JP7544003B2 - Tank manufacturing method - Google Patents
Tank manufacturing method Download PDFInfo
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- JP7544003B2 JP7544003B2 JP2021138114A JP2021138114A JP7544003B2 JP 7544003 B2 JP7544003 B2 JP 7544003B2 JP 2021138114 A JP2021138114 A JP 2021138114A JP 2021138114 A JP2021138114 A JP 2021138114A JP 7544003 B2 JP7544003 B2 JP 7544003B2
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J12/00—Pressure vessels in general
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/12—Moulds or cores; Details thereof or accessories therefor with incorporated means for positioning inserts, e.g. labels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C39/10—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles incorporating preformed parts or layers, e.g. casting around inserts or for coating articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/24—Feeding the material into the mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/26—Moulds or cores
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/42—Casting under special conditions, e.g. vacuum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/32—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core on a rotating mould, former or core
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
- B29C70/446—Moulding structures having an axis of symmetry or at least one channel, e.g. tubular structures, frames
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
- B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/86—Incorporated in coherent impregnated reinforcing layers, e.g. by winding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2022/00—Hollow articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7154—Barrels, drums, tuns, vats
- B29L2031/7156—Pressure vessels
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- General Engineering & Computer Science (AREA)
- Moulding By Coating Moulds (AREA)
- Pressure Vessels And Lids Thereof (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Description
本発明は、繊維によって補強(強化)されたタンクの製造方法に関するものである。 The present invention relates to a method for manufacturing a tank that is reinforced (strengthened) with fibers.
特許文献1は、FRP製タンク(以下、高圧タンクとも称する)の製造方法を開示している。この製造方法では、ライナーに繊維を巻き付けて被覆する被覆工程を実行した後、繊維に樹脂を含浸させる含浸工程を行い、その後、樹脂を含浸させた繊維を加熱することによって、樹脂を硬化させる。 Patent Document 1 discloses a method for manufacturing an FRP tank (hereinafter also referred to as a high-pressure tank). In this manufacturing method, a coating process is carried out in which fibers are wrapped around the liner to cover it, followed by an impregnation process in which the fibers are impregnated with resin, and then the resin-impregnated fibers are heated to harden the resin.
また、特許文献2は、かかるRTM(Resin Transfer Molding)法を利用した高圧タンクの製造方法を開示している。この製造方法では、高圧タンクの内部空間を形成するライナーの外表面に繊維層が形成されたプリフォームを金型内に配置し、前記金型内に配置された前記プリフォームに向けてゲートから樹脂を射出しながら、前記プリフォームの中心軸線を回転中心にして、前記プリフォームを前記金型内で周方向に回転させる。 Patent Document 2 also discloses a method for manufacturing a high-pressure tank using this RTM (Resin Transfer Molding) method. In this manufacturing method, a preform in which a fiber layer is formed on the outer surface of a liner that forms the internal space of the high-pressure tank is placed in a mold, and the preform is rotated in the circumferential direction within the mold around the central axis of the preform as the center of rotation while resin is injected from a gate toward the preform placed in the mold.
上記RTM法を利用した製造方法では、高圧タンクの製造時に、繊維巻き付け工程と樹脂含浸工程とを分けて行う。しかし、高圧タンクの繊維巻き付け量は多く、繊維を巻き付けて成る繊維層(積層)の厚さが大きいため、繊維層の奥(最内層)まで樹脂を含浸させるまでに時間がかかり、未含浸が発生する可能性がある。 In the manufacturing method using the RTM method, the fiber winding process and the resin impregnation process are carried out separately when manufacturing a high-pressure tank. However, because the amount of fiber wound on a high-pressure tank is large and the fiber layer (lamination) formed by winding the fiber is thick, it takes time to impregnate the resin deep into the fiber layer (innermost layer), and there is a possibility that some parts may not be impregnated.
本発明は、上記事情に鑑みてなされたものであり、短時間で繊維層の奥(最内層)まで樹脂を含浸させることのできるタンクの製造方法を提供することを目的とする。 The present invention was made in consideration of the above circumstances, and aims to provide a method for manufacturing a tank that can impregnate resin deep into the fiber layer (the innermost layer) in a short period of time.
前記目的を達成すべく、本発明の一態様は、中空のライナーの外表面に繊維を巻き付けて成る繊維層が形成されたプリフォームを金型内に配置するプリフォーム配置工程と、前記金型の内表面に接着性を付与して、前記プリフォームの前記繊維層に隙間を形成する接着性付与工程と、前記金型内に樹脂を注入して前記繊維層に前記樹脂を含浸させる樹脂注入工程と、を含むことを特徴とする。 To achieve the above object, one aspect of the present invention is characterized by including a preform placement step in which a preform having a fiber layer formed by wrapping fiber around the outer surface of a hollow liner is placed in a mold; an adhesion imparting step in which adhesiveness is imparted to the inner surface of the mold to form gaps in the fiber layer of the preform; and a resin injection step in which resin is injected into the mold to impregnate the fiber layer with the resin.
他の態様では、前記接着性付与工程において、前記金型内に液体窒素ガスを充填する、前記金型の内表面に樹脂を塗布する、または、前記金型の内表面に静電気を帯電させることによって、前記金型の内表面に接着性を付与してもよい。 In another embodiment, in the adhesiveness imparting step, adhesiveness may be imparted to the inner surface of the mold by filling the mold with liquid nitrogen gas, applying a resin to the inner surface of the mold, or charging the inner surface of the mold with static electricity.
他の態様では、前記接着性付与工程において、前記金型の内表面に接着性を付与して、前記金型の一部を前記プリフォームから相対的に離間させる、または、前記金型の一部を前記プリフォームに対して相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成してもよい。 In another embodiment, in the adhesive imparting step, adhesiveness may be imparted to the inner surface of the mold, and a portion of the mold may be spaced relatively away from the preform, or a portion of the mold may be ultrasonically vibrated relative to the preform to form a gap in the fiber layer of the preform.
他の態様では、前記接着性付与工程において、前記金型の内表面に接着性を付与して、前記金型の一部を前記プリフォームから相対的に離間させながら、前記金型の一部を前記プリフォームに対して相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成してもよい。 In another embodiment, in the adhesive imparting step, adhesiveness may be imparted to the inner surface of the mold, and a gap may be formed in the fiber layer of the preform by ultrasonically vibrating a portion of the mold relative to the preform while moving the portion of the mold relatively away from the preform.
他の態様では、前記金型の一部を前記プリフォームの長手方向に相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成してもよい。 In another embodiment, gaps may be formed in the fiber layer of the preform by ultrasonically vibrating a portion of the mold relatively in the longitudinal direction of the preform.
