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JP7461127B2 - Oil-in-water emulsion composition for foaming cake dough - Google Patents
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JP7461127B2 - Oil-in-water emulsion composition for foaming cake dough - Google Patents

Oil-in-water emulsion composition for foaming cake dough Download PDF

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JP7461127B2
JP7461127B2 JP2019184820A JP2019184820A JP7461127B2 JP 7461127 B2 JP7461127 B2 JP 7461127B2 JP 2019184820 A JP2019184820 A JP 2019184820A JP 2019184820 A JP2019184820 A JP 2019184820A JP 7461127 B2 JP7461127 B2 JP 7461127B2
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JP2020058348A (en
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渉 会田
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D13/00Finished or partly finished bakery products
    • A21D13/80Pastry not otherwise provided for elsewhere, e.g. cakes, biscuits or cookies
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Edible Oils And Fats (AREA)

Description

本発明は、ケーキ生地起泡用水中油型乳化組成物に関する。 The present invention relates to an oil-in-water emulsion composition for foaming cake dough.

ケーキ類は、小麦粉、卵、糖類、油脂等を原料としてケーキ生地を調製し、このケーキ生地を焼成して製造される。ケーキ類は一般に、比容積が大きく、ふんわりとした食感のものが好まれる。この食感を達成するためには、ケーキ生地を十分に起泡させることが重要であり、通常、多量の空気を包み込むことができる卵がその役割を担っている。
一方、比容積及び食感の更なる向上のために、ケーキ生地に、さらに起泡性の乳化組成物を配合することも知られている。この乳化組成物として、グリセリン脂肪酸モノエステルを主な成分として含有するものが広く用いられている。
Cakes are produced by preparing cake batter using ingredients such as flour, eggs, sugar, oils and fats, and baking the cake batter. Cakes are generally preferred to have a large specific volume and a fluffy texture. To achieve this texture, it is important to foam the cake batter sufficiently, and usually eggs, which can enclose a large amount of air, play this role.
On the other hand, it is also known to further improve the specific volume and texture by blending a foaming emulsion composition into the cake dough, and as such an emulsion composition, one containing glycerin fatty acid monoester as a main component is widely used.

グリセリン脂肪酸モノエステル(モノアシルグリセロール)は、α結晶(αゲル)の状態では起泡力及びこれを維持する力が高いものの、β結晶(βゲル)に転移した後には、起泡力等が大きく低下する。そこで、モノアシルグリセロールのαゲルの状態を維持するために、モノアシルグリセロールに加えてソルビトールを含有させた乳化組成物からなる起泡剤が提案されている(例えば特許文献1~3参照)。 Glycerin fatty acid monoester (monoacylglycerol) has high foaming power and ability to maintain this foaming power in the α crystal (α gel) state, but after transitioning to β crystal (β gel), foaming power etc. is greatly reduced. Therefore, in order to maintain the α gel state of monoacylglycerol, a foaming agent consisting of an emulsion composition containing sorbitol in addition to monoacylglycerol has been proposed (see, for example, Patent Documents 1 to 3).

特開昭57-22640号公報Japanese Patent Application Laid-Open No. 57-22640 特開2002-247952号公報Japanese Patent Application Publication No. 2002-247952 特開2004-329156号公報JP 2004-329156 A

しかし、特許文献1~3に開示されている気泡剤は含水量が多く、ケーキ生地を充分に起泡させるためには、より多量の気泡剤を添加する必要がある。また、これらの起泡剤は、添加した起泡剤が生地全体に広がり生地が充分に起泡するのに相応の時間を要する。 However, the foaming agents disclosed in Patent Documents 1 to 3 have a high water content, and in order to adequately foam the cake batter, a larger amount of foaming agent must be added. In addition, it takes a considerable amount of time for the foaming agent to spread throughout the batter and for the batter to be adequately foamed.

乳化組成物は温度条件などが乳化安定性に影響し、保存中に構成成分の分離、相状態の変化、及び変色が起こりやすい傾向にある。乳化状態や相状態が崩れてしまうと起泡作用が大きく低下する。したがって、乳化組成物からなる起泡剤には長期に亘り起泡作用を安定に発現できる特性が求められる。 Temperature conditions and other factors affect the emulsion stability of emulsion compositions, and the components tend to separate, change in phase state, and discolor during storage. If the emulsion state or phase state is disrupted, the foaming action is greatly reduced. Therefore, foaming agents made from emulsion compositions are required to have the ability to stably exert foaming action over a long period of time.

本発明は、ケーキ生地に対する優れた起泡作用を長期に亘り安定に発現することでき、長期保管されても外観が変色せず乳化状態も安定であり、ケーキ生地の製造時に速やかに起泡し、焼き上がったケーキをバラケが良く、口溶け良好な食感とすることができるケーキ生地起泡用水中油型乳化組成物の提供に関する。 The present invention can stably exhibit an excellent foaming effect on cake batter over a long period of time, does not discolor in appearance even after long-term storage, and has a stable emulsified state, and can be quickly foamed during the production of cake batter. The present invention relates to an oil-in-water emulsion composition for foaming cake dough, which can give a baked cake a texture with good flakiness and melt-in-the-mouth texture.

本発明者らは上記課題に鑑み、鋭意検討を行った。その結果、飽和脂肪酸を構成脂肪酸とするモノアシルグリセロールを特定量含有し、かつ、油脂の含有量を抑えた油相を分散相とし、特定炭素数の糖アルコールとショ糖脂肪酸エステルと水とを特定量組合せて含有する水相を連続相として有する水中油型乳化組成物が、長期保存安定性に優れ、ケーキ生地に対する起泡作用を長期に亘り安定に発現でき、ケーキ生地の製造時に速やかに起泡し、かつ焼き上がったケーキはバラケが良く、口溶け良好な食感を有することを見出した。
本発明はこれらの知見に基づき完成されるに至ったものである。
In view of the above problems, the present inventors have conducted extensive research and have found that an oil-in-water emulsion composition containing a specific amount of monoacylglycerol having saturated fatty acids as its constituent fatty acids, an oil phase having a reduced content of fats and oils as a dispersed phase, and an aqueous phase containing a specific amount of a sugar alcohol having a specific carbon number, a sucrose fatty acid ester, and water in combination as a continuous phase, has excellent long-term storage stability, can stably exert a foaming effect on cake batter for a long period of time, foams quickly during the preparation of the cake batter, and produces baked cakes that break apart easily and have a texture that melts easily in the mouth.
The present invention has been completed based on these findings.

本発明は、A:飽和脂肪酸を構成脂肪酸とするモノアシルグリセロール(以下、「飽和モノアシルグリセロール」、「成分A」とも称す。)、B:炭素数6以上の糖アルコール(以下、「成分B」とも称す。)、C:ショ糖脂肪酸エステル(以下、「成分C」とも称す。)、D:水(以下、「成分D」とも称す。)を含有し、前記成分Bの含有量が20~65質量%、前記成分Dの含有量が10~30質量%、前記成分Aの含有量に対する前記成分Cの含有量の比の値が質量比で0.45~1.5であり、油脂の含有量が2.0質量%以下である、ケーキ生地起泡用水中油型乳化組成物を提供するものである。 The present invention is characterized in that A: monoacylglycerol whose constituent fatty acids are saturated fatty acids (hereinafter also referred to as "saturated monoacylglycerol" or "component A"), B: sugar alcohol having 6 or more carbon atoms (hereinafter referred to as "component B"). ), C: sucrose fatty acid ester (hereinafter also referred to as "component C"), D: water (hereinafter also referred to as "component D"), and the content of component B is 20%. -65% by mass, the content of the component D is 10-30% by mass, the ratio of the content of the component C to the content of the component A is 0.45-1.5 in mass ratio, and the content of the component D is 10-30% by mass. To provide an oil-in-water emulsion composition for foaming cake dough, the content of which is 2.0% by mass or less.

本発明のケーキ生地起泡用水中油型乳化組成物は、ケーキ生地に対する優れた起泡作用を長期に亘り安定に維持することができ、長期保管されても外観が変色せず乳化状態も安定であり、ケーキ生地の製造時に速やかに起泡し、得られるケーキをバラケが良く、口溶け良好な食感とすることができる。また、本発明のケーキは、バラケが良く、口溶け良好な食感を有している。 The oil-in-water emulsion composition for foaming cake batter of the present invention can stably maintain its excellent foaming effect on cake batter for a long period of time, does not discolor the appearance even when stored for a long period of time, and has a stable emulsified state. It foams quickly during the production of cake batter, and the resulting cake has good crumbling and a texture that melts easily in the mouth. The cake of the present invention also has a texture that crumbles easily and melts easily in the mouth.

本発明のケーキ生地起泡用水中油型乳化組成物(以下、単に、本発明の乳化組成物と呼ぶことがある。)について、好ましい実施形態を以下に説明する。 A preferred embodiment of the oil-in-water emulsion composition for whipping cake batter of the present invention (hereinafter, sometimes simply referred to as the emulsion composition of the present invention) is described below.

本発明の乳化組成物に含まれる成分A(飽和モノアシルグリセロール)は、グリセリンが有する3つのヒドロキシ基のいずれか1つと、飽和脂肪酸が有するカルボキシル基とがエステル結合した構造を有するモノエステル化合物である。飽和脂肪酸が結合するグリセリンのヒドロキシ基は、α-位であってもβ-位であってもよいが、α位であることが好ましい。
上記飽和脂肪酸の種類に特に制限はなく、組成物の初期及び長期保存後の起泡性を良好とする観点から、ミリスチン酸(C14:0)、パルミチン酸(C16:0)、ステアリン酸(C18:0)、及びアラキジン酸(C20:0)からなる群より選ばれる1種又は2種以上を含むことが好ましく、パルミチン酸及びステアリン酸を含むことがより好ましい。成分Aの構成脂肪酸に占めるステアリン酸の割合は40質量%以上が好ましく、50質量%以上がより好ましい。成分Aとして、飽和モノアシルグリセロールの1種又は2種以上を用いることができる。
Component A (saturated monoacylglycerol) contained in the emulsion composition of the present invention is a monoester compound having an ester bond between any one of three hydroxyl groups of glycerin and a carboxyl group of a saturated fatty acid. The hydroxyl group of glycerin to which the saturated fatty acid is bonded may be either the α-position or the β-position, but is preferably the α-position.
The type of the saturated fatty acid is not particularly limited, and from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage, it is preferable to include one or more selected from the group consisting of myristic acid (C14:0), palmitic acid (C16:0), stearic acid (C18:0), and arachidic acid (C20:0), and more preferably palmitic acid and stearic acid. The proportion of stearic acid in the constituent fatty acids of component A is preferably 40% by mass or more, more preferably 50% by mass or more. As component A, one or more saturated monoacylglycerols can be used.

本発明の乳化組成物中の成分Aの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、2.0~10質量%であることが好ましく、3.0~9.5質量%であることがより好ましく、5.0~9.0質量%であることがさらに好ましい。
成分Aは、本発明の乳化組成物の油相を構成する。
The content of component A in the emulsified composition of the present invention is preferably 2.0 to 10% by mass, and 3.0% by mass from the viewpoint of improving the foaming properties of the composition at the initial stage and after long-term storage. It is more preferably 9.5% by mass, and even more preferably 5.0% to 9.0% by mass.
Component A constitutes the oil phase of the emulsified composition of the present invention.

本発明の乳化組成物に含まれる成分B(炭素数6以上の糖アルコール)は、アルドース又はケトースのカルボニル基を還元して得られる糖を意味する。成分Bの具体例としては、ソルビトール、キシリトール、エリスリトール、マルチトール、マンニトール、還元水飴、イソマルト、及びラクチトールが挙げられ、中でもソルビトール又はマルチトールが好ましく、ソルビトールがより好ましい。成分Bとして、炭素数6以上の糖アルコールの1種又は2種以上を用いることができる。 Component B (sugar alcohol having 6 or more carbon atoms) contained in the emulsion composition of the present invention means a sugar obtained by reducing the carbonyl group of an aldose or ketose. Specific examples of component B include sorbitol, xylitol, erythritol, maltitol, mannitol, reduced starch syrup, isomalt, and lactitol, of which sorbitol or maltitol is preferred, and sorbitol is more preferred. One or more sugar alcohols having 6 or more carbon atoms can be used as component B.

