JP7244201B2 - Liquid eggs for heat cooking and processed egg products using the same - Google Patents
Liquid eggs for heat cooking and processed egg products using the same Download PDFInfo
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Description
本発明は、加熱調理用液卵及びこれを用いた卵加工品に関する。TECHNICAL FIELD The present invention relates to a liquid egg for cooking with heat and a processed egg product using the same.
家庭用や業務用として市販されている卵加工品、あるいはレストラン等で提供される卵料理には、厚焼き玉子、スクランブルエッグ、オムレツ、親子丼、かに玉等、やわらかい半熟様の食感が好まれるものがある。
卵は過加熱状態となるとタンパク質の凝固が促進され、水分も抜け、パサパサした硬い食感となりやすい。そのため、卵加工品のやわらかい半熟様の食感を維持することが食品工業上の課題となっている。Processed egg products that are commercially available for home and business use, and egg dishes that are served at restaurants, etc., have a soft, half-boiled texture, such as thick omelet, scrambled egg, omelet, oyakodon, and crab balls. There are things I like.
When eggs are overheated, protein coagulation is accelerated, moisture is lost, and the texture tends to be dry and hard. Therefore, maintaining the soft, soft-boiled texture of processed egg products has become an issue in the food industry.
卵加工品の製造には、あらかじめ割卵され、殺菌処理を施された殺菌済液卵を用いられているが、やわらかい半熟様の食感を維持するために、種々の工夫がなされている。
従来から、糖や、澱粉、ガム類等多糖類の添加などが行われてきたが、その他には、例えば、アルギン酸、ローメトキシルペクチン等のカルシウム反応性のゲル化剤を含有させる方法(特許文献1)、青価が0.4~1.2であるデキストリンを含有させる方法(特許文献2)等がある。
しかしながら、特許文献1に記載の方法ではゲル化剤が加わるために卵のみを焼成した場合の自然な食感が失われやすい。また、特許文献2に記載の方法では、やわらかい半熟様の食感を得るには不十分であった。
したがって、やわらかい半熟様の食感を有する卵加工品を製造するための液卵の技術にはまだ改善の余地がある。In the production of processed egg products, sterilized liquid eggs that have been cracked and sterilized in advance are used.
Conventionally, addition of sugar, starch, polysaccharides such as gums, etc. has been performed, but in addition, for example, a method of incorporating calcium-reactive gelling agents such as alginic acid and low-methoxyl pectin (Patent Documents 1), and a method of incorporating dextrin having a blue value of 0.4 to 1.2 (Patent Document 2).
However, in the method described in Patent Document 1, the addition of a gelling agent tends to result in loss of the natural texture when only eggs are baked. In addition, the method described in Patent Document 2 was insufficient to obtain a soft, soft-boiled texture.
Therefore, there is still room for improvement in the technology of liquid eggs for producing processed egg products having a soft, soft-boiled texture.
本発明は、やわらかい半熟様の食感を有する卵加工品を製造するための液卵を提供することを目的とする。An object of the present invention is to provide a liquid egg for producing a processed egg product having a soft, half-boiled texture.
本発明者は、前記目的を達成すべく鋭意検討を重ねた。
その結果、酢酸と特定の有機酸とを含有し、pHが5.5以上7以下である液卵を用いることによりはじめて、卵を加熱調理した際に意外にもやわらかい半熟様の食感が得られること、さらに、過加熱状態となっても上記の食感が維持されることを見出し、本発明を完成するに至った。The inventor of the present invention has made intensive studies to achieve the above object.
As a result, only by using a liquid egg containing acetic acid and a specific organic acid and having a pH of 5.5 or more and 7 or less can an unexpectedly soft soft-boiled texture be obtained when the egg is cooked. Furthermore, the inventors have found that the texture described above is maintained even in an overheated state, and have completed the present invention.
