JP7223479B2 - emulsion composition - Google Patents

Description

The present invention relates to emulsion compositions.

α-Gel is a hydrated crystal structure and has a lamellar structure. Most of the stratum corneum intercellular lipids present in the stratum corneum, the outermost layer of the skin, also have this α-gel structure. In addition, it has the function of suppressing the invasion of substances from the outside and the evaporation of water from the inside of the skin, and maintaining the skin's flexibility and smooth appearance by retaining moisture itself. . It is known that the stratum corneum retains about 33% by mass of water in the form of bound water in the skin, and the stratum corneum intercellular lipid retains about 13% by mass of bound water.
Since α-gel can retain moisture in this way, its application to cosmetics and the like has been investigated.
For example, Patent Document 1 describes that an emulsified composition containing ceramides, glycerin monofatty acid ester, higher alcohol, etc. forms an α-gel structure.

Japanese Unexamined Patent Application Publication No. 2007-22997

By the way, in makeup using foundation, blush, etc., there is a demand for good makeup application and makeup retention without unevenness, but unevenness occurs due to surface roughness of the skin that most people have. In addition, the make-up paste and make-up hold deteriorate.
The present inventors found that when the emulsified composition described in Patent Document 1 was applied continuously for a long period of time, no improvement in surface roughness of the skin was observed in a short period of continuous use. It was found that the make-up paste and make-up lasting were insufficient when makeup was applied with water, milky lotion and foundation. In addition, the emulsified composition described in Patent Document 1 also has a problem that when the emulsified composition is applied to the skin and then the foundation is overcoated on the coating film, the foundation tends to be uneven.

The present invention relates to an emulsified composition capable of improving makeup stickiness and makeup hold when applying make-up after cleansing the site of frequent use even if the composition is used continuously for a short period of time.

The present inventors added one or more compounds selected from sphingosine, sphingosine salts, pseudosphingosine, pseudosphingosine salts and cationic surfactants, ceramides, glycerin fatty acid esters, and higher alcohols. In addition, an emulsified composition in which cationic polymers having a main chain having a glass transition temperature Tg of 25°C or less are combined in a specific mass ratio unexpectedly cleanses the site of continuous use even for short-term continuous use. The present inventors have found that it is possible to improve the make-up paste and make-up durability when applying make-up using the powder, and completed the present invention.

The present invention contains the following components (A), (B), (C), (D) and (E), and the component ( Provided is an emulsified composition in which the content mass ratio of E) [(E)/{(A)+(B)+(C)+(D)}] is 0.01 or more and 1 or less.
(A) one or more compounds selected from sphingosine, sphingosine salts, pseudosphingosine, pseudosphingosine salts and cationic surfactants (B) ceramides (C) glycerol fatty acid esters (D) higher alcohols (E) ) A cationic polymer whose main chain has a glass transition temperature Tg of 25° C. or lower

According to the emulsified composition of the present invention, even if it is used continuously for a short period of time, it is possible to improve the make-up stickiness and make-up hold when applying make-up after cleansing the area of continuous use. Further, the emulsified composition of the present invention is less likely to cause unevenness in the foundation when the emulsified composition is applied to the skin and then the foundation is overcoated on the coating film.

<Component (A)>
Among the compounds of component (A) used in the present invention, sphingosines and pseudosphingosines include sphingosines represented by the following general formula (1).

[In formula (1),
R ¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 4 to 30 carbon atoms which may be substituted with a hydroxyl group, a carbonyl group or an amino group;
Y represents a methylene group, a methine group or an oxygen atom;
X ¹ , X ² and X ³ each independently represent a hydrogen atom, a hydroxyl group or an acetoxy group;
X ⁴ represents a hydrogen atom, an acetyl group or a glyceryl group, or forms an oxo group together with an adjacent oxygen atom (provided that when Y is a methine group, either X ¹ or X ² is is a hydrogen atom and the other is absent.When X ⁴ forms an oxo group, X ³ is absent.);
R ² and R ³ each independently represent a hydrogen atom, a hydroxyl group, a hydroxymethyl group or an acetoxymethyl group;
a R's are each independently a hydrogen atom or an amidino group, or a total carbon number of 1 to 8 optionally having a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group represents a linear or branched, saturated or unsaturated hydrocarbon group;
a represents a number of 2 or 3;
A dashed line portion indicates that it may be an unsaturated bond. ]

In formula (1), R ¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 4 to 30 carbon atoms which may be substituted with a hydroxyl group, a carbonyl group or an amino group. However, a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 7 to 22 carbon atoms which may be substituted with a hydroxyl group is preferred.
Among these, a linear or branched alkyl group having 10 to 20 carbon atoms and a linear or branched alkyl group having 10 to 20 carbon atoms having a hydroxyl group at the Y-side terminal are preferable. In that case, the branched chain is preferably methyl-branched. Preferred specific examples include tridecyl, tetradecyl, pentadecyl, hexadecyl, 1-hydroxytridecyl, 1-hydroxypentadecyl, isohexadecyl and isostearyl groups.

Y represents either a methylene group ( _CH2 ), a methine group (CH) or an oxygen atom.
X ¹ , X ² and X ³ each independently represent a hydrogen atom, a hydroxyl group or an acetoxy group, and X ⁴ represents a hydrogen atom, an acetyl group, a glyceryl group or together with an adjacent oxygen atom an oxo The substituents that form the group are shown.
A preferred combination of X ¹ , X ² and X ³ is a combination in which 0 to 1 of X ¹ , X ² and X ³ are hydroxyl groups and the rest are hydrogen atoms. X ⁴ is preferably a hydrogen atom.
When Y is a methine group, only one of X ¹ and X ² is a hydrogen atom and the other does not exist. Also, when X ⁴ forms an oxo group, X ³ is absent.

R ² and R ³ each independently represent a hydrogen atom, a hydroxyl group, a hydroxymethyl group or an acetoxymethyl group. Among R ³ , a hydrogen atom is particularly preferred.

Further, a represents a number of 2 or 3, and when a is 2, R represents ^R4 and ^R5 , and when a is 3, R represents ^R4 , ^R5 and ^R6 .

R ⁴ , R ⁵ and R ⁶ are each independently a hydrogen atom or an amidino group, or the total number of carbon atoms optionally having a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group. 1 to 8 linear or branched saturated or unsaturated hydrocarbon groups. As the hydroxyalkoxy group that can be substituted on the hydrocarbon group, a straight or branched hydroxyalkoxy group having 1 to 7 carbon atoms is preferable. As the alkoxy group, a linear or branched alkoxy group having 1 to 7 carbon atoms is preferable.
R ⁴ , R ⁵ and R ⁶ include, for example, a hydrogen atom; an amidino group; a straight or branched chain alkyl group such as a methyl group, ethyl group, propyl group, 2-ethylhexyl group and isopropyl group; alkenyl group such as allyl group; hydroxymethyl group, 2-hydroxyethyl group, 1,1-dimethyl-2-hydroxyethyl group, 2-hydroxypropyl group, 2,3-dihydroxypropyl group, 2-hydroxy-3-methoxy propyl group, 2,3,4,5,6-pentahydroxyhexyl group, 1,1-bis(hydroxymethyl)ethyl group, 2-(2-hydroxyethoxy)ethyl group, 2-methoxyethyl group, 1- selected from hydroxyl group, hydroxyalkoxy group and alkoxy group such as methyl-2-hydroxyethyl group, 3-hydroxypropyl group, 3-methoxypropyl group, 1,1-bis(hydroxymethyl)-2-hydroxyethyl group; A hydrocarbon group having a total of 1 to 8 carbon atoms substituted with 1 to 6 groups can be mentioned.

Among these, R ⁴ , R ⁵ and R ⁶ are hydrogen atoms, methyl groups, 2-hydroxyethyl groups, 1,1-dimethyl-2-hydroxyethyl groups, 1,1-bis(hydroxymethyl)ethyl groups. Alkyl groups optionally substituted by 1 to 3 groups selected from hydroxyl groups and hydroxyalkoxy groups, such as groups, 2-(2-hydroxyethoxy)ethyl groups, etc., are preferred.

The sphingosines represented by the general formula (1) include naturally occurring sphingosines represented by the following general formula (2), synthetic products having the same structure, and derivatives thereof (hereinafter also referred to as natural sphingosines), or Pseudo-type sphingosines represented by the following general formula (3) (hereinafter also referred to as pseudo-type sphingosines) are preferred.

[In formula (2),
R ⁷ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms which may be substituted with a hydroxyl group;
Y ₁ represents a methylene group or a methine group;
^X5 , ^X6 and ^X7 each independently represents a hydrogen atom, a hydroxyl group or an acetoxy group;
X ⁸ represents a hydrogen atom or forms an oxo group together with an adjacent oxygen atom (provided that when Y ₁ is a methine group, either X ⁵ or X ⁶ represents a hydrogen atom, the other is absent.When X ⁸ forms an oxo group, X ⁷ is absent.);
R ⁸ represents a hydroxymethyl group or an acetoxymethyl group;
a R ₁ are each independently a hydrogen atom or an amidino group, or have a total carbon number of 1 to 4 and may have a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group; represents a linear or branched, saturated or unsaturated hydrocarbon group of;
a represents a number of 2 or 3;
A dashed line indicates that an unsaturated bond may be present. ]

[In formula (3),
R ⁹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 10 to 22 carbon atoms which may be substituted with a hydroxyl group;
X ⁹ represents a hydrogen atom, an acetyl group or a glyceryl group;
each of a R ₂ is independently a hydrogen atom or an amidino group, or has a total carbon number of 1 to 8 and may have a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group; represents a linear or branched, saturated or unsaturated hydrocarbon group of;
a represents the number of 2 or 3; ]

Here, the natural sphingosine represented by the general formula (2) will be described.
In formula (2), R ⁷ is preferably a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and a linear saturated or unsaturated hydrocarbon group having 13 to 15 carbon atoms. A hydrocarbon group is more preferred. Further, a in formula (2) is preferably 2, and each R ₁ in formula (2) is preferably independently a hydrogen atom or a linear or branched alkyl group having 1 to 4 carbon atoms. .

Specific examples of natural sphingosine represented by general formula (2) include sphingosine (natural sphingosine), dihydrosphingosine, phytosphingosine, sphingadienine, dehydrosphingosine, dehydrophytosphingosine, and their N-alkyl isomers (eg, N-methyl isomers) and the like.
These sphingosines can be used as natural (D(+) form) optically active forms, as non-natural (L(-) form) optically active forms, or as mixtures of natural and non-natural forms. may be used. The relative configuration of the above compounds may be a natural configuration, a non-natural configuration, or a mixture thereof.
Among such natural sphingosines, those selected from the compound group (α) represented by the following formula are preferable, and PHYTOSPHINGOSINE (INCI name; 8th Edition) is more preferable.

These may be either natural extracts or synthetic products, and commercially available products can be used.
Commercially available natural sphingosines include, for example, D-Sphingosine (4-Sphingenine) (manufactured by SIGMA-ALDRICH), DS-phytosphingosine (manufactured by DOOSAN), and phytosphingosine (manufactured by Cosmo Pharm).

Next, pseudo-type sphingosines represented by general formula (3) will be described.
In formula (3), R ⁹ is preferably an iso-branched alkyl group having 14 to 20 carbon atoms, particularly preferably an isostearyl group. The isostearyl group is most preferably an isostearyl group obtained by using isostearyl alcohol, which is a by-product of dimer acid production using fatty acids derived from animal and vegetable oils, as a raw material oil.
In formula (3), R ₂ represents R ^a10 and R ^a11 when a is 2, and R ₂ represents R ^a10 , R ^a11 and R ^a12 when a is 3.

