Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP7560657B2 - Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same - Google Patents
[go: Go Back, main page]

JP7560657B2 - Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same - Google Patents

Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same Download PDF

Info

Publication number
JP7560657B2
JP7560657B2 JP2023511764A JP2023511764A JP7560657B2 JP 7560657 B2 JP7560657 B2 JP 7560657B2 JP 2023511764 A JP2023511764 A JP 2023511764A JP 2023511764 A JP2023511764 A JP 2023511764A JP 7560657 B2 JP7560657 B2 JP 7560657B2
Authority
JP
Japan
Prior art keywords
airbags
yarn
synthetic fiber
fiber
variation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2023511764A
Other languages
Japanese (ja)
Other versions
JPWO2022211130A1 (en
Inventor
健斗 桑原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Original Assignee
Asahi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Corp filed Critical Asahi Kasei Corp
Publication of JPWO2022211130A1 publication Critical patent/JPWO2022211130A1/ja
Priority to JP2024162431A priority Critical patent/JP2024169601A/en
Application granted granted Critical
Publication of JP7560657B2 publication Critical patent/JP7560657B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D7/00Collecting the newly-spun products
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/02Inflatable articles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Air Bags (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)

Description

本発明は、エアバック用合成繊維、及びこれを用いたエアバック用織物の製造方法に関するものである。 The present invention relates to synthetic fibers for airbags and a method for manufacturing airbag fabrics using the same.

エアバッグ装置は、自動車の衝突事故の際、乗員を保護するという目的で搭載が進んでいる。エアバッグは、自動車の衝突を感知してから、インフレ―タ―から高圧ガスを発生させ、エアバッグクッションを膨張させることで乗員を保護する。乗員を的確に保護するには、エアバッグクッションの膨張状態を長時間維持する、つまり内圧保持性が必要となる。また、近年では運転者と助手席の同乗者の衝突を避けるファーサードカーテンエアバッグや歩行者を保護する歩行者用エアバッグが登場しているが、これらはシートやボンネットの狭い場所に収納する必要があり、エアバッグクッションのコンパクト性が一層求められている。 Airbag devices are increasingly being installed in automobiles with the aim of protecting occupants in the event of a car crash. After detecting a car collision, airbags protect occupants by generating high-pressure gas from an inflator and inflating the airbag cushion. To adequately protect occupants, the airbag cushion needs to maintain its inflated state for a long period of time, meaning it needs to be able to retain internal pressure. In recent years, front-third curtain airbags that prevent collisions between the driver and front passenger and pedestrian airbags that protect pedestrians have appeared, but these need to be stored in the narrow space of the seat or bonnet, creating an even greater demand for compact airbag cushions.

エアバッグクッションの製造工程は主に、紡糸・製織・縫製・組立の4つの工程に分けられる。その中の製織工程においては、ウォータージェットルーム織機(WJL)がよく用いられている。WJLは、ノズル後方から入った糸に対して水が側方から斜めに噴射され、糸は形成された水柱の水流に乗って緯入れが行われる。経糸が開口したところに緯入れされた緯糸は反ノズル側にて把持された後、筬打ちされ織物が形成される。 The manufacturing process for airbag cushions is mainly divided into four steps: spinning, weaving, sewing, and assembly. Of these, water jet looms (WJL) are often used in the weaving process. In a WJL, water is jetted obliquely from the side onto the yarn that enters from the rear of the nozzle, and the yarn is inserted by riding the water current of the water column that is formed. The weft yarn inserted at the opening of the warp yarn is then held on the opposite side of the nozzle and beaten with a reed to form a woven fabric.

WJLによる製織工程では、近年、生産性向上のために製織速度の高速化、かかる工程の効率化、省力化が進められている。
以下の特許文献1では、緯入れノズルから噴射される水の拡散を規制し、緯糸を安定かつ確実に飛走させることで製織効率向上を達成している。他方、糸によっては製織速度を向上させると緯入れの際に飛走不足が生じ、製織トラブルが発生することがある。
In recent years, in the weaving process by WJL, efforts have been made to increase the weaving speed, improve the efficiency of the process, and reduce the labor required in order to improve productivity.
In the following Patent Document 1, the diffusion of water sprayed from the weft insertion nozzle is restricted, and the weft yarn is allowed to fly stably and reliably, thereby improving the weaving efficiency. On the other hand, depending on the yarn, increasing the weaving speed may cause insufficient flight during weft insertion, resulting in weaving problems.

この問題を解決するため、以下の特許文献2には、製織における緯糸飛走性が向上するような交絡を施したエアバッグ用合成繊維が開示されている。これにより、850rpm~1000rpmにおける高速製織を可能にし、かかる工程における欠点を減少させたとある。しかしながら、言及されているのは製織停台回数のみで、織物製品の品質についての記載はない。 To solve this problem, the following Patent Document 2 discloses synthetic fibers for airbags that are entangled to improve weft flight during weaving. This allows high-speed weaving at 850 rpm to 1000 rpm, reducing defects in the process. However, all that is mentioned is the number of weaving stops, and there is no mention of the quality of the woven product.

また、以下の特許文献3では、合成繊維の中間荷重弾性率を上げ、中間弾性伸度を下げ、高速の緯糸挿入に対する応答性を向上させ、かつ中間荷重弾性率のバラつきを抑制することで、900rpmの高速で製織した織物においても均一な通気性を達成している。In addition, in the following Patent Document 3, uniform breathability is achieved even in fabrics woven at a high speed of 900 rpm by increasing the intermediate load elastic modulus of synthetic fibers, decreasing the intermediate elastic elongation, improving responsiveness to high speed weft insertion, and suppressing variation in the intermediate load elastic modulus.

特開2000-34646号公報JP 2000-34646 A 特開2007-126796号公報JP 2007-126796 A 特許第5253685号公報Patent No. 5253685

前記のとおり、従来の技術では、緯糸の飛走方向への力に対する応答性を向上させ、かつ応答性の糸長方向のバラつきを抑制することで、高速製織でありながらも均一な通気性となる織物の製織を達成している。織物の通気性は、織物表面からのエアリークに関係するパラメータであり、エアバッグの内圧保持性に影響を与える。しかし、エアバッグ展開時は織物表面からのエアリークよりも、縫製部からのエアリークの方が大きく、織物の通気性が内圧保持性に与える影響は微々たるものである。As described above, conventional technology has achieved the weaving of fabrics with uniform breathability despite high speed weaving by improving the responsiveness to forces in the direction of weft yarn flight and suppressing variations in responsiveness along the yarn length. The breathability of fabrics is a parameter related to air leakage from the surface of the fabric, and affects the internal pressure retention of airbags. However, when an airbag is deployed, air leakage from the stitching is greater than air leakage from the surface of the fabric, and the effect of fabric breathability on internal pressure retention is negligible.

織物の縫製部からのエアリークに関係するパラメータが滑脱抵抗力である。滑脱抵抗力が大きいと、エアバッグ展開時に縫製部に応力がかかった際、縫製部の目ズレが起こりにくく、内圧が低下しにくい。 A parameter related to air leakage from the seams of woven fabric is slippage resistance. If slippage resistance is high, the seams are less likely to become misaligned when stress is applied to the seams during airbag deployment, and the internal pressure is less likely to decrease.

他方、エアバッグの車内への収納性に関係するパラメータとして剛軟度がある。エアバッグクッションは折りたたまれて収納され、エアバッグ装置として車内に搭載されるが、剛軟度が高いと折りたたみ後の嵩が大きくなり、十分に収納できない。On the other hand, stiffness is a parameter related to the storability of an airbag inside a vehicle. Airbag cushions are folded and stored inside a vehicle as an airbag device, but if the stiffness is high, the airbag cushion will be too bulky after folding and will not be able to be stored properly.

滑脱抵抗力を向上させるには、通常、織密度やクリンプ率の増加という方法がとられるが、これらは織物の柔軟性を損ねてしまうという問題がある。そのため、滑脱抵抗力が高く、かつ、柔軟性も高いエアバッグ織物が切望され、両特性が両立するように寄与しうるエアバッグ原糸が切望されている。 To improve slippage resistance, the usual method is to increase the weave density or crimp rate, but this has the problem of impairing the flexibility of the fabric. For this reason, there is a strong demand for airbag fabrics that are both highly slippage resistant and flexible, and there is a strong demand for airbag yarns that can contribute to achieving both properties at the same time.

かかる状況下、本発明が解決しようとする課題は、エアバッグに用いる織物をWJLにて製織する際に、経緯糸共に好適に用いることができるエアバッグ用合成繊維を提供することである。とりわけ、緯糸が高速で飛走し、さらに、反ノズル側に到達した際の張力ムラを減少させ、噴射水への追従性が均一であり、かつ、高速で飛走し、織物幅方向での品質のバラつきを抑制し(ポリアミド糸の瞬間弾性回復は織物幅方向で落ち着いてから組織化されるため)、織物においてトレードオフとなる高滑脱抵抗力と高柔軟性を両立可能なエアバッグ用合成繊維を提供することである。Under these circumstances, the problem that the present invention aims to solve is to provide a synthetic fiber for airbags that can be used for both warp and weft yarns when weaving fabrics for airbags with WJL. In particular, the problem is to provide a synthetic fiber for airbags that allows the weft yarn to fly at high speed, reduces uneven tension when it reaches the opposite side of the nozzle, has uniform follow-up to the sprayed water, and also flies at high speed, suppresses variation in quality in the width direction of the fabric (because the instantaneous elastic recovery of polyamide yarn settles in the width direction of the fabric before it is organized), and achieves both high slippage resistance and high flexibility, which are a trade-off in fabrics.

本発明者は、WJLを用いた前記織物の製織において、糸の均一飛走性においては非交絡部面積の均一性、噴射水への追従性は糸の瞬間的な親水性が重要であることを予想外に見出し、本発明を完成するに至ったものである。The inventors unexpectedly discovered that in weaving the above-mentioned fabric using WJL, the uniformity of the area of the unentangled parts is important for the uniform flight of the yarn, and the instantaneous hydrophilicity of the yarn is important for its ability to follow the sprayed water, which led to the completion of the present invention.

すなわち、本発明は以下のとおりのものである。
[1]交絡部と非交絡部を有するエアバッグ用マルチフィラメント合成繊維であって、単糸表面の水滴接触角が50~75°であり、かつ、20cmごとの非交絡部面積のバラつきがCV値で10%以下であることを特徴とするエアバッグ用合成繊維。
[2]前記非交絡部面積が糸長方向に20cm範囲ごとの評価で12.5~20cmの範囲である、前記[1]に記載のエアバッグ用合成繊維。
[3]単糸数が60~250本である、前記[1]又は[2]に記載のエアバッグ用合成繊維。
[4]単糸繊度が1~7dtexである、前記[1]~[3]のいずれかに記載のエアバッグ用合成繊維。
[5]単糸数が200~250本、かつ、単糸繊度が1.0dtex~1.8dtexである、前記[1]~[4]のいずれかに記載のエアバッグ用合成繊維。
[6]交絡度が10~35個/mである、前記[1]~[5]のいずれかに記載のエアバッグ用合成繊維。
[7]単糸表面の水滴接触角の長さ方向のバラつきがCV値で5%以下である、前記[1]~[6]のいずれかに記載のエアバッグ用合成繊維。
[8]仕上剤付着率が0.6~1.2重量%である、前記[1]~[7]のいずれかに記載のエアバッグ用合成繊維。
[9]リン原子を含むアニオン性界面活性剤及び/又は硫黄原子を含むアニオン性界面活性剤が繊維重量に対して200~500ppm付着している、前記[1]~[8]のいずれかに記載のエアバッグ用合成繊維。
[10]下記要件(1)~(4):
(1)総繊度が150~800dtexである;
(2)強度が7.5~9cN/dtexである;
(3)伸度が15~25%である;及び
(4)沸水収縮率が4~11%である;
を満たす、前記[1]~[9]のいずれかに記載のエアバッグ用合成繊維。
[11]パッケージの幅Wが8~22cmである、前記[1]~[10]のいずれかに記載のエアバッグ用合成繊維の巻き取りパッケージ。
[12]以下の工程:
溶融紡糸により紡糸された合成繊維を、1つ以上の仕上剤付与(給油)装置、多段延伸ローラ、交絡付与装置、及び該交絡付与装置の前後に設けられた1つ以上の糸道規制ガイドを経由して、管軸方向に糸条を搖動するためのトラバーサーを備えた巻き取り機を用いて、管に巻き取る工程;
を含む、エアバッグ用合成繊維の製造方法であって、該工程における、巻き取り前の張力が0.1~0.3cNであり、かつ、トラバーサーによる糸条の搖動における短周期揺動幅比率Bが0.5~5%であることを特徴とする前記方法。
[13]合成繊維を管に巻き取ることで得られるパッケージの幅Wが8~22cmである、前記[12]に記載のエアバッグ用合成繊維の製造方法。
[14]前記仕上剤付与装置によって、リン原子を含むアニオン性界面活性剤及び/又は硫黄原子を含むアニオン性界面活性剤が繊維重量に対して200~500ppm付着するように仕上剤を付与する、前記[12]又は[13]に記載のエアバッグ用合成繊維の製造方法。
[15]前記仕上剤付与装置が糸道方向の異なる位置に2つ以上あり、かつ少なくとも2つの仕上剤付与装置の給油部の方向が正対している、前記[12]~[14]のいずれかに記載のエアバッグ用合成繊維の製造方法
[16]以下の工程:
ウォータージェットルーム織機において、緯糸に前記[1]~[10]のいずれかに記載のエアバッグ用合成繊維を用いて、製織速度800rpm以上で、織物を製織する工程;
を含む、エアバッグ用織物の製造方法。
That is, the present invention is as follows.
[1] A multifilament synthetic fiber for airbags having entangled portions and unentangled portions, characterized in that the water droplet contact angle on the surface of a single yarn is 50 to 75°, and the variation in the area of the unentangled portions per 20 cm is 10% or less in terms of CV value.
[2] The synthetic fiber for airbags according to [1] above, wherein the area of the unentangled parts is in the range of 12.5 to 20 cm2 when evaluated every 20 cm in the yarn length direction.
[3] The synthetic fiber for airbags according to [1] or [2] above, wherein the number of single yarns is 60 to 250.
[4] The synthetic fiber for airbags according to any one of [1] to [3] above, having a single yarn fineness of 1 to 7 dtex.
[5] The synthetic fiber for airbags according to any one of [1] to [4] above, wherein the number of single yarns is 200 to 250 and the single yarn fineness is 1.0 dtex to 1.8 dtex.
[6] The synthetic fiber for airbags according to any one of [1] to [5] above, having a degree of entanglement of 10 to 35 pcs/m.
[7] The synthetic fiber for airbags according to any one of [1] to [6] above, wherein the variation in the water droplet contact angle on the surface of a single yarn in the longitudinal direction is 5% or less in terms of CV value.
[8] The synthetic fiber for airbags according to any one of [1] to [7] above, wherein the finishing agent adhesion rate is 0.6 to 1.2% by weight.
[9] The synthetic fiber for airbags according to any one of the above [1] to [8], wherein an anionic surfactant containing a phosphorus atom and/or an anionic surfactant containing a sulfur atom is adhered in an amount of 200 to 500 ppm based on the fiber weight.
[10] The following requirements (1) to (4):
(1) The total fineness is 150 to 800 dtex;
(2) Tenacity is 7.5 to 9 cN/dtex;
(3) Elongation is 15 to 25%; and (4) Boiled water shrinkage is 4 to 11%;
The synthetic fiber for airbags according to any one of the above [1] to [9],
[11] The synthetic fiber winding package for an airbag according to any one of [1] to [10] above, wherein the package width W is 8 to 22 cm.
[12] The steps of:
A step of winding synthetic fibers spun by melt spinning onto a tube using a winding machine equipped with a traverser for swinging the yarn in the tube axial direction, the yarn passing through one or more finishing agent applying (oiling) devices, multi-stage drawing rollers, an entanglement applying device, and one or more yarn path regulating guides provided before and after the entanglement applying device;
wherein in said step, the tension before winding is 0.1 to 0.3 cN, and the short-period oscillation width ratio B in the oscillation of the yarn by a traverser is 0.5 to 5%.
[13] The method for producing a synthetic fiber for airbags according to [12] above, wherein the width W of a package obtained by winding the synthetic fiber around a tube is 8 to 22 cm.
[14] The method for producing a synthetic fiber for an airbag according to [12] or [13] above, wherein the finishing agent is applied by the finishing agent application device so that the anionic surfactant containing a phosphorus atom and/or the anionic surfactant containing a sulfur atom adheres to the fiber in an amount of 200 to 500 ppm based on the fiber weight.
[15] The method for producing a synthetic fiber for an airbag according to any one of [12] to [14], wherein the finishing agent applicator is provided at two or more positions in a yarn path direction, and the oil supply parts of at least two of the finishing agent applicators face each other. [16] The method for producing a synthetic fiber for an airbag according to any one of [12] to [14], comprising the steps of:
Weaving a fabric in a water jet loom at a weaving speed of 800 rpm or more using the synthetic fiber for an airbag according to any one of [1] to [10] as a weft;
A method for producing a fabric for an airbag, comprising:

本発明のエアバッグ用合成繊維は、単糸表面の水滴接触角および非交絡部面積のバラツキを特定範囲にすることで、WJLを用いた製織において、緯糸飛走性(噴射水への追従性)を飛躍的に改善し、かつ、均一かつ直線的に飛走する特性(糸の均一飛走性)に優れる。これら2点の特性から、基布幅方向での品質のバラつきなく、高速製織を行うことが可能となる。 The synthetic fiber for airbags of the present invention achieves a specific range of variation in the water droplet contact angle on the surface of the single yarn and the area of the unentangled parts, which dramatically improves the weft yarn flight properties (ability to follow the sprayed water) when weaving using WJL, and also provides excellent uniform and linear flight properties (uniform yarn flight properties). These two characteristics make it possible to weave at high speeds without variation in quality across the width of the base fabric.

エアバッグ用合成繊維の巻き取りパッケージの幅Wを説明する図である。FIG. 2 is a diagram illustrating the width W of a winding package of synthetic fiber for an airbag. エアバッグ用合成繊維を製造する装置の一例を説明する図である。FIG. 2 is a diagram illustrating an example of an apparatus for producing synthetic fibers for airbags. 巻き取り機におけるトラバースの速度増減方式を決めるための、短周期揺動幅比率B、及び巻き始めの綾角θの定義を説明する図である。1 is a diagram for explaining the definition of the short-period oscillation width ratio B and the winding start winding angle θ for determining the method of increasing or decreasing the traverse speed in a winding machine. FIG. 水滴接触角の計測における説明図である。FIG. 1 is an explanatory diagram for measuring a water droplet contact angle. 非交絡部面積、及びそのCV値を求めるための、非交絡部の長さaと幅bの定義の説明図である。FIG. 2 is an explanatory diagram of the definition of the length a and width b of an unentangled portion for determining the area of the unentangled portion and its CV value.

以下、本発明の実施形態を詳細に説明する。
本発明の1の実施形態は、交絡部と非交絡部を有するエアバッグ用マルチフィラメント合成繊維であって、単糸表面の水滴接触角が50~75°であり、かつ、20cmごとの非交絡部面積のバラつきがCV値で10%以下であることを特徴とするエアバッグ用合成繊維である。
Hereinafter, an embodiment of the present invention will be described in detail.
One embodiment of the present invention is a multifilament synthetic fiber for airbags having entangled portions and unentangled portions, characterized in that the water droplet contact angle on the surface of a single yarn is 50 to 75°, and the variation in the area of the unentangled portions per 20 cm is 10% or less in terms of CV value.

本実施形態におけるエアバッグ用合成繊維の単糸表面の水滴接触角は、50°以上75°以下である。水滴接触角とは、図4に示すように、エアバッグ用合成繊維の単糸に一定量の水滴を付着し、側面から接触角を経時観察し、100ms内(動画の1フレームは8ms)で最大を示す接触角の値をいう。
水滴接触角が50°以上であれば、緯入れ時に糸条内で噴射水の表面張力が適度に働き、糸がばらけずに飛走できる。糸がばらけないことで、飛走時に糸条が受ける空気抵抗が減り、緯糸飛走性が向上し、緯入れ性が高速で安定化する。緯入れ挙動が安定化することで、緯糸は瞬間弾性回復が落ち着いてから経糸に織り込みされるため、高速製織におけるエアバッグ織物物性の均一化に寄与する。また、糸条内に包含される噴射水が均一になることで、均一な飛走となり、織物物性の均一化に寄与する。また、接触角が75°以下であれば、糸条の親水性が高くなり、噴射水への追従性が向上することで、こぶ状現象(噴射水の爆発現象)を起こして、噴射水が飛散して糸条が反ノズル側まで届かず、飛走不足となり、製織トラブルが発生するという問題が生じない。水滴接触角が低いことにより、糸条の噴射水包含がミリ秒単位で素早く起こるため、非交絡部の拡幅が素早く生じ、噴射水による飛走性が効率的になり、上記同様の理由で、織物物性が均一化に寄与する。水滴接触角αが低いほどエアバッグ基布物性が均一化する。水滴接触角は、より好ましくは50~70°であり、さらに好ましくは50~65°である。
The water droplet contact angle on the surface of a single yarn of the synthetic fiber for airbags in this embodiment is from 50° to 75°. The water droplet contact angle refers to the maximum contact angle within 100 ms (one frame of a video is 8 ms) when a certain amount of water droplet is attached to a single yarn of the synthetic fiber for airbags and the contact angle is observed over time from the side as shown in Figure 4.
If the water droplet contact angle is 50° or more, the surface tension of the jet water acts appropriately within the yarn during weft insertion, allowing the yarn to fly without coming apart. By preventing the yarn from coming apart, the air resistance experienced by the yarn during flight is reduced, improving the weft flight property and stabilizing the weft insertion property at high speed. By stabilizing the weft insertion behavior, the weft yarn is woven into the warp yarn after the instantaneous elastic recovery has settled, which contributes to the uniformity of the physical properties of the airbag fabric during high-speed weaving. In addition, the jet water contained in the yarn becomes uniform, resulting in uniform flight, which contributes to the uniformity of the physical properties of the fabric. In addition, if the contact angle is 75° or less, the hydrophilicity of the yarn is increased and the ability to follow the jet water is improved, which causes a bump-like phenomenon (explosion phenomenon of the jet water), causing the jet water to scatter and the yarn to not reach the opposite nozzle side, resulting in insufficient flight and weaving troubles. A low water droplet contact angle allows the yarn to quickly absorb the jet of water in milliseconds, which quickly widens the unentangled parts and makes the water more efficient to fly, contributing to uniform fabric properties for the same reasons as above. The lower the water droplet contact angle α, the more uniform the airbag fabric properties. The water droplet contact angle is more preferably 50 to 70°, and even more preferably 50 to 65°.

本実施形態におけるエアバッグ用合成繊維の単糸表面の水滴接触角の糸長方向のバラつきがCV値(変動係数)で5%以下である。CV値が5%以下であれば、単糸への仕上剤の付着が糸長方向で均一であり、緯入れ時に糸条が包含する水量が、均一となり、飛走性のバラつきがなくなり、滑脱抵抗力と剛軟度の比(EC/V)のバラつきを低減できる、つまり均一な品質の織物、とりわけ基布幅方向に均一な品質の織物を得ることができる。CV値は好ましくは4.5%以下である。CV値の下限は特に限定されないが、経済的に実現可能な範囲として1%以上であってよい。In this embodiment, the variation in the water droplet contact angle on the surface of a single yarn of the synthetic fiber for airbags in the yarn length direction is 5% or less in CV value (coefficient of variation). If the CV value is 5% or less, the adhesion of the finishing agent to the single yarn is uniform in the yarn length direction, the amount of water contained in the yarn at the time of weft insertion is uniform, there is no variation in the flying property, and the variation in the ratio of slip resistance to bending resistance (EC/V) can be reduced, that is, a woven fabric of uniform quality, particularly a woven fabric of uniform quality in the width direction of the base fabric, can be obtained. The CV value is preferably 4.5% or less. The lower limit of the CV value is not particularly limited, but may be 1% or more as an economically feasible range.

本実施形態におけるエアバッグ用合成繊維の20cmごとの非交絡部面積のバラつきがCV値(変動係数)で10%以下である。CV値が10%以下であれば、図5に示すような、非交絡部の長さa、及び仕上剤の表面張力による糸条の広がりの幅bが均一であり、WJLにて製織する際の緯入れ時に、糸条が包含する水量が均一となり、飛走性のバラつきがなくなり、滑脱抵抗力と剛軟度の比(EC/V)のバラつきを低減できる、つまり均一な品質の織物、とりわけ基布幅方向に均一な品質の織物を得ることができる。CV値は好ましくは8%以下、より好ましくは7%以下である。CV値の下限は特に限定されないが、経済的に実現可能な範囲として3%以上であってよい。20cm糸長の計測でどこをとっても非交絡部の様子が均一であれば、噴射水による飛走性が均一になる。In this embodiment, the variation in the area of the unentangled portion of the synthetic fiber for airbags every 20 cm is 10% or less in terms of CV value (coefficient of variation). If the CV value is 10% or less, the length a of the unentangled portion and the width b of the spread of the yarn due to the surface tension of the finishing agent are uniform, as shown in FIG. 5, and the amount of water contained in the yarn during weft insertion when weaving with WJL is uniform, eliminating the variation in the flying property and reducing the variation in the ratio of slip resistance to bending resistance (EC/V), that is, a woven fabric of uniform quality, particularly a woven fabric of uniform quality in the width direction of the base fabric, can be obtained. The CV value is preferably 8% or less, more preferably 7% or less. The lower limit of the CV value is not particularly limited, but may be 3% or more as an economically feasible range. If the appearance of the unentangled portion is uniform anywhere when measuring a 20 cm yarn length, the flying property when sprayed with water will be uniform.