すなわち、本発明は、
(1)加熱調理用液卵であって、
酢酸と、
炭素数が3以上6以下である有機酸から選ばれる1種以上とを含有し、
pHが5.5以上7以下である、
加熱調理用液卵。
(2)(1)の加熱調理用液卵において、
前記炭素数が3以上6以下である有機酸がグルコン酸である、
加熱調理用液卵、
(3)(1)又は(2)の加熱調理用液卵において、
前記液卵全量に対して、
前記酢酸及び前記炭素数が3以上6以下である有機酸の合計含有量が0.01%以上2%以下である、
加熱調理用液卵、
(4)(1)乃至(3)のいずれかに記載の加熱調理用液卵において、
カリウム、マグネシウム及びカルシウムの合計含有量が200ppm以上である、
加熱調理用液卵、
(5)(1)乃至(4)のいずれかの加熱調理用液卵を用いた、
卵焼成品。
(6)(1)乃至(5)のいずれかの加熱調理用液卵を用いた、
卵とじ、
である。That is, the present invention
(1) A liquid egg for cooking with heat,
acetic acid;
and one or more selected from organic acids having 3 to 6 carbon atoms,
pH is 5.5 or more and 7 or less,
Liquid egg for cooking with heat.
(2) In the liquid egg for heat cooking of (1),
The organic acid having 3 or more and 6 or less carbon atoms is gluconic acid.
Liquid egg for cooking with heat,
(3) In the liquid egg for heat cooking of (1) or (2),
For the liquid egg total amount,
The total content of the acetic acid and the organic acid having 3 to 6 carbon atoms is 0.01% to 2%,
Liquid egg for cooking with heat,
(4) In the liquid egg for heat cooking according to any one of (1) to (3),
The total content of potassium, magnesium and calcium is 200 ppm or more,
Liquid egg for cooking with heat,
(5) Using the liquid egg for heat cooking according to any one of (1) to (4),
Baked eggs.
(6) Using the liquid egg for heat cooking according to any one of (1) to (5),
egg binding,
is.
本発明によれば、加熱調理時に卵が過度に凝固することなく、やわらかい半熟様の食感の卵加工品を得ることができ、さらに過加熱状態となっても同様の食感を維持することが可能となる。
したがって、製造時に加熱殺菌処理が必要な卵加工品や、喫食時に再加熱される親子丼等の弁当類の品位向上に貢献できる。
加えて、レストラン等でも調理の習熟度合いによらず一定の品位の商品を提供することが可能となり、卵料理の調理オペレーションの簡素化及び負担の軽減と、生産効率の向上に貢献できる。According to the present invention, it is possible to obtain a processed egg product having a soft soft-boiled texture without excessive coagulation of the egg during cooking, and to maintain the same texture even when the egg is overheated. becomes possible.
Therefore, it can contribute to improving the quality of processed egg products that require heat sterilization at the time of production, and boxed lunches such as oyakodon that are reheated at the time of eating.
In addition, it becomes possible for restaurants and the like to provide products of a certain quality regardless of the cooking proficiency level, which contributes to the simplification and reduction of the burden of cooking egg dishes and the improvement of production efficiency.
以下本発明を詳細に説明する。
なお、本発明において「%」は「質量%」を、「部」は「質量部」を意味する。The present invention will be described in detail below.
In the present invention, "%" means "mass %" and "part" means "mass part".
<本発明の特徴>
本発明は、酢酸と特定の有機酸とを含有し、pHが5.5以上7以下である液卵を用いることにより、卵を加熱調理した際にやわらかい半熟様の食感が得られ、さらに、加熱調理時に過加熱状態となっても上記の食感が維持されることに特徴を有する。<Characteristics of the present invention>
In the present invention, by using a liquid egg containing acetic acid and a specific organic acid and having a pH of 5.5 or more and 7 or less, a soft half-boiled texture can be obtained when the egg is cooked. , is characterized in that the above texture is maintained even when overheated during cooking.
<加熱調理用液卵>
本発明の加熱調理用液卵は、少なくとも卵黄液、卵白液、酢酸及び炭素数3以上6以下の有機酸を1種以上含んであり、加熱調理を行った際に黄色を呈するものをいう。
具体的には、例えば、卵を割卵して得られた全卵液をろ過、殺菌、凍結したもの、これらを乾燥等の各種処理を施した後液状に戻したもの、コレステロール、糖分、リチゾーム等の成分の一部を除去したもの、卵黄液と卵白液とを任意の比率で混合したもの等が挙げられる。
本発明の加熱調理用液卵は、加熱調理した際に卵のやわらかい半熟様の食感を維持できるため、卵加工品の中でも卵のやわらかい半熟様の食感が好まれるメニュー、具体的には、厚焼き玉子、だし巻き卵、オムレツ、スクランブルエッグ、かに玉等の卵焼成品、親子丼の具、カツ丼の具、ウナギの卵とじ等、具材と煮汁を卵で加熱凝固させる卵とじに好適に用いることができる。
さらに、本発明の加熱調理用液卵は、過加熱状態となった場合にも上記の食感が維持できることから、製造後真空パックされて常温で喫食される製品のほか、加熱殺菌が必要な卵加工品、喫食時に再加熱される弁当やレトルトパックの卵とじ等の品位を向上させることも可能となる。<Liquid egg for cooking with heat>
The liquid egg for heat cooking of the present invention contains at least one kind of liquid egg yolk, liquid egg white, acetic acid and organic acid having 3 to 6 carbon atoms, and exhibits a yellow color when heated.