他の態様では、前記接着性付与工程において、前記プリフォームの長手方向に向けて不活性ガスを吐出して、前記プリフォームの前記繊維層に隙間を形成してもよい。 In another embodiment, in the adhesive imparting step, an inert gas may be discharged in the longitudinal direction of the preform to form gaps in the fiber layer of the preform.
他の態様では、前記接着性付与工程において、前記金型の内表面に接着性を付与して、前記金型の一部を前記プリフォームから相対的に離間させながら、前記金型の一部を前記プリフォームに対して相対的に超音波振動させるとともに、前記プリフォームの長手方向に向けて不活性ガスを吐出して、前記プリフォームの前記繊維層に隙間を形成してもよい。 In another embodiment, in the adhesive imparting step, adhesiveness may be imparted to the inner surface of the mold, and while a portion of the mold is spaced relatively away from the preform, the portion of the mold may be ultrasonically vibrated relative to the preform, and an inert gas may be ejected in the longitudinal direction of the preform to form gaps in the fiber layer of the preform.
他の態様では、前記金型は、第1の型と第2の型とを含み、前記プリフォーム配置工程において、前記第1の型と前記プリフォームとの間の第1の隙間よりも大きい第2の隙間を前記第2の型と前記プリフォームとの間に形成するように、前記プリフォームを前記第1の型と前記第2の型との間に配置し、前記接着性付与工程において、前記金型の内表面に前記プリフォームの前記繊維層に対する接着性を付与し、前記第2の型を前記プリフォームに相対的に接近させることによって、前記第2の型の内表面に前記プリフォームの前記繊維層を接着させ、前記第2の型の内表面に前記プリフォームの前記繊維層を接着させながら、前記第2の型を前記プリフォームから相対的に離間させつつ、前記第2の型を前記プリフォームに対して相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成し、前記樹脂注入工程において、前記第2の型を前記プリフォームに相対的に接近させた後、前記金型内に前記樹脂を注入してもよい。 In another aspect, the mold includes a first mold and a second mold, and in the preform placement step, the preform is placed between the first mold and the second mold so as to form a second gap between the second mold and the preform that is larger than a first gap between the first mold and the preform. In the adhesion imparting step, adhesion to the fiber layer of the preform is imparted to the inner surface of the mold, the fiber layer of the preform is adhered to the inner surface of the second mold by bringing the second mold relatively close to the preform, and while adhering the fiber layer of the preform to the inner surface of the second mold, the second mold is moved relatively away from the preform and ultrasonically vibrated relative to the preform to form a gap in the fiber layer of the preform. In the resin injection step, the second mold is brought relatively close to the preform, and then the resin is injected into the mold.
本発明の一態様によれば、繊維を浮かせて繊維層(の積層間)に隙間を形成した後に樹脂の注入・含浸を行うことで、短時間で繊維層の奥(最内層)まで樹脂を含浸させることが可能となる。 According to one aspect of the present invention, by floating the fibers to form gaps between the fiber layers (between the laminated layers) and then injecting and impregnating the resin, it is possible to impregnate the resin deep into the fiber layers (the innermost layer) in a short time.
以下、図面を参照して本発明の実施形態を説明する。 The following describes an embodiment of the present invention with reference to the drawings.
以下では、タンクの一例としての燃料電池車用高圧タンクを例に挙げて説明する。但し、本発明の適用対象となるタンクは、燃料電池車用高圧タンクに限定されるものではなく、タンクを構成するライナーないしプリフォームの形状、素材等も図示例に限られない。 The following description uses a high-pressure tank for a fuel cell vehicle as an example of a tank. However, the tank to which the present invention is applicable is not limited to high-pressure tanks for fuel cell vehicles, and the shape and material of the liner or preform that constitutes the tank are not limited to the illustrated example.
RTM法においては、ライナーに炭素繊維を幾重(幾層)にも巻き付ける(巻回する)ことによってライナーの外表面に繊維層が形成されたプリフォームを作成し、プリフォームの繊維層にエポキシ樹脂を含浸させて硬化させることによって、ライナーの外周に炭素繊維とエポキシ樹脂を含む繊維強化樹脂層が形成された燃料電池車用高圧タンクが製造される。ライナーは、高圧タンクの内部空間を形成する樹脂製(例えばナイロン樹脂製)の中空容器である。 In the RTM method, a preform is created in which a fiber layer is formed on the outer surface of the liner by wrapping (wrapping) carbon fiber around the liner in multiple layers, and the fiber layer of the preform is impregnated with epoxy resin and cured to produce a high-pressure tank for fuel cell vehicles in which a fiber-reinforced resin layer containing carbon fiber and epoxy resin is formed on the outer periphery of the liner. The liner is a hollow container made of resin (e.g., nylon resin) that forms the internal space of the high-pressure tank.
燃料電池車用高圧タンクは、炭素繊維が厚肉に積層されるため、炭素繊維の内層まで樹脂が含浸していかない。炭素繊維の内層まで樹脂を含浸させるために高圧で樹脂を注入すると、タンク自体の変形が発生するなど、品質、性能低下が発生する。また、タンク形状が円筒形であるため、樹脂を全体に均一に充填するのが困難で、樹脂含浸が均一にならない。また、ゲート付近に圧力が集中しやすく、そのゲート部が高圧になると共にゲート部と樹脂流動端末部(ゲート部とは反対側)の圧力差が大きい。 High-pressure tanks for fuel cell vehicles are made of thickly laminated carbon fibers, so the resin does not penetrate to the inner layers of the carbon fibers. If resin is injected at high pressure to penetrate to the inner layers of the carbon fibers, the tank itself will deform, resulting in a decrease in quality and performance. In addition, because the tank is cylindrical, it is difficult to fill the entire tank with resin evenly, and the resin is not impregnated evenly. In addition, pressure tends to concentrate near the gate, and the gate becomes highly pressurized, while the pressure difference between the gate and the resin flow terminal (the opposite side of the gate) is large.
