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JP7584733B2 - Crushing and drying equipment, carbonization equipment and systems - Google Patents
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JP7584733B2 - Crushing and drying equipment, carbonization equipment and systems - Google Patents

Crushing and drying equipment, carbonization equipment and systems Download PDF

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JP7584733B2
JP7584733B2 JP2021158446A JP2021158446A JP7584733B2 JP 7584733 B2 JP7584733 B2 JP 7584733B2 JP 2021158446 A JP2021158446 A JP 2021158446A JP 2021158446 A JP2021158446 A JP 2021158446A JP 7584733 B2 JP7584733 B2 JP 7584733B2
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康晴 川端
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Description

本発明は、地球温暖化原因物質の二酸化炭素発生源となる、炭素を含む有機物を、再生可能エネルギーを活用して効率よく連続的に炭化したり、半炭化固形物として回収する方法と、この方法を適用した、再生可能エネルギー活用型の有機物炭化システムに関するものである。The present invention relates to a method for efficiently and continuously carbonizing carbon-containing organic matter, which is a source of carbon dioxide, a substance that causes global warming, using renewable energy, or recovering it as semi-carbonized solid matter, and to a renewable energy-based organic matter carbonization system to which this method is applied.

地球温暖化の防止にむけて、主要な原因物質となっている二酸化炭素の排出削減や、大気中に蓄積された二酸化炭素の分離回収と地下圧入による固定化が実施されつつある。特に、バイオマス資源を燃焼利用した際に発生する排気ガス中の二酸化炭素や、大気中の二酸化炭素を分離回収して固定化する技術は、大気中に蓄積された二酸化炭素の積極的な削減に資するネガティブエミッション技術として、社会実装と普及拡大が期待されている。To prevent global warming, efforts are being made to reduce emissions of carbon dioxide, which is the main cause of global warming, and to separate and capture carbon dioxide accumulated in the atmosphere and fix it by injecting it underground. In particular, technology to separate and capture and fix carbon dioxide in exhaust gases generated when biomass resources are burned and carbon dioxide in the atmosphere is expected to be implemented in society and become more widespread as a negative emission technology that contributes to the active reduction of carbon dioxide accumulated in the atmosphere.

一方、排気ガスや大気中からの分離回収した気体の二酸化炭素は、化学的な安定性が高く分解が困難なため、地下深部に圧入固定させる際には、圧縮液化して地下貯留サイトまで輸送し、地下深部に圧入するために、液化二酸化炭素をさらに圧縮する必要があり、多大なエネルギー消費と、そのエネルギー消費に伴う二酸化炭素の排出によってコストが嵩み、正味の二酸化炭素固定化量も減少するという課題がある。On the other hand, carbon dioxide gas separated and captured from exhaust gases and the atmosphere is highly chemically stable and difficult to decompose, so when it is injected and fixed deep underground, it must be compressed and liquefied, transported to an underground storage site, and then further compressed in order to be injected deep underground. This poses the issue of increased costs due to the huge amount of energy consumption and the carbon dioxide emissions associated with that energy consumption, as well as a reduction in the net amount of carbon dioxide fixed.

また、二酸化炭素を長期安定的に地下貯留できる場所や、各貯留場所によって、圧入固定できる量が限定されるため、圧入量が限度に達すれば、二酸化炭素を輸送できても、圧入による固定化そのものが不可能となるという課題もある。In addition, there are limitations on the locations where carbon dioxide can be stored underground stably for the long term, and on the amount that can be injected and fixed, depending on each storage location. Therefore, once the injection amount reaches its limit, even if the carbon dioxide can be transported, it will become impossible to fix it by injection.