Specifically, for example, whole egg liquid obtained by breaking an egg is filtered, sterilized, and frozen, or is reconstituted after being subjected to various treatments such as drying, cholesterol, sugar, lithisome and the like, and those obtained by mixing egg yolk liquid and egg white liquid at an arbitrary ratio.
The liquid egg for heat cooking of the present invention can maintain the texture of a soft, soft-boiled egg when cooked. , Atsuyaki tamago, dashimaki tamago, omelets, scrambled eggs, baked egg products such as crab balls, oyakodon ingredients, katsudon ingredients, eel egg binding, etc. Eggs that heat and solidify ingredients and broth It can be suitably used for binding.
Furthermore, since the liquid egg for heat cooking of the present invention can maintain the above-mentioned texture even when it is overheated, it can be vacuum-packed after production and eaten at room temperature. It is also possible to improve the quality of processed egg products, boxed lunches that are reheated when eaten, and retort packs bound with eggs.
<卵>
本発明の卵は、食用に供されるものであれば特に制限はなく、鶏、ウズラ、アヒル等の卵が挙げられる。また、卵の形態は問わず、例えば、殻付き卵を用いてもよいし、液全卵、液卵黄、液卵白のようにあらかじめ割卵されているものを用いてもよい。<Egg>
The egg of the present invention is not particularly limited as long as it is edible, and examples thereof include eggs of chickens, quails, ducks, and the like. The form of the egg is not limited, and for example, a shell egg may be used, or an egg that has been broken in advance such as a liquid whole egg, a liquid egg yolk, or a liquid egg white may be used.
<酢酸及び炭素数3以上6以下である有機酸>
本発明の加熱調理用液卵は、酢酸及び後述する炭素数3以上6以下である有機酸(以下、有機酸と記載する)の両方を含有することが重要である。酢酸及び有機酸の両方を含有することにより、糖や澱粉等を含有させずとも、卵加工品のやわらかい半熟様の食感を維持することが可能となる。
食感維持のメカニズムは定かではないが、卵タンパク質の一部が適度に変性し、加熱時にタンパク質が過度に凝固することを防いでいるものと推測される。
また、食品工業においては、タンク内にストックされた大量の液卵を用いて種々の卵加工品を製造するが、液卵に対して酢酸のみもしくは後述する有機酸のみを添加した場合には、卵タンパク質の変性が急速に進む。そうすると、タンクに長時間ストックされていた液卵を用いて加熱製造された卵加工品は部分的にゲル様の食感となって品位が低下する。また、変性によってゲル化した卵がストックタンクの配管内に付着して生産ラインのサニタイズ性が低下する、配管詰まりの原因になる等、生産上の問題も生じやすくなる。酢酸及び後述する有機酸の両方を含有する液卵はこのような問題が生じ難く、食品工業上の大量生産に適する。<Acetic acid and organic acid having 3 to 6 carbon atoms>
It is important that the liquid egg for heat cooking of the present invention contains both acetic acid and an organic acid having 3 to 6 carbon atoms (hereinafter referred to as an organic acid) described later. By containing both acetic acid and organic acid, it is possible to maintain the soft, half-boiled texture of the processed egg product without containing sugar, starch, or the like.
Although the mechanism for maintaining the texture is not clear, it is speculated that part of the egg protein is moderately denatured to prevent excessive coagulation of the protein during heating.
