paper by a short-mesh papermaking method to form a wet web, which is then lightly squeezed with a press roller and dried with a rotary drying drum at 140° C. to obtain a basis weight of 30 g/m 2 and a thickness of 0.2 mm. A wet-laid nonwoven of Example 5 was obtained.

〔比較例1〕
低融点ポリエステル繊維(22dtex、平均繊維長64mm、平均繊維径45μm)、低融点ポリエステル繊維(4.4dtex、平均繊維長51mm、平均繊維径20μm)、レギュラーポリエステル繊維(17dtex、平均繊維長51mm、平均繊維径40μm)を、重量比5:3:2で混繊し、サーマルボンド法により、厚み0.2mm、目付65g/m、の比較例1のサーマルボンド不織布を得た。
[Comparative Example 1]
Low melting point polyester fiber (22 dtex, average fiber length 64 mm, average fiber diameter 45 μm), low melting point polyester fiber (4.4 dtex, average fiber length 51 mm, average fiber diameter 20 μm), regular polyester fiber (17 dtex, average fiber length 51 mm, average A fiber diameter of 40 μm) was mixed at a weight ratio of 5:3:2, and a thermal bonded nonwoven fabric of Comparative Example 1 having a thickness of 0.2 mm and a basis weight of 65 g/m 2 was obtained by the thermal bonding method.

〔比較例2〕
ビニロン繊維(7dtex、平均繊維長10mm、平均繊維径25μm)、ビニロン繊維(2.2dtex、平均繊維長6mm、平均繊維径15μm)ポリエステル繊維(0.6dtex、平均繊維長5mm、平均繊維径8μm)、ポリエステル繊維(2.2dtex、平均繊維長5mm、平均繊維径15μm)、PVA繊維(1.1dtex、平均繊維長3mm、平均繊維径10μm)を、51:7.6:16.2:16.2:9の重量比で混繊し、パルパーで水中に分散させ、湿式抄紙用原液を調整した。
この湿式抄紙用原液を短網式抄紙法にて抄紙して湿潤ウェッブをつくり、その後プレスローラーで軽く絞り140℃で回転乾燥ドラムにて乾燥し、目付30g/m、厚み0.2mmの比較例2の湿式不織布を得た。
[Comparative Example 2]
Vinylon fiber (7 dtex, average fiber length 10 mm, average fiber diameter 25 μm), vinylon fiber (2.2 dtex, average fiber length 6 mm, average fiber diameter 15 μm) polyester fiber (0.6 dtex, average fiber length 5 mm, average fiber diameter 8 μm) , polyester fiber (2.2 dtex, average fiber length 5 mm, average fiber diameter 15 μm), PVA fiber (1.1 dtex, average fiber length 3 mm, average fiber diameter 10 μm), 51:7.6:16.2:16. The fibers were mixed at a weight ratio of 2:9 and dispersed in water using a pulper to prepare a stock solution for wet papermaking.
This wet papermaking undiluted solution is made into paper by a short - mesh papermaking method to form a wet web, which is then lightly squeezed with a press roller and dried with a rotary drying drum at 140°C. A wet-laid nonwoven of Example 2 was obtained.

〔比較例3〕
ビニロン繊維(7dtex、平均繊維長10mm、平均繊維径25μm)、ビニロン繊維(2.2dtex、平均繊維長6mm、平均繊維径15μm)ポリエステル繊維(0.6dtex、平均繊維長5mm、平均繊維径8μm)、ポリエステル繊維(2.2dtex、平均繊維長5mm、平均繊維径15μm)、PVA繊維(1.1dtex、平均繊維長3mm、平均繊維径10μm)を、45:7.6:16.2:16.2:15の重量比で混繊し、更にポリアクリル酸エステルを投入した繊維重量に対して0.0009%となるように測り、パルパーで水中に分散させ、湿式抄紙用原液を調整した。
この湿式抄紙用原液を短網式抄紙法にて抄紙して湿潤ウェッブをつくり、その後プレスローラーで軽く絞り140℃で回転乾燥ドラムにて乾燥し、目付30g/m、厚み0.2mmの比較例3の湿式不織布を得た。
[Comparative Example 3]
Vinylon fiber (7 dtex, average fiber length 10 mm, average fiber diameter 25 μm), vinylon fiber (2.2 dtex, average fiber length 6 mm, average fiber diameter 15 μm) polyester fiber (0.6 dtex, average fiber length 5 mm, average fiber diameter 8 μm) , polyester fiber (2.2 dtex, average fiber length 5 mm, average fiber diameter 15 μm), PVA fiber (1.1 dtex, average fiber length 3 mm, average fiber diameter 10 μm), 45:7.6:16.2:16. Fibers were mixed at a weight ratio of 2:15, and polyacrylic acid ester was added so that the weight of the fibers was 0.0009%.
This wet papermaking undiluted solution is made into paper by a short - mesh papermaking method to form a wet web, which is then lightly squeezed with a press roller and dried with a rotary drying drum at 140°C. A wet-laid nonwoven of Example 3 was obtained.