R ^a10 , R ^a11 and R ^a12 include, for example, hydrogen atom; amidino group; linear or branched alkyl group such as methyl group, ethyl group, propyl group, 2-ethylhexyl group and isopropyl group; vinyl group , alkenyl groups such as allyl group; hydroxymethyl group, 2-hydroxyethyl group, 1,1-dimethyl-2-hydroxyethyl group, 2-hydroxypropyl group, 2,3-dihydroxypropyl group, 2-hydroxy-3- methoxypropyl group, 2,3,4,5,6-pentahydroxyhexyl group, 1,1-bis(hydroxymethyl)ethyl group, 2-(2-hydroxyethoxy)ethyl group, 2-methoxyethyl group, 1 - selected from a hydroxyl group, a hydroxyalkoxy group and an alkoxy group such as a methyl-2-hydroxyethyl group, a 3-hydroxypropyl group, a 3-methoxypropyl group, a 1,1-bis(hydroxymethyl)-2-hydroxyethyl group; and an alkyl group having a total carbon number of 1 to 8 having a substituent group. The number of substituents is preferably 1-6, more preferably 1-3.
As a combination of R ^a10 and R ^a11 , one of R ^a10 and R ^a11 is a hydrogen atom, and the other is a 2-hydroxyethyl group, a 1,1-dimethyl-2-hydroxyethyl group, a 1,1- Combinations (secondary amines) of bis(hydroxymethyl)ethyl groups or 2-(2-hydroxyethoxy)ethyl groups are preferred.

As the pseudo-sphingosine, R ⁹ in formula (3) is an isostearyl group, X ⁹ is a hydrogen atom, R ^a10 is a hydrogen atom, R ^a11 is a 2-hydroxyethyl group, 1,1 -Dimethyl-2-hydroxyethyl group, 1,1-bis(hydroxymethyl)ethyl group, or 2-(2-hydroxyethoxy)ethyl group, such as hydroxyl group and hydroxyalkoxy group 1 to 3 substituted is preferably an alkyl group.
Preferable specific examples of pseudo-type sphingosines include the following pseudo-type sphingosines (i) to (iv). Among these, pseudotype sphingosine (ii) is preferred, and 1-(2-hydroxyethylamino)-3-isostearyloxy-2-propanol is more preferred.
Pseudotype sphingosine may be a commercial product or one obtained by synthesis according to a conventional method.

Salts of these sphingosines and pseudosphingosines include acidic amino acid salts such as glutamic acid and aspartic acid; basic amino acid salts such as arginine; inorganic acid salts such as phosphoric acid and hydrochloric acid; monocarboxylic acid salts such as acetic acid; and oxycarboxylic acid salts such as citric acid, lactic acid and malic acid.
Among these, the sphingosine salt and the pseudosphingosine salt are preferably succinate, lactate, arginine salt, and glutamate, and more preferably glutamate.
Among the sphingosines, sphingosine salts, pseudo-sphingosines, and pseudo-sphingosine salts described above, one of them may be used alone, or two or more thereof may be used in combination. Among sphingosine, salts of sphingosine, pseudo-sphingosine, and salts of pseudo-sphingosine, pseudo-sphingosine and salts of pseudo-sphingosine are preferable from the viewpoint of storage stability and the like.

Among the compounds of component (A), cationic surfactants include, for example, quaternary ammonium salt-type cationic surfactants and amine salt-type cationic surfactants. Surfactants are preferred. Examples of amine salt-type cationic surfactants include alkylamine salts.
Among such cationic surfactants, quaternary ammonium salt-type cationic surfactants represented by the following general formula (7) are preferred.

[In formula (7),
R ³¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 6 or more carbon atoms,
R ³² represents an alkyl group having 1 to 4 carbon atoms,
R ³³ and R ³⁴ each independently represents an alkyl group having 1 to 4 carbon atoms, or a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 6 or more carbon atoms,
AN ⁻ denotes a salt-forming anion. ]

In formula (7), the number of carbon atoms in the "linear, branched or cyclic saturated or unsaturated hydrocarbon group" represented by R ³¹ , R ³³ and R ³⁴ is preferably 6 to 30, more preferably 8. to 24, more preferably 12-22, particularly preferably 16-20.
Examples of the hydrocarbon groups include alkyl groups, alkenyl groups, and aralkyl groups. Among these, an alkyl group and an alkenyl group are preferable, and an alkyl group is more preferable.
The number of carbon atoms in the alkyl group is preferably 6-30, more preferably 8-24, still more preferably 12-22, and particularly preferably 16-20, as described above. In addition, the above alkyl group may be linear or branched. For example, octyl group, nonyl group, decyl group, undecyl group, 1-methyldecyl group, dodecyl group, 1-methylundecyl group, 1-ethyldecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, octadecyl group, behenyl and the like.
The alkenyl group may be linear or branched. Examples thereof include decenyl group, undecenyl group, dodecenyl group, tetradecenyl group, hexadecenyl group and the like.
A benzyl group, a phenethyl group, etc. are mentioned as said aralkyl group.

The number of carbon atoms in the "alkyl group having 1 to 4 carbon atoms" represented by R ³² , R ³³ and R ³⁴ is preferably 1 or 2, particularly preferably 1. Also, this alkyl group may be linear or branched. Examples include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group and the like.

The combination of R ³³ and R ³⁴ includes a combination in which both R ³³ and R ³⁴ are alkyl groups having 1 to 4 carbon atoms, one of R ³³ and R ³⁴ is an alkyl group having 1 to 4 carbon atoms, a combination in which the remainder is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 6 or more carbon atoms, and both R ³³ and R ³⁴ are linear, branched or cyclic saturated or Combinations of unsaturated hydrocarbon groups are included. Among these combinations, R ³³ and R ³⁴ are both C 1-4 alkyl groups, one of R ³³ and R ³⁴ is a C 1-4 alkyl group, and the remainder are C 1-4 alkyl groups. A combination of 6 or more linear, branched or cyclic saturated or unsaturated hydrocarbon groups is preferred, one of R ³³ and R ³⁴ is an alkyl group having 1 to 4 carbon atoms, and the remainder is 6 carbon atoms. Combinations of the above linear, branched or cyclic saturated or unsaturated hydrocarbon groups are more preferred.

Moreover, in formula (7), AN ⁻ represents a salt-forming anion. For example, halide ions (eg chloride ions, iodide ions), sulfate ions, phosphate ions, acetate ions, lactate ions, p-toluenesulfonate ions, perchlorate ions, monoalkyl nitrate ions (eg methyl sulfate ions) , ethyl sulfate ion) and the like, and halide ions are preferred.

Examples of cationic surfactants include octyltrimethylammonium chloride, decyltrimethylammonium chloride, lauryltrimethylammonium chloride, tetradecyltrimethylammonium chloride, hexadecyltrimethylammonium chloride, hexadecyltrimethylammonium bromide, stearyltrimethylammonium chloride, and behenyl chloride. Alkyltrimethylammonium salts such as trimethylammonium; dialkyldimethylammonium salts such as didecyldimethylammonium chloride and distearyldimethylammonium chloride; and trialkylmethylammonium salts. Among these cationic surfactants, one type may be used alone, or two or more types may be used in combination.
As the cationic surfactant, a commercially available product or a product obtained by synthesis according to a conventional method may be used.

The compound of component (A) may be used alone or in combination of two or more. It is preferable to use at least two kinds from the viewpoints of storage stability, lack of unevenness when the foundation is overcoated on the coating film, and the like. Among them, it is more preferable to use at least one or more selected from phytosphingosine, salts of phytosphingosine, pseudosphingosine (ii), and salts of pseudosphingosine (ii), and phytosphingosine and salts of phytosphingosine. , 1-(2-hydroxyethylamino)-3-isostearyloxy-2-propanol, and 1-(2-hydroxyethylamino)-3-isostearyloxy-2-propanol. It is particularly preferred to use at least one or more seeds.
When using at least one or more selected from sphingosine, sphingosine salts, pseudosphingosine, and pseudosphingosine salts, a cationic surfactant may be further contained.

The content of component (A) improves the storage stability, safety, the lack of unevenness when the foundation is overcoated on the paint film, and the skin with good makeup glue and makeup retention when makeup is applied. from the viewpoint of the emulsified composition of the present invention, preferably 0.001% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, particularly preferably 0.2% by mass or more is. In addition, from the viewpoint of storage stability, safety, lack of unevenness when foundation is overcoated on the coating film, and improvement of the skin with good makeup glue and makeup retention when makeup is applied, the use of the present invention. It is preferably 5% by mass or less, more preferably 1.5% by mass or less, still more preferably 1% by mass or less, and particularly preferably 0.5% by mass or less in the emulsified composition. A specific range is preferably 0.001% by mass or more and 5% by mass or less, more preferably 0.05% by mass or more and 1.5% by mass or less, and 0.1% by mass or more in the emulsion composition of the present invention. 1% by mass or less is more preferable, and 0.2% by mass or more and 0.5% by mass or less is particularly preferable.
In the present specification, the content of sphingosine, sphingosine salt, pseudo-sphingosine, and pseudo-sphingosine salt in the emulsified composition among component (A) indicates the mass in terms of acid. The same applies to the content mass ratio of component (A) and other components hereinafter.

In addition, the content mass ratio of component (A) to the cationic polymer of component (E) [(A)/(E)] is not only the absence of unevenness when the foundation is overcoated on the coating film, but also the effect of makeup. It is preferably 0.005 or more, more preferably 0.01 or more, still more preferably 0.05 or more, and particularly preferably 0.1 or more, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when applied. . In addition, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film, it is preferably 2 or less, more preferably 1. It is 5 or less, more preferably 1 or less, and particularly preferably 0.5 or less. A specific range is preferably 0.005 or more and 2 or less, more preferably 0.01 or more and 1.5 or less, still more preferably 0.05 or more and 1 or less, and particularly preferably 0.1 or more and 0.5 or less.

<Component (B)>
The emulsion composition of the present invention contains (B) ceramides.
Examples of ceramides include those represented by general formula (4).

[In formula (4),
R ¹¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 4 to 30 carbon atoms which may be substituted with a hydroxyl group, a carbonyl group or an amino group, or a hydrogen atom;
Z represents a methylene group, a methine group or an oxygen atom;
X ¹¹ , X ¹² and X ¹³ each independently represent a hydrogen atom, a hydroxyl group or an acetoxy group;
X ¹⁴ represents a hydrogen atom, an acetyl group or a glyceryl group, or forms an oxo group together with an adjacent oxygen atom (provided that when Z is a methine group, either X ¹¹ or X ¹² is a hydrogen atom and the other is absent.When X ¹⁴ forms an oxo group, X ¹³ is absent.);
R ¹² and R ¹³ each independently represent a hydrogen atom, a hydroxyl group, a hydroxyalkyl group (e.g., hydroxymethyl group, hydroxyethyl group, etc.) or an acetoxymethyl group;
R ¹⁴ may be substituted with a hydroxyl group, a carbonyl group or an amino group, and may be a linear or branched chain having 5 to 60 carbon atoms which may have an ether bond, an ester bond or an amide bond in the main chain. indicating a chain or cyclic saturated or unsaturated hydrocarbon group;
R ¹⁵ represents a hydrogen atom or a linear or branched saturated or saturated or represents an unsaturated hydrocarbon group (when R ¹¹ is a hydrogen atom and Z is an oxygen atom, R ¹⁵ has a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group; Also, when R ¹¹ is a hydrocarbon group, R ¹⁵ represents a hydrogen atom or a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group. A hydrocarbon group having a total of 1 to 8 carbon atoms, which may have selected substituents, is preferred);
A dashed line portion indicates that it may be an unsaturated bond. ]

In formula (4), represented by R ¹¹ "a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 4 to 30 carbon atoms which may be substituted with a hydroxyl group, a carbonyl group or an amino group. ” is preferably a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 7 to 22 carbon atoms which may be substituted with a hydroxyl group.
Z represents a methylene group, a methine group or an oxygen atom.

X ¹¹ , X ¹² and X ¹³ each independently represent a hydrogen atom, a hydroxyl group or an acetoxy group. The combination of X ¹¹ , X ¹² and X ¹³ is preferably a combination in which 0 to 1 of X ¹¹ , X ¹² and X ¹³ are hydroxyl groups and the rest are hydrogen atoms. When Z is a methine group, only one of X ¹¹ and X ¹² is a hydrogen atom and the other does not exist.
Moreover, X ¹⁴ is preferably a hydrogen atom or a glyceryl group.
R ¹² and R ¹³ each independently represent a hydrogen atom, a hydroxyl group, a hydroxyalkyl group (e.g., hydroxymethyl group, hydroxyethyl group, etc.) or an acetoxymethyl group, preferably R ¹² is a hydrogen atom or a hydroxymethyl group. and preferably R ¹³ is a hydrogen atom.