In the food industry, a large amount of liquid eggs stocked in tanks is used to produce various processed egg products. Egg protein denaturation progresses rapidly. As a result, processed egg products produced by heating using liquid eggs that have been stocked in a tank for a long period of time have a partially gel-like texture and are of poor quality. In addition, eggs that have gelled due to denaturation adhere to the inside of the pipes of the stock tank, reducing the sanitization of the production line and causing clogging of the pipes. A liquid egg containing both acetic acid and an organic acid, which will be described later, is less likely to cause such problems and is suitable for mass production in the food industry.
<酢酸>
酢酸は、天然又は合成のもののうち、食用に適するものであれば特に制限されない。<acetic acid>
Acetic acid is not particularly limited as long as it is edible among natural or synthetic ones.
<炭素数3以上6以下である有機酸>
本発明の加熱調理用液卵は、酢酸のほか、炭素数が3以上6以下である有機酸を含有する。これらの有機酸は食用に用いられるものであればよく、具体的には、乳酸、リンゴ酸、コハク酸、酒石酸、クエン酸、グルコン酸等が挙げられ、天然又は合成のもののうち、食用に適するものであれば特に制限されない。
本発明においては、卵のやわらかい半熟様の食感を得る観点から、上記有機酸のうち、特にグルコン酸を含有させた場合にやわらかい半熟様の食感と卵の食味とに優れた卵加工品が得られる。<Organic acid having 3 to 6 carbon atoms>
The liquid egg for cooking with heat of the present invention contains an organic acid having 3 or more and 6 or less carbon atoms in addition to acetic acid. These organic acids may be used as long as they are edible, and specific examples include lactic acid, malic acid, succinic acid, tartaric acid, citric acid, gluconic acid, and the like. It is not particularly limited as long as it is a substance.
In the present invention, from the viewpoint of obtaining a soft soft-boiled egg-like texture, a processed egg product excellent in soft soft-boiled-like texture and egg taste when gluconic acid is contained among the above organic acids. is obtained.
<酢酸及び炭素数3以上6以下の有機酸の添加方法>
前記酢酸及び前記有機酸は、酢酸そのものあるいは有機酸そのものとして添加してもよいし、これらを含有する食品素材、例えば、柑橘類、リンゴ等の果汁、清酒、ワイン、醸造酢、合成酢、出汁、エキス類、はちみつ等を添加してもよい。また、グルコノラクトン等の有機酸前駆体があるものはこれを添加してもよい。<Method of adding acetic acid and organic acid having 3 to 6 carbon atoms>
The acetic acid and the organic acid may be added as acetic acid itself or the organic acid itself, and food materials containing these, such as citrus fruits, apple juice, sake, wine, brewed vinegar, synthetic vinegar, soup stock, Extracts, honey, etc. may be added. Also, if there is an organic acid precursor such as gluconolactone, it may be added.
<加熱調理用液卵のpH>
本発明の加熱調理用液卵のpHは5.5以上7以下であり、さらに6以上7以下であるとよい。
加熱調理用液卵のpHが前記範囲より高いと、加熱調理後のやわらかい半熟様の食感に乏しく、pHが前記範囲より低いと、酸味が強くなり卵の食味が損なわれる。
なお、加熱調理用液卵のpHは、前記酢酸及び前記有機酸の添加によって調整することが可能であるが、その他に必要に応じて、酢酸塩、前記有機酸の塩、水酸化カルシウム、炭酸水素ナトリウム、炭酸カルシウム、卵殻、貝殻カルシウム等、食品に一般的に用いられるpH調整剤を用いればよい。<pH of liquid egg for cooking with heat>
The liquid egg for cooking with heat according to the present invention has a pH of 5.5 or more and 7 or less, preferably 6 or more and 7 or less.
If the pH of the liquid egg for cooking is higher than the above range, the soft and soft-boiled texture after cooking is poor.
The pH of the liquid egg for cooking can be adjusted by adding the acetic acid and the organic acid. A pH adjuster commonly used in foods, such as sodium hydride, calcium carbonate, eggshell, and shell calcium, may be used.
<酢酸と炭素数3以上6以下の有機酸の合計含有量>
前記酢酸及び前記有機酸の合計含有量は、卵の食味を損なわずにやわらかい半熟様の食感を維持できる観点から、加熱調理用液卵全量に対して0.01%以上2%以下がよく、さらに0.1%以上1%以下であるとよい。<Total content of acetic acid and organic acid having 3 to 6 carbon atoms>
The total content of the acetic acid and the organic acid is preferably 0.01% or more and 2% or less relative to the total amount of the liquid egg for heat cooking, from the viewpoint of maintaining a soft and soft-boiled texture without impairing the taste of the egg. , and more preferably 0.1% or more and 1% or less.