表1に実施例及び比較例の湿式不織布の評価を示す。 Table 1 shows the evaluation of the wet-laid nonwoven fabrics of Examples and Comparative Examples.

Figure 0007200494000001
Figure 0007200494000001

表1から、通気の上流に配置される面の表面粗さ(SMD)が2.7μm以下である湿式不織布を用いることで、異物の除去性能に優れることが分かる。つまり、本発明のフィルター用湿式不織布を用いたフィルターの清掃を容易にすることができる。 From Table 1, it can be seen that the use of a wet-laid nonwoven fabric having a surface roughness (SMD) of 2.7 μm or less on the surface located upstream of the airflow provides excellent foreign matter removal performance. In other words, it is possible to facilitate the cleaning of filters using the wet-laid nonwoven fabric for filters of the present invention.

なお、上記開示した実施の形態および各実施例はすべて例示であり制限的なものではない。また、実施の形態および各実施例で開示した構成を適宜組み合わせた実施の形態や実施例も本発明に含まれる。つまり、本発明の技術的範囲は、特許請求の範囲によって有効であり、特許請求の範囲の記載と均等の意味および範囲内のすべての変更・修正・置き換え等を含むものである。 It should be noted that the above-disclosed embodiments and examples are all examples and are not restrictive. The present invention also includes embodiments and examples in which the configurations disclosed in the embodiments and examples are appropriately combined. In other words, the technical scope of the present invention is valid according to the scope of the claims, and includes all changes, modifications, replacements, etc. within the meaning and scope of equivalents to the description of the scope of the claims.

本発明のフィルター用不織布は、フィルターを清掃する際の異物除去に対して優れており、空調用フィルター、エアコン用フィルター、自動車用フィルター等のフィルター全般に有効に利用できる。 The nonwoven fabric for filters of the present invention is excellent in removing foreign matter when cleaning filters, and can be effectively used for filters in general, such as filters for air conditioners, filters for air conditioners, and filters for automobiles.

Claims (5)

ビニロン、ポリエステル、及びポリビニルアルコールから成る繊維から構成された不織布であり、
通気の上流側に配置される面の表面粗さ(カトーテック製摩擦感テスター(KES-SE)による評価において、表面の凹凸データの平均偏差を示すSMD)が2.7μm以下であり、
前記繊維はポリアクリル酸エステルを0.001~0.1重量%含有しており、
前記繊維の平均繊維径1~100μmであり、
目付10~100g/m 、厚み0.1~3.0mmである、ことを特徴とするフィルター用湿式不織布。
A nonwoven fabric composed of fibers made of vinylon, polyester, and polyvinyl alcohol,
The surface roughness of the surface arranged on the upstream side of the ventilation (SMD indicating the average deviation of surface unevenness data in evaluation by Kato Tech's friction tester (KES-SE)) is 2.7 μm or less,
The fiber contains 0.001 to 0.1% by weight of polyacrylate ,
The average fiber diameter of the fibers is 1 to 100 μm,
A wet-laid nonwoven fabric for filters, characterized by having a basis weight of 10 to 100 g/m 2 and a thickness of 0.1 to 3.0 mm .
通気の上流側に配置される面の平均摩擦係数(MIU)が0.15以下であることを特
徴とする請求項1に記載のフィルター用湿式不織布。
2. The wet-laid nonwoven fabric for filters according to claim 1, wherein the average coefficient of friction (MIU) of the surface arranged on the upstream side of ventilation is 0.15 or less.
前記繊維は前記ポリビニルアルコールを10~20重量%含有していることを特徴とする請求項1または2に記載のフィルター用湿式不織布。 3. The wet-laid nonwoven fabric for filters according to claim 1 , wherein said fibers contain 10 to 20% by weight of said polyvinyl alcohol. 前記繊維は繊維長30mm以下であることを特徴とする請求項1~3のいずれか1項に記載のフィルター用湿式不織布。 The wet-laid nonwoven fabric for filters according to any one of claims 1 to 3 , wherein the fibers have a fiber length of 30 mm or less. 請求項1~のいずれか1項に記載のフィルター用湿式不織布を用いたフィルター。 A filter using the wet-laid nonwoven fabric for filters according to any one of claims 1 to 4 .
JP2018068385A 2018-03-30 2018-03-30 Wet-laid non-woven fabric for filters Active JP7200494B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2018068385A JP7200494B2 (en) 2018-03-30 2018-03-30 Wet-laid non-woven fabric for filters
PCT/JP2019/012395 WO2019188923A1 (en) 2018-03-30 2019-03-25 Wet non-woven fabric for filter, filter medium for filter, and filter
EP19777006.8A EP3777991A4 (en) 2018-03-30 2019-03-25 WET NON-WOVEN FOR FILTER, FILTER MEDIA FOR FILTER AND FILTER
US17/040,655 US20210016213A1 (en) 2018-03-30 2019-03-25 Wet non-woven fabric for filter, filter medium for filter, and filter
CN201980023208.6A CN111971105A (en) 2018-03-30 2019-03-25 Wet-type nonwoven fabric for filter, filter medium for filter, and filter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2018068385A JP7200494B2 (en) 2018-03-30 2018-03-30 Wet-laid non-woven fabric for filters

