JP7260860B2 - Serpentine-containing fiber and method for producing the same - Google Patents
Serpentine-containing fiber and method for producing the same Download PDFInfo
- Publication number
- JP7260860B2 JP7260860B2 JP2020020215A JP2020020215A JP7260860B2 JP 7260860 B2 JP7260860 B2 JP 7260860B2 JP 2020020215 A JP2020020215 A JP 2020020215A JP 2020020215 A JP2020020215 A JP 2020020215A JP 7260860 B2 JP7260860 B2 JP 7260860B2
- Authority
- JP
- Japan
- Prior art keywords
- serpentine
- fiber
- powder
- containing fiber
- chrysotile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 title claims description 55
- 239000000835 fiber Substances 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000000843 powder Substances 0.000 claims description 25
- 239000002657 fibrous material Substances 0.000 claims description 20
- 229910052620 chrysotile Inorganic materials 0.000 claims description 12
- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 claims description 12
- 229920000297 Rayon Polymers 0.000 claims description 10
- 239000002964 rayon Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000000047 product Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000010425 asbestos Substances 0.000 description 3
- 239000010450 olivine Substances 0.000 description 3
- 229910052609 olivine Inorganic materials 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910052895 riebeckite Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052898 antigorite Inorganic materials 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- 229910052899 lizardite Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- IBPRKWGSNXMCOI-UHFFFAOYSA-N trimagnesium;disilicate;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IBPRKWGSNXMCOI-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 206010027406 Mesothelioma Diseases 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical compound [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052655 plagioclase feldspar Inorganic materials 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910052611 pyroxene Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000002881 soil fertilizer Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Description
本発明は、繊維材料の改良、更に詳しくは、蛇紋石中のクリソタイルを除去して無害化することができ、かつ、繊維への含有量を大きくしても形態安定性に優れた蛇紋石含有繊維に関するものである。 The present invention is an improvement of fiber materials, more specifically, it is possible to remove chrysotile in serpentine to make it harmless, and even if the content in the fiber is increased, the serpentine containing serpentine has excellent shape stability. It relates to fibers.
保温性の高い布団やダウンジャケットには羽毛が使用されることも多いが、殺処分や動物アレルギーの問題などがあったことから、遠赤外線放射性を有するセラミック粉末等を含有した人造繊維、及びその人造繊維を用いた繊維製品がこれまでに多数開発されている（例えば、特許文献１または２参照）。 Feathers are often used for futons and down jackets with high heat retention. A large number of textile products using artificial fibers have been developed so far (see, for example, Patent Documents 1 and 2).
ところで、セラミックス粉末より優れた蓄熱性や遠赤外線放射性を有する天然鉱石として「蛇紋石」が知られており、カンラン岩（フォスライト）が地下深部で水分の作用を受けて変質したものである。 By the way, "serpentinite" is known as a natural ore having heat storage properties and far-infrared radiation properties superior to those of ceramic powder, and is obtained by altering peridotite (phoslite) under the action of moisture deep underground.
カンラン岩は地殻の岩石ではなくマントルを構成する主要な岩石であるため、地表に露出することは稀で、特殊な地域にしか分布しない。カンラン岩は、主にカンラン石と輝石が構成しており、斜長石やスピネルを含んでいることもある。色はカンラン石の色を反映した明るい緑色をしており、粗粒であるために、一つ一つの鉱物がはっきり肉眼で確認できることが多い。カンラン石は変質に弱く、変質すると蛇紋石になる。 Peridotite is not a crustal rock, but a major rock that constitutes the mantle. Peridotite is composed mainly of olivine and pyroxene, and may also contain plagioclase and spinel. Its color is a bright green that reflects the color of olivine, and because it is coarse-grained, individual minerals are often clearly visible with the naked eye. Olivine is vulnerable to alteration, and when altered, it becomes serpentine.
また、蛇紋石は、クリソタイル、アンチゴライト、リザルダイトの３種類の鉱物が主要構成物であるが、アンチゴライトとリザルダイトは、不定形状、板状の粒子形態であり、繊維状鉱物ではない。これら３種類の鉱物の構成比は、採掘される鉱脈によって異なる。 Serpentine is mainly composed of three types of minerals, chrysotile, antigorite, and lizardite, but antigorite and lizardite are in the form of amorphous plate-like particles and are not fibrous minerals. The composition ratio of these three types of minerals varies depending on the veins to be mined.
また、蛇紋石は比較的粉砕しやすいことから、製鉄用原料、道路・鉄道・建築用の砕石、土壌改良材や肥料などに現在も用いられている。 In addition, since serpentine is relatively easy to pulverize, it is still used as a raw material for iron manufacturing, crushed stone for roads, railways and construction, as a soil conditioner and fertilizer.
そしてまた、蛇紋石に含有するクリソタイル（アスベスト）は、耐熱性、耐摩擦性、耐薬品性などの工業的に優れた性質を有する繊維状鉱物であり、建材、摩擦材等の工業製品に長年用いられた。 Chrysotile (asbestos) contained in serpentine is a fibrous mineral with industrially superior properties such as heat resistance, friction resistance, and chemical resistance. used.
しかしながら、最近になりアスベスト暴露による中皮腫発症が明確となり、２００６年には国内では全面使用禁止となっており、蛇紋石粉末中にも、微量（５％未満）ではあるが、クリソタイルが含まれていることが分かっていることから、この蛇紋石粉末を人造繊維などの原料としてそのまま用いることには問題がある。 However, it has recently become clear that mesothelioma is caused by exposure to asbestos, and in 2006 the use of asbestos was completely banned in Japan. Therefore, it is problematic to use this serpentine powder as it is as a raw material for artificial fibers and the like.
また、通常の蛇紋石粉末では、繊維の形態安定性を維持するために、繊維素材に対して２～３重量％しか含有させることができず、蛇紋石の持つ蓄熱性や遠赤外線放射性などの効果を十分に発揮させることができないという問題がある。 In addition, in ordinary serpentine powder, in order to maintain the shape stability of the fiber, only 2 to 3% by weight can be contained in the fiber material, and the heat storage and far-infrared radiation properties of serpentine are reduced. There is a problem that the effect cannot be exhibited sufficiently.
さらに、通常の蛇紋石粉末を含有しても繊維の形態安定性が悪く、数ｃｍ程度の細切れの短い繊維長にしか成形することできないため、例えば、この繊維を使用した綿状体などを成形することができず、布団やダウンジャケットなどの詰め物としての使用ができず繊維製品の用途が限定されてしまうという不満がある。 Furthermore, even if ordinary serpentine powder is contained, the morphological stability of the fiber is poor, and it can only be formed into a short fiber length of about several cm. There is a dissatisfaction that the application of the textile product is limited because it cannot be used as a stuffing for futons, down jackets, and the like.
本発明は、従来の繊維材料に上記のような問題があったことに鑑みて為されたものであり、その目的とするところは、蛇紋石中のクリソタイルを除去して無害化することができ、かつ、繊維への含有量を大きくしても形態安定性に優れた蛇紋石含有繊維およびその製造方法を提供することにある。 The present invention has been made in view of the above-mentioned problems with conventional fiber materials, and the object thereof is to remove chrysotile in serpentine and render it harmless. And to provide a serpentine-containing fiber excellent in shape stability even when the content in the fiber is increased, and a method for producing the same.
本発明は、高温の焼成処理によりクリソタイルが除去され、かつ、微粉末状に粉砕処理された蛇紋石粉末を、繊維素材に含有させて繊維状に形成するという技術的手段を採用したことによって、蛇紋石含有繊維を完成させた。 The present invention employs a technical means of incorporating serpentine powder from which chrysotile has been removed by high-temperature firing and pulverized into fine powder into a fibrous material to form a fibrous form. A serpentine-containing fiber was completed.