そこで、これらの課題を解決する手段として、二酸化炭素排出の原因物質となる有機物を炭化して固体炭素として回収し、回収した固体炭素を地中埋設したり沿岸埋立等に活用し、酸素や微生物等と接触しない措置を講じた上で長期保管することで、廃プラスチック等の化石燃料起源の有機物を焼却することによる二酸化炭素の排出量を削減したり、草木剪定枝や食品廃棄物、下水汚泥等のバイオマス起源の有機物を焼却処分する際の二酸化炭素排出を防止することで、ネガティブエミッションを実現することも可能である。Therefore, as a means of solving these problems, organic matter that causes carbon dioxide emissions can be carbonized and recovered as solid carbon, and the recovered solid carbon can be buried underground or used for coastal landfill, and stored for a long period of time after taking measures to prevent it from coming into contact with oxygen, microorganisms, etc., thereby reducing carbon dioxide emissions caused by incinerating organic matter of fossil fuel origin such as waste plastics, and preventing carbon dioxide emissions when incinerating organic matter of biomass origin such as pruned branches of vegetation, food waste, and sewage sludge, thereby achieving negative emissions.

また、固体炭素を含む炭素系材料には、軽量かつ高強度な炭素繊維や、高い耐熱性と熱伝導性を有するシリコンカーバイド、高い吸着性を有する活性炭などが、様々な分野で利用されており、こうした機能性材料の製造原料として回収した固体炭素を利用し、製造された炭素含有材料が長期にわたって利用され続ければ、二酸化炭素の排出を抑制しながら、高機能材料を長期利用することも可能となる。Furthermore, carbon-based materials containing solid carbon are used in a variety of fields, including lightweight, high-strength carbon fiber, silicon carbide with high heat resistance and thermal conductivity, and activated carbon with high adsorption properties. If recovered solid carbon could be used as a raw material for producing such functional materials and the produced carbon-containing materials could be used over the long term, it would be possible to use highly functional materials for a long period of time while suppressing carbon dioxide emissions.

以上の観点から、廃プラスチックや廃タイヤといった、化石燃料起源の炭素を含む廃棄物のほか、草木剪定枝や下水汚泥等のバイオマス起源の炭素を含む廃棄物を焼却処理することなく炭化させて、固体炭素として回収し、炭素系材料の原料として有効利用する技術も期待されている。From the above perspective, there are hopes for technology that can carbonize waste containing carbon from fossil fuels, such as waste plastics and tires, as well as waste containing carbon from biomass sources, such as pruned branches of vegetation and sewage sludge, without incineration, recover it as solid carbon, and effectively use it as a raw material for carbon-based materials.

一方、有機物を含む多様な廃棄物の炭化処理については、様々な技術や装置が提案されており、低酸素環境下で伝熱面からの伝熱や輻射によって有機物を揮発させて炭化を進める際に、生ゴミのような含水率の高い廃棄物を乾燥した上で昇温して炭化させる技術(特許文献1)や、バイオマスを高温ガスと接触させ、熱分解して炭化物を生成する技術(特許文献2)が開示されている。Meanwhile, various technologies and devices have been proposed for the carbonization of various types of waste, including organic matter. Disclosed are a technology in which waste with a high moisture content, such as food waste, is dried and then heated to carbonize it when carbonization is promoted by volatilizing organic matter through heat transfer or radiation from a heat transfer surface in a low-oxygen environment (Patent Document 1), and a technology in which biomass is brought into contact with high-temperature gas and pyrolyzed to produce a charcoal (Patent Document 2).