Publications (2)

Publication Number Publication Date
JP2019177349A JP2019177349A (en) 2019-10-17
JP7200494B2 true JP7200494B2 (en) 2023-01-10

Family

ID=68277336

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2018068385A Active JP7200494B2 (en) 2018-03-30 2018-03-30 Wet-laid non-woven fabric for filters

Country Status (1)

Country Link
JP (1) JP7200494B2 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009242973A (en) 2008-03-31 2009-10-22 Toray Ind Inc Textile using cellulose fiber
WO2009139194A1 (en) 2008-05-16 2009-11-19 ミドリホクヨー株式会社 Topcoat
JP2012218284A (en) 2011-04-08 2012-11-12 Toyobo Co Ltd Surface decorative film having tattile impression of plain wood

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3290755B2 (en) * 1993-06-01 2002-06-10 旭化成株式会社 Spacer sheet for beverage containers
JP3653863B2 (en) * 1995-06-07 2005-06-02 東レ株式会社 Non-woven fabric for liquid filter and liquid filtration apparatus using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009242973A (en) 2008-03-31 2009-10-22 Toray Ind Inc Textile using cellulose fiber
WO2009139194A1 (en) 2008-05-16 2009-11-19 ミドリホクヨー株式会社 Topcoat
JP2012218284A (en) 2011-04-08 2012-11-12 Toyobo Co Ltd Surface decorative film having tattile impression of plain wood

Also Published As

Publication number Publication date
JP2019177349A (en) 2019-10-17

Similar Documents

Publication Publication Date Title
EP2987544B1 (en) Filter material for air filter, method for manufacturing same, and air filter provided with same
JP6668203B2 (en) Manufacturing method of filter medium for air filter
JP6158061B2 (en) Air filter media
JP7200494B2 (en) Wet-laid non-woven fabric for filters
JP4110628B2 (en) Fabric and manufacturing method thereof
WO2019188923A1 (en) Wet non-woven fabric for filter, filter medium for filter, and filter
JP4556318B2 (en) Heat resistant fabric and filter comprising the same
JP7424298B2 (en) Filter media and filters
JP2023152337A (en) Filter medium for air filter and its manufacturing method
JPH08196829A (en) Air cleaning filter medium and method for producing the same
WO2021054465A1 (en) Non-woven fabric
JP3114079B2 (en) Filter material made of non-woven fabric for removing salt and air filter using the same
WO2024203820A1 (en) Laminated filter medium and air filter
JPH0456645B2 (en)
JP7281419B2 (en) Filter material for filter and manufacturing method thereof
JP6276044B2 (en) Gas turbine intake air filter
JP3991576B2 (en) FILTER ELEMENT, MANUFACTURING METHOD THEREOF, AND FILTER
JP7200495B2 (en) Filter media and filters
JP7117174B2 (en) glass filter
JP2004209470A (en) Air filter media, air filter and washing regeneration filter
JP4254893B2 (en) Fabric and manufacturing method thereof
JP4741748B2 (en) Disposable paper bag filter for vacuum cleaner and manufacturing method thereof
JP2521111B2 (en) Filter medium for air cleaner of internal combustion engine and manufacturing method thereof
JP2014054595A (en) Filter medium for air filter
JP6858678B2 (en) Filter media for air filters and their manufacturing methods

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20210215

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20211130

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20220127

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220325

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20220628

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220824

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20221122

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20221205

R151 Written notification of patent or utility model registration

Ref document number: 7200494

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250