また、本発明は、上記課題を解決するために、必要に応じて上記手段に加え、蛇紋石粉末の平均粒径を０．５μｍ以下にするという技術的手段を採用することもできる。 Moreover, in order to solve the above problems, the present invention can also adopt technical means of making the average particle size of the serpentine powder 0.5 μm or less in addition to the above means, if necessary.
更にまた、本発明は、上記課題を解決するために、必要に応じて上記手段に加え、蛇紋石を繊維素材に５重量％以上含有するという技術的手段を採用することもできる。 Furthermore, in order to solve the above-mentioned problems, the present invention can adopt technical means of containing 5% by weight or more of serpentine in the fibrous material, in addition to the above-mentioned means, if necessary.
更にまた、本発明は、上記課題を解決するために、必要に応じて上記手段に加え、繊維素材をポリエステル、あるいはレーヨンにするという技術的手段を採用することもできる。 Furthermore, in order to solve the above problems, the present invention can also employ technical means of using polyester or rayon as the fiber material in addition to the above means, if necessary.
また、本発明は、上記課題を解決するために、蛇紋石を高温で焼成してクリソタイルを除去し、かつ、微粉末状に粉砕して、
この蛇紋石粉末を繊維素材に混入して繊維状に形成するという技術的手段を採用することによって、蛇紋石含有繊維の製造方法を完成させた。
In addition, in order to solve the above problems, the present invention burns serpentine at a high temperature to remove chrysotile, and pulverizes it into fine powder,
By adopting the technical means of mixing this serpentine powder into a fibrous material and forming it into fibers, a method for producing serpentine-containing fibers has been completed.
また、本発明は、上記課題を解決するために、必要に応じて上記手段に加え、蛇紋石を１０００℃以上かつ６０分以上焼成するという技術的手段を採用することもできる。 Moreover, in order to solve the above problems, the present invention can adopt technical means of firing serpentine at 1000° C. or higher for 60 minutes or longer, in addition to the above means, if necessary.
本発明は、蛇紋石を高温で焼成してクリソタイルを除去し、かつ、微粉末状に粉砕して、この蛇紋石粉末を繊維素材に混入して繊維状に形成することによって、蛇紋石中のクリソタイルを除去して無害化することができ、かつ、繊維への含有量を大きくしても形態安定性に優れている。 In the present invention, serpentine is fired at a high temperature to remove chrysotile, pulverized into a fine powder, and the serpentine powder is mixed with a fiber material to form a fibrous material. It can remove chrysotile to make it harmless, and has excellent shape stability even when the content in the fiber is increased.
本発明の蛇紋石含有繊維は、最終製品ベースで最大１２％の含有量であっても、繊維としての高い形態安定性を維持できる。また、従来は鉱物等の添加物の含有量を大きくすると数ｃｍ程度の繊維長でしか形態を維持できなかったが、６ｃｍの繊維長でも優れた形態安定性を発揮することができる The serpentine-containing fibers of the present invention can maintain high dimensional stability as fibers even at contents of up to 12% based on the final product. In addition, conventionally, when the content of additives such as minerals is increased, the shape can be maintained only with a fiber length of about several cm, but even a fiber length of 6 cm can exhibit excellent shape stability.
したがって、本発明の蛇紋石含有繊維を使用して種々の繊維製品に用途を拡大することができ、特に、衣類や寝具類などの高い保温性が要求される物品の詰め物などに使用して繊維製品の用途を拡大することができることから、産業上の利用価値は頗る大きい。 Therefore, the serpentine-containing fiber of the present invention can be used to expand the application to various textile products. Since the application of the product can be expanded, the industrial utility value is extremely large.
本発明の実施形態を以下に説明する。本発明の蛇紋石含有繊維は、蛇紋石を高温で焼成してクリソタイルを除去し、かつ、微粉末状に粉砕して、この蛇紋石粉末を繊維素材に混入して繊維状に形成することによって構成されるものである。 Embodiments of the invention are described below. The serpentine-containing fiber of the present invention is produced by baking serpentine at a high temperature to remove chrysotile, pulverizing it into a fine powder, and mixing the serpentine powder into a fiber material to form a fiber. It is configured.
具体的な製造方法としては、まず、蛇紋石を５０～６０μｍ程度の粒径に予備粉砕した後、１０００℃以上かつ６０分以上焼成する。本実施形態では、１２００℃で２４時間の焼成処理を行う。こうすることにより、天然の蛇紋石に含まれていたクリソタイルをほぼ完全に除去することができる。この段階で、蛇紋石は結合分子の崩壊によって４５～５０μｍの粒径に細分化される。 As a specific manufacturing method, first, serpentine is pre-crushed to a particle size of about 50 to 60 μm, and then fired at 1000° C. or higher for 60 minutes or longer. In this embodiment, the baking treatment is performed at 1200° C. for 24 hours. By doing so, the chrysotile contained in the natural serpentine can be almost completely removed. At this stage, the serpentine is fragmented to a particle size of 45-50 μm by the breakdown of binding molecules.
そして、更に粉砕処理を行うことによって、蛇紋石粉末の平均粒径を０．５μｍ以下にし、より好ましくは、０．３～０．４μｍの範囲にする。粉砕処理には、ロールクラッシャーやボールミル、石臼式の粉挽き装置等を使用して微粉末状に成形する。 Further pulverization is performed to make the average particle size of the serpentine powder 0.5 μm or less, more preferably in the range of 0.3 to 0.4 μm. For pulverization, a roll crusher, a ball mill, a millstone-type pulverizer, or the like is used to form a fine powder.
次いで、本実施形態では、この蛇紋石粉末を繊維素材に５重量％以上含有させる。本実施形態の繊維素材としては、風合いや加工性の良さから、ポリエステルやレーヨンが好適である。 Next, in this embodiment, the fibrous material is made to contain 5% by weight or more of this serpentine powder. Polyester and rayon are suitable for the fiber material of the present embodiment because of their good texture and workability.
繊維素材をポリエステル樹脂にして蛇紋石含有繊維を形成する場合、蛇紋石粉末は、繊維製造工程中において混入することができる。例えば、原料の調整工程、重合工程などで３０～４０％をバインダー（ＰＢＴ等）に添加して、含有量の高いマスターバッチを製造し、これを通常のチップに混ぜて溶融紡糸したり、あるいは直接的に紡糸液に混合して湿式紡糸することもできる。 When polyester resin is used as the fibrous material to form serpentine-containing fibers, serpentine powder can be incorporated during the fiber manufacturing process. For example, 30 to 40% is added to a binder (PBT, etc.) in the raw material adjustment process, polymerization process, etc. to produce a masterbatch with a high content, which is mixed with ordinary chips and melt-spun, or It can also be mixed directly with the spinning solution and wet-spun.
ポリエステルを繊維素材として採用した場合における蛇紋石含有繊維の成分および含有量の分析結果を以下に示す。
成分 含有量（％）
酸化マグネシウム ３．３
二酸化ケイ素（シリカ） ２．８
酸化鉄（ＩＩＩ） ０．５
酸化カルシウム ０．２
酸化アルミニウム ０．１
酸化マンガン（ＩＩ） ＜０．１
酸化銅（ＩＩ） ＜０．１
酸化チタン（ＩＶ） ＜０．１
ポリエステル樹脂 約９３
その他、微量の金属酸化物を含む。
The analysis results of the component and content of the serpentine-containing fiber in the case of using polyester as the fiber material are shown below.
Component Content (%)
Magnesium oxide 3.3
Silicon dioxide (silica) 2.8
Iron (III) oxide 0.5
Calcium oxide 0.2
Aluminum oxide 0.1
Manganese (II) oxide <0.1
Copper(II) oxide <0.1
Titanium (IV) oxide <0.1
Polyester resin about 93
In addition, it contains trace amounts of metal oxides.