つまり、燃料電池車用高圧タンクの炭素繊維の積層厚みは、強度確保のため、非常に厚く(通常のRTM成形ボデー部品の約10倍)、樹脂含浸が困難であるが、特許文献2のようなタンク回転では、炭素繊維の内層までの樹脂含浸効果は少ない。また、炭素繊維の内層まで樹脂を含浸させるために高圧で樹脂を注入すると、圧力分布が不均一になり、部分的に高圧になった部位では、タンク内側の樹脂製ライナーの変形が発生するなど、品質、性能低下が発生する。また、金型とタンクの隙間が狭く、ゲート部の反対側には樹脂が流れにくいため、樹脂が硬化する前に、全体へ樹脂を流動するためには、特許文献2のようにタンクを金型内で高速回転させる必要があるが、金型内のスペースは少なく、また、炭素繊維を損傷する可能性がある。 In other words, the carbon fiber lamination thickness of the high-pressure tank for fuel cell vehicles is very thick (about 10 times that of normal RTM-molded body parts) to ensure strength, making resin impregnation difficult, but tank rotation as in Patent Document 2 does little to impregnate the inner layer of the carbon fiber with resin. Also, if resin is injected at high pressure to impregnate the inner layer of the carbon fiber, the pressure distribution becomes uneven, and in areas where the pressure is partially high, the resin liner inside the tank deforms, resulting in a decrease in quality and performance. Also, since the gap between the mold and the tank is narrow and it is difficult for resin to flow to the opposite side of the gate, in order to flow the resin throughout the entire tank before it hardens, it is necessary to rotate the tank at high speed in the mold as in Patent Document 2, but there is little space in the mold and the carbon fiber may be damaged.
そこで、本実施形態は、以下の構成が採用されている。 Therefore, this embodiment adopts the following configuration:
[高圧タンクの製造装置]
図1は、実施形態に係る高圧タンクの製造装置を示す縦断面図である。
[High pressure tank manufacturing equipment]
FIG. 1 is a vertical cross-sectional view showing a high-pressure tank manufacturing apparatus according to an embodiment of the present invention.
本実施形態において製造される高圧タンクの中間体としてのプリフォーム2は、ライナー4と、ライナー4の外表面に形成され、ライナー4と一体になった繊維層5とを含む。ライナー4は、高圧タンクの内部空間を形成する、ガスバリア性を有する樹脂製の中空容器である。中空(換言すれば、筒状)のライナー4は、例えば、0.5mm~1mm程度の厚みを有する。繊維層5は、例えば、15mm~30mm程度の厚みを有する。繊維層5は、フィラメントワインディング法によって、ライナー4の外表面に繊維が幾重にも巻き付けられることによって形成される。 The preform 2, which serves as an intermediate for the high-pressure tank manufactured in this embodiment, includes a liner 4 and a fiber layer 5 formed on the outer surface of the liner 4 and integrated with the liner 4. The liner 4 is a hollow container made of resin with gas barrier properties that forms the internal space of the high-pressure tank. The hollow (in other words, cylindrical) liner 4 has a thickness of, for example, about 0.5 mm to 1 mm. The fiber layer 5 has a thickness of, for example, about 15 mm to 30 mm. The fiber layer 5 is formed by wrapping fibers multiple times around the outer surface of the liner 4 using a filament winding method.
ライナー4に巻回される繊維としては、例えば、炭素繊維やガラス繊維、アラミド繊維等を用いることができる。繊維は、連続繊維から構成されてもよく、長繊維や短繊維から構成されてもよい。後述するように、ライナー4に巻回された繊維(層)に樹脂を含浸させて硬化させることにより、ライナー4の周囲を被覆する繊維強化樹脂層が形成される。樹脂としては、エポキシ樹脂、不飽和ポリエステル樹脂、ポリアミド樹脂等の熱硬化性樹脂や、ポリエチレン樹脂やポリエステル樹脂等の熱可塑性樹脂を用いることが可能である。 The fibers wound around the liner 4 may be, for example, carbon fibers, glass fibers, aramid fibers, etc. The fibers may be made of continuous fibers, long fibers, or short fibers. As described below, a fiber-reinforced resin layer that covers the periphery of the liner 4 is formed by impregnating the fibers (layer) wound around the liner 4 with resin and curing it. The resin may be a thermosetting resin such as epoxy resin, unsaturated polyester resin, or polyamide resin, or a thermoplastic resin such as polyethylene resin or polyester resin.
製造装置1は、RTM(Resin Transfer Molding)法を用いて、プリフォーム2を構成する繊維層5に樹脂6(符号は図8に図示)を含浸させ、さらに、含浸させた樹脂6を硬化させることによって、高圧タンクを製造する。 The manufacturing device 1 uses the RTM (Resin Transfer Molding) method to impregnate the fiber layer 5 that constitutes the preform 2 with resin 6 (the symbol is shown in Figure 8), and then hardens the impregnated resin 6 to manufacture a high-pressure tank.
製造装置1は、複数の型、例えば、固定型である下型11と、可動型である上型12とからなる金型10を備える。下型11と上型12とを閉じる(型締めともいう)ことによって、繊維強化樹脂層のためのキャビティーが形成される。繊維を積層したプリフォーム2を金型10内に配置するため、例えば、金型10のキャビティーは、プリフォーム2の公差分だけ大きく作製される。 The manufacturing device 1 is equipped with a mold 10 consisting of multiple molds, for example, a lower mold 11 which is a fixed mold, and an upper mold 12 which is a movable mold. By closing the lower mold 11 and the upper mold 12 (also called mold clamping), a cavity for the fiber reinforced resin layer is formed. In order to place the preform 2 with laminated fibers inside the mold 10, for example, the cavity of the mold 10 is made larger by the tolerance of the preform 2.
なお、ここでは、下型11を固定型、上型12を可動型(固定型に対して可動する型)としているが、例えば、上型12を固定型、下型11を可動型としてもよいし、下型11および上型12の双方を可動型としてもよい。また、ここでは、金型10を、下型11および上型12の2個の型で構成しているが、3個以上の型で構成してもよい。 Here, the lower mold 11 is a fixed mold and the upper mold 12 is a movable mold (a mold that can move relative to the fixed mold), but for example, the upper mold 12 may be a fixed mold and the lower mold 11 a movable mold, or both the lower mold 11 and the upper mold 12 may be movable molds. Also, here, the mold 10 is composed of two molds, the lower mold 11 and the upper mold 12, but it may be composed of three or more molds.
プリフォーム2は、ライナー4の軸に沿って配置される中空のシャフト25により金型10内に軸支されている。つまり、シャフト25は、プリフォーム2を金型10内(キャビティー内)に支持する支持機構を構成している。 The preform 2 is supported in the mold 10 by a hollow shaft 25 that is arranged along the axis of the liner 4. In other words, the shaft 25 constitutes a support mechanism that supports the preform 2 in the mold 10 (inside the cavity).
金型10(図示例では下型11)には、真空脱気配管15が埋設されている。真空脱気配管15には真空ポンプ50が接続されている。真空ポンプ50を駆動することによって真空脱気配管15を介して金型10内(キャビティー内)を真空脱気(排気)することが可能である。 A vacuum degassing pipe 15 is embedded in the mold 10 (lower mold 11 in the illustrated example). A vacuum pump 50 is connected to the vacuum degassing pipe 15. By driving the vacuum pump 50, it is possible to vacuum degas (exhaust) the inside of the mold 10 (inside the cavity) through the vacuum degassing pipe 15.
また、金型10(図示例では上型12)には、キャビティーに開口するゲート(樹脂注入口)14を形成する樹脂注入配管16が埋設されている。ゲート14は、本例では、プリフォーム2の(軸方向の)中央部に対向する位置に配置されている。樹脂注入配管16には樹脂注入機60が接続されている。樹脂注入機60から樹脂注入配管16を介してゲート14から金型10内(キャビティー内)に樹脂6を注入(供給)することができる。樹脂6は、例えば、主剤と硬化剤とからなる2液系の熱硬化性のエポキシ樹脂である。樹脂注入機60は、加圧装置66と、主剤と硬化剤を混合した樹脂6を貯留する樹脂溜まり64と、樹脂6を樹脂注入配管16に供給する開閉バルブ62とを備える。 In addition, a resin injection pipe 16 is embedded in the mold 10 (upper mold 12 in the illustrated example) to form a gate (resin injection port) 14 that opens into the cavity. In this example, the gate 14 is disposed at a position facing the center (axial direction) of the preform 2. A resin injection machine 60 is connected to the resin injection pipe 16. Resin 6 can be injected (supplied) from the resin injection machine 60 through the resin injection pipe 16 from the gate 14 into the mold 10 (cavity). The resin 6 is, for example, a two-part thermosetting epoxy resin consisting of a base agent and a hardener. The resin injection machine 60 includes a pressure device 66, a resin reservoir 64 that stores the resin 6, which is a mixture of the base agent and the hardener, and an opening/closing valve 62 that supplies the resin 6 to the resin injection pipe 16.
本例では、金型10(図示例では上型12)に、液体窒素ガス供給配管18が埋設されている。液体窒素ガス供給配管18には、調圧バルブ82が付設された液体窒素ガスタンク84を備える液体窒素ガス供給装置80が接続されている。液体窒素ガス供給装置80から液体窒素ガス供給配管18を介して金型10内(つまり、金型10内に配置されたプリフォーム2の外側)に液体窒素ガスを加圧充填することができる。 In this example, a liquid nitrogen gas supply pipe 18 is embedded in the mold 10 (upper mold 12 in the illustrated example). A liquid nitrogen gas supply device 80 including a liquid nitrogen gas tank 84 equipped with a pressure regulating valve 82 is connected to the liquid nitrogen gas supply pipe 18. Liquid nitrogen gas can be pressurized and filled from the liquid nitrogen gas supply device 80 through the liquid nitrogen gas supply pipe 18 into the mold 10 (i.e., the outside of the preform 2 placed in the mold 10).
また、製造装置1は、プリフォーム2を所定位置まで搬送するための搬送機構20と、金型10(詳しくは、上型12)を開閉方向(上下方向)または軸方向(横方向)に駆動するための駆動機構30と、金型10(下型11、上型12)の温度を制御する温度制御装置40と、製造装置1全体の稼働状態(詳しくは、搬送機構20、駆動機構30、温度制御装置40、真空ポンプ50、樹脂注入機60の加圧装置66と開閉バルブ62、液体窒素ガス供給装置80の調圧バルブ82の稼働状態等)を制御するコントローラとしての制御装置90とを備える。 The manufacturing apparatus 1 also includes a transport mechanism 20 for transporting the preform 2 to a predetermined position, a drive mechanism 30 for driving the mold 10 (specifically, the upper mold 12) in the opening/closing direction (vertical direction) or the axial direction (horizontal direction), a temperature control device 40 for controlling the temperature of the mold 10 (lower mold 11, upper mold 12), and a control device 90 as a controller for controlling the operating state of the entire manufacturing apparatus 1 (specifically, the operating states of the transport mechanism 20, drive mechanism 30, temperature control device 40, vacuum pump 50, pressure device 66 and opening/closing valve 62 of the resin injector 60, pressure regulating valve 82 of the liquid nitrogen gas supply device 80, etc.).
[高圧タンクの製造方法]
図2は、実施形態に係る高圧タンクの製造方法を説明するフローチャートである。また、図3は、図2の接着性付与工程を説明するフローチャートである。また、図4~図9はそれぞれ、プリフォーム配置工程および真空脱気工程、接着性付与工程の液体窒素ガス充填工程、接着性付与工程の上型下降工程、接着性付与工程の上型上昇工程、本締め工程および樹脂注入工程、樹脂注入停止工程および樹脂硬化工程の状態を示す縦断面図である。
[Manufacturing method of high pressure tank]
Fig. 2 is a flow chart for explaining a method for manufacturing a high-pressure tank according to an embodiment. Fig. 3 is a flow chart for explaining the adhesiveness imparting step in Fig. 2. Figs. 4 to 9 are vertical cross-sectional views respectively showing states of a preform arrangement step and a vacuum degassing step, a liquid nitrogen gas filling step in the adhesiveness imparting step, an upper die lowering step in the adhesiveness imparting step, an upper die raising step in the adhesiveness imparting step, a final tightening step and a resin injection step, a resin injection stopping step, and a resin hardening step.
(金型準備工程:S201)
まず、前述した構成の下型11と上型12とからなる金型10を用意する。
(Mold preparation process: S201)
First, the mold 10 consisting of the lower mold 11 and the upper mold 12 having the above-mentioned configuration is prepared.
(プリフォーム準備工程:S202)
また、前述したように、中空のライナー4の外表面に繊維を巻き付ける(巻回する)ことによって繊維層5を形成したプリフォーム2を予め用意する。
(Preform preparation process: S202)
As described above, the preform 2 is prepared in advance, in which the fiber layer 5 is formed by winding (wrapping) fibers around the outer surface of the hollow liner 4 .
(金型保温工程:S203)
次に、制御装置90が温度制御装置40を制御することによって、金型10(下型11、上型12)を所定温度に保温する。樹脂6が熱硬化性樹脂である場合、この所定温度は、樹脂6の硬化温度以上の温度である。
(Mold warming process: S203)
Next, the control device 90 controls the temperature control device 40 to keep the mold 10 (the lower mold 11 and the upper mold 12) at a predetermined temperature. If the resin 6 is a thermosetting resin, the predetermined temperature is a temperature equal to or higher than the hardening temperature of the resin 6.