また、有機物で構成される多様な廃棄物を燃料として再利用する際には、廃棄物中の過剰な水分を高温の空気や燃焼ガスによって脱水乾燥蒸発させ、炭化させずに廃棄物起源の燃料成分となる有機物を多く残すことでエネルギー密度を最大化する半炭化処理が行われることが多く、バイオマスの水分が蒸発しやすい負圧条件下で酸素濃度が低い燃焼排ガスを廃棄物に吹き付けてバイオマスを半炭化させる技術(特許文献3)や、空気の侵入を遮断した低酸素環境や無酸素環境下でバイオマスを昇温し、発生する熱分解ガスを燃焼させて得られる熱を利用して廃棄物の半炭化を行う技術(特許文献4)のほか、有機物を密閉状態で加熱しながら圧縮して半炭化固形物を生成した後、生成した半炭化固形物を冷却することで、緻密なバイオマス固形物を製造する技術(特許文献5)も開示されている。Furthermore, when various waste materials composed of organic matter are reused as fuel, a semi-carbonization process is often performed in which excess moisture in the waste material is dehydrated, dried, and evaporated using high-temperature air or combustion gas, and the waste material is not carbonized, leaving behind a large amount of organic matter that becomes a fuel component originating from the waste material, thereby maximizing the energy density. Examples of such a process include a technology for semi-carbonizing biomass by blowing combustion exhaust gas with a low oxygen concentration onto the waste material under negative pressure conditions in which moisture in the biomass is likely to evaporate (Patent Document 3), a technology for heating biomass in a low-oxygen or oxygen-free environment where air intrusion is blocked, and using the heat obtained by burning the generated pyrolysis gas to semi-carbonize the waste material (Patent Document 4), and a technology for producing dense biomass solid material by compressing organic matter in a sealed state while heating it to generate a semi-carbonized solid material, and then cooling the generated semi-carbonized solid material (Patent Document 5).

特開2014-234948号JP 2014-234948 A 特開2013-216780号JP 2013-216780 A 特開2019-45078号JP 2019-45078 A 特開2018-115307号JP 2018-115307 A 特許第4088933号Patent No. 4088933

前記の通り、特許文献に示された従来技術によれば、二酸化炭素の排出起源となる有機物で構成される廃棄物から、活性炭等の高機能材料や炭素系材料の原料に利用できる固体炭素を回収したり、含水率が高い廃棄物であっても、廃棄物を効率よく乾燥させて昇温することで、炭化水素の密度を高めた半炭化固形物を製造することができるが、これらの技術には以下に示す5つの課題がある。As described above, according to the conventional technologies shown in the patent documents, it is possible to recover solid carbon that can be used as a raw material for high-performance materials such as activated carbon or carbon-based materials from waste composed of organic matter that is the source of carbon dioxide emissions, and it is possible to produce semi-carbonized solids with increased hydrocarbon density by efficiently drying and heating even waste with a high moisture content. However, these technologies have the following five problems.

まず従来の技術では、寸法の大きな廃棄物を乾燥させたり半炭化または炭化させる際に必要となる廃棄物の破砕や粉砕に係わる記述がなく、予め破砕、粉砕された廃棄物の投入と搬送による攪拌と乾燥を前提としており、廃棄物処理の工程で大きなエネルギー消費を伴う破砕や粉砕に係わるエネルギー消費の効率化と、エネルギー消費に伴う二酸化炭素排出量の削減にむけた解決策が開示されていない。特に大型で含水率の高い廃棄物を効率よく乾燥させたり、半炭化や炭化を行う上では、廃棄物を早期に破砕しながら加熱乾燥を同時に行って含水率を低下させて、さらに廃棄物を破砕しやすくすることで、効率的に廃棄物の破砕乾燥を実現することができるが、破砕工程と攪拌乾燥工程が分かれて実施される場合には装置が大型化し、大きな設置面積が必要となるという課題もある。First, the conventional technology does not describe the crushing or pulverization of waste, which is necessary when drying or semi-carbonizing or carbonizing large waste, and assumes that pre-crushed or crushed waste is input and transported for stirring and drying, and does not disclose any solutions to improve the efficiency of energy consumption involved in crushing and pulverization, which involves a large amount of energy consumption in the waste treatment process, and to reduce carbon dioxide emissions associated with energy consumption. In particular, when efficiently drying large waste with a high moisture content, or semi-carbonizing or carbonizing it, efficient crushing and drying of the waste can be achieved by crushing the waste early and heating and drying it at the same time to reduce the moisture content and make the waste easier to crush, but when the crushing process and the stirring and drying process are performed separately, there is also the problem that the equipment becomes large and a large installation area is required.