R ¹⁴ may be substituted with a hydroxyl group, a carbonyl group or an amino group, and may be a linear or branched chain having 5 to 60 carbon atoms which may have an ether bond, an ester bond or an amide bond in the main chain. Indicates a chain or cyclic saturated or unsaturated hydrocarbon group. R ¹⁴ is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 5 to 35 carbon atoms which may be substituted with a hydroxyl group or an amino group, or at the ω position of the hydrocarbon group, Examples include those in which linear, branched or cyclic saturated or unsaturated fatty acids having 8 to 22 carbon atoms which may be substituted with hydroxyl groups are linked by ester bonds or amide bonds. Isostearic acid, 12-hydroxystearic acid or linoleic acid is preferred as the fatty acid to be bound.

R ¹⁵ represents a hydrogen atom or a saturated or unsaturated linear or branched chain having 1 to 30 carbon atoms in total which may have a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group. Indicates a saturated hydrocarbon group.
When R ¹¹ is a hydrogen atom and Z is an oxygen atom, R ¹⁵ is a hydrocarbon having a total of 10 to 30 carbon atoms which may have a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group. groups are preferred. Further, when R ¹¹ is a hydrocarbon group, R ¹⁵ represents a hydrogen atom or may have a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group. A hydrocarbon group of 8 is preferable, and a hydrocarbon group having a total of 1 to 8 carbon atoms which represents a hydrogen atom or may be substituted by 1 to 3 groups selected from a hydroxyl group, a hydroxyalkoxy group and an alkoxy group is more preferable. . Here, the hydroxyalkoxy group and alkoxy group preferably have 1 to 7 carbon atoms.

Examples of ceramides include naturally occurring ceramides represented by the following general formula (5), synthetic products having the same structure, and derivatives thereof (hereinafter also referred to as natural ceramides), or those represented by the following general formula (6). Pseudo-ceramides (hereinafter also referred to as pseudo-ceramides) are preferred. Among natural ceramides and pseudo-ceramides, pseudo-ceramides are preferred from the viewpoint of productivity and the like.

[In formula (5),
R ²¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms which may be substituted with a hydroxyl group;
Z ₁ represents a methylene group or a methine group;
X ¹⁵ , X ¹⁶ and X ¹⁷ each independently represent a hydrogen atom, a hydroxyl group or an acetoxy group;
X ¹⁸ represents a hydrogen atom or forms an oxo group together with an adjacent oxygen atom (provided that when Z ₁ is a methine group, either one of X ¹⁵ and X ¹⁶ is a hydrogen atom and the other is absent.When X ¹⁸ forms an oxo group, X ¹⁷ is absent.);
R ²² represents a hydroxyalkyl group (e.g., hydroxymethyl group, hydroxyethyl group, etc.) or an acetoxymethyl group;
R ²³ represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms;
R ²⁴ is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 5 to 30 carbon atoms (the hydrocarbon group is preferably an alkyl group) optionally substituted by a hydroxyl group; or an ester of a linear or branched, saturated or unsaturated fatty acid having 8 to 22 carbon atoms which may be substituted with a hydroxyl group at the ω end of the hydrocarbon group (the hydrocarbon group is preferably an alkyl group); indicate the bound;
A dashed line portion indicates that it may be an unsaturated bond. ]

[In formula (6),
R ²⁵ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 10 to 22 carbon atoms which may be substituted with a hydroxyl group, or a hydrogen atom;
X ¹⁹ represents a hydrogen atom, an acetyl group or a glyceryl group;
R ²⁶ is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 5 to 22 carbon atoms which may be substituted with a hydroxyl group or an amino group (the hydrocarbon group is preferably an alkyl group); or a linear or branched saturated or unsaturated fatty acid having 8 to 22 carbon atoms which may be substituted with a hydroxyl group at the ω end of the hydrocarbon group (the hydrocarbon group is preferably an alkyl group) is ester-bonded;
R ²⁷ represents a hydrogen atom or a hydrocarbon group having a total of 1 to 30 carbon atoms (the hydrocarbon group is preferably an alkyl group) which may be substituted with a hydroxyl group, a hydroxyalkoxy group, an alkoxy group or an acetoxy group; show. ]

Here, the natural ceramide represented by the general formula (5) will be explained.
In formula (5), the hydrocarbon group represented by R ²¹ has 7 to 19 carbon atoms, preferably 11 to 15 carbon atoms, more preferably 13 to 15 carbon atoms. A straight-chain alkyl group is preferable as the hydrocarbon group represented by R ²¹ .
X ¹⁸ represents a hydrogen atom or forms an oxo group together with an adjacent oxygen atom.
R ²⁴ is preferably a linear alkyl group having 9 to 27 carbon atoms which may be substituted with a hydroxyl group, or a group in which linoleic acid is ester-bonded to the ω-end of the alkyl group. R ²⁴ is more preferably a tricosyl group, a 1-hydroxypentadecyl group, a 1-hydroxytricosyl group, a heptadecyl group, a 1-hydroxyundecyl group, a nonacosyl group in which linoleic acid is ester-bonded to the ω-position, or a pentacosyl group.

Specific examples of natural ceramides include ceramide Types 1 to 7 in which sphingosine, dihydrosphingosine, phytosphingosine or sphingadienin is amidated (for example, J. Lipid Res., 24:759 (1983), Fig. 2, and J. Lipid. Res., 35:2069 (1994), porcine and human ceramides described in Fig. 4).
Further, N-alkyl derivatives (eg, N-methyl derivatives) of these are also included in natural ceramides.
These ceramides may be in the form of natural (D(−) form) optically active forms, non-natural (L(+) form) optically active forms, or mixtures of natural and non-natural forms. may be used. The relative configuration of the above compounds may be a natural configuration, a non-natural configuration, or a mixture thereof.
Among natural ceramides, CERAMIDE1, CERAMIDE2, CERAMIDE3, CERAMIDE5 and CERAMIDE6II compounds (INCI, 8th Edition) and those represented by the following formulas are particularly preferred.

These may be either natural extracts or synthetic products, and commercially available products can be used.
Commercially available natural ceramides include, for example, Ceramide I, Ceramide II, Ceramide III, Ceramide IIIA, Ceramide IIIB, Ceramide IIIC, Ceramide VI (manufactured by Cosmo Farm), Ceramide TIC-001 (Takasago perfume company), CERAMIDE II (manufactured by Quest International), DS-Ceramide VI, DS-CLA-Phytoceramide, C6-Phytoceramide, DS-ceramide Y3S (manufactured by DOOSAN), and CERAMIDE2 (manufactured by Sederma).

Next, pseudo-ceramides represented by general formula (6) will be described.
In formula (6), R ²⁶ includes a heptyl group, a 1-hydroxyheptyl group, a nonyl group, a tridecyl group, a pentadecyl group, an undecyl group in which linoleic acid is ester-bonded at the ω-position, and an ester of linoleic acid at the ω-position. A bonded pentadecyl group, a pentadecyl group in which 12-hydroxystearic acid is ester-bonded at the ω-position, and an undecyl group in which methyl-branched isostearic acid is amide-bonded at the ω-position are preferred.
When R ²⁵ is a hydrogen atom, R ²⁷ is a hydrocarbon group having a total of 1 to 30 carbon atoms which may be substituted with a hydroxyl group, a hydroxyalkoxy group, an alkoxy group or an acetoxy group (the hydrocarbon group is preferably an alkyl group), more preferably a hydrocarbon group having a total of 10 to 30 carbon atoms (the hydrocarbon group is preferably an alkyl group) optionally substituted by a hydroxyl group, a hydroxyalkoxy group, an alkoxy group or an acetoxy group. Preferred are alkyl groups having a total of 12 to 20 carbon atoms.
When R ²⁵ is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 10 to 22 carbon atoms which may be substituted with a hydroxyl group, R ²⁷ is a hydrogen atom. Alternatively, an alkyl group having a total of 1 to 8 carbon atoms which may be substituted with a hydroxyl group, a hydroxyalkoxy group, an alkoxy group or an acetoxy group is preferred.
As the hydroxyalkoxy group or alkoxy group for R ²⁷ , those having 1 to 7 carbon atoms are preferred.

Among pseudo-ceramides, R ²⁵ in general formula (6) is a hexadecyl group, X ¹⁹ is a hydrogen atom, R ²⁶ is a pentadecyl group, and R ²⁷ is a hydroxyethyl group; ²⁵ is a hexadecyl group, X ¹⁹ is a hydrogen atom, R ²⁶ is a nonyl group, and R ²⁷ is a hydroxyethyl group; R ²⁵ in the general formula (6) is a hexadecyl group, X ¹⁹ is a glyceryl group, and R ²⁶ is a tridecyl group , R ²⁷ is a 3-methoxypropyl group; R ²⁵ is a hydrogen atom, X ¹⁹ is a hydrogen atom, R ²⁶ is a pentadecyl group, and R ²⁷ is a dodecyl group; General formula (6) Preferably, R ²⁵ is a hydrogen atom, X ¹⁹ is a hydrogen atom, R ²⁶ is a 1-hydroxyheptyl group, and R ²⁷ is a dodecyl group.
R ²⁵ in the general formula (6) is a hexadecyl group, X ^{19 is} a hydrogen atom, R ²⁶ is a pentadecyl group, and R ²⁷ is a hydroxyethyl group ^; A hydrogen atom, R ²⁶ is a nonyl group, and R ²⁷ is a hydroxyethyl group; R ²⁵ in the general formula (6) is a hexadecyl group, X ¹⁹ is a glyceryl group, R ²⁶ is a tridecyl group, and R ²⁷ is 3-methoxypropyl is more preferred,
In the general formula (6), R ²⁵ is a hexadecyl group, X ¹⁹ is a hydrogen atom, R ²⁶ is a pentadecyl group, and R ²⁷ is a hydroxyethyl group (N-(hexadecyloxyhydroxypropyl)-N-hydroxyethylhexadeca Namid) is particularly preferred.

The ceramides of component (B) may be used alone or in combination of two or more.

The content of component (B) improves the storage stability, safety, the absence of unevenness when the foundation is overcoated on the paint film, and the skin with good makeup glue and makeup retention when makeup is applied. from the viewpoint of the emulsified composition of the present invention, preferably 0.001% by mass or more, more preferably 0.05% by mass or more, still more preferably 1% by mass or more, particularly preferably 1.5% by mass or more . In addition, from the viewpoint of storage stability, safety, lack of unevenness when foundation is overcoated on the coating film, and improvement of the skin with good makeup glue and makeup retention when makeup is applied, the use of the present invention. It is preferably 10% by mass or less, more preferably 7% by mass or less, even more preferably 5% by mass or less, and particularly preferably 4% by mass or less in the emulsified composition. A specific range is preferably 0.001% by mass or more and 10% by mass or less, more preferably 0.05% by mass or more and 7% by mass or less, and 1% by mass or more and 5% by mass or less in the emulsion composition of the present invention. is more preferable, and 1.5% by mass or more and 4% by mass or less is particularly preferable.

In addition, the content mass ratio of component (B) to the cationic polymer of component (E) [(B)/(E)] is important for storage stability, safety, and lack of unevenness when the foundation is overcoated on the coating film. In addition, it is preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.5 or more, and particularly preferably from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied. is greater than or equal to 0.75. In addition, from the viewpoint of storage stability, safety, lack of unevenness when foundation is overcoated on the coating film, and improvement of skin with good makeup glue and makeup hold when makeup is applied, 15 is preferable. , more preferably 10 or less, still more preferably 7.5 or less, and particularly preferably 5 or less. A specific range is preferably 0.05 or more and 15 or less, more preferably 0.1 or more and 10 or less, still more preferably 0.5 or more and 7.5 or less, and particularly preferably 0.75 or more and 5 or less.

<Component (C)>
The emulsified composition of the present invention contains (C) a glycerin fatty acid ester.
As the glycerin fatty acid ester, glycerin monofatty acid ester is preferable from the viewpoint of emulsion stability. The glycerin monofatty acid ester preferably has a fatty acid residue of 10 to 24 carbon atoms, more preferably a fatty acid residue of 16 to 24 carbon atoms, and a fatty acid residue of 18 to 24 carbon atoms. is particularly preferred. In addition, the "fatty acid" constituting the glycerin monofatty acid ester may be saturated fatty acid or unsaturated fatty acid, and may be linear fatty acid or branched fatty acid. As the glycerin monofatty acid ester, those having a saturated fatty acid residue are preferred, and those having a linear saturated fatty acid residue are more preferred.
Examples of glycerin monofatty acid esters include glycerin monolaurate, glycerin monomyristate, glycerin monopalmitate, glycerin monostearate, glycerin monobehenate, glycerin monooleate, glycerin monoisostearate, Glycerin monolinoleic acid ester and the like can be mentioned. Among these, glycerin monostearate and glycerin monobehenate are preferred.
In addition, the glycerin fatty acid ester of the component (C) may be used alone or in combination of two or more.

The content of component (C) improves the storage stability, safety, the absence of unevenness when the foundation is overcoated on the paint film, and the skin with good makeup glue and makeup retention when makeup is applied. from the viewpoint of the emulsified composition of the present invention, preferably 0.001% by mass or more, more preferably 0.05% by mass or more, even more preferably 0.1% by mass or more, particularly preferably 0.5% by mass or more is. In addition, from the viewpoint of storage stability, safety, lack of unevenness when foundation is overcoated on the coating film, and improvement of the skin with good makeup glue and makeup retention when makeup is applied, the use of the present invention. It is preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 5% by mass or less, and particularly preferably 3% by mass or less in the emulsified composition. A specific range is preferably 0.001% by mass or more and 10% by mass or less, more preferably 0.05% by mass or more and 7% by mass or less, and 0.1% by mass or more and 5% by mass in the emulsion composition of the present invention. % or less is more preferable, and 0.5% by mass or more and 3% by mass or less is particularly preferable.

In addition, the content mass ratio of component (C) to the cationic polymer of component (E) [(C)/(E)] is not only the absence of unevenness when the foundation is overcoated on the coating film, but also the effect of makeup. It is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.1 or more, and particularly preferably 0.3 or more, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when applied. . In addition, it is preferably 10 or less, more preferably 5 or less, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film. , more preferably 3 or less, particularly preferably 1 or less. A specific range is preferably 0.01 to 10, more preferably 0.05 to 5, even more preferably 0.1 to 3, and particularly preferably 0.3 to 1.

<Component (D)>
The emulsion composition of the present invention contains (D) a higher alcohol.
As the higher alcohol, a monohydric alcohol having 10 to 24 carbon atoms is preferable, a monohydric alcohol having 12 to 22 carbon atoms is more preferable, and a monohydric alcohol having 14 to 22 carbon atoms is particularly preferable. Higher alcohols may be linear or branched, and may be saturated or unsaturated alcohols, but linear saturated or unsaturated alcohols are preferred.
Examples of higher alcohols include lauryl alcohol, myristyl alcohol, cetanol, stearyl alcohol, behenyl alcohol, and oleyl alcohol. Among these, cetanol, stearyl alcohol and behenyl alcohol are preferred, and cetanol and behenyl alcohol are more preferred.
The higher alcohol of component (D) may be used alone or in combination of two or more.

The content of component (D) improves the storage stability, safety, the absence of unevenness when the foundation is overcoated on the paint film, and the skin with good makeup glue and makeup retention when makeup is applied. from the viewpoint of the emulsified composition of the present invention, preferably 0.001% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, particularly preferably 0.6% by mass or more is. In addition, from the viewpoint of storage stability, safety, lack of unevenness when foundation is overcoated on the coating film, and improvement of the skin with good makeup glue and makeup retention when makeup is applied, the use of the present invention. It is preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 5% by mass or less, and particularly preferably 3% by mass or less in the emulsified composition. A specific range is preferably 0.001% by mass or more and 10% by mass or less, more preferably 0.05% by mass or more and 7% by mass or less, and 0.1% by mass or more and 5% by mass in the emulsion composition of the present invention. % or less is more preferable, and 0.6 mass % or more and 3 mass % or less is particularly preferable.

In addition, the content mass ratio of component (D) to the cationic polymer of component (E) [(D)/(E)] is not only the absence of unevenness when the foundation is overcoated on the coating film, but also the effect of makeup. It is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.1 or more, and particularly preferably 0.3 or more, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when applied. . In addition, it is preferably 10 or less, more preferably 5 or less, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film. , more preferably 3 or less, particularly preferably 1 or less. A specific range is preferably 0.01 to 10, more preferably 0.05 to 5, even more preferably 0.1 to 3, and particularly preferably 0.3 to 1.

In addition, the content mass ratio of component (B) to the total of components (B), (C) and (D) [(B) / {(B) + (C) + (D)}] is the α-type structure It is preferably 0.1 or more, more preferably 0.2 or more, from the viewpoint of forming a gel and having excellent storage stability. From the viewpoint of obtaining a gel having an α-type structure and excellent storage stability, it is preferably 1 or less, more preferably 0.75 or less, and particularly preferably 0.6 or less. A specific range is preferably 0.1 or more and 1 or less, more preferably 0.1 or more and 0.75 or less, and particularly preferably 0.2 or more and 0.6 or less.

In addition, the content mass ratio of component (C) to the total of components (C) and (D) [(C) / {(C) + (D)}] is an α-structured gel with excellent storage stability. From the viewpoint of optimizing, it is preferably 0.1 or more, more preferably 0.25 or more. From the viewpoint of obtaining a gel having an α-type structure and excellent storage stability, it is preferably 1 or less, more preferably 0.75 or less, and particularly preferably 0.65 or less. A specific range is preferably 0.1 or more and 1 or less, more preferably 0.1 or more and 0.75 or less, and particularly preferably 0.25 or more and 0.65 or less.

<Component (E)>
The emulsion composition of the present invention contains (E) a cationic polymer whose main chain has a glass transition temperature Tg of 25° C. or lower.

The cationic polymer of component (E) has a main chain glass transition temperature Tg of 25° C. or lower.
The glass transition temperature Tg of the main chain is preferably 15 from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film. °C or lower, more preferably 0°C or lower, still more preferably -25°C or lower, still more preferably -50°C or lower, and particularly preferably -100°C or lower. Although the lower limit of the glass transition temperature Tg of the main chain is not particularly limited, it is -150°C, for example.
In this specification, the glass transition temperature Tg of the main chain is measured by differential scanning calorimetry (DSC) or the like. The glass transition temperature Tg of the raw material polymer of the cationic polymer of component (E) is measured by DSC, or the glass transition temperature Tg of the polymer from which the cationic polymer of component (E) is removed by a chemical reaction other than the main chain portion. can be obtained by measuring with DSC or the like. However, when the cationic polymer of component (E) is a terminal-modified polymer such as terminal-modified silicone, the segment introduced at the end is the "main chain" in measuring the glass transition temperature Tg of the main chain. shall not be included. For example, the "glass transition temperature Tg of the main chain" of a terminal-type amino-modified silicone means the glass transition temperature Tg of the silicone chain (organopolysiloxane segment) of this polymer.

In addition, as the cationic polymer of component (E), in addition to the absence of unevenness when the foundation is overcoated on the coating film, when makeup is applied, it improves the skin with good makeup glue and makeup retention. , and a polymer having a light transmittance of 90% or more when 25 parts by weight of 100 parts by weight of cetanol are mixed at 85°C.
The above-mentioned light transmittance is more preferably 92.0 from the viewpoint of the lack of unevenness when the foundation is overcoated on the coating film, and the improvement of the skin with good makeup application and makeup retention when makeup is applied. It is 5% or more, more preferably 95% or more, still more preferably 96% or more, and particularly preferably 98% or more. Also, the above light transmittance is usually less than 100%.
In the present specification, the above-mentioned light transmittance refers to the light transmittance measured by mixing 25 parts by mass of polymer with 100 parts by mass of cetanol at 85° C. and measuring this mixture using the following apparatus and conditions. .

(Measurement device and measurement conditions for light transmittance)
Apparatus: Spectrophotometer Wavelength: 555 nm
Optical path length: 1 cm

Moreover, the cationic polymer may have a cationic group, and may have a cationic group in its main chain or a cationic group in its side chain. Among these, those having a cationic group on the side chain are preferred.
Here, in the present specification, the cationic group is a concept that includes not only groups having cations such as quaternary ammonium groups, but also groups that can become cations when protons are present in the system. Examples include primary to tertiary amino groups, quaternary ammonium groups, biguanide residues and the like. Among these, primary to tertiary amino groups are used from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film. , quaternary ammonium groups are preferred, primary to tertiary amino groups are more preferred, and secondary amino groups are particularly preferred.

The charge density of the cationic polymer of component (E) is selected from the viewpoint of improving the smoothness of the coating film when the foundation is overcoated, and improving the skin with good makeup adhesion and makeup retention when makeup is applied. , preferably 0.01 meq/g or more, more preferably 0.03 meq/g or more, still more preferably 0.05 meq/g or more, still more preferably 0.08 meq/g or more, still more preferably 0.1 meq/g or more, More preferably 0.15 meq/g or more, particularly preferably 0.2 meq/g or more. In addition, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film, it is preferably 10.0 meq / g or less, more. It is preferably 9.0 meq/g or less, more preferably 8.0 meq/g or less, particularly preferably 2.0 meq/g or less. A specific range is preferably 0.01 meq/g or more and 10.0 meq/g or less, more preferably 0.1 meq/g or more and 9.0 meq/g or less, and 0.15 meq/g or more and 8.0 meq/g or less. is more preferable, and 0.2 meq/g or more and 2.0 meq/g or less is particularly preferable.
In this specification, the charge density of a cationic polymer refers to the amount of charge distribution per unit weight, which can be measured with a zeta potential measuring device or the like.

In addition, as the cationic polymer of component (E), in addition to the absence of unevenness when the foundation is overcoated on the coating film, when makeup is applied, it improves the skin with good makeup glue and makeup retention. , an organopolysiloxane segment, a polyoxyalkylene segment, and a segment containing repeating structural units derived from an unsaturated monomer. is more preferable. When the cationic polymer of component (E) contains an organopolysiloxane segment in the main chain (in the case of a silicone polymer), the "main chain" in the "glass transition temperature Tg of the main chain" is the organopolysiloxane segment. be. Examples of the unsaturated monomers include (meth)acrylic acid, (meth)acrylate-based monomers, (meth)acrylamide-based monomers, and styrene-based monomers. Among these unsaturated monomers, (meth)acrylic acid; (meth)acrylate monomers such as methyl (meth)acrylate, ethyl (meth)acrylate, stearyl (meth)acrylate, and cyclohexyl (meth)acrylate are preferred.
Among such polymer species, the cationic polymer of component (E) is not only smooth when the foundation is overcoated on the coating film, but also has good makeup glue and makeup longevity when makeup is applied. From the viewpoint of improving the skin, a polymer having an organopolysiloxane segment as a main chain and a cationic group as a side chain is preferred.
The component (E) cationic polymer may further have a poly(N-acylalkyleneimine) segment, etc., in addition to the above-mentioned segments contained in the main chain. Among such polymers, graft polymers having an organopolysiloxane segment as a main chain and poly(N-acylalkyleneimine) segments and cationic groups as side chains are preferred.

Specific examples of the cationic polymer of component (E) include poly(N-acylalkyleneimine)-modified silicones (eg, oxazoline-modified silicones), amino-modified silicones, and the like. In addition, among these, only one type may be used alone, or two or more types may be used in combination.
Among these, poly (N-acyl alkyleneimine ) modified silicones are preferred.

(Poly(N-acylalkyleneimine) modified silicone)
As the poly(N-acylalkyleneimine)-modified silicone, at least two of the silicon atoms of the organopolysiloxane segment constituting the main chain are attached via a cationic divalent linking group to the following general formula (11): Organopolysiloxane formed by bonding poly (N-acylalkyleneimine) segments consisting of repeating units represented, wherein the poly(N-acylalkyleneimine) segment has a number average molecular weight of 500 to 4000, and the main chain The weight-average molecular weight of the organopolysiloxane segment constituting the is 10,000 to 200,000 (hereinafter, this organopolysiloxane is also referred to as organopolysiloxane (OX)).

[In the formula (11), R ⁴¹ represents a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group or an aryl group, and t represents 2 or 3; ]

Organopolysiloxane (OX) will now be described in detail.
At least two poly(N-acylalkyleneimine) segments are bonded to arbitrary silicon atoms constituting the organopolysiloxane segment via cationic divalent linking groups, but both ends of the organopolysiloxane segment It is preferably bonded to one or more silicon atoms excluding a cationic divalent linking group, and is bonded to two or more silicon atoms excluding both terminals via a cationic divalent linking group. is more preferred.

A cationic divalent linking group functions as a linking group for poly(N-acylalkyleneimine) segments.
The cationic divalent linking group includes an alkylene group containing a cationic group, preferably an alkylene group having 2 to 20 carbon atoms containing 1 to 3 cationic groups, a primary amino group, a secondary An alkylene group having 2 to 20 carbon atoms and containing 1 to 3 cationic groups of one or more selected from an amino group, a tertiary amino group and a quaternary ammonium group is more preferred.
Among such cationic divalent linking groups, in addition to the lack of unevenness when the foundation is overcoated on the coating film, from the viewpoint of improving the skin with good makeup glue and makeup retention when makeup is applied. , A group represented by any one of the following formulas (A1) to (A6) is preferable, a group represented by formula (A1) or (A2) is more preferable, and a group represented by formula (A1) is particularly preferable. .
In the formula, An ⁻ represents a counterion of the quaternary ammonium salt. For example, halide ions (eg chloride ions, iodide ions), sulfate ions, phosphate ions, acetate ions, lactate ions, p-toluenesulfonate ions, perchlorate ions, monoalkyl nitrate ions (eg methyl sulfate ions) , ethyl sulfate ion) and the like.

In the N-acylalkyleneimine unit constituting the poly(N-acylalkyleneimine) segment, the alkyl group represented by R ⁴¹ in general formula (11) has 1 to 22 carbon atoms, preferably 1 to 14 carbon atoms. , more preferably 1 to 6, particularly preferably 1 to 3. In addition, the above alkyl group may be linear or branched. Examples include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, tert-butyl group, pentyl group, hexyl group and the like.
The aralkyl group represented by R ⁴¹ is preferably an aralkyl group having 7 to 15 carbon atoms. Examples thereof include benzyl group, phenethyl group, trityl group, naphthylmethyl group, anthracenylmethyl group and the like.
The aryl group represented by R ⁴¹ is preferably an aryl group having 6 to 14 carbon atoms. Examples thereof include phenyl group, tolyl group, xylyl group, naphthyl group, biphenyl group, anthracenyl group, phenanthryl group and the like.
Among these, R ⁴¹ is preferably a hydrogen atom or a linear or branched alkyl group having 1 to 3 carbon atoms, more preferably a linear or branched alkyl group having 1 to 3 carbon atoms. .
Although t in Formula (11) shows 2 or 3, 2 is preferable.

The mass ratio (a/b) between the organopolysiloxane segment (a) and the poly(N-acylalkyleneimine) segment (b) constituting the main chain is In addition to smoothness, it is preferably 45/55 to 82/18, more preferably 60/40 to 80/20, and 65/35 from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied. 80/20 is more preferred, 68/32 to 80/20 is more preferred, and 70/30 to 79/21 is particularly preferred.
In this specification, the mass ratio (a/b) is determined by dissolving 5% by mass of organopolysiloxane (OX) in deuterated chloroform and analyzing the organopolysiloxane segment by nuclear magnetic resonance ( ¹ H-NMR) analysis. A value obtained from the integral ratio of the alkyl group or phenyl group of and the methylene group in the poly(N-acylalkyleneimine) segment.

In the organopolysiloxane (OX), the weight average molecular weight (hereinafter also referred to as "MWg") of the organopolysiloxane segment between adjacent poly(N-acylalkyleneimine) segments is the unevenness when the foundation is overcoated on the coating film. It is preferably from 1,000 to 40,000, more preferably from 1,500 to 30,000, and particularly preferably from 1,750 to 5,000, from the viewpoint of smoothness of makeup and improvement of skin with good makeup application and long-lasting makeup.

As used herein, the term "organopolysiloxane segment between adjacent poly(N-acylalkyleneimine) segments" means an organopolysiloxane segment of a poly(N-acylalkyleneimine) segment, as shown in formula (12) below. A portion surrounded by a dashed line between two points from the bonding point (bonding point A) to the segment to the bonding point (bonding point B) of the adjacent poly(N-acylalkyleneimine) segment, A segment composed of R ⁴² SiO units, one R ⁴³ and y+1 (R ⁴² ) ₂ SiO units. Further, the “poly(N-acylalkyleneimine) segment” refers to —Z ¹¹ —R ⁴⁴ linked to R ⁴³ above.

[In formula (12), R ⁴² each independently represents an alkyl group having 1 to 22 carbon atoms or a phenyl group, R ⁴³ represents a cationic divalent linking group, -Z ¹¹ -R ⁴⁴ represents poly(N -acylalkyleneimine) segment, R ⁴⁴ represents a residue of a polymerization initiator or a hydrogen atom, and y represents a positive number. Plural R ⁴² , R ⁴³ and R ⁴⁴ may be the same or different. ]

MWg is the molecular weight of the portion enclosed by the dashed line in the above formula (12), but it can be interpreted as the mass (g/mol) of the organopolysiloxane segment per 1 mol of the poly(N-acylalkyleneimine) segment. can. When 100% of the functional groups of the modified organopolysiloxane of the raw material compound are replaced with poly(N-acylalkyleneimine), the functional group equivalent (g/mol) of the modified organopolysiloxane is obtained.

Further, the molecular weight of the poly(N-acylalkyleneimine) segment can be calculated from the molecular weight and polymerization degree of the N-acylalkyleneimine unit, or can be measured by a gel permeation chromatography (GPC) method. In the specification, the polystyrene equivalent number average molecular weight (hereinafter also referred to as MNox) measured by GPC under the measurement conditions described below is used. MNox is preferably 800 to 3500, more preferably 800 to 3500, from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film. 1000-3000.

Also, MWg can be determined by the following formula (I) using the content (% by mass) of the organopolysiloxane segment that constitutes the main chain (hereinafter also referred to as Csi).

MWg = Csi x MNox/(100-Csi) (I)

The weight-average molecular weight (hereinafter also referred to as MWsi) of the organopolysiloxane segment that constitutes the main chain is not only good for evenness when foundation is applied to the coating film, but also good for makeup glue and makeup hold when makeup is applied. is preferably 15,000 to 160,000, more preferably 20,000 to 150,000, and particularly preferably 25,000 to 100,000, from the viewpoint of improving to good skin.
Since the organopolysiloxane segment constituting the main chain has a common skeleton with the modified organopolysiloxane of the raw material compound, MWsi is substantially the same as the weight average molecular weight of the modified organopolysiloxane of the raw material compound. The weight average molecular weight of the modified organopolysiloxane of the raw material compound is the polystyrene-equivalent weight average molecular weight measured by GPC under the following measurement conditions.

(Conditions for measuring weight average molecular weight of modified organopolysiloxane)
Column: Super HZ4000 + Super HZ2000 (manufactured by Tosoh Corporation)
Eluent: 1 mM triethylamine/THF
Flow rate: 0.35 mL/min
Column temperature: 40℃
Detector: UV
Sample: 50 μL

The weight-average molecular weight (hereinafter also referred to as MWt) of the organopolysiloxane (OX) is not only good for the lack of unevenness when the foundation is overcoated on the coating film, but also for good makeup glue and makeup longevity when makeup is applied. From the viewpoint of improving the skin, it is preferably 12,000 to 200,000, more preferably 25,000 to 160,000, and particularly preferably 35,000 to 150,000. MWt is a polystyrene-equivalent value measured by GPC under the measurement conditions described below.

(Measurement conditions for MNox and MWt)
Column: Two K-804L (manufactured by Tosoh Corporation) connected in series Eluent: 1 mM dimethyldodecylamine/chloroform Flow rate: 1.0 mL/min
Column temperature: 40℃
Detector: RI
Sample: 50 μL

When the poly(N-acylalkyleneimine) segment is a poly(N-propionylethyleneimine) segment, ^{the 1} H-NMR measurement for calculating the mass ratio (a/b) should be performed under the following conditions, for example. can be done.
( ¹ H-NMR measurement conditions)
0.5 g of a polymer sample is dissolved in 2 g of a measuring solvent (heavy chloroform), and measured by ¹ H-NMR (400 MHz, manufactured by Varian). Then, the ratio of silicone to poly(N-propionylethyleneimine) is calculated from each integrated value.
PULSE SEQUENCE
・Relax.delay: 30 seconds ・Pulse: 45 degrees ・Number of times of accumulation: 8 Confirmation peak Around 0 ppm: Methyl group of polydimethylsiloxane,
Around 3.4 ppm: Methylene portion of ethyleneimine.

Organopolysiloxane (OX) may be synthesized according to the methods described in JP-A-2008-143820, JP-A-2009-24114, JP-A-2015-67603, and the like. For example, obtained by ring-opening polymerization of organopolysiloxane modified with a functional group that induces a cationic divalent linking group and a cyclic imino ether corresponding to the repeating unit represented by the general formula (11) It can be produced by reacting with a terminally reactive poly(N-acylalkyleneimine).

Specifically, the organopolysiloxane (OX) used in the present invention is prepared according to the description of Example 8 of JP-A-2009-24114 (main chain Tg: -121 ° C., 100 parts by mass of cetanol On the other hand, when 25 parts by mass are mixed at 85 ° C., the light transmittance: 98%, the charge density: 0.3 meq / g) and JP 2008-143820 prepared according to the description of Synthesis Example 2 ( Main chain Tg: -121°C, light transmittance when 25 parts by weight of cetanol is mixed at 85°C with 100 parts by weight of cetanol: 98%, charge density: 0.1 meq/g), and the like.

(amino-modified silicone)
Examples of the amino-modified silicone include those represented by the following general formula (13).

[In formula (13),
R ⁵¹ to R ⁵³ each independently represent a hydrogen atom, a hydroxyl group, or a monovalent organic group having 1 to 20 carbon atoms,
R ⁵⁴ represents a group represented by the following general formula (14),
R ⁵⁵ to R ⁵⁶ each independently represents a hydroxyl group, an alkoxy group having 1 to 20 carbon atoms, a monovalent organic group having 1 to 20 carbon atoms, or a group represented by the following general formula (14); ,
R ⁵⁷ to R ⁶⁰ are each independently a hydrogen atom, a hydroxyl group, an alkoxy group having 1 to 20 carbon atoms, a monovalent organic group having 1 to 20 carbon atoms, or represented by the following general formula (14) indicate the group,
d represents a number of 10 ≤ d ≤ 10000,
e indicates a number of 0.1≦e≦1000. ]

[In formula (14),
R ⁶¹ to R ⁶² each independently represent an alkanediyl group having 1 to 8 carbon atoms,
R ⁶³ to R ⁶⁵ each independently represents a hydrogen atom or a monovalent organic group having 1 to 10 carbon atoms,
f represents a number of 0 ≤ f ≤ 6,
* indicates a bond. ]

In formula (13), the monovalent organic groups having 1 to 20 carbon atoms represented by R ⁵¹ to R ⁵³ , R ⁵⁵ to R ⁵⁶ and R ⁵⁷ to R ⁶⁰ include, for example, methyl group, ethyl group and propyl group. , butyl group, pentyl group, hexyl group, heptyl group, octyl group, decyl group, dodecyl group, tetradecyl group, hexadecyl group, octadecyl group, eicosyl group, and other linear or branched alkyl groups; cyclopentyl group, cyclohexyl group, etc. Alkenyl groups such as vinyl group and allyl group; Aryl groups such as phenyl group and tolyl group; 3,3,3-trifluoropropyl group, 2-(perfluorobutyl)ethyl group, 2-(per and halogenoalkyl groups such as fluorohexyl)ethyl group and 2-(perfluorooctyl)ethyl group.

R ⁵¹ to R ⁵³ are preferably monovalent organic groups having 1 to 20 carbon atoms. Further, it is preferable that 90 mol % or more of all R ⁵¹ to R ⁵³ contained in formula (13) are methyl groups.

The alkoxy groups represented by R ⁵⁵ to R ⁵⁶ and R ⁵⁷ to R ⁶⁰ have 1 to 20 carbon atoms, preferably 1 to 12 carbon atoms, more preferably 1 to 6 carbon atoms. Also, the alkoxy group may be linear or branched. Examples include methoxy group, ethoxy group, propoxy group, butoxy group, pentyloxy group, hexyloxy group and the like.
R ⁵⁵ to R ⁵⁶ and R ⁵⁷ to R ⁶⁰ are preferably a hydroxyl group, an alkoxy group having 1 to 20 carbon atoms or a monovalent organic group having 1 to 20 carbon atoms, more preferably a hydroxyl group, a methoxy group or a methyl group. preferable.

Further, d is a number of 10≤d≤10000, preferably 100≤d≤2000.
Also, e is a number of 0.1≦e≦1000, but preferably 1≦e≦100.
The sum of d and e is preferably 10 or more and less than 1000 in number average, more preferably 30 or more and less than 1000 in number average, and particularly preferably 40 or more and less than 800 in number average.

In formula (14), R ⁶¹ to R ⁶² each independently represent an alkanediyl group having 1 to 8 carbon atoms.
The alkanediyl group represented by R ⁶¹ preferably has 1 to 6 carbon atoms. On the other hand, the alkanediyl group represented by R ⁶² preferably has 1 to 4 carbon atoms.
The alkanediyl groups represented by R ⁶¹ to R ⁶² may be linear or branched. As the alkanediyl group, methane-1,1-diyl group, ethane-1,1-diyl group, ethane-1,2-diyl group, propane-1,1-diyl group, propane-1,2-diyl group , propane-1,3-diyl group, propane-2,2-diyl group, butane-1,4-diyl group, pentane-1,5-diyl group, hexane-1,6-diyl group and the like. Among these, R ⁶¹ is preferably a propane-1,3-diyl group (trimethylene group), and R ⁶² is preferably an ethane-1,2-diyl group (dimethylene group).

R ⁶³ to R ⁶⁵ each independently represent a hydrogen atom or a monovalent organic group having 1 to 10 carbon atoms. Examples of organic groups represented by R ⁶³ to R ⁶⁵ include linear or branched alkyl groups such as methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group and decyl group. groups; cycloalkyl groups such as cyclopentyl group and cyclohexyl group; alkenyl groups such as vinyl group and allyl group; aryl groups such as phenyl group and tolyl group; alkanoyl groups such as acetyl group and propionyl group; A group in which some or all of the atoms are substituted with a substituent selected from a halogen atom, a hydroxyl group, an alkoxy group and a hydroxyalkoxy group, such as a 3,3,3-trifluoropropyl group and 2-(perfluorobutyl) Halogenoalkyl groups such as ethyl group, 2-(perfluorohexyl)ethyl group, 2-(perfluorooctyl)ethyl group; acid anhydrides, epoxy compounds, monovalent organic groups obtained by reaction with acrylic compounds (e.g. -COCH ₃ , -CH ₂ CH(OH)CH ₂ OH, -CH ₂ CH(OH)CH ₂ OCH ₂ CH ₂ OH) and the like.
R ⁶³ to R ⁶⁵ are particularly preferably hydrogen atoms, but when at least one of R ⁶³ to R ⁶⁵ is a hydrogen atom, some or all of the remaining groups are the above acid anhydrides, epoxy compounds, acrylic It may be a group such as a monovalent organic group obtained by reaction with a compound.
Also, f indicates a number of 0≦f≦6, preferably a number of 0≦f≦3.

Specific examples of such R ⁵⁴ include the following.

The amino equivalent of the amino-modified silicone is preferably 200 g/mol to 30,000 g/mol, more preferably 400 g/mol to 10,000 g/mol, and particularly preferably 600 g/mol to 5000 g/mol.
Preferred amino-modified silicones are amodimethicone, aminoethylaminopropyl dimethicone, and aminopropyl dimethicone.

The amino-modified silicone may be a commercially available product or one obtained by synthesis according to a conventional method. Commercial products of amino-modified silicone include amino-modified silicone oils such as SF8451C, SF8452C, SF8457C (manufactured by Toray Dow Corning Silicone Co., Ltd.), KF8003, KF867 (manufactured by GE Toshiba Silicone Co., Ltd.), and SM8704C (Toray · amodimethicone emulsions such as Dow Corning Silicone Co., Ltd.). Also, the amino-modified silicone oil may be blended in the form of an emulsion. The emulsion of amino-modified silicone can be prepared by mechanical emulsification (high-shear mechanical mixing of amino-modified silicone and water), chemical emulsification (emulsifying amino-modified silicone with water and an emulsifier), or a combination thereof, or by emulsion polymerization. can also be prepared by

The component (E) cationic polymer may be used alone or in combination of two or more.

The content of the component (E) is the amount of the present invention from the viewpoint of improving the skin with good makeup glue and makeup retention when makeup is applied, as well as the lack of unevenness when the foundation is overcoated on the coating film. It is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, and particularly preferably 1% by mass or more in the emulsified composition. In addition, in the emulsion composition of the present invention, preferably It is 15% by mass or less, more preferably 10% by mass or less, still more preferably 7.5% by mass or less, and particularly preferably 5% by mass or less. As a specific range, in the emulsion composition of the present invention, 0.01% by mass or more and 15% by mass or less is preferable, 0.05% by mass or more and 10% by mass or less is more preferable, and 0.1% by mass or more and 7.0% by mass or less. 5 mass % or less is more preferable, and 1 mass % or more and 5 mass % or less is particularly preferable.

The emulsified composition of the present invention has a content mass ratio of component (E) to the total of components (A), (B), (C) and (D) [(E) / {(A) + (B) + ( C)+(D)}] is 0.01 or more and 1 or less.
In addition, the content mass ratio [(E) / {(A) + (B) + (C) + (D)}] is not only the lack of unevenness when the foundation is overcoated on the coating film, but also the makeup. It is preferably 0.03 or more, more preferably 0.05 or more, still more preferably 0.1 or more, and particularly preferably 0.2 or more, from the viewpoint of improving the skin with good makeup paste and makeup hold when applied. . In addition, it is preferably 0.95 or less, more preferably 0.95 or less, more preferably from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, in addition to the lack of unevenness when the foundation is overcoated on the coating film. It is 0.9 or less, more preferably 0.85 or less, and particularly preferably 0.8 or less. A specific range is preferably 0.03 or more and 0.95 or less, more preferably 0.05 or more and 0.9 or less, still more preferably 0.1 or more and 0.85 or less, and 0.2 or more and 0.8 or less. is particularly preferred.

<Component (F)>
The emulsified composition of the present invention preferably contains (F) water in addition to components (A) to (E), from the viewpoint of storage stability, feeling in use, skin improvement effect, and the like.
The content of water in the emulsified composition of the present invention is preferably 30% by mass or more, more preferably 50% by mass or more, and particularly preferably 60% by mass or more, from the viewpoint of skin improvement effect and the like. From the viewpoint of feeling during use, etc., it is preferably 99.99% by mass or less, more preferably 97.5% by mass or less, and particularly preferably 95% by mass or less in the emulsified composition of the present invention. A specific range is preferably 30% by mass or more and 99.99% by mass or less, more preferably 50% by mass or more and 97.5% by mass or less, and 60% by mass or more and 95% by mass or less in the emulsion composition of the present invention. is particularly preferred.

<Component (G)>
The emulsified composition of the present invention further contains (G) a polyhydric alcohol in addition to the components (A) to (E) from the viewpoint of storage stability, feeling in use, spreadability on the skin, etc. preferable. In addition, (F) water and (G) polyhydric alcohol may be contained in combination.
Polyhydric alcohols include, for example, glycols, glycerins, polyoxyalkylenemethylglucoses, as well as sorbitol, maltitol, sorbitan, glucose, fructose, sucrose and maltose.

Examples of glycols include alkylene glycols such as ethylene glycol, propylene glycol and 1,3-butylene glycol; and polyalkylene glycols such as diethylene glycol, dipropylene glycol and polyethylene glycol. Examples of glycerins include glycerin, diglycerin, polyglycerin and the like. Polyoxyalkylene methyl glucoses include, for example, polyoxyethylene methyl glucose, polyoxypropylene methyl glucose and the like.
Among these, glycerins are preferred, and glycerin is particularly preferred.
In addition, a polyhydric alcohol may be used individually by 1 type, or may be used in combination of 2 or more types.

The content of the polyhydric alcohol in the emulsified composition of the present invention is preferably 0% by mass or more, more preferably 0.001% by mass or more, and particularly preferably 5% by mass or more. In addition, it is preferably 60% by mass or less, more preferably 30% by mass or less, and particularly preferably 20% by mass or less in the emulsified composition of the present invention.

The emulsified composition of the present invention may also contain other aqueous bases (for example, lower alcohols having 1 to 4 carbon atoms such as ethanol and propanol).

Moreover, the emulsified composition of the present invention may further contain an oily component other than the above.
Examples of such oily components include hydrocarbon oils such as liquid paraffin, squalane, petrolatum; ether oils such as cetyldimethylbutyl ether, ethylene glycol dioctyl ether, and glycerol monooleyl ether; octyldodecyl myristate, isopropyl palmitate, and stearin. Ester oils such as butyl acid, di-2-ethylhexyl adipate, neopentyl glycol dicaprate, trioctanoin; vegetable oils such as olive oil; dimethylpolysiloxane, cyclic dimethylpolysiloxane, methylphenylpolysiloxane, carboxy-modified silicone, alcohol-modified silicone oils such as silicone, alkyl-modified silicone, polyether-modified silicone, and fluorine-modified silicone; fluorine-based oils such as perfluoroalkylethyl phosphate, perfluoroalkylpolyoxyethylene phosphate, perfluoropolyether, and polytetrafluoroethylene; sterols such as cholesterol and phytosterol; The oily component may be used alone or in combination of two or more.
The content of these oily components is preferably 0% by mass or more and 20% by mass or less in the emulsified composition of the present invention.

In addition, the emulsified composition of the present invention may contain other active ingredients, additives, and the like that are commonly used in cosmetics.
Examples of such active ingredients and additives include water-soluble vitamins such as ascorbic acid, nicotinamide, and nicotinic acid; Animal and plant extracts such as carrot extract, hamamelis extract, placenta extract, seaweed extract, horse chestnut extract, yuzu extract, asunaro extract, royal jelly extract, eucalyptus extract, asunaro extract; potassium hydroxide, sodium hydroxide, triethanolamine, Bases such as sodium carbonate and arginine; acids such as citric acid, tartaric acid, lactic acid, phosphoric acid, succinic acid, adipic acid, and glutamic acid; carboxyvinyl polymer, sodium alginate, carrageenan, carboxymethylcellulose, hydroxyethylcellulose, guar gum, xanthan gum, carboxymethyl Thickeners such as chitosan, sodium hyaluronate, N,N-dimethylaminoethyl methacrylate diethyl sulfate/N,N-dimethylacrylamide/polyethylene glycol dimethacrylate copolymer, and the like are included. These may be used alone or in combination of two or more.

The emulsified composition of the present invention can be produced by a conventional method. For example, an oil phase component containing components (A) to (D) and an aqueous phase component containing water (when component (G) is used, an aqueous phase component containing water and component (G)) It can be produced by a production method that includes an emulsifying step and uses one or both of the oil phase component and the aqueous phase component used in the emulsifying step that further contains the component (E).
From the viewpoint of storage stability and the like, the method for producing the emulsified composition is emulsification in which an oil phase component containing components (A) to (D) and an aqueous phase component containing water and component (E) are emulsified. A manufacturing method comprising steps is preferred.

The oil phase component and the water phase component used in the emulsification step are preferably prepared by heating and mixing (preferably at 70 to 95°C, more preferably at 75 to 90°C).
In addition, the emulsification process is performed by heating and mixing from the viewpoint of improving the skin with good makeup adhesion and makeup retention when makeup is applied, as well as eliminating unevenness when the foundation is overcoated on the coating film. is preferred, it is more preferred to heat and mix at 70 to 95°C, and it is particularly preferred to heat and mix at 75 to 90°C. By mixing the oil phase component and the water phase component which are separately heated in advance, a state in which the oil phase component and the water phase component coexist under high temperature conditions may be created.
More specifically, the method for producing the emulsified composition of the present invention is as follows. That is, water and component (E) (and optionally component (G)) are heated and mixed to homogenize them to form an aqueous phase component. In addition, the components (A) to (D) are heat-mixed and homogenized to form an oil phase component. The aqueous phase component and the oil phase component are mixed under heating conditions to make them uniform, and then cooled as necessary to produce the composition.

Further, according to the emulsified composition of the present invention, even if it is used continuously for a short period of time, it is possible to improve the makeup stickiness and makeup hold when applying makeup after washing the area of continuous use. The present inventors believe that the reason why such an effect can be obtained is that the roughness of the skin surface is improved even with long-term use for a short period of time, so that the skin itself has good makeup application and makeup longevity. Guess.
The emulsified composition of the present invention is suitable for use as a cosmetic (more specifically, a skin care cosmetic). For example, it can be milky lotion, gel, beauty essence, and the like.
In addition, the emulsified composition of the present invention is also useful as a make-up base because the foundation is less likely to be uneven when the emulsified composition is applied to the skin and then the foundation is overcoated on the coating film.

In addition, the emulsified composition of the present invention can be used by being applied to the skin (preferably the skin excluding the scalp, more preferably the face, body, limbs, etc.). This method is suitable as a skin care method. The make-up may be normal make-up using foundation, blush, or the like, and if necessary, normal lotion or milky lotion may be used. After applying the emulsified composition of the present invention, the skin may be washed or dried with a towel prior to applying makeup.

The emulsification type of the emulsified composition of the present invention is not particularly limited, but examples include oil-in-water type and water-in-oil type, and the oil-in-water type emulsified composition is preferable from the viewpoint of feeling of use, skin improvement effect, and the like.
In addition, the emulsified composition of the present invention has good storage stability, safety, and unevenness when the foundation is applied to the coating film, and when makeup is applied, the makeup paste and makeup hold on the skin. From the viewpoint of improvement, a gel having an α-type structure is preferred.
The α-type structure can be confirmed by X-ray structural analysis. The α-type structure is a hexagonal system, in which the lipophilic group is oriented perpendicular to the surface of the hydrophilic base layer, and is characterized by the appearance of a sharp single diffraction peak near the Bragg angle of 21 to 23°. be.

Regarding the above-described embodiments, the present invention further discloses the following emulsified compositions and the like.
<1> Contains the following components (A), (B), (C), (D) and (E), and component (E ) content mass ratio [(E)/{(A)+(B)+(C)+(D)}] is 0.01 or more and 1 or less.
(A) one or more compounds selected from sphingosine, sphingosine salts, pseudosphingosine, pseudosphingosine salts and cationic surfactants (B) ceramides (C) glycerol fatty acid esters (D) higher alcohols (E) ) A cationic polymer whose main chain has a glass transition temperature Tg of 25°C or less <2> Component (A) is preferably a natural sphingosine represented by the following general formula (2), a salt of the natural sphingosine, The emulsified composition according to <1>, which is one or more compounds selected from pseudo-sphingosine represented by the following general formula (3), salts of the pseudo-sphingosine, and cationic surfactants.

[In formula (2),
R ⁷ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms which may be substituted with a hydroxyl group;
Y ₁ represents a methylene group or a methine group;
^X5 , ^X6 and ^X7 each independently represents a hydrogen atom, a hydroxyl group or an acetoxy group;
X ⁸ represents a hydrogen atom or forms an oxo group together with an adjacent oxygen atom (provided that when Y ₁ is a methine group, either one of X ⁵ and X ⁶ represents a hydrogen atom, the other is absent.When X ⁸ forms an oxo group, X ⁷ is absent.);
R ⁸ represents a hydroxymethyl group or an acetoxymethyl group;
each of a R ₁ is independently a hydrogen atom or an amidino group, or has a total carbon number of 1 to 4 and may have a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group; represents a linear or branched, saturated or unsaturated hydrocarbon group of;
a represents a number of 2 or 3;
A dashed line indicates that an unsaturated bond may be present. ]

[In formula (3),
R ⁹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 10 to 22 carbon atoms which may be substituted with a hydroxyl group;
X ⁹ represents a hydrogen atom, an acetyl group or a glyceryl group;
each of a R ₂ is independently a hydrogen atom or an amidino group, or has a total carbon number of 1 to 8 and may have a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group; represents a linear or branched, saturated or unsaturated hydrocarbon group of;
a represents the number of 2 or 3; ]

<3> The natural sphingosine is preferably one or more selected from sphingosine, dihydrosphingosine, phytosphingosine, sphingadienine, dehydrosphingosine, dehydrophytosphingosine, and N-alkyl derivatives thereof, and more The emulsified composition according to <2>, preferably phytosphingosine.
<4> The pseudo-type sphingosine is preferably one or more selected from the following pseudo-type sphingosines (i) to (iv), more preferably pseudo-type sphingosine (ii), <2> or The emulsified composition according to <3>.

<5> The cationic surfactant is preferably a quaternary ammonium salt-type cationic surfactant, more preferably a quaternary ammonium salt-type cationic surfactant represented by the following general formula (7). The emulsion composition according to any one of <1> to <4>.

[In formula (7),
R ³¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 6 or more carbon atoms,
R ³² represents an alkyl group having 1 to 4 carbon atoms,
R ³³ and R ³⁴ each independently represent an alkyl group having 1 to 4 carbon atoms or a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 6 or more carbon atoms,
AN ⁻ denotes a salt-forming anion. ]
<6> The content of component (A) in the emulsified composition of the present invention is preferably 0.001% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, especially It is preferably 0.2% by mass or more, and preferably 5% by mass or less, more preferably 1.5% by mass or less, even more preferably 1% by mass or less, particularly preferably 0% by mass or less in the emulsion composition of the present invention. The emulsion composition according to any one of <1> to <5>, which is 5% by mass or less.

<7> Component (B) is preferably represented by the following general formula (4), more preferably represented by the following general formula (5) or (6). The emulsified composition according to any one of <6>.

[In formula (4),
R ¹¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 4 to 30 carbon atoms which may be substituted with a hydroxyl group, a carbonyl group or an amino group, or a hydrogen atom;
Z represents a methylene group, a methine group or an oxygen atom;
X ¹¹ , X ¹² and X ¹³ each independently represent a hydrogen atom, a hydroxyl group or an acetoxy group;
X ¹⁴ represents a hydrogen atom, an acetyl group or a glyceryl group, or forms an oxo group together with an adjacent oxygen atom (provided that when Z is a methine group, either X ¹¹ or X ¹² is a hydrogen atom and the other is absent.When X ¹⁴ forms an oxo group, X ¹³ is absent.);
R ¹² and R ¹³ each independently represent a hydrogen atom, a hydroxyl group, a hydroxyalkyl group (e.g., hydroxymethyl group, hydroxyethyl group, etc.) or an acetoxymethyl group;
R ¹⁴ may be substituted with a hydroxyl group, a carbonyl group or an amino group, and may be a linear or branched chain having 5 to 60 carbon atoms which may have an ether bond, an ester bond or an amide bond in the main chain. indicating a chain or cyclic saturated or unsaturated hydrocarbon group;
R ¹⁵ represents a hydrogen atom or a linear or branched saturated or saturated or represents an unsaturated hydrocarbon group (when R ¹¹ is a hydrogen atom and Z is an oxygen atom, R ¹⁵ has a substituent selected from a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group; Also, when R ¹¹ is a hydrocarbon group, R ¹⁵ represents a hydrogen atom or a hydroxyl group, a hydroxyalkoxy group, an alkoxy group and an acetoxy group. A hydrocarbon group having a total of 1 to 8 carbon atoms, which may have selected substituents, is preferred);
A dashed line portion indicates that it may be an unsaturated bond. ]

[In formula (5),
R ²¹ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms which may be substituted with a hydroxyl group;
Z ₁ represents a methylene group or a methine group;
X ¹⁵ , X ¹⁶ and X ¹⁷ each independently represent a hydrogen atom, a hydroxyl group or an acetoxy group;
X ¹⁸ represents a hydrogen atom or forms an oxo group together with an adjacent oxygen atom (provided that when Z ₁ is a methine group, either one of X ¹⁵ and X ¹⁶ is a hydrogen atom and the other is absent.When X ¹⁸ forms an oxo group, X ¹⁷ is absent.);
R ²² represents a hydroxyalkyl group (e.g., hydroxymethyl group, hydroxyethyl group, etc.) or an acetoxymethyl group;
R ²³ represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms;
R ²⁴ is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 5 to 30 carbon atoms (the hydrocarbon group is preferably an alkyl group) optionally substituted by a hydroxyl group; or an ester of a linear or branched, saturated or unsaturated fatty acid having 8 to 22 carbon atoms which may be substituted with a hydroxyl group at the ω end of the hydrocarbon group (the hydrocarbon group is preferably an alkyl group); indicate the bound;
A dashed line portion indicates that it may be an unsaturated bond. ]

[In formula (6),
R ²⁵ represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 10 to 22 carbon atoms which may be substituted with a hydroxyl group, or a hydrogen atom;
X ¹⁹ represents a hydrogen atom, an acetyl group or a glyceryl group;
R ²⁶ is a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 5 to 22 carbon atoms which may be substituted with a hydroxyl group or an amino group (the hydrocarbon group is preferably an alkyl group); or a linear or branched saturated or unsaturated fatty acid having 8 to 22 carbon atoms which may be substituted with a hydroxyl group at the ω end of the hydrocarbon group (the hydrocarbon group is preferably an alkyl group) is ester-bonded;
R ²⁷ represents a hydrogen atom or a hydrocarbon group having a total of 1 to 30 carbon atoms which may be substituted with a hydroxyl group, a hydroxyalkoxy group, an alkoxy group or an acetoxy group (the hydrocarbon group is preferably an alkyl group); show. ]
<8> The content of component (B) in the emulsion composition of the present invention is preferably 0.001% by mass or more, more preferably 0.05% by mass or more, still more preferably 1% by mass or more, and particularly preferably 1.5% by mass or more, preferably 10% by mass or less, more preferably 7% by mass or less, even more preferably 5% by mass or less, particularly preferably 4% by mass or less in the emulsion composition of the present invention The emulsion composition according to any one of <1> to <7>.

<9> Component (C) is preferably a glycerin monofatty acid ester having a fatty acid residue of 10 to 24 carbon atoms, more preferably a glycerin monofatty acid ester having a fatty acid residue of 16 to 24 carbon atoms. The emulsified composition according to any one of <1> to <8>, which is preferably a glycerin monofatty acid ester having a residue of a saturated fatty acid having 18 to 24 carbon atoms.
<10> The content of component (C) in the emulsion composition of the present invention is preferably 0.001% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, especially It is preferably 0.5% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less, even more preferably 5% by mass or less, and particularly preferably 3% by mass in the emulsion composition of the present invention. The emulsified composition according to any one of <1> to <9> below.

<11> Component (D) is preferably a monohydric alcohol having 10 to 24 carbon atoms, more preferably a monohydric alcohol having 12 to 22 carbon atoms, even more preferably a monohydric alcohol having 14 to 22 carbon atoms. The emulsion composition according to any one of <1> to <10>.
<12> The content of component (D) in the emulsified composition of the present invention is preferably 0.001% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, especially It is preferably 0.6% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less, even more preferably 5% by mass or less, and particularly preferably 3% by mass in the emulsion composition of the present invention. The emulsified composition according to any one of <1> to <11> below.
<13> The content mass ratio of component (B) to the sum of components (B), (C) and (D) [(B)/{(B)+(C)+(D)}] is preferably 0 .1 or more, more preferably 0.2 or more, preferably 1 or less, more preferably 0.75 or less, and particularly preferably 0.6 or less, any one of <1> to <12> The emulsion composition described.
<14> The content mass ratio of component (C) to the total of components (C) and (D) [(C)/{(C)+(D)}] is preferably 0.1 or more, more preferably 0 0.25 or more, preferably 1 or less, more preferably 0.75 or less, and particularly preferably 0.65 or less, according to any one of <1> to <13>.