<酢酸と炭素数3以上6以下の有機酸の含有比>
本発明の加熱調理用液卵における前記酢酸及び前記有機酸の含有比は、やわらかい半熟様の食感を維持できる観点から、1:0.01~1:1であるとよく、さらに1:0.05~1:0.5であるとよい。<Content ratio of acetic acid and organic acid having 3 to 6 carbon atoms>
The content ratio of the acetic acid and the organic acid in the liquid egg for heat cooking of the present invention is preferably 1:0.01 to 1:1, more preferably 1:0, from the viewpoint of maintaining a soft and soft-boiled texture. 0.05 to 1:0.5.
<カリウム、カルシウム、マグネシウム>
本発明の加熱調理用液卵は、加熱調理の際に卵のやわらかい半熟様の食感を得やすくし、前記酢酸及び前記有機酸に由来する酸味・酸臭をマスキングして卵本来の味わいを感じやすくする観点から、さらにカリウム、カルシウム及びマグネシウムを含有するのがよい。食感維持のメカニズムは定かではないが、前記酢酸及び有機酸の効果を補助し、卵タンパクの変性をコントロールするものと推測される。
カリウム、カルシウム及びマグネシウムは、食用に適するものであれば由来は特に制限されない。前記酢酸及び有機酸を食品素材として添加する場合には、その食品素材に由来するものでもよく、上述したpH調整剤に由来するものでもよい。また、添加物指定されている物質、例えば、塩化カリウム、硫酸マグネシウム、にがり等として添加してもよい。<Potassium, Calcium, Magnesium>
The liquid egg for cooking with heat of the present invention makes it easy to obtain a soft and soft-boiled egg-like texture during cooking, and masks the sour taste and sour smell derived from the acetic acid and the organic acid to retain the original taste of the egg. It is preferable to further contain potassium, calcium, and magnesium from the viewpoint of making it easy to feel. Although the mechanism of maintaining texture is not clear, it is presumed that it assists the effects of the acetic acid and the organic acid and controls the denaturation of the egg protein.
The sources of potassium, calcium and magnesium are not particularly limited as long as they are edible. When the acetic acid and the organic acid are added as food materials, they may be derived from the food materials, or may be derived from the above-described pH adjuster. In addition, substances designated as additives, such as potassium chloride, magnesium sulfate, bittern, etc., may be added.
<カリウム、カルシウム、マグネシウム>
本発明の加熱調理用液卵におけるカリウム、カルシウム及びマグネシウムの合計含有量は、200ppm以上、さらに250ppm以上となるようにすると、卵のやわらかい半熟様の食感がより得られやすくなり、好ましい。
カリウム、カルシウム及びマグネシウムの合計含有量の上限は特に制限されないが、エグ味等で卵の食味を損なわない観点から、2000ppm以下がよく、さらに1500ppm以下であるとよい。<Potassium, Calcium, Magnesium>
When the total content of potassium, calcium and magnesium in the liquid egg for cooking with heat of the present invention is 200 ppm or more, preferably 250 ppm or more, a soft, half-boiled egg-like texture can be obtained more easily, which is preferable.
Although the upper limit of the total content of potassium, calcium and magnesium is not particularly limited, it is preferably 2000 ppm or less, more preferably 1500 ppm or less, from the viewpoint of not impairing the taste of eggs due to harshness or the like.
<その他の原料>
本発明においては、本発明の必須原料である酢酸、炭素数3以上6以下の有機酸以外の原料を、本発明の効果を損なわない範囲で適宜選択し、配合することができる。
具体的には、例えば、食塩、醤油、その他の調味料、各種アミノ酸、各種ビタミン、各種ペプチド、各種ミネラル、アスパルテーム、フェニルアラニン等の甘味料、キサンタンガム、カラギーナン、デンプン、加工デンプンなどの増粘多糖類、着色料、香料、保存料等が挙げられる。<Other raw materials>
In the present invention, raw materials other than acetic acid and organic acids having 3 to 6 carbon atoms, which are the essential raw materials of the present invention, can be appropriately selected and blended within a range that does not impair the effects of the present invention.
Specifically, for example, salt, soy sauce, other seasonings, various amino acids, various vitamins, various peptides, various minerals, sweeteners such as aspartame and phenylalanine, polysaccharide thickeners such as xanthan gum, carrageenan, starch and modified starch. , coloring agents, fragrances, preservatives, and the like.
以下、本発明について、実施例、比較例及び試験例に基づき具体的に説明する。なお、本発明は、これらに限定するものではない。Hereinafter, the present invention will be specifically described based on Examples, Comparative Examples and Test Examples. In addition, this invention is not limited to these.
[実施例1]
表1の配合に準じ、液全卵、酢酸、グルコン酸、カリウム、カルシウム及びマグネシウムを混合し、本発明の加熱調理用液卵を得た。[Example 1]
A liquid whole egg, acetic acid, gluconic acid, potassium, calcium and magnesium were mixed according to the composition shown in Table 1 to obtain a liquid egg for heat cooking of the present invention.
実施例2~7、比較例1~4についても、表1の配合に準じ、実施例1と同様の方法で加熱調理用液卵を得た。For Examples 2 to 7 and Comparative Examples 1 to 4, liquid eggs for heat cooking were obtained in the same manner as in Example 1 according to the formulations in Table 1.
[試験例1]加熱調理用液卵のpH
加熱調理用液卵のpHは、下記の測定装置及び方法により測定した。
<測定方法>
実施例1~7及び比較例1~4の加熱調理用液卵を撹拌しながら電極を浸し、3分後に指示された値を加熱調理用液卵のpHとした。
<測定装置>
機器:FiveEasyPlus pH meter型番FEP20(METTLER TOLEDO製)
電極:LE438複合電極(METTLER TOLEDO製)[Test Example 1] pH of liquid egg for heat cooking
The pH of the liquid egg for cooking was measured by the following measuring device and method.
<Measurement method>
The electrode was immersed while stirring the liquid eggs for heat cooking of Examples 1 to 7 and Comparative Examples 1 to 4, and the indicated value after 3 minutes was taken as the pH of the liquid eggs for heat cooking.
<Measuring device>
Equipment: FiveEasyPlus pH meter model number FEP20 (manufactured by METTLER TOLEDO)
Electrode: LE438 composite electrode (manufactured by METTLER TOLEDO)
[試験例2]カリウム、カルシウム及びマグネシウム量の測定
加熱調理用液卵中のカリウム、カルシウム及びマグネシウム量は、キャピラリー電気泳動法を用いて間接吸光法により測定した。
<標準溶液>
1000ppmのアンモニア溶液0.5mLと、カリウムイオン、カルシウムイオン、マグネシウムイオンの各標準原液(1000ppm)0.5mLずつを、50mLのメスフラスコに入れてメスアップし、標準溶液とした。
<泳動試薬>
0.6mol/Lの2-ヒドロキシイソ酢酸1mL、0.8mol/Lのイミダゾール溶液0.5mL、1.2%18-CROWN-6.99%1mL、酢酸0.1mLを60mLのメスフラスコに入れてメスアップし、泳動試薬とした。
<測定装置>
機器:キャピラリー電気泳動装置CAPI‐3300(大塚電子(株)製)
キャピラリー:フューズドシリカ 内径100μm、外径0.375mm、長さ725mm
<測定条件>
使用ファイル:(新)陽イオン
検出波長:215nm
波長下限:200nm
波長上限:280nm
波長間隔:5nm
サンプル注入:落差25mm、30sec
泳動条件:定電圧15.0kV
分析時間:9~10分間
<測定方法>
加熱調理用液卵を100倍希釈した希釈液卵を試験溶液とし、標準添加法により測定した。[Test Example 2] Measurement of Potassium, Calcium and Magnesium Amounts The amounts of potassium, calcium and magnesium in liquid eggs for cooking were measured by an indirect absorption method using capillary electrophoresis.
<Standard solution>
0.5 mL of a 1000 ppm ammonia solution and 0.5 mL each of standard undiluted solutions (1000 ppm) of potassium ions, calcium ions and magnesium ions were placed in a 50 mL volumetric flask and diluted to obtain standard solutions.