本発明の乳化組成物中の成分Bの含有量は20~65質量%であり、組成物の初期及び長期保存後の起泡性を良好とする観点から、20~55質量%であることが好ましく、22~50質量%であることがより好ましく、25~45質量%であることがさらに好ましい。
成分Bは、本発明の乳化組成物の水相を構成する。
The content of component B in the emulsified composition of the present invention is 20 to 65% by mass, and from the viewpoint of improving the foaming properties of the composition at the initial stage and after long-term storage, it is preferably 20 to 55% by mass. The amount is preferably 22 to 50% by weight, more preferably 25 to 45% by weight.
Component B constitutes the aqueous phase of the emulsified composition of the invention.

本発明の乳化組成物に含まれる成分C(ショ糖脂肪酸エステル)は、水相を構成する成分である。成分Cの一分子が有する構成脂肪酸の数は、成分Cが水相成分として存在できれば特に制限されない。本発明の乳化組成物に含まれるすべての成分Cに占める、脂肪酸モノエステルの形態である成分Cの割合は、30~90質量%であることが好ましく、40~85質量%であることがより好ましく、50~80質量%であることがさらに好ましい。ショ糖脂肪酸エステルを構成する脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、エルカ酸等が挙げられ、これらのうち飽和脂肪酸がより好ましい。本発明に用いる成分Cは、ショ糖ステアリン酸エステルを含むこと(好ましくは成分Cに占めるショ糖ステアリン酸エステルの割合が50質量%以上)が好ましい。成分Cとして、ショ糖脂肪酸エステルの1種又は2種以上を用いることができる。 Component C (sucrose fatty acid ester) contained in the emulsion composition of the present invention is a component that constitutes the aqueous phase. The number of constituent fatty acids in one molecule of component C is not particularly limited as long as component C can exist as an aqueous phase component. The proportion of component C in the form of fatty acid monoester in all components C contained in the emulsion composition of the present invention is preferably 30 to 90 mass%, more preferably 40 to 85 mass%, and even more preferably 50 to 80 mass%. Examples of fatty acids that constitute sucrose fatty acid ester include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, erucic acid, etc., and among these, saturated fatty acids are more preferred. Component C used in the present invention preferably contains sucrose stearate (preferably the proportion of sucrose stearate in component C is 50 mass% or more). One or more types of sucrose fatty acid esters can be used as component C.

本発明の乳化組成物中の成分Cの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、1.0~10質量%であることが好ましく、2.0~8.0質量%であることがより好ましく、4.0~6.0質量%であることがさらに好ましい。 The content of component C in the emulsified composition of the present invention is preferably 1.0 to 10% by mass, and 2.0% by mass from the viewpoint of improving the foaming properties of the composition at the initial stage and after long-term storage. It is more preferably 8.0% by mass, and even more preferably 4.0% to 6.0% by mass.

本発明の乳化組成物に含まれる成分D(水)は、飲用水であれば特に制限はなく、例えば、水道水、精製水、イオン交換水、ミネラルウォーター等を用いることができる。また、成分D以外の成分を水溶液等の水を含む状態で配合した場合には、当該水溶液等に含まれる水は、成分Dを構成する。 Component D (water) contained in the emulsion composition of the present invention is not particularly limited as long as it is potable water, and for example, tap water, purified water, ion-exchanged water, mineral water, etc. can be used. In addition, when a component other than component D is blended in a state containing water such as an aqueous solution, the water contained in the aqueous solution constitutes component D.

本発明の乳化組成物中の成分Dの含有量は、10~30質量%である。組成物の初期及び長期保存後の起泡性を良好とする観点から、本発明の乳化組成物中の成分Dの含有量は15~29質量%であることが好ましく、20~28質量%であることがより好ましい。
成分Dは、本発明の乳化組成物における水相成分の基剤となる。
本発明の乳化組成物は、成分Dの含有量を上記特定範囲に抑えても保存安定性が高められ、優れた起泡作用を長期に亘り安定に発現することができる。また、成分Dの含有量が上記特定範囲に抑えられ、他の成分の相対的な量が高められるため、ケーキ生地に対する乳化組成物の使用量を抑えることができる。また、成分Dの含有量を上記特定範囲に抑えることにより、乳化組成物がケーキ生地全体に素早く均一に広がることができ、ケーキ生地をより素早く、十分に起泡させることが可能となる。
The content of component D in the emulsion composition of the present invention is 10 to 30% by mass. From the viewpoint of improving the foamability of the composition at an initial stage and after long-term storage, the content of component D in the emulsion composition of the present invention is preferably 15 to 29% by mass, and more preferably 20 to 28% by mass.
Component D serves as a base for the aqueous phase components in the emulsion composition of the present invention.
The emulsion composition of the present invention has high storage stability even when the content of component D is controlled within the above-mentioned specific range, and can stably exhibit excellent foaming action for a long period of time. In addition, since the content of component D is controlled within the above-mentioned specific range and the relative amounts of other components are increased, the amount of the emulsion composition used for the cake batter can be reduced. In addition, by controlling the content of component D within the above-mentioned specific range, the emulsion composition can be spread quickly and uniformly throughout the cake batter, and the cake batter can be foamed more quickly and sufficiently.

本発明の乳化組成物は、E:グリセリン(以下、「成分E」とも称す。)を含有してもよい。本発明の乳化組成物が成分Eを含有する場合、乳化組成物中の成分Eの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、0~40質量%であることが好ましく、3.0~35質量%であることがより好ましく、7.0~30質量%であることがさらに好ましい。
成分Eは、本発明の乳化組成物の水相を構成する。
The emulsified composition of the present invention may contain E: glycerin (hereinafter also referred to as "component E"). When the emulsified composition of the present invention contains component E, the content of component E in the emulsified composition is 0 to 40% by mass from the viewpoint of improving the foaming properties of the composition at the initial stage and after long-term storage. The content is preferably 3.0 to 35% by mass, more preferably 7.0 to 30% by mass.
Component E constitutes the aqueous phase of the emulsified composition of the invention.

本発明の乳化組成物は、F:油脂(以下、「成分F」とも称す。)を含有してもよい。本発明の乳化組成物が成分Fを含有する場合でも、乳化組成物中の成分Fの含有量は2.0質量%以下である。成分Fは、例えば、食用の動物性油脂、及び食用の植物性油脂に含まれ、また、他の原料の製剤等に含まれていることがある。
本発明において、成分Fは、トリアシルグリセロール及びジアシルグリセロールを意味し、モノアシルグリセロールは上記「油脂」には含まれないものとする。
The emulsion composition of the present invention may contain F: fats and oils (hereinafter also referred to as "component F"). Even when the emulsion composition of the present invention contains component F, the content of component F in the emulsion composition is 2.0 mass% or less. Component F is contained in, for example, edible animal fats and oils and edible vegetable fats and oils, and may also be contained in preparations of other raw materials.
In the present invention, component F means triacylglycerol and diacylglycerol, and monoacylglycerol is not included in the above "oils and fats".

本発明の乳化組成物が成分Fを含有する場合、乳化組成物中の成分Fの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、1.0質量%以下であることが好ましく、0.60質量%以下であることがより好ましく、0.30質量%以下であることがさらに好ましい。
成分Fは、本発明の乳化組成物の油相を構成する。
When the emulsion composition of the present invention contains component F, the content of component F in the emulsion composition is preferably 1.0% by mass or less, more preferably 0.60% by mass or less, and even more preferably 0.30% by mass or less, from the viewpoint of improving the foamability of the composition initially and after long-term storage.
Component F constitutes the oil phase of the emulsion composition of the present invention.

本発明の乳化組成物中、上記成分Aの含有量に対する上記成分Cの含有量の比の値(成分Cの含有量/成分Aの含有量、質量比)は、0.45~1.5である。組成物の初期及び長期保存後の起泡性を良好とする観点、及び焼成後ケーキを食した時にバラケよく口溶けを良好とする観点から、上記成分Aの含有量に対する上記成分Cの含有量の比の値は、0.45~1.3であることが好ましく、0.50~1.0であることがより好ましく、0.55~0.80であることがさらに好ましい。 In the emulsified composition of the present invention, the ratio of the content of component C to the content of component A (content of component C/content of component A, mass ratio) is 0.45 to 1.5. It is. From the viewpoint of improving the foaming properties of the composition at the initial stage and after long-term storage, and from the viewpoint of ensuring that the cake melts in the mouth without breaking apart when eaten after baking, the content of the above-mentioned component C relative to the content of the above-mentioned component A should be adjusted. The value of the ratio is preferably from 0.45 to 1.3, more preferably from 0.50 to 1.0, even more preferably from 0.55 to 0.80.

本発明の乳化組成物中、上記成分Bの含有量と上記成分Eの含有量の合計は、40~70質量%であることが好ましく、組成物の初期及び長期保存後の起泡性を良好とする観点から、上記成分Bの含有量と上記成分Eの含有量は合計で、42~65質量%であることがより好ましく、44~60質量%であることがさらに好ましく、46~55質量%であることが特に好ましい。 In the emulsion composition of the present invention, the total content of the above-mentioned component B and the above-mentioned component E is preferably 40 to 70% by mass, and from the viewpoint of improving the foamability of the composition both initially and after long-term storage, the total content of the above-mentioned component B and the above-mentioned component E is more preferably 42 to 65% by mass, even more preferably 44 to 60% by mass, and particularly preferably 46 to 55% by mass.

また、本発明の乳化組成物が上記成分Eを含有する場合、乳化組成物中、上記成分Bの含有量に対する上記成分Eの含有量の比の値(成分Eの含有量/成分Bの含有量、質量比)は、組成物の初期及び長期保存後の起泡性を良好とする観点から、0.10~1.0であることが好ましく、0.15~0.95であることがより好ましく、0.20~0.90であることがさらに好ましい。 When the emulsion composition of the present invention contains the above-mentioned component E, the ratio of the content of the above-mentioned component E to the content of the above-mentioned component B in the emulsion composition (content of component E/content of component B, mass ratio) is preferably 0.10 to 1.0, more preferably 0.15 to 0.95, and even more preferably 0.20 to 0.90, from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage.

本発明の乳化組成物はさらに、上記成分に加え、G:プロピレングリコール脂肪酸エステル(以下、「成分G」とも称す。)を含有することも好ましい。成分Gを構成する脂肪酸に特に制限はなく、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、エルカ酸が挙げられ、これらのうち飽和脂肪酸がより好ましい。成分Gは、プロピレングリコール脂肪酸モノエステルを含むことが好ましく、なかでもプロピレングリコールベヘン酸エステルを含むことが好ましい。成分Gとして、プロピレングリコール脂肪酸エステルの1種又は2種以上を用いることができる。 In addition to the above components, the emulsion composition of the present invention preferably further contains G: propylene glycol fatty acid ester (hereinafter also referred to as "component G"). There are no particular limitations on the fatty acid constituting component G, and examples include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, and erucic acid, of which saturated fatty acids are more preferred. Component G preferably contains a propylene glycol fatty acid monoester, and more preferably contains a propylene glycol behenic acid ester. One or more types of propylene glycol fatty acid esters can be used as component G.

本発明の乳化組成物中の成分Gの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、1.5~5.5質量%であることが好ましく、2.0~5.5質量%であることがより好ましく、3.0~5.4質量%であることがさらに好ましい。
成分Gは、本発明の乳化組成物の油相を構成する。
From the viewpoint of improving the foamability of the composition initially and after long-term storage, the content of component G in the emulsion composition of the present invention is preferably 1.5 to 5.5 mass%, more preferably 2.0 to 5.5 mass%, and even more preferably 3.0 to 5.4 mass%.
Component G constitutes the oil phase of the emulsion composition of the present invention.

本発明の乳化組成物は、H:脂肪酸(以下、「成分H」とも称す。)を含有することも好ましい。成分Hは、油相の構成成分であることが好ましい。本発明に好ましく用いられる脂肪酸としては、飽和、不飽和のいずれでもよく、好ましくは炭素原子数16~24の脂肪酸であり、より好ましくは炭素原子数18~22の脂肪酸であり、さらに好ましくは炭素原子数20~22の脂肪酸である。成分Hはベヘン酸を含むことが好ましい。成分Hとして、脂肪酸の1種又は2種以上を用いることができる。 It is also preferable that the emulsified composition of the present invention contains H: fatty acid (hereinafter also referred to as "component H"). Preferably, component H is a constituent of the oil phase. The fatty acids preferably used in the present invention may be either saturated or unsaturated, preferably having 16 to 24 carbon atoms, more preferably having 18 to 22 carbon atoms, and even more preferably having 16 to 24 carbon atoms. It is a fatty acid with 20 to 22 atoms. Preferably, component H comprises behenic acid. As component H, one or more fatty acids can be used.

本発明の乳化組成物中の成分Hの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、0.10~1.0質量%であることが好ましく、0.15~0.80質量%であることがより好ましく、0.20~0.60質量%であることがさらに好ましい。 From the viewpoint of improving the foamability of the composition both initially and after long-term storage, the content of component H in the emulsion composition of the present invention is preferably 0.10 to 1.0% by mass, more preferably 0.15 to 0.80% by mass, and even more preferably 0.20 to 0.60% by mass.

本発明の乳化組成物は、I:ソルビタン脂肪酸エステル(以下、「成分I」とも称す。)を含有することも好ましい。成分Iを構成する脂肪酸に特に制限はなく、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、エルカ酸が挙げられる。なかでも飽和脂肪酸を含むことが好ましい。成分Iを構成する脂肪酸は、より好ましくはステアリン酸を含む。成分Iは、ソルビタン脂肪酸モノエステル、ソルビタン脂肪酸ジエステル、又はソルビタン脂肪酸トリエステルの形態が好ましい。成分Iとして、ソルビタン脂肪酸エステルの1種又は2種以上を用いることができる。 The emulsion composition of the present invention also preferably contains I: sorbitan fatty acid ester (hereinafter also referred to as "component I"). There are no particular limitations on the fatty acid constituting component I, and examples include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, and erucic acid. Of these, it is preferable that it contains a saturated fatty acid. The fatty acid constituting component I more preferably contains stearic acid. Component I is preferably in the form of a sorbitan fatty acid monoester, a sorbitan fatty acid diester, or a sorbitan fatty acid triester. One or more types of sorbitan fatty acid esters can be used as component I.

本発明の乳化組成物中の成分Iの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、0.5~5.0質量%であることが好ましく、1.0~4.0質量%であることがより好ましく、1.5~3.5質量%であることがさらに好ましい。
成分Iは、本発明の乳化組成物の油相を構成する。
From the viewpoint of improving the foamability of the composition initially and after long-term storage, the content of component I in the emulsion composition of the present invention is preferably 0.5 to 5.0 mass%, more preferably 1.0 to 4.0 mass%, and even more preferably 1.5 to 3.5 mass%.
Component I constitutes the oil phase of the emulsion composition of the present invention.

本発明の乳化組成物は、J:リン脂質(以下、「成分J」とも称す。)を含有することも好ましい。成分Jとして、例えば、フォスファチジルコリン、フォスファチジルエタノールアミン、フォスファチジルイノシトール、フォスファチジン酸等又はこれらの酵素処理物が挙げられる。成分Jとして、大豆レシチンや卵黄レシチン等の天然レシチンやその酵素分解物を用いることもできる。また、成分Jとして、リン脂質複合体(例えば、リン脂質とタンパク質との複合体等)を用いることもできる。成分Jとして、リン脂質の1種又は2種以上を用いることができる。 It is also preferable that the emulsified composition of the present invention contains J: phospholipid (hereinafter also referred to as "component J"). Examples of component J include phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidic acid, and enzyme-treated products thereof. As component J, natural lecithins such as soybean lecithin and egg yolk lecithin, and their enzymatically decomposed products can also be used. Moreover, as component J, a phospholipid complex (for example, a complex of phospholipid and protein, etc.) can also be used. As component J, one type or two or more types of phospholipids can be used.

本発明の乳化組成物中の成分Jの含有量は、組成物の初期及び長期保存後の起泡性を良好とする観点から、0~1.0質量%であることが好ましく、0.05~0.80質量%であることがより好ましく、0.10~0.50質量%であることがさらに好ましい。
成分Jは、本発明の乳化組成物の油相を構成する。
From the viewpoint of improving the foamability of the composition initially and after long-term storage, the content of component J in the emulsion composition of the present invention is preferably 0 to 1.0 mass%, more preferably 0.05 to 0.80 mass%, and even more preferably 0.10 to 0.50 mass%.
Component J constitutes the oil phase of the emulsion composition of the present invention.

本発明の乳化組成物は、K:低級アルコール(以下、「成分K」とも称す。)を含有することも好ましい。成分Kとして、エタノールが好適である。
本発明の乳化組成物中の成分Kの含有量は、乳化物の製造を容易にする観点から、0~10質量%であることが好ましく、1.0~8.0質量%であることがより好ましく、2.0~7.0質量%であることがさらに好ましい。
成分Kは、本発明の乳化組成物の水相を構成する。
The emulsion composition of the present invention preferably contains K: a lower alcohol (hereinafter, also referred to as "component K"). As component K, ethanol is preferred.
From the viewpoint of facilitating production of the emulsion, the content of component K in the emulsion composition of the present invention is preferably 0 to 10 mass%, more preferably 1.0 to 8.0 mass%, and even more preferably 2.0 to 7.0 mass%.
Component K constitutes the aqueous phase of the emulsion composition of the present invention.

本発明の乳化組成物は、上記成分に加え、本発明の効果を損なわない範囲で、各種の添加剤を含有してもよい。添加剤の例としては、液体担体、油性担体、安定化剤、湿潤剤、乳化剤、結合剤、等張化剤、崩壊剤、滑沢剤、増量剤、界面活性剤、分散剤、懸濁剤、希釈剤、浸透圧調整剤、pH調整剤、防腐剤、抗酸化剤、着色剤、紫外線吸収剤、保湿剤、増粘剤、光沢剤、緩衝剤、保存剤、嬌味剤、香料、被膜剤、矯臭剤、細菌抑制剤等が挙げられる。 In addition to the above-mentioned components, the emulsified composition of the present invention may contain various additives within a range that does not impair the effects of the present invention. Examples of additives include liquid carriers, oily carriers, stabilizers, wetting agents, emulsifiers, binders, tonicity agents, disintegrants, lubricants, fillers, surfactants, dispersants, suspending agents. , diluent, osmotic pressure adjuster, pH adjuster, preservative, antioxidant, colorant, ultraviolet absorber, humectant, thickener, brightener, buffer, preservative, flavoring agent, fragrance, coating agents, flavoring agents, bacterial inhibitors, etc.

本発明の乳化組成物は、例えば、油相成分を含有する油脂組成物と、水相成分を含有する水溶液とを、通常の方法で乳化混合することで得ることができる。例えば、油相の各構成成分を含有させた油脂組成物を、80℃程度まで加熱して攪拌し、これとは別に、水相の各構成成分を含有させた水溶液を80℃程度まで加熱して撹拌する。そして、上記水溶液中に上記油脂組成物を加えて攪拌し、水溶液中に油脂組成物を乳化分散することにより、目的の水中油型乳化組成物を得ることができる。本発明の乳化組成物の乳化安定性を高める観点から、上記水溶液は、上記油脂組成物に対して、質量比(水溶液/油脂組成物)で2.0以上であることが好ましく、4.0~15であることがより好ましい。 The emulsion composition of the present invention can be obtained, for example, by emulsifying and mixing an oil-and-fat composition containing an oil phase component and an aqueous solution containing an aqueous phase component by a conventional method. For example, an oil-and-fat composition containing each component of the oil phase is heated to about 80°C and stirred, and separately, an aqueous solution containing each component of the aqueous phase is heated to about 80°C and stirred. The oil-and-fat composition is then added to the aqueous solution and stirred to emulsify and disperse the oil-and-fat composition in the aqueous solution, thereby obtaining the desired oil-in-water emulsion composition. From the viewpoint of enhancing the emulsion stability of the emulsion composition of the present invention, the aqueous solution preferably has a mass ratio (aqueous solution/oil-and-fat composition) of 2.0 or more relative to the oil-and-fat composition, and more preferably 4.0 to 15.

本発明の水中油型乳化組成物は、ケーキ製品の製造に用いられる。ケーキ製品としては、スポンジケーキ、バターケーキ、シフォンケーキ、ロールケーキ、スイスロール、ブッセ、バウムクーヘン、パウンドケーキ、チーズケーキ、スナックケーキ、蒸しケーキ等が挙げられる。 The oil-in-water emulsion composition of the present invention is used to produce cake products. Examples of cake products include sponge cake, butter cake, chiffon cake, roll cake, Swiss roll, bouillon, baumkuchen, pound cake, cheesecake, snack cake, steamed cake, etc.

本発明のケーキは、本発明の乳化組成物を含有させたケーキ生地を焼成することで製造される。このケーキ生地は、本発明の乳化組成物を添加すること以外は、通常の方法で調製することができる。例えば、少なくとも穀粉と、卵と、糖類と、本発明の乳化組成物とを混合して得ることができる。良好な食感と風味を得る観点から、本発明のケーキは、少なくとも穀粉と、該穀粉100質量部に対して、卵50~300質量部と、糖類20~250質量部と、本発明の乳化剤3~100質量部とを混合して抱気させたケーキ生地を調製し、このケーキ生地を焼成して製造されることが好ましい。より好ましくは、穀粉100質量部に対して、卵を80~250質量部、糖類を50~180質量部、本発明の乳化組成物を5~50質量部の割合で混合し、抱気させたケーキ生地を焼成して製造される。
上記穀粉に特に制限はないが、例えば、小麦粉、米粉、大麦粉、ライ麦粉、トウモロコシ粉、ひえ粉等が挙げられ、中でも小麦粉が好適に用いられる。
上記卵として、鶏卵、ダチョウ卵、アヒル卵等が挙げられるが、中でも鶏卵が好適に用いられる。また、上記卵は、卵白及び/又は卵黄を意味する。
使用する卵の加工形態に特に制限はなく、生卵、凍結卵、粉末卵、加糖卵、殺菌卵等を用いることができるが、中でも殺菌卵が好適に用いられる。
上記ケーキ生地は、さらに粉乳、ベーキングパウダー、砂糖、食用油、香料等の、ケーキ生地に配合される慣用添加物等を含むことができる。
The cake of the present invention is produced by baking a cake batter containing the emulsion composition of the present invention. This cake batter can be prepared by a normal method except for adding the emulsion composition of the present invention. For example, it can be obtained by mixing at least flour, eggs, sugars, and the emulsion composition of the present invention. From the viewpoint of obtaining a good texture and flavor, the cake of the present invention is preferably produced by mixing at least flour, 50 to 300 parts by mass of eggs, 20 to 250 parts by mass of sugars, and 3 to 100 parts by mass of the emulsifier of the present invention per 100 parts by mass of the flour to prepare an aerated cake batter, and baking this cake batter. More preferably, it is produced by mixing 80 to 250 parts by mass of eggs, 50 to 180 parts by mass of sugars, and 5 to 50 parts by mass of the emulsion composition of the present invention per 100 parts by mass of flour, and baking the aerated cake batter.
The above-mentioned cereal flour is not particularly limited, but examples thereof include wheat flour, rice flour, barley flour, rye flour, corn flour, and barnyard millet flour, and among these, wheat flour is preferably used.
The eggs include chicken eggs, ostrich eggs, duck eggs, etc., among which chicken eggs are preferably used. Moreover, the eggs refer to egg whites and/or egg yolks.
There are no particular limitations on the processed form of the eggs used; raw eggs, frozen eggs, powdered eggs, sweetened eggs, pasteurized eggs, etc. can be used, with pasteurized eggs being preferred.
The cake dough may further contain conventional additives such as milk powder, baking powder, sugar, edible oil, flavorings, etc., which are commonly used in cake dough.

上記焼成方法に特に制限はないが、通常には、ケーキ生地を所望の型(円筒、三角筒や四角筒等の角筒等)に入れ、オーブン等で焼き上げる(加熱する)ことで行われる。 There are no particular limitations to the baking method, but it is usually done by putting the cake batter into the desired mold (cylinder, triangular tube, square tube, etc.) and baking (heating) it in an oven, etc.

上述した実施形態に関し、本発明はさらに以下の水中油型乳化組成物、ケーキ、及びケーキの製造方法を開示する。 With respect to the above-mentioned embodiment, the present invention further discloses the following oil-in-water emulsion composition, cake, and method for producing the cake.

