JP7565720B2 - Foaming oil-in-water emulsified fat composition - Google Patents
Foaming oil-in-water emulsified fat composition Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims description 171
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 162
- 238000005187 foaming Methods 0.000 title claims description 13
- 239000003921 oil Substances 0.000 claims description 259
- 239000003925 fat Substances 0.000 claims description 112
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- 238000002844 melting Methods 0.000 claims description 88
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- 235000021243 milk fat Nutrition 0.000 claims description 70
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- 235000014113 dietary fatty acids Nutrition 0.000 claims description 49
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- 239000000194 fatty acid Substances 0.000 claims description 49
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- 239000000470 constituent Substances 0.000 claims description 35
- 150000004665 fatty acids Chemical class 0.000 claims description 35
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 27
- -1 C22 saturated fatty acids Chemical class 0.000 claims description 26
- 239000008346 aqueous phase Substances 0.000 claims description 18
- 229910019142 PO4 Inorganic materials 0.000 claims description 16
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- SZYSLWCAWVWFLT-UTGHZIEOSA-N [(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl octadecanoate Chemical compound O([C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@]1(COC(=O)CCCCCCCCCCCCCCCCC)O[C@H](CO)[C@@H](O)[C@@H]1O SZYSLWCAWVWFLT-UTGHZIEOSA-N 0.000 description 9
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- 239000005639 Lauric acid Substances 0.000 description 3
- 229940116224 behenate Drugs 0.000 description 3
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 description 3
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- 235000010692 trans-unsaturated fatty acids Nutrition 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- ZCSHACFHMFHFKK-UHFFFAOYSA-N 2-methyl-1,3,5-trinitrobenzene;2,4,6-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)C1NC([N+]([O-])=O)NC([N+]([O-])=O)N1.CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O ZCSHACFHMFHFKK-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
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- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
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- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
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- 235000008429 bread Nutrition 0.000 description 1
- 235000015155 buttermilk Nutrition 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 229940071162 caseinate Drugs 0.000 description 1
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- 239000011248 coating agent Substances 0.000 description 1
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- 235000020186 condensed milk Nutrition 0.000 description 1
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- 238000009472 formulation Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000019866 hydrogenated palm kernel oil Nutrition 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
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- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
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- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
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- Dairy Products (AREA)
- Grain Derivatives (AREA)
- Edible Oils And Fats (AREA)
Description
本発明は、リン酸塩とエステル交換油脂を実質的に含有しない起泡性水中油型乳化油脂組成物、及び、それをホイップして得られるホイップドクリームに関する。 The present invention relates to a foamable oil-in-water emulsified oil composition that is substantially free of phosphates and transesterified oils and fats, and to a whipped cream obtained by whipping the same.
ホイップドクリームには、口溶けが良好で、かつ適度な硬さを維持することが求められている。また、該ホイップドクリームの原料となる起泡性水中油型乳化油脂組成物には、原液安定性、及びホイップ性が求められている。
また、ホイップドクリームに乳のコクや風味を付与したり、ホイップ性を上げることを目的に、生クリームを混合してホイップドコンパウンドクリームにすることが多々ある。
Whipped cream is required to have good meltability in the mouth and maintain a suitable hardness, and the foamable oil-in-water emulsified oil composition that is the raw material of the whipped cream is required to have stability as a concentrate and whipping properties.
Furthermore, in order to impart a rich milk flavor and taste to the whipped cream or to improve whipping properties, fresh cream is often mixed in to produce a whipped compound cream.
従来、前記起泡性水中油型乳化油脂組成物の原料油脂としては、口溶けの観点からラウリン系油脂が多用されてきたが、ラウリン系油脂を多く含むクリームは起泡後の硬さの維持が難しく、ラウリン系油脂は価格の乱高下も激しい。 Conventionally, lauric fats have been widely used as the raw material fats for the foamable oil-in-water emulsified fat composition in terms of meltability in the mouth, but creams containing a large amount of lauric fats have difficulty maintaining their hardness after foaming, and the price of lauric fats also fluctuates wildly.
近年、ラウリン系油脂の代替として安価で供給が安定しているパーム系油脂が使用されることがある。しかし、油脂中にパーム系油脂を多く配合すると粗大結晶を形成するため、原液安定性、ホイップ性、及びホイップ後の硬さが悪化し、口溶けも悪くなってしまう傾向がある。これらの点を改善するため起泡性クリームにリン酸塩やエステル交換油脂を配合することが行われているが、リン酸塩は苦味を呈する上に健康上好ましくなく、エステル交換油脂は製造コストが高く、コクを低下させたり、口溶けを悪化させる。 In recent years, palm-based fats, which are inexpensive and have a stable supply, have been used as an alternative to lauric fats. However, when palm-based fats are blended in large amounts in fats and oils, coarse crystals are formed, which deteriorates the stability of the original liquid, whipping properties, and hardness after whipping, and also tends to make the cream melt in the mouth. To improve these points, phosphates and interesterified fats have been blended into whipping creams, but phosphates have a bitter taste and are undesirable from a health perspective, and interesterified fats are expensive to produce, reduce the richness of the flavor, and make the cream melt in the mouth worse.
これまで、リン酸塩やトランス脂肪酸を実質的に含有せず、起泡後の保型性及び口溶けが良好なホイップドコンパウンドクリームが開示されている(特許文献1)が、当該ホイップドコンパウンドクリームはパーム系油脂が主体であるため、口溶けは、ラウリン系油脂を主体とするホイップドコンパウンドクリームに及ばず、また、ホイップ後の硬さが十分ではない。 A whipped compound cream that is substantially free of phosphates and trans fatty acids and has good shape retention and melt-in-the-mouth properties after whipping has been disclosed (Patent Document 1). However, because this whipped compound cream is mainly made of palm-based oils and fats, it does not melt in the mouth as well as whipped compound creams that are mainly made of lauric oils and fats, and the hardness after whipping is insufficient.
本発明の目的は、リン酸塩とエステル交換油脂を実質的に含有せず、ラウリン系油脂の一部をパーム系油脂に代替しているにも関わらず、原液安定性とホイップ性が良好な起泡性水中油型乳化油脂組成物、及び、それをホイップして得られ、口溶けが早く、且つ硬さが良好なホイップドクリームを提供することである。 The object of the present invention is to provide a foamable oil-in-water emulsified oil composition that is substantially free of phosphates and transesterified oils and fats, and has good liquid stability and whipping properties despite the fact that part of the lauric oils and fats is replaced with palm-based oils and fats, and to provide a whipped cream obtained by whipping the composition, which melts quickly in the mouth and has good hardness.
本発明者らは上記課題を解決するために鋭意研究を重ねた結果、リン酸塩とエステル交換油脂を実質的に含有せず、特定量の油脂を含み、該油脂中に特定量以下の乳脂肪と、C12以下の飽和脂肪酸を構成脂肪酸として特定量含み、特定の融点である油脂Aと、C16~C22の飽和脂肪酸を構成脂肪酸として特定量含み、且つS2Uを特定量含み特定の融点である油脂Bを特定量含み、さらに水相中に特定範囲のHLBで特定の飽和脂肪酸を構成脂肪酸として含む特定の乳化剤Aを特定量含む起泡性水中油型乳化油脂組成物は、ラウリン系油脂の一部をパーム系油脂に代替しているにも関わらず、原液安定性とホイップ性が良好であり、その起泡性水中油型乳化油脂組成物をホイップして得られるホイップドクリームは、口溶けが早く、且つ硬さが良好であることを見出し、本発明を完成するに至った。 As a result of intensive research conducted by the present inventors to solve the above-mentioned problems, it has been found that a foamable oil-in-water emulsified oil-and-fat composition which is substantially free of phosphates and interesterified oils and fats, contains a specific amount of oil-and-fat, in which the oil-and -fat contains not more than a specific amount of milk fat, a specific amount of C12 or less saturated fatty acids as constituent fatty acids and has a specific melting point, and a specific amount of oil-and-fat B which contains C16 to C22 saturated fatty acids as constituent fatty acids, a specific amount of S2U and has a specific melting point, and further contains in the aqueous phase a specific amount of a specific emulsifier A which contains a specific saturated fatty acid with a specific HLB in a specific range as a constituent fatty acid, has good concentrate stability and whipping properties, despite the lauric oil-and-fat being partly replaced with palm-based oil-and-fat, and whipped cream obtained by whipping the foamable oil-in-water emulsified oil-and-fat composition melts quickly in the mouth and has good hardness, thereby completing the present invention.
即ち、本発明の第一は、起泡性水中油型乳化油脂組成物全体中、油脂含量が25~50重量%、リン酸塩含量が0.02重量%未満であり、
起泡性水中油型乳化油脂組成物の水相中に乳化剤Aを、起泡性水中油型乳化油脂組成物全体中0.01~0.7重量%含有し、
前記油脂全体中、エステル交換油脂含量が1重量%未満、乳脂肪含量が83重量%以下であり、
前記油脂の内、前記乳脂肪を除く油脂全体中、油脂A及び油脂Bの合計含量が80~100重量%であり、油脂B/(油脂A+油脂B)(重量比)が0.37~0.5である、起泡性水中油型乳化油脂組成物に関する。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。
好ましくは、前記乳脂肪が生クリーム由来である。
本発明の第二は、前記起泡性水中油型乳化油脂組成物がホイップされたホイップドクリームに関する。
本発明の第三は、前記ホイップドクリームをサンド、ナッペ、フィリング、又はトッピングした食品に関する。
本発明の第四は、起泡性水中油型乳化油脂組成物全体中、乳脂肪を含まず、油脂含量が25~50重量%、リン酸塩含量が0.02重量%未満であり、前記油脂全体中、エステル交換油脂含量が1重量%未満である水中油型乳化油脂組成物の製造方法であって、
前記起泡性水中油型乳化油脂組成物全体中、乳化剤A含量が0.01~0.7重量%となるように乳化剤Aを水に添加して撹拌しながら溶解した水相部に、前記油脂全体中、油脂Aと油脂Bの合計含量が80~100重量%且つ油脂B/(油脂A+油脂B)(重量比)が0.37~0.5となるように油脂A及び油脂Bを混合した油脂混合物を添加し、予備乳化した後、微細化し、さらに高圧処理することを特徴とする、起泡性水中油型乳化油脂組成物の製造方法に関する。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。
本発明の第五は、起泡性コンパウンドクリーム全体中、油脂含量が25~50重量%、リン酸塩含量が0.02重量%未満であり、前記油脂全体中、エステル交換油脂含量が1重量%未満である起泡性コンパウンドクリームの製造方法であって、
起泡性水中油型乳化油脂組成物全体中、乳化剤A含量が0.01~0.7重量%となるように乳化剤Aを水に添加して撹拌しながら溶解した水相部に、前記起泡性水中油型乳化油脂組成物の油脂全体中、油脂Aと油脂Bの合計含量が80~100重量%且つ油脂B/(油脂A+油脂B)(重量比)が0.37~0.5となるように油脂A及び油脂Bを混合した油脂混合物を添加し、予備乳化した後、微細化し、さらに高圧処理して得た起泡性水中油型乳化油脂組成物に、前記起泡性コンパウンドクリームの油脂全体中の乳脂肪含量が83重量%以下になるように生クリームを混合・撹拌することを特徴とする、起泡性コンパウンドクリームの製造方法に関する。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。
That is, the first aspect of the present invention is a foamable oil-in-water emulsified oil composition, the oil content is 25 to 50% by weight, and the phosphate content is less than 0.02% by weight,
The aqueous phase of the foamable oil-in-water emulsified oil composition contains emulsifier A in an amount of 0.01 to 0.7% by weight based on the entire foamable oil-in-water emulsified oil composition;
In the total oil and fat, the interesterified oil and fat content is less than 1% by weight, and the milk fat content is 83% by weight or less,
The present invention relates to a foamable oil-in-water emulsified oil composition, in which the total content of oil A and oil B in all of the oils and fats excluding the milk fat is 80 to 100% by weight, and the weight ratio of oil B/(oil A + oil B) is 0.37 to 0.5.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
Preferably, the milk fat is derived from cream.
A second aspect of the present invention relates to a whipped cream obtained by whipping the foamable oil-in-water emulsified oil composition.
A third aspect of the present invention relates to a food product in which the whipped cream is used as a sandwich, a nappe, a filling, or a topping.
The fourth aspect of the present invention is a method for producing a foamable oil-in-water emulsified oil composition, the foamable oil-in-water emulsified oil composition as a whole does not contain milk fat, has an oil content of 25 to 50% by weight, has a phosphate content of less than 0.02% by weight, and has an interesterified oil content of less than 1% by weight in the whole oil,
The present invention relates to a method for producing a foamable oil-in-water emulsified oil composition, comprising adding emulsifier A to water so that the content of emulsifier A in the entire foamable oil-in-water emulsified oil composition is 0.01 to 0.7% by weight, dissolving the emulsifier in the aqueous phase while stirring, adding an oil mixture obtained by mixing oils A and B so that the total content of oils A and B in the entire oil is 80 to 100% by weight and the weight ratio of oil B/(oil A + oil B) is 0.37 to 0.5, pre-emulsifying the oil mixture, followed by pulverizing the oil mixture and further treating under high pressure.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
A fifth aspect of the present invention is a method for producing a foaming compound cream, the foaming compound cream having a total fat content of 25 to 50% by weight, a phosphate content of less than 0.02% by weight, and an interesterified fat content of less than 1% by weight of the total fat content,
The present invention relates to a method for producing a foamable compound cream, which comprises adding emulsifier A to water so that the content of emulsifier A in the entire foamable oil-in-water emulsified oil composition is 0.01 to 0.7% by weight, stirring to dissolve emulsifier A in an aqueous phase, adding an oil mixture of oils A and B so that the total content of oils A and B in the entire oils and fats of the foamable oil-in-water emulsified oil composition is 80 to 100% by weight and the weight ratio of oils B/(oils A + oils B) is 0.37 to 0.5, pre-emulsifying the resulting mixture, pulverizing the mixture, and further treating it under high pressure to obtain a foamable oil-in-water emulsified oil composition, and mixing and stirring fresh cream with the resulting foamable oil-in-water emulsified oil composition so that the milk fat content in the entire oils and fats of the foamable compound cream is 83% by weight or less.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
本発明に従えば、リン酸塩とエステル交換油脂を実質的に含有せず、ラウリン系油脂の一部をパーム系油脂に代替しているにも関わらず、原液安定性とホイップ性が良好な起泡性水中油型乳化油脂組成物、及び、それをホイップして得られ、口溶けが早く、且つ硬さが良好なホイップドクリームを提供することができる。 According to the present invention, it is possible to provide a foamable oil-in-water emulsified oil composition that is substantially free of phosphates and transesterified oils and fats, and has good stock solution stability and whipping properties, even though a portion of the lauric oils and fats is replaced with palm-based oils and fats, and a whipped cream obtained by whipping the same, which melts quickly in the mouth and has good hardness, can be provided.
以下、本発明につき、さらに詳細に説明する。本発明の起泡性水中油型乳化油脂組成物は、リン酸塩とエステル交換油脂を実質的に含有せず、特定量の油脂を含み、水相中に特定の乳化剤Aを特定量含み、2種類の特定の油脂(油脂Aと油脂B)を特定量含むことを特徴とする。該起泡性水中油型乳化油脂組成物は、乳脂肪を含まなくてもよいし、特定量以下含んでもよい。乳脂肪を含む場合、該起泡性水中油型乳化油脂組成物を起泡性コンパウンドクリームということもできる。そして、前記起泡性水中油型乳化油脂組成物をホイップすることで、本発明のホイップドクリームを得ることができる。乳脂肪を含む場合、該ホイップドクリームをホイップドコンパウンドクリームということもできる。 The present invention will be described in more detail below. The foamable oil-in-water emulsified oil composition of the present invention is characterized in that it is substantially free of phosphates and transesterified oils and fats, contains a specific amount of oils and fats, contains a specific amount of a specific emulsifier A in the aqueous phase, and contains specific amounts of two specific oils and fats (oil A and oil B). The foamable oil-in-water emulsified oil composition may not contain milk fat, or may contain less than a specific amount of milk fat. When milk fat is contained, the foamable oil-in-water emulsified oil composition can also be called a foamable compound cream. The whipped cream of the present invention can be obtained by whipping the foamable oil-in-water emulsified oil composition. When milk fat is contained, the whipped cream can also be called a whipped compound cream.
前記起泡性水中油型乳化油脂組成物に含まれるリン酸塩は、少なければ少ないほど良く、起泡性水中油型乳化油脂組成物全体中0.02重量%未満が好ましく、0.01重量%未満がより好ましく、全く含まないことがさらに好ましい。前記リン酸塩としては、リン酸ナトリウム、メタリン酸ナトリウム等が例示でき、それらの群より選ばれる少なくとも1種を用いることができる。 The less phosphate contained in the foamable oil-in-water emulsified oil composition, the better, and the amount is preferably less than 0.02% by weight, more preferably less than 0.01% by weight, and even more preferably none at all. Examples of the phosphate include sodium phosphate and sodium metaphosphate, and at least one selected from this group can be used.
前記起泡性水中油型乳化油脂組成物は、油脂を起泡性水中油型乳化油脂組成物全体中25~50重量%含有することが好ましい。より好ましくは30~45重量%であり、さらに好ましくは35~40重量%である。25重量%より少ないと、ホイップ性とホイップ後の硬さが悪い場合があり、50重量%より多いと、原液安定性が悪い場合がある。なお前記油脂には、少なくとも油脂A及び油脂Bが含まれており、更に乳脂肪が含まれていても良い。 The foamable oil-in-water emulsified oil composition preferably contains 25 to 50% by weight of oil based on the entire foamable oil-in-water emulsified oil composition. More preferably, it is 30 to 45% by weight, and even more preferably, it is 35 to 40% by weight. If it is less than 25% by weight, the whipping property and hardness after whipping may be poor, and if it is more than 50% by weight, the stability of the original solution may be poor. The oil contains at least oil A and oil B, and may further contain milk fat.
前記起泡性水中油型乳化油脂組成物に含まれるエステル交換油脂の含有量は少なければ少ないほど良く、前記起泡性水中油型乳化油脂組成物に含まれる油脂全体中1重量%未満が好ましく、0.5重量%未満がより好ましく、全く含まないことがさらに好ましい。エステル交換油脂の含有量が1重量%以上であると、コストがアップしたり、口溶けが遅くなる場合がある。 The less the content of transesterified oils and fats contained in the foamable oil-in-water emulsified oil composition, the better. The content is preferably less than 1% by weight, more preferably less than 0.5% by weight, and even more preferably none at all, of the total oils and fats contained in the foamable oil-in-water emulsified oil composition. If the content of transesterified oils and fats is 1% by weight or more, the cost may increase and the melting in the mouth may be delayed.
本発明においてエステル交換油脂とは、食用油脂をエステル交換反応して得られる油脂を指す。前記食用油脂としては菜種油、コーン油、綿実油、パーム油、パーム核油、ヤシ油、大豆油、ひまわり油、サフラワー油、オリーブ油等の植物性油脂や、牛脂、豚脂、魚油等の動物性油脂が例示でき、これらを硬化、分別、エステル交換等の加工処理を行ったものも用いることができる。前記エステル交換油脂の製法については特に限定なく、常法を用いて製造することができる。例えば、ナトリウムメチラートまたはナトリウムエチラートを原料油脂に対して0.01~1.0重量%添加してランダムエステル交換反応を起こす化学法や、リパーゼなどの酵素を用いてエステル交換を行なう酵素法などを適用できる。 In the present invention, the term "transesterified oils and fats" refers to oils and fats obtained by transesterifying edible oils and fats. Examples of the edible oils and fats include vegetable oils and fats such as rapeseed oil, corn oil, cottonseed oil, palm oil, palm kernel oil, coconut oil, soybean oil, sunflower oil, safflower oil, and olive oil, and animal oils and fats such as beef tallow, lard, and fish oil. These oils and fats may also be processed by hardening, fractionation, transesterification, and the like. There are no particular limitations on the method for producing the transesterified oils and fats, and they can be produced using conventional methods. For example, a chemical method in which 0.01 to 1.0% by weight of sodium methylate or sodium ethylate is added to the raw oil and fat to cause a random transesterification reaction, or an enzymatic method in which transesterification is performed using an enzyme such as lipase, can be used.
前記起泡性水中油型乳化油脂組成物は乳脂肪を含まなくてもよいし、含んでもよいが、前記乳脂肪の含有量は、前記起泡性水中油型乳化油脂組成物に含まれる油脂全体中83重量%以下が好ましい。83重量%を超えると、ホイップ性が悪化したり、口溶けが遅くなる場合がある。前記乳脂肪の由来としては、生クリーム、バターミルクパウダー、バター、バターオイル、クリームチーズ、生乳、牛乳、全粉乳、濃縮乳、サワークリーム、無糖練乳、加糖練乳等が例示でき、それらの群より選ばれる少なくとも1種を原料として用いることができる。風味やホイップ後の硬さの観点では、乳脂肪の由来として生クリームを用いることが好ましい。 The foamable oil-in-water emulsified oil composition may or may not contain milk fat, but the content of the milk fat is preferably 83% by weight or less of the total fats and oils contained in the foamable oil-in-water emulsified oil composition. If the content exceeds 83% by weight, the whipping properties may deteriorate and the melting in the mouth may be delayed. Examples of the origin of the milk fat include fresh cream, buttermilk powder, butter, butter oil, cream cheese, raw milk, cow's milk, whole milk powder, concentrated milk, sour cream, unsweetened condensed milk, sweetened condensed milk, etc., and at least one selected from these groups can be used as a raw material. From the viewpoint of flavor and hardness after whipping, it is preferable to use fresh cream as the origin of the milk fat.
前記生クリームは、乳等省令で定義される「生乳、牛乳または特別牛乳から乳脂肪分以外の成分を除去し、乳脂肪分が18.0%以上にしたもの」をいい、本発明においては、乳脂肪分が30~48%のものを使用することが、良好なホイップ性を得る観点から好ましい。 The fresh cream is defined in the Milk and Dairy Products Ordinance as "a product made by removing components other than milk fat from raw milk, cow's milk or special milk, resulting in a milk fat content of 18.0% or more." In the present invention, it is preferable to use cream with a milk fat content of 30 to 48% in order to obtain good whipping properties.
前記油脂Aは、C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含むことが好ましい。40重量%未満だと、口溶けが遅い場合がある。前記油脂Aの構成脂肪酸に含まれるC12以下の飽和脂肪酸の含量は構成脂肪酸全体中100重量%以下であればよい。 The fat A preferably contains 40% by weight or more of saturated fatty acids of C12 or less based on the total constituent fatty acids. If the content is less than 40% by weight, melting in the mouth may be slow. The content of saturated fatty acids of C12 or less included in the constituent fatty acids of the fat A may be 100% by weight or less based on the total constituent fatty acids.
前記油脂Aは、S2Uを油脂A全体中0重量%以上40重量%未満含むことが好ましく、0~20重量%がより好ましく、0~10重量%がさらに好ましい。40重量%以上であると、本発明の効果を奏しない場合がある。ここで、S2Uとは、1分子のグリセリンに、構成脂肪酸として、C16以上(好ましくはC24以下)の飽和脂肪酸Sが2分子、C16以上(好ましくはC24以下)の不飽和脂肪酸Uが1分子結合しているトリグリセリドのことをいい、S及びUの結合位置は限定されない。 The fat/oil A preferably contains S2U in an amount of 0% by weight or more and less than 40% by weight, more preferably 0 to 20% by weight, and even more preferably 0 to 10% by weight, based on the total weight of the fat/oil A. If the amount is 40% by weight or more, the effects of the present invention may not be achieved. Here, S2U refers to a triglyceride in which, as constituent fatty acids, two molecules of saturated fatty acid S having a C 16 or more (preferably C 24 or less) and one molecule of unsaturated fatty acid U having a C 16 or more (preferably C 24 or less) are bound to one molecule of glycerin, and the binding positions of S and U are not limited.
また、前記油脂Aの上昇融点は、23~30℃であることが好ましく、24~29℃がより好ましく、25~29℃がさらに好ましく、26~28℃が特に好ましい。23℃より低いと、ホイップ後の硬さを維持できない場合があり、30℃より高いと、原液安定性及びホイップ後の硬さが悪くなる場合がある。 The slip melting point of the oil A is preferably 23 to 30°C, more preferably 24 to 29°C, even more preferably 25 to 29°C, and particularly preferably 26 to 28°C. If it is lower than 23°C, the hardness after whipping may not be maintained, and if it is higher than 30°C, the stability of the concentrate and the hardness after whipping may be deteriorated.
前記油脂Aの種類としては、ラウリン系油脂が挙げられ、具体的にはヤシ油(上昇融点:24±1℃)やパーム核油(上昇融点:27±1℃)、パーム核オレイン(上昇融点:23±1℃)が例示でき、それらの群より選ばれる少なくとも1種を用いることができる。また、油脂Aが複数種の油脂をブレンドした混合油脂である場合は、当該混合油脂全体に含まれるC12以下の飽和脂肪酸含量及びS2U含量が前記含量の範囲に入り、且つ当該複数種の油脂の上昇融点の平均値が前記上昇融点の範囲に入っていれば良い。 The type of the fat A includes lauric fats, specifically, coconut oil (elevation melting point: 24±1° C.), palm kernel oil (elevation melting point: 27±1° C.), and palm kernel olein (elevation melting point: 23±1° C.), and at least one selected from these groups can be used. When the fat A is a mixed fat obtained by blending a plurality of types of fats and oils, it is sufficient that the saturated fatty acid content of C12 or less and the S2U content contained in the entire mixed fat and oil are within the above-mentioned ranges, and the average value of the elevating melting points of the plurality of types of fats and oils is within the above-mentioned ranges.
前記油脂Bは、C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含むことが好ましい。40重量%未満だと、口溶けが遅い場合がある。前記油脂Bの構成脂肪酸に含まれるC16~C22の飽和脂肪酸の含量は構成脂肪酸全体中100重量%以下であればよい。 The fat B preferably contains 40% by weight or more of C16 - C22 saturated fatty acids based on the total constituent fatty acids. If the content is less than 40% by weight, melting in the mouth may be slow. The content of C16 - C22 saturated fatty acids contained in the constituent fatty acids of the fat B may be 100% by weight or less based on the total constituent fatty acids.
前記油脂Bは、S2Uを油脂B全体中45~70重量%含むことが好ましく、50~60重量%がより好ましい。45重量%より少ないとホイップ性とホイップ後の硬さが悪くなる場合があり、70重量%より多いと、口溶けが遅くなる場合がある。ここで、S2Uとは、1分子のグリセリンに、構成脂肪酸として、C16以上(好ましくはC24以下)の飽和脂肪酸Sが2分子、C16以上(好ましくはC24以下)の不飽和脂肪酸Uが1分子結合しているトリグリセリドのことをいい、S及びUの結合位置は限定されない。 The fat B preferably contains 45 to 70% by weight, more preferably 50 to 60% by weight, of S2U based on the total amount of fat B. If the amount is less than 45% by weight, the whipping property and hardness after whipping may deteriorate, and if the amount is more than 70% by weight, the melting in the mouth may be delayed. Here, S2U refers to a triglyceride in which, as constituent fatty acids, two molecules of saturated fatty acid S having a C 16 or more (preferably C 24 or less) and one molecule of unsaturated fatty acid U having a C 16 or more (preferably C 24 or less) are bound to one molecule of glycerin, and the binding positions of S and U are not limited.
また、油脂Bの上昇融点は、23~30℃であることが好ましく、24~29℃がより好ましく、25~29℃がさらに好ましく、26~28℃が特に好ましい。23℃より低いと、ホイップ後の硬さを維持できない場合があり、30℃より高いと、原液安定性、ホイップ性、及びホイップ後の硬さが悪くなったり、口溶けが遅くなる場合がある。 The melting point of the fat or oil B is preferably 23 to 30°C, more preferably 24 to 29°C, even more preferably 25 to 29°C, and particularly preferably 26 to 28°C. If it is lower than 23°C, the hardness after whipping may not be maintained, and if it is higher than 30°C, the stability of the concentrate, whipping properties, and hardness after whipping may deteriorate, or melting in the mouth may be delayed.
前記油脂Bの種類としては、パーム系油脂が挙げられ、具体的にはパーム油(上昇融点:33±1℃)、パーム油中融点部(上昇融点:27±1℃)、パームオレイン(上昇融点:22±1℃)等が例示でき、それらの群より選ばれる少なくとも1種を用いることができる。また、油脂Bが複数種の油脂をブレンドした混合油脂である場合は、当該混合油脂全体に含まれるC16~C22の飽和脂肪酸含量及びS2U含量が前記含量の範囲に入り、且つ当該複数種の油脂の上昇融点の平均値が前記上昇融点の範囲に入っていれば良い。 Examples of the type of fat B include palm-based fats and oils, and specific examples include palm oil (slope melting point: 33±1° C.), palm mid-melting point (slope melting point: 27±1° C.), palm olein (slope melting point: 22±1° C.), etc., and at least one selected from these groups can be used. When fat B is a mixed fat obtained by blending multiple types of fats and oils, it is sufficient that the C 16 to C 22 saturated fatty acid content and S2U content contained in the entire mixed fat and oil are within the above-mentioned ranges, and the average value of the slip melting points of the multiple types of fats and oils is within the above-mentioned range.
なお、前記油脂A及び油脂Bの上昇融点の測定は、日本油化学会 基準油脂分析試験法に従い、自動上昇融点測定器を用いて実施すればよい。 The slip melting points of the fats and oils A and B may be measured using an automatic slip melting point measuring device in accordance with the standard method for analysis of fats and oils set forth by the Japan Oil Chemists' Society.
前記起泡性水中油型乳化油脂組成物に含まれる油脂の内、前記乳脂肪を除く油脂全体中、前記油脂A及び前記油脂Bの合計含有量は80~100重量%が好ましく、83~100重量%がより好ましく、88~100重量%がさらに好ましく、95~100重量%が特に好ましい。合計含有量が80重量%より少ないと、口溶けが遅い場合がある。 Of the fats and oils contained in the foamable oil-in-water emulsified fat composition, the total content of fats and oils A and B in the total fats and oils excluding the milk fat is preferably 80 to 100% by weight, more preferably 83 to 100% by weight, even more preferably 88 to 100% by weight, and particularly preferably 95 to 100% by weight. If the total content is less than 80% by weight, the melting in the mouth may be slow.
前記油脂B/(前記油脂A+前記油脂B)(重量比)は、0.37~0.5であることが好ましく、0.38~0.5がより好ましく、0.43~0.5がさらに好ましく、0.45~0.5が特に好ましい。前記比が0.37より小さいと、ホイップ後の硬さが悪くなったり、口溶けが遅くなる場合があり、0.5より大きいと、原液安定性、ホイップ性、ホイップ後の硬さが悪化したり、口溶けが遅くなる場合がある。 The weight ratio of the oil/fat B/(the oil/fat A+the oil/fat B) is preferably 0.37 to 0.5, more preferably 0.38 to 0.5, even more preferably 0.43 to 0.5, and particularly preferably 0.45 to 0.5. If the ratio is less than 0.37, the hardness after whipping may be poor and melting in the mouth may be delayed, while if it is more than 0.5, the stability of the concentrate, whipping properties, and hardness after whipping may be poor and melting in the mouth may be delayed.
本発明の起泡性水中油型乳化油脂組成物の油脂としては、前記乳脂肪、油脂A、油脂B以外にも、それらの含有量が満たされており、本発明の効果を損なわなければ、必要に応じて更に別の油脂を含んでも良い。別の油脂としては、例えば、菜種油、コーン油、綿実油、大豆油、ひまわり油、サフラワー油、オリーブ油、米油、牛脂、豚脂、魚油等が挙げられる。 In addition to the milk fat, oil A, and oil B, the oil in the foamable oil-in-water emulsified oil composition of the present invention may contain other oils and fats as necessary, provided that the content of these oils and fats is sufficient and does not impair the effects of the present invention. Examples of other oils and fats include rapeseed oil, corn oil, cottonseed oil, soybean oil, sunflower oil, safflower oil, olive oil, rice oil, beef tallow, lard, and fish oil.
前記起泡性水中油型乳化油脂組成物には、水分を起泡性水中油型乳化油脂組成物全体中40~70重量%含有することが好ましく、45~70重量%であることがより好ましく、50~70重量%がさらに好ましく、55~70重量%が特に好ましい。40重量%より少ないと、ホイップ後のみずみずしさに欠けたり、原液安定性が悪い場合があり、70重量%より多いと、ホイップ性とホイップ後の硬さが悪かったり油のコクを感じ難くなる場合がある。 The foamable oil-in-water emulsified oil composition preferably contains 40 to 70% by weight of water based on the entire foamable oil-in-water emulsified oil composition, more preferably 45 to 70% by weight, even more preferably 50 to 70% by weight, and particularly preferably 55 to 70% by weight. If the water content is less than 40% by weight, the freshness after whipping may be lacking and the stability of the concentrate may be poor, and if the water content is more than 70% by weight, the whipping properties and hardness after whipping may be poor and it may be difficult to feel the richness of the oil.
前記油脂含量と前記水分含量との重量比(油脂/水分)は0.4~1.2であることが好ましく、0.5~1.0であることがより好ましい。0.4未満であると起泡性が悪化する場合があり、1.2より大きいと原液安定性が悪化したり、水中油型乳化とならない場合がある。 The weight ratio of the oil content to the water content (oil/water) is preferably 0.4 to 1.2, and more preferably 0.5 to 1.0. If it is less than 0.4, the foaming properties may deteriorate, and if it is more than 1.2, the stability of the concentrate may deteriorate or oil-in-water emulsion may not be obtained.
前記乳化剤Aは、HLBが2.8~6.2であることが好ましく、3.5~5.5がより好ましい。HLBが2.8より低いと、ホイップ性やホイップ後の硬さが悪化する場合があり、6.2より高いと、ホイップ性やホイップ後の硬さが悪化する場合がある。 The emulsifier A preferably has an HLB of 2.8 to 6.2, more preferably 3.5 to 5.5. If the HLB is lower than 2.8, the whipping properties and hardness after whipping may deteriorate, and if it is higher than 6.2, the whipping properties and hardness after whipping may deteriorate.
前記乳化剤Aは、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステルであることが好ましい。C10~C22の飽和脂肪酸の合計量が70重量%より少ないと、口溶けが遅くなったり、乳化剤特有の異味が発現する場合がある。 The emulsifier A is preferably a sucrose fatty acid ester and/or a polyglycerin fatty acid ester containing 70 to 100% by weight of C10 to C22 saturated fatty acids based on the total amount of constituent fatty acids. If the total amount of C10 to C22 saturated fatty acids is less than 70% by weight, the emulsifier may dissolve slowly in the mouth or may have an unpleasant taste specific to the emulsifier.
前記乳化剤Aは、起泡性水中油型乳化油脂組成物の水相中に含まれる。乳化剤Aが水相に含まれず油相に含まれると、ホイップ性やホイップ後の硬さが悪化する場合がある。水相中の前記乳化剤Aの含有量は、起泡性水中油型乳化油脂組成物全体中0.01~0.7重量%であることが好ましく、0.01~0.4重量%であることがより好ましく、0.01~0.3重量%であることがさらに好ましく、0.02~0.2重量%であることが特に好ましい。0.01重量%より少ないと、ホイップ性やホイップ後の硬さが悪化する場合があり、0.7重量%より多いと、原液安定性が悪化する場合がある。 The emulsifier A is contained in the aqueous phase of the foamable oil-in-water emulsified oil composition. If emulsifier A is contained in the oil phase but not in the aqueous phase, the whipping properties and hardness after whipping may deteriorate. The content of emulsifier A in the aqueous phase is preferably 0.01 to 0.7% by weight, more preferably 0.01 to 0.4% by weight, even more preferably 0.01 to 0.3% by weight, and particularly preferably 0.02 to 0.2% by weight, of the entire foamable oil-in-water emulsified oil composition. If it is less than 0.01% by weight, the whipping properties and hardness after whipping may deteriorate, and if it is more than 0.7% by weight, the stability of the original solution may deteriorate.
なお、乳化剤A以外にも、必要に応じて、HLBが6.0未満の乳化剤を油相に配合してもよいし、HLBが6.0以上の乳化剤を水相に配合してもよい。 In addition to emulsifier A, if necessary, an emulsifier with an HLB of less than 6.0 may be added to the oil phase, and an emulsifier with an HLB of 6.0 or more may be added to the aqueous phase.
しかし、不飽和脂肪酸の結合した乳化剤は異味を発現する場合があるため、風味を良くする観点から、不飽和脂肪酸の結合した乳化剤の含有量は少ないほど良く、起泡性水中油型乳化油脂組成物全体中0.02重量%未満であることが好ましい。 However, since emulsifiers with bound unsaturated fatty acids may produce an unpleasant taste, from the viewpoint of improving the flavor, the lower the content of emulsifiers with bound unsaturated fatty acids, the better, and it is preferable that the content be less than 0.02% by weight of the entire foamable oil-in-water emulsified oil composition.
本発明の起泡性水中油型乳化油脂組成物は、本発明の効果を損なわない範囲で、必要に応じて、増粘剤、糖類、乳固形分、呈味剤、着色料、香料、塩分、ビタミン類、ミネラル類、酸化防止剤、その他の食品成分、添加剤等を含有してもよい。 The foamable oil-in-water emulsified oil composition of the present invention may contain thickeners, sugars, milk solids, flavorings, colorants, fragrances, salt, vitamins, minerals, antioxidants, other food ingredients, additives, etc., as necessary, within the scope of not impairing the effects of the present invention.
前記起泡性水中油型乳化油脂組成物をホイップすることで、ホイップドクリームが得られる。得られるホイップドクリームは、様々な食品にトッピングしたり、ナッペしたり、フィリングしたり、サンドしたりして利用できる。前記食品としては、クリームパン、クリームサンド、サンドイッチ等のパン、ケーキ、シュー、オムレット、どら焼き等の菓子が挙げられる。 Whipped cream is obtained by whipping the foamable oil-in-water emulsified oil composition. The whipped cream obtained can be used as a topping, a coating, a filling, or a sandwich for various foods. Examples of such foods include breads such as cream buns, cream sandwiches, and sandwiches, as well as cakes, choux pastries, omelets, and dorayaki.
本発明の起泡性水中油型乳化油脂組成物の製造方法を以下に例示する。即ち、まず起泡性水中油型乳化油脂組成物全体中、乳化剤A含量が0.01~0.7重量%となるように乳化剤Aを水に添加して撹拌しながら60℃以上に加熱して溶解し、起泡性水中油型乳化油脂組成物全体中のリン酸塩含量を0.02重量%未満且つ水分含量を40~70重量%になるように調整した水相部を作製する。 The method for producing the foamable oil-in-water emulsified oil composition of the present invention is exemplified below. That is, first, emulsifier A is added to water so that the emulsifier A content in the entire foamable oil-in-water emulsified oil composition is 0.01 to 0.7% by weight, and the mixture is heated to 60°C or higher while stirring to dissolve, and an aqueous phase is prepared in which the phosphate content in the entire foamable oil-in-water emulsified oil composition is adjusted to less than 0.02% by weight and the water content is adjusted to 40 to 70% by weight.