<Electrophoresis reagent>
1 mL of 0.6 mol/L 2-hydroxyisoacetic acid, 0.5 mL of 0.8 mol/L imidazole solution, 1 mL of 1.2% 18-CROWN-6.99%, and 0.1 mL of acetic acid were placed in a 60 mL volumetric flask. It was made up to volume and used as an electrophoresis reagent.
<Measuring device>
Equipment: capillary electrophoresis apparatus CAPI-3300 (manufactured by Otsuka Electronics Co., Ltd.)
Capillary: fused silica inner diameter 100 μm, outer diameter 0.375 mm, length 725 mm
<Measurement conditions>
File used: (New) Positive ion detection wavelength: 215 nm
Lower wavelength limit: 200 nm
Upper wavelength limit: 280 nm
Wavelength interval: 5 nm
Sample injection: drop 25 mm, 30 sec
Electrophoresis conditions: constant voltage 15.0 kV
Analysis time: 9 to 10 minutes <Measurement method>
A diluted liquid egg obtained by diluting a liquid egg for cooking with heat 100 times was used as a test solution, and the measurement was performed by the standard addition method.
[試験例3]官能評価
官能評価は、実施例1~7及び比較例1~4の加熱調理用液卵を、下記の条件で加熱凝固させて得た蒸し卵焼きを専門パネル10名で食し、下記の評価基準に沿って評点し、その平均点を評価値とした。
<蒸し卵焼きの製造条件>
実施例1~7及び比較例1~4の加熱調理用液卵200mLを250mLのパウチに充填して密封し、85℃の湯につけて10分間加熱して、蒸し卵焼きを得た。
<評価基準>
5:やわらかい半熟様の食感が非常に好ましい
4:やわらかい半熟様の食感である
3:対照と同程度である
2:対照よりもやや硬く、やわらかい食感に乏しい
1:対照よりも硬く、ぼそぼそしている[Test Example 3] Sensory evaluation In the sensory evaluation, the liquid eggs for heat cooking of Examples 1 to 7 and Comparative Examples 1 to 4 were heated and coagulated under the following conditions. It was rated according to the following evaluation criteria, and the average score was used as the evaluation value.
<Conditions for producing steamed omelet>
200 mL of liquid eggs for heat cooking of Examples 1 to 7 and Comparative Examples 1 to 4 were filled in a 250 mL pouch, sealed, and immersed in hot water at 85° C. and heated for 10 minutes to obtain a steamed omelet.
<Evaluation Criteria>
5: Soft soft-boiled-like texture is very preferable 4: Soft soft-boiled-like texture 3: Similar to control 2: Slightly harder than control, poor soft texture 1: Harder than control, mumbling
表1より、酢酸と有機酸を含有させ、pHが5.5以上7以下である加熱調理用液卵を用いて製した蒸し卵焼き(実施例1~7)は、対照と比較してやわらかい半熟様の食感であった。特に、pHが6以上7以下、酢酸と有機酸の合計含有量が0.2以上2%以下、カリウム、カルシウム及びマグネシウムの合計含有量が200ppm以上である加熱調理用液卵を用いて製した蒸し卵焼き(実施例1~3、5、6)は、やわらかい半熟様の食感が非常に好ましいものであり、特に酢酸とグルコン酸を併用した加熱調理用液卵を用いて製した蒸し卵焼き(実施例1~3)は、卵の食味にも優れる好ましいものであった。From Table 1, it can be seen that the steamed eggs (Examples 1 to 7) made using liquid eggs for heat cooking containing acetic acid and organic acids and having a pH of 5.5 to 7 are soft and soft compared to the control. It tasted like you. In particular, it is prepared using a liquid egg for cooking with a pH of 6 or more and 7 or less, a total content of acetic acid and organic acids of 0.2 or more and 2% or less, and a total content of potassium, calcium and magnesium of 200 ppm or more. Steamed eggs (Examples 1 to 3, 5, 6) have a very preferable soft and soft-boiled texture. Examples 1 to 3) were preferable because the taste of eggs was excellent.