<1>
A:飽和脂肪酸を構成脂肪酸とするモノアシルグリセロール、
B:炭素数6以上の糖アルコール、
C:ショ糖脂肪酸エステル、及び
D:水
を含有し、
前記炭素数6以上の糖アルコールの含有量が20~65質量%、好ましくは20~55質量%、より好ましくは22~50質量%、さらに好ましくは25~45質量%、であり、
前記水の含有量が10~30質量%、好ましくは15~29質量%、より好ましくは20~28質量%、であり、
前記飽和脂肪酸を構成脂肪酸とするモノアシルグリセロールの含有量に対する前記ショ糖脂肪酸エステルの含有量の比の値が質量比で0.45~1.5、好ましくは0.45~1.3、より好ましくは0.50~1.0、さらに好ましくは0.55~0.80、であり、
油脂の含有量が2.0質量%以下、好ましくは1.0質量%以下、より好ましくは0.60質量%以下、さらに好ましくは0.30質量%以下、である、
ケーキ生地起泡用水中油型乳化組成物。
<1>
A: Monoacylglycerol whose constituent fatty acids are saturated fatty acids,
B: sugar alcohol with 6 or more carbon atoms,
C: contains sucrose fatty acid ester, and D: water,
The content of the sugar alcohol having 6 or more carbon atoms is 20 to 65% by mass, preferably 20 to 55% by mass, more preferably 22 to 50% by mass, even more preferably 25 to 45% by mass,
The water content is 10 to 30% by mass, preferably 15 to 29% by mass, more preferably 20 to 28% by mass,
The value of the ratio of the content of the sucrose fatty acid ester to the content of monoacylglycerol whose constituent fatty acids are the saturated fatty acids is 0.45 to 1.5, preferably 0.45 to 1.3 in terms of mass ratio, or more. preferably 0.50 to 1.0, more preferably 0.55 to 0.80,
The content of fats and oils is 2.0% by mass or less, preferably 1.0% by mass or less, more preferably 0.60% by mass or less, even more preferably 0.30% by mass or less,
Oil-in-water emulsion composition for foaming cake dough.

<2>
E:グリセリン
を含有し、前記炭素数6以上の糖アルコールの含有量と前記グリセリンの含有量との合計が40質量%以上、好ましくは42質量%以上、より好ましくは44質量%以上、さらに好ましくは46質量%以上であり、前記炭素数6以上の糖アルコールの含有量に対する前記グリセリンの含有量の比の値が質量比で0.1以上、好ましくは0.15以上、より好ましくは0.20以上である、前記<1>項記載のケーキ生地起泡用水中油型乳化組成物。
<3>
E:グリセリン
を含有し、前記炭素数6以上の糖アルコールの含有量と前記グリセリンの含有量との合計が70質量%以下、好ましくは65質量%以下、より好ましくは60質量%以下、さらに好ましくは55質量%以下であり、前記炭素数6以上の糖アルコールの含有量に対する前記グリセリンの含有量の比の値が質量比で1以下、好ましくは0.95以下、より好ましくは0.90以下である、前記<1>又は<2>項記載のケーキ生地起泡用水中油型乳化組成物。
<4>
E:グリセリン
を含有し、前記炭素数6以上の糖アルコールの含有量と前記グリセリンの含有量との合計が40~70質量%、好ましくは42~65質量%、より好ましくは44~60質量%、さらに好ましくは46~55質量%であり、前記炭素数6以上の糖アルコールの含有量に対する前記グリセリンの含有量の比の値が質量比で0.1~1、好ましくは0.15~0.95、より好ましくは0.20~0.90である、前記<1>~<3>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<5>
前記モノアシルグリセロールの構成脂肪酸である飽和脂肪酸が、ミリスチン酸、パルミチン酸、ステアリン酸、及びアラキジン酸からなる群より選ばれる1種又は2種以上であり、好ましくはパルミチン酸及びステアリン酸であり、より好ましくはパルミチン酸又はステアリン酸、である、前記<1>~<4>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<6>
前記乳化組成物中の飽和脂肪酸を構成脂肪酸とするモノアシルグリセロールの含有量が、好ましくは2.0質量%以上、より好ましくは3.0質量%以上、さらに好ましくは5.0質量%以上、である、前記<1>~<5>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<7>
前記乳化組成物中の飽和脂肪酸を構成脂肪酸とするモノアシルグリセロールの含有量が、好ましくは10質量%以下、より好ましくは9.5質量%以下、さらに好ましくは9.0質量%以下、である、前記<1>~<6>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<8>
前記乳化組成物中の飽和脂肪酸を構成脂肪酸とするモノアシルグリセロールの含有量が、好ましくは2.0~10質量%、より好ましくは3.0~9.5質量%、さらに好ましくは5.0~9.0質量%、である、前記<1>~<7>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<9>
前記糖アルコールが、好ましくはソルビトール、キシリトール、エリスリトール、マルチトール、及びプロピレングリコールから選ばれる1種又は2種以上であり、より好ましくはソルビトール又はマルチトールであり、さらに好ましくはソルビトールである、前記<1>~<8>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<10>
前記ショ糖脂肪酸エステルが、好ましくはモノエステル含量が30~90質量%、より好ましくは40~85質量%、さらに好ましくは50~80質量%のショ糖脂肪酸エステルである、前記<1>~<9>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<11>
前記ショ糖脂肪酸エステルを構成する脂肪酸が、好ましくはラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、又はエルカ酸であり、より好ましくはこれらのうち飽和脂肪酸であり、さらに好ましくはステアリン酸、である、前記<1>~<10>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<12>
前記乳化組成物中のショ糖脂肪酸エステルの含有量が、好ましくは1.0質量%以上、より好ましくは2.0質量%以上、さらに好ましくは4.0質量%以上、である、前記<1>~<11>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<13>
前記乳化組成物中のショ糖脂肪酸エステルの含有量が、好ましくは10質量%以下、より好ましくは8.0質量%以下、さらに好ましくは6.0質量%以下、である、前記<1>~<12>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<14>
前記乳化組成物中のショ糖脂肪酸エステルの含有量が、好ましくは1.0~10質量%、より好ましくは2.0~8.0質量%、さらに好ましくは4.0~6.0質量%、である、前記<1>~<13>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<15>
前記乳化組成物中のグリセリンの含有量が、好ましくは0質量%以上、より好ましくは3.0質量%以上、さらに好ましくは7.0質量%以上、である、前記<1>~<14>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<16>
前記乳化組成物中のグリセリンの含有量が、好ましくは40質量%以下、より好ましくは35質量%以下、さらに好ましくは30質量%以下、である、前記<1>~<15>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<17>
前記乳化組成物中のグリセリンの含有量が、好ましくは0~40質量%、より好ましくは3.0~35質量%、さらに好ましくは7.0~30質量%、である、前記<1>~<16>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<18>
前記油脂が、食用の動物性油脂、食用の植物性油脂に含まれる油脂である、前記<1>~<17>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<19>
前記植物性油脂が、大豆油、オリーブ油、サフラワー油、コーン油、ナタネ油、綿実油、これらの分別油、エステル交換油、硬化油から選ばれる1種又は2種以上の油脂である、前記<18>項に記載のケーキ生地起泡用水中油型乳化組成物。
<2>
E: The oil-in-water emulsion composition for whipping cake batter according to item <1> above, which contains glycerin, wherein the sum of the content of the sugar alcohol having 6 or more carbon atoms and the content of the glycerin is 40% by mass or more, preferably 42% by mass or more, more preferably 44% by mass or more, and even more preferably 46% by mass or more, and the ratio of the content of the glycerin to the content of the sugar alcohol having 6 or more carbon atoms is 0.1 or more, preferably 0.15 or more, and more preferably 0.20 or more, in terms of mass ratio.
<3>
E: The oil-in-water emulsion composition for whipping cake batter according to item <1> or <2>, which contains glycerin, wherein the sum of the content of the sugar alcohol having 6 or more carbon atoms and the content of the glycerin is 70% by mass or less, preferably 65% by mass or less, more preferably 60% by mass or less, and even more preferably 55% by mass or less, and the ratio of the content of the glycerin to the content of the sugar alcohol having 6 or more carbon atoms is 1 or less, preferably 0.95 or less, and more preferably 0.90 or less, in terms of mass ratio.
<4>
E: The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <3> above, which contains glycerin, the sum of the content of the sugar alcohol having 6 or more carbon atoms and the content of the glycerin is 40 to 70% by mass, preferably 42 to 65% by mass, more preferably 44 to 60% by mass, and even more preferably 46 to 55% by mass, and the ratio of the content of the glycerin to the content of the sugar alcohol having 6 or more carbon atoms is 0.1 to 1, preferably 0.15 to 0.95, and more preferably 0.20 to 0.90 by mass.
<5>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <4> above, wherein the saturated fatty acid that is a constituent fatty acid of the monoacylglycerol is one or more selected from the group consisting of myristic acid, palmitic acid, stearic acid, and arachidic acid, preferably palmitic acid and stearic acid, and more preferably palmitic acid or stearic acid.
<6>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <5>, wherein the content of monoacylglycerol having a saturated fatty acid as a constituent fatty acid in the emulsion composition is preferably 2.0% by mass or more, more preferably 3.0% by mass or more, and even more preferably 5.0% by mass or more.
<7>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <6>, wherein the content of monoacylglycerol having a constituent fatty acid as a saturated fatty acid in the emulsion composition is preferably 10% by mass or less, more preferably 9.5% by mass or less, and even more preferably 9.0% by mass or less.
<8>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <7>, wherein the content of monoacylglycerol having a saturated fatty acid as a constituent fatty acid in the emulsion composition is preferably 2.0 to 10 mass%, more preferably 3.0 to 9.5 mass%, and even more preferably 5.0 to 9.0 mass%.
<9>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <8> above, wherein the sugar alcohol is preferably one or more selected from sorbitol, xylitol, erythritol, maltitol, and propylene glycol, more preferably sorbitol or maltitol, and even more preferably sorbitol.
<10>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <9>, wherein the sucrose fatty acid ester is a sucrose fatty acid ester having a monoester content of preferably 30 to 90% by mass, more preferably 40 to 85% by mass, and even more preferably 50 to 80% by mass.
<11>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <10>, wherein the fatty acid constituting the sucrose fatty acid ester is preferably lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, or erucic acid, more preferably a saturated fatty acid among these, and even more preferably stearic acid.
<12>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <11>, wherein the content of the sucrose fatty acid ester in the emulsion composition is preferably 1.0% by mass or more, more preferably 2.0% by mass or more, and even more preferably 4.0% by mass or more.
<13>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <12>, wherein the content of the sucrose fatty acid ester in the emulsion composition is preferably 10% by mass or less, more preferably 8.0% by mass or less, and even more preferably 6.0% by mass or less.
<14>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <13>, wherein the content of the sucrose fatty acid ester in the emulsion composition is preferably 1.0 to 10% by mass, more preferably 2.0 to 8.0% by mass, and even more preferably 4.0 to 6.0% by mass.
<15>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <14>, wherein the content of glycerin in the emulsion composition is preferably 0% by mass or more, more preferably 3.0% by mass or more, and even more preferably 7.0% by mass or more.
<16>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <15>, wherein the content of glycerin in the emulsion composition is preferably 40% by mass or less, more preferably 35% by mass or less, and even more preferably 30% by mass or less.
<17>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <16>, wherein the content of glycerin in the emulsion composition is preferably 0 to 40% by mass, more preferably 3.0 to 35% by mass, and even more preferably 7.0 to 30% by mass.
<18>
The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <17>, wherein the oil is an oil contained in edible animal fats or edible vegetable fats.
<19>
The oil-in-water emulsion composition for whipping cake batter according to item <18>, wherein the vegetable oil is one or more oils selected from the group consisting of soybean oil, olive oil, safflower oil, corn oil, rapeseed oil, cottonseed oil, fractionated oils thereof, transesterified oils, and hardened oils.