ポリエステル樹脂が約９３％であったことから、蛇紋石の主成分が約７％含有されていることが確認された。 Since the polyester resin was about 93%, it was confirmed that the main component of serpentine was about 7%.
こうして製造された蛇紋石含有繊維は、最終製品ベースで最大１２％の含有量であっても、繊維としての高い形態安定性を維持できることがわかった。また、従来は鉱物等の添加物の含有量を大きくすると数ｃｍ程度の繊維長でしか形態を維持できなかったが、本実施形態では、６ｃｍの繊維長でも十分な強度があり、優れた形態安定性を発揮することができる。 It has been found that the serpentine-containing fibers thus produced are able to maintain high dimensional stability as fibres, even at contents of up to 12% based on the final product. In addition, conventionally, when the content of additives such as minerals is increased, the shape can only be maintained with a fiber length of about several cm, but in the present embodiment, even a fiber length of 6 cm has sufficient strength and excellent shape. Stability can be exhibited.
したがって、本実施形態の蛇紋石含有繊維を使用して種々の繊維製品に用途を拡大することができ、特に、衣類や寝具類などの高い保温性が要求される物品の詰め物などに好適である。 Therefore, the serpentine-containing fiber of the present embodiment can be used to expand the application to various textile products, and is particularly suitable for filling articles such as clothing and bedding that require high heat retention. .
また、繊維素材としてレーヨンを採用する場合においては、ビスコースの製造からレーヨンの紡糸までの工程には公知の方法を使用することができる。即ち、パルプやセルロースを苛性ソーダで処理してアルカリセルロースを生成し、二硫化炭素と反応させてセルロース誘導体（セルロースザントゲン酸ソーダ）として、これを希アルカリ溶液に溶解してビスコースを得る。 When rayon is used as the fibrous material, known methods can be used for the steps from the production of viscose to the spinning of rayon. Specifically, pulp or cellulose is treated with caustic soda to produce alkali cellulose, reacted with carbon disulfide to form a cellulose derivative (sodium cellulose xanthate), and dissolved in a dilute alkaline solution to obtain viscose.
そして、このビスコースに前記のように製造した蛇紋石の微粉末を添加混入して、ミューラー浴（酸性浴）中にノズルから押し出して凝固させることによりレーヨン（本発明の蛇紋石粉末含有繊維）が完成する。 Then, the serpentine fine powder produced as described above is added to and mixed with this viscose, and rayon (the serpentine powder-containing fiber of the present invention) is obtained by extruding from a nozzle into a Muller bath (acid bath) and solidifying it. is completed.
本発明は、概ね上記のように構成されるが、図示の実施形態に限定されるものでは決してなく、「特許請求の範囲」の記載内において種々の変更が可能であって、例えば、繊維素材は、ポリエステルやレーヨンに限らず、ポリアミド系、ポリアクリロニトリル系、ポリビニル系、ポリウレタン系などの合成繊維や、アセテート系などの半合成繊維などを単独または複合的に採用することもできる。 Although the present invention is generally configured as described above, it is by no means limited to the illustrated embodiments, and various modifications are possible within the scope of the claims. is not limited to polyester or rayon, and synthetic fibers such as polyamide, polyacrylonitrile, polyvinyl and polyurethane, and semi-synthetic fibers such as acetate can be used singly or in combination.
また、焼成温度や焼成時間などの条件や、分量、大きさなども必要に応じて変更することができ、これら何れのものも本発明の技術的範囲に属する。 Moreover, the conditions such as the baking temperature and baking time, the amount, the size, etc., can be changed as needed, and all of these belong to the technical scope of the present invention.
Claims (7)
この蛇紋石粉末を繊維素材に混入して繊維状に形成することを特徴とする蛇紋石含有繊維の製造方法。 calcining serpentine at high temperature to remove chrysotile and pulverizing into fine powder;
A method for producing a serpentine-containing fiber, which comprises mixing the serpentine powder into a fiber material to form a fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020020215A JP7260860B2 (en) | 2020-02-08 | 2020-02-08 | Serpentine-containing fiber and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020020215A JP7260860B2 (en) | 2020-02-08 | 2020-02-08 | Serpentine-containing fiber and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2021123836A JP2021123836A (en) | 2021-08-30 |
| JP7260860B2 true JP7260860B2 (en) | 2023-04-19 |
Family
ID=77458317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020020215A Active JP7260860B2 (en) | 2020-02-08 | 2020-02-08 | Serpentine-containing fiber and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP7260860B2 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009072709A (en) | 2007-09-21 | 2009-04-09 | Nishimatsu Constr Co Ltd | Recycling method for waste containing asbestos |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2879024B2 (en) * | 1997-01-31 | 1999-04-05 | 株式会社ジェガラニン | A method for producing rayon having far-infrared radiation properties, antibacterial properties, deodorizing properties, fungicidal properties and insect repellency, and having an antistatic effect |
-
2020
- 2020-02-08 JP JP2020020215A patent/JP7260860B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009072709A (en) | 2007-09-21 | 2009-04-09 | Nishimatsu Constr Co Ltd | Recycling method for waste containing asbestos |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2021123836A (en) | 2021-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6753299B2 (en) | Composite silica proppant material | |
| US4954462A (en) | Microcrystalline alumina-based ceramic articles | |
| US9234127B2 (en) | Angular abrasive proppant, process for the preparation thereof and process for hydraulic fracturing of oil and gas wells | |
| US8614157B2 (en) | Sintered particles and methods for producing sintered particles from a slurry of an alumina-containing raw material | |
| CN105164229B (en) | Mine pit treatment fluid decomposability fiber, its manufacture method and mine pit processing method | |
| KR101559392B1 (en) | Method for manufacturing fiber containing ilite of nano particle and complex functional mineral | |
| WO2009020296A1 (en) | Method for producing textiles and masterbatch contained of powdered ore | |
| WO2017142439A1 (en) | Ceramic proppant and method for producing same | |
| CN101298707A (en) | Nano compound modified polyphenyl thioether fibre and preparing method thereof | |
| CN107445187A (en) | A kind of preparation method of oyster shell whiting modified calcium carbonate | |
| JP7260860B2 (en) | Serpentine-containing fiber and method for producing the same | |
| CN101982422A (en) | Method for preparing cobaltosic oxide with large grain size and high safety | |
| CN104805279A (en) | Magnesium-containing compounded additive and preparation method thereof | |
| CN104016367B (en) | Attapulgite clay after sodium | |
| CN101516803A (en) | Polycrystalline corundum fibers and method for the production thereof | |
| Visinescu et al. | Polysaccharides route: a new green strategy for metal oxides synthesis | |
| CN104004385B (en) | A kind of preparation method of the modified grammite for papermaking filler | |
| CN102764015B (en) | Products with quantum-energy core | |
| CN103305959A (en) | Nano TiO2 ceramic modified polyester staple fiber based on high-energy ball milling dispersion and preparation method of fiber | |
| KR101713548B1 (en) | Manufacturing method of functional fiber and the fiber | |
| CN104194418A (en) | Modified attapulgite with flame retardant property and preparation method thereof | |
| CN109603300A (en) | The method of low-grade diatomite production low bulk density composite filter aid | |
| CN102676151A (en) | Ultra-low-density ceramic proppant taking pebbles as main additive and preparation method thereof | |
| CN1290794C (en) | Preparing method for ultra-fine tourmaline powder material | |
| KR100936293B1 (en) | Manufacturing method of chalk using naturalminerals |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220314 |
|
| TRDD | Decision of grant or rejection written | ||
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20230322 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20230323 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20230324 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7260860 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |