Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP7517508B2 - Manufacturing method of welded joint - Google Patents
[go: Go Back, main page]

JP7517508B2 - Manufacturing method of welded joint - Google Patents

Manufacturing method of welded joint Download PDF

Info

Publication number
JP7517508B2
JP7517508B2 JP2023054743A JP2023054743A JP7517508B2 JP 7517508 B2 JP7517508 B2 JP 7517508B2 JP 2023054743 A JP2023054743 A JP 2023054743A JP 2023054743 A JP2023054743 A JP 2023054743A JP 7517508 B2 JP7517508 B2 JP 7517508B2
Authority
JP
Japan
Prior art keywords
less
surface layer
welded
steel
steel material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2023054743A
Other languages
Japanese (ja)
Other versions
JP2023085407A (en
Inventor
康 森影
哲哉 田川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
JFE Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JFE Steel Corp filed Critical JFE Steel Corp
Priority to JP2023054743A priority Critical patent/JP7517508B2/en
Publication of JP2023085407A publication Critical patent/JP2023085407A/en
Application granted granted Critical
Publication of JP7517508B2 publication Critical patent/JP7517508B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)

Description

本発明は、船舶、海洋構造物、橋梁など、さらには建設機械、建築物、タンクなどの各種溶接構造物用として好適な鋼材、特に、繰返し荷重を受ける部材用として好適な、溶接部の耐疲労特性に優れた鋼材を用いた溶接継手の製造方法に関する。ここでいう「鋼材」とは、主として厚鋼板、さらには形鋼、薄鋼板、鋼管、鋼管用原板等を含むものとする。 The present invention relates to a method for manufacturing welded joints using steel materials suitable for various welded structures such as ships, marine structures, bridges, and even construction machinery, buildings, and tanks, and in particular steel materials with excellent fatigue resistance at the welds, suitable for components that are subjected to repeated loads. The term "steel materials" as used here primarily includes thick steel plates, as well as shaped steel, thin steel plates, steel pipes, and base plates for steel pipes.

近年、溶接構造物の建造にあたっては、設計の合理化や使用する鋼材重量の低減、薄肉化による溶接施工の省力化を図るため、高強度鋼材が適用される事例が多くなってきている。このため、適用される高強度鋼材には、優れた延性、優れた低温靭性を有していることに加えて、優れた溶接性、さらには構造安全性を確保するため、優れた耐疲労特性を有していることが要求されている。溶接構造物では、溶接止端部から疲労き裂が発生し、溶接構造物の鋼材中を伝ぱして、破壊(疲労破壊)する事例が多い。これは、溶接止端部がその形状からも応力集中部となりやすいことに加えて、溶接後に引張の残留応力が生じることなどに起因するとされている。このため、溶接止端部からのき裂発生を抑制する技術として、付加溶接を施して溶接止端部の形状を改善することによって応力集中を低減させる技術、あるいはショットピーニングなどで圧縮の残留応力を導入する技術などが広く知られている。 In recent years, high-strength steel has been increasingly used in the construction of welded structures to streamline design, reduce the weight of steel used, and reduce the labor required for welding by thinning. For this reason, the high-strength steel used is required to have excellent ductility and low-temperature toughness, as well as excellent weldability and excellent fatigue resistance to ensure structural safety. In many cases, fatigue cracks initiate at the weld toe of a welded structure, propagate through the steel material of the welded structure, and cause the structure to break (fatigue fracture). This is believed to be due to the fact that the weld toe is prone to become a stress concentration area due to its shape, and that tensile residual stress occurs after welding. For this reason, widely known techniques for suppressing crack initiation from the weld toe include a technique for reducing stress concentration by improving the shape of the weld toe by applying additional welding, and a technique for introducing compressive residual stress by shot peening, etc.

しかし、このような技術を、多数存在する溶接止端部に工業的規模で施すことは、多大な労力と多大な時間とを必要とし、生産性や経済性の観点からも、現実的とは言いがたい。そこで、仮に、疲労き裂が発生したとしても、その後の鋼材中のき裂伝ぱ速度を低減させることができれば、溶接構造物の疲労寿命を延長することができる。このようなことから、鋼材の耐疲労き裂伝ぱ特性を向上させることが強く要望されている。 However, applying such technology to the many weld toes that exist on an industrial scale requires a great deal of effort and time, and is not realistic from the standpoint of productivity or economics. Therefore, even if a fatigue crack does occur, if the subsequent crack propagation rate in the steel material can be reduced, the fatigue life of a welded structure can be extended. For these reasons, there is a strong demand for improving the fatigue crack propagation resistance of steel materials.

このような要望に対し、例えば特許文献1には、「溶接継手用高疲労強度鋼板」が提案されている。特許文献1に記載された鋼板は、表裏層が板厚内部の硬さより少なくともビッカース硬さで50ポイント以上の硬度を有する高強度鋼板である。特許文献1に記載された技術では、表層組織を板厚内部の硬さより硬くして、疲労き裂の初期過程の伝播を大きく遅延させようとするものである。 In response to such demands, for example, Patent Document 1 proposes a "high fatigue strength steel plate for welded joints." The steel plate described in Patent Document 1 is a high strength steel plate in which the surface and back layers have a hardness that is at least 50 points or more harder on the Vickers hardness scale than the hardness of the inner part of the plate. The technology described in Patent Document 1 aims to significantly delay the early stage of fatigue crack propagation by making the surface layer structure harder than the hardness of the inner part of the plate.

また、特許文献2には、構造物表面での残留応力を低減させた溶接継手が提案されている。特許文献2に記載された技術では、多層溶接により溶接する際に、最終層に用いる溶接材料を、被溶接材または初層側で用いた溶接材料に比べて、同じひずみ量に対して小さい応力となる応力とひずみの関係をもつ材料とすることが好ましいとしている。これにより、溶接部の残留応力を低減させることができるとしている。 Patent Document 2 also proposes a welded joint that reduces residual stress on the surface of a structure. The technology described in Patent Document 2 suggests that when welding by multi-layer welding, it is preferable to use a welding material used in the final layer that has a stress-strain relationship that results in a smaller stress for the same amount of strain than the welding material used in the material to be welded or the first layer. This makes it possible to reduce residual stress in the weld.

また、特許文献3には、高張力鋼の溶接部疲労強度の増進方法が提案されている。特許文献3に記載された技術では、高張力鋼材表面、少なくとも溶接余盛止端相当部分に、予め母材に比して強度の低い軟質の表層を生成させておくことにより、軟質の表層を生成させない場合にくらべて、溶接部の疲労強度が高くなるとしている。 Patent Document 3 also proposes a method for increasing the fatigue strength of welds in high-tensile steel. The technology described in Patent Document 3 claims that by forming a soft surface layer with lower strength than the base material in advance on the surface of the high-tensile steel, at least in the area corresponding to the toe of the weld, the fatigue strength of the weld is increased compared to when no soft surface layer is formed.

また、特許文献4には、表層に硬化領域を有する厚鋼板が提案されている。特許文献4に記載された技術では、鋼板の表裏面から板厚方向に2mmまでの領域の平均ビッカース硬さを、板厚1/4位置から3/4位置までの領域の平均ビッカース硬さの1.20倍以上と、疲労亀裂の起点となる表層を高強度として、溶接部の疲労強度を向上させことができるとしている。 Patent Document 4 also proposes a thick steel plate with a hardened region on the surface. The technology described in Patent Document 4 claims that the average Vickers hardness of the region from the front and back sides of the steel plate to 2 mm in the plate thickness direction is 1.20 times or more the average Vickers hardness of the region from 1/4 to 3/4 of the plate thickness, making the surface layer, which is the starting point of fatigue cracks, strong and improving the fatigue strength of the welded part.

特開平6-49587号公報Japanese Patent Application Publication No. 6-49587 特開平10-146688号公報Japanese Patent Application Publication No. 10-146688 特開昭56-50797号公報Japanese Unexamined Patent Publication No. 56-50797 特開2012-92419号公報JP 2012-92419 A

しかしながら、特許文献1に記載された技術では、疲労き裂の発生に対する抑制効果が少なく、また、特許文献2に記載された技術では、最終層のみに使用する別種の溶接材料を必要とし、溶接作業が複雑となり、また、特許文献3に記載された技術では、溶接部の耐疲労特性の向上に有効な、表層の硬さおよび厚さ範囲が必ずしも明確になっていない。また、特許文献4に記載された技術では、溶接部の引張残留応力も高くなるため、耐疲労特性に対する効果が小さいと考えられる。 However, the technology described in Patent Document 1 has little effect in suppressing the occurrence of fatigue cracks, the technology described in Patent Document 2 requires a different type of welding material to be used only for the final layer, making the welding work complicated, and the technology described in Patent Document 3 does not necessarily clarify the hardness and thickness range of the surface layer that is effective in improving the fatigue resistance properties of the welded part. Furthermore, the technology described in Patent Document 4 also increases the tensile residual stress of the welded part, which is thought to have little effect on the fatigue resistance properties.

本発明は、かかる従来技術の問題を解決し、耐疲労特性に優れた鋼材を用いた溶接継手の製造方法を提案することを目的とする。 The present invention aims to solve the problems of the conventional technology and propose a method for manufacturing welded joints using steel materials with excellent fatigue resistance.

本発明者らは、上記した目的を達成するため、鋼材の板厚方向の組織変化に着目した。そして、溶接継手部の耐疲労特性向上のために、鋼材の表層部を硬さの低い軟質の層とし、中央部(以下、バルクともいう)を、耐疲労き裂伝播特性に優れた組織とすることに思い至った。鋼材表層部を軟質な層(軟質層)とすることにより、図1に模式的に示すように、疲労亀裂発生位置である溶接止端部において、引張負荷時に軟質な層がまず降伏するため、除荷時に圧縮側に転じ、軟質層には圧縮応力が残留することになり、繰返し応力負荷時に圧縮(σmin)-引張(σmax)の繰返し応力負荷となり、疲労き裂の発生が抑制されると考えた。さらに、中央部を耐疲労き裂伝播特性に優れた鋼材とすれば、発生した疲労き裂の進展(疲労き裂伝播)を抑制することができる。これらにより、溶接構造物の破断までの寿命を飛躍的に向上させることができることを知見した。 In order to achieve the above-mentioned object, the inventors focused on the change in the structure of the steel material in the thickness direction. Then, in order to improve the fatigue resistance of the welded joint, they came up with the idea of making the surface layer of the steel material a soft layer with low hardness and making the center part (hereinafter also referred to as the bulk) a structure with excellent fatigue crack propagation resistance. By making the surface layer of the steel material a soft layer (soft layer), as shown in FIG. 1, at the weld toe where fatigue cracks occur, the soft layer first yields when a tensile load is applied, and when the load is removed, the soft layer is compressed, and compressive stress remains in the soft layer, and when repeated stress loads are applied, the repeated stress load is compression (σmin) - tension (σmax), and the occurrence of fatigue cracks is suppressed. Furthermore, if the center part is made of steel material with excellent fatigue crack propagation resistance, the progression (fatigue crack propagation) of the fatigue cracks that have occurred can be suppressed. It was found that these can dramatically improve the life until fracture of a welded structure.

本発明は、かかる知見に基づき、さらに検討を加えて完成されたものである。すなわち、本発明の要旨はつぎのとおりである。
[1]鋼材同士を、溶接により溶接部を形成して接合し溶接継手とするにあたり、
前記鋼材が、片面もしくは両面の表層部と、該表層部と冶金的に接合してなる中央部と、を有する鋼材であって、
前記表層部が、ビッカース硬さで90HV以上150HV未満の硬さと、0.10mm以上鋼材全厚の30%以下の厚さと、を有し、
前記中央部が、ビッカース硬さで150HV以上の硬さを有し、かつ応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度が1.75×10-8m/cycle以下となる優れた耐疲労き裂伝播特性を有する鋼材とし、
前記溶接直後に、溶接部近傍に表層の温度が800℃以上となる加熱処理を施し、加熱停止後、表層の温度が約600℃まで低下した時点で、前記溶接部に水、圧縮空気又は液体窒素を0.1~1MPaの圧力で吹きかける急冷処理を、該溶接部の表層が100℃以下となるまで施し、その後放冷することを特徴とする溶接継手の製造方法。
[2]前記中央部が、質量%で、
C :0.02~0.25%、 Si:0.01~0.60%、
Mn:0.5~3.0%、 P :0.05%以下、
S :0.02%以下、 Al:0.10%以下
を含み、
あるいはさらに、Cu:1.0%以下、Ni:2.0%以下、Cr:1.0%以下、Mo:1.0%以下、Nb:0.1%以下、V:0.1%以下、Ti:0.1%以下、B:0.005%以下のうちから選ばれた1種以上を、
下記(1)式で定義される炭素当量Ceqが0.45%以下、
および下記(2)式で定義される溶接割れ感受性組成Pcmが0.28%以下、
を満足するように含有し、残部Fe及び不可避的不純物からなる組成を有することを特徴とする[1]に記載の溶接継手の製造方法。

Ceq(%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5・・・(1)
Pcm(%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B・・・(2)
ここで、C、Si、Mn、Ni、Cr、Mo、Cu、V、B:各元素の含有量(質量%)
The present invention was completed based on these findings and further investigations.
[1] When joining steel materials together to form a welded joint by welding,
The steel material has a surface layer portion on one or both sides and a central portion metallurgically joined to the surface layer portion,
The surface layer portion has a Vickers hardness of 90 HV or more and less than 150 HV and a thickness of 0.10 mm or more and 30% or less of the total thickness of the steel material,
the central portion is a steel material having excellent fatigue crack propagation resistance, that is, a Vickers hardness of 150 HV or more and a fatigue crack propagation rate of 1.75×10 −8 m/cycle or less when the stress intensity factor range is 15 MPa√m;
This method for manufacturing a welded joint is characterized in that immediately after the welding, a heat treatment is performed near the welded portion until the temperature of the surface layer is 800°C or higher, and when the temperature of the surface layer has dropped to approximately 600°C after the heating is stopped, a quenching treatment is performed in which water, compressed air or liquid nitrogen is sprayed onto the welded portion at a pressure of 0.1 to 1 MPa until the surface layer of the welded portion reaches 100°C or lower, and then the welded portion is allowed to cool.
[2] The central portion is, in mass%,
C: 0.02-0.25%, Si: 0.01-0.60%,
Mn: 0.5 to 3.0%, P: 0.05% or less,
S: 0.02% or less; Al: 0.10% or less;
Alternatively, one or more selected from Cu: 1.0% or less, Ni: 2.0% or less, Cr: 1.0% or less, Mo: 1.0% or less, Nb: 0.1% or less, V: 0.1% or less, Ti: 0.1% or less, and B: 0.005% or less,
The carbon equivalent Ceq defined by the following formula (1) is 0.45% or less,
and the weld crack susceptibility composition Pcm defined by the following formula (2) is 0.28% or less;
The method for producing a welded joint according to [1], characterized in that the composition satisfies the above, with the balance being Fe and unavoidable impurities.
Note Ceq (%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5...(1)
Pcm (%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B...(2)
Here, C, Si, Mn, Ni, Cr, Mo, Cu, V, B: Content of each element (mass%)

本発明によれば、溶接継手部(溶接部)の耐疲労特性を向上でき、溶接構造物の破断までの寿命が飛躍的に向上し、産業上格段の効果を奏する。 The present invention can improve the fatigue resistance of welded joints (welds), dramatically improving the lifespan of welded structures until fracture, providing significant benefits to the industry.

表層を軟質の層とした鋼材の疲労寿命向上の考え方を示す説明図である。FIG. 1 is an explanatory diagram showing the concept of improving the fatigue life of a steel material having a soft surface layer. 鋼板の断面硬さの一例を示すグラフである。1 is a graph showing an example of cross-sectional hardness of a steel plate. 鋼材の溶接方法を示す説明図である。FIG. 2 is an explanatory diagram showing a method for welding steel materials. 実施例で用いた疲労試験片の概要を示す説明図である。FIG. 2 is an explanatory diagram showing an outline of a fatigue test piece used in the examples.

[本発明に係る溶接継手の製造方法に用いる鋼材]
まず、本発明に係る溶接継手の製造方法に用いる鋼材(以下、単に「本発明鋼材」ともいう。)について説明する。
本発明鋼材は、片面もしくは両面の表層部と、該表層部と冶金的に接合してなる中央部(以下、バルクともいう)と、を有する二層または三層からなる鋼材である。本発明鋼材(鋼板)の断面硬さ分布の一例を図2に示す。
[Steel material used in the manufacturing method of the welded joint according to the present invention]
First, a steel material used in the method for producing a welded joint according to the present invention (hereinafter, simply referred to as the "invention steel material") will be described.
The steel material of the present invention is a two- or three-layer steel material having surface layers on one or both sides and a central portion (hereinafter also referred to as bulk) metallurgically joined to the surface layers. An example of the cross-sectional hardness distribution of the steel material (steel plate) of the present invention is shown in Figure 2.

表層部は、ビッカース硬さで90HV以上150HV未満の硬さと、0.10mm以上鋼材全厚の30%以下の厚さと、を有する層とする。 The surface layer has a Vickers hardness of 90 HV or more and less than 150 HV, and a thickness of 0.10 mm or more and 30% or less of the total thickness of the steel material.

表層部の硬さがビッカース硬さで90HV未満では、表層が軟化しすぎて、鋼材表面が傷つきやすくなる。一方、150HVを超えて高くなると、表層が硬くなりすぎて、耐疲労き裂発生特性の効果が低下する。このため、鋼材の表層部の硬さはビッカース硬さで90HV以上150HV未満に限定した。なお、好ましくは95~145HVである。また、軟化した表層部の厚さが0.10mm未満では、薄すぎて上記した軟化層による効果が期待できなくなる。一方、全厚の30%を超えて厚くなると、構造物として所定の強度を確保できなくなる。このため、表層部の厚さは0.10mm以上鋼材全厚の30%以下の範囲に限定した。なお、表層部の厚さは好ましくは0.5~3mmである。 If the hardness of the surface layer is less than 90 HV in Vickers hardness, the surface layer will be too soft and the steel surface will be easily damaged. On the other hand, if it exceeds 150 HV, the surface layer will be too hard and the effect of fatigue crack initiation resistance will decrease. For this reason, the hardness of the surface layer of the steel is limited to 90 HV or more and less than 150 HV in Vickers hardness. The hardness is preferably 95 to 145 HV. If the thickness of the softened surface layer is less than 0.10 mm, it will be too thin and the above-mentioned effect of the softened layer cannot be expected. On the other hand, if it is thicker than 30% of the total thickness, the required strength as a structure cannot be secured. For this reason, the thickness of the surface layer is limited to a range of 0.10 mm or more and 30% or less of the total thickness of the steel. The thickness of the surface layer is preferably 0.5 to 3 mm.

なお、鋼材の表層部に上記した軟質の層を形成する方法としては、
(イ)中央部(バルク)となる鋼材の片面もしくは両面の全面に所定厚さの軟質の鋼材(軟鋼)を接合し圧延する方法(いわゆるクラッド法)、
(ロ)中央部(バルク)となる鋼材の片面もしくは両面の全面に軟質の溶接金属を所定の厚さに肉盛り(複層溶接)して、圧延する方法、
(ハ)中央部(バルク)となる鋼材に、脱炭雰囲気(酸化雰囲気)中で高温長時間の熱処理を施し、表層を脱炭する方法、
(ニ)鋳型内に静置した中央部相当材のまわりに低炭素鋼(軟鋼)溶湯を鋳込み、凝固させて鋳片とし、圧延する方法(鋳包みクラッド法)、
(ホ)中央部(バルク)となる鋼材を一定温度で加熱したのち、放冷し表層部をフェライト変態させる方法(熱処理法)、
などが、例示できる。しかし、本発明では、上記した方法に限定されないことは言うまでもない。
The method for forming the soft layer on the surface of the steel material includes the following:
(a) A method in which a soft steel material (mild steel) of a predetermined thickness is bonded to one or both entire surfaces of a steel material that will be the central portion (bulk) and then rolled (the so-called cladding method);
(b) A method in which soft weld metal is applied to the entire surface of one or both sides of the central (bulk) steel material to a specified thickness (multi-layer welding), and then rolled.
(c) A method in which the steel material to be the central part (bulk) is subjected to a high-temperature, long-term heat treatment in a decarburizing atmosphere (oxidizing atmosphere) to decarburize the surface layer;
(d) A method in which molten low-carbon steel (mild steel) is poured around the central part of the material placed in the mold, solidified, and rolled into a cast piece (cast-in clad method);
(e) A method in which the steel material to be the central part (bulk) is heated at a constant temperature and then cooled to cause ferrite transformation of the surface part (heat treatment method);
However, it goes without saying that the present invention is not limited to the above-mentioned methods.

本発明鋼材は、上記した表層部と境界面を介して冶金的に接合した中央部(バルク)とを有する。本発明鋼材の中央部(バルク)は、ビッカース硬さで150HV以上の硬さを有し、かつ応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度が1.75×10-8m/cycle以下となる優れた耐疲労き裂伝播特性を有する層とする。 The steel material of the present invention has the above-mentioned surface layer and a central portion (bulk) metallurgically joined via a boundary surface. The central portion (bulk) of the steel material of the present invention is a layer having a Vickers hardness of 150 HV or more and excellent fatigue crack propagation resistance such that the fatigue crack propagation rate is 1.75× 10−8 m/cycle or less when the stress intensity factor range is 15 MPa√m.

中央部(バルク)の硬さが、ビッカース硬さで150HV未満では、溶接構造物用として所望の高強度を確保できなくなる。中央部の硬さは、板厚方向で表面から上記表層部を除いた位置でかつ板厚の1/4または1/2のいずれか複数点(3点以上)測定し、その平均値を用いるものとする。なお、中央部(バルク)の硬さの上限はとくに限定しないが、350HVを超えて高くなると、強度増加が顕著となり、低温靭性が低下する。このようなことから、中央部(バルク)の硬さは150HV以上、好ましくは350HV以下に限定した。 If the hardness of the central portion (bulk) is less than 150 HV in Vickers hardness, the desired high strength for a welded structure cannot be ensured. The hardness of the central portion is measured at multiple points (three or more points) in the thickness direction from the surface excluding the above-mentioned surface layer and at either 1/4 or 1/2 of the plate thickness, and the average value is used. There is no particular upper limit for the hardness of the central portion (bulk), but if it exceeds 350 HV, the strength increases significantly and low-temperature toughness decreases. For these reasons, the hardness of the central portion (bulk) is limited to 150 HV or more, and preferably 350 HV or less.

また、中央部(バルク)は、上記した硬さを有し、かつ優れた耐疲労き裂伝播特性を有する層とする。耐疲労き裂伝播特性として、応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度が1.75×10-8m/cycle以下を満足する特性であれば、発生した疲労き裂の伝播を遅延することができ、溶接構造物の破断までの寿命を大きく延長できる。なお、疲労き裂伝播特性は、ASTM E 647に準拠して測定するものとする。このような鋼材としては、例えば特開2014-95145号公報、特開2015-206112号公報等に例示されている。 The central portion (bulk) is a layer having the above-mentioned hardness and excellent fatigue crack propagation resistance. If the fatigue crack propagation resistance satisfies a fatigue crack propagation rate of 1.75×10 −8 m/cycle or less when the stress intensity factor range is 15 MPa√m, the propagation of an initiated fatigue crack can be delayed, and the life of the welded structure until fracture can be significantly extended. The fatigue crack propagation resistance is measured in accordance with ASTM E 647. Examples of such steel materials are given in, for example, JP 2014-95145 A and JP 2015-206112 A.

また、上記した特性を有する中央部(バルク)として、好適な鋼組成はつぎのとおりである。組成における質量%は、単に%で記す。 The preferred steel composition for the central portion (bulk) having the above-mentioned properties is as follows. The mass percentages in the composition are simply indicated as %.

本発明鋼材において、中央部(バルク)として好適な鋼材は、上記した硬さを有し、C:0.02~0.25%、Si:0.01~0.60%、Mn:0.5~3.0%、P:0.05%以下、S:0.02%以下、Al:0.10%以下を含み、あるいはさらにCu:1.0%以下、Ni:2.0%以下、Cr:1.0%以下、Mo:1.0%以下、Nb:0.1%以下、V:0.1%以下、Ti:0.1%以下、B:0.005%以下のうちから選ばれた1種以上を含み、炭素当量Ceqが0.45%以下および溶接割れ感受性組成Pcmが0.28%以下、を満足するように含有し、残部Fe及び不可避的不純物からなる組成を有する鋼材である。 In the steel material of the present invention, a steel material suitable for the central portion (bulk) has the above-mentioned hardness, contains C: 0.02-0.25%, Si: 0.01-0.60%, Mn: 0.5-3.0%, P: 0.05% or less, S: 0.02% or less, Al: 0.10% or less, or further contains one or more selected from Cu: 1.0% or less, Ni: 2.0% or less, Cr: 1.0% or less, Mo: 1.0% or less, Nb: 0.1% or less, V: 0.1% or less, Ti: 0.1% or less, and B: 0.005% or less, and has a carbon equivalent Ceq of 0.45% or less and a weld crack susceptibility composition Pcm of 0.28% or less, with the balance being Fe and unavoidable impurities.

ここで、炭素当量Ceqは、次(1)式
Ceq(%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5・・・(1)
ここで、C、Mn、Cu、Ni、Cr、Mo、V:各元素の含有量(質量%)
で定義される。また、溶接割れ感受性組成Pcmは、次(2)式
Pcm(%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B・・・(2)
ここで、C、Si、Mn、Ni、Cr、Mo、Cu、V、B:各元素の含有量(質量%)
で定義される。なお、上記した各式に記載された元素が含有されない場合には、0%として扱うものとする。
Here, the carbon equivalent Ceq is calculated by the following formula (1): Ceq(%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5 (1)
Here, C, Mn, Cu, Ni, Cr, Mo, V: Content of each element (mass%)
The weld crack susceptibility composition Pcm is defined as follows (2): Pcm(%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B... (2)
Here, C, Si, Mn, Ni, Cr, Mo, Cu, V, B: Content of each element (mass%)
In addition, when the element described in each formula is not contained, it is regarded as 0%.

中央部(バルク)として好適な鋼材の組成限定理由はつぎのとおりである。
C:0.02~0.25%
Cは、強度増加に寄与する元素であり、所望の高強度を確保するために、0.02%以上の含有を必要とする。一方、0.25%を超える含有は、延性、靭性や、溶接性を低下させる。このため、Cは0.02~0.25%の範囲に限定した。なお、好ましくは0.04~0.20%である。
The reasons for limiting the composition of the steel material suitable for the central portion (bulk) are as follows.
C: 0.02-0.25%
C is an element that contributes to increasing strength, and in order to ensure the desired high strength, a content of 0.02% or more is required. On the other hand, a content of more than 0.25% reduces ductility, toughness, and weldability. For this reason, the C content is limited to the range of 0.02 to 0.25%, and preferably 0.04 to 0.20%.

Si:0.01~0.60%
Siは、脱酸剤として作用するとともに、固溶して鋼材の強度増加に寄与する元素であり、所望の強度を確保するためには、0.01%以上の含有を必要とする。一方、0.60%を超えて含有すると、溶接性、靭性を低下させる。このため、Siは0.01~0.60%の範囲に限定した。なお、好ましくは0.02~0.40%である。
Si: 0.01~0.60%
Silicon acts as a deoxidizer and is an element that contributes to increasing the strength of steel by forming a solid solution. In order to ensure a desired strength, a content of 0.01% or more is required. If the content exceeds 0.60%, it reduces weldability and toughness. For this reason, the Si content is limited to the range of 0.01 to 0.60%, and preferably 0.02 to 0.40%. be.

Mn:0.5~3.0%
Mnは、焼入れ性増加を介して、鋼材の強度増加および靭性向上に寄与する元素であり、所望の強度、靭性を確保するために、0.5%以上の含有を必要とする。一方、3.0%を超える含有は、溶接性、靭性の低下を招く。このため、Mnは0.5~3.0%の範囲に限定した。なお、好ましくは0.5~2.0%である。
Mn: 0.5-3.0%
Mn is an element that contributes to increasing the strength and toughness of steel materials through increasing hardenability, and must be contained in an amount of 0.5% or more in order to ensure the desired strength and toughness. A content exceeding 0.0% leads to a decrease in weldability and toughness. For this reason, the Mn content is limited to the range of 0.5 to 3.0%, and preferably 0.5 to 2.0%. .

P:0.05%以下、S:0.02%以下
P、Sは、不純物として存在し、靭性、延性に悪影響を及ぼす元素であり、できるだけ低減することが望ましいが、Pは0.05%以下、Sは0.02%以下であれば許容できる。このため、Pは0.05%以下、Sは0.02%以下に限定した。なお、好ましくはP:0.035%以下、S:0.015%以下である。
P: 0.05% or less, S: 0.02% or less P and S are present as impurities and are elements that adversely affect toughness and ductility, and it is desirable to reduce them as much as possible, but P is permissible if it is 0.05% or less and S is 0.02% or less. For this reason, P is limited to 0.05% or less and S is limited to 0.02% or less. Preferably, P is 0.035% or less and S is 0.015% or less.

Al:0.10%以下
Alは、脱酸剤として作用するとともに、窒化物AlNを形成して、結晶粒の微細化に寄与する元素である。このような効果を得るためには、Alは0.005%以上含有することが好ましいが、0.10%を超えて多量に含有すると、延性、靭性の低下を招く。このため、Alは0.10%以下に限定した。なお、好ましくは0.020~0.050%である。
Al: 0.10% or less Al acts as a deoxidizer and also forms the nitride AlN, which contributes to the refinement of crystal grains. In order to obtain such an effect, it is preferable to contain 0.005% or more of Al, but if it is contained in a large amount exceeding 0.10%, it will lead to a decrease in ductility and toughness. For this reason, Al is limited to 0.10% or less. The preferable range is 0.020 to 0.050%.

上記した成分が基本の成分であるが、上記した成分に加えてさらに、Cu:1.0%以下、Ni:2.0%以下、Cr:1.0%以下、Mo:1.0%以下、Nb:0.1%以下、V:0.1%以下、Ti:0.1%以下、B:0.005%以下のうちから選ばれた1種以上を含んでもよい。 The above components are the basic components, but in addition to the above components, it may contain one or more selected from the following: Cu: 1.0% or less, Ni: 2.0% or less, Cr: 1.0% or less, Mo: 1.0% or less, Nb: 0.1% or less, V: 0.1% or less, Ti: 0.1% or less, B: 0.005% or less.

Cu:1.0%以下、Ni:2.0%以下、Cr:1.0%以下、Mo:1.0%以下、Nb:0.1%以下、V:0.1%以下、Ti:0.1%以下、B:0.005%以下のうちから選ばれた1種以上
Cu、Ni、Cr、Mo、Nb、V、Ti、Bはいずれも、鋼材の強度増加に寄与する元素であり、必要に応じて1種以上を選択して含有できる。
One or more selected from Cu: 1.0% or less, Ni: 2.0% or less, Cr: 1.0% or less, Mo: 1.0% or less, Nb: 0.1% or less, V: 0.1% or less, Ti: 0.1% or less, B: 0.005% or less Cu, Ni, Cr, Mo, Nb, V, Ti and B are all elements which contribute to increasing the strength of the steel material, and one or more of them can be selected and contained as necessary.

Cu:1.0%以下
Cuは、固溶してあるいは析出して、鋼材の強度増加に寄与するとともに、耐食性をも向上させる元素であり、これらの効果を得るために、0.05%以上含有することが好ましい。一方、1.0%を超える含有は、靭性の低下を招くとともに、鋼材製造時の表面疵の発生を招く。このようなことから、含有する場合は、Cuは1.0%の範囲に限定することが好ましい。なお、より好ましくは、0.1~0.8%である。
Cu: 1.0% or less Cu is an element that contributes to increasing the strength of steel material by dissolving or precipitating, and also improves corrosion resistance. In order to obtain these effects, it is preferable to contain 0.05% or more. On the other hand, a content of more than 1.0% leads to a decrease in toughness and the occurrence of surface defects during the production of steel material. For this reason, when Cu is contained, it is preferable to limit the Cu content to the range of 1.0%. More preferably, it is 0.1 to 0.8%.

Ni:2.0%以下
Niは、鋼材の強度増加に寄与するとともに、とくに低温靭性の向上、耐食性の向上、Cu起因の熱間脆性の改善に有効に寄与する元素である。このような効果を得るためには、0.2%以上含有することが好ましい。一方、2.0%を超える含有は、製造コストの高騰を招く。このため、含有する場合には、Niは2.0%以下の範囲に限定することが好ましい。なお、より好ましくは0.4~2.0%である。
Ni: 2.0% or less Ni is an element that contributes to increasing the strength of steel material and also effectively contributes to improving low-temperature toughness, corrosion resistance, and hot brittleness caused by Cu. In order to obtain such effects, it is preferable to contain 0.2% or more. On the other hand, a content of more than 2.0% leads to an increase in manufacturing costs. For this reason, when Ni is contained, it is preferable to limit the Ni content to a range of 2.0% or less. The Ni content is more preferably 0.4 to 2.0%.

Cr:1.0%以下
Crは、鋼材の強度増加に寄与する元素であり、このような効果を得るためには、0.05%以上含有することが好ましい。一方、1.0%を超える含有は、溶接性および靭性の低下を招く。このため、含有する場合には、Crは1.0%以下の範囲に限定することが好ましい。なお、より好ましくは0.05~1.0%である。
Cr: 1.0% or less Cr is an element that contributes to increasing the strength of steel materials, and in order to obtain this effect, it is preferable to contain 0.05% or more. On the other hand, a content of more than 1.0% leads to a decrease in weldability and toughness. Therefore, if Cr is contained, it is preferable to limit the Cr content to a range of 1.0% or less. The more preferable range is 0.05 to 1.0%.

Mo:1.0%以下
Moは、鋼材の強度増加に有効に寄与する元素であり、このような効果を得るためには、0.1%以上の含有を必要とする。一方、1.0%を超える含有は、溶接性および靭性の低下を招く。このため、含有する場合には、Moは1.0%以下の範囲に限定することが好ましい。なお、より好ましくは、0.2~0.8%である。
Mo: 1.0% or less Mo is an element that effectively contributes to increasing the strength of steel materials, and in order to obtain this effect, a content of 0.1% or more is required. On the other hand, a content of more than 1.0% leads to a decrease in weldability and toughness. For this reason, when Mo is contained, it is preferable to limit the Mo content to a range of 1.0% or less. More preferably, it is 0.2 to 0.8%.

Nb:0.1%以下
Nbは、固溶してあるいは炭化物、窒化物等として析出して、鋼材の強度増加に寄与するとともに、結晶粒の細粒化に寄与する元素である。このような効果を得るためには、0.005%以上の含有を必要とする。一方、0.1%を超える多量の含有は、靭性の低下を招く。このため、含有する場合には、Nbは0.1%以下の範囲に限定することが好ましい。なお、より好ましくは、0.01~0.05%である。
Nb: 0.1% or less Nb is an element that contributes to increasing the strength of steel materials and also to refining crystal grains by dissolving in solid solution or precipitating as carbides, nitrides, etc. In order to obtain such effects, a content of 0.005% or more is required. On the other hand, a large content exceeding 0.1% leads to a decrease in toughness. For this reason, when Nb is contained, it is preferable to limit the Nb content to a range of 0.1% or less. More preferably, it is 0.01 to 0.05%.

V:0.1%以下
Vは、Nbと同様に、炭化物等として析出して、鋼材の強度増加に寄与する元素である。このような効果を得るためには、0.02%以上含有することが好ましい。一方、0.1%を超える含有は、溶接性および靭性の低下を招く。このため、含有する場合には、Vは0.1%以下の範囲に限定することが好ましい。なお、より好ましくは、0.02~0.8%である。
V: 0.1% or less Like Nb, V is an element that precipitates as carbides and the like, and contributes to increasing the strength of steel. In order to obtain such an effect, it is preferable to contain 0.02% or more. On the other hand, a content exceeding 0.1% leads to a decrease in weldability and toughness. For this reason, when V is contained, it is preferable to limit the V content to a range of 0.1% or less. More preferably, it is 0.02 to 0.8%.

Ti:0.1%以下
Tiは、炭化物、窒化物等の析出物の析出を介して鋼材の強度増加に寄与するとともに、溶接部靭性の向上に寄与する元素である。このような効果を得るためには、0.02%以上含有することが好ましい。一方、0.1%を超える含有は、製造コストの上昇を招く。このため、含有する場合には、Tiは0.1%以下の範囲に限定することが好ましい。なお、より好ましくは、0.02~0.8%である。
Ti: 0.1% or less Ti is an element that contributes to increasing the strength of steel materials through the precipitation of precipitates such as carbides and nitrides, and also contributes to improving the toughness of welds. In order to obtain such effects, it is preferable to contain 0.02% or more. On the other hand, a content exceeding 0.1% leads to an increase in manufacturing costs. Therefore, when Ti is contained, it is preferable to limit the Ti content to a range of 0.1% or less. More preferably, it is 0.02 to 0.8%.

B:0.005%以下
Bは、焼入れ性向上を介して鋼材の強度増加に寄与する元素である。このような効果を得るためには、0.0001%以上含有することが好ましい。一方、0.005%を超える多量の含有は、溶接性の低下を招く。このため、含有する場合には、Bは0.005%以下の範囲に限定することが好ましい。なお、より好ましくは、0.0001~0.001%である。
B: 0.005% or less B is an element that contributes to increasing the strength of steel material by improving hardenability. To obtain such an effect, it is preferable to contain 0.0001% or more. On the other hand, a large content of more than 0.005% leads to a decrease in weldability. For this reason, when B is contained, it is preferable to limit the B content to a range of 0.005% or less. More preferably, it is 0.0001 to 0.001%.

本発明鋼材の中央部では、上記した成分を上記した範囲内で、かつ炭素当量Ceq:0.45%以下、溶接割れ感受性組成Pcm:0.28%以下を満足するように含有する。なお、Ceq、Pcmは、次(1)式、次(2)式
Ceq(%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5・・・(1)
Pcm(%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B・・・(2)
ここで、C、Si、Mn、Ni、Cr、Mo、Cu、V、B:各元素の含有量(質量%)
で、それぞれ定義される。
The central portion of the steel material of the present invention contains the above-mentioned components within the above-mentioned ranges, and satisfies the carbon equivalent Ceq: 0.45% or less and the weld crack susceptibility Pcm: 0.28% or less. Ceq and Pcm are expressed by the following formulas (1) and (2): Ceq(%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5... (1)
Pcm (%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B...(2)
Here, C, Si, Mn, Ni, Cr, Mo, Cu, V, B: Content of each element (mass%)
are defined as follows, respectively.

Ceqが0.45%を、Pcmが0.28%を、それぞれ超えると、溶接硬化性、溶接割れ感受性が高くなりすぎて、溶接部の硬さが高くなり、溶接割れの発生傾向が高くなる。 If Ceq exceeds 0.45% and Pcm exceeds 0.28%, respectively, the weld hardenability and weld crack susceptibility become too high, the hardness of the weld increases, and the tendency for weld cracks to occur increases.

上記した構成の本発明鋼材を溶接して溶接構造物とすれば、繰返し応力負荷に際し、図1に示すように、軟質な表層部の存在により、引張負荷時に軟質な表層部がまず降伏するため、除荷時に圧縮側に転じ、圧縮-引張の繰返し応力負荷となる。そのため、軟質の表層部がない場合に比べ、疲労き裂の発生が抑制され、中央部が耐疲労き裂伝播特性に優れた特性を有していれば、き裂の伝播速度が低くなり、耐疲労特性が向上した溶接構造物となる。 When the steel material of the present invention having the above-mentioned configuration is welded to form a welded structure, when repeated stress loads are applied, as shown in Figure 1, due to the presence of the soft surface layer, the soft surface layer will first yield when a tensile load is applied, and when the load is removed, the load changes to the compressive side, resulting in repeated compression-tension stress loads. Therefore, compared to when there is no soft surface layer, the occurrence of fatigue cracks is suppressed, and if the central part has excellent fatigue crack propagation resistance properties, the crack propagation speed will be slower, resulting in a welded structure with improved fatigue resistance properties.

[本発明に係る溶接継手の製造方法]
次に、耐疲労特性が向上した溶接構造物とするための好ましい本発明に係る溶接継手の製造方法について説明する。
[Method of manufacturing a welded joint according to the present invention]
Next, a preferred method for manufacturing a welded joint according to the present invention for producing a welded structure having improved fatigue resistance will be described.

鋼材同士を、溶接により溶接部を形成して接合して、溶接構造物(溶接継手)を製造するにあたり、鋼材同士の溶接は、とくにその溶接条件を限定する必要はないが、鋼材の強度に対応した溶接材料を用いて、当該溶接材料の標準の溶接条件で溶接することが望ましい。そして、溶接直後に、溶接部に急冷処理を、該溶接部の表層が100℃以下となるまで施し、その後放冷する。溶接直後に、溶接部に急冷処理を施すと、溶接部とその近傍の表層だけが先に冷却され収縮するため、溶接止端部には一時的に引張の残留応力が発生する。その後の冷却で、中心部も収縮するため、溶接止端部の引張の残留応力が低下するか、圧縮の残留応力が発生する。これにより、き裂発生位置である溶接止端部の耐疲労き裂発生特性が向上することになる。この状況を図3(a)に模式的に示す。なお、溶接後に、溶接部近傍(溶接止端部近傍)の表層のみに急冷処理を施す方法として、水、圧縮空気や液体窒素等を、ノズル等を介して、吹きかける方法が例示できる。また、圧縮空気を吹き付ける場合、吹き付ける圧縮空気の圧力は、0.1~1MPaとすることが好ましい。圧縮空気の圧力が0.1MPa未満では冷却が不十分となり、一方、1MPaを超えて大きくなると、機器の安全上の問題がある。 When steel materials are joined together by welding to form a welded joint to manufacture a welded structure (welded joint), there is no need to limit the welding conditions for welding steel materials together, but it is desirable to use welding materials that correspond to the strength of the steel materials and to weld them under the standard welding conditions for the welding materials. Then, immediately after welding, the weld is quenched until the surface layer of the weld falls to 100°C or less, and then allowed to cool. When the weld is quenched immediately after welding, only the weld and the surface layer in its vicinity are cooled and contracted first, so that tensile residual stress temporarily occurs at the weld toe. Subsequent cooling causes the center to shrink as well, so that the tensile residual stress at the weld toe decreases or compressive residual stress occurs. This improves the fatigue crack initiation resistance of the weld toe, which is the crack initiation position. This situation is shown diagrammatically in Figure 3(a). As a method for rapidly cooling only the surface layer near the weld (near the weld toe) after welding, an example is to spray water, compressed air, liquid nitrogen, etc. through a nozzle, etc. When spraying compressed air, the pressure of the sprayed compressed air is preferably 0.1 to 1 MPa. If the pressure of the compressed air is less than 0.1 MPa, cooling will be insufficient, while if it exceeds 1 MPa, there will be a safety problem for the equipment.

また、上記した溶接後で上記した溶接部への急冷処理の前に、溶接部に加熱処理を施し、しかる後に該溶接部に前記急冷処理を施してもよい。溶接部への加熱処理により、溶接部全体が膨張し、その後の急冷処理による中心部の収縮により、溶接止端部の引張の残留応力の低下量が大きくなり、溶接部止端部の耐疲労き裂発生特性はさらに改善される。この状況を図3(b)に模式的に示す。なお、溶接後に、溶接部近傍全体を加熱するには、ガスバーナー、高周波加熱炉等を用いることができる。なお、加熱は、表層の温度が800℃以上になる加熱とすることが好ましい。 In addition, after the above-mentioned welding and before the above-mentioned quenching treatment of the welded portion, the welded portion may be subjected to a heat treatment, and then the quenching treatment may be applied to the welded portion. The heat treatment of the welded portion causes the entire welded portion to expand, and the subsequent quenching treatment causes the center portion to shrink, which increases the amount of reduction in the tensile residual stress at the weld toe, and further improves the fatigue crack initiation resistance of the welded toe. This situation is shown diagrammatically in Figure 3(b). Note that a gas burner, high-frequency heating furnace, etc. can be used to heat the entire vicinity of the welded portion after welding. Note that the heating is preferably performed so that the surface layer temperature reaches 800°C or higher.

このような溶接を、ビッカース硬さで150HV以上の硬さを有し、かつ応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度が1.75×10-8m/cycle以下となる優れた耐疲労き裂伝播特性を有する鋼材同士の溶接に適用すれば、溶接止端部の耐疲労き裂発生特性がさらに向上し、しかも発生した疲労き裂の伝播も遅くなり、溶接構造物の破断までの寿命が延長されることになる。 If this type of welding is applied to welding between steel materials that have a Vickers hardness of 150 HV or more and excellent fatigue crack propagation resistance, such as a fatigue crack propagation rate of 1.75 x 10 -8 m/cycle or less when the stress intensity factor range is 15 MPa√m, the fatigue crack initiation resistance of the weld toe will be further improved, and the propagation of any fatigue cracks that do occur will be slowed down, thereby extending the life of the welded structure until fracture.

さらに、上記した溶接を、本発明鋼材である、片面もしくは両面の表層部と、該表層部と冶金的に接合してなる中央部と、を有し、かつ前記表層部が、ビッカース硬さで90HV以上150HV未満の硬さと、0.10mm以上鋼材全厚の30%以下の厚さと、を有し、前記中央部が、ビッカース硬さで150HV以上の硬さを有し、かつ応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度が1.75×10-8m/cycle以下となる優れた耐疲労き裂伝播特性を有する鋼材に適用することが、溶接構造物の耐疲労特性の更なる向上のために好ましい。軟質な表層部と優れた耐疲労き裂伝播特性を有する中央部との組合せにより、溶接部止端部の耐疲労き裂発生特性が向上するとともに、発生した疲労き裂の伝播速度も遅くなって、全体として、溶接構造物の破断までの寿命が大きく延長されることになる。 Furthermore, in order to further improve the fatigue resistance of a welded structure, it is preferable to apply the above-mentioned welding to a steel material of the present invention, which has a surface layer portion on one or both sides and a central portion metallurgically joined to the surface layer portion, and wherein the surface layer portion has a Vickers hardness of 90 HV or more but less than 150 HV and a thickness of 0.10 mm or more and 30% or less of the total thickness of the steel material, and the central portion has a Vickers hardness of 150 HV or more and has excellent fatigue crack propagation resistance such that the fatigue crack propagation rate is 1.75×10 -8 m/cycle or less when the stress intensity factor is in the range of 15 MPa√m. The combination of the soft surface layer portion and the central portion having excellent fatigue crack propagation resistance improves the fatigue crack initiation resistance of the weld toe and also slows down the propagation rate of an initiated fatigue crack, thereby significantly extending the life of the welded structure as a whole.

以下、実施例に基づき、さらに本発明について説明する。 The present invention will be further explained below based on examples.

(実施例1)
表1に示す組成の鋼板A2の両面に、軟鋼用溶接材料を用い溶接金属を多層盛溶接で形成し、熱間圧延したのち、さらに大気雰囲気中で熱処理(900℃×48時間保持)を施して表面を脱炭させたのち、水冷して、両面の表層に軟質層を有する鋼板(板厚25mm)Aとした。表層部A1は表1に示す組成を有し、硬さが122HV、厚さが平均で3.2mmの軟質な層となっている。なお、中心部(バルク)用の鋼板A2は、590MPa級の高張力鋼板であり、平均硬さ(板厚中央位置付近で測定)が195HVで、ASTM E 647の規定に準拠して測定した、応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度da/dNが、1.75×10-8m/cycle以下の1.27×10-8m/cycleの耐疲労き裂伝播特性に優れた鋼板である。
Example 1
A weld metal was formed by multi-layer welding on both sides of steel plate A2 having the composition shown in Table 1 using a welding material for mild steel, hot-rolled, and then heat-treated in air (holding at 900°C for 48 hours) to decarburize the surface, followed by water-cooling to obtain steel plate A (plate thickness 25 mm) having soft layers on both surfaces. The surface layer A1 has the composition shown in Table 1 and is a soft layer with a hardness of 122 HV and an average thickness of 3.2 mm. In addition, steel plate A2 for the center (bulk) is a high-tensile steel plate of 590 MPa class, with an average hardness (measured near the center of the plate thickness) of 195 HV, and excellent fatigue crack propagation resistance, with a fatigue crack propagation rate da/dN of 1.27 x 10 -8 m/cycle, less than 1.75 x 10 -8 m/cycle, when the stress intensity factor range is 15 MPa√m, measured in accordance with the provisions of ASTM E 647.

また、表1に示す組成の鋼板C2の両面に、表1に示す組成の鋼板C1を張り合わせたのち、熱間圧延を施し、鋼板(板厚23mm)Cとした。鋼板Cは、両面の表層に軟質層を有するクラッド鋼板である。表層部は表1に示す組成を有し、硬さが116HV、厚さが平均で3.0mmの軟質な層となっている。なお、中心部(バルク)用の鋼板C1は、590MPa級の高張力鋼板であり、表1に示すように、平均硬さ(板厚中央位置付近で測定)が220HVで、ASTM E 647の規定に準拠して測定した、応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度da/dNが、1.33×10-8m/cycleの耐疲労き裂伝播特性に優れた鋼板である。 In addition, the steel plate C1 having the composition shown in Table 1 was laminated on both sides of the steel plate C2 having the composition shown in Table 1, and then hot rolling was performed to obtain the steel plate C (plate thickness 23 mm). The steel plate C is a clad steel plate having a soft layer on the surface of both sides. The surface layer has the composition shown in Table 1, and is a soft layer having a hardness of 116 HV and an average thickness of 3.0 mm. The steel plate C1 for the center (bulk) is a high-tensile steel plate of 590 MPa class, and as shown in Table 1, the average hardness (measured near the center position of the plate thickness) is 220 HV, and the fatigue crack propagation rate da/dN at a stress intensity factor range of 15 MPa√m measured in accordance with the provisions of ASTM E 647 is 1.33×10 −8 m/cycle, which is excellent in fatigue crack propagation resistance.

得られた鋼板A、鋼板Cから、試験材(幅80mm×長さ600mm)を採取し、該試験材の両面に鋼板(板厚10mm×幅60mm×長さ100mm)を図4に示すように、回し溶接によって接合し面外ガセット継手を作製した。回し溶接の溶接条件は、平均で、電流:240A、電圧:31V、溶接速度:20cm/minとした。なお、溶接材料はフラックス入りワイヤ(JIS Z3313 T 49J 0 T1-0C A-U相当)を用いた。なお、シールドガスは80%Ar-20%CO2とした。 Test materials (width 80 mm x length 600 mm) were taken from the obtained steel plates A and C, and steel plates (plate thickness 10 mm x width 60 mm x length 100 mm) were joined to both sides of the test materials by box welding to produce out-of-plane gusset joints, as shown in Figure 4. The welding conditions for the box welding were, on average, current: 240 A, voltage: 31 V, and welding speed: 20 cm/min. The welding material used was flux-cored wire (equivalent to JIS Z3313 T 49J 0 T1-0C A-U). The shielding gas was 80% Ar-20% CO2 .

得られた面外ガセット継手について、疲労試験を実施し、破断までの寿命(cycle)を測定した。疲労試験は、試験片長手方向を負荷方向とし、表2に示す負荷応力範囲(応力比0.1)で実施した。 A fatigue test was conducted on the obtained out-of-plane gusset joint to measure the life (cycle) until fracture. The fatigue test was conducted in the longitudinal direction of the test piece as the load direction, within the load stress range (stress ratio 0.1) shown in Table 2.

なお、表層部に軟質の層を有しない鋼板Bについて、上記したと同様の面外ガセット継手を作製し、同様の疲労試験を実施し、破断までの寿命(cycle)を測定し、比較例とした。得られた結果を表2に示す。 For steel plate B, which does not have a soft layer on the surface, an out-of-plane gusset joint similar to that described above was fabricated and subjected to a similar fatigue test to measure the life (cycles) until fracture, which was used as a comparative example. The results obtained are shown in Table 2.

Figure 0007517508000001
Figure 0007517508000001

Figure 0007517508000002
Figure 0007517508000002

本発明例(試験No.1~3、No.7~8)は、表層部が軟質でない鋼板Bを用いた溶接継手(比較例:試験No.4~6)の場合に比べて、破断寿命は向上している。
(実施例2)
表1に示す鋼板A、B、D、Eからそれぞれ、試験材(幅80mm×長さ600mm)を採取し、実施例1と同様に、該試験材の両面に鋼板(板厚10mm×幅60mm×長さ100mm)を図4に示すように、回し溶接によって接合し、面外ガセット継手を作製した。なお、回し溶接の溶接条件は、実施例1と同様に、平均で、電流:240A、電圧:31V、溶接速度:20cm/minとした。なお、溶接材料はフラックス入りワイヤ(JIS Z3313 T 49J 0 T1-0C A-U相当)を用いた。なお、シールドガスは80%Ar-20%CO2とした。
The inventive examples (Test Nos. 1 to 3, 7 to 8) had improved fracture life compared to the welded joints (Comparative Examples: Test Nos. 4 to 6) using Steel Plate B whose surface layer was not soft.
Example 2
Test pieces (width 80 mm x length 600 mm) were taken from each of the steel plates A, B, D, and E shown in Table 1, and steel plates (plate thickness 10 mm x width 60 mm x length 100 mm) were joined to both sides of the test pieces by box welding as shown in Figure 4 to produce out-of-plane gusset joints, as in Example 1. The welding conditions for the box welding were, on average, current: 240 A, voltage: 31 V, and welding speed: 20 cm/min, as in Example 1. The welding material used was a flux-cored wire (equivalent to JIS Z3313 T 49J 0 T1-0C A-U). The shielding gas was 80% Ar-20% CO2 .

そして、上記した溶接直後に、ガスバーナーで溶接部近傍を表面温度が900℃程度になるまで加熱し、加熱停止後、表面温度が約600℃まで低下した時点で、溶接部近傍に圧縮空気(圧力:0.9MPa)を吹きかける急冷処理を施し、表層が97℃に低下した時点で、急冷処理を終了し、室温まで放冷した。 Immediately after the above welding, the vicinity of the weld was heated with a gas burner until the surface temperature reached approximately 900°C. After the heating was stopped, when the surface temperature had dropped to approximately 600°C, a rapid cooling process was carried out by blowing compressed air (pressure: 0.9 MPa) around the weld. When the surface temperature had dropped to 97°C, the rapid cooling process was terminated and the weld was allowed to cool to room temperature.

得られた面外ガセット継手を試験片として、実施例1と同様に、疲労試験を実施し、破断までの寿命(cycle)を測定した。なお、疲労試験条件は、表3に示す負荷応力範囲(応力比0.1)とした。 Using the obtained out-of-plane gusset joint as a test piece, a fatigue test was performed in the same manner as in Example 1, and the life (cycle) until fracture was measured. The fatigue test conditions were the load stress range (stress ratio 0.1) shown in Table 3.

得られた結果を表3に示す。 The results are shown in Table 3.

Figure 0007517508000003
Figure 0007517508000003

鋼板Bを用いた溶接継手(面外ガセット継手)の溶接後に、溶接部に加熱、急冷処理を施した本発明例(試験No.11、No.12)はいずれも、溶接部への急冷を行わない例(試験No.5、No.6参照:表2)に比べて、継手の破断寿命が向上している。また、表層部に軟質の層を有する鋼板Aを用いた溶接継手(試験No.9、No.10)においても、溶接後の溶接部への急冷処理により、継手の破断寿命が向上している(試験No.2、No.3参照)。また、鋼板D、Eを用いた溶接継手(試験No.13~16)についても、継手の破断寿命が向上し、優れた耐疲労特性を有する溶接継手となっている。 In the present invention examples (Tests No. 11 and No. 12) in which the welded joint (out-of-plane gusset joint) using steel plate B was heated and quenched after welding, the fracture life of the joint was improved compared to the examples in which the welded joint was not quenched (see Tests No. 5 and No. 6: Table 2). In the welded joints using steel plate A, which has a soft layer on the surface (Tests No. 9 and No. 10), the fracture life of the joint was also improved by quenching the welded joint after welding (see Tests No. 2 and No. 3). In the welded joints using steel plates D and E (Tests No. 13 to 16), the fracture life of the joint was also improved, resulting in welded joints with excellent fatigue resistance.

Claims (2)

鋼材同士を、溶接により溶接部を形成して接合し溶接継手とするにあたり、
前記鋼材が、片面もしくは両面の表層部と、該表層部と冶金的に接合してなる中央部と、を有する鋼材であって、
前記表層部が、ビッカース硬さで90HV以上150HV未満の硬さと、0.10mm以上鋼材全厚の30%以下の厚さと、を有し、
前記中央部が、ビッカース硬さで150HV以上の硬さを有し、かつ応力拡大係数範囲15MPa√mのときの疲労き裂伝播速度が1.75×10-8m/cycle以下となる優れた耐疲労き裂伝播特性を有する鋼材とし、
前記溶接直後に、溶接部近傍に表層の温度が800℃以上となる加熱処理を施し、加熱停止後、表層の温度が600℃まで低下した時点で、前記溶接部に水、圧縮空気又は液体窒素を0.1~1MPaの圧力で吹きかける急冷処理を、該溶接部の表層が100℃以下となるまで施し、その後放冷することを特徴とする溶接継手の製造方法。
When joining steel materials together to form a welded joint,
The steel material has a surface layer portion on one or both sides and a central portion metallurgically joined to the surface layer portion,
The surface layer portion has a Vickers hardness of 90 HV or more and less than 150 HV and a thickness of 0.10 mm or more and 30% or less of the total thickness of the steel material,
the central portion is a steel material having excellent fatigue crack propagation resistance, that is, a Vickers hardness of 150 HV or more and a fatigue crack propagation rate of 1.75×10 −8 m/cycle or less when the stress intensity factor range is 15 MPa√m;
This method for manufacturing a welded joint is characterized in that immediately after the welding, a heat treatment is performed near the welded portion until the temperature of the surface layer is 800°C or higher, and when the temperature of the surface layer drops to 600°C after heating is stopped, a quenching treatment is performed in which water, compressed air or liquid nitrogen is sprayed onto the welded portion at a pressure of 0.1 to 1 MPa until the surface layer of the welded portion reaches 100°C or lower, and then the welded portion is allowed to cool.
前記中央部が、質量%で、
C :0.02~0.25%、 Si:0.01~0.60%、
Mn:0.5~3.0%、 P :0.05%以下、
S :0.02%以下、 Al:0.10%以下
を含み、
あるいはさらに、Cu:1.0%以下、Ni:2.0%以下、Cr:1.0%以下、Mo:1.0%以下、Nb:0.1%以下、V:0.1%以下、Ti:0.1%以下、B:0.005%以下のうちから選ばれた1種以上を、
下記(1)式で定義される炭素当量Ceqが0.45%以下、
および下記(2)式で定義される溶接割れ感受性組成Pcmが0.28%以下、
を満足するように含有し、残部Fe及び不可避的不純物からなる組成を有することを特徴とする請求項1に記載の溶接継手の製造方法。

Ceq(%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5・・・(1)
Pcm(%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B・・・(2)
ここで、C、Si、Mn、Ni、Cr、Mo、Cu、V、B:各元素の含有量(質量%)
The central portion is, in mass%,
C: 0.02-0.25%, Si: 0.01-0.60%,
Mn: 0.5 to 3.0%, P: 0.05% or less,
S: 0.02% or less; Al: 0.10% or less;
Alternatively, one or more selected from Cu: 1.0% or less, Ni: 2.0% or less, Cr: 1.0% or less, Mo: 1.0% or less, Nb: 0.1% or less, V: 0.1% or less, Ti: 0.1% or less, and B: 0.005% or less,
The carbon equivalent Ceq defined by the following formula (1) is 0.45% or less,
and the weld crack susceptibility composition Pcm defined by the following formula (2) is 0.28% or less;
2. The method for producing a welded joint according to claim 1, characterized in that the composition satisfies the above, with the balance consisting of Fe and unavoidable impurities.
Ceq (%)=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+V)/5...(1)
Pcm (%)=C+Si/30+Mn/20+Ni/60+Cr/20+Mo/15+Cu/20+V/10+5B...(2)
Here, C, Si, Mn, Ni, Cr, Mo, Cu, V, B: Content of each element (mass%)
JP2023054743A 2020-05-29 2023-03-30 Manufacturing method of welded joint Active JP7517508B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2023054743A JP7517508B2 (en) 2020-05-29 2023-03-30 Manufacturing method of welded joint

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2020093900A JP7298548B2 (en) 2020-05-29 2020-05-29 Steel material with excellent fatigue resistance in welds
JP2023054743A JP7517508B2 (en) 2020-05-29 2023-03-30 Manufacturing method of welded joint

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP2020093900A Division JP7298548B2 (en) 2020-05-29 2020-05-29 Steel material with excellent fatigue resistance in welds

Publications (2)

Publication Number Publication Date
JP2023085407A JP2023085407A (en) 2023-06-20
JP7517508B2 true JP7517508B2 (en) 2024-07-17

Family

ID=78848142

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2020093900A Active JP7298548B2 (en) 2020-05-29 2020-05-29 Steel material with excellent fatigue resistance in welds
JP2023054743A Active JP7517508B2 (en) 2020-05-29 2023-03-30 Manufacturing method of welded joint

Family Applications Before (1)

Application Number Title Priority Date Filing Date
JP2020093900A Active JP7298548B2 (en) 2020-05-29 2020-05-29 Steel material with excellent fatigue resistance in welds

Country Status (1)

Country Link
JP (2) JP7298548B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102911966B1 (en) * 2023-02-21 2026-01-13 주식회사 포스코 Welding member having excellent fatigue property of welding portion

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003239037A (en) 2002-02-19 2003-08-27 Nippon Steel Corp Multilayer steel material for welded structure excellent in fatigue strength, method for producing the same, and welded steel structure
JP2005240177A (en) 2004-01-30 2005-09-08 Jfe Steel Kk Manufacturing method of steel with excellent strength uniformity in the thickness direction and fatigue crack propagation characteristics
JP2005240176A (en) 2004-01-30 2005-09-08 Jfe Steel Kk Manufacturing method of steel with excellent strength uniformity in the thickness direction and fatigue crack propagation characteristics
JP2007231308A (en) 2006-02-27 2007-09-13 Jfe Steel Kk Thick steel plate with excellent fatigue resistance
JP2014095145A (en) 2012-10-10 2014-05-22 Jfe Steel Corp Steel sheet for welded structure excellent in weldability and fatigue crack propagation resistance and its manufacturing method
JP2015206112A (en) 2014-04-09 2015-11-19 Jfeスチール株式会社 High strength steel material with excellent fatigue crack propagation resistance and method for producing the same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5650797A (en) * 1979-04-11 1981-05-08 Kawasaki Steel Corp Increasing method for weld-part fatigue strength of high-tension steel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003239037A (en) 2002-02-19 2003-08-27 Nippon Steel Corp Multilayer steel material for welded structure excellent in fatigue strength, method for producing the same, and welded steel structure
JP2005240177A (en) 2004-01-30 2005-09-08 Jfe Steel Kk Manufacturing method of steel with excellent strength uniformity in the thickness direction and fatigue crack propagation characteristics
JP2005240176A (en) 2004-01-30 2005-09-08 Jfe Steel Kk Manufacturing method of steel with excellent strength uniformity in the thickness direction and fatigue crack propagation characteristics
JP2007231308A (en) 2006-02-27 2007-09-13 Jfe Steel Kk Thick steel plate with excellent fatigue resistance
JP2014095145A (en) 2012-10-10 2014-05-22 Jfe Steel Corp Steel sheet for welded structure excellent in weldability and fatigue crack propagation resistance and its manufacturing method
JP2015206112A (en) 2014-04-09 2015-11-19 Jfeスチール株式会社 High strength steel material with excellent fatigue crack propagation resistance and method for producing the same

Also Published As

Publication number Publication date
JP7298548B2 (en) 2023-06-27
JP2021188088A (en) 2021-12-13
JP2023085407A (en) 2023-06-20

Similar Documents

Publication Publication Date Title
CN106102940B (en) Heavy wall high tenacity high-tensile steel and its manufacture method
JP6725020B2 (en) Valve plate and method for manufacturing valve plate
CN107109561A (en) The excellent heavy wall high tenacity high-tensile steel of property uniform in material and its manufacture method
KR20170128574A (en) Thick steel sheet for structural pipe, method for manufacturing thick steel sheet for structural pipe, and structural pipe
US7967923B2 (en) Steel plate that exhibits excellent low-temperature toughness in a base material and weld heat-affected zone and has small strength anisotropy, and manufacturing method thereof
WO2009072663A1 (en) Steel with weld heat-affected zone having excellent ctod properties and process for producing the steel
JPWO2001057286A1 (en) High-strength, high-toughness seamless steel pipe for line pipe and manufacturing method thereof
JP2014008513A (en) Method for manufacturing continuously cast slab and method for manufacturing high strength cold-rolled steel sheet
CN110088331B (en) Hot-rolled steel sheet for electric resistance welded steel pipe having excellent weldability and method for producing same
US9669482B2 (en) Submarine hull steel having enhanced weldability
JP7517508B2 (en) Manufacturing method of welded joint
JP5716419B2 (en) Steel plate with excellent fatigue resistance and method for producing the same
JP2005187934A (en) Steel material with excellent fatigue characteristics and method for producing the same
JP2011080103A (en) Method for manufacturing high toughness steel
JP5028761B2 (en) Manufacturing method of high strength welded steel pipe
JP3432428B2 (en) Deformed bar for reinforcing steel and method for producing the same
JP7207358B2 (en) Manufacturing method of low yield ratio high tensile steel plate
KR100723201B1 (en) High strength toughness steel with excellent toughness of multi-layer welded part and manufacturing method
JPH05245657A (en) Production of high ni alloy clad steel sheet excellent in brittleness propagation stoppage property of base metal
JP3432430B2 (en) Deformed bar for reinforcing steel and method for producing the same
KR101707340B1 (en) Chain steel and manufacturing method thereof
JP5126790B2 (en) Steel material excellent in fatigue crack growth resistance and method for producing the same
JPH09143555A (en) Method for producing high strength thick steel plate with excellent toughness
JP2025130176A (en) Welded joint and manufacturing method thereof
KR101400516B1 (en) Steel sheet for line pipe and method of manufacturing the same

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20230330

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20240430

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20240520

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20240604

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20240617

R150 Certificate of patent or registration of utility model

Ref document number: 7517508

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150