一方、酢酸のみを含有させた加熱調理用液卵を用いて製した蒸し卵焼き(比較例1)は、対照と同程度の食感ではあったが、部分的にゲル様の食感が感じられ、好ましいものではなかった。
有機酸のみを含有させた加熱調理用液卵を用いて製した蒸し卵焼き(比較例2、3)は対照よりも硬い食感となり、やわらかい食感に乏しいものであった。
酢酸と有機酸を併用し、pHが5.5未満である加熱調理用液卵を用いて製した蒸し卵焼き(比較例4)は、やわらかい食感は有するものの一部が十分に凝固せずに液状であり、酸のツンとした臭いも強く感じられ、卵焼きの食味として好ましいものではなかった。
グルコン酸カリウムを含有させ、pHが7を超える加熱調理用液卵を用いて製した蒸し卵焼き(比較例5)は、対照と比較して硬い食感となり、好ましくなかった。On the other hand, the steamed omelette (Comparative Example 1) prepared using a liquid egg for heat cooking containing only acetic acid had a texture similar to that of the control, but a gel-like texture was partially felt. , was not preferred.
Steamed omelettes prepared using liquid eggs for heat cooking containing only organic acids (Comparative Examples 2 and 3) had a harder texture than the control, and lacked a soft texture.
Steamed tamagoyaki (Comparative Example 4) made using a liquid egg for heat cooking with a combined use of acetic acid and an organic acid and a pH of less than 5.5 has a soft texture, but a part of it does not solidify sufficiently. It was liquid and had a strong acrid odor, which was not preferable as a taste for fried eggs.
The steamed omelet (Comparative Example 5) prepared using a liquid egg for cooking with a pH of over 7 and containing potassium gluconate had a harder texture than the control, which was not preferable.
[実施例8]
液全卵97.5%、グルコン酸酢2.5%及びカルシウム475ppmを混合し、本発明の加熱調理用液卵を得た。得られた加熱調理用液卵の酢酸含有量は1.1%、グルコン酸含有量は0.05%であった。
得られた加熱調理用液卵150g、和風だし65g、鶏肉100g、玉ねぎ100gを用意し、和風だし、鶏肉、玉ねぎを鍋に入れて火が通るまで加熱した後、加熱調理用液卵を回し入れてさらに5分間加熱し、親子丼の具を得た。
得られた親子丼の具は、やわらかい半熟様の食感であり、卵の食味にも優れる好ましいものであった。[Example 8]
97.5% liquid whole egg, 2.5% gluconic acid vinegar and 475 ppm calcium were mixed to obtain the liquid egg for heat cooking of the present invention. The obtained liquid egg for heat cooking had an acetic acid content of 1.1% and a gluconic acid content of 0.05%.
Prepare 150 g of the obtained liquid egg for cooking with heat, 65 g of Japanese-style broth, 100 g of chicken, and 100 g of onion, put the Japanese-style broth, chicken, and onion in a pot and heat until cooked, then add the liquid egg for cooking with heat. The mixture was further heated for 5 minutes to obtain ingredients for oyakodon.
The ingredients of the resulting oyakodon had a soft, half-boiled texture and an excellent taste of the egg, which was preferable.
Claims (5)
酢酸と、
有機酸としてグルコン酸を含有し、
前記酢酸及び前記有機酸の含有比が、1:0.01~1:1であり、
pHが5.5以上7以下である、
加熱調理用液卵。 A liquid egg for cooking with heat,
acetic acid;
containing gluconic acid as an organic acid ,
The content ratio of the acetic acid and the organic acid is 1:0.01 to 1:1,
pH is 5.5 or more and 7 or less,
Liquid egg for cooking with heat.
前記液卵全量に対して、
前記酢酸及び前記有機酸の合計含有量が0.01%以上2%以下である、
加熱調理用液卵。 In the liquid egg for heat cooking according to claim 1,
For the liquid egg total amount,
The total content of the acetic acid and the organic acid is 0.01% or more and 2% or less,
Liquid egg for cooking with heat.
カリウム、マグネシウム及びカルシウムの合計含有量が200ppm以上である、
加熱調理用液卵。 In the liquid egg for heat cooking according to claim 1 or 2,
The total content of potassium, magnesium and calcium is 200 ppm or more,
Liquid egg for cooking with heat.
卵焼成品。 Using the liquid egg for heat cooking according to any one of claims 1 to 3,
Baked eggs.
卵とじ。 Using the liquid egg for heat cooking according to any one of claims 1 to 4,
Egg binding.
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