JP7392977B2 - Manufacturing method of sheet material - Google Patents
Manufacturing method of sheet material Download PDFInfo
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- JP7392977B2 JP7392977B2 JP2019213792A JP2019213792A JP7392977B2 JP 7392977 B2 JP7392977 B2 JP 7392977B2 JP 2019213792 A JP2019213792 A JP 2019213792A JP 2019213792 A JP2019213792 A JP 2019213792A JP 7392977 B2 JP7392977 B2 JP 7392977B2
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- 238000004519 manufacturing process Methods 0.000 title claims description 16
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- 239000000834 fixative Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 27
- 238000007906 compression Methods 0.000 claims description 25
- 230000006835 compression Effects 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
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- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
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- 235000005822 corn Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
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- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
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- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
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Landscapes
- Floor Finish (AREA)
- Treatment Of Fiber Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は、シート材の製造方法に関する。 The present invention relates to a method for manufacturing a sheet material.
麻、葛及び木綿等の植物を組織に含む織編物が様々な用途で広く用いられている。緯糸をい草の茎とし、経糸を麻糸又は綿糸として織られた織編物が畳表である。特許文献1には、絵柄図柄の印刷を容易にするために、畳表を表裏から圧縮して板状に圧縮する方法が開示されている。当該畳表の製造方法では、あらかじめ表面及び裏面に固着剤を塗布した畳表が圧縮プレス機にかけられる。 Woven and knitted fabrics containing plants such as hemp, kudzu, and cotton in their tissues are widely used for various purposes. Tatami omote is a woven or knitted fabric that uses rush stems as the weft and linen or cotton yarn as the warp. Patent Document 1 discloses a method of compressing a tatami mat from the front and back into a plate shape in order to facilitate printing of patterns. In the method for producing tatami mats, a tatami mat surface whose front and back surfaces are coated with a fixing agent in advance is subjected to a compression press.
特許文献1に開示された製造方法によれば、圧縮後の畳表の膨張が固着剤によってある程度は抑制されるが、天然い草の膨張作用は強いため十分ではない。しかも圧縮前に固着剤を畳表に塗布するため、圧縮プレス機に固着剤が付着し、固着剤が畳表の表面及び裏面に均一に付着しないおそれがある。 According to the manufacturing method disclosed in Patent Document 1, the expansion of the tatami surface after compression is suppressed to some extent by the adhesive agent, but this is not sufficient because the expansion effect of natural rush is strong. Moreover, since the adhesive is applied to the tatami facing surface before compression, the adhesive may adhere to the compression press and may not adhere uniformly to the front and back surfaces of the tatami mat surface.
本発明は、上記実情に鑑みてなされたものであり、植物を組織に含む織編物を圧縮したシート材における圧縮後の復元を極力抑えることができるシート材の製造方法を提供することを目的とする。 The present invention has been made in view of the above-mentioned circumstances, and an object of the present invention is to provide a method for manufacturing a sheet material that can suppress as much as possible the restoration after compression of a sheet material made of a compressed woven or knitted fabric containing plants in its tissue. do.
本発明に係るシート材の製造方法は、
植物を組織に含む布状の織編物を加熱しながら表裏方向に圧縮する圧縮工程と、
圧縮された前記織編物に固定剤を塗布する塗布工程と、
を含む。
The method for manufacturing a sheet material according to the present invention includes:
A compression process in which a cloth-like woven or knitted fabric containing plants in its tissue is compressed from front to back while being heated;
an application step of applying a fixing agent to the compressed woven or knitted fabric;
including.
この場合、前記織編物は、
畳表である、
こととしてもよい。
In this case, the woven or knitted fabric is
It is a tatami mat,
It may also be a thing.
また、前記圧縮工程では、前記織編物を60~110℃に加熱する、
こととしてもよい。
Further, in the compression step, the woven or knitted fabric is heated to 60 to 110°C.
It may also be a thing.
また、前記圧縮工程では、前記織編物に30~300kg/cm2の圧力をかける、
こととしてもよい。
Further, in the compression step, a pressure of 30 to 300 kg/cm 2 is applied to the woven or knitted fabric.
It may also be a thing.
また、前記塗布工程では、
前記織編物に複数種の固定剤を積層させる、
こととしてもよい。
Furthermore, in the coating step,
laminating multiple types of fixatives on the woven or knitted fabric;
It may also be a thing.
本発明によれば、植物を組織に含む織編物を圧縮したシート材における圧縮後の復元を極力抑えることができる。 According to the present invention, recovery after compression of a sheet material obtained by compressing a woven or knitted fabric containing plants in its tissue can be suppressed as much as possible.
本発明に係る実施の形態について説明する。なお、本発明は下記の実施の形態によって限定されるものではない。 Embodiments according to the present invention will be described. Note that the present invention is not limited to the embodiments described below.
(実施の形態)
本実施の形態に係るシート材の製造方法は、圧縮工程と、塗布工程とを含む。圧縮工程では、植物を組織に含む布状の織編物を加熱しながら表裏方向に圧縮する。植物は、織編物の組織となるものであれば特に限定されない。植物としては、い草、大麻、亜麻、葛、楮、木綿、バショウケナフ、ジュート麻、マニラ麻、サイザル麻、雁皮、三椏、バナナ、パイナップル、ココヤシ、トウモロコシ、サトウキビ、バガス、ヤシ、パピルス、葦、エスパルト、サバイグラス、麦、稲、竹、針葉樹、広葉樹及び綿花等が挙げられる。繊維(糸)として利用できる部分であれば植物の任意の部位、例えば、非木質部、茎部、根部、葉部及び木質部等が用いられる。好ましくは、植物はい草の茎である。
(Embodiment)
The method for manufacturing a sheet material according to this embodiment includes a compression step and a coating step. In the compression step, a cloth-like woven or knitted fabric containing plants in its tissue is compressed from front to back while being heated. The plant is not particularly limited as long as it forms the structure of the woven or knitted fabric. Plants include rush, hemp, flax, kudzu, kozo, cotton, kenaf, jute hemp, Manila hemp, sisal, gampi, mitsumata, banana, pineapple, coconut palm, corn, sugarcane, bagasse, palm, papyrus, reed, and esparto. , Sabai grass, wheat, rice, bamboo, coniferous trees, broad-leaved trees, cotton, and the like. Any part of the plant that can be used as fiber (thread) can be used, such as non-woody parts, stems, roots, leaves, and woody parts. Preferably, it is the stem of the rush plant.
織編物は、繊維が組織を形成するものであって、例えば織物又は編物である。織物は経糸及び緯糸が交差して組織が形成されている。織物は、平織、綾織及び朱子織のいずれでもよい。編物はループによって組織が形成されている。織編物は表面及び裏面を有する布状であればよく、表面又は裏面からの平面視での織編物の形状は特に限定されない。織編物は単色に限らず複色であってもよいし、公知の加工技術で織編物の表面に図柄等を付与してもよい。好適には、織編物は畳表である。 A woven or knitted fabric is one in which fibers form a structure, such as a woven fabric or a knitted fabric. A texture of a woven fabric is formed by intersecting warp and weft threads. The woven fabric may be plain weave, twill weave, or satin weave. The texture of knitted fabrics is formed by loops. The woven or knitted fabric may be cloth-like as long as it has a front surface and a back surface, and the shape of the woven or knitted material in plan view from the front or back surface is not particularly limited. The woven or knitted fabric is not limited to a single color, but may be of multiple colors, and a pattern or the like may be added to the surface of the woven or knitted fabric using known processing techniques. Preferably, the woven or knitted fabric is a tatami mat.
圧縮工程では、織編物を60~110℃、70~100℃、好ましくは90~100℃に加熱する。圧縮工程では、加熱プレス機等を用いて、織編物を加熱すると同時に、織編物を表裏方向に圧縮する。圧力の大きさは、例えば織編物1cm2あたり10~500kg、15~450kg、20~400kg、25~350kg、30~300kg又は35~200kgであってもよいし、20~80kg、30~60kg又は35~45kgであってもよい。圧力の大きさは、0.5~50MPa、1.5~45MPa、2~40MPa、2.5~35MPa、3~30MPa又は3.5~20MPaであってもよいし、2~8MPa、3~6MPa又は4~5MPaであってもよい。圧縮する時間は、織編物の厚み及び材質等に応じて、適宜調整される。織編物が畳表の場合、圧縮工程によって、織編物の表面の凹凸がなくなり、織編物の厚みは圧縮工程の前の厚みの約1/3となる。 In the compression step, the woven or knitted fabric is heated to 60-110°C, 70-100°C, preferably 90-100°C. In the compression step, the woven or knitted fabric is heated using a heating press or the like, and at the same time, the woven or knitted fabric is compressed in the front and back directions. The magnitude of the pressure may be, for example, 10 to 500 kg, 15 to 450 kg, 20 to 400 kg, 25 to 350 kg, 30 to 300 kg, or 35 to 200 kg, or 20 to 80 kg, 30 to 60 kg, or It may be 35-45 kg. The magnitude of the pressure may be 0.5 to 50 MPa, 1.5 to 45 MPa, 2 to 40 MPa, 2.5 to 35 MPa, 3 to 30 MPa, or 3.5 to 20 MPa, or 2 to 8 MPa, 3 to 20 MPa. It may be 6 MPa or 4 to 5 MPa. The compression time is appropriately adjusted depending on the thickness and material of the woven or knitted fabric. When the woven or knitted fabric has a tatami facing surface, the compression process eliminates unevenness on the surface of the woven or knitted fabric, and the thickness of the woven or knitted fabric becomes about 1/3 of the thickness before the compression process.
塗布工程では、圧縮された織編物に固定剤を塗布する。固定剤は、織編物の表面又は裏面に塗布してもよいし、表面と裏面の両方に塗布してもよい。固定剤は、織編物を圧縮された状態で固めるものであれば特に限定されない。固定剤は、例えばウレタン、アクリル及びエステル等の樹脂を含むコーティング剤である。好適には、固定剤はウレタン樹脂塗料等の合成樹脂塗料又は油性塗料である。合成樹脂塗料には、例えばウレタン樹脂の他に、酢酸エチル、酢酸ブチル、油脂、ワックス及び脂肪性ホワイトスピリット等が含まれていてもよい。好ましくは、固定剤は液体である。固定剤の用量は、固定剤の種類又はシート材の用途に応じて適宜設定される。液体の固定剤を用いる場合、固定剤の用量は、織編物1cm2あたり0.1~100mL、0.5~50mL又は1~10mLである。なお、固定剤を塗布する前に織編物を放熱させてもよいし、冷却してもよい。 In the application step, a fixative is applied to the compressed woven or knitted fabric. The fixative may be applied to the front or back side of the woven or knitted fabric, or to both the front and back sides. The fixing agent is not particularly limited as long as it can solidify the woven or knitted fabric in a compressed state. The fixative is a coating agent containing resins such as urethane, acrylic, and ester. Preferably, the fixative is a synthetic resin paint, such as a urethane resin paint, or an oil-based paint. The synthetic resin paint may contain, for example, ethyl acetate, butyl acetate, oil, wax, fatty white spirit, etc. in addition to the urethane resin. Preferably the fixative is a liquid. The dosage of the fixative is appropriately set depending on the type of fixative or the use of the sheet material. If a liquid fixative is used, the dose of the fixative is 0.1-100 mL, 0.5-50 mL or 1-10 mL per cm 2 of woven or knitted fabric. Note that the woven or knitted fabric may be allowed to radiate heat or may be cooled before applying the fixative.
固定剤として天然素材の固定剤を用いてもよい。天然素材の固定剤としては、例えば膠、カゼイン、澱粉、天然ゴム及び漆等が挙げられる。固定剤は、複数の天然素材を混合したものでもよい。例えば、膠と澱粉とを混合した固定剤が使用できる。織編物が畳表の場合、天然素材の固定剤を用いることで、い草が有する有害物質吸着機能等を、シート材が維持することができる。 A fixative made of natural materials may be used as the fixative. Examples of natural fixatives include glue, casein, starch, natural rubber, and lacquer. The fixative may be a mixture of multiple natural materials. For example, a fixative containing a mixture of glue and starch can be used. When the woven or knitted fabric is a tatami surface, by using a fixative made of natural materials, the sheet material can maintain the harmful substance adsorption function of rush.
塗布工程では、固定剤の他に、任意の表面処理剤を織編物に塗布してもよい。シート材の用途に応じて、織編物の表面をさらに加工処理してもよい。例えば、シート材が壁紙又は天井用壁等に用いられる場合は、撥水性付与剤、退色防止剤、防カビ剤及び光沢付与剤等を織編物に塗布してもよい。撥水性付与剤としては、高級脂肪酸塩類、高級脂肪酸アマイド類、ワックス類、シリコンオイル又はこれらの混合物等が挙げられる。退色防止剤は、光照射による退色並びにオゾン、活性酸素、NOx及びSOx等の各種の酸化性ガスによる退色を抑制するものあって、例えば、グリシン、アラニン及びグルタミン酸等のアミノ酸、サリチル酸並びにその塩等である。光沢付与剤としては、脂肪酸エチレングリコールエステル、脂肪酸ポリエチレングリコールエステル及び脂肪酸モノエタノールアミド等が挙げられる。 In the coating step, an arbitrary surface treatment agent may be applied to the woven or knitted fabric in addition to the fixing agent. Depending on the use of the sheet material, the surface of the woven or knitted material may be further processed. For example, when the sheet material is used for wallpaper, ceiling walls, etc., a water repellent agent, an anti-fading agent, a fungicide, a gloss agent, etc. may be applied to the woven or knitted fabric. Examples of the water repellent agent include higher fatty acid salts, higher fatty acid amides, waxes, silicone oil, and mixtures thereof. Antifading agents suppress discoloration due to light irradiation and discoloration due to various oxidizing gases such as ozone, active oxygen, NOx, and SOx, and include amino acids such as glycine, alanine, and glutamic acid, salicylic acid, and salts thereof, etc. It is. Examples of the brightening agent include fatty acid ethylene glycol ester, fatty acid polyethylene glycol ester, fatty acid monoethanolamide, and the like.