<15> The glass transition temperature Tg of the main chain of the cationic polymer of component (E) is preferably 15° C. or lower, more preferably 0° C. or lower, further preferably −25° C. or lower, further preferably −50° C. or lower, The emulsion composition according to any one of <1> to <14>, which is particularly preferably -100°C or lower.
<16> Light transmittance when 25 parts by mass of the cationic polymer of component (E) is mixed with 100 parts by mass of cetanol at 85°C is preferably 90% or more, more preferably 92.5% or more, and further The emulsion composition according to any one of <1> to <15>, which is preferably 95% or more, more preferably 96% or more, and particularly preferably 98% or more.
<17> The charge density of the cationic polymer of component (E) is preferably 0.01 meq/g or more, more preferably 0.03 meq/g or more, still more preferably 0.05 meq/g or more, still more preferably 0.05 meq/g or more. 08 meq/g or more, more preferably 0.1 meq/g or more, still more preferably 0.15 meq/g or more, particularly preferably 0.2 meq/g or more, and preferably 10.0 meq/g or less, more preferably is 9.0 meq/g or less, more preferably 8.0 meq/g or less, and particularly preferably 2.0 meq/g or less, the emulsion composition according to any one of <1> to <16>.

<18> The cationic polymer of component (E) preferably contains one or more segments selected from organopolysiloxane segments, polyoxyalkylene segments, and segments containing repeating structural units derived from unsaturated monomers. The emulsion composition according to any one of <1> to <17>, which is a polymer having a chain, more preferably a polymer having an organopolysiloxane segment as a main chain.
<19> The cationic polymer of component (E) preferably contains one or more cationic polymers selected from primary amino groups, secondary amino groups, tertiary amino groups and quaternary ammonium groups. group, more preferably one or more cationic groups selected from a primary amino group, a secondary amino group and a tertiary amino group, still more preferably a tertiary The emulsion composition according to any one of <1> to <18>, which has a secondary amino group.
<20> The cationic polymer of component (E) preferably has a cationic group in its main chain or side chain, and more preferably has a cationic group in its side chain, <1> to <19>.

<21> The cationic polymer of component (E) is preferably one or more polymers selected from poly(N-acylalkyleneimine)-modified silicone and amino-modified silicone, more preferably poly(N- The emulsified composition according to any one of <1> to <20>, which is an acylalkyleneimine)-modified silicone.

<22> The poly(N-acylalkyleneimine)-modified silicone is preferably attached to at least two of the silicon atoms of the organopolysiloxane segment that constitutes the main chain via a cationic divalent linking group of the following general formula ( 11) is an organopolysiloxane in which poly(N-acylalkyleneimine) segments composed of repeating units represented by the formula are bonded, wherein the poly(N-acylalkyleneimine) segments have a number average molecular weight of 500 to 4,000. , The emulsion composition according to <21>, which is an organopolysiloxane in which the weight average molecular weight of the organopolysiloxane segment constituting the main chain is 10,000 to 200,000.

[In the formula (11), R ⁴¹ represents a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group or an aryl group, and t represents 2 or 3; ]

<23> The emulsified composition according to <21> or <22>, wherein the amino-modified silicone is represented by the following general formula (13).

[In formula (13),
R ⁵¹ to R ⁵³ each independently represent a hydrogen atom, a hydroxyl group, or a monovalent organic group having 1 to 20 carbon atoms,
R ⁵⁴ represents a group represented by the following general formula (14),
R ⁵⁵ to R ⁵⁶ each independently represents a hydroxyl group, an alkoxy group having 1 to 20 carbon atoms, a monovalent organic group having 1 to 20 carbon atoms, or a group represented by the following general formula (14); ,
R ⁵⁷ to R ⁶⁰ are each independently a hydrogen atom, a hydroxyl group, an alkoxy group having 1 to 20 carbon atoms, a monovalent organic group having 1 to 20 carbon atoms, or represented by the following general formula (14) indicate the group,
d represents a number of 10 ≤ d ≤ 10000,
e indicates a number of 0.1≦e≦1000. ]

[In formula (14),
R ⁶¹ to R ⁶² each independently represents an alkanediyl group having 1 to 8 carbon atoms,
R ⁶³ to R ⁶⁵ each independently represents a hydrogen atom or a monovalent organic group having 1 to 10 carbon atoms,
f represents a number of 0 ≤ f ≤ 6,
* indicates a bond. ]

<24> The content of component (E) in the emulsified composition of the present invention is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, especially It is preferably 1% by mass or more, and preferably 15% by mass or less, more preferably 10% by mass or less, even more preferably 7.5% by mass or less, and particularly preferably 5% by mass in the emulsion composition of the present invention. The emulsified composition according to any one of <1> to <23> below.
<25> Content mass ratio [(E) / {(A) + (B) + (C) + (D)}] is preferably 0.03 or more, more preferably 0.05 or more, and still more preferably 0 .1 or more, particularly preferably 0.2 or more, and preferably 0.95 or less, more preferably 0.9 or less, still more preferably 0.85 or less, and particularly preferably 0.8 or less. 1> to the emulsion composition according to any one of <24>.

<26> The emulsified composition according to any one of <1> to <25>, further comprising (F) water.
<27> The content of water in the emulsion composition of the present invention is preferably 30% by mass or more, more preferably 50% by mass or more, and particularly preferably 60% by mass or more, and the emulsion composition of the present invention The emulsion composition according to <26>, which is medium, preferably 99.99% by mass or less, more preferably 97.5% by mass or less, and particularly preferably 95% by mass or less.
<28> The emulsified composition according to any one of <1> to <27>, further comprising (G) a polyhydric alcohol.

<29> The emulsified composition according to any one of <1> to <28>, which is preferably oil-in-water or water-in-oil, more preferably oil-in-water.
<30> The emulsified composition according to any one of <1> to <29>, which is an α-structured gel.

<31> A method of skin care (preferably a method of improving skin quality), comprising the step of applying the emulsified composition according to any one of <1> to <30> to the skin.

EXAMPLES The present invention will be described in detail below with reference to Examples, but the present invention is not limited to these Examples.

(Examples 1 to 5, 7 to 8, Comparative Examples 2, 4 to 6 oil-in-water emulsion cosmetics)
According to the formulations shown in Tables 1 and 2, oil-in-water emulsified cosmetics were prepared by the following method.
That is, the lamellar solid fat phase components in Tables 1 and 2 were uniformly mixed and heated to 85° C. to dissolve. Separately, the polymer components and aqueous phase components in Tables 1 and 2 were mixed at 85° C. and homogenized. This mixture was added to the above lamellar solid fat phase component heated to 85°C, followed by stirring at 85°C to homogenize, and then cooled to 25°C while stirring.

(Example 6 oil-in-water emulsified cosmetic)
According to the formulation shown in Table 1, an oil-in-water emulsified cosmetic was prepared by the following method.
Specifically, the lamellar solid fat phase components in Table 1 are uniformly mixed, heated to 85°C to dissolve, and then the aqueous phase components in Table 1 are added to the lamellar solid fat phase components while stirring at 85°C. to make it uniform. The mixture was then cooled to 25° C. while stirring, and then the polymer components in Table 1 were added and homogenized.

(Comparative Example 1 Oil-in-water emulsified cosmetic)
According to the formulation shown in Table 2, an oil-in-water emulsified cosmetic was prepared by the following method.
That is, the lamellar solid fat phase components in Table 2 are uniformly mixed, heated to 85°C to dissolve, and then the aqueous phase components in Table 2 are added to the lamellar solid fat phase components while stirring at 85°C. After homogenization, the mixture was cooled to 25°C while stirring.

(Comparative Example 3 cosmetics)
According to the formulation shown in Table 2, a cosmetic was prepared by mixing the polymer components and aqueous phase components in Table 2 at 25°C.

The cosmetics obtained in Examples 1 to 8 and Comparative Examples 1 to 6 were evaluated according to the following methods and criteria. Evaluation results are shown in Tables 1 and 2.

(1) No unevenness of foundation after application of cosmetics Five expert panelists applied 600 mg of the cosmetic of Examples or Comparative Examples to the entire face, and then applied a commercially available powder foundation to the entire face. and evaluated the lack of unevenness when the powder foundation was applied according to the following criteria. The evaluation result was shown by the total value of five persons.

(Evaluation Criteria for Evenness)
1 point: uneven 2 points: slightly uneven 3 points: neither 4 points: evenly applied without much unevenness 5 points: very evenly applied without unevenness

(2) Continual use of cosmetics for 3 days and application of make-up after cleansing For 5 specialist panelists, 600 mg of the cosmetics of Examples or Comparative Examples were applied to the entire face twice a day, morning and evening, for 3 days. I had it painted. After thoroughly washing and acclimatizing the site that has been used continuously for 3 days, apply a commercially available lotion and milky lotion, and then apply a commercially available powder foundation to the entire face. They were evaluated according to the following criteria. The evaluation result was shown by the total value of five persons.

(Evaluation criteria for makeup glue)
1 point: Poor makeup application 2 points: Somewhat poor application of makeup 3 points: Neither 4 points: Slightly good application of makeup 5 points: Good application of makeup

(3) Continuous use of cosmetics for 3 days and longevity of makeup after cleansing Five specialist panelists were given 600 mg of the cosmetics of Examples or Comparative Examples twice a day, morning and evening, for 3 days, on the entire face. I had it painted. After thoroughly washing and acclimatizing the site that had been used continuously for 3 days, a commercially available lotion and milky lotion were applied, and then 60 mg of a commercially available powder foundation was applied to the entire face. After 5 hours from the application of the powder foundation, the adhesive tape is attached and peeled to the application site, and the amount of foundation adhered to the adhesive tape is used as an index, and the makeup hold of the foundation after 5 hours (to the skin degree of residual) was visually evaluated according to the following criteria. The evaluation result was shown by the total value of five persons.

(Evaluation Criteria for Makeup Stickiness)
1 point: No foundation remains on the skin (not attached to the tape)
2 points: The foundation hardly remains on the skin 3 points: The foundation does not remain on the skin very much 4 points: The foundation slightly remains on the skin 5 points: The foundation remains very much on the skin

Symbols in the table indicate the following, respectively.
*1: Prepared according to the description in JP-A-2009-24114 Example 8 (Tg of the main chain: -121 ° C., light when 25 parts by mass with respect to 100 parts by mass of cetanol are mixed at 85 ° C. Transmittance: 98%, charge density: 0.3 meq/g)
*2: Prepared according to the description in Japanese Patent Application Laid-Open No. 2008-143820 Synthesis Example 2 (Tg of the main chain: -121 ° C., light when 25 parts by mass with respect to 100 parts by mass of cetanol are mixed at 85 ° C. Transmittance: 98%, charge density: 0.1 meq/g)
* 3: KF-8003 manufactured by Shin-Etsu Chemical Co., Ltd. (Tg of the main chain: -121 ° C., light transmittance when 25 parts by mass is mixed with 100 parts by mass of cetanol at 85 ° C.: 95%, charge density: 0.4 meq/g)
* 4: PEG6000 manufactured by Toho Chemical Industry Co., Ltd. (Tg: -23 ° C., charge density: 0 meq / g)
*5: Structure XL manufactured by Akzo Nobel (charge density: 0 meq/g)
* 6: Shin-Etsu Chemical Co., Ltd. KF96-10000CS (Tg: -121 ° C., charge density: 0 meq / g)

Claims (5)

Contains the following components (A), (B), (C), (D) and (E), and contains component (E) with respect to the total of components (A), (B), (C) and (D) An emulsion composition having a mass ratio [(E)/{(A)+(B)+(C)+(D)}] of 0.01 or more and 1 or less.
(A) one or more compounds selected from sphingosine, sphingosine salts, pseudosphingosine, pseudosphingosine salts and cationic surfactants (B) ceramides (C) glycerol fatty acid esters (D) higher alcohols (E) ) A cationic polymer whose main chain has a glass transition temperature Tg of 25° C. or lower 2. The emulsion composition according to claim 1, wherein the cationic polymer of component (E) is a polymer having an organopolysiloxane segment as a main chain. The cationic polymer of component (E) has one or more cationic groups selected from primary amino groups, secondary amino groups, tertiary amino groups and quaternary ammonium groups. 3. The emulsion composition according to claim 1 or 2, wherein 4. The emulsion composition according to claim 3, wherein the cationic polymer of component (E) has a cationic group in its side chain. 5. The emulsified composition according to any one of claims 1 to 4, which is an α-structured gel.