本実施形態におけるエアバッグ用合成繊維の非交絡部の面積は、糸長方向に20cm範囲ごとの評価で12.5~20cm2であることが好ましい。非交絡部面積が12.5cm2以上であれば、糸条の水の包含が十分となり、緯糸の飛走性が良く、織機の停台を防ぐことができる。他方、非交絡部の面積が20cm2以下であれば、交絡部の長さを適度にとることができ、糸がばらけず、織機の停台を防ぐことができる。非交絡部の面積は、糸長方向に20cm範囲ごとの評価で、より好ましくは14~17.5cm2である。 In the present embodiment, the area of the unentangled portions of the synthetic fiber for airbags is preferably 12.5 to 20 cm2 when evaluated every 20 cm in the yarn length direction. If the area of the unentangled portions is 12.5 cm2 or more, the yarns will be able to fully contain water, the weft will fly well, and the loom will be prevented from stopping. On the other hand, if the area of the unentangled portions is 20 cm2 or less, the length of the entangled portions can be made appropriate, the yarns will not come apart, and the loom will be prevented from stopping. The area of the unentangled portions is more preferably 14 to 17.5 cm2 when evaluated every 20 cm in the yarn length direction.

本実施形態におけるエアバッグ用合成繊維は、リン原子を含むアニオン性界面活性剤及び/又は硫黄原子を含むアニオン性界面活性剤が、繊維重量に対して200~500ppm付着していることが好ましい。イオン性界面活性剤を200ppm以上含有することで、水滴接触角が十分低くなり、糸がより親水化して製織工程における緯入れ時に、噴射水への追従性がアップし、緯糸飛走性が向上する。他方、付着率が500ppm以下であれば、水滴接触角が小さすぎて、製織における緯糸飛走時に糸がばらけるということがない。アニオン性界面活性剤の、繊維重量に対する付着率は、より好ましくは250~500ppmであり、さらに好ましくは300ppm~500ppmである。リン原子を含むアニオン性界面活性剤は、特に限定されないが、例えば、アルキルリン酸エステル(以下、ホスフェートと略記する。)の金属塩又はアミン塩、ポリオキシエチレンアルキルホスフェートの金属塩又はアミン塩が挙げられる。より具体的には、例えば、ラウリルホスフェートカリウム塩、ラウリルホスフェートナトリウム塩、オクチルホスフェートカリウム塩、オクチルホスフェートナトリウム塩等が挙げられる。硫黄原子を含むアニオン性界面活性剤は、特に限定されないが、例えば、アルカンスルホン酸塩が挙げられる。イオン性界面活性剤の付着方法は特に限定しないが、仕上剤中に混合して付着させることが好ましい。In the present embodiment, the synthetic fiber for airbags preferably has an anionic surfactant containing phosphorus atoms and/or an anionic surfactant containing sulfur atoms attached in an amount of 200 to 500 ppm relative to the fiber weight. By containing 200 ppm or more of ionic surfactant, the water droplet contact angle is sufficiently low, the yarn becomes more hydrophilic, and the weft thread flying property is improved by improving the tracking ability of the sprayed water during weft insertion in the weaving process. On the other hand, if the attachment rate is 500 ppm or less, the water droplet contact angle is too small and the yarn does not break apart when the weft thread flies in weaving. The attachment rate of the anionic surfactant relative to the fiber weight is more preferably 250 to 500 ppm, and even more preferably 300 ppm to 500 ppm. The anionic surfactant containing phosphorus atoms is not particularly limited, but examples thereof include metal salts or amine salts of alkyl phosphate esters (hereinafter abbreviated as phosphates), and metal salts or amine salts of polyoxyethylene alkyl phosphates. More specifically, examples of the surfactant include potassium lauryl phosphate, sodium lauryl phosphate, potassium octyl phosphate, and sodium octyl phosphate. The anionic surfactant containing a sulfur atom is not particularly limited, but examples thereof include alkanesulfonates. The method of attaching the ionic surfactant is not particularly limited, but it is preferable to attach it by mixing it into the finishing agent.

本実施形態におけるエアバッグ用合成繊維の交絡度は、図5に示すような、水浸法における測定において10~35個/mが好ましい。交絡度が10個/m以上であれば、製織の際の経糸に要求される集束性を十分に満足し、製織効率の低下を招いたり、織物品位を損なうことがない。他方、交絡数が35個/m以下であれば、非交絡部面積が適切な大きさになり、緯糸の飛走性が良くなり、また、糸条の長さ方向において単糸長のバラつきが少なく、製織中の糸切れや毛羽の発生を抑制し、織機の停台を防ぐことができる。交絡度はより好ましくは15~30個/mである。In this embodiment, the degree of entanglement of the synthetic fiber for airbags is preferably 10 to 35 pieces/m as measured by the water immersion method as shown in Figure 5. If the degree of entanglement is 10 pieces/m or more, the bundling required for the warp yarn during weaving is fully satisfied, and there is no decrease in weaving efficiency or loss of woven quality. On the other hand, if the number of entanglements is 35 pieces/m or less, the area of the non-entangled part becomes an appropriate size, the flying property of the weft yarn is improved, and there is little variation in the single yarn length in the length direction of the yarn, which suppresses the occurrence of yarn breakage and fluff during weaving and prevents the loom from stopping. The degree of entanglement is more preferably 15 to 30 pieces/m.

本実施形態のエアバッグ用合成繊維は、マルチフィラメントであり、単糸数が60~250本であることが好ましい。単糸数が60本以上であれば、交絡を構成するのに十分な本数となり、交絡が形成できず、ばらつくということがない。単糸数は、より好ましくは120本以上である。他方、単糸数が250本以下であれば、交絡を付与するためのエアーのエネルギーの利用効率が良く、均一で良好な交絡とすることができる。単糸数は、より好ましくは200本以下である。The synthetic fiber for airbags in this embodiment is a multifilament, and preferably has 60 to 250 single threads. If the number of single threads is 60 or more, the number is sufficient to form an entanglement, and there is no variation in the number of single threads due to the inability to form an entanglement. The number of single threads is more preferably 120 or more. On the other hand, if the number of single threads is 250 or less, the efficiency of the use of air energy for imparting entanglement is good, and uniform and good entanglement can be achieved. The number of single threads is more preferably 200 or less.

本実施形態のエアバッグ用マルチフィラメント合成繊維の単糸繊度は、1~7dtexであることが好ましい。単糸繊度が1dtex以上であれば、単糸タフネスなどの引張り特性が十分で、製糸工程の毛羽発生を抑制できる。他方、単糸繊度が7dtex以下であれば、交絡処理の際の糸条旋回を、より小さなエネルギーで行うことができ、意図した交絡状態を得ることができる。さらに4dtex以下であれば、単糸間の空隙が少なくなるため、緯入れ時に糸条内での噴射水の表面張力の効果が大きくなり、より糸がばらけずに飛走できる。十分な引張り特性を得るという観点からは、単糸繊度はより好ましくは2~7dtexであり、緯入れ時の飛走性という観点からは、単糸繊度は、より好ましくは1~4dtexであり、さらに好ましくは1~3dtexであり、いっそう好ましくは1.0dtex以上1.8dtex以下である。The single yarn fineness of the multifilament synthetic fiber for airbags of this embodiment is preferably 1 to 7 dtex. If the single yarn fineness is 1 dtex or more, the tensile properties such as single yarn toughness are sufficient, and the generation of fuzz during the spinning process can be suppressed. On the other hand, if the single yarn fineness is 7 dtex or less, the yarn can be swirled with less energy during the entanglement process, and the intended entanglement state can be obtained. Furthermore, if the single yarn fineness is 4 dtex or less, the gap between the single yarns is reduced, so that the effect of the surface tension of the sprayed water in the yarn during weft insertion is greater, and the twisted yarn can fly without coming apart. From the viewpoint of obtaining sufficient tensile properties, the single yarn fineness is more preferably 2 to 7 dtex, and from the viewpoint of flight property during weft insertion, the single yarn fineness is more preferably 1 to 4 dtex, even more preferably 1 to 3 dtex, and even more preferably 1.0 dtex to 1.8 dtex.

本実施形態のエアバッグ用マルチフィラメント合成繊維は、単糸数が200~250本、かつ、単糸繊度が1.0dtex以上1.8dtex以下であることが好ましい。単糸繊度が1.0dtex以上1.8dtex以下であれば、織物にした場合、一層の柔軟性を有する。単糸数が200~250本であれば、単糸繊度が1.0dtex以上1.8dtex以下の低繊度であっても、マルチフィラメント繊維として十分な機械物性を有する。In the multifilament synthetic fiber for airbags of this embodiment, it is preferable that the number of single yarns is 200 to 250 and the single yarn fineness is 1.0 dtex or more and 1.8 dtex or less. If the single yarn fineness is 1.0 dtex or more and 1.8 dtex or less, it has a higher degree of flexibility when woven. If the number of single yarns is 200 to 250, even if the single yarn fineness is a low fineness of 1.0 dtex or more and 1.8 dtex or less, it has sufficient mechanical properties as a multifilament fiber.

本実施形態のエアバッグ用マルチフィラメント合成繊維の総繊度150~800dtex、強度7.5~9cN/dtex、伸度15~25%、及び沸水収縮率4~11%の物性を有することが望ましい。
総繊度が150dtex以上であれば、エアバッグ用織物にした場合、十分な機械物性を有する。他方、総繊度が800dtex以下であれば、交絡付与工程において、集束性を付与することが容易になる。つまり、繊度が大きくなると適度な交絡を付与するには、糸旋回に必要なエアー圧、又はエアー流量を著しく増加する必要があり、用役増分のコストアップだけでなく、交絡ノズル部において糸条がダメージを受け易く、毛羽が生じ、糸条品位の低下を招き易いが、総繊度が800dtex以下であれば、そのようなことがない。総繊度は、より好ましくは200~550dtexである。
The multifilament synthetic fiber for airbags of this embodiment preferably has physical properties of a total fineness of 150 to 800 dtex, a strength of 7.5 to 9 cN/dtex, an elongation of 15 to 25%, and a boiling water shrinkage of 4 to 11%.
If the total fineness is 150 dtex or more, the fabric has sufficient mechanical properties when made into an airbag fabric. On the other hand, if the total fineness is 800 dtex or less, it becomes easy to impart bundling properties in the entanglement imparting step. In other words, when the fineness is large, in order to impart appropriate entanglement, the air pressure or air flow rate required for yarn rotation must be significantly increased, which not only increases the cost of additional utilities but also makes the yarn susceptible to damage at the entanglement nozzle, causing fluffing and reducing the yarn quality. However, if the total fineness is 800 dtex or less, this does not occur. The total fineness is more preferably 200 to 550 dtex.

(引張)強度は7.5~9.0cN/dtexであることが好ましい。引張強度が7.5cN/dtex以上と高ければ、織物の機械特性向上に寄与する。引張強度は、より好ましくは8.0cN/dtex以上である。エアバッグ用合成繊維の引張強度は、他の特性、製造コスト等を考慮すると、実質的に9.0cN/dtex以下である。 The (tensile) strength is preferably 7.5 to 9.0 cN/dtex. A high tensile strength of 7.5 cN/dtex or more contributes to improving the mechanical properties of the fabric. The tensile strength is more preferably 8.0 cN/dtex or more. Taking into account other properties, production costs, etc., the tensile strength of synthetic fibers for airbags is substantially 9.0 cN/dtex or less.

伸度は15~25%であることが好ましい。伸度が15%以上であれば、展開時に膨張部と非膨張部の境界部分に応力が過剰にかかって、破壊するようなことがない。また、伸度と強度はトレードオフであり、強度とのバランスをとるために伸度は25%以下であることが好ましい。It is preferable that the elongation is 15 to 25%. If the elongation is 15% or more, excessive stress will not be applied to the boundary between the inflatable and non-inflatable parts during deployment, which may result in breakage. Furthermore, there is a trade-off between elongation and strength, and it is preferable that the elongation is 25% or less in order to achieve a balance with strength.

沸水収縮率は4~11%の範囲であることが好ましい。沸水収縮率が4%以上であれば、製織後の加工工程で織物を収縮させ、織物の仕上がりを高密度にすることに寄与できる。沸水収縮率は6%以上がさらに好ましい。沸水収縮率が6%以上あれば、製織後の加工工程で織物を収縮させ、織物機械物性のばらつきの均一化に寄与できる。沸水収縮率は特に好ましくは7%以上である。沸水収縮率が11%以下であれば、織物にした場合、過度の収縮で経緯のアンバランスが出て目開きを誘発することがない。沸水収縮率はより好ましくは9.5%以下であり、さらに好ましくは9%以下である。 The boiling water shrinkage rate is preferably in the range of 4 to 11%. If the boiling water shrinkage rate is 4% or more, the fabric can be shrunk in the processing step after weaving, which contributes to making the finished fabric denser. A boiling water shrinkage rate of 6% or more is more preferable. If the boiling water shrinkage rate is 6% or more, the fabric can be shrunk in the processing step after weaving, which contributes to equalizing the variation in the mechanical properties of the fabric. A boiling water shrinkage rate of 7% or more is particularly preferable. If the boiling water shrinkage rate is 11% or less, when the fabric is woven, excessive shrinkage will not cause imbalance in the warp and weft directions, which will induce opening of the mesh. A boiling water shrinkage rate of 9.5% or less is more preferable, and 9% or less is even more preferable.

本発明の他の実施形態は、パッケージの幅Wが8~22cmである、前記エアバッグ用合成繊維の巻き取りパッケージである。
かかる巻き取りパッケージ(繊維を巻取り機にて紙管等に巻きつけたものの繊維包装形態)は、図1に示すように、パッケージの幅Wが8~22cmであるものが好ましい。Wが8cm以上であれば、形状が安定し、かつ輸送効率も良い。他方、幅W22cm以下であれば、巻取り時にパッケージの幅方向における中心と両端での張力差により非交絡部面積の変動が低減される。Wは、より好ましくは8~18cmである。
Another embodiment of the present invention is the above-mentioned synthetic airbag fiber winding package, wherein the width W of the package is 8 to 22 cm.
Such a winding package (a fiber packaging form in which the fibers are wound around a paper tube or the like by a winding machine) preferably has a package width W of 8 to 22 cm as shown in Figure 1. If W is 8 cm or more, the shape is stable and transportation efficiency is also good. On the other hand, if the width W is 22 cm or less, the variation in the area of the unentangled parts due to the difference in tension between the center and both ends in the width direction of the package during winding is reduced. W is more preferably 8 to 18 cm.

本実施形態のエアバッグ用合成繊維を構成する合成繊維は、ポリアミドやポリエステルのマルチフィラメントからなる長繊維であることが好ましい。特に好ましくは、ポリアミド繊維であり、融点が高く、熱容量も大きいため、耐熱性に優れる。例えば、ポリアミド6、ポリアミド6・6、ポリアミド11、ポリアミド12、ポリアミド6・10、ポリアミド6・12、ポリアミド4・6、それらの共重合体およびそれらの混合物からなる繊維が挙げられる。中でも、主としてポリヘキサメチレンアジパミド繊維からなるポリアミド6・6繊維が好ましい。ポリヘキサメチレンアジパミド、とは100%のヘキサメチレンジアミンとアジピン酸とから構成される融点が250℃以上のポリアミド繊維を指す。本発明のポリアミド6・6繊維は、融点が250℃未満とならない範囲で、ポリヘキサメチレンアジパミドにポリアミド8、ポリアミド6.I、ポリアミド10、ポリアミド6・Tなどを共重合、あるいはブレンドしたポリマーからなる繊維でもよい。The synthetic fibers constituting the synthetic fiber for airbags of this embodiment are preferably long fibers made of polyamide or polyester multifilaments. Polyamide fibers are particularly preferred, as they have a high melting point and a large heat capacity, and therefore have excellent heat resistance. For example, fibers made of polyamide 6, polyamide 6.6, polyamide 11, polyamide 12, polyamide 6.10, polyamide 6.12, polyamide 4.6, copolymers thereof, and mixtures thereof may be mentioned. Among them, polyamide 6.6 fibers made mainly of polyhexamethylene adipamide fibers are preferred. Polyhexamethylene adipamide refers to polyamide fibers made of 100% hexamethylene diamine and adipic acid and having a melting point of 250°C or higher. The polyamide 6.6 fibers of the present invention are made of polyhexamethylene adipamide, polyamide 8, polyamide 6, etc., within a range in which the melting point is not less than 250°C. Alternatively, fibers made of a copolymer or blend of polyamide I, polyamide 10, polyamide 6.T, etc. may be used.

本発明のさらに他の実施形態は、以下の工程:
溶融紡糸により紡糸された合成繊維を、1つ以上の仕上剤付与(給油)装置、多段延伸ローラ、交絡付与装置、及び該交絡付与装置の前後に設けられた1つ以上の糸道規制ガイドを経由して、管軸方向に糸条を搖動するためのトラバーサーを備えた巻き取り機を用いて、管に巻き取る工程;
を含む、エアバッグ用合成繊維の製造方法であって、該工程における、巻き取り前の張力が0.1~0.3cNであり、かつ、トラバーサーによる糸条の搖動における短周期揺動幅比率Bが0.5~5%であることを特徴とする前記方法である。
Yet another embodiment of the present invention is a method for producing a process comprising the steps of:
A step of winding synthetic fibers spun by melt spinning onto a tube using a winding machine equipped with a traverser for swinging the yarn in the tube axial direction, the yarn passing through one or more finishing agent applying (oiling) devices, multi-stage drawing rollers, an entanglement applying device, and one or more yarn path regulating guides provided before and after the entanglement applying device;
wherein the tension before winding in the process is 0.1 to 0.3 cN, and the short-period oscillation width ratio B in the oscillation of the yarn by a traverser is 0.5 to 5%.

以下、本実施形態のエアバッグ用合成繊維の巻き取りパッケージを製造する方法について説明する。
図2は、本実施形態のエアバッグ用合成繊維を製造する設備の一例を示す説明図である。まず、溶融状態のポリマーはスピンヘッド3と呼ばれる紡糸機の一部によって均温化され、紡糸口金4より紡出される。紡出されたポリマーは、冷却チャンバー5からの冷風により固化され糸条を形成する。各エンドにまとめられた糸条は、その後、給油装置6で仕上剤を付与された後、引き取りローラ7、第1ローラ8から第4ローラ11からなるローラ群による延伸工程へと進む。すなわち、糸条はローラ7により所定の速度で引き取られた後、若干の緊張力で第1段ローラ8に導き、第1段ローラ8から多段の加熱延伸ローラ9、10、11により延伸される。その後、糸道規制ガイド12を通って交絡付与装置13に供給され、さらに糸道規制ガイド12を通って巻取り機14で巻取られる。
A method for producing a winding package of synthetic fibers for an airbag according to this embodiment will now be described.
FIG. 2 is an explanatory diagram showing an example of equipment for producing the synthetic fiber for airbags according to the present embodiment. First, the molten polymer is uniformly heated by a part of the spinning machine called the spin head 3, and is spun out from the spinneret 4. The spun polymer is solidified by cold air from the cooling chamber 5 to form a yarn. The yarn gathered at each end is then given a finishing agent by the oiling device 6, and then proceeds to a drawing process by a group of rollers consisting of a take-up roller 7 and a first roller 8 to a fourth roller 11. That is, the yarn is taken up at a predetermined speed by the roller 7, and then guided to the first-stage roller 8 with a slight tension, and drawn from the first-stage roller 8 by multiple heated drawing rollers 9, 10, and 11. The yarn is then supplied to an entanglement imparting device 13 through a yarn path regulating guide 12, and wound up by a winder 14 through the yarn path regulating guide 12.

給油装置6は、一般的にはロールタイプもしくはノズルタイプが用いられる。給油装置6の構成は、1つ以上あればよいが、糸道方向の異なる位置に2個以上あり、かつその給油部のうち少なくとも2つの方向が正対していることが好ましい。特に単糸繊度が1,0~1.8dtexの場合、冷却チャンバー5からの冷風により固化する工程での糸の揺れが給油工程に伝搬し、給油装置6への糸の接触が乱れ、仕上剤の付着が不均一となる傾向がある。給油装置を糸道方向の異なる位置に2個以上、かつその給油部のうち少なくとも2つの方向を正対させることで、給油装置への糸の接触乱れを抑制することで、単糸繊度が1.0~1.8dtexであっても仕上剤を均一に付着させることができ、単糸表面の水滴接触角の糸長方向のバラつきを抑制することができる。The oiling device 6 is generally of the roll type or nozzle type. The oiling device 6 may have one or more, but it is preferable that there are two or more at different positions in the yarn path direction, and that at least two of the oiling parts face each other. In particular, when the single yarn fineness is 1.0 to 1.8 dtex, the vibration of the yarn during the process of solidifying it with cold air from the cooling chamber 5 is transmitted to the oiling process, causing the contact of the yarn with the oiling device 6 to become disturbed, and the application of the finishing agent tends to become uneven. By providing two or more oiling devices at different positions in the yarn path direction and having at least two of the oiling parts face each other, the contact disturbance of the yarn with the oiling device can be suppressed, and the finishing agent can be applied uniformly even when the single yarn fineness is 1.0 to 1.8 dtex, and the variation in the water droplet contact angle on the single yarn surface in the yarn length direction can be suppressed.

給油装置6にて合成繊維に付与される仕上剤の付着率は、0.6~1.2重量%の範囲であることが好ましい。1.2重量%以下の仕上剤付着率を有する糸条は、べたつき(タック性)によって緯糸が飛走し難いということがほとんどない。0.6重量%以上の仕上剤付着率であれば、製糸工程における延伸中での単糸毛羽の発生を抑制できる。The adhesion rate of the finishing agent applied to the synthetic fibers by the oiling device 6 is preferably in the range of 0.6 to 1.2% by weight. Yarn with an adhesion rate of finishing agent of 1.2% by weight or less rarely has stickiness (tackiness) that makes it difficult for the weft yarn to fly. A finishing agent adhesion rate of 0.6% by weight or more can suppress the occurrence of fuzz in the single yarn during drawing in the spinning process.

給油装置6にて合成繊維に付与される仕上剤の成分は、上述したイオン性界面活性剤の他に、製糸工程における糸条の延伸がスムーズに行われるように平滑性に優れ、かつ耐熱性を有する成分を用いることが、糸条品位、産業資材用途の観点から好ましい。In addition to the ionic surfactants mentioned above, the components of the finishing agent applied to the synthetic fibers by the oiling device 6 preferably contain components that are excellent in smoothness and heat resistance so that the yarn can be smoothly stretched during the spinning process, from the viewpoints of yarn quality and industrial material applications.

平滑剤としての成分は、エステル化合物が好ましい。分子中にエステル結合を3つ以上有するエステル化合物、及び分子中に硫黄元素を有するエステル化合物から選ばれる少なくとも一種のエステル化合物を含むものが好ましい。
分子中に硫黄元素を有するエステル化合物は、例えば、(1)ジアルキルチオジプロピオナート等の二価カルボン酸と一価アルコールとのエステル化合物、(2)アルキルメルカプトプロピオナート等の1価カルボン酸と1価アルコールとのエステル化合物等が挙げられる。
The component as a smoothing agent is preferably an ester compound, and preferably contains at least one ester compound selected from an ester compound having three or more ester bonds in the molecule and an ester compound having a sulfur element in the molecule.
Examples of the ester compound having a sulfur element in the molecule include (1) ester compounds of a divalent carboxylic acid and a monohydric alcohol, such as dialkylthiodipropionate, and (2) ester compounds of a monovalent carboxylic acid and a monohydric alcohol, such as alkylmercaptopropionate.

分子中にエステル結合を3つ以上有するエステル化合物としては、例えば、(3)トリメチロールプロパントリアルキレート、グリセリントリ脂肪酸エステル、ペンタエリスリトールテトラ脂肪酸エステル、トリメチロールプロパン脂肪酸エステル等の多価アルコールと一価カルボン酸とのエステル化合物、(4)トリアルキルトリメリタート、クエン酸トリエチル等の多価カルボン酸と一価アルコールとのエステル化合物、(5)ひまし油、パーム油、ナタネ白絞油等の天然油脂等が挙げられる。これらの成分は、1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。Examples of ester compounds having three or more ester bonds in the molecule include (3) ester compounds of polyhydric alcohols and monovalent carboxylic acids, such as trimethylolpropane trialchelate, glycerin trifatty acid ester, pentaerythritol tetrafatty acid ester, and trimethylolpropane fatty acid ester; (4) ester compounds of polyhydric carboxylic acids and monovalent alcohols, such as trialkyl trimellitate and triethyl citrate; and (5) natural fats and oils, such as castor oil, palm oil, and rapeseed oil. These components may be used alone or in combination of two or more.

非イオン界面活性剤は、乳化作用、摩擦作用の調節剤として用いることができる。
例えば、(1)ポリエチレングリコールジアルキレート、ポリオキシエチレンソルビタンモノアルキレート、ポリオキシブチレンソルビタントリアルキレート、ポリオキシプロピレンひまし油、ポリオキシエチレン硬化ひまし油、ポリオキシエチレンプロピレン硬化ひまし油トリアルキレート、ポリオキシエチレン硬化ひまし油トリアルキレート、ひまし油のエチレンオキサイド(以下、EOという。)付加物及び硬化ひまし油のEO付加物から選ばれる少なくとも1種の化合物と、モノカルボン酸及びジカルボン酸とを縮合させたエーテルエステル化合物等のポリオキシアルキレン多価アルコール脂肪酸エステル型ノニオン界面活性剤、(2)有機酸、有機アルコール、有機アミン、及び有機アミドから選ばれる少なくとも一種に炭素数2~4のアルキレンオキサイドを付加した化合物、より具体的には、例えばポリオキシエチレン脂肪酸エステル、ポリオキシエチレン脂肪酸エステルメチルエーテル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレンノニルフェニルエーテル、ポリオキシエチレンアルキルアミノエーテル、ポリオキシエチレン脂肪酸アミドエーテル等のエーテル型ノニオン界面活性剤、(3)ソルビタンモノ脂肪酸エステル、ソルビタントリ脂肪酸エステル、グリセリンモノ脂肪酸エステル等の多価アルコール部分エステル型ノニオン界面活性剤、(4)ジエタノールアミンモノ脂肪酸アミド等のアルキルアミド型ノニオン界面活性剤等が挙げられる。これらの成分は、1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。
仕上剤は鉱物油などで希釈してもよく、水系のエマルジョンにしてもよい。特に限定されるものではないが、後工程における水との相溶性を考慮した際には、エマルジョンにして用いることが好ましい。
The nonionic surfactant can be used as an emulsifying agent and an agent for adjusting friction.
For example, (1) polyoxyalkylene polyhydric alcohol fatty acid ester-type nonionic surfactants such as ether ester compounds obtained by condensing at least one compound selected from polyethylene glycol dialkylate, polyoxyethylene sorbitan monoalkylate, polyoxybutylene sorbitan trialchelate, polyoxypropylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene propylene hydrogenated castor oil trialchelate, polyoxyethylene hydrogenated castor oil trialchelate, ethylene oxide (hereinafter referred to as EO) adduct of castor oil, and EO adduct of hydrogenated castor oil with monocarboxylic acid and dicarboxylic acid; (2) at least one compound selected from organic acid, organic alcohol, organic amine, and organic amide with carbonyl group; Compounds having alkylene oxides with prime numbers of 2 to 4 added thereto, more specifically, ether-type nonionic surfactants such as polyoxyethylene fatty acid esters, polyoxyethylene fatty acid ester methyl ethers, polyoxyethylene alkyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, polyoxyethylene polyoxypropylene nonylphenyl ethers, polyoxyethylene alkylamino ethers, and polyoxyethylene fatty acid amide ethers, (3) polyhydric alcohol partial ester-type nonionic surfactants such as sorbitan mono fatty acid esters, sorbitan tri fatty acid esters, and glycerin mono fatty acid esters, and (4) alkylamide-type nonionic surfactants such as diethanolamine mono fatty acid amides, etc. These components may be used alone or in combination of two or more.
The finishing agent may be diluted with mineral oil or may be made into a water-based emulsion. Although there is no particular limitation, it is preferable to use it as an emulsion when considering compatibility with water in the subsequent process.

交絡付与装置13の上流部と下流部には、糸走を安定させるための糸道規制ガイド12が設けられる。これらと交絡付与装置の交絡ノズル部で規定される糸走角度を1~10°の範囲に保つことは、バラつきの少ないエアバッグ用合成繊維を得るうえで好ましい方法である。二つの糸道規制ガイド12間を50~90mmに設定することは、好適な非交絡部面積を得るうえで好ましい。交絡付与装置13は、交絡ノズルにより圧縮流体を糸条に噴射する公知の装置を用いることができるが、糸条への圧縮流体は、0.5~3.5kWのエネルギーにて供給をすることが好ましい。圧縮流体の供給エネルギーは、供給圧(Mpa)と使用流量(Nm3/hr)の積により算出することができ、供給圧、交絡ノズルの流体導入口径を任意に選択することにより、上記供給エネルギーの範囲を満足することができる。さらに第4ローラ11と巻取り機間の速度比と上記範囲内で第4ローラ11の温度を調整して、第4ローラ11と巻取り機14間の巻取り張力(巻き取り前張力)を0.1~0.3cN/dtexの範囲にすることが好ましい。巻取り張力が0.1cN以上であれば、糸落ちがなく、パッケージ形状が安定する。また、パッケージ密度が上がり、輸送効率が高くなる。他方、巻き取り前張力が0.3cN以下であれば、交絡が十分に入り、交絡部が安定したバラツキが少なくなると同時にパッケージを解除する際の張力変動を最小限にすることができパッケージの解舒性にも優れる。 The entanglement device 13 is provided at its upstream and downstream with yarn path control guides 12 for stabilizing the yarn running. It is preferable to maintain the yarn running angle, determined by these and the entanglement nozzle of the entanglement device, in the range of 1 to 10° in order to obtain synthetic fibers for airbags with little variation. It is preferable to set the distance between the two yarn path control guides 12 to 50 to 90 mm in order to obtain a suitable non-entangled area. The entanglement device 13 may be a known device that injects compressed fluid onto the yarns using an entanglement nozzle, but it is preferable to supply the compressed fluid to the yarns with an energy of 0.5 to 3.5 kW. The supply energy of the compressed fluid can be calculated by the product of the supply pressure (Mpa) and the usage flow rate (Nm 3 /hr), and the above supply energy range can be satisfied by arbitrarily selecting the supply pressure and the fluid inlet diameter of the entanglement nozzle. Furthermore, it is preferable to adjust the speed ratio between the fourth roller 11 and the winder and the temperature of the fourth roller 11 within the above range, and set the winding tension (tension before winding) between the fourth roller 11 and the winder 14 in the range of 0.1 to 0.3 cN/dtex. If the winding tension is 0.1 cN or more, there is no yarn drop and the package shape is stable. In addition, the package density increases and the transport efficiency increases. On the other hand, if the tension before winding is 0.3 cN or less, the yarn is sufficiently entangled, the entangled portion is stable and there is little variation, and at the same time, tension fluctuation when the package is released can be minimized, and the package unwinding property is excellent.

本実施形態のエアバッグ用合成繊維は巻取り機14により、紙管等に巻きつけられる。その際、糸条はトラバーサーによって紙管軸方向に揺動され、巻取りパッケージ幅の間で左右に振られて、円柱状にパッケージされる。トラバースした繊維糸条がドラム上に巻上げられる方向とパッケージドラムの回転軸に直角な面との角度を綾角θ とすると、(トラバース速度)=(捲取速度)×(tanθ)であり、綾角を設定することでトラバース速度を制御する。トラバース速度を制御するにあたり、巻取り幅の間で左右に振られる速度は、綾角の設定に加えて、短周期揺動幅比率Bが0.5~5%を満たすような短周期の揺動手段を適用することが好ましい。The synthetic fiber for airbags in this embodiment is wound around a paper tube or the like by a winding machine 14. At that time, the yarn is oscillated in the axial direction of the paper tube by a traverser, and oscillated left and right within the winding package width to be packaged in a cylindrical shape. If the angle between the direction in which the traversed fiber yarn is wound up on the drum and the plane perpendicular to the rotation axis of the package drum is the twill angle θ, then (traverse speed) = (winding speed) x (tan θ), and the traverse speed is controlled by setting the twill angle. In controlling the traverse speed, it is preferable to apply a short-period oscillation means such that the speed at which the yarn is oscillated left and right within the winding width satisfies the short-period oscillation width ratio B of 0.5 to 5%, in addition to setting the twill angle.

短周期揺動幅比率Bは、図3で定義される。Bはトラバーサー制御のアプリケーション上で設定することができる。綾角θは通常巻時間ごとに変化するが、Bを設定することで、ある巻時間での綾角に対して細かい綾角変化を入れることができる。例えば、巻き始めの綾角が10°の場合にBを1%と設定すると、経時的に変化する綾角に対して短周期的に-0.1~0.1°(10°の±1%)の綾角変化を入れることができる。このとき、短周期とは0.1~2秒の周期をいう。Bはリボン巻を防ぐために設定されるが、本発明者は、このような変動的なトラバースを行うことで、トラバースによる糸条の巻取り張力変動を抑制し、交絡を損なうことなく、非交絡部面積のバラツキの少ない均一なエアバッグ用合成繊維を得ることができることを見出した。短周期揺動幅比率Bを0.5%以上にすれば、リボン巻を回避し、巻取りの張力変動を抑制できる。他方、Bを5%以下にすれば、短周期での綾角の大小により巻径のバラつきが生じて糸落ちすることがない。The short-period oscillation width ratio B is defined in FIG. 3. B can be set on the traverser control application. The twill angle θ usually changes with each winding time, but by setting B, it is possible to make fine changes in the twill angle at a certain winding time. For example, if the twill angle at the start of winding is 10°, setting B to 1% allows a short-period twill angle change of -0.1 to 0.1° (±1% of 10°) to be made to the twill angle that changes over time. In this case, a short period refers to a period of 0.1 to 2 seconds. B is set to prevent ribbon winding, but the inventor has found that by performing such a variable traverse, it is possible to suppress the fluctuation in the winding tension of the yarn due to traversing, and to obtain a uniform synthetic fiber for airbags with little variation in the area of the non-entangled part without impairing the entanglement. If the short-period oscillation width ratio B is set to 0.5% or more, ribbon winding can be avoided and tension fluctuations in winding can be suppressed. On the other hand, if B is set to 5% or less, the winding diameter does not vary depending on the magnitude of the winding angle in a short period, and the yarn does not fall off.

本発明のさらに他の実施形態は、以下の工程:
ウォータージェットルーム織機において、緯糸に前記エアバッグ用合成繊維を用いて、製織速度800rpm以上で、織物を製織する工程;
を含む、エアバッグ用織物の製造方法である。
WJLにおいて飛走性が良いエアバッグ用合成繊維を得るためには、特に前記した、トラバース条件の調整による交絡均一性の向上と、仕上剤の選定による糸の親水性の向上がポイントとなる。
Yet another embodiment of the present invention is a method for producing a process comprising the steps of:
weaving a fabric using the synthetic fiber for an airbag as a weft yarn in a water jet loom at a weaving speed of 800 rpm or more;
The method for producing a fabric for an airbag includes the steps of:
In order to obtain a synthetic fiber for airbags with good flying properties in WJL, it is important to improve the entanglement uniformity by adjusting the traverse conditions as described above, and to improve the hydrophilicity of the yarn by selecting a finishing agent.

本実施形態のエアバッグ用合成繊維は、WJLでの製織、とりわけ800rpm以上の高速製織、及び2m以上の広幅織機での製織において、緯糸として用いることに適している。製織に用いる経糸としても、本実施形態のエアバッグ用合成繊維を好適に用いることができる。また、製織前の経糸に平滑性を向上させるためのサイジング処理を行ってもよい。また、製織後は精練工程で油分を除去してもよいし、精練工程を省略してもよい。織物を温水や熱風処理して収縮させてもよい。この収縮工程で織物の幅方向や反長方向について張力制御したり、寸法変化率を調整させてもよい。The synthetic fiber for airbags of this embodiment is suitable for use as a weft thread in weaving with a WJL, particularly in high-speed weaving at 800 rpm or more, and in weaving with a wide loom of 2 m or more. The synthetic fiber for airbags of this embodiment can also be suitably used as a warp thread for weaving. In addition, a sizing treatment may be performed on the warp thread before weaving to improve its smoothness. In addition, after weaving, oil may be removed in a refining process, or the refining process may be omitted. The woven fabric may be shrunk by treatment with hot water or hot air. In this shrinkage process, the tension in the width direction or the reverse length direction of the woven fabric may be controlled, or the dimensional change rate may be adjusted.

本実施形態のエアバッグ用合成繊維は、これを織糸に用いて製織して高密度織物とするに適しており、カバーファクターが2000~2500の織物とすることが好ましい。カバーファクターが2000以上であれば、エアバッグ用織物として十分な強度、低通気性を確保することができる。他方、カバーファクターが2500以下であれば、十分な柔軟性、薄地性、軽量性を持たせることができる。カバーファクターは、より好ましくは2200~2500である。尚、カバーファクターは{経糸密度(本/2.54cm)×(経糸繊度(dtex))1/2+緯糸密度(本/2.54cm)×(緯糸繊度(dtex))1/2}である。 The synthetic fiber for airbags of this embodiment is suitable for weaving into a high-density fabric using the same as weaving yarn, and it is preferable to use the synthetic fiber for airbags in a fabric having a cover factor of 2000 to 2500. If the cover factor is 2000 or more, sufficient strength and low air permeability can be ensured as a fabric for airbags. On the other hand, if the cover factor is 2500 or less, sufficient flexibility, thinness, and lightness can be achieved. The cover factor is more preferably 2200 to 2500. The cover factor is {warp density (pieces/2.54 cm) x (warp fineness (dtex)) 1/2 + weft density (pieces/2.54 cm) x (weft fineness (dtex)) 1/2 }.

本実施形態の合成繊維を用いたエアバッグ用織物は、滑脱抵抗力と剛軟度の比(EC/V)が、25N/N以上であることが好ましい。EC/Vが、25N/N以上であれば、エアバッグ用途として、低通気性と柔軟性を十分に備えた織物となる。EC/Vは、より好ましくは35N/N以上、さらに好ましくは45N/N以上である。 The airbag fabric using the synthetic fiber of this embodiment preferably has a ratio of slippage resistance to bending resistance (EC/V) of 25 N/N or more. If the EC/V is 25 N/N or more, the fabric will have sufficient low breathability and flexibility for use in airbags. The EC/V is more preferably 35 N/N or more, and even more preferably 45 N/N or more.

本実施形態のエアバッグ用合成繊維を用いたエアバッグ用織物は、滑脱抵抗力と剛軟度の比(EC/V)のバラつきがCV値で20%以下であることが好ましい。EC/VのCV値が20%以下であれば、織物幅方向でのバラつきが少なく、基布物性が安定化し、高滑脱抵抗力かつ柔軟性のよいエアバッグ織物となる。そのため、エアバッグパーツを織物の如何なる部分から切断してきても同等な物性をもち、エアバッグの信頼性が向上する。EC/VのCV値は、より好ましくは17.5%以下、さらに好ましくは15%以下である。In the airbag fabric using the synthetic airbag fiber of this embodiment, it is preferable that the variation in the ratio of slippage resistance to bending resistance (EC/V) is 20% or less in CV value. If the EC/V CV value is 20% or less, the variation in the width direction of the fabric is small, the physical properties of the base fabric are stabilized, and the airbag fabric has high slippage resistance and good flexibility. Therefore, no matter which part of the fabric the airbag parts are cut from, they have the same physical properties, and the reliability of the airbag is improved. The EC/V CV value is more preferably 17.5% or less, and even more preferably 15% or less.

以下、実施例、比較例を挙げて本発明を具体的に説明するが、本発明はこれらの実施例のみに限定されるものではない。尚、明細書中、以下の実施例等で用いた仕上剤組成、物性の定義、及び測定方法は次の通りのものである。The present invention will be specifically explained below with reference to examples and comparative examples, but the present invention is not limited to these examples. In addition, the finishing agent composition, definitions of physical properties, and measurement methods used in the following examples are as follows.

(1)仕上剤調合
紡糸油剤に用いる仕上剤を以下の方法で調合した。
まず、ベースとなる組成Aを作製した。組成Aの組成内容は下記であった。
・ジアルキル(C12~18)チオジプロピオネート:40重量部
・硬化ひまし油のエチレンオキサイド25モル付加物:30重量部
・プロピレンオキサイド/エチレンオキサイドアルキル(C12~18)ポリエーテル:30重量部
上記ベースの組成Aに、イオン性界面活性剤であるアルキル(C12~16)リン酸アミン塩を、以下の表1、2に記載の「仕上剤中のイオン界面活性剤含有率(重量%)」となるように加え仕上剤を調整した。仕上剤の含有量が22重量%となるように水を添加してエマルジョン液を作製した。
(1) Preparation of Finishing Agent The finishing agent used in the spinning oil was prepared by the following method.
First, a base composition A was prepared. The composition A had the following components:
Dialkyl (C12-18) thiodipropionate: 40 parts by weight Ethylene oxide 25 mole adduct of hydrogenated castor oil: 30 parts by weight Propylene oxide/ethylene oxide alkyl (C12-18) polyether: 30 parts by weight An ionic surfactant, alkyl (C12-16) phosphate amine salt, was added to the above base composition A so as to obtain the "ionic surfactant content (wt%) in the finishing agent" shown in Tables 1 and 2 below, to adjust the finishing agent. Water was added so that the finishing agent content was 22 wt% to prepare an emulsion liquid.

(2)水滴接触角(°)
水滴接触角の測定は、自動極小接触角計(協和界面科学(株)製“MCA-J”)で行った。図4は水滴接触角の計測における説明図である。測定条件としては、気温25℃湿度50%の室内の大気中で、測定治具間に単糸を固定し、24℃の水を20pL単糸に乗せ、水滴の様子を側方からカメラにて動画撮影して接触角αを測定する。接触角αは経時的に低下する(水が糸になじんでいく)が、糸の瞬間的な水なじみを確認するため100ms内(動画の1フレームは8ms)での接触角の最大値を測定値とした。この操作を別の単糸で繰り返し行い、全5回の平均値をそれぞれの単糸の水に対する水滴接触角とした。
(2) Water droplet contact angle (°)
The water droplet contact angle was measured using an automatic contact angle meter ("MCA-J" manufactured by Kyowa Interface Science Co., Ltd.). Figure 4 is an explanatory diagram of the measurement of the water droplet contact angle. The measurement conditions were: temperature In the air at 25°C and 50% humidity, the single yarn was fixed between the measuring jigs, 20 pL of water at 24°C was placed on the single yarn, and the state of the water droplet was recorded from the side with a camera to measure the contact angle. The contact angle α decreases over time (as the water becomes accustomed to the thread), but in order to confirm the instantaneous water accustoming of the thread, the contact angle α is measured within 100 ms (one frame of the video is 8 ms). This procedure was repeated for another single yarn, and the average value of all five measurements was taken as the water droplet contact angle of each single yarn.

(3)水滴接触角の糸長方向の変動係数CV
水滴接触角について、1本の単糸について5cmおきに10点測定し、以下の計算で単糸のCV値を求めた。
CV(%)=(s/X)×100
ここで、sは標準偏差であり、Xは平均値である。
この操作を別の5本の単糸で繰り返し行い、各単糸のCV値の平均値を水滴接触角の糸長方向の変動係数CVとした。CV値が高いほど、ばらつきが大きいことを示す。
(3) Coefficient of variation of water droplet contact angle in the thread length direction, CV
The water droplet contact angle was measured at 10 points at 5 cm intervals for one single yarn, and the CV value of the single yarn was calculated as follows.
CV (%) = (s/X) x 100
where s is the standard deviation and X is the mean.
This procedure was repeated for five other single yarns, and the average CV value of each single yarn was taken as the coefficient of variation CV of the water droplet contact angle in the yarn length direction. A higher CV value indicates a larger variation.

(4)交絡度(個/m)
交絡度測定用の水浴バスは、長さ1.2m、幅20cm、高さ(水深)15cmの大きさで、両端から各10cmの部分、つまり間隔が1mとなるように白線があり、供給口から供給された水はバスから溢流により排水される。すなわち、常に新しい水を約500cc/分の流量で供給することによって測定バス内の水を更新させる。測定方法は、1.2mほどにカットした糸条の両端を持って、測定バス内に約10cNの張力をかけた状態で浸漬させ、水面で弛緩状態になった時の白線間の交絡数(個/m)を目視により読み取る。これらの測定を50回繰り返し、その平均値を評価する。
(4) Degree of entanglement (pieces/m)
The water bath for measuring the degree of entanglement was 1.2 m long, 20 cm wide, and 15 cm high (depth), with white lines 10 cm apart from each end, i.e., 1 m apart. The water supplied from the bath is drained by overflow. In other words, the water in the measurement bath is constantly renewed by supplying new water at a flow rate of about 500 cc/min. The cut yarn is held at both ends and immersed in a measurement bath under a tension of about 10 cN, and when it becomes relaxed on the water surface, the number of entanglements between the white lines (pieces/m) is visually read. These measurements are repeated 50 times and the average value is evaluated.

(5)非交絡部面積(cm2
上記(4)と同様に測定バス内に糸条を浸漬させ、図5に示すように水面に拡がった糸条の非交絡部の長さa、及び非交絡部の幅bをスケールにて測定し、a×bを非交絡部面積とする。糸長さ20cm区域で、水面上に広がった非交絡部面積を合計して1回の測定とし、この測定を毎回異なる20cm区域について25回繰り返して平均値を求めた。
(5) Unentangled area (cm 2 )
As in (4) above, the yarn is immersed in the measurement bath, and the length a of the unentangled portion of the yarn spread on the water surface and the width b of the unentangled portion are measured on a scale as shown in FIG. The area of the unentangled part that spreads above the water surface in a 20 cm section of the yarn length is totaled as one measurement, and this measurement is repeated 25 times for different 20 cm sections each time. The average value was calculated.

(6)非交絡部面積の変動係数CV
上記(5)で測定した非交絡部面積について以下の計算で求めた。CV値が高いほど、ばらつきが大きいことを示す。
CV(%)=(s/X)×100
ここで、sは標準偏差であり、Xは平均値である。
(6) Coefficient of variation of unentangled area CV
The area of the unentangled portion measured in (5) above was calculated by the following formula. A higher CV value indicates a larger variation.
CV (%) = (s/X) x 100
where s is the standard deviation and X is the mean.

(7)繊度
JIS L 1017 8.3aにより測定した。尚、試料は巻き取りパッケージから枠周1.25mの検尺機を用いて50m採取した。
(7) Fineness: Measured according to JIS L 1017 8.3a. A 50 m sample was taken from the winding package using a measuring machine with a frame circumference of 1.25 m.

(8)強度(cN/dtex)、伸度(%)
試料を標準状態(20℃、65%)で12時間放置した後、JIS L 1017 8.5aにより測定した。尚、試料長は250mm、引張速度は300mm/分で測定した。
(8) Strength (cN/dtex), elongation (%)
The sample was left for 12 hours under standard conditions (20° C., 65%) and then measured according to JIS L 1017 8.5a with a sample length of 250 mm and a tensile speed of 300 mm/min.

(9)沸水収縮率(%)
JIS L 1017 8.14により測定した。尚、沸騰水に浸漬後は標準状態(20℃、65%)の室内にて12時間放置した。
(9) Boiling water shrinkage rate (%)
The measurement was performed according to JIS L 1017 8.14. After immersion in boiling water, the sample was left to stand for 12 hours in a room under standard conditions (20° C., 65%).

(10)仕上剤付着率(重量%)
JIS L 1017 8.16bにより測定した。抽出溶剤にはシクロヘキサンを用いた。
(10) Finishing agent adhesion rate (wt%)
The measurement was performed according to JIS L 1017 8.16b. Cyclohexane was used as the extraction solvent.

(11)イオン性界面活性剤付着率(ppm)
上記(10)で測定した値(仕上剤付着率(重量%))と仕上剤中のイオン性界面活性剤濃度(仕上剤中イオン性界面活性剤含有率(%))から算出した。
(11) Ionic surfactant adhesion rate (ppm)
This was calculated from the value measured in (10) above (finishing agent adhesion rate (wt %)) and the ionic surfactant concentration in the finishing agent (ionic surfactant content (%) in the finishing agent).

(12)緯糸滑脱抵抗力EC(N)
サンプルを基布幅方向に5か所採取する工程を基布長さ方向に5回、つまり計25点のサンプルを採取し、それらの緯糸滑脱抵抗力(N)をASTM D6479にしたがって測定し、その平均値を算出した。
(12) Weft slippage resistance EC (N)
The process of taking samples at five locations in the width direction of the base fabric was repeated five times in the length direction of the base fabric, i.e., a total of 25 samples were taken. The weft slippage resistance (N) of these samples was measured according to ASTM D6479, and the average value was calculated.

(13)基布剛軟度V(N)
上記(12)緯糸滑脱抵抗力EC試験でサンプルの近接部位からサンプルをとり、得られた25点のサンプルの基布剛軟度(N)をASTM D4032にしたがって測定し、その平均値を算出した。
(13) Base fabric stiffness V (N)
In the above (12) weft slippage resistance EC test, samples were taken from adjacent parts of the sample, and the fabric stiffness (N) of the obtained 25 samples was measured according to ASTM D4032, and the average value was calculated. .

[実施例1]
図2に示す装置により、常法の重合方法にて得られた90%蟻酸相対粘度が80のナイロン66ポリマーを300℃にて溶融後、スピンヘッド3により均温化させ、孔数136の紡糸口金4により吐出して、直接紡糸延伸プロセスによって巻取り、470dtex、136フィラメントのポリアミド66繊維を製糸した。すなわち、吐出されたナイロン66ポリマーは、冷風チャンバー5にて冷却固化され糸条を形成した後、給油装置6、引取りローラ7、第1ローラ8から第4ローラ11を順次通過させ、糸道規制ガイド12にて糸走を安定させた後、交絡付与装置13にて糸条に交絡を付与し、糸道規制ガイド12を通過させ、巻取り機14にて巻き取った。
[Example 1]
2, nylon 66 polymer having a relative viscosity of 80 in 90% formic acid obtained by a conventional polymerization method was melted at 300°C, uniformly heated by a spin head 3, discharged from a spinneret 4 having 136 holes, and wound up by a direct spinning and drawing process to spin a polyamide 66 fiber of 470 dtex and 136 filaments. That is, the discharged nylon 66 polymer was cooled and solidified in a cold air chamber 5 to form a yarn, which was then passed through an oil supplying device 6, a take-up roller 7, a first roller 8 to a fourth roller 11 in this order, the yarn running was stabilized by a yarn path regulating guide 12, the yarn was entangled by an entanglement imparting device 13, passed through the yarn path regulating guide 12, and wound up by a winder 14.

給油工程では、一つの仕上剤付与装置で仕上剤を付着率が0.7%、イオン性界面活性剤の付着率が350ppmとなるような組成で付与した。交絡付与装置13への圧縮空気の付与は0.5MPaで、空気供給エネルギーは1.2kWとした。糸道規制ガイド12間の距離は7.3cmとした。巻取張力は0.19cN/dtexとなるように調整した。巻取条件は、短周期揺動幅比率Bを4.0%、巻き始め綾角を7.8°、パッケージ幅Wを16cmとした。得られたポリアミド66繊維の物性等を以下の表1に示す。In the oiling process, a finishing agent was applied in one finishing agent application device with a composition such that the adhesion rate was 0.7% and the adhesion rate of the ionic surfactant was 350 ppm. Compressed air was applied to the interlacing device 13 at 0.5 MPa, and the air supply energy was 1.2 kW. The distance between the yarn path control guides 12 was 7.3 cm. The winding tension was adjusted to 0.19 cN/dtex. The winding conditions were a short-period oscillation width ratio B of 4.0%, a winding start twill angle of 7.8°, and a package width W of 16 cm. The physical properties of the obtained polyamide 66 fiber are shown in Table 1 below.

得られたポリアミド66繊維をWJLを用いて900rpmの速度で平織りし、織物を得た。得られた織物を80℃の連続精練で精練し、170℃のテンターで織物送りのオーバーフィード4%、織物幅を1%の幅入れで熱セットし、経糸及び緯糸の織密度を2.54cmあたり53本×53本の織物を得た。カバーファクターは2298である。この織物の滑脱抵抗力と基布剛軟度を評価した。評価結果を以下の表1に示す。水滴接触角が適切な程度となり、非交絡部面積の変動係数が小さく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。The obtained polyamide 66 fibers were plain woven at 900 rpm using a WJL to obtain a woven fabric. The obtained woven fabric was refined by continuous scouring at 80°C, and heat set in a tenter at 170°C with an overfeed of 4% and a width of 1% to obtain a woven fabric with a warp and weft density of 53 x 53 threads per 2.54 cm. The cover factor was 2298. The slippage resistance and stiffness of the base fabric of this woven fabric were evaluated. The evaluation results are shown in Table 1 below. The water droplet contact angle was at an appropriate level, the coefficient of variation of the unentangled area was small, and the coefficient of variation of EC/V was small, resulting in a woven fabric with little variation.

[実施例2]
給油工程にて、イオン性界面活性剤の付着率を490ppmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表1に示す。水滴接触角が適切な程度となり、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 2]
Except for changing the adhesion rate of the ionic surfactant to 490 ppm in the oiling step, the same procedure as in Example 1 was carried out. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in the following Table 1. The water droplet contact angle was at an appropriate level, and the coefficient of variation of EC/V was small, resulting in a woven fabric with little variation.

[実施例3]
給油工程にて、イオン性界面活性剤の付着率を210ppmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表1に示す。水滴接触角が適切な程度なかでも少々大きくなり、EC/Vの変動係数がやや大きく、ややバラつきのある織物となった。
[Example 3]
Except for changing the adhesion rate of the ionic surfactant to 210 ppm in the oiling step, the same procedure as in Example 1 was carried out. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in the following Table 1. The water drop contact angle was slightly large even within an appropriate range, and the coefficient of variation of EC/V was somewhat large, resulting in a woven fabric with some variation.

[実施例4]
給油工程にて、イオン性界面活性剤の付着率を490ppmとし、巻取工程にて、パッケージ幅Wを8.5cmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表1に示す。水滴接触角が適切な程度となり、非交絡部面積の変動係数が小さく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 4]
The same procedure as in Example 1 was carried out except that in the oiling process, the adhesion rate of the ionic surfactant was set to 490 ppm, and in the winding process, the package width W was set to 8.5 cm. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in the following Table 1. The water drop contact angle was at an appropriate level, and the coefficient of variation of the unentangled part area and the coefficient of variation of EC/V were small, resulting in a woven fabric with little variation.

[実施例5]
巻取工程にて、短周期揺動幅比率Bを1.5%、パッケージ幅Wを8.5cmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表1に示す。非交絡部面積の変動係数が小さく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 5]
The same procedure as in Example 1 was carried out except that in the winding process, the short cycle oscillation width ratio B was 1.5% and the package width W was 8.5 cm. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in the following Table 1. The coefficient of variation of the unentangled part area and the coefficient of variation of EC/V were small, resulting in a woven fabric with little variation.

[実施例6]
巻取工程にて、短周期揺動幅比率Bを0.8%、パッケージ幅Wを8.5cmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表1に示す。非交絡部面積の変動係数がやや大きくなり、EC/Vの変動係数がやや大きく、ややバラつきのある織物となった。
[Example 6]
The same procedure as in Example 1 was carried out except that in the winding process, the short cycle oscillation width ratio B was set to 0.8% and the package width W was set to 8.5 cm. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in the following Table 1. The coefficient of variation of the unentangled part area was slightly large, and the coefficient of variation of EC/V was slightly large, resulting in a woven fabric with some variation.

[実施例7]
巻取工程にて、パッケージ幅Wを19.0cmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表1に示す。非交絡部面積の変動係数がやや大きくなり、EC/Vの変動係数がやや大きく、ややバラつきのある織物となった。
[Example 7]
The same procedure as in Example 1 was carried out except that the package width W in the winding process was set to 19.0 cm. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in the following Table 1. The coefficient of variation of the unentangled part area was slightly large, and the coefficient of variation of EC/V was slightly large, resulting in a woven fabric with some variation.

[実施例8]
交絡付与工程にて、糸道規制ガイド12間の距離を7.8cmとした以外は実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表1に示す。非交絡部面積が大きく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 8]
The same procedure as in Example 1 was carried out, except that in the entanglement step, the distance between the yarn path regulating guides 12 was set to 7.8 cm. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in the following Table 1. The woven fabric had a large unentangled part area, a small coefficient of variation of EC/V, and little variation.

[実施例9]
交絡付与工程にて、空気供給エネルギーを0.7kWとした以外は実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表2に示す。非交絡部面積が大きく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 9]
The same procedure as in Example 1 was carried out, except that the air supply energy in the entanglement step was 0.7 kW. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 2. The woven fabric had a large unentangled area, a small coefficient of variation of EC/V, and little variation.

[実施例10]
ポリマーの吐出工程にて、紡糸口金4の孔数を72とし、470dtex、72フィラメントのポリアミド66繊維を製糸した以外は実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表2に示す。水滴接触角がやや大きく、EC/Vの変動係数がやや大きく、ややバラつきのある織物となった。
[Example 10]
The same procedure as in Example 1 was carried out, except that in the polymer discharge step, the number of holes in the spinneret 4 was set to 72, and polyamide 66 fiber of 470 dtex and 72 filaments was spun. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 2 below. The water drop contact angle was somewhat large, and the coefficient of variation of EC/V was somewhat large, resulting in a woven fabric with some variation.

[実施例11]
ポリマーの吐出工程にて、350dtex、136フィラメントのポリアミド66繊維を製糸した。製織工程にて、経糸及び緯糸の織密度を2.54cmあたり60本×60本とし、カバーファクターが2245の織物を得た。上記の吐出工程と製織工程以外は実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表2に示す。水滴接触角が適切な程度となり、非交絡部面積の変動係数が小さく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 11]
In the polymer discharge step, polyamide 66 fibers of 350 dtex and 136 filaments were spun. In the weaving step, the weaving density of the warp and weft yarns was 60 x 60 yarns per 2.54 cm, and a woven fabric with a cover factor of 2245 was obtained. The same procedures as in Example 1 were carried out except for the above discharge and weaving steps. The physical properties of the obtained polyamide 66 fibers and the evaluation results of the woven fabric are shown in Table 2 below. The water droplet contact angle was at an appropriate level, the coefficient of variation of the unentangled part area was small, and the coefficient of variation of EC/V was small, resulting in a woven fabric with little variation.

[実施例12]
ポリマーの吐出工程にて、紡糸口金4の孔数を216とし、350dtex、216フィラメントのポリアミド66繊維を製糸した。上記の吐出工程以外は実施例11と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表2に示す。水滴接触角のばらつきが大きくなり、EC/Vの変動係数がやや大きく、ややバラつきのある織物となった。
[Example 12]
In the polymer discharge step, the number of holes in the spinneret 4 was set to 216, and polyamide 66 fiber of 350 dtex and 216 filaments was spun. The procedure was the same as in Example 11 except for the above-mentioned discharge step. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 2 below. The water droplet contact angle had a large variation, and the coefficient of variation of EC/V was somewhat large, resulting in a woven fabric with some variation.

[実施例13]
ポリマーの吐出工程にて、紡糸口金4の孔数を216とし、給油工程にて給油装置を糸道方向の異なる位置に2個、かつその給油部の方向を正対させて仕上剤を付与し、350dtex、216フィラメントのポリアミド66繊維を製糸した。上記の吐出工程と給油工程以外は実施例11と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表2に示す。水滴接触角が適切な程度となり、単糸が細いながらも水滴接触角のばらつきが小さく、非交絡部面積の変動係数が小さく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 13]
In the polymer discharge step, the number of holes in the spinneret 4 was set to 216, and in the oiling step, two oiling devices were installed at different positions in the yarn path direction, and the oiling parts were directed opposite to each other to apply a finishing agent, thereby spinning a polyamide 66 fiber of 350 dtex and 216 filaments. The same procedure as in Example 11 was carried out except for the above-mentioned discharge step and oiling step. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 2 below. The water droplet contact angle was at an appropriate level, and although the single yarn was thin, the variation in the water droplet contact angle was small, the coefficient of variation of the unentangled part area was small, and the coefficient of variation of EC/V was small, resulting in a woven fabric with little variation.

[実施例14]
ポリマーの吐出工程にて、紡糸口金4の孔数を216とし、235dtex、216フィラメントのポリアミド66繊維を製糸した。製織工程にて、経糸及び緯糸の織密度を2.54cmあたり72本×72本とし、カバーファクターが2207の織物を得た。上記の吐出工程と製織工程以外は実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表2に示す。水滴接触角のばらつきが大きくなり、EC/Vの変動係数がやや大きく、ややバラつきのある織物となった。
[Example 14]
In the polymer discharge step, the number of holes in the spinneret 4 was set to 216, and polyamide 66 fibers of 235 dtex and 216 filaments were spun. In the weaving step, the weaving density of the warp and weft yarns was set to 72 x 72 threads per 2.54 cm, and a woven fabric with a cover factor of 2207 was obtained. The same procedures as in Example 1 were carried out except for the above discharge step and weaving step. The physical properties of the obtained polyamide 66 fibers and the evaluation results of the woven fabric are shown in Table 2 below. The variation in water droplet contact angle was large, and the coefficient of variation of EC/V was somewhat large, resulting in a woven fabric with some variation.

[実施例15]
ポリマーの吐出工程にて、紡糸口金4の孔数を216とし、給油工程にて給油装置を糸道方向の異なる位置に2個、かつその給油部の方向を正対させて仕上剤を付与し、235dtex、216フィラメントのポリアミド66繊維を製糸した。上記の給油工程以外は実施例14と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表2に示す。水滴接触角が適切な程度となり、単糸が細いながらも水滴接触角のばらつきが小さく、非交絡部面積の変動係数が小さく、EC/Vの変動係数が小さく、バラつきの少ない織物となった。
[Example 15]
In the polymer discharge step, the number of holes in the spinneret 4 was set to 216, and in the oiling step, two oiling devices were installed at different positions in the yarn path direction, and the oiling parts were directed opposite to each other to apply a finishing agent, thereby spinning a polyamide 66 fiber of 235 dtex and 216 filaments. The procedure was the same as in Example 14 except for the above-mentioned oiling step. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 2 below. The water droplet contact angle was at an appropriate level, and although the single yarn was thin, the variation in the water droplet contact angle was small, the coefficient of variation of the unentangled part area was small, and the coefficient of variation of EC/V was small, resulting in a woven fabric with little variation.

[比較例1]
給油工程にて、イオン性界面活性剤付着率を70ppmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表3に示す。水滴接触角が大きく、EC/Vの変動係数が大きく、バラつきの大きい織物となった。
[Comparative Example 1]
Except for changing the ionic surfactant adhesion rate to 70 ppm in the oiling step, the same procedure as in Example 1 was carried out. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 3 below. The woven fabric had a large water drop contact angle and a large coefficient of variation of EC/V, resulting in a large variation.

[比較例2]
給油工程にて、イオン性界面活性剤付着率を840ppmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表3に示す。水滴接触角が小さく、EC/Vの変動係数が大きく、バラつきのある織物となった。
[Comparative Example 2]
Except for changing the ionic surfactant adhesion rate to 840 ppm in the oiling step, the same procedure as in Example 1 was carried out. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 3 below. The water drop contact angle was small, and the coefficient of variation of EC/V was large, resulting in a woven fabric with variation.

[比較例3]
巻取工程にて、短周期揺動幅比率Bを0.2とし、パッケージ幅Wを8.5cmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表3に示す。非交絡部面積の変動係数が大きくなり、EC/Vの変動係数が大きく、バラつきのある織物となった。
[Comparative Example 3]
The same procedure as in Example 1 was carried out except that in the winding process, the short-period oscillation width ratio B was set to 0.2 and the package width W was set to 8.5 cm. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 3 below. The coefficient of variation of the unentangled part area was large, and the coefficient of variation of EC/V was large, resulting in a woven fabric with variation.

[比較例4]
巻取工程にて、パッケージ幅Wを32cmとした以外は、実施例1と同様に実施した。得られたポリアミド66繊維の物性等と織物の評価結果等を以下の表3に示す。非交絡部面積の変動係数が大きくなり、EC/Vの変動係数が大きく、バラつきのある織物となった。
[Comparative Example 4]
The same procedure as in Example 1 was carried out except that the package width W in the winding process was set to 32 cm. The physical properties of the obtained polyamide 66 fiber and the evaluation results of the woven fabric are shown in Table 3 below. The coefficient of variation of the unentangled part area was large, and the coefficient of variation of EC/V was also large, resulting in a woven fabric with variation.

Figure 0007560657000001
Figure 0007560657000001

Figure 0007560657000002
Figure 0007560657000002

Figure 0007560657000003
Figure 0007560657000003

本発明のエアバッグ用合成繊維は、WJLを用いた製織において、水の包含性(糸の瞬間的な親水性)に優れることで、緯糸飛走性(噴射水への追従性)を飛躍的に改善し、かつ、均一な非交絡部面積を有することで、均一かつ直線的に飛走する特性(糸の均一飛走性)に優れる。これら2点の特性から、基布幅方向での品質のバラつきなく、高速製織を行うことが可能となる。よって、本発明のエアバッグ用合成繊維は、エアバッグ用織物の製織のための織糸、特に緯糸として好適に利用可能である。The synthetic fiber for airbags of the present invention has excellent water inclusion (instantaneous hydrophilicity of the yarn) in weaving using WJL, which dramatically improves weft yarn flight properties (ability to follow sprayed water), and has a uniform non-entangled area, which gives it excellent uniform and linear flight properties (uniform yarn flight properties). These two characteristics make it possible to weave at high speeds without variation in quality across the width of the base fabric. Therefore, the synthetic fiber for airbags of the present invention can be suitably used as a weaving yarn, particularly a weft yarn, for weaving airbag fabrics.

1 パッケージ
2 紙管
3 スピンヘッド
4 紡口口金
5 冷風チャンバー
6 給油装置(仕上剤付与装置)
7 引き取りローラ
8 第1ローラ
9 第2ローラ
10 第3ローラ
11 第4ローラ
12 糸道規制ガイド
13 交絡付与装置
14 巻取り機
15 単糸
16 水滴
W 巻き取りパッケージの幅
B 短周期搖動幅比率
θ 巻き始めの綾角
α 水滴接触角
a 非交絡部の長さ
b 非交絡部の幅
1 Package 2 Paper tube 3 Spin head 4 Spinneret 5 Cold air chamber 6 Oil supply device (finishing agent application device)
Reference Signs List 7 Take-up roller 8 First roller 9 Second roller 10 Third roller 11 Fourth roller 12 Yarn path control guide 13 Intertwining device 14 Winding machine 15 Single yarn 16 Water drop W Width of winding package B Short period oscillation width ratio θ Twirl angle at start of winding α Water drop contact angle a Length of non-entangled portion b Width of non-entangled portion

Claims (16)

交絡部と非交絡部を有するエアバッグ用マルチフィラメント合成繊維であって、単糸表面の水滴接触角が50~75°であり、かつ、20cmごとの非交絡部面積のバラつきがCV値で10%以下であることを特徴とするエアバッグ用合成繊維。A synthetic multifilament fiber for airbags having entangled and unentangled portions, characterized in that the water droplet contact angle on the surface of the single yarn is 50 to 75°, and the variation in the area of unentangled portions per 20 cm is 10% or less in CV value. 前記非交絡部面積が糸長方向に20cm範囲ごとの評価で12.5~20cmの範囲である、請求項1に記載のエアバッグ用合成繊維。 2. The synthetic fiber for airbags according to claim 1, wherein the area of the unentangled portions is in the range of 12.5 to 20 cm2 when evaluated every 20 cm in the length direction of the fiber. 単糸数が60~250本である、請求項1又は2に記載のエアバッグ用合成繊維。 A synthetic fiber for airbags as described in claim 1 or 2, having a single yarn count of 60 to 250. 単糸繊度が1~7dtexである、請求項1又は2に記載のエアバッグ用合成繊維。 A synthetic fiber for airbags according to claim 1 or 2, having a single yarn fineness of 1 to 7 dtex. 単糸数が200~250本、かつ、単糸繊度が1.0dtex~1.8dtexである、請求項1又は2に記載のエアバッグ用合成繊維。 A synthetic fiber for airbags according to claim 1 or 2, having a single yarn count of 200 to 250 and a single yarn fineness of 1.0 dtex to 1.8 dtex. 交絡度が10~35個/mである、請求項1又は2に記載のエアバッグ用合成繊維。 A synthetic fiber for airbags as described in claim 1 or 2, having a degree of entanglement of 10 to 35 pieces/m. 単糸表面の水滴接触角の長さ方向のバラつきがCV値で5%以下である、請求項1又は2に記載のエアバッグ用合成繊維。 A synthetic fiber for airbags as described in claim 1 or 2, in which the variation in the length direction of the water droplet contact angle on the surface of a single yarn is 5% or less in CV value. 仕上剤付着率が0.6~1.2重量%である、請求項1又は2に記載のエアバッグ用合成繊維。 A synthetic fiber for airbags as described in claim 1 or 2, in which the finishing agent adhesion rate is 0.6 to 1.2 weight %. リン原子を含むアニオン性界面活性剤及び/又は硫黄原子を含むアニオン性界面活性剤が繊維重量に対して200~500ppm付着している、請求項1又は2に記載のエアバッグ用合成繊維。 The synthetic fiber for airbags according to claim 1 or 2, in which an anionic surfactant containing a phosphorus atom and/or an anionic surfactant containing a sulfur atom is attached in an amount of 200 to 500 ppm based on the fiber weight. 下記要件(1)~(4):
(1)総繊度が150~800dtexである;
(2)強度が7.5~9cN/dtexである;
(3)伸度が15~25%である;及び
(4)沸水収縮率が4~11%である;
を満たす、請求項1又は2に記載のエアバッグ用合成繊維。
The following requirements (1) to (4):
(1) The total fineness is 150 to 800 dtex;
(2) Tenacity is 7.5 to 9 cN/dtex;
(3) Elongation is 15 to 25%; and (4) Boiled water shrinkage is 4 to 11%;
3. The synthetic fiber for an airbag according to claim 1 or 2, which satisfies the above.
パッケージの幅Wが8~22cmである、請求項1又は2に記載のエアバッグ用合成繊維の巻き取りパッケージ。 A winding package of synthetic fiber for airbags as described in claim 1 or 2, wherein the width W of the package is 8 to 22 cm. 以下の工程:
溶融紡糸により紡糸された合成繊維を、1つ以上の仕上剤付与(給油)装置、多段延伸ローラ、交絡付与装置、及び該交絡付与装置の前後に設けられた1つ以上の糸道規制ガイドを経由して、管軸方向に糸条を搖動するためのトラバーサーを備えた巻き取り機を用いて、管に巻き取る工程;
を含む、エアバッグ用合成繊維の製造方法であって、該工程における、巻き取り前の張力が0.1~0.3cNであり、かつ、トラバーサーによる糸条の搖動における短周期揺動幅比率Bが0.5~5%であることを特徴とする前記方法。
The following steps:
A step of winding synthetic fibers spun by melt spinning onto a tube using a winding machine equipped with a traverser for swinging the yarn in the tube axial direction, the yarn passing through one or more finishing agent applying (oiling) devices, multi-stage drawing rollers, an entanglement applying device, and one or more yarn path regulating guides provided before and after the entanglement applying device;
wherein in said step, the tension before winding is 0.1 to 0.3 cN, and the short-period oscillation width ratio B in the oscillation of the yarn by a traverser is 0.5 to 5%.
合成繊維を管に巻き取ることで得られるパッケージの幅Wが8~22cmである、請求項12に記載のエアバッグ用合成繊維の製造方法。 A method for producing synthetic fibers for airbags as described in claim 12, wherein the width W of the package obtained by winding the synthetic fibers around a tube is 8 to 22 cm. 前記仕上剤付与装置によって、リン原子を含むアニオン性界面活性剤及び/又は硫黄原子を含むアニオン性界面活性剤が繊維重量に対して200~500ppm付着するように仕上剤を付与する、請求項12又は13に記載のエアバッグ用合成繊維の製造方法。 The method for producing synthetic fibers for airbags according to claim 12 or 13, wherein the finishing agent is applied by the finishing agent application device so that the anionic surfactant containing phosphorus atoms and/or the anionic surfactant containing sulfur atoms adheres to the fiber in an amount of 200 to 500 ppm based on the fiber weight. 前記仕上剤付与装置が糸道方向の異なる位置に2つ以上あり、かつ少なくとも2つの仕上剤付与装置の給油部の方向が正対している、請求項12又は13に記載のエアバッグ用合成繊維の製造方法The method for producing a synthetic fiber for an airbag according to claim 12 or 13, wherein the finishing agent application device is provided at two or more positions different from each other in the yarn path direction, and the oil supply portions of at least two of the finishing agent application devices face each other. 以下の工程:
ウォータージェットルーム織機において、緯糸に請求項1又は2に記載のエアバッグ用合成繊維を用いて、製織速度800rpm以上で、織物を製織する工程;
を含む、エアバッグ用織物の製造方法。
The following steps:
weaving a fabric in a water jet loom at a weaving speed of 800 rpm or more using the synthetic fiber for an airbag according to claim 1 or 2 as a weft;
A method for producing a fabric for an airbag, comprising:
JP2023511764A 2021-04-02 2022-04-01 Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same Active JP7560657B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2024162431A JP2024169601A (en) 2021-04-02 2024-09-19 Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2021063485 2021-04-02
JP2021063485 2021-04-02
PCT/JP2022/017011 WO2022211130A1 (en) 2021-04-02 2022-04-01 Synthetic fibers for airbag, and method for manufacturing woven fabric for airbag using same

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2024162431A Division JP2024169601A (en) 2021-04-02 2024-09-19 Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same

Publications (2)

Publication Number Publication Date
JPWO2022211130A1 JPWO2022211130A1 (en) 2022-10-06
JP7560657B2 true JP7560657B2 (en) 2024-10-02

Family

ID=83459659

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2023511764A Active JP7560657B2 (en) 2021-04-02 2022-04-01 Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same
JP2024162431A Pending JP2024169601A (en) 2021-04-02 2024-09-19 Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2024162431A Pending JP2024169601A (en) 2021-04-02 2024-09-19 Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same

Country Status (3)

Country Link
JP (2) JP7560657B2 (en)
CN (1) CN117098882A (en)
WO (1) WO2022211130A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001288638A (en) 2000-03-31 2001-10-19 Toray Ind Inc Entangled yarns and fabrics and airbags
JP2006124859A (en) 2004-10-28 2006-05-18 Toray Ind Inc Original yarn package for airbag and airbag fabric using the same
JP2007284826A (en) 2006-04-18 2007-11-01 Toray Ind Inc Manufacturing method for air bag base fabric
JP2009185421A (en) 2008-02-08 2009-08-20 Toray Ind Inc Silicone coated airbag fabric and method for producing the same
WO2013084322A1 (en) 2011-12-07 2013-06-13 旭化成せんい株式会社 Synthetic fiber

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111155219B (en) * 2015-06-29 2021-06-15 东洋纺株式会社 Fabric for airbag, method for producing same, and airbag
KR102584803B1 (en) * 2017-11-28 2023-10-05 도레이 카부시키가이샤 High-strength, fine-fine polyester multifilament
CN108716049B (en) * 2018-06-28 2021-07-09 东华大学 Warp and weft yarn density and composition fiber unidirectional perspiration waterproof interwoven fabric and its application
CN109898214A (en) * 2019-04-16 2019-06-18 江苏恒能家纺新材料有限公司 A method of Hygroscopic material is produced using water-jet loom

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001288638A (en) 2000-03-31 2001-10-19 Toray Ind Inc Entangled yarns and fabrics and airbags
JP2006124859A (en) 2004-10-28 2006-05-18 Toray Ind Inc Original yarn package for airbag and airbag fabric using the same
JP2007284826A (en) 2006-04-18 2007-11-01 Toray Ind Inc Manufacturing method for air bag base fabric
JP2009185421A (en) 2008-02-08 2009-08-20 Toray Ind Inc Silicone coated airbag fabric and method for producing the same
WO2013084322A1 (en) 2011-12-07 2013-06-13 旭化成せんい株式会社 Synthetic fiber

Also Published As

Publication number Publication date
JP2024169601A (en) 2024-12-05
JPWO2022211130A1 (en) 2022-10-06
WO2022211130A1 (en) 2022-10-06
CN117098882A (en) 2023-11-21

Similar Documents

Publication Publication Date Title
JP5253685B1 (en) Synthetic fiber
JP4618391B2 (en) Air bag base fabric, air bag yarn and method of manufacturing the same
JP5365272B2 (en) Fabric for airbag and method for producing fabric for airbag
KR101642155B1 (en) High tenacity low shrinkage polyamide yarns
JP7560657B2 (en) Synthetic fiber for airbags and method for manufacturing fabric for airbags using the same
JP2007284826A (en) Manufacturing method for air bag base fabric
JP4603297B2 (en) Polyhexamethylene adipamide fiber
JP4538967B2 (en) Airbag fabric
US20180086301A1 (en) Airbag-use woven fabric and airbag
JP2003020566A (en) Polyamide fiber
JP4770152B2 (en) Airbag yarn package, airbag fabric using the same, and method for producing airbag yarn package
JPH08269870A (en) Method for producing polyester multifilament yarn for air bag and polyester fabric for air bag
JP4749838B2 (en) Entangled yarn and method for producing the same
JP3821604B2 (en) Method for producing inorganic particle-containing polyamide fiber
US12612006B2 (en) Polyamide fibers for airbag and method for producing same
JP2859532B2 (en) Direct spin drawing method of nylon 6 fiber
JP2005307380A (en) Conjugate fiber package and method for winding the same
JP2003020567A (en) Aliphatic polyester fiber
JP2008133566A (en) Method for producing polyamide fiber
JP2004360112A (en) Method for drawing and winding polyhexamethylene adipamide fiber
JP2004270108A (en) Processing agent for synthetic fiber woven and knitted fabric
JPH10131051A (en) Original polyester fiber for seat belt
JPH05148705A (en) Direct spinning and drawing method of modified cross section yarn
JP2016194183A (en) Polyester fiber yarn for air bag

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20230613

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20240820

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20240919

R150 Certificate of patent or registration of utility model

Ref document number: 7560657

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150