なお、ここでは、最初に金型10を樹脂6の硬化温度以上に保温しているが、例えば、最初は金型10を樹脂6の硬化温度未満に保温しておき、後述する工程の適宜のタイミング(例えば樹脂6を注入して樹脂6が積層内に含浸完了した後等)において金型10を樹脂6の硬化温度以上に保温してもよい。 Here, the mold 10 is initially kept at a temperature equal to or higher than the curing temperature of the resin 6. However, for example, the mold 10 may be initially kept at a temperature lower than the curing temperature of the resin 6, and then at an appropriate timing in the process described below (for example, after the resin 6 is injected and has completely impregnated into the layers), the mold 10 may be kept at a temperature equal to or higher than the curing temperature of the resin 6.
(プリフォーム配置工程:S204)
続いて、制御装置90が搬送機構20と駆動機構30を制御することによって、プリフォーム2を金型10内(つまり、下型11と上型12との間)に配置する(図1、図4)。具体的には、上型12を開いた状態で、搬送機構20が、制御装置90の制御に従って、下型11にプリフォーム2を載置する。このとき、プリフォーム2がシャフト25により軸支される。その後、駆動機構30が、制御装置90の制御に従って、型締めを開始し、上型12を仮締めする。仮締めとは、上型12が開いた状態と本締めの状態との中間的な状態であって、下型11と上型12とが隙間を空けた状態として、図4に示すように、上型12とプリフォーム2との間に数mmの隙間(第2の隙間)が空く位置に移動させることである。この上型12とプリフォーム2との間に形成される隙間(第2の隙間)は、下型11とプリフォーム2との隙間(第1の隙間)よりも大きい。
(Preform placement process: S204)
Next, the control device 90 controls the transport mechanism 20 and the drive mechanism 30 to place the preform 2 in the mold 10 (i.e., between the lower mold 11 and the upper mold 12) (FIGS. 1 and 4). Specifically, with the upper mold 12 open, the transport mechanism 20 places the preform 2 on the lower mold 11 under the control of the control device 90. At this time, the preform 2 is supported by the shaft 25. Then, the drive mechanism 30 starts clamping under the control of the control device 90 to provisionally clamp the upper mold 12. Provisional clamping is an intermediate state between the open state and the fully clamped state, in which the lower mold 11 and the upper mold 12 are spaced apart from each other, and is moved to a position where a gap (second gap) of several mm is formed between the upper mold 12 and the preform 2, as shown in FIG. The gap (second gap) formed between the upper mold 12 and the preform 2 is larger than the gap (first gap) between the lower mold 11 and the preform 2.
(真空脱気工程:S205)
次に、上記の仮締めの状態において(言い換えれば、型締め完了前に)、制御装置90が真空ポンプ50を制御することによって、金型10内を真空脱気する(図4)。
(Vacuum degassing process: S205)
Next, in the above-mentioned provisionally clamped state (in other words, before the mold clamping is completed), the controller 90 controls the vacuum pump 50 to evacuate the inside of the mold 10 (FIG. 4).
(接着性付与工程:S206)
上記の真空脱気停止(完了)後、金型10の内表面(キャビティー面)に、プリフォーム2の繊維層5(を構成する繊維)に対する接着性を付与し、その接着性を利用して繊維層5(の積層間)に隙間を形成する。ここで、「繊維層5に隙間を形成する」ことには、繊維層5に介在する隙間を増大させることを含む。
(Adhesiveness imparting step: S206)
After the above-mentioned vacuum degassing is stopped (completed), the inner surface (cavity surface) of the mold 10 is given adhesiveness to the fiber layer 5 (fibers constituting the fiber layer 5) of the preform 2, and the adhesiveness is utilized to perform the Thus, gaps are formed in (between) the fiber layers 5. Here, "forming gaps in the fiber layers 5" includes increasing the gaps present in the fiber layers 5.
本例では、上記の接着性付与工程(S206)は、図3に示すように、液体窒素ガス充填工程(S2061)、上型下降工程(S2062)、上型上昇工程(S2063)を含んで構成される。 In this example, the adhesiveness imparting process (S206) includes a liquid nitrogen gas filling process (S2061), an upper die lowering process (S2062), and an upper die raising process (S2063), as shown in FIG. 3.
(液体窒素ガス充填工程:S2601)
上記の接着性付与工程(S206)において、まず、制御装置90が液体窒素ガス供給装置80の調圧バルブ82を開くことによって、液体窒素ガスタンク84から金型10内に液体窒素ガスを加圧充填する(図5)。上型12が仮締めであるため、上型12とプリフォーム2(の上面)との間に形成された隙間(第2の隙間)に向けて液体窒素ガスが吐出(加圧充填)される。これによって、金型10の内表面に、プリフォーム2の繊維層5に対する接着性を付与する。
(Liquid nitrogen gas filling process: S2601)
In the above-mentioned adhesiveness imparting step (S206), first, the control device 90 opens the pressure adjusting valve 82 of the liquid nitrogen gas supply device 80, thereby pressurizing and filling the liquid nitrogen gas from the liquid nitrogen gas tank 84 into the mold 10 (FIG. 5). Since the upper mold 12 is temporarily fastened, the liquid nitrogen gas is discharged (pressurized and filled) toward the gap (second gap) formed between the upper mold 12 and the preform 2 (upper surface). This imparts adhesiveness to the fiber layer 5 of the preform 2 to the inner surface of the mold 10.
(上型下降工程:S2062)
次に、制御装置90が駆動機構30を制御することによって、上型12を下降端まで下降して(プリフォーム2に相対的に接近させて)、金型10(上型12および下型11)を閉じる(図6)。これによって、金型10の内表面に、プリフォーム2の繊維層5を接触させて接着する。
(Upper mold lowering process: S2062)
Next, the control device 90 controls the drive mechanism 30 to lower the upper mold 12 to the lower end (to approach the preform 2 relatively), and the mold 10 (the upper mold 12 and the lower mold 11) is closed. ) is then closed (FIG. 6). As a result, the fiber layer 5 of the preform 2 is brought into contact with and bonded to the inner surface of the mold 10.
(上型上昇工程:S2063)
続いて、制御装置90が駆動機構30を制御することによって、プリフォーム2の繊維層5を金型10の内表面に付着させながら、上型12を(例えば、仮締めの状態まで)上昇する(プリフォーム2から相対的に離間させる)。このとき、制御装置90が駆動機構30を制御することによって、上型12を軸方向(すなわち、プリフォーム2の長手方向)に超音波振動させる(図7)。これによって、金型10の内表面に付着したプリフォーム2の繊維層5(の積層間)に隙間を形成する。
(Upper die rising process: S2063)
Next, the control device 90 controls the drive mechanism 30 to raise (for example, to a provisionally fastened state) the upper die 12 (relatively move it away from the preform 2) while adhering the fiber layer 5 of the preform 2 to the inner surface of the mold 10. At this time, the control device 90 controls the drive mechanism 30 to ultrasonically vibrate the upper die 12 in the axial direction (i.e., the longitudinal direction of the preform 2) (FIG. 7). As a result, gaps are formed between the layers of the fiber layer 5 of the preform 2 attached to the inner surface of the mold 10.
なお、このとき、プリフォーム2の長手方向に加えて、もしくは、プリフォーム2の長手方向に代えて、プリフォーム2の短手方向(繊維層5の積層方向ないし厚さ方向)に上型12を超音波振動させてもよい。 At this time, in addition to or instead of the longitudinal direction of the preform 2, the upper mold 12 may be ultrasonically vibrated in the transverse direction of the preform 2 (the lamination direction or thickness direction of the fiber layer 5).
また、このとき、図示しない不活性ガス供給配管を設けることによって、プリフォーム2の長手方向に向けて窒素ガス等の不活性ガスを吐出して、金型10の内表面に付着したプリフォーム2の繊維層5(の積層間)に隙間を形成する(大きくする)ようにしてもよい。 At this time, an inert gas supply pipe (not shown) may be provided to discharge an inert gas such as nitrogen gas in the longitudinal direction of the preform 2, thereby forming (enlarging) gaps in (between) the fiber layers 5 of the preform 2 attached to the inner surface of the mold 10.
なお、上型12の上昇完了まで、プリフォーム2の繊維層5が金型10の内表面に付着し続けている必要は無く、繊維を浮かせてプリフォーム2の繊維層5(の積層間)に隙間を形成できれば、上型12が所定高さまで上昇するまで、プリフォーム2の繊維層5が金型10の内表面に付着していればよい(換言すると、上型12が所定高さまで上昇したときに、プリフォーム2の繊維層5が金型10の内表面から剥がれてもよい)。 It is not necessary for the fiber layer 5 of the preform 2 to remain attached to the inner surface of the mold 10 until the upper mold 12 has finished rising. As long as the fibers can be floated to form gaps in the fiber layer 5 (between the layers) of the preform 2, it is sufficient for the fiber layer 5 of the preform 2 to remain attached to the inner surface of the mold 10 until the upper mold 12 rises to a predetermined height (in other words, the fiber layer 5 of the preform 2 may peel off from the inner surface of the mold 10 when the upper mold 12 rises to a predetermined height).
(本締め工程:S207)
続いて、制御装置90が駆動機構30を制御することによって、上型12を下降端まで下降して完全に閉じて(プリフォーム2に相対的に接近させて)、上型12および下型11を完全に型締め(本締め)する(図8)。
(Final tightening process: S207)
Next, the control device 90 controls the drive mechanism 30 to lower the upper mold 12 to its lowering end and completely close it (bring it relatively close to the preform 2), thereby completely clamping the upper mold 12 and the lower mold 11 (finally clamping) (Figure 8).
(樹脂注入工程:S208)
その後、樹脂6を金型10内に射出・注入する(図8)。具体的には、制御装置90は、開閉バルブ62を開き、樹脂溜まり64に貯留されている樹脂6を加圧装置66によって加圧する。これによって、上型12に設けられた樹脂注入配管16内を(未硬化の)樹脂6が流れ、ゲート(図示例では、プリフォーム2の中央部に設けられたゲート)14から、プリフォーム2に向けて樹脂6が射出・注入され、プリフォーム2の繊維層5の積層内に含浸される。
(Resin injection process: S208)
Thereafter, the resin 6 is injected/filled into the mold 10 (FIG. 8). Specifically, the control device 90 opens the open/close valve 62, and presses the resin 6 stored in the resin reservoir 64 into the pressure device 66. As a result, the (uncured) resin 6 flows through the resin injection pipe 16 provided in the upper mold 12 and is ejected from the gate 14 (in the illustrated example, the gate is provided in the center of the preform 2). Resin 6 is injected/filled into the preform 2 and is impregnated into the laminated fiber layers 5 of the preform 2 .
(樹脂注入停止工程:S209)
樹脂6がプリフォーム2の繊維層5の積層内に含浸完了し、樹脂6の硬化発熱終了後、樹脂6の注入を停止する(図9)。
(Resin injection stop step: S209)
After the resin 6 has completely impregnated the laminated fiber layers 5 of the preform 2 and the resin 6 has cured and heated, the injection of the resin 6 is stopped (FIG. 9).
(樹脂硬化工程:S210)
前述の樹脂6の注入停止後、樹脂6を硬化させる(図9)。
(Resin curing process: S210)
After the injection of the resin 6 is stopped, the resin 6 is hardened (FIG. 9).
(脱型工程:S211)
樹脂6が硬化した後、制御装置90が駆動機構30を制御することによって、上型12を開く。樹脂6の硬化が完了することで、ライナーの外周に繊維強化樹脂層が形成された高圧タンク8が得られる。
(Demolding process: S211)
After the resin 6 has hardened, the control device 90 controls the drive mechanism 30 to open the upper mold 12. When the hardening of the resin 6 is completed, a fiber-reinforced resin layer is formed on the outer periphery of the liner of the high-pressure tank. 8 is obtained.
なお、上記の接着性付与工程(S206)において金型10の内表面に接着性を付与する方法は、上述した方法に限定されない。例えば、液体窒素ガスに代えて、金型10の内表面に、樹脂6と同種の樹脂(例えばエポキシ樹脂)を塗布して接着性を付与してもよいし、静電気を帯電させて接着性を付与してもよい。また、金型10の内表面に、静電気によって接着性を付与する場合、上型12を下降させたり上昇させたりする工程を省略してもよい。 The method of imparting adhesiveness to the inner surface of the mold 10 in the adhesiveness imparting step (S206) is not limited to the above-mentioned method. For example, instead of liquid nitrogen gas, the inner surface of the mold 10 may be coated with the same type of resin as the resin 6 (e.g., epoxy resin) to impart adhesiveness, or may be imparted with static electricity. In addition, when imparting adhesiveness to the inner surface of the mold 10 by static electricity, the step of lowering and raising the upper mold 12 may be omitted.
また、上記の方法では、上型12とプリフォーム2との間に数mmの隙間(第2の隙間)を設けた仮締めの状態において、金型10内に液体窒素ガスを加圧充填している。これによって、液体窒素ガスをプリフォーム2(の上面)の全体に略均一に供給しやすくなる。但し、液体窒素ガスの圧力を調整するなどして、液体窒素ガスをプリフォーム2(の表面)に供給できれば、上型12とプリフォーム2との間に数mmの隙間(第2の隙間)を予め設ける必要は無く、例えば金型10(下型11および上型12)を閉じた状態で、金型10内に液体窒素ガスを加圧充填してもよい。 In addition, in the above method, liquid nitrogen gas is pressurized and filled into the mold 10 in a temporary fastening state with a gap (second gap) of several mm between the upper mold 12 and the preform 2. This makes it easier to supply liquid nitrogen gas almost uniformly to the entire preform 2 (top surface). However, if the liquid nitrogen gas can be supplied to the preform 2 (surface) by adjusting the pressure of the liquid nitrogen gas, there is no need to previously provide a gap (second gap) of several mm between the upper mold 12 and the preform 2, and liquid nitrogen gas may be pressurized and filled into the mold 10 with the mold 10 (lower mold 11 and upper mold 12) closed, for example.
以上で説明したように、燃料電池車用高圧タンクにおいて、RTM含浸技術によるタンク製造時、エポキシ樹脂を、厚肉積層の(炭素繊維を厚肉に巻いた)大型タンク全体に、均一に樹脂圧力をかけて、充填、含浸、硬化させることは困難であり、生産性低下やタンク性能低下に繋がる。また、タンクは、炭素繊維を厚肉積層しているため、高圧充填しないと、積層の最内層まで含浸しないが、そのため、ゲート直下等の圧力が高くなりすぎて、タンク内部の樹脂製ライナーの変形や、繊維ズレ等、生産性低下やタンク性能低下に繋がる重要品質問題が発生する。 As explained above, when manufacturing high-pressure tanks for fuel cell vehicles using RTM impregnation technology, it is difficult to apply resin pressure uniformly throughout a large, thickly laminated tank (thickly wrapped with carbon fiber) to fill, impregnate, and harden the epoxy resin, leading to reduced productivity and reduced tank performance. In addition, because the tank is made of thickly laminated carbon fiber, the innermost layer of the laminate will not be impregnated unless it is filled at high pressure, but this causes the pressure directly below the gate to become too high, leading to major quality issues such as deformation of the resin liner inside the tank and fiber displacement that lead to reduced productivity and reduced tank performance.
本実施形態は、積層タンクの樹脂流動性の画期的向上のため、金型を閉じた後、樹脂注入前に金型表面に接着性を付与(液体窒素ガス充填、エポキシ樹脂塗布、静電気等)することで、プリフォーム2に巻回された炭素繊維を接着させて積層方向に持ち上げ、積層間の隙間を確保する。それと共に、上型12を超音波振動(タンク(プリフォーム2)の長手方向に垂直な方向、あるいは、平行な方向)させ、且つ、タンク(プリフォーム2)の長手方向に窒素ガス等の不活性ガスを吐出して、積層間に隙間を形成する。 In this embodiment, in order to dramatically improve the resin fluidity of the laminated tank, after the mold is closed, adhesiveness is imparted to the mold surface (filling with liquid nitrogen gas, applying epoxy resin, static electricity, etc.) before resin is injected, thereby adhering the carbon fiber wound around the preform 2 and lifting it in the stacking direction, thereby securing gaps between the layers. At the same time, the upper mold 12 is subjected to ultrasonic vibrations (perpendicular to or parallel to the longitudinal direction of the tank (preform 2)), and an inert gas such as nitrogen gas is discharged in the longitudinal direction of the tank (preform 2) to form gaps between the layers.
樹脂注入前に金型表面に炭素繊維を接着して隙間を形成することで、繊維層の内層に樹脂が浸透しやすくなる。また、上型12を超音波振動(タンク(プリフォーム2)の長手方向に垂直な方向、あるいは、平行な方向)させ、且つ、タンク(プリフォーム2)の長手方向に、窒素ガス等の不活性ガスを吐出して、積層間に隙間を形成することで、繊維層の内層に樹脂がより浸透しやすくなる。上型12を超音波振動させる際、タンクの長手方向に垂直な方向に振動する場合と比べて、タンクの長手方向に平行な方向に振動させる方が、RTM金型のシール性確保が容易である。 By bonding carbon fibers to the mold surface before injecting resin to form gaps, the resin can easily penetrate into the inner layer of the fiber layer. In addition, by ultrasonically vibrating the upper mold 12 (perpendicular or parallel to the longitudinal direction of the tank (preform 2)) and discharging an inert gas such as nitrogen gas in the longitudinal direction of the tank (preform 2) to form gaps between the layers, the resin can easily penetrate into the inner layer of the fiber layer. When ultrasonically vibrating the upper mold 12, it is easier to ensure the sealing of the RTM mold by vibrating in a direction parallel to the longitudinal direction of the tank compared to vibrating in a direction perpendicular to the longitudinal direction of the tank.
したがって、本実施形態では、RTM含浸技術によりエポキシ樹脂を含浸させる際、タンク全体に均一に、且つ、低圧で積層延在方向(タンクの長手方向に平行な方向)及び板厚方向(タンクの長手方向に垂直な方向)に、エポキシ樹脂を含浸させることができるため、高圧タンクの性能向上と品質の安定化を図ることができる。すなわち、エポキシ樹脂注入時の低圧化と樹脂の均一含浸化を図ることができるため、高圧タンクにおいて、樹脂含浸性、および、タンク性能向上と良好な表面品質を得ることができる。それと共に、樹脂の高速充填も可能になり、大幅な成形サイクル短縮も図れる。 Therefore, in this embodiment, when epoxy resin is impregnated using RTM impregnation technology, the entire tank can be uniformly impregnated with epoxy resin at low pressure in the stack extension direction (parallel to the longitudinal direction of the tank) and in the plate thickness direction (perpendicular to the longitudinal direction of the tank), improving the performance and stabilizing the quality of the high-pressure tank. In other words, the epoxy resin can be injected at low pressure and the resin can be uniformly impregnated, resulting in improved resin impregnation, improved tank performance, and good surface quality in the high-pressure tank. At the same time, high-speed resin filling is possible, significantly shortening the molding cycle.
このように、本実施形態によれば、繊維を浮かせて繊維層5(の積層間)に隙間を形成した後に樹脂6の注入・含浸を行うことで、短時間で繊維層5の奥(最内層)まで樹脂6を含浸させることが可能となる。 In this way, according to this embodiment, by floating the fibers to form gaps between the layers of fiber layer 5, and then injecting and impregnating with resin 6, it is possible to impregnate resin 6 deep into fiber layer 5 (innermost layer) in a short time.
以上、本発明の実施の形態を図面を用いて詳述してきたが、具体的な構成はこの実施形態に限定されるものではなく、本発明の要旨を逸脱しない範囲における設計変更等があっても、それらは本発明に含まれるものである。 The above describes the embodiment of the present invention in detail using the drawings, but the specific configuration is not limited to this embodiment, and even if there are design changes, etc., within the scope of the gist of the present invention, they are included in the present invention.
1 高圧タンク(タンク)の製造装置
2 プリフォーム
4 ライナー
5 繊維層
6 樹脂
8 高圧タンク(タンク)
10 金型
11 下型(第1の型)
12 上型(第2の型)
14 ゲート(樹脂注入口)
15 真空脱気配管
16 樹脂注入配管
18 液体窒素ガス供給配管
20 搬送機構
25 シャフト
30 駆動機構
40 温度制御装置
50 真空ポンプ
60 樹脂注入機
80 液体窒素ガス供給装置
90 制御装置
1 High-pressure tank (tank) manufacturing device 2 Preform 4 Liner 5 Fiber layer 6 Resin 8 High-pressure tank (tank)
10 Mold 11 Lower mold (first mold)
12 Upper mold (second mold)
14 Gate (resin injection port)
15 Vacuum degassing pipe 16 Resin injection pipe 18 Liquid nitrogen gas supply pipe 20 Conveyor mechanism 25 Shaft 30 Drive mechanism 40 Temperature control device 50 Vacuum pump 60 Resin injection machine 80 Liquid nitrogen gas supply device 90 Control device
Claims (7)
前記金型の内表面に接着性を付与して、前記金型の一部を前記プリフォームから相対的に離間させる、または、前記金型の一部を前記プリフォームに対して相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成する接着性付与工程と、
前記金型内に樹脂を注入して前記繊維層に前記樹脂を含浸させる樹脂注入工程と、を含むことを特徴とするタンクの製造方法。 a preform placement step of placing a preform having a fiber layer formed by winding fibers on the outer surface of a hollow liner in a mold;
an adhesiveness imparting step of imparting adhesiveness to an inner surface of the mold, and forming a gap in the fiber layer of the preform by separating a part of the mold relatively from the preform or by ultrasonically vibrating a part of the mold relatively to the preform ;
and a resin injection step of injecting resin into the mold to impregnate the fiber layer with the resin.
前記接着性付与工程において、前記金型内に液体窒素ガスを充填する、前記金型の内表面に樹脂を塗布する、または、前記金型の内表面に静電気を帯電させることによって、前記金型の内表面に接着性を付与することを特徴とするタンクの製造方法。 2. The method for manufacturing a tank according to claim 1,
A method for manufacturing a tank, characterized in that in the adhesiveness imparting step, adhesiveness is imparted to the inner surface of the mold by filling the mold with liquid nitrogen gas, applying a resin to the inner surface of the mold, or charging the inner surface of the mold with static electricity.
前記接着性付与工程において、前記金型の内表面に接着性を付与して、前記金型の一部を前記プリフォームから相対的に離間させながら、前記金型の一部を前記プリフォームに対して相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成することを特徴とするタンクの製造方法。 2. The method for manufacturing a tank according to claim 1,
a step of providing an adhesive to an inner surface of the mold, and ultrasonically vibrating a portion of the mold relative to the preform while separating the portion of the mold relatively from the preform, thereby forming a gap in the fiber layer of the preform.
前記金型の一部を前記プリフォームの長手方向に相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成することを特徴とするタンクの製造方法。 4. The method for manufacturing a tank according to claim 3 ,
A method for manufacturing a tank, comprising the steps of: ultrasonically vibrating a part of the mold relatively in a longitudinal direction of the preform, thereby forming gaps in the fiber layer of the preform.
前記接着性付与工程において、前記プリフォームの長手方向に向けて不活性ガスを吐出して、前記プリフォームの前記繊維層に隙間を形成することを特徴とするタンクの製造方法。 2. The method for manufacturing a tank according to claim 1 ,
A method for manufacturing a tank, wherein in the adhesion imparting step, an inert gas is discharged in a longitudinal direction of the preform to form gaps in the fiber layer of the preform.
前記接着性付与工程において、前記金型の内表面に接着性を付与して、前記金型の一部を前記プリフォームから相対的に離間させながら、前記金型の一部を前記プリフォームに対して相対的に超音波振動させるとともに、前記プリフォームの長手方向に向けて不活性ガスを吐出して、前記プリフォームの前記繊維層に隙間を形成することを特徴とするタンクの製造方法。 2. The method for manufacturing a tank according to claim 1,
a step of imparting adhesiveness to an inner surface of the mold, and while separating a portion of the mold from the preform, ultrasonically vibrating the portion of the mold relative to the preform, and ejecting an inert gas in the longitudinal direction of the preform, thereby forming gaps in the fiber layer of the preform.
前記金型は、第1の型と第2の型とを含み、
前記プリフォーム配置工程において、前記第1の型と前記プリフォームとの間の第1の隙間よりも大きい第2の隙間を前記第2の型と前記プリフォームとの間に形成するように、前記プリフォームを前記第1の型と前記第2の型との間に配置し、
前記接着性付与工程において、
前記金型の内表面に前記プリフォームの前記繊維層に対する接着性を付与し、
前記第2の型を前記プリフォームに相対的に接近させることによって、前記第2の型の内表面に前記プリフォームの前記繊維層を接着させ、
前記第2の型の内表面に前記プリフォームの前記繊維層を接着させながら、前記第2の型を前記プリフォームから相対的に離間させつつ、前記第2の型を前記プリフォームに対して相対的に超音波振動させることによって、前記プリフォームの前記繊維層に隙間を形成し、
前記樹脂注入工程において、前記第2の型を前記プリフォームに相対的に接近させた後、前記金型内に前記樹脂を注入することを特徴とするタンクの製造方法。 2. The method for manufacturing a tank according to claim 1,
The mold includes a first mold and a second mold,
In the preform placement step, the preform is placed between the first mold and the second mold so as to form a second gap between the second mold and the preform, the second gap being larger than a first gap between the first mold and the preform;
In the adhesion imparting step,
imparting adhesion to the fiber layer of the preform to an inner surface of the mold;
Bringing the second mold relatively close to the preform, thereby adhering the fiber layer of the preform to an inner surface of the second mold;
while adhering the fiber layer of the preform to the inner surface of the second mold, the second mold is relatively spaced from the preform, and the second mold is ultrasonically vibrated relative to the preform to form a gap in the fiber layer of the preform;
A method for manufacturing a tank, wherein in the resin injection step, the second mold is brought relatively close to the preform, and then the resin is injected into the metal mold.
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