<20>
前記乳化組成物が、
G:プロピレングリコール脂肪酸エステル
を含有し、該プロピレングリコール脂肪酸エステルの含有量が1.5質量%以上、好ましくは2.0質量%以上、より好ましくは3.0質量%以上である、前記<1>~<19>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<21>
前記乳化組成物が、
G:プロピレングリコール脂肪酸エステル
を含有し、該プロピレングリコール脂肪酸エステルの含有量が5.5質量%以下、好ましくは5.4質量%以下である、前記<1>~<20>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<22>
前記乳化組成物が、
G:プロピレングリコール脂肪酸エステル
を含有し、該プロピレングリコール脂肪酸エステルの含有量が1.5~5.5質量%、好ましくは2.0~5.5質量%、より好ましくは3.0~5.4質量%である、前記<1>~<21>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<23>
前記プロピレングリコール脂肪酸エステルを構成する脂肪酸が、好ましくはラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、又はエルカ酸であり、より好ましくは飽和脂肪酸であり、さらに好ましくはベヘン酸である、前記<20>~<22>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<20>
The emulsified composition is
G: Contains a propylene glycol fatty acid ester, and the content of the propylene glycol fatty acid ester is 1.5% by mass or more, preferably 2.0% by mass or more, more preferably 3.0% by mass or more, <1 above The oil-in-water emulsion composition for foaming cake dough according to any one of items > to <19>.
<21>
The emulsified composition is
G: Any one of <1> to <20> above, which contains a propylene glycol fatty acid ester, and the content of the propylene glycol fatty acid ester is 5.5% by mass or less, preferably 5.4% by mass or less. An oil-in-water emulsion composition for foaming cake dough as described in .
<22>
The emulsified composition is
G: Contains propylene glycol fatty acid ester, and the content of the propylene glycol fatty acid ester is 1.5 to 5.5% by mass, preferably 2.0 to 5.5% by mass, more preferably 3.0 to 5.5% by mass. The oil-in-water emulsion composition for foaming cake dough according to any one of <1> to <21> above, which has a content of 4% by mass.
<23>
The fatty acid constituting the propylene glycol fatty acid ester is preferably lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, or erucic acid, more preferably a saturated fatty acid, and even more preferably behenic acid. The oil-in-water emulsion composition for foaming cake dough according to any one of <20> to <22> above.

<24>
前記乳化組成物が、
H:脂肪酸
を含有し、該脂肪酸の含有量が0.10質量%以上、好ましくは0.15質量%以上、より好ましくは0.20質量%以上である、前記<1>~<23>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<25>
前記乳化組成物が、
H:脂肪酸
を含有し、該脂肪酸の含有量が1.0質量%以下、好ましくは0.80質量%以下、より好ましくは0.60質量%以下である、前記<1>~<24>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<26>
前記乳化組成物が、
H:脂肪酸
を含有し、該脂肪酸の含有量が0.10~1.0質量%、好ましくは0.15~0.80質量%、より好ましくは0.20~0.60質量%である、前記<1>~<25>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<27>
前記脂肪酸が、好ましくは炭素原子数16~24の脂肪酸、より好ましくは炭素原子数18~22の脂肪酸、さらに好ましくは炭素原子数20~22の脂肪酸、である、前記<24>~<26>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<24>
The emulsion composition comprises:
H: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <23>, which contains a fatty acid and has a content of the fatty acid of 0.10% by mass or more, preferably 0.15% by mass or more, and more preferably 0.20% by mass or more.
<25>
The emulsion composition comprises:
H: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <24>, which contains a fatty acid and has a content of the fatty acid of 1.0 mass% or less, preferably 0.80 mass% or less, and more preferably 0.60 mass% or less.
<26>
The emulsion composition comprises:
H: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <25>, which contains a fatty acid, and the content of the fatty acid is 0.10 to 1.0 mass%, preferably 0.15 to 0.80 mass%, and more preferably 0.20 to 0.60 mass%.
<27>
The oil-in-water emulsion composition for whipping cake batter according to any one of the items <24> to <26>, wherein the fatty acid is preferably a fatty acid having 16 to 24 carbon atoms, more preferably a fatty acid having 18 to 22 carbon atoms, and even more preferably a fatty acid having 20 to 22 carbon atoms.

<28>
前記乳化組成物が、
I:ソルビタン脂肪酸エステル
を含有し、該ソルビタン脂肪酸エステルの含有量が0.5質量%以上、好ましくは1.0質量%以上、より好ましくは1.5質量%以上である、前記<1>~<27>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<29>
前記乳化組成物が、
I:ソルビタン脂肪酸エステル
を含有し、該ソルビタン脂肪酸エステルの含有量が5.0質量%以下、好ましくは4.0質量%以下、より好ましくは3.5質量%以下である、前記<1>~<28>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<30>
前記乳化組成物が、
I:ソルビタン脂肪酸エステル
を含有し、該ソルビタン脂肪酸エステルの含有量が0.5~5.0質量%、好ましくは1.0~4.0質量%、より好ましくは1.5~3.5質量%である、前記<1>~<29>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<31>
前記ソルビタン脂肪酸エステルを構成する脂肪酸が、好ましくはラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、又はエルカ酸であり、より好ましくは飽和脂肪酸であり、さらに好ましくはステアリン酸である、前記<28>~<30>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<32>
前記乳化組成物が、
J:リン脂質
を含有し、該リン脂質の含有量が0質量%以上、好ましくは0.05質量%以上、より好ましくは0.10質量%以上である、前記<1>~<31>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<33>
前記乳化組成物が、
J:リン脂質
を含有し、該リン脂質の含有量が1.0質量%以下、好ましくは0.80質量%以下、より好ましくは0.50質量%以下である、前記<1>~<32>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<34>
前記乳化組成物が、
J:リン脂質
を含有し、該リン脂質の含有量が0~1.0質量%、好ましくは0.05~0.80質量%、より好ましくは0.10~0.50質量%である、前記<1>~<33>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<35>
前記乳化組成物が、
K:低級アルコール
を含有し、該低級アルコールの含有量が0質量%以上、好ましくは1.0質量%以上、より好ましくは2.0質量%以上である、前記<1>~<34>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<36>
前記乳化組成物が、
K:低級アルコール
を含有し、該低級アルコールの含有量が10質量%以下、好ましくは8.0質量%以下、より好ましくは7.0質量%以下である、前記<1>~<35>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<37>
前記乳化組成物が、
K:低級アルコール
を含有し、該低級アルコールの含有量が0~10質量%、好ましくは1.0~8.0質量%、より好ましくは2.0~7.0質量%である、前記<1>~<36>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<38>
前記低級アルコールが、好ましくはエタノールである、前記<35>~<37>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
<28>
The emulsion composition comprises:
I: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <27>, which contains a sorbitan fatty acid ester, and the content of the sorbitan fatty acid ester is 0.5% by mass or more, preferably 1.0% by mass or more, and more preferably 1.5% by mass or more.
<29>
The emulsion composition comprises:
I: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <28>, which contains a sorbitan fatty acid ester, and the content of the sorbitan fatty acid ester is 5.0% by mass or less, preferably 4.0% by mass or less, and more preferably 3.5% by mass or less.
<30>
The emulsion composition comprises:
I: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <29>, which contains a sorbitan fatty acid ester, and the content of the sorbitan fatty acid ester is 0.5 to 5.0 mass%, preferably 1.0 to 4.0 mass%, and more preferably 1.5 to 3.5 mass%.
<31>
The oil-in-water emulsion composition for whipping cake batter according to any one of <28> to <30>, wherein the fatty acid constituting the sorbitan fatty acid ester is preferably lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, or erucic acid, more preferably a saturated fatty acid, and even more preferably stearic acid.
<32>
The emulsion composition comprises:
J: The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <31>, which contains a phospholipid and has a phospholipid content of 0 mass% or more, preferably 0.05 mass% or more, and more preferably 0.10 mass% or more.
<33>
The emulsion composition comprises:
J: The oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <32>, which contains a phospholipid and has a phospholipid content of 1.0% by mass or less, preferably 0.80% by mass or less, and more preferably 0.50% by mass or less.
<34>
The emulsion composition comprises:
J: The oil-in-water emulsion composition for whipping cake batter according to any one of the above items <1> to <33>, which contains a phospholipid and has a phospholipid content of 0 to 1.0% by mass, preferably 0.05 to 0.80% by mass, and more preferably 0.10 to 0.50% by mass.
<35>
The emulsion composition comprises:
K: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <34>, which contains a lower alcohol, and has a content of the lower alcohol of 0 mass% or more, preferably 1.0 mass% or more, and more preferably 2.0 mass% or more.
<36>
The emulsion composition comprises:
K: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <35>, which contains a lower alcohol, and the content of the lower alcohol is 10% by mass or less, preferably 8.0% by mass or less, and more preferably 7.0% by mass or less.
<37>
The emulsion composition comprises:
K: The oil-in-water emulsion composition for whipping cake batter according to any one of the items <1> to <36>, which contains a lower alcohol, and the content of the lower alcohol is 0 to 10% by mass, preferably 1.0 to 8.0% by mass, and more preferably 2.0 to 7.0% by mass.
<38>
The oil-in-water emulsion composition for whipping cake batter according to any one of <35> to <37>, wherein the lower alcohol is preferably ethanol.

<39>
前記<1>~<38>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物を含むケーキ生地を焼成して得られるケーキ。
<40>
前記<1>~<38>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物を生地に配合してケーキ生地を調製し、該ケーキ生地を焼成することを含む、ケーキの製造方法。
<41>
前記ケーキ生地が、少なくとも穀粉と、該穀粉100質量部に対して、卵50~300質量部と、糖類20~250質量部と、前記<1>~<38>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物3~100質量部とを配合するものであり、好ましくは穀粉100質量部に対して、卵80~250質量部、糖類50~180質量部、前記<1>~<38>のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物5~50質量部とを配合するものである、前記<40>項記載のケーキの製造方法。
<39>
A cake obtained by baking a cake batter containing the oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <38>.
<40>
A method for producing a cake, comprising: preparing a cake batter by blending the oil-in-water emulsion composition for whipping cake batter according to any one of <1> to <38> above into a batter; and baking the cake batter.
<41>
The method for producing a cake according to item <40> above, wherein the cake batter is a mixture of at least cereal flour, 50 to 300 parts by mass of an egg, 20 to 250 parts by mass of a sugar, and 3 to 100 parts by mass of the oil-in-water emulsion composition for whipping cake batter described in any one of items <1> to <38> above, per 100 parts by mass of the cereal flour, and preferably a mixture of 80 to 250 parts by mass of an egg, 50 to 180 parts by mass of a sugar, and 5 to 50 parts by mass of the oil-in-water emulsion composition for whipping cake batter described in any one of items <1> to <38> above, per 100 parts by mass of the cereal flour.

以下、本発明を実施例に基づき詳細に説明するが、本発明はこれらに限定されるものではない。 EXAMPLES Hereinafter, the present invention will be explained in detail based on Examples, but the present invention is not limited thereto.

[調製例1 水中油型乳化組成物の調製]
飽和モノアシルグリセロール(商品名:エキセルVS-95、グリセリンモノステアレート、花王株式会社製)、ソルビタン脂肪酸エステル(商品名:エマゾールS-10VHL、ソルビタンモノステアレート、花王株式会社製、又は商品名:エマゾールS-30V、ソルビタントリステアレート、花王株式会社製)、プロピレングリコール脂肪酸エステル(商品名:グリンステッドPGMB、プロピレングリコールモノベヘネート、Danisco製)、脂肪酸(商品名:ルナックBA、ベヘン酸、花王株式会社製)、レシチン(商品名:Yelkin TS、大豆レシチン、ADM社製)、ポリオキシエチレンソルビタン脂肪酸エステル(商品名:エマゾールS-120V、花王株式会社製)、及び菜種油(商品名:ナタネ白絞油、日清オイリオグループ株式会社製)を下記表1に示す割合で混合し、80℃に加熱して攪拌溶解することで油相を形成するための油脂組成物を調製した。
なお、表1の上欄に記載の各成分の数値は油相成分と水相成分の合計を100質量%としたときの質量%を示す。
Preparation Example 1: Preparation of oil-in-water emulsion composition
Saturated monoacylglycerol (trade name: Excel VS-95, glycerin monostearate, manufactured by Kao Corporation), sorbitan fatty acid ester (trade name: Emazol S-10VHL, sorbitan monostearate, manufactured by Kao Corporation, or trade name: Emazol S-30V, sorbitan tristearate, manufactured by Kao Corporation), propylene glycol fatty acid ester (trade name: Grinstead PGMB, propylene glycol monobehenate, manufactured by Danisco), fatty acid (trade name: Lunac BA, behenic acid, manufactured by Kao Corporation), lecithin (trade name: Yelkin TS, soy lecithin, manufactured by ADM), polyoxyethylene sorbitan fatty acid ester (trade name: Emazol S-120V, manufactured by Kao Corporation), and rapeseed oil (trade name: Rapeseed White Oil, manufactured by Nisshin Oillio Group Co., Ltd.) were mixed in the ratios shown in Table 1 below, heated to 80 ° C., stirred and dissolved, and an oil and fat composition for forming an oil phase was prepared.
The numerical values of each component shown in the upper column of Table 1 indicate mass % when the total of the oil phase components and the aqueous phase components is taken as 100 mass %.

ショ糖脂肪酸エステル(商品名:リョートーシュガーエステルS-1170S、ショ糖ステアリン酸エステル(モノエステル55%、ジ・トリ・ポリエステル45%)、三菱ケミカルフーズ株式会社製)、水(イオン交換水)、ソルビトール(商品名:ソルビトール(固形分70%)、花王株式会社製)、糖アルコール(商品名:スイートOL(固形分70%,原料DE45)、還元水飴、物産フードサイエンス社製)、精製グリセリン(商品名:グリセリン、花王株式会社製)、エタノール(商品名:トレーサブル95、日本アルコール産業社製)、微結晶セルロース(商品名:セオラスRC-N30、旭化成株式会社製)、キサンタンガム(商品名:ビストップD-3000、三栄源エフ・エフ・アイ社製)、を下記表1に示す割合で混合し、80℃に調温した後、パドル120rpm、ホモミキサー1500rpmの条件で5分間攪拌溶解することで水相を形成するための水溶液を得た。
なお、表1の上欄に記載の各成分の数値は油相成分と水相成分の合計を100質量%としたときの質量%を示す。
Sucrose fatty acid ester (trade name: Ryoto Sugar Ester S-1170S, sucrose stearate (monoester 55%, di-tri-polyester 45%), manufactured by Mitsubishi Chemical Foods Corporation), water (ion-exchanged water), sorbitol (trade name: Sorbitol (solid content 70%), manufactured by Kao Corporation), sugar alcohol (trade name: Sweet OL (solid content 70%, raw material DE 45), reduced starch syrup, manufactured by Bussan Food Science Co., Ltd.), purified glycerin (trade name: Glycerin, manufactured by Kao Corporation), ethanol (trade name: Traceable 95, manufactured by Japan Alcohol Industry Co., Ltd.), microcrystalline cellulose (trade name: CEOLUS RC-N30, manufactured by Asahi Kasei Corporation), and xanthan gum (trade name: Bistop D-3000, manufactured by San-Ei Gen F.F.I.) were mixed in the ratios shown in Table 1 below, and the mixture was adjusted to 80° C., and then stirred and dissolved for 5 minutes under conditions of a paddle of 120 rpm and a homomixer of 1500 rpm, to obtain an aqueous solution for forming an aqueous phase.
The numerical values of each component shown in the upper column of Table 1 indicate mass % when the total of the oil phase components and the aqueous phase components is taken as 100 mass %.

上記水溶液に上記油脂組成物を徐々に添加しながらアジホモミキサー(プライミクス社製、2M-03型社製)を用いて80℃、パドル120rpm、ホモミキサー1500rpmの条件で10分間攪拌乳化し、水中油型乳化組成物(本発明品1~9、比較品1~13)を得た。得られた各乳化組成物を20℃まで冷却した後、後述する試験例に用いた。
表1には、各乳化組成物中の飽和脂肪酸を構成脂肪酸とするモノアシルグリセロール(成分A)、炭素数6以上の糖アルコール(成分B)、ショ糖脂肪酸エステル(成分C)、水(成分D)、グリセリン(成分E)、油脂(成分F)、プロピレングリコール脂肪酸エステル(成分G)、脂肪酸(成分H)の各含有量(単位:質量%)を併せて示し、さらに成分Bの含有量と成分Eの含有量の合計値、成分Aの含有量に対する成分Cの含有量の比率(C/A、質量比)、及び成分Bの含有量に対する成分Eの含有量の比率(E/B、質量比)も併せて示した。
The oil composition was gradually added to the aqueous solution and emulsified by stirring for 10 minutes using an Ajihomomixer (2M-03 model, manufactured by Primix Corporation) at 80°C, paddle speed of 120 rpm, and homomixer speed of 1500 rpm to obtain oil-in-water emulsion compositions (Products 1 to 9 of the present invention, and Comparative Products 1 to 13). Each of the obtained emulsion compositions was cooled to 20°C and then used in the test examples described below.
Table 1 shows the contents (unit: mass %) of monoacylglycerol (component A) having a saturated fatty acid as a constituent fatty acid, sugar alcohol having 6 or more carbon atoms (component B), sucrose fatty acid ester (component C), water (component D), glycerin (component E), oils and fats (component F), propylene glycol fatty acid ester (component G), and fatty acid (component H) in each emulsion composition, as well as the total content of component B and the content of component E, the ratio of the content of component C to the content of component A (C/A, mass ratio), and the ratio of the content of component E to the content of component B (E/B, mass ratio).

[試験例1 起泡性試験]
卵(生鶏卵)200gに上白糖180gを加え、卓上ミキサー(HOBART社製N-50、ホイッパー:N-5D)を用いて低速で攪拌しながら20℃まで加温した。上記調製例1にて作製した乳化組成物(本発明品1~9、又は比較品1~13)30g、及び水50gを加え中速で1分間攪拌した。薄力粉(日清製粉社製)200gを加え、低速で1分間撹拌した後に、中速で9分間攪拌し、ケーキ生地を得た。得られたケーキ生地を108mlカップに移して速やかに計量し、ケーキ生地の比重(かさ比重、単位:g/cm)を算出して、起泡性を評価した。この比重が小さいほど、撹拌後のケーキ生地の膨らみが大きいことを意味し、起泡性が高いことを意味する。
なお、上記乳化組成物は、製造直後(1~3日後)のもの、次に、製造後20℃で30日間(30d)保存したもの、最後に、製造後40℃で40日間(40d)保存したものを使用し、ケーキ生地の比重が0.43g/cmを上回った場合、次の試験を行わないものとした。
結果を下記表1に示す。
[Test Example 1: Foaming Test]
180 g of white sugar was added to 200 g of eggs (raw chicken eggs), and the mixture was heated to 20° C. while stirring at low speed using a tabletop mixer (HOBART N-50, whipper: N-5D). 30 g of the emulsion composition (products 1 to 9 of the present invention, or comparative products 1 to 13) prepared in Preparation Example 1 above and 50 g of water were added and stirred at medium speed for 1 minute. 200 g of weak flour (Nissin Flour Milling Co., Ltd.) was added, stirred at low speed for 1 minute, and then stirred at medium speed for 9 minutes to obtain a cake batter. The obtained cake batter was transferred to a 108 ml cup and quickly weighed, and the specific gravity (bulk specific gravity, unit: g/cm 3 ) of the cake batter was calculated to evaluate the foamability. The smaller the specific gravity, the greater the swelling of the cake batter after stirring, and the higher the foamability.
The above emulsion compositions were used immediately after production (after 1 to 3 days), then stored at 20°C for 30 days (30 d) after production, and finally stored at 40°C for 40 days (40 d) after production. If the specific gravity of the cake batter exceeded 0.43 g/ cm3 , the following test was not carried out.
The results are shown in Table 1 below.

Figure 0007461127000001
Figure 0007461127000001

Figure 0007461127000002
Figure 0007461127000002

上記表1から明らかなように、比較品を用いてケーキ生地を撹拌した場合、比較品8~13では製造直後から起泡性が悪く(かさ比重が0.43g/cmを越える)、比較品2~7は20℃で30日間保存することで起泡性が損なわれ(かさ比重が0.43g/cmを越え)、さらに比較品1は40℃で40日間保存することで、起泡性が損なわれる(かさ比重が0.43g/cmを越える)ことがわかった。一方で、本発明品を用いてケーキ生地を調製した場合、起泡性に優れたケーキ生地を得ることができ、さらに本発明品を20℃で30日間、又は40℃で40日間保存した後に使用しても、起泡性に優れることが明らかとなった(本発明品1~9)。 As is clear from Table 1 above, when cake batter was stirred using comparative products, Comparative Products 8 to 13 had poor foaming properties immediately after production (bulk specific gravity exceeded 0.43 g/cm 3 ); Products 2 to 7 lose their foaming properties (bulk specific gravity exceeds 0.43 g/ cm3 ) when stored at 20°C for 30 days, and Comparative Product 1 loses foaming properties when stored at 40°C for 40 days. It was found that foamability was impaired (bulk specific gravity exceeded 0.43 g/cm 3 ). On the other hand, when a cake batter is prepared using the product of the present invention, a cake batter with excellent foaming properties can be obtained, and furthermore, after storing the product of the present invention at 20°C for 30 days or at 40°C for 40 days. Even when used, it was found that the foaming properties were excellent (Products 1 to 9 of the present invention).

[調製例2 水中油型乳化組成物の調製]
飽和モノアシルグリセロール(商品名:エキセルVS-95、花王株式会社製)、ソルビタン脂肪酸エステル(商品名:エマゾールS-10VHL、花王株式会社製)、プロピレングリコール脂肪酸エステル(商品名:グリンステッドPGMB、Danisco製)、脂肪酸(商品名:ルナックBA、花王株式会社製)、レシチン(商品名:Yelkin TS、ADM社製)、リポ蛋白質、及び菜種油(商品名:ナタネ白絞油、日清オイリオグループ株式会社製)を、下記表2に示す割合で混合し、80℃に加熱して攪拌溶解することで油相成分を調製した。
なお、表2の上欄に記載の各成分の数値は油相成分と水相成分の合計を100質量%としたときの質量%を示す。
Preparation Example 2: Preparation of oil-in-water emulsion composition
Saturated monoacylglycerol (trade name: Excel VS-95, manufactured by Kao Corporation), sorbitan fatty acid ester (trade name: Emazol S-10VHL, manufactured by Kao Corporation), propylene glycol fatty acid ester (trade name: Grinstead PGMB, manufactured by Danisco), fatty acid (trade name: Lunac BA, manufactured by Kao Corporation), lecithin (trade name: Yelkin TS, manufactured by ADM), lipoprotein, and rapeseed oil (trade name: Rapeseed Oil, manufactured by Nisshin Oillio Group, Ltd.) were mixed in the ratios shown in Table 2 below, heated to 80°C, and stirred to dissolve, to prepare an oil phase component.
The numerical values of each component shown in the upper column of Table 2 indicate mass % when the total of the oil phase components and the aqueous phase components is taken as 100 mass %.

ショ糖脂肪酸エステル(商品名:リョートーシュガーエステルS-1170S、三菱ケミカルフーズ株式会社製)、水(イオン交換水)、ソルビトール(商品名:ソルビトール(固形分70%)、花王株式会社製)、液糖(商品名:ハイマルトースMC-45、糖分70質量%、グルコースとマルトースを主成分とするシラップ、日本食品化工株式会社製)、異性化糖(商品名:ハイスイートLI(固形分76%)、大日本明治製糖株式会社製)、精製グリセリン(商品名:グリセリン、花王株式会社製)、エタノール(商品名:トレーサブル95、日本アルコール産業社製)、微結晶セルロース(商品名:セオラスRC-N30、旭化成株式会社製)、キサンタンガム(商品名:ビストップD-3000、三栄源エフ・エフ・アイ社製)、を下記表2に示す割合で混合し、80℃に調温した後、パドル120rpm、ホモミキサー1500rpmの条件で5分間攪拌溶解することで水相成分を得た。
なお、表2の上欄に記載の各成分の数値は油相成分と水相成分の合計を100質量%としたときの質量%を示す。
Sucrose fatty acid ester (product name: Ryoto Sugar Ester S-1170S, manufactured by Mitsubishi Chemical Foods Corporation), water (ion-exchanged water), sorbitol (product name: Sorbitol (solid content 70%), manufactured by Kao Corporation), liquid sugar (product name: Hi-Maltose MC-45, sugar content 70% by mass, syrup mainly composed of glucose and maltose, manufactured by Nippon Shokuhin Kako Co., Ltd.), isomerized sugar (product name: Hi-Sweet LI (solid content 76%), manufactured by Dai-Nippon Meiji Sugar Co., Ltd.), refined sugar Glycerin (trade name: Glycerin, manufactured by Kao Corporation), ethanol (trade name: Traceable 95, manufactured by Japan Alcohol Industry Co., Ltd.), microcrystalline cellulose (trade name: CEOLUS RC-N30, manufactured by Asahi Kasei Corporation), and xanthan gum (trade name: Bistop D-3000, manufactured by San-Ei Gen F.F.I.) were mixed in the ratios shown in Table 2 below, and the mixture was adjusted to 80°C. After that, the mixture was stirred and dissolved for 5 minutes under conditions of a paddle speed of 120 rpm and a homomixer speed of 1500 rpm, to obtain an aqueous phase component.
The numerical values of each component shown in the upper column of Table 2 indicate mass % when the total of the oil phase components and the aqueous phase components is taken as 100 mass %.

上記水相成分を上記油相成分に徐々に添加しながらアジホモミキサー(プライミクス社製、2M-03型社製)を用いて80℃、パドル120rpm、ホモミキサー1,500rpmの条件で10分間攪拌乳化し、水中油型乳化組成物(本発明品10、及び比較品14)を得た。得られた各乳化組成物(本発明品10、及び比較品14)と、上記調製例1で得られた乳化組成物(比較品12及び13)を20℃まで冷却した後、後述する試験例に用いた。
表2には、各乳化組成物中の飽和脂肪酸を構成脂肪酸とするモノアシルグリセロール(成分A)、炭素数6以上の糖アルコール(成分B)、ショ糖脂肪酸エステル(成分C)、水(成分D)、グリセリン(成分E)、油脂(成分F)、プロピレングリコール脂肪酸エステル(成分G)、脂肪酸(成分H)の各含有量(単位:質量%)を併せて示し、さらに成分Bの含有量と成分Eの含有量の合計値、成分Aの含有量に対する成分Cの含有量の比率(C/A、質量比)、及び成分Bの含有量に対する成分Eの含有量の比率(E/B、質量比)も併せて示した。
Gradually adding the water phase component to the oil phase component, stir for 10 minutes using an Ajihomo mixer (manufactured by Primix, Model 2M-03) at 80°C, paddle speed of 120 rpm, and homomixer speed of 1,500 rpm. The mixture was emulsified to obtain oil-in-water emulsion compositions (product 10 of the present invention and comparative product 14). After cooling each of the obtained emulsified compositions (present invention product 10 and comparative product 14) and the emulsified compositions obtained in Preparation Example 1 (comparative products 12 and 13) to 20°C, the test examples described below were performed. It was used for.
Table 2 shows monoacylglycerol (component A) whose constituent fatty acids are saturated fatty acids in each emulsified composition, sugar alcohol with 6 or more carbon atoms (component B), sucrose fatty acid ester (component C), and water (component D), the content (unit: mass %) of glycerin (component E), fats and oils (component F), propylene glycol fatty acid ester (component G), and fatty acids (component H) are also shown, and the content of component B is also shown. and the total content of component E, the ratio of the content of component C to the content of component A (C/A, mass ratio), and the ratio of the content of component E to the content of component B (E/B , mass ratio) are also shown.

[試験例2 起泡性試験]
卵(生鶏卵)260gに上白糖210gを加え、卓上ミキサー(HOBART社製N-50、ホイッパー:N-5D)で攪拌しながら20℃まで加温した。上記調製例1及び2にて作製した乳化組成物(本発明品10、又は比較品12~14)10g、及び水100gを加え中速で1分間攪拌した。薄力粉(日清製粉社製)200g、及び菜種油を20g加え、中速で9分間攪拌し、その後ケーキ生地を108mlカップに移して速やかに計量して比重を計算し、起泡性を評価した。
なお、上記乳化組成物は、製造直後(1~3日後)のもの、製造後40℃で40日間(40d)保存したもの、製造後40℃で2ヶ月間(2M)保存したもの、及び製造後40℃で3ヶ月間(3M)保存したものを使用した。
結果を下記表2に示す。
[Test Example 2 Foaming Test]
210 g of white sugar was added to 260 g of eggs (raw chicken eggs), and the mixture was heated to 20° C. while stirring with a tabletop mixer (HOBART N-50, whipper: N-5D). 10 g of the emulsified composition prepared in Preparation Examples 1 and 2 (invention product 10 or comparative products 12 to 14) and 100 g of water were added and stirred at medium speed for 1 minute. 200 g of soft flour (manufactured by Nisshin Seifun Co., Ltd.) and 20 g of rapeseed oil were added, stirred at medium speed for 9 minutes, and then the cake batter was transferred to a 108 ml cup and promptly weighed to calculate the specific gravity and evaluate the foaming properties.
The above emulsified compositions include those immediately after production (1 to 3 days later), those stored at 40 °C for 40 days (40d) after production, those stored at 40 °C for 2 months (2M) after production, and those stored at 40 °C after production (2M). It was then stored at 40°C for 3 months (3M) and used.
The results are shown in Table 2 below.

[試験例3 乳化組成物の変色試験]
上記調製例1及び2で調製した乳化組成物(本発明品10、及び比較品12~14)について、製造直後と製造後40℃で3ヶ月間保存したときの色調を、色差計(NIPPON DENSHOKU Color Meter ZE2000)を用いてCIE表色系(L、a、b)で計測した。なお、試験には視感明度(L)の値を用い、Lの値が0に近いほど明度が低い(黒色が強い)ことを意味し、Lの値が100に近いほど明度が高い(白色が強い)ことを意味する。また、保存前後の乳化組成物の外観について目視により観察した。
結果を下記表2に示す。
[Test Example 3 Discoloration test of emulsified composition]
The color tone of the emulsified compositions prepared in Preparation Examples 1 and 2 (inventive product 10 and comparative products 12 to 14) was measured using a color difference meter (NIPPON DENSHOKU) immediately after production and when stored at 40°C for 3 months after production. Color Meter ZE2000) was used for measurement according to the CIE color system (L * , a * , b * ). The visual lightness (L * ) value is used in the test; the closer the L * value is to 0, the lower the lightness (stronger black), and the closer the L * value is to 100, the lower the lightness. It means high (strong white color). In addition, the appearance of the emulsified composition before and after storage was visually observed.
The results are shown in Table 2 below.

Figure 0007461127000003
Figure 0007461127000003

表2から明らかなように、製造直後、40℃で40日間保存後、40℃で2ヶ月間保存後、又は40℃で3ヵ月間保存後の比較品14を用いてケーキ生地を撹拌した場合、起泡性に劣り、また40℃での保存期間が長くなるにつれ、撹拌後のケーキ生地の比重が大きくなり、起泡性が損なわれることがわかった。また、比較品12及び13では、製造直後のものを用いた場合であっても起泡性が顕著に劣ることがわかった。さらに、40℃保存前後における比較品14の色味を計測したところ、40℃保存前が63.6であったのに対し、保存後は59.0であり、その差は4.6であった。このことは、40℃3ヵ月間の保存により、比較品の色味が褐変したことを示している。さらに、40℃保存前後における比較品14の色味を目視により比較したところ、比較品は40℃で3ヵ月間保存することによりメイラード反応等が進行して褐変することが明らかとなった。
一方で本発明品(本発明品10)を用いてケーキ生地を撹拌した場合は、製造直後、40℃で40日間保存後、40℃で2ヶ月間保存後、又は40℃で3ヵ月間保存後のものを使用しても、撹拌後のケーキ生地の比重に差が見られず、全て起泡性に優れていた。さらに、40℃保存前後における本発明品(本発明品10)の色味を計測したところ、40℃保存前が59.1であったのに対し、保存後は59.7と、保存前後でほとんど色味が変化しなかった。さらに、40℃保存前後における本発明品(本発明品10)の色味を目視により比較したところ、本発明品は40℃で3ヵ月間保存しても外観が変化しなかった。
As is clear from Table 2, when the cake dough is stirred using the comparative product 14 immediately after production, after 40 days storage at 40°C, after 2 months storage at 40°C, or after 3 months storage at 40°C, the foaming property is poor, and as the storage period at 40°C increases, the specific gravity of the cake dough after stirring increases, and the foaming property is impaired. In addition, it was found that the foaming property of the comparative products 12 and 13 is significantly poor even when the comparative products are used immediately after production. Furthermore, when the color of the comparative product 14 was measured before and after storage at 40°C, it was 63.6 before storage at 40°C, while it was 59.0 after storage, the difference being 4.6. This indicates that the color of the comparative product has browned due to storage at 40°C for 3 months. Furthermore, when the color of the comparative product 14 before and after storage at 40°C was visually compared, it was found that the comparative product browned due to the progress of the Maillard reaction and the like when stored at 40°C for 3 months.
On the other hand, when the cake dough was stirred using the product of the present invention (product 10 of the present invention), no difference was observed in the specific gravity of the cake dough after stirring, even if it was used immediately after production, after 40 days of storage at 40°C, after 2 months of storage at 40°C, or after 3 months of storage at 40°C, and all of them had excellent foaming properties. Furthermore, when the color of the product of the present invention (product 10 of the present invention) was measured before and after storage at 40°C, it was 59.1 before storage at 40°C, while it was 59.7 after storage, so the color hardly changed before and after storage. Furthermore, when the color of the product of the present invention (product 10 of the present invention) before and after storage at 40°C was compared visually, the product of the present invention did not change in appearance even after storage at 40°C for 3 months.

[調製例3 水中油型乳化組成物の調製]
上記調製例2と同様の方法により、本発明品11、12、及び比較品15を下記表3に示す割合で調製した。なお、表3の上欄に記載の各成分の数値は油相成分と水相成分の合計を100質量%としたときの質量%を示す。
また、表3には、各乳化組成物中の飽和脂肪酸を構成脂肪酸とするモノアシルグリセロール(成分A)、炭素数6以上の糖アルコール(成分B)、ショ糖脂肪酸エステル(成分C)、水(成分D)、グリセリン(成分E)、油脂(成分F)、プロピレングリコール脂肪酸エステル(成分G)、脂肪酸(成分H)の各含有量(単位:質量%)を併せて示し、さらに成分Bの含有量と成分Eの含有量の合計値、成分Aの含有量に対する成分Cの含有量の比率(C/A、質量比)、及び成分Bの含有量に対する成分Eの含有量の比率(E/B、質量比)も併せて示した。
[Preparation Example 3: Preparation of oil-in-water emulsion composition]
Using the same method as in Preparation Example 2, Invention Products 11 and 12 and Comparative Product 15 were prepared in the proportions shown in Table 3 below. The numerical values for each component shown in the upper column of Table 3 indicate the mass % when the total of the oil phase components and the aqueous phase components is taken as 100 mass %.
Table 3 also shows the contents (unit: mass %) of monoacylglycerol (component A) having a saturated fatty acid as its constituent fatty acid, sugar alcohol having 6 or more carbon atoms (component B), sucrose fatty acid ester (component C), water (component D), glycerin (component E), oils and fats (component F), propylene glycol fatty acid ester (component G), and fatty acid (component H) in each emulsion composition, as well as the total content of component B and the content of component E, the ratio of the content of component C to the content of component A (C/A, mass ratio), and the ratio of the content of component E to the content of component B (E/B, mass ratio).

[試験例3 起泡性試験]
卵(生鶏卵)260gに上白糖210gを加え、卓上ミキサー(HOBART社製N-50、ホイッパー:N-5D)で攪拌しながら20℃まで加温した。上記調製例1にて作製した乳化組成物(本発明品1、3、4、7)、上記調製例2にて作製した乳化組成物(本発明品10)、又は上記調製例3にて作製した乳化組成物(本発明品11、12、比較品15)10g、及び水100gを加え中速で1分間攪拌した。薄力粉(日清製粉社製)200g、及び菜種油を20g加え、中速で5、7、又は9分間攪拌し、ケーキ生地を得た。得られたケーキ生地を108mlカップに移して速やかに計量し、ケーキ生地の比重(かさ比重、単位:g/cm)を算出して、起泡性を評価した。
なお、上記乳化組成物は、製造直後(1~3日後)のものを使用した。
[Test Example 3: Foaming Test]
210g of white sugar was added to 260g of eggs (raw chicken eggs), and the mixture was heated to 20°C while stirring with a tabletop mixer (HOBART N-50, whipper: N-5D). 10g of the emulsion composition prepared in Preparation Example 1 (Products 1, 3, 4, 7 of the present invention), the emulsion composition prepared in Preparation Example 2 (Product 10 of the present invention), or the emulsion composition prepared in Preparation Example 3 (Products 11, 12, Comparative Product 15 of the present invention) and 100g of water were added and stirred at medium speed for 1 minute. 200g of weak flour (Nissin Flour Milling Co., Ltd.) and 20g of rapeseed oil were added and stirred at medium speed for 5, 7, or 9 minutes to obtain a cake batter. The obtained cake batter was transferred to a 108ml cup and quickly weighed, and the specific gravity (bulk specific gravity, unit: g/cm 3 ) of the cake batter was calculated to evaluate the foamability.
The above emulsion composition was used immediately after production (after 1 to 3 days).

[試験例4 乳化組成物の製剤物性試験]
上記調製例1にて作製した乳化組成物(本発明品1、3、4、7)、上記調製例2にて作製した乳化組成物(本発明品10)、又は上記調製例3にて作製した乳化組成物(本発明品11、12、比較品15)を、容器(底面φ45mm/上面61mm/高さ47mmの逆円錐台状カップ)に隙間が出来ないように入れてヘラで表面を平らにした。PENETROMETER RPM-101(離合社製)を用い、金属円すい(種別1/1A、重さ102.5g)を乳化組成物表面に接触するように合わせ、コーンを乳化組成物中に5秒間侵入させ、乳化組成物表面から侵入したコーンの先端までの深さを測定した。侵入した深さ[mm]の10倍値をちょう度とした。
結果を上記試験例3の結果と併せて下記表3に示す。
[Test Example 4: Test of formulation properties of emulsion composition]
The emulsion composition prepared in Preparation Example 1 (Products 1, 3, 4, and 7 of the present invention), the emulsion composition prepared in Preparation Example 2 (Product 10 of the present invention), or the emulsion composition prepared in Preparation Example 3 (Products 11, 12, and Comparative Product 15 of the present invention) was placed in a container (an inverted truncated cone cup with a bottom surface of φ45 mm, a top surface of 61 mm, and a height of 47 mm) without leaving any gaps, and the surface was flattened with a spatula. Using a PENETROMETER RPM-101 (manufactured by Rigo Co., Ltd.), a metal cone (type 1/1A, weight 102.5 g) was placed so as to contact the surface of the emulsion composition, and the cone was inserted into the emulsion composition for 5 seconds, and the depth from the surface of the emulsion composition to the tip of the cone that had penetrated was measured. The value 10 times the penetration depth [mm] was taken as the consistency.
The results are shown in Table 3 below together with the results of Test Example 3 above.

Figure 0007461127000004
Figure 0007461127000004

上記表3に示されるように、本発明の規定を満たす乳化組成物は、グリセリンを含有する形態(本発明品3、4、7、及び10~12)とすることにより、ちょう度を高めることができた。そして、グリセリンを含有する本発明の乳化組成物を用いてケーキ生地を撹拌した場合、調製したケーキ生地は、起泡性に優れていた。
他方、本発明の規定を満たさない乳化組成物(比較品15)は、グリセリンを含有していてもちょう度を高めることができず、硬い物性となった。さらに、グリセリンを含有する該乳化組成物(比較品15)を用いてケーキ生地を調製しても、得られる生地の比重は大きく、起泡性にも劣っていた。
As shown in Table 3 above, the emulsified composition that satisfies the provisions of the present invention can increase the consistency by containing glycerin (products of the present invention 3, 4, 7, and 10 to 12). was completed. When cake batter was stirred using the emulsified composition of the present invention containing glycerin, the prepared cake batter had excellent foaming properties.
On the other hand, the emulsified composition (comparative product 15) that did not meet the specifications of the present invention could not increase the consistency even though it contained glycerin, and had hard physical properties. Furthermore, even when cake dough was prepared using the emulsified composition containing glycerin (Comparative Product 15), the resulting dough had a high specific gravity and was poor in foamability.

[試験例4 ケーキの焼成試験]
卵(生鶏卵)200gに上白糖180gを加え、卓上ミキサー(HOBART社製N-50、ホイッパー:N-5D)で攪拌しながら20℃まで加温した。上記調製例1にて作製した乳化組成物(本発明品3)、又は上記調製例3にて作製した乳化組成物(比較品15)30g、及び水50gを加え中速で1分間攪拌した。薄力粉(日清製粉社製)200gを加え、低速で1分間撹拌した後に、中速で比重が0.36~0.37となるまで攪拌した。その後得られたケーキ生地300gを、丸型スチール型(型6号)に流し入れ、上火175℃、下火180℃のオーブンで30分焼成してケーキを製造し、20℃で一晩放冷した。
得られたケーキについては専門パネラー5名にて、食感を下記評価基準により評価した。専門パネラー間で評価がバラついた際には、評価数値を協議により決定した。
[Test Example 4: Cake Baking Test]
180g of white sugar was added to 200g of eggs (raw chicken eggs), and the mixture was heated to 20°C while stirring with a tabletop mixer (HOBART N-50, whipper: N-5D). 30g of the emulsion composition (Product 3 of the present invention) prepared in Preparation Example 1 above or the emulsion composition (Comparative Product 15) prepared in Preparation Example 3 above, and 50g of water were added and stirred at medium speed for 1 minute. 200g of weak flour (Nissin Flour Milling Co., Ltd.) was added, stirred at low speed for 1 minute, and then stirred at medium speed until the specific gravity became 0.36 to 0.37. 300g of the resulting cake dough was then poured into a round steel mold (Mold No. 6) and baked in an oven with upper heat of 175°C and lower heat of 180°C for 30 minutes to produce a cake, which was then allowed to cool at 20°C overnight.
The texture of the resulting cakes was evaluated by five expert panelists according to the following evaluation criteria. When the evaluations varied among the expert panelists, the evaluation values were agreed upon by consensus.

-食感の評価基準-
3:バラケが良く、ネトつきなく口溶け良好
2:バラケが良いが、ネトつきがあってやや呑み込みにくい
1:バラケが悪く、強いネトつきがあって呑み込みにくい
結果を表4に示す。
- Texture evaluation criteria -
3: Good melting in the mouth with no stickiness; 2: Good melting, but a bit sticky and difficult to swallow; 1: Poor breakup, strong stickiness, and difficult to swallow. The results are shown in Table 4.

Figure 0007461127000005
Figure 0007461127000005

表4から明らかなように、比較品15の乳化組成物を用いてケーキ生地を調製した場合、生地比重が0.36~0.37となるまで撹拌するのに約9分の時間を要した。さらに、該ケーキ生地を焼成して得られたケーキは、バラケが良いが、ネトつきがあってやや呑み込みにくい結果となった。一方で本発明の乳化組成物(本発明品3)を用いてケーキ生地を調製した場合、生地比重が0.36~0.37となるまで撹拌するのに要した時間は約5分であり、速やかに起泡性を発揮することが明らかとなった。さらに、本発明の乳化組成物を用いてケーキ生地を調製し、それを焼成して得られたケーキは、バラケが良く、ネトつきがなく口溶けも良好であった。 As is clear from Table 4, when cake batter was prepared using the emulsion composition of Comparative Product 15, it took about 9 minutes to stir until the batter density reached 0.36 to 0.37. Furthermore, the cake obtained by baking this cake batter spread easily, but was sticky and somewhat difficult to swallow. On the other hand, when cake batter was prepared using the emulsion composition of the present invention (Invention Product 3), it took about 5 minutes to stir until the batter density reached 0.36 to 0.37, making it clear that it quickly exhibited foaming properties. Furthermore, the cake obtained by preparing cake batter using the emulsion composition of the present invention and baking it spread easily, was not sticky, and had good melt-in-the-mouth properties.

以上のように、本発明の乳化組成物を用いることにより、速やかに起泡し、さらに起泡性にも優れたケーキ生地を得ることができる。また本発明の乳化組成物は、長期保存しても起泡性が損なわれず、変色もせず、長期に亘り安定した起泡作用ないし品質を維持することができる。さらに本発明の乳化組成物を用いてケーキを製造することで、ケーキをバラケが良く、口どけ良好な食感とすることができる。 As described above, by using the emulsion composition of the present invention, a cake dough that foams quickly and has excellent foaming properties can be obtained. Furthermore, the emulsion composition of the present invention does not lose its foaming properties or discolor even when stored for a long period of time, and can maintain stable foaming action and quality over a long period of time. Furthermore, by producing a cake using the emulsion composition of the present invention, the cake can be made to have a texture that breaks up easily and melts in the mouth well.

Claims (6)

A:飽和脂肪酸を構成脂肪酸とするモノアシルグリセロール、
B:炭素数6以上の糖アルコール、
C:ショ糖脂肪酸エステル
D:水
I:ソルビタン脂肪酸エステル、
J:リン脂質、及び
K:低級アルコール
を含有し、前記成分Aにおける前記飽和脂肪酸がミリスチン酸、パルミチン酸、ステアリン酸、及びアラキジン酸から選ばれる脂肪酸であり、前記成分Cを構成する脂肪酸がラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、及びエルカ酸から選ばれる脂肪酸であり、
前記成分Aの含有量が2.0~10質量%、前記成分Bの含有量が20~65質量%、前記成分Cの含有量が1.0~10質量%、前記成分Dの含有量が10~30質量%、前記成分Iの含有量が0.5~5.0質量%、前記成分Jの含有量が0.05~1.0質量%、前記成分Kの含有量が1.0~10質量%、前記成分Aの含有量に対する前記成分Cの含有量の比の値が質量比で0.45~1.5であり、油脂の含有量が.0質量%以下である、ケーキ生地起泡用水中油型乳化組成物。
A: Monoacylglycerol whose constituent fatty acids are saturated fatty acids,
B: sugar alcohol with 6 or more carbon atoms,
C: sucrose fatty acid ester ,
D: water ,
I: sorbitan fatty acid ester,
J: phospholipid, and
K: lower alcohol
The saturated fatty acid in component A is a fatty acid selected from myristic acid, palmitic acid, stearic acid, and arachidic acid, and the fatty acid constituting component C is lauric acid, myristic acid, palmitic acid, and stearic acid. is a fatty acid selected from , oleic acid, behenic acid, and erucic acid,
The content of the component A is 2.0 to 10% by mass, the content of the component B is 20 to 65% by mass, the content of the component C is 1.0 to 10% by mass, and the content of the component D is 10 to 30% by mass, the content of component I is 0.5 to 5.0% by mass, the content of component J is 0.05 to 1.0% by mass, and the content of component K is 1.0%. 10% by mass, the ratio of the content of component C to the content of component A is 0.45 to 1.5 in terms of mass ratio, and the content of fats and oils is 1.5% by mass. An oil-in-water emulsion composition for foaming cake dough, the content of which is 0% by mass or less.
E:グリセリン
を含有し、前記成分Bの含有量と前記成分Eの含有量との合計が40~70質量%であり、前記Bの含有量に対する前記成分Eの含有量の比の値が質量比で0.1~1である、請求項1記載のケーキ生地起泡用水中油型乳化組成物。
E: Contains glycerin, the sum of the content of component B and the content of component E is 40 to 70% by mass, and the ratio of the content of component E to the content of B is by mass The oil-in-water emulsion composition for foaming cake dough according to claim 1, which has a ratio of 0.1 to 1.
G:プロピレングリコール脂肪酸エステル
を含有し、前記成分Gの含有量が1.5~5.5質量%である、請求項1又は2記載のケーキ生地起泡用水中油型乳化組成物。
G: The oil-in-water emulsion composition for foaming cake dough according to claim 1 or 2, which contains propylene glycol fatty acid ester, and the content of component G is 1.5 to 5.5% by mass.
H:脂肪酸
を含有し、前記成分Hの含有量が0.1~1.0質量%である、請求項1~3のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。
H: The oil-in-water emulsion composition for whipping cake batter according to any one of claims 1 to 3, comprising a fatty acid, and the content of said component H is 0.1 to 1.0 mass%.
前記油脂の含有量が0.60質量%以下である、請求項1~4のいずれか1項に記載のケーキ生地起泡用水中油型乳化組成物。The oil-in-water emulsion composition for whipping cake batter according to any one of claims 1 to 4, wherein the content of the oil or fat is 0.60% by mass or less. 請求項1~のいずれか1項に記載の乳化組成物を生地に配合してケーキ生地を調製し、該ケーキ生地を焼成することを含む、ケーキの製造方法。
A method for producing a cake, which comprises blending the emulsified composition according to any one of claims 1 to 5 into dough to prepare cake dough, and baking the cake dough.
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