次いで、起泡性水中油型乳化油脂組成物の油脂全体中における油脂Aと油脂Bの合計含有量が80~100重量%且つ油脂B/(油脂A+油脂B)(重量比)が0.37~0.5となるように油脂A及び油脂Bを混合し、必要に応じて他の油脂も混合して、起泡性水中油型乳化油脂組成物全体中の油脂含量を25~50重量%且つ前記油脂全体中のエステル交換油脂含量を1重量%未満になるように調整した油脂混合物を前記水相部に添加し、予備乳化した後、微細化し、さらに高圧処理することにより、乳脂肪を含有しない実施形態に係る水中油型乳化油脂組成物を作製することができる。 Next, fats A and B are mixed so that the total content of fats A and B in the entire fat of the foamable oil-in-water emulsified oil composition is 80 to 100% by weight and the weight ratio of fats B/(fat A + fat B) is 0.37 to 0.5, and other fats are also mixed as necessary to adjust the fat content in the entire fat of the foamable oil-in-water emulsified oil composition to 25 to 50% by weight and the transesterified fat content in the entire fat is less than 1% by weight. The oil mixture is added to the aqueous phase, pre-emulsified, pulverized, and further treated under high pressure to produce an oil-in-water emulsified oil composition according to an embodiment that does not contain milk fat.
次いで、前記水中油型乳化油脂組成物に、前記水中油型乳化油脂組成物の油脂全体中の乳脂肪含量が83重量%以下になるように生クリーム等の乳脂肪含有成分を混合・撹拌することで、乳脂肪を含有する実施形態に係る起泡性水中油型乳化油脂組成物(起泡性コンパウンドクリームともいう)を得ることができる。 Next, a milk fat-containing component such as fresh cream is mixed and stirred into the oil-in-water emulsified oil composition so that the milk fat content in the total oil and fat of the oil-in-water emulsified oil composition is 83% by weight or less, thereby obtaining a foamable oil-in-water emulsified oil composition (also called a foamable compound cream) according to an embodiment that contains milk fat.
なお、前記生クリーム等の乳脂肪含有成分は、前記水相部の原料として他原料と混合し、そこへ前記油脂混合物を添加し、予備乳化した後、微細化し、さらに高圧処理することで、乳脂肪を含有する実施形態に係る起泡性水中油型乳化油脂組成物を得ることもできる。 The milk fat-containing component such as the fresh cream can be mixed with other ingredients as the raw material for the aqueous phase, to which the oil mixture is added, pre-emulsified, then pulverized and further treated under high pressure to obtain a foamable oil-in-water emulsified oil composition according to the embodiment containing milk fat.
以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 The present invention will be described in more detail below with reference to examples, but the present invention is in no way limited to these examples. Note that in the examples, "parts" and "%" are by weight.
<製造例、実施例及び比較例で使用した原料>
1)(株)カネカ製「パーム核油」(C12以下の飽和脂肪酸:51.2重量%、上昇融点:27.4℃、ラウリン酸:44.9重量%、S2U:3.6重量%)
2)(株)カネカ製「パーム核硬化油」(C12以下の飽和脂肪酸:53.0重量%、上昇融点:40.3℃、ラウリン酸:46.4重量%、S2U:1.3重量%)
3)(株)カネカ製「パーム油中融点部」(C16~C22の飽和脂肪酸:53.7重量%、上昇融点:26.8℃、トランス脂肪酸:0.1重量%、総飽和脂肪酸:55.6重量%、S2U:65.8重量%)
4)(株)カネカ製「パームオレイン」(C16~C22の飽和脂肪酸:44.7重量%、上昇融点:21.9℃、トランス脂肪酸:0.2重量%、総飽和脂肪酸:45.9重量%、S2U:44.0重量%)
5)(株)カネカ製「パームエステル交換油」(パーム核とパーム油のエステル交換油、C16~C22の飽和脂肪酸:31.0重量%、上昇融点:27.5℃、S2U含:0重量%)
6)(株)カネカ製「ナタネ油」(C12以下の飽和脂肪酸:0重量%、C16~C22の飽和脂肪酸:6.5重量%、S2U:0重量%、融点は測定不可)
7)ADM(株)製「Yelkin TS」(不飽和脂肪酸:78.9重量%)
8)阪本薬品工業(株)製ポリグリセリン混酸エステル「SYグリスター CV-23」(不飽和脂肪酸:0.1重量%)
9)阪本薬品工業(株)製ポリグリセリンベヘン酸エステル「SYグリスターDDB-750」(HLB:2.5、不飽和脂肪酸:0.1重量%)
10)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスター MS-3S」(HLB:8.4、不飽和脂肪酸:0.1重量%)
11)よつ葉乳業(株)製「ヨツバ脱脂粉乳」(乳脂肪分:0.7重量%)
12)Friesland Campina DMV社製「カゼインカリウムSPRAY」
13)HILMAR社製「ラクトース HILMAR FINE GRAIND」
14)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスター TS-3S」(HLB:4.6、C10~C22の飽和脂肪酸:99.4重量%)
15)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスターMS-5S」(HLB:11.6、C10~C22の飽和脂肪酸:99.8重量%)
16)(株)明治製「明治フレッシュクリーム43」(乳脂肪分:43重量%、水分:52.33重量%)
17)三菱ケミカルフーズ(株)製ショ糖ステアリン酸エステル「S-370」(HLB:3.0、C10~C22の飽和脂肪酸:100.0重量%)
18)阪本薬品工業(株)製「SYグリスター PS-5S」(HLB:4.5、C10~C22の飽和脂肪酸:99.6重量%)
19)三菱ケミカルフーズ(株)製ショ糖ステアリン酸エステル「S-570」(HLB:5.0、C10~C22の飽和脂肪酸:100.0重量%)
20)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスター PS-3S」(HLB:2.6、C10~C22の飽和脂肪酸:99.8重量%)
21)太陽化学(株)製ポリグリセリンステアリン酸エステル「サンソフトQ18-B」(HLB:6.5、C10~C22の飽和脂肪酸:99.7重量%)
22)三菱ケミカルフーズ(株)製ショ糖ステアリン酸エステル「S-770」(HLB:7.0、C10~C22の飽和脂肪酸:100.0重量%)
23)阪本薬品工業(株)製ポリグリセリンオレイン酸エステル「SYグリスター MO-5S」(HLB:11.6、C10~C22の飽和脂肪酸:29.81重量%、不飽和脂肪酸:70重量%)
24)(株)カネカ製「パーム核オレイン」(C12以下の飽和脂肪酸:47.5重量%、上昇融点:23.0℃、ラウリン酸:40.5重量%、S2U:2.6重量%)
25)(株)カネカ製「パーム油中融点部」(C16~C22の飽和脂肪酸:64.2重量%、S2U:91.8重量%、上昇融点:31.3℃)
<Raw materials used in the Production Examples, Examples and Comparative Examples>
1) "Palm kernel oil" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 51.2% by weight, melting point: 27.4°C, lauric acid: 44.9% by weight, S2U: 3.6% by weight)
2) "Hydrogenated Palm Kernel Oil" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 53.0% by weight, melting point: 40.3°C, lauric acid: 46.4% by weight, S2U: 1.3% by weight)
3) "Palm oil mid-melting point fraction" manufactured by Kaneka Corporation ( C16 - C22 saturated fatty acids: 53.7% by weight, slip melting point: 26.8°C, trans fatty acids: 0.1% by weight, total saturated fatty acids: 55.6% by weight, S2U: 65.8% by weight)
4) "Palm Olein" manufactured by Kaneka Corporation ( C16 to C22 saturated fatty acids: 44.7% by weight, slip melting point: 21.9°C, trans fatty acids: 0.2% by weight, total saturated fatty acids: 45.9% by weight, S2U: 44.0% by weight)
5) "Palm interesterified oil" manufactured by Kaneka Corporation (interesterified oil of palm kernel and palm oil, C16 - C22 saturated fatty acids: 31.0% by weight, slip melting point: 27.5°C, S2U content: 0% by weight)
6) "Rapeseed oil" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 0% by weight, C16 to C22 saturated fatty acids: 6.5% by weight, S2U: 0% by weight, melting point not measurable)
7) “Yelkin TS” manufactured by ADM Co., Ltd. (unsaturated fatty acid: 78.9% by weight)
8) Polyglycerol mixed acid ester "SY Glyster CV-23" (unsaturated fatty acid: 0.1% by weight) manufactured by Sakamoto Pharmaceutical Co., Ltd.
9) Polyglycerol behenate "SY Glystar DDB-750" (HLB: 2.5, unsaturated fatty acid: 0.1% by weight) manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
10) Polyglycerol stearate "SY Glyster MS-3S" (HLB: 8.4, unsaturated fatty acid: 0.1% by weight) manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
11) Yotsuba skim milk powder (milk fat content: 0.7% by weight) manufactured by Yotsuba Milk Industry Co., Ltd.
12) "Casein Potassium SPRAY" manufactured by Friesland Campina DMV
13) "Lactose HILMAR FINE GRAIN" manufactured by HILMAR
14) Polyglycerol stearate "SY Glyster TS-3S" (HLB: 4.6, C10 - C22 saturated fatty acids: 99.4% by weight) manufactured by Sakamoto Pharmaceutical Co., Ltd.
15) Polyglycerol stearate "SY Glystar MS-5S" (HLB: 11.6, C10 - C22 saturated fatty acids: 99.8% by weight) manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
16) Meiji Fresh Cream 43 (Milk fat content: 43% by weight, moisture content: 52.33% by weight) manufactured by Meiji Co., Ltd.
17) Mitsubishi Chemical Foods Corporation, sucrose stearate "S-370" (HLB: 3.0, C10 - C22 saturated fatty acids: 100.0% by weight)
18) "SY Glystar PS-5S" manufactured by Sakamoto Pharmaceutical Co., Ltd. (HLB: 4.5, C10 - C22 saturated fatty acids: 99.6% by weight)
19) Mitsubishi Chemical Foods Corporation, sucrose stearate "S-570" (HLB: 5.0, C10 - C22 saturated fatty acids: 100.0% by weight)
20) Polyglycerol stearate "SY Glyster PS-3S" (HLB: 2.6, C10 - C22 saturated fatty acids: 99.8% by weight) manufactured by Sakamoto Pharmaceutical Co., Ltd.
21) Polyglycerol stearate "Sunsoft Q18-B" (HLB: 6.5, C10 - C22 saturated fatty acids: 99.7% by weight) manufactured by Taiyo Kagaku Co., Ltd.
22) Mitsubishi Chemical Foods Corporation, sucrose stearate "S-770" (HLB: 7.0, C10 - C22 saturated fatty acids: 100.0% by weight)
23) Polyglycerol oleate "SY Glyster MO-5S" manufactured by Sakamoto Pharmaceutical Co., Ltd. (HLB: 11.6, C10 - C22 saturated fatty acids: 29.81% by weight, unsaturated fatty acids: 70% by weight)
24) "Palm kernel olein" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 47.5% by weight, slip melting point: 23.0°C, lauric acid: 40.5% by weight, S2U: 2.6% by weight)
25) "Palm oil mid-melting point fraction" manufactured by Kaneka Corporation ( C16 - C22 saturated fatty acids: 64.2% by weight, S2U: 91.8% by weight, slip melting point: 31.3°C)
<原液安定性評価>
実施例・比較例で得られた起泡性水中油型乳化油脂組成物又は起泡性コンパウンドクリームをガラスビーカーに60g取り分け、15℃で1時間静置した後、120rpmで撹拌し、増粘するまでの時間(ボテ時間)(分)を測定し、評価値とした。
<Evaluation of stability of stock solution>
60 g of the foamable oil-in-water emulsified oil composition or foamable compound cream obtained in the Examples and Comparative Examples was dispensed into a glass beaker and allowed to stand at 15° C. for 1 hour. The mixture was then stirred at 120 rpm, and the time (minutes) until the mixture thickened was measured and used as an evaluation value.
<ホイップ性(オーバーラン)評価>
実施例・比較例で得られた起泡性水中油型乳化油脂組成物又は起泡性コンパウンドクリームを、硬さが0.30Nになるまでホイップした時の体積あたりの含気率の計算値をオーバーラン(%)とした。
<Whipping property (overrun) evaluation>
The foamable oil-in-water emulsified oil composition or foamable compound cream obtained in the Examples and Comparative Examples was whipped to a hardness of 0.30 N, and the calculated air content per volume was taken as overrun (%).
<ホイップ性(ホイップタイム)評価>
実施例・比較例で得られた起泡性水中油型乳化油脂組成物又は起泡性コンパウンドクリームを、硬さが0.30Nになるまでホイップした時の時間(分、秒)を測定し、評価値とした。
<Whipability (whip time) evaluation>
The time (minutes, seconds) required for whipping the foamable oil-in-water emulsified oil composition or foamable compound cream obtained in the Examples and Comparative Examples until the hardness reached 0.30 N was measured, and this was used as an evaluation value.
<ホイップ後の硬さ評価>
実施例・比較例で得られた硬さが0.30Nのホイップドクリーム又はホイップドコンパウンドクリームを室温にて30分間静置した後の最大荷重をレオナーで測定し、その変化を評価した。その際の評価は、下記の基準で行った。
5点:ホイップ後の硬さ変化が0.03N以上且つ0.06N以下
4点:ホイップ後の硬さ変化が0.02N以上0.03N未満、又は0.06Nより大きく0.07N以下
3点:ホイップ後の硬さ変化が0.01N以上0.02N未満、又は0.07Nより大きく0.09N以下
2点:ホイップ後の硬さ変化が0.09Nより大きく0.2N未満、又は-0.05N以上0.01N未満
1点:ホイップ後の硬さ変化が0.2N以上、又は-0.05N未満
<Evaluation of hardness after whipping>
The whipped cream or whipped compound cream having a hardness of 0.30 N obtained in the Examples and Comparative Examples was left to stand at room temperature for 30 minutes, after which the maximum load was measured using a Leonar and the change was evaluated. The evaluation was performed according to the following criteria.
5 points: change in hardness after whipping is 0.03N or more and 0.06N or less; 4 points: change in hardness after whipping is 0.02N or more and less than 0.03N, or more than 0.06N and less than 0.07N; 3 points: change in hardness after whipping is 0.01N or more and less than 0.02N, or more than 0.07N and less than 0.09N; 2 points: change in hardness after whipping is 0.09N or more and less than 0.2N, or -0.05N or more and less than 0.01N; 1 point: change in hardness after whipping is 0.2N or more, or less than -0.05N
<ホイップドクリーム(乳脂肪0%)の口溶け(早さ)評価>
実施例・比較例で得られたホイップドクリームを、熟練のパネラー10人が口に含み、5点満点で評価して、その平均点を評価点とした。その際の評価基準は、以下の通りであった。
5点:比較例2のホイップドクリームよりも極めて口溶けが早い
4点:比較例2のホイップドクリームよりも口溶けが早い
3点:比較例2のホイップドクリームと口溶けの早さが同等
2点:比較例2のホイップドクリームよりも口溶けが遅い
1点:比較的2のホイップドクリームよりも極めて口溶けが遅い
<Evaluation of melting speed (speed) of whipped cream (0% milk fat)>
The whipped creams obtained in the Examples and Comparative Examples were put into the mouths of 10 experienced panelists, who rated them on a scale of 1 to 5, and the average score was taken as the evaluation score. The evaluation criteria were as follows:
5 points: melts in the mouth much faster than the whipped cream of Comparative Example 2 4 points: melts in the mouth much faster than the whipped cream of Comparative Example 2 3 points: melts in the mouth as quickly as the whipped cream of Comparative Example 2 2 points: melts in the mouth slower than the whipped cream of Comparative Example 2 1 point: melts in the mouth much slower than the whipped cream of Comparative Example 2
<ホイップドコンパウンドクリームの口溶け(早さ)評価>
実施例・比較例で得られたホイップドコンパウンドクリームを、熟練のパネラー10人が口に含み、5点満点で評価して、その平均点を評価点とした。その際の評価基準は、以下の通りであった。
5点:水中油型乳化油脂組成物B2と生クリームを用いて得たコンパウンド比率が同等のホイップドコンパウンドクリームよりも極めて口溶けが早い
4点:水中油型乳化油脂組成物B2と生クリームを用いて得たコンパウンド比率が同等のホイップドコンパウンドクリームよりも口溶けが早い
3点:水中油型乳化油脂組成物B2と生クリームを用いて得たコンパウンド比率が同等のホイップドコンパウンドクリームと口溶けが同等
2点:水中油型乳化油脂組成物B2と生クリームを用いて得たコンパウンド比率が同等のホイップドコンパウンドクリームよりも口溶けが遅い
1点:水中油型乳化油脂組成物B2と生クリームを用いて得たコンパウンド比率が同等のホイップドコンパウンドクリームよりも極めて口溶けが遅い
<Evaluation of whipped compound cream melting speed>
The whipped compound creams obtained in the Examples and Comparative Examples were put into the mouths of 10 experienced panelists, who evaluated them on a scale of 1 to 5, and the average score was taken as the evaluation score. The evaluation criteria were as follows:
5 points: melts in the mouth much faster than a whipped compound cream with an equivalent compound ratio obtained using the oil-in-water emulsified oil composition B2 and fresh cream; 4 points: melts in the mouth much faster than a whipped compound cream with an equivalent compound ratio obtained using the oil-in-water emulsified oil composition B2 and fresh cream; 3 points: melts in the mouth the same as a whipped compound cream with an equivalent compound ratio obtained using the oil-in-water emulsified oil composition B2 and fresh cream; 2 points: melts in the mouth slower than a whipped compound cream with an equivalent compound ratio obtained using the oil-in-water emulsified oil composition B2 and fresh cream; 1 point: melts in the mouth much slower than a whipped compound cream with an equivalent compound ratio obtained using the oil-in-water emulsified oil composition B2 and fresh cream
<総合評価>
評価した原液安定性(ボテ時間)、ホイップ性(オーバーラン、ホイップタイム)、ホイップ後の硬さ、口溶け(早さ)の各評価を、以下の基準に従って、総合評価した。
A:ボテ時間30分以上、オーバーラン110%以上、ホイップタイム5~7分、ホイップ後の硬さの評価が5点、及び、口溶け(早さ)の評価が4.5~5点を満足するもの
B:Aの要件を満たさず、ボテ時間30分以上、オーバーラン110%以上、ホイップタイム5~7分、ホイップ後の硬さの評価が4点以上、及び、口溶け(早さ)の評価が3.5点以上を満足するもの
C:A及びBの要件を満たさず、ボテ時間30分以上、オーバーラン110%以上、ホイップタイム5~7分、ホイップ後の硬さの評価が3点以上、及び、口溶け(早さ)の評価が3.0点超えを満足するもの
D:Eの要件を満たさず、ボテ時間20分以上30分未満、オーバーラン90%以上110%未満、ホイップタイム7分以上8分半未満、ホイップ後の硬さの評価が2点、及び、口溶け(早さ)の評価が2.0点以上3.0点以下からなる評価群より選ばれる少なくとも一つに該当するもの
E:ボテ時間20分未満、オーバーラン90%未満、ホイップタイム8分半以上、ホイップ後の硬さの評価が1点、及び、口溶け(早さ)の評価が2.0点未満からなる評価群より選ばれる少なくとも一つに該当するもの
<Overall evaluation>
The evaluated ingredients stability (blotting time), whipping properties (overrun, whipping time), hardness after whipping, and melting in the mouth (speed) were evaluated and comprehensively rated according to the following criteria.
A: Satisfies the following: a weighting time of 30 minutes or more, an overrun of 110% or more, a whipping time of 5 to 7 minutes, a rating of 5 points for hardness after whipping, and a rating of 4.5 to 5 points for melting in the mouth (speed). B: Does not satisfy the requirements of A, and satisfies the following: a weighting time of 30 minutes or more, an overrun of 110% or more, a whipping time of 5 to 7 minutes, a rating of 4 points for hardness after whipping, and a rating of 3.5 points for melting in the mouth (speed). C: Does not satisfy the requirements of A and B, and satisfies the following: a weighting time of 30 minutes or more, an overrun of 110% or more, a whipping time of 5 to 7 minutes, a rating of 3 points for hardness after whipping, and a rating of 3.5 points for melting in the mouth (speed). ) exceeds 3.0 points. D: Does not satisfy the requirements of E and falls under at least one of the following evaluation groups: a stuffing time of 20 minutes or more and less than 30 minutes, an overrun of 90% or more and less than 110%, a whipping time of 7 minutes or more and less than 8.5 minutes, a hardness after whipping evaluation of 2 points, and a melting speed evaluation of 2.0 points or more and 3.0 points or less. E: Falls under at least one of the following evaluation groups: a stuffing time of less than 20 minutes, an overrun of less than 90%, a whipping time of 8.5 minutes or more, a hardness after whipping evaluation of 1 point, and a melting speed evaluation of less than 2.0 points.
(実施例1)起泡性水中油型乳化油脂組成物A1及びホイップドクリームA1
表1の配合に従い、パーム核油:18.5重量部、パーム油中融点部(PMF):11.3重量部及びパームオレイン:7.2重量部の油脂混合物に、大豆レシチン:0.2重量部、ポリグリセリン混酸エステル:0.06重量部、ポリグリセリンベヘン酸エステル:0.03重量部を添加し、65℃で溶解して油相部を作製した。
(Example 1) Foamable oil-in-water emulsified oil composition A1 and whipped cream A1
According to the formulation in Table 1, 0.2 part by weight of soybean lecithin, 0.06 part by weight of polyglycerol mixed acid ester, and 0.03 part by weight of polyglycerol behenate were added to an oil and fat mixture of 18.5 parts by weight of palm kernel oil, 11.3 parts by weight of palm mid fraction (PMF), and 7.2 parts by weight of palm olein, and dissolved at 65° C. to prepare an oil phase.
また別に、脱脂粉乳:3.7重量部、カゼインカリウム:0.5重量部、乳糖1.5重量部、ポリグリセリンステアリン酸エステル(乳化剤A、HLB:4.6、C10~C22の飽和脂肪酸:99.4重量%):0.15重量部、ポリグリセリンステアリン酸エステル(HLB:11.6、C10~C22の飽和脂肪酸:98.0重量%)0.05重量部を、表1の配合と最終的に同じになるように60℃以上の温水に溶解して水相部を作製した。 Separately, 3.7 parts by weight of skim milk powder, 0.5 parts by weight of potassium caseinate, 1.5 parts by weight of lactose, 0.15 parts by weight of polyglycerol stearate (emulsifier A, HLB: 4.6, C10 - C22 saturated fatty acids: 99.4% by weight), and 0.05 parts by weight of polyglycerol stearate (HLB: 11.6, C10 - C22 saturated fatty acids: 98.0% by weight) were dissolved in hot water of 60°C or higher to give a final composition identical to that in Table 1 to prepare an aqueous phase.
前記の油相部と水相部とを混合して20分以上予備乳化した後、高周速回転式乳化機(エム・テクニック(株)製「クレアミックス」)を用いて周速31.4m/sの回転速度で微細化した。次いで、高圧ホモジナイザーを用いて1段目:2.0MPa/2段目:1.0MPaの圧力で処理した後に、プレート式加熱機を用いて90℃まで予備加熱した後、UHT殺菌機(スチームインジェクション)を用いて142℃で4秒間殺菌処理した。次に、蒸発冷却せずにプレート式冷却機を用いて60℃まで冷却し、再び高圧ホモジナイザーを用いて1段目:9.0MPa/2段目:3.0MPaの圧力で処理し、その後、プレート式冷却機で5℃まで冷却したものを容器に充填し、5℃の冷蔵庫で48時間保管し、起泡性水中油型乳化油脂組成物A1を得た。 The oil phase and the water phase were mixed and pre-emulsified for 20 minutes or more, and then finely milled at a rotation speed of 31.4 m/s using a high-speed rotary emulsifier ("Clearmix" manufactured by M Technique Co., Ltd.). Next, the mixture was treated with a high-pressure homogenizer at a pressure of 2.0 MPa in the first stage and 1.0 MPa in the second stage, preheated to 90°C using a plate heater, and sterilized at 142°C for 4 seconds using a UHT sterilizer (steam injection). Next, the mixture was cooled to 60°C using a plate cooler without evaporative cooling, and then treated again with a high-pressure homogenizer at a pressure of 9.0 MPa in the first stage and 3.0 MPa in the second stage. The mixture was then cooled to 5°C using a plate cooler, filled into a container, and stored in a refrigerator at 5°C for 48 hours to obtain a foamable oil-in-water emulsified oil composition A1.
得られた起泡性水中油型乳化油脂組成物A1をカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、グラニュー糖320gを入れ、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドクリームA1(乳脂肪0%)を得た。得られた起泡性水中油型乳化油脂組成物A1とホイップドクリームA1の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ))を行い、それらの結果を表1にまとめた。 4 kg of the obtained foamable oil-in-water emulsified oil composition A1 was placed in a Kanto mixer ("CS type 20" manufactured by Kanto Mixing Machinery Co., Ltd.), the product temperature was adjusted to 5°C, 320 g of granulated sugar was added, and the mixture was whipped under high speed stirring conditions (380 rpm) until the hardness reached 0.30 N, yielding whipped cream A1 (0% milk fat). The obtained foamable oil-in-water emulsified oil composition A1 and whipped cream A1 were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, and melting in the mouth (quickness)), and the results are summarized in Table 1.
(実施例2)起泡性水中油型乳化油脂組成物A2及びホイップドクリームA2
表1に従って、パーム核油:20.3重量部、パーム油中融点部(PMF):10.2重量部及びパームオレイン:6.5重量部に変更した以外は、実施例1と同様にして起泡性水中油型乳化油脂組成物A2及びホイップドクリームA2(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表1にまとめた。
(Example 2) Foamable oil-in-water emulsified oil composition A2 and whipped cream A2
According to Table 1, except for changing the ingredients to palm kernel oil: 20.3 parts by weight, palm mid fraction (PMF): 10.2 parts by weight, and palm olein: 6.5 parts by weight, foamable oil-in-water emulsified oil composition A2 and whipped cream A2 (0% milk fat) were obtained in the same manner as in Example 1, and evaluated in the same manner as in Example 1. The results are shown in Table 1.
(実施例3)起泡性水中油型乳化油脂組成物A3及びホイップドクリームA3
表1に従って、パーム核油:21.1重量部、パーム油中融点部(PMF):9.7重量部及びパームオレイン:6.2重量部に変更した以外は、実施例1と同様にして起泡性水中油型乳化油脂組成物A3及びホイップドクリームA3(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表1にまとめた。
(Example 3) Foamable oil-in-water emulsified oil composition A3 and whipped cream A3
According to Table 1, except for changing the amounts of palm kernel oil: 21.1 parts by weight, palm mid fraction (PMF): 9.7 parts by weight, and palm olein: 6.2 parts by weight, foamable oil-in-water emulsified oil composition A3 and whipped cream A3 (0% milk fat) were obtained in the same manner as in Example 1, and evaluated in the same manner as in Example 1. The results are shown in Table 1.
(実施例4)起泡性水中油型乳化油脂組成物A4及びホイップドクリームA4
表1に従って、パーム核油:23.0重量部、パーム油中融点部(PMF):8.5重量部及びパームオレイン:5.5重量部に変更した以外は、実施例1と同様にして起泡性水中油型乳化油脂組成物A4及びホイップドクリームA4(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表1にまとめた。
(Example 4) Foamable oil-in-water emulsified oil composition A4 and whipped cream A4
According to Table 1, except for changing the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein to 23.0 parts by weight, 8.5 parts by weight, and 5.5 parts by weight, respectively, the same procedures as in Example 1 were repeated to obtain foamable oil-in-water emulsified oil composition A4 and whipped cream A4 (0% milk fat). These were evaluated in the same manner as in Example 1, and the results are shown in Table 1.
(比較例1)起泡性水中油型乳化油脂組成物B1及びホイップドクリームB1
表1に従って、パーム核油:23.9重量部、パーム油中融点部(PMF):8.0重量部及びパームオレイン:5.1重量部に変更した以外は、実施例1と同様にして起泡性水中油型乳化油脂組成物B1及びホイップドクリームB1(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表1にまとめた。
(Comparative Example 1) Foamable oil-in-water emulsified oil composition B1 and whipped cream B1
According to Table 1, except for changing the amounts of palm kernel oil: 23.9 parts by weight, palm mid fraction (PMF): 8.0 parts by weight, and palm olein: 5.1 parts by weight, foamable oil-in-water emulsified oil composition B1 and whipped cream B1 (0% milk fat) were obtained in the same manner as in Example 1, and evaluated in the same manner as in Example 1. The results are shown in Table 1.
表1にまとめた結果より、以下のことがわかった。実施例1~4及び比較例1より、本発明の効果を奏するには油脂B/(油脂A+油脂B)(重量比)は0.37~0.5が好適であり、0.37を下回るとホイップ後の硬さが悪化する場合があることが明らかとなった。 The results summarized in Table 1 reveal the following. From Examples 1 to 4 and Comparative Example 1, it became clear that in order to achieve the effects of the present invention, a weight ratio of oil B/(oil A + oil B) of 0.37 to 0.5 is suitable, and if it is below 0.37, the hardness after whipping may deteriorate.
(実施例5)起泡性水中油型乳化油脂組成物A5及びホイップドクリームA5
表2に従って、パーム核油:15.7重量部、パーム油中融点部(PMF):9.6重量部及びパームオレイン:6.1重量部に変更し、さらにその他の油脂として菜種油:5.6重量部を混合して油脂混合物とし、水量を調整した以外は、実施例1と同様にして起泡性水中油型乳化油脂組成物A5及びホイップドクリームA5(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表2にまとめた。
(Example 5) Foamable oil-in-water emulsified oil composition A5 and whipped cream A5
According to Table 2, the ingredients were changed to palm kernel oil: 15.7 parts by weight, palm mid fraction (PMF): 9.6 parts by weight, and palm olein: 6.1 parts by weight, and 5.6 parts by weight of rapeseed oil was further added as other oils and fats to prepare an oil and fat mixture, and the amount of water was adjusted. Except for this, foamable oil-in-water emulsified oil composition A5 and whipped cream A5 (0% milk fat) were obtained in the same manner as in Example 1, and evaluated in the same manner as in Example 1. The results are shown in Table 2.
(比較例2)起泡性水中油型乳化油脂組成物B2及びホイップドクリームB2
表2に従って、パーム核油:29.6重量部、パーム油中融点部(PMF):4.5重量部及びパームオレイン:2.9重量部に変更した以外は、実施例1と同様にして起泡性水中油型乳化油脂組成物B2及びホイップドクリームB2(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表2にまとめた。
(Comparative Example 2) Foamable oil-in-water emulsified oil composition B2 and whipped cream B2
According to Table 2, except for changing the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein to 29.6 parts by weight, 4.5 parts by weight, and 2.9 parts by weight, respectively, the same procedures as in Example 1 were repeated to obtain a foamable oil-in-water emulsified oil composition B2 and a whipped cream B2 (0% milk fat). These were evaluated in the same manner as in Example 1, and the results are shown in Table 2.
(比較例3)起泡性水中油型乳化油脂組成物B3及びホイップドクリームB3
表2に従って、混合油脂としてパーム油中融点部(PMF)とパームオレインは含まず、パーム核油:25.5重量部に変更し、さらにパーム核硬化油:4.0重量部、パームエステル交換油:7.5重量部を混合し、ポリグリセリン混酸エステル、及びHLB2.5のポリグリセリンベヘン酸エステルを配合せず、油相にHLB8.4のポリグリセリンステアリン酸エステル:0.09重量部を配合した以外は、実施例1と同様にして起泡性水中油型乳化油脂組成物B3及びホイップドクリームB3(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表2にまとめた。
(Comparative Example 3) Foamable oil-in-water emulsified oil composition B3 and whipped cream B3
According to Table 2, the mixed oil/fat did not contain palm mid (PMF) and palm olein, but was changed to 25.5 parts by weight of palm kernel oil, and further contained 4.0 parts by weight of palm kernel hardened oil and 7.5 parts by weight of palm interesterified oil. The polyglycerol mixed acid ester and polyglycerol behenate having an HLB of 2.5 were not blended, and 0.09 part by weight of polyglycerol stearate having an HLB of 8.4 was blended in the oil phase. In the same manner as in Example 1, a foamable oil-in-water emulsified oil/fat composition B3 and whipped cream B3 (0% milk fat) were obtained. They were evaluated in the same manner as in Example 1, and the results are shown in Table 2.
表2にまとめた結果より、以下のことがわかった。実施例1、5及び比較例2より、本発明の効果を奏するには、油脂B/(油脂A+油脂B)(重量比)は0.37~0.5が好適であり、0.37を下回ると、ホイップ後の硬さが悪化したり、口溶けが遅くなる場合があることが明らかとなった。また、実施例1、5及び比較例3より、乳脂肪を除く油脂全体中の油脂A及び油脂Bの合計含有量は80~100重量%が好適であり、前記合計含有量を下回ると口溶けが遅くなる場合があることが明らかとなった。 From the results summarized in Table 2, the following was found. From Examples 1 and 5 and Comparative Example 2, it was revealed that in order to achieve the effects of the present invention, a weight ratio of fat B/(fat A + fat B) of 0.37 to 0.5 is preferable, and if it is less than 0.37, the hardness after whipping may deteriorate and melting in the mouth may become slow. Furthermore, from Examples 1 and 5 and Comparative Example 3, it was revealed that a total content of fat A and fat B in all fats excluding milk fat is preferably 80 to 100% by weight, and if it is less than this total content, melting in the mouth may become slow.
(実施例6)起泡性水中油型乳化油脂組成物A6及びホイップドクリームA6
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.08重量部に変更し、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A6及びホイップドクリームA6(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表3にまとめた。
(Example 6) Foamable oil-in-water emulsified oil composition A6 and whipped cream A6
According to Table 3, except that the amount of emulsifier A (polyglycerol stearate) was changed to 0.08 parts by weight and the amount of water was adjusted, foamable oil-in-water emulsified oil composition A6 and whipped cream A6 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 3.
(実施例7)起泡性水中油型乳化油脂組成物A7及びホイップドクリームA7
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.50重量部に変更し、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A7及びホイップドクリームA7(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表3にまとめた。
(Example 7) Foamable oil-in-water emulsified oil composition A7 and whipped cream A7
According to Table 3, except that the amount of emulsifier A (polyglycerol stearate) was changed to 0.50 parts by weight and the amount of water was adjusted, foamable oil-in-water emulsified oil composition A7 and whipped cream A7 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 3.
(比較例4)起泡性水中油型乳化油脂組成物B4及びホイップドクリームB4
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.005重量部に変更し、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B4及びホイップドクリームB4(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表3にまとめた。
(Comparative Example 4) Foamable oil-in-water emulsified oil composition B4 and whipped cream B4
According to Table 3, except that the amount of emulsifier A (polyglycerol stearate) was changed to 0.005 parts by weight and the amount of water was adjusted, foamable oil-in-water emulsified oil composition B4 and whipped cream B4 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 3.
(比較例5)起泡性水中油型乳化油脂組成物B5及びホイップドクリームB5
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.80重量部に変更し、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B5及びホイップドクリームB5(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表3にまとめた。
(Comparative Example 5) Foamable oil-in-water emulsified oil composition B5 and whipped cream B5
According to Table 3, except that the amount of emulsifier A (polyglycerol stearate) was changed to 0.80 parts by weight and the amount of water was adjusted, foamable oil-in-water emulsified oil composition B5 and whipped cream B5 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 3.
表3にまとめた結果より、以下のことがわかった。実施例2、6~7及び比較例4~5より、本発明の効果を奏するには、乳化剤Aの含有量は起泡性水中油型乳化油脂組成物全体中0.01~0.7重量%が好適であり、前記範囲を外れると、原液安定性やホイップ性が悪くなったり、ホイップ後の硬さが損なわれる場合があることが明らかとなった。 The results summarized in Table 3 reveal the following. From Examples 2, 6-7 and Comparative Examples 4-5, it became clear that in order to achieve the effects of the present invention, the content of emulsifier A is preferably 0.01-0.7% by weight of the entire foamable oil-in-water emulsified oil composition, and that if it is outside this range, the stability of the original liquid and whipping properties may deteriorate, and the hardness after whipping may be impaired.
(実施例8)起泡性水中油型乳化油脂組成物A8及びホイップドクリームA8
表4に従って、乳化剤Aとしてポリグリセリンステアリン酸エステル:0.15重量部に加えてショ糖ステアリン酸エステル:0.08重量部を添加し、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A8及びホイップドクリームA8(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表4にまとめた。
(Example 8) Foamable oil-in-water emulsified oil composition A8 and whipped cream A8
According to Table 4, a foamable oil-in-water emulsified oil composition A8 and a whipped cream A8 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.15 part by weight of polyglycerol stearate was added as emulsifier A, and 0.08 part by weight of sucrose stearate was added, and the amount of water was adjusted. These compositions were evaluated in the same manner as in Example 1, and the results are shown in Table 4.
(実施例9)起泡性水中油型乳化油脂組成物A9及びホイップドクリームA9
表4に従って、乳化剤Aとしてポリグリセリンステアリン酸エステル:0.15重量部に加えてショ糖ステアリン酸エステル:0.15重量部を添加し、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A9及びホイップドクリームA9(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表4にまとめた。
(Example 9) Foamable oil-in-water emulsified oil composition A9 and whipped cream A9
According to Table 4, a foamable oil-in-water emulsified oil composition A9 and a whipped cream A9 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.15 parts by weight of sucrose stearate was added in addition to 0.15 parts by weight of polyglycerol stearate as emulsifier A, and the amount of water was adjusted. These compositions were evaluated in the same manner as in Example 1, and the results are shown in Table 4.
(実施例10)起泡性水中油型乳化油脂組成物A10及びホイップドクリームA10
表4に従って、乳化剤Aとしてポリグリセリンステアリン酸エステル:0.15重量部に加えてショ糖ステアリン酸エステル:0.50重量部を添加し、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A10及びホイップドクリームA10(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表4にまとめた。
(Example 10) Foamable oil-in-water emulsified oil composition A10 and whipped cream A10
According to Table 4, a foamable oil-in-water emulsified oil composition A10 and a whipped cream A10 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.15 part by weight of polyglycerol stearate was added as emulsifier A, and 0.50 part by weight of sucrose stearate was added, and the amount of water was adjusted. These compositions were evaluated in the same manner as in Example 1, and the results are shown in Table 4.
(比較例6)起泡性水中油型乳化油脂組成物B6及びホイップドクリームB6
表4に従って、乳化剤A:0.15重量部を水相に添加せずに、油相に添加した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B6及びホイップドクリームB6(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表4にまとめた。
(Comparative Example 6) Foamable oil-in-water emulsified oil composition B6 and whipped cream B6
According to Table 4, a foamable oil-in-water emulsified oil composition B6 and whipped cream B6 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.15 parts by weight of emulsifier A was added to the oil phase instead of the aqueous phase, and evaluated in the same manner as in Example 1. The results are shown in Table 4.
表4にまとめた結果より、以下のことがわかった。実施例2、8~10より、HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含む乳化剤Aとして、ショ糖脂肪酸エステル及びポリグリセリン脂肪酸エステルを併用した場合も、本発明の効果を奏することが明らかとなった。また、実施例2及び比較例6より、本発明の効果を奏するには前記乳化剤Aを水相に配合することが好適であり、水相に配合せず油相に配合すると、ホイップ性が悪くなったり、ホイップ後の硬さが損なわれる場合があることが明らかとなった。 The results summarized in Table 4 reveal the following. From Examples 2 and 8 to 10, it was revealed that the effects of the present invention can be achieved even when sucrose fatty acid ester and polyglycerin fatty acid ester are used in combination as emulsifier A having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C10 to C22 saturated fatty acids in the total constituent fatty acids. Moreover, from Example 2 and Comparative Example 6, it was revealed that in order to achieve the effects of the present invention, it is preferable to blend the emulsifier A in the aqueous phase, and that blending the emulsifier A in the oil phase rather than in the aqueous phase may result in poor whipping properties or loss of hardness after whipping.
(実施例11)起泡性水中油型乳化油脂組成物A11及びホイップドクリームA11
表5に従って、乳化剤Aとして、ポリグリセリンステアリン酸エステル(HLB4.6):0.15重量部をショ糖ステアリン酸エステル(HLB3.0):0.15重量部に変更した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A11及びホイップドクリームA11(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表5にまとめた。
(Example 11) Foamable oil-in-water emulsified oil composition A11 and whipped cream A11
According to Table 5, a foamable oil-in-water emulsified oil composition A11 and a whipped cream A11 (0% milk fat) were obtained in the same manner as in Example 2, except that as emulsifier A, 0.15 parts by weight of polyglycerol stearate (HLB 4.6) was used instead of 0.15 parts by weight of sucrose stearate (HLB 3.0). These were evaluated in the same manner as in Example 1, and the results are shown in Table 5.
(実施例12)起泡性水中油型乳化油脂組成物A12及びホイップドクリームA12
表5に従って、乳化剤Aとして、ポリグリセリンステアリン酸エステル(HLB4.6):0.15重量部をショ糖ステアリン酸エステル(HLB5.0):0.15重量部に変更した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A12及びホイップドクリームA12(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表5にまとめた。
(Example 12) Foamable oil-in-water emulsified oil composition A12 and whipped cream A12
According to Table 5, a foamable oil-in-water emulsified oil composition A12 and a whipped cream A12 (0% milk fat) were obtained in the same manner as in Example 2, except that as emulsifier A, 0.15 parts by weight of polyglycerol stearate (HLB 4.6) was used instead of 0.15 parts by weight of sucrose stearate (HLB 5.0). These were then evaluated in the same manner as in Example 1, and the results are shown in Table 5.
(比較例7)起泡性水中油型乳化油脂組成物B7及びホイップドクリームB7
表5に従って、乳化剤Aであるポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しないポリグリセリンステアリン酸エステル(HLB:2.6):0.15重量部を用いた以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B7及びホイップドクリームB7(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表5にまとめた。
(Comparative Example 7) Foamable oil-in-water emulsified oil composition B7 and whipped cream B7
According to Table 5, foamable oil-in-water emulsified oil composition B7 and whipped cream B7 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.15 parts by weight of polyglycerol stearate (HLB: 2.6), which does not correspond to emulsifier A, was used instead of 0.15 parts by weight of polyglycerol stearate (HLB: 4.6), which is emulsifier A. They were then evaluated in the same manner as in Example 1, and the results are shown in Table 5.
(比較例8)起泡性水中油型乳化油脂組成物B8及びホイップドクリームB8
表5に従って、乳化剤Aであるポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しないポリグリセリンステアリン酸エステル(HLB:6.5):0.15重量部を用いた以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B8及びホイップドクリームB8(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表5にまとめた。
(Comparative Example 8) Foamable oil-in-water emulsified oil composition B8 and whipped cream B8
According to Table 5, foamable oil-in-water emulsified oil composition B8 and whipped cream B8 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.15 parts by weight of polyglycerol stearate (HLB: 6.5), which does not correspond to emulsifier A, was used instead of 0.15 parts by weight of polyglycerol stearate (HLB: 4.6), which is emulsifier A. They were then evaluated in the same manner as in Example 1, and the results are shown in Table 5.
(比較例9)起泡性水中油型乳化油脂組成物B9及びホイップドクリームB9
表5に従って、乳化剤Aであるポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しないショ糖ステアリン酸エステル(HLB:7.0):0.15重量部を用いた以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B9及びホイップドクリームB9(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表5にまとめた。
(Comparative Example 9) Foamable oil-in-water emulsified oil composition B9 and whipped cream B9
According to Table 5, foamable oil-in-water emulsified oil composition B9 and whipped cream B9 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.15 parts by weight of sucrose stearate (HLB: 7.0), which does not correspond to emulsifier A, was used instead of 0.15 parts by weight of polyglycerol stearate (HLB: 4.6), which is emulsifier A, and evaluated in the same manner as in Example 1. The results are shown in Table 5.
表5にまとめた結果より、以下のことがわかった。実施例11~12及び比較例7~9より、本発明の効果を奏するには、乳化剤AのHLBは2.8~6.2が好適であり、前記範囲を外れるとホイップ性が悪くなったり、ホイップ後の硬さが損なわれる場合があることが明らかとなった。 The results summarized in Table 5 reveal the following. From Examples 11-12 and Comparative Examples 7-9, it became clear that in order to achieve the effects of the present invention, the HLB of emulsifier A is preferably 2.8-6.2, and that outside this range, whipping properties may deteriorate or hardness after whipping may be impaired.
(実施例13)起泡性水中油型乳化油脂組成物A13及びホイップドクリームA13
表6に従って、パーム核油の含有量を19.2重量部に変更し、パーム核硬化油:1.1重量部を添加した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A13及びホイップドクリームA13(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表6にまとめた。
(Example 13) Foamable oil-in-water emulsified oil composition A13 and whipped cream A13
According to Table 6, except that the content of palm kernel oil was changed to 19.2 parts by weight and 1.1 parts by weight of hardened palm kernel oil was added, the same procedures as in Example 2 were repeated to obtain foamable oil-in-water emulsified oil composition A13 and whipped cream A13 (0% milk fat). These were evaluated in the same manner as in Example 1, and the results are shown in Table 6.
(実施例14)起泡性水中油型乳化油脂組成物A14及びホイップドクリームA14
表6に従って、パーム核油の含有量を2.4重量部に変更し、パーム核オレイン:17.9重量部を添加した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物14及びホイップドクリームA14(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表6にまとめた。
(Example 14) Foamable oil-in-water emulsified oil composition A14 and whipped cream A14
According to Table 6, except that the content of palm kernel oil was changed to 2.4 parts by weight and 17.9 parts by weight of palm kernel olein was added, foamable oil-in-water emulsified oil composition 14 and whipped cream A14 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 6.
(比較例10)起泡性水中油型乳化油脂組成物B10及びホイップドクリームB10
表6に従って、パーム核油の含有量を14.6重量部に変更し、パーム核硬化油:5.7重量部を添加した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B10及びホイップドクリームB10(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表6にまとめた。
(Comparative Example 10) Foamable oil-in-water emulsified oil composition B10 and whipped cream B10
According to Table 6, except that the content of palm kernel oil was changed to 14.6 parts by weight and 5.7 parts by weight of hardened palm kernel oil was added, the same procedures as in Example 2 were repeated to obtain foamable oil-in-water emulsified oil composition B10 and whipped cream B10 (0% milk fat). These were evaluated in the same manner as in Example 1, and the results are shown in Table 6.
(比較例11)起泡性水中油型乳化油脂組成物B11及びホイップドクリームB11
表6に従って、パーム核油の含有量を20.0重量部に変更し、パーム油中融点部の含有量を10.0重量部に変更し、パームオレインの含有量を6.4重量部に変更し、パームエステル交換油:0.6重量部を添加した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B11及びホイップドクリームB11(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表6にまとめた。
(Comparative Example 11) Foamable oil-in-water emulsified oil composition B11 and whipped cream B11
According to Table 6, the content of palm kernel oil was changed to 20.0 parts by weight, the content of palm mid part was changed to 10.0 parts by weight, the content of palm olein was changed to 6.4 parts by weight, and 0.6 parts by weight of palm interesterified oil was added. Except for this, foamable oil-in-water emulsified oil composition B11 and whipped cream B11 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 6.
表6にまとめた結果より、以下のことがわかった。実施例2、13~14及び比較例10より、本発明の効果を奏するには、C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含む油脂Aの上昇融点は23~30℃が好適であり、油脂Aの上昇融点が30℃より高くなると、原液安定性が悪くなったり、ホイップ後の硬さが損なわれる場合があることが明らかとなった。また、実施例2及び比較例11より、本発明の効果を奏するには油脂全体中のエステル交換油の含有量は1重量%未満が好適であり、1重量%以上では口溶けが遅くなる場合があることが明らかとなった。 From the results summarized in Table 6, the following was found. From Examples 2, 13 to 14 and Comparative Example 10, it was revealed that in order to achieve the effects of the present invention, the slip melting point of fat A containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids is preferably 23 to 30°C, and if the slip melting point of fat A is higher than 30°C, the stability of the original liquid may be deteriorated and the hardness after whipping may be impaired. Furthermore, from Example 2 and Comparative Example 11, it was revealed that in order to achieve the effects of the present invention, the content of interesterified oil in the total fat is preferably less than 1% by weight, and if it is 1% by weight or more, the melting in the mouth may be delayed.
(実施例15)起泡性水中油型乳化油脂組成物A15及びホイップドクリームA15
表7に従って、パーム油中融点部の含有量を5.5重量部に変更し、パームオレインの含有量を11.2重量部に変更した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A15及びホイップドクリームA15(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表7にまとめた。
(Example 15) Foamable oil-in-water emulsified oil composition A15 and whipped cream A15
According to Table 7, except that the content of palm oil mid-point fraction was changed to 5.5 parts by weight and the content of palm olein was changed to 11.2 parts by weight, foamable oil-in-water emulsified oil composition A15 and whipped cream A15 (0% milk fat) were obtained in the same manner as in Example 2 and evaluated in the same manner as in Example 1. The results are shown in Table 7.
(実施例16)起泡性水中油型乳化油脂組成物A16及びホイップドクリームA16
表7に従って、パームオレインの含有量を7.6重量部に変更し、パーム油中融点部(上昇融点:26.8℃)を配合せず、上昇融点の異なるパーム油中融点部(上昇融点:31.3℃):9.1重量部を添加した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A16及びホイップドクリームA16(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表7にまとめた。
(Example 16) Foamable oil-in-water emulsified oil composition A16 and whipped cream A16
According to Table 7, the palm olein content was changed to 7.6 parts by weight, palm oil mid fraction (ascent melting point: 26.8° C.) was not blended, and 9.1 parts by weight of palm oil mid fraction (ascent melting point: 31.3° C.) having a different ascent melting point was added. Except for this, foamable oil-in-water emulsified oil composition A16 and whipped cream A16 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 7.
(実施例17)起泡性水中油型乳化油脂組成物A17及びホイップドクリームA17
表7に従って、パーム核油の含有量を21.2重量部に変更し、パーム油中融点部の含有量を10.6重量部に変更し、パームオレインの含有量を6.7重量部に変更し、ポリグリセリン混酸エステル及び乳糖を配合せず、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物A17及びホイップドクリームA17(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表7にまとめた。
(Example 17) Foamable oil-in-water emulsified oil composition A17 and whipped cream A17
According to Table 7, the palm kernel oil content was changed to 21.2 parts by weight, the palm oil mid content was changed to 10.6 parts by weight, the palm olein content was changed to 6.7 parts by weight, the polyglycerol mixed acid ester and lactose were not blended, and the amount of water was adjusted. Except for this, a foamable oil-in-water emulsified oil composition A17 and a whipped cream A17 (0% milk fat) were obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 1. The results are shown in Table 7.
(比較例12)起泡性水中油型乳化油脂組成物B12及びホイップドクリームB12
表7に従って、パームオレインを添加せず、パーム油中融点部(上昇融点:26.8℃)の配合量を1.2重量部に変更し、更に、上昇融点の異なるパーム油中融点部(上昇融点:31.3℃):15.5重量部を添加した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B12及びホイップドクリームB12(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表7にまとめた。
(Comparative Example 12) Foamable oil-in-water emulsified oil composition B12 and whipped cream B12
According to Table 7, foamable oil-in-water emulsified oil composition B12 and whipped cream B12 (0% milk fat) were obtained in the same manner as in Example 2, except that palm olein was not added, the amount of palm oil mid-melting point (ascent melting point: 26.8° C.) was changed to 1.2 parts by weight, and 15.5 parts by weight of palm oil mid-melting point (ascent melting point: 31.3° C.) with a different ascent melting point was added. These were evaluated in the same manner as in Example 1, and the results are shown in Table 7.
(比較例13)起泡性水中油型乳化油脂組成物B13及びホイップドクリームB13
表7に従って、乳化剤Aであるポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しない飽和脂肪酸量が少なく不飽和脂肪酸量が多いポリグリセリンオレイン酸エステル(HLB:11.6、C10~C22の飽和脂肪酸:29.81重量%、不飽和脂肪酸:70重量%):0.04重量部を用い、水量を調整した以外は、実施例2と同様にして起泡性水中油型乳化油脂組成物B13及びホイップドクリームB13(乳脂肪0%)を得、実施例1と同様に評価し、それらの結果を表7にまとめた。
(Comparative Example 13) Foamable oil-in-water emulsified oil composition B13 and whipped cream B13
According to Table 7, a foamable oil-in-water emulsified oil composition B13 and a whipped cream B13 (0% milk fat) were obtained in the same manner as in Example 2, except that 0.04 part by weight of a polyglycerol oleate (HLB: 11.6, C10 - C22 saturated fatty acid: 29.81% by weight, unsaturated fatty acid: 70% by weight) which has less saturated fatty acid and more unsaturated fatty acid and does not correspond to emulsifier A was used instead of 0.15 part by weight of polyglycerol stearate (HLB: 4.6) which is emulsifier A, and the amount of water was adjusted. The same procedures as in Example 2 were repeated, and the results are shown in Table 7.
表7にまとめた結果より、以下のことがわかった。実施例2、15~17及び比較例12より、本発明の効果を奏するには、C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含む油脂B全体中のS2U含有量は45~70重量%、油脂Bの上昇融点は23~30℃を満たすことが好適であり、前記範囲を外れると、原液安定性やホイップ性、ホイップ後の硬さが悪化したり、口溶けが遅くなる場合があることが明らかとなった。また、実施例2及び比較例13より、乳化剤Aを配合せずに、不飽和脂肪酸量の多い乳化剤を配合すると、口溶けが遅くなる上に異味を呈するため、風味を良くする観点では、起泡性水中油型乳化油脂組成物全体中の、不飽和脂肪酸量の多い乳化剤の含有量は0.02重量%未満が好ましいことが明らかとなった。 From the results summarized in Table 7, the following was found. From Examples 2, 15 to 17 and Comparative Example 12, it was found that in order to achieve the effects of the present invention, it is preferable that the S2U content in the entire fat B containing 40% by weight or more of C 16 to C 22 saturated fatty acids in the entire constituent fatty acids is 45 to 70% by weight, and the slip melting point of fat B is 23 to 30°C. If the above range is not met, the stock solution stability, whipping property, and hardness after whipping may deteriorate, and melting in the mouth may become slow. Furthermore, from Example 2 and Comparative Example 13, it was found that the content of the emulsifier with a large amount of unsaturated fatty acids in the entire foamable oil-in-water emulsified fat composition is preferably less than 0.02% by weight, since the melting in the mouth becomes slow and an unpleasant taste is exhibited when emulsifier A is not blended and an emulsifier with a large amount of unsaturated fatty acids is blended.
(実施例1V)起泡性コンパウンドクリームA1V及びホイップドコンパウンドクリームA1V
実施例1で得られた起泡性水中油型乳化油脂組成物A1と生クリーム(乳脂肪分:43%)とを重量比95:5で混合することで起泡性コンパウンドクリームA1Vを得た。得られた起泡性コンパウンドクリームA1Vをカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、グラニュー糖320gを入れ、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドコンパウンドクリームA1Vを得た。得られた起泡性コンパウンドクリームA1V及びホイップドコンパウンドクリームA1Vの評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ))を行い、それらの結果を表8にまとめた。
(Example 1V) Foaming compound cream A1V and whipped compound cream A1V
The foamable oil-in-water emulsified oil composition A1 obtained in Example 1 was mixed with fresh cream (milk fat content: 43%) in a weight ratio of 95:5 to obtain a foamable compound cream A1V. 4 kg of the obtained foamable compound cream A1V was placed in a Kanto mixer (Kanto Mixing Machinery Co., Ltd. "CS type 20"), the product temperature was adjusted to 5°C, 320 g of granulated sugar was added, and the mixture was whipped under high-speed stirring conditions (380 rpm) until the hardness reached 0.30 N to obtain a whipped compound cream A1V. The obtained foamable compound cream A1V and whipped compound cream A1V were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, and melting in the mouth (speed)), and the results are summarized in Table 8.
(実施例2V~4V)起泡性コンパウンドクリームA2V~A4V及びホイップドコンパウンドクリームA2V~A4V
起泡性水中油型乳化油脂組成物A1を、起泡性水中油型乳化油脂組成物A2~A4に変えた以外は、実施例1Vと同様にして起泡性コンパウンドクリームA2V~A4V及びホイップドコンパウンドクリームA2V~A4Vを得た。得られた起泡性コンパウンドクリームA2V~A4V及びホイップドコンパウンドクリームA2V~A4Vの評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ))を行い、それらの結果を表8にまとめた。
(Examples 2V to 4V) Foaming compound creams A2V to A4V and whipped compound creams A2V to A4V
Foamable compound creams A2V to A4V and whipped compound creams A2V to A4V were obtained in the same manner as in Example 1V, except that the foamable oil-in-water emulsified oil composition A1 was changed to the foamable oil-in-water emulsified oil compositions A2 to A4. The obtained foamable compound creams A2V to A4V and whipped compound creams A2V to A4V were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed)), and the results are summarized in Table 8.
(比較例1V~2V)起泡性コンパウンドクリームB1V~B2V及びホイップドコンパウンドクリームB1V~B2V
起泡性水中油型乳化油脂組成物A1を、起泡性水中油型乳化油脂組成物B1~B2に変えた以外は、実施例1Vと同様にして起泡性コンパウンドクリームB1V~B2V及びホイップドコンパウンドクリームB1V~B2Vを得た。得られた起泡性コンパウンドクリームB1V~B2V及びホイップドコンパウンドクリームB1V~B2Vの評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ))を行い、それらの結果を表8にまとめた。なお、ホイップドコンパウンドクリームB2Vの口溶け(早さ)を、ホイップドコンパウンドクリームA1V~A4V及びB1Vの口溶け(早さ)を評価する時の基準値(3.0点)とした。
(Comparative Examples 1V to 2V) Foaming compound creams B1V to B2V and whipped compound creams B1V to B2V
Foamable compound creams B1V to B2V and whipped compound creams B1V to B2V were obtained in the same manner as in Example 1V, except that the foamable oil-in-water emulsified oil composition A1 was changed to foamable oil-in-water emulsified oil compositions B1 to B2. The obtained foamable compound creams B1V to B2V and whipped compound creams B1V to B2V were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed)), and the results are summarized in Table 8. The melting in the mouth (speed) of whipped compound cream B2V was set as the standard value (3.0 points) when evaluating the melting in the mouth (speed) of whipped compound creams A1V to A4V and B1V.
表8にまとめた結果より、以下のことがわかった。実施例1V~4V及び比較例1V~2Vより、乳脂肪を含むコンパウンドクリームが本発明の効果を奏するには、油脂B/(油脂A+油脂B)(重量比)は0.37~0.5が好適であり、前記重量比を外れると、ホイップ後の硬さが損なわれる場合があることが明らかとなった。 The results summarized in Table 8 reveal the following. From Examples 1V to 4V and Comparative Examples 1V to 2V, it became clear that for a compound cream containing milk fat to achieve the effects of the present invention, a weight ratio of fat B/(fat A + fat B) of 0.37 to 0.5 is suitable, and that deviations from this weight ratio may impair the firmness after whipping.
(実施例2W~2Z)起泡性コンパウンドクリームA2W~A2Z及びホイップドコンパウンドクリームA2W~A2Z
実施例2で得られた起泡性水中油型乳化油脂組成物A2と生クリーム(乳脂肪分:43%)との重量比をそれぞれ90:10(実施例2W)、80:20(実施例2X)、58:42(実施例2Y)、又は、30:70(実施例2Z)に変えた以外は、実施例2Vと同様にして起泡性コンパウンドクリームA2W~A2Z及びホイップドコンパウンドクリームA2W~A2Zを得た。得られた起泡性コンパウンドクリームA2W~A2Z及びホイップドコンパウンドクリームA2W~A2Zの評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ))を行い、それらの結果を表9にまとめた。
(Examples 2W to 2Z) Foaming compound creams A2W to A2Z and whipped compound creams A2W to A2Z
Foamable compound creams A2W to A2Z and whipped compound creams A2W to A2Z were obtained in the same manner as in Example 2V, except that the weight ratio of the foamable oil-in-water emulsified oil composition A2 obtained in Example 2 to fresh cream (milk fat content: 43%) was changed to 90:10 (Example 2W), 80:20 (Example 2X), 58:42 (Example 2Y), or 30:70 (Example 2Z). The obtained foamable compound creams A2W to A2Z and whipped compound creams A2W to A2Z were evaluated (stability of concentrate, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed)), and the results are summarized in Table 9.
(比較例2W~2Z)起泡性コンパウンドクリームB2W~B2Z及びホイップドコンパウンドクリームB2W~B2Z
比較例2で得られた起泡性水中油型乳化油脂組成物B2と生クリーム(乳脂肪分:43%)との重量比をそれぞれ90:10(比較例2W)、80:20(比較例2X)、58:42(比較例2Y)、又は、30:70(比較例2Z)に変えた以外は、比較例2Vと同様にして起泡性コンパウンドクリームB2W~B2Z及びホイップドコンパウンドクリームB2W~B2Zを得た。得られた起泡性コンパウンドクリームB2W~B2ZとホイップドコンパウンドクリームB2W~B2Zの評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ))を行い、それらの結果を表9にまとめた。なお、ホイップドコンパウンドクリームB2W~B2Zの口溶け(早さ)を、コンパウンド比率が同等のホイップドコンパウンドクリームA2W~A2Zの口溶け(早さ)を評価する時の基準値(3.0点)とした。
(Comparative Examples 2W to 2Z) Foaming compound creams B2W to B2Z and whipped compound creams B2W to B2Z
Foamable compound creams B2W to B2Z and whipped compound creams B2W to B2Z were obtained in the same manner as in Comparative Example 2V, except that the weight ratio of the foamable oil-in-water emulsified oil composition B2 obtained in Comparative Example 2 to fresh cream (milk fat content: 43%) was changed to 90:10 (Comparative Example 2W), 80:20 (Comparative Example 2X), 58:42 (Comparative Example 2Y), or 30:70 (Comparative Example 2Z). The obtained foamable compound creams B2W to B2Z and whipped compound creams B2W to B2Z were evaluated (stability of concentrate, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed)), and the results are summarized in Table 9. The melting speed (speed) of the whipped compound creams B2W to B2Z was set as the standard value (3.0 points) when evaluating the melting speed (speed) of the whipped compound creams A2W to A2Z, which have the same compound ratio.
表9にまとめた結果より、以下のことがわかった。実施例2V~2Zより、油脂全体中の乳脂肪含量が83重量%以下の範囲で乳脂肪を含むコンパウンドクリームは本発明の効果を奏することが明らかとなった。
The results summarized in Table 9 reveal the following: Examples 2V to 2Z reveal that the compound cream containing milk fat in a range in which the milk fat content in the total fats and oils is 83% by weight or less can achieve the effects of the present invention.
Claims (5)
起泡性水中油型乳化油脂組成物の水相中に乳化剤Aを、起泡性水中油型乳化油脂組成物全体中0.01~0.7重量%含有し、
前記油脂全体中、エステル交換油脂含量が1重量%未満、乳脂肪含量が83重量%以下であり、
前記油脂の内、前記乳脂肪を除く油脂全体中、油脂A及び油脂Bの合計含量が80~100重量%であり、油脂B/(油脂A+油脂B)(重量比)が0.37~0.5である、
起泡性水中油型乳化油脂組成物。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。 The foamable oil-in-water emulsified oil composition as a whole contains 25 to 50% by weight of oil and phosphate in an amount of less than 0.02% by weight,
The aqueous phase of the foamable oil-in-water emulsified oil composition contains emulsifier A in an amount of 0.01 to 0.7% by weight based on the entire foamable oil-in-water emulsified oil composition;
In the total oil and fat, the interesterified oil and fat content is less than 1% by weight, and the milk fat content is 83% by weight or less,
Among the fats and oils, the total content of fats and oils A and B in the entire fats and oils excluding the milk fat is 80 to 100% by weight, and the weight ratio of fats and oils B/(fat and oil A + fat and oil B) is 0.37 to 0.5;
Foaming oil-in-water emulsified fat composition.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
起泡性水中油型乳化油脂組成物全体中、乳化剤A含量が0.01~0.7重量%となるように乳化剤Aを水に添加して撹拌しながら溶解した水相部に、前記起泡性水中油型乳化油脂組成物の油脂全体中、油脂Aと油脂Bの合計含量が80~100重量%且つ油脂B/(油脂A+油脂B)(重量比)が0.37~0.5となるように油脂A及び油脂Bを混合した油脂混合物を添加し、予備乳化した後、微細化し、さらに高圧処理して得た起泡性水中油型乳化油脂組成物に、前記起泡性コンパウンドクリームの油脂全体中の乳脂肪含量が83重量%以下になるように生クリームを混合・撹拌することを特徴とする、起泡性コンパウンドクリームの製造方法。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。 A method for producing a foaming compound cream, the foaming compound cream having a fat content of 25 to 50% by weight, a phosphate content of less than 0.02% by weight, and an interesterified fat content of less than 1% by weight of the total fat content, comprising:
A method for producing a foamable compound cream, comprising the steps of: adding emulsifier A to water so that the emulsifier A content in the entire foamable oil-in-water emulsified oil composition is 0.01 to 0.7% by weight; stirring and dissolving the emulsifier in an aqueous phase; adding an oil mixture obtained by mixing oils A and B so that the total content of oils A and B in the entire oils and fats of the foamable oil-in-water emulsified oil composition is 80 to 100% by weight and the weight ratio of oils B/(oils A + oils B) is 0.37 to 0.5; pre-emulsifying the mixture, pulverizing the mixture, and subjecting the mixture to high pressure treatment to obtain a foamable oil-in-water emulsified oil composition; and mixing and stirring fresh cream with the resulting foamable oil-in-water emulsified oil composition so that the milk fat content in the entire oils and fats of the foamable compound cream is 83% by weight or less.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
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