シート材が床に用いられる場合は、撥水性付与剤、強度増強剤及び耐摩耗性付与剤等を織編物に塗布してもよい。強度増強剤としては、例えば、ポリエチレンイミン、ポリアミドポリアミンエピクロルヒドリン、尿素樹脂及びメラミン樹脂等が挙げられる。耐摩耗性付与剤としては、例えば、硬質の充填剤粉末、アルミナ及びフッ素樹脂粉末等が挙げられる。また、吸着剤を織編物に塗布することで、有害物質を吸着する機能をシート材に付与することもできる。吸着剤は、例えば、活性炭、合成ゼオライト及び多孔性粘土成分等である。なお、表面処理剤、例えば上記の撥水性付与剤、退色防止剤、防カビ剤、光沢付与剤、強度増強剤又は耐摩耗性付与剤は、固定剤としても使用され得る。 When the sheet material is used for a floor, a water repellent agent, a strength enhancer, an abrasion resistance agent, etc. may be applied to the woven or knitted fabric. Examples of the strength enhancer include polyethyleneimine, polyamide polyamine epichlorohydrin, urea resin, and melamine resin. Examples of the wear resistance imparting agent include hard filler powder, alumina, and fluororesin powder. Furthermore, by applying an adsorbent to a woven or knitted fabric, the sheet material can be given the ability to adsorb harmful substances. Adsorbents include, for example, activated carbon, synthetic zeolites, porous clay components, and the like. Note that the surface treatment agent, such as the above-mentioned water repellency imparting agent, anti-fading agent, fungicide, gloss imparting agent, strength enhancer or abrasion resistance imparting agent, may also be used as a fixing agent.
塗布工程では、織編物に複数種の固定剤を積層させてもよい。この場合、塗布工程は、第1の固定剤を織編物に塗布する第1の塗布工程と、第1の固定剤と異なる第2の固定剤を前記第1の固定剤の上に塗布する第2の塗布工程と、を含む。第1の塗布工程と第2の塗布工程との間に、第1の固定剤を乾燥させる乾燥工程があってもよい。固定剤は3種以上であってもよく、固定剤に順次上塗りされて、複数種の固定剤が積層される。複数種の固定剤を積層させる場合、織編物を下として最上層の固定剤は、強度が高く、耐摩耗性に優れる樹脂等が好ましい。最上層の固定剤は、例えば、撥水性付与剤、強度増強剤及び耐摩耗性付与剤等の少なくとも1つを含有する固定剤であってもよい。最上層を強度が高く、耐摩耗性に優れる固定剤の層とすることで、床への使用に適したシート材を製造することができる。 In the coating step, a plurality of types of fixatives may be layered on the woven or knitted fabric. In this case, the application process includes a first application process of applying a first fixative to the woven or knitted fabric, and a second application process of applying a second fixative different from the first fixative onto the first fixative. 2 coating process. There may be a drying step of drying the first fixing agent between the first coating step and the second coating step. There may be three or more types of fixatives, and the fixatives are sequentially overcoated to form a layer of multiple types of fixatives. When multiple types of fixatives are laminated, the fixing agent in the uppermost layer with the woven or knitted fabric at the bottom is preferably a resin or the like that has high strength and excellent abrasion resistance. The fixing agent in the uppermost layer may be a fixing agent containing at least one of a water repellency imparting agent, a strength enhancer, an abrasion resistance imparting agent, and the like. By using a fixing agent layer with high strength and excellent abrasion resistance as the top layer, a sheet material suitable for use on floors can be manufactured.
以上詳細に説明したように、本実施の形態に係るシート材の製造方法によれば、織編物を加熱しながら圧縮するため、植物を組織に含む布状の織編物を十分に圧縮することができる。また、圧縮後に固定剤を織編物に塗布するため、固定剤を効率よく均一に織編物の表面に拡げることができる。こうすることで、植物を組織に含む布状の織編物における圧縮後の復元を極力抑えることができる。 As explained in detail above, according to the method for manufacturing a sheet material according to the present embodiment, the woven or knitted fabric is compressed while being heated, so that the fabric-like woven or knitted fabric containing plants in its tissue can be sufficiently compressed. can. Furthermore, since the fixative is applied to the woven or knitted fabric after compression, the fixative can be efficiently and uniformly spread over the surface of the woven or knitted fabric. By doing so, it is possible to suppress the restoration after compression of the cloth-like woven or knitted fabric containing plants in its tissue as much as possible.
なお、本実施の形態に係るシート材の製造方法は、圧縮工程の前又は圧縮工程と塗布工程のとの間に、織編物に着色する着色工程をさらに含んでもよい。着色工程では、例えば着色料を織編物に接触させればよい。また、本実施の形態に係るシート材の製造方法は、圧縮工程の前、圧縮工程と塗布工程のとの間、又は塗布工程の後に、表面処理工程をさらに含んでもよい。表面処理工程では、光を反射するラメ又は着色料を織編物に塗布してもよいし、球体、多面体、粉体、綿状及び線状等の装飾材又は植物の一部、例えば植物の粉体等を表面に固定してもよい。塗布工程の後に表面処理工程を行った場合、表面処理工程に続いて、さらに上述の塗布工程を行って、織編物に固定剤を塗布してもよい。 Note that the method for manufacturing a sheet material according to the present embodiment may further include a coloring step of coloring the woven or knitted fabric before the compression step or between the compression step and the coating step. In the coloring step, for example, a coloring agent may be brought into contact with the woven or knitted fabric. Moreover, the method for manufacturing a sheet material according to the present embodiment may further include a surface treatment step before the compression step, between the compression step and the coating step, or after the coating step. In the surface treatment step, a light-reflecting glitter or colorant may be applied to the woven or knitted fabric, or decorative materials such as spheres, polyhedrons, powders, cotton-like and linear forms, or parts of plants, such as plant powder, may be applied to the woven or knitted fabric. A body etc. may be fixed to the surface. When the surface treatment step is performed after the application step, the above-mentioned application step may be further performed following the surface treatment step to apply the fixing agent to the woven or knitted fabric.
本発明は、本発明の広義の精神と範囲を逸脱することなく、様々な実施の形態及び変形が可能とされるものである。また、上述した実施の形態は、本発明を説明するためのものであり、本発明の範囲を限定するものではない。すなわち、本発明の範囲は、実施の形態ではなく、特許請求の範囲によって示される。そして、特許請求の範囲内及びそれと同等な発明の意義の範囲内で施される様々な変形が、本発明の範囲内とみなされる。 The present invention is capable of various embodiments and modifications without departing from the broad spirit and scope of the invention. Further, the embodiments described above are for explaining the present invention, and do not limit the scope of the present invention. That is, the scope of the present invention is indicated by the claims rather than the embodiments. Various modifications made within the scope of the claims and the meaning of the invention equivalent thereto are considered to be within the scope of the present invention.
本発明は、植物を組織に含む布状の織編物を加工したシート材の製造に好適である。 INDUSTRIAL APPLICATION This invention is suitable for manufacturing the sheet material processed from the cloth-like woven or knitted fabric which contains a plant in its tissue.
Claims (5)
圧縮された前記織編物に固定剤を塗布する塗布工程と、
を含む、シート材の製造方法。 A compression process in which a cloth-like woven or knitted fabric containing plants in its tissue is compressed from front to back while being heated;
an application step of applying a fixing agent to the compressed woven or knitted fabric;
A method of manufacturing a sheet material, including:
畳表である、
請求項1に記載のシート材の製造方法。 The woven or knitted fabric is
It is a tatami mat,
A method for manufacturing a sheet material according to claim 1.
請求項1又は2に記載のシート材の製造方法。 In the compression step, the woven or knitted fabric is heated to 60 to 110°C.
The method for manufacturing a sheet material according to claim 1 or 2.
請求項1から3のいずれか一項に記載のシート材の製造方法。 In the compression step, a pressure of 30 to 300 kg/cm 2 is applied to the woven or knitted fabric.
The method for manufacturing a sheet material according to any one of claims 1 to 3.
前記織編物に複数種の固定剤を積層させる、
請求項1から4のいずれか一項に記載のシート材の製造方法。 In the coating step,
laminating multiple types of fixatives on the woven or knitted fabric;
The method for manufacturing a sheet material according to any one of claims 1 to 4.
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