また、廃棄物の破砕や攪拌、乾燥と、半炭化および炭化を行う各工程では、モーターやブロワ等の電動機器が使用されているが、これらの機器を稼働させる電力が再生可能エネルギーによるものでない場合には、装置の稼働に伴って二酸化炭素が発生し、正味の二酸化炭素削減効果が低減するほか、電力消費に伴うコストが嵩むという課題がある。In addition, electric equipment such as motors and blowers are used in the processes of crushing, mixing, drying, and semi-carbonizing and carbonizing the waste. If the electricity used to operate this equipment is not derived from renewable energy sources, carbon dioxide is generated as the equipment operates, reducing the net carbon dioxide reduction effect and raising the issue of increased costs associated with electricity consumption.

また、本技術を構成する機器の駆動電力を、全て再生可能エネルギー起源の電力受給によって賄う場合であっても、再生可能エネルギーの発生場所で得られる回転駆動力や再生可能エネルギー熱を直接利用することができないために、発生場所で得られる回転駆動力を電力に変換する発電損失や得られた電力を消費地に送る際の送電損失が発生してエネルギー効率が低下するほか、再生可能エネルギー由来の冷温熱を直接利用することが困難となる課題がある。Furthermore, even if the driving power of the equipment that makes up this technology is entirely covered by receiving electricity of renewable energy origin, it is not possible to directly use the rotational driving force or renewable energy heat obtained at the renewable energy generation site, which results in power generation losses when converting the rotational driving force obtained at the generation site into electricity and transmission losses when sending the obtained electricity to the consumption site, resulting in reduced energy efficiency. In addition, there is the issue that it is difficult to directly use the hot and cold energy derived from renewable energy.

一方、昼夜や天候を問わず安定的に再生可能エネルギー起源の電気や熱を得られる地熱地帯や水力発電地帯は、送配電網が整備されていなかったり、送配電線の容量が少ない山間地域であることが多いため、常時安定的に活用できる再生可能エネルギー資源が豊富に存在していても、これを有効活用できなかったり、活用可能量が限定されるという課題があるが、こうした地域における再生可能エネルギーを廃棄物処理や二酸化炭素の削減に活用する具体的な方策が開示されていない。On the other hand, geothermal and hydroelectric power generation areas, where electricity and heat from renewable energy sources can be obtained stably regardless of day or night or weather, are often located in mountainous regions where the transmission and distribution grid is not well developed or the capacity of the transmission and distribution lines is low. As a result, even if there are abundant renewable energy resources that can be used stably at all times, they cannot be used effectively or the amount that can be used is limited. No specific measures have been disclosed for using renewable energy in such areas for waste treatment or carbon dioxide reduction.

加えて、生ゴミや漁業廃棄物、下水汚泥といった、含水率が高い有機廃棄物を乾燥する際には、廃棄物の加熱による廃棄物中の水分蒸発による脱水乾燥のために多大なエネルギーを必要とするため、有機廃棄物の熱分解によって得られる熱分解ガスの燃焼ガスから得られる熱だけでは賄いきれない場合があり、廃棄物の乾燥処理や乾燥前の予熱のために、補助燃料として化石燃料を使用する場合には、化石燃料の利用に伴って二酸化炭素が発生し、正味の二酸化炭素削減効果が低減するとともに、化石燃料の利用に伴うコストが嵩むという課題もある。In addition, when drying organic waste with a high moisture content, such as food waste, fishery waste, and sewage sludge, a huge amount of energy is required to dehydrate and dry the waste by heating it and evaporating the water in it. In some cases, this cannot be met with just the heat obtained from the combustion gas of the pyrolysis gas obtained by the thermal decomposition of the organic waste. When fossil fuels are used as auxiliary fuels for drying the waste or for preheating before drying, carbon dioxide is generated as a result of the use of fossil fuels, which reduces the net carbon dioxide reduction effect and increases the costs associated with using fossil fuels.

本発明は上記の課題に鑑みてなされたものであり、その目的は、地熱蒸気や水力といった、常時安定的に活用できる再生可能エネルギーから得られる回転駆動力や、地熱蒸気が保有する再生可能エネルギー熱を直接または間接的に、有機物の破砕と攪拌乾燥のほか、半炭化や炭化の工程にも活用し、これらの処理を一貫して効率よく実施できる再生可能エネルギー活用型の炭素回収方法を提供するとともに、発明技術を適用した、再生可能エネルギー活用型の炭素回収システムを提供することである。The present invention has been made in consideration of the above-mentioned problems, and its purpose is to provide a renewable energy-based carbon recovery method that can consistently and efficiently carry out all of these processes by directly or indirectly using rotational driving force obtained from renewable energy sources that can be used stably at all times, such as geothermal steam and hydropower, and the renewable energy heat contained in geothermal steam, for crushing, stirring and drying of organic matter, as well as for the semi-carbonization and carbonization processes, and to provide a renewable energy-based carbon recovery system that applies the technology of the invention.

請求項1に記載の発明は、有機物を破砕乾燥すると共に加熱して半炭化する破砕乾燥装置であって、有機物が投入される投入部と半炭化された当該有機物が排出される排出部とを有する筐体と、前記筐体内部で回転可能に設けられた回転軸と、を備え、前記筐体は、破砕加熱板が設けられた内殻と、前記内殻の外側に設けられた外殻と、を備えた二重殻構造であり、前記内殻と前記外殻との間に、前記投入部から前記排出部へ至り前記有機物が通る螺旋流路が形成され、前記螺旋流路は、前記排出部側から前記投入部側へ向かって徐々に流路幅が大きくなるように構成され、前記回転軸には、当該回転軸の回転に伴って回転することにより前記有機物を搬送する破砕搬送板が設けられていることを特徴とする。The invention described in claim 1 is a crushing and drying device that crushes and dries organic matter and heats it to semi-carbonize it, comprising a housing having an input section into which the organic matter is input and an output section from which the semi-carbonized organic matter is output, and a rotating shaft rotatably arranged inside the housing, the housing having a double-shell structure comprising an inner shell in which a crushing heating plate is provided and an outer shell provided on the outside of the inner shell, a spiral flow path through which the organic matter passes from the input section to the output section is formed between the inner shell and the outer shell, the spiral flow path is configured so that the flow path width gradually increases from the output section side to the input section side, and the rotating shaft is provided with a crushing and transport plate that rotates in conjunction with the rotation of the rotating shaft to transport the organic matter.
請求項2に記載の発明は、前記破砕加熱板と前記破砕搬送板との隙間が、前記螺旋流路における前記投入部側ほど大きく、前記排出部側ほど小さくなるように、当該破砕加熱板および当該破砕搬送板が配置されていることを特徴とする。The invention described in claim 2 is characterized in that the crushing heating plate and the crushing transport plate are arranged so that the gap between them is larger toward the input section side in the spiral flow path and smaller toward the discharge section side.
請求項3に記載の発明は、高温蒸気を、前記螺旋流路における前記排出部側から供給し、前記投入部側から排出させることにより、当該螺旋流路を通る前記有機物を加熱することを特徴とする。The invention described in claim 3 is characterized in that high-temperature steam is supplied from the discharge side of the spiral flow path and discharged from the input side, thereby heating the organic matter passing through the spiral flow path.
請求項4に記載の発明は、排出する前記有機物を、最終粒子径を5mm以下とし、含水率を15%以下とすることを特徴とする。The invention described in claim 4 is characterized in that the organic matter to be discharged has a final particle size of 5 mm or less and a moisture content of 15% or less.
請求項5に記載の発明は、排出する前記有機物の含水率が15%以下となるよう、当該有機物への加熱量を制御することを特徴とする。The invention described in claim 5 is characterized in that the amount of heat applied to the organic matter to be discharged is controlled so that the moisture content of the organic matter to be discharged is 15% or less.
請求項6に記載の発明は、前記有機物を5~30MPaの範囲で圧縮するとともに、100~450℃の範囲で加熱することを特徴とする。The invention described in claim 6 is characterized in that the organic matter is compressed in the range of 5 to 30 MPa and heated in the range of 100 to 450°C.
請求項7に記載の発明は、前記有機物の温度が100~450℃となるよう、当該有機物への加熱量を制御することを特徴とする。The invention described in claim 7 is characterized in that the amount of heat applied to the organic matter is controlled so that the temperature of the organic matter is 100 to 450°C.
請求項8に記載の発明は、半炭化された有機物を加熱して炭化する炭化装置であって、前記半炭化された有機物の入口と加熱後の炭化物の出口とを有する筐体と、前記筐体内部で回転可能に設けられた回転軸と、を備え、前記筐体は、圧縮加熱板が設けられた内殻と、前記内殻の外側に設けられた外殻と、を備えた二重殻構造であり、前記内殻と前記外殻との間に、前記入口から前記出口へ至り前記半炭化された有機物が通る螺旋流路が形成され、前記螺旋流路は、前記出口側から前記入口側へ向かって徐々に流路幅が大きくなるように構成され、前記回転軸には、当該回転軸の回転に伴って回転することにより前記半炭化された有機物を搬送する圧縮搬送板が設けられていることを特徴とする。The invention described in claim 8 is a carbonization device that heats and carbonizes semi-carbonized organic matter, comprising a housing having an inlet for the semi-carbonized organic matter and an outlet for the heated carbonized material, and a rotating shaft rotatably arranged inside the housing, the housing having a double shell structure comprising an inner shell in which a compression heating plate is provided and an outer shell provided on the outside of the inner shell, a spiral flow path through which the semi-carbonized organic matter passes from the inlet to the outlet is formed between the inner shell and the outer shell, the spiral flow path is configured so that the flow path width gradually increases from the outlet side to the inlet side, and the rotating shaft is provided with a compression conveying plate that rotates in conjunction with the rotation of the rotating shaft to convey the semi-carbonized organic matter.
請求項9に記載の発明は、高温蒸気を、前記螺旋流路における前記出口側から供給し、前記入口側から排出させることにより、当該螺旋流路を通る前記半炭化された有機物を加熱することを特徴とする。The invention described in claim 9 is characterized in that high-temperature steam is supplied from the outlet side of the spiral flow path and discharged from the inlet side, thereby heating the torrefied organic matter passing through the spiral flow path.
請求項10に記載の発明は、前記半炭化された有機物を450~700℃の範囲で加熱することを特徴とする。The invention described in claim 10 is characterized in that the semi-carbonized organic matter is heated in the range of 450 to 700°C.
請求項11に記載の発明は、前記半炭化された有機物の温度が450~700℃となるよう、当該半炭化された有機物への加熱量を制御することを特徴とする。The invention described in claim 11 is characterized in that the amount of heat applied to the semi-carbonized organic matter is controlled so that the temperature of the semi-carbonized organic matter is 450 to 700°C.
請求項12に記載の発明は、請求項1から請求項3のいずれか一つに記載された破砕乾燥装置と、前記破砕乾燥装置により半炭化された有機物を炭化する請求項8または請求項9に記載された炭化装置と、前記炭化装置により炭化された生成物を冷却する冷却装置と、を備え、前記冷却装置は、前記炭化装置の生成物の入口と冷却後の当該生成物の出口とを有する筐体と、前記筐体内部で回転可能に設けられた回転軸と、を備え、前記筐体は、内殻と外殻とを備えた二重殻構造であり、前記内殻と前記外殻との間に、前記入口から前記出口へ至る螺旋流路が形成され、前記回転軸には、当該回転軸の回転に伴って回転することにより前記生成物を搬送する圧縮搬送板が設けられており、前記螺旋流路を冷却水が通ることにより、前記内殻の内部を通る前記生成物を冷却することを特徴とする。The invention described in claim 12 comprises a crushing and drying apparatus described in any one of claims 1 to 3, a carbonization apparatus described in claim 8 or claim 9 for carbonizing organic matter semi-carbonized by the crushing and drying apparatus, and a cooling apparatus for cooling a product carbonized by the carbonization apparatus, wherein the cooling apparatus comprises a housing having an inlet for the product of the carbonization apparatus and an outlet for the product after cooling, and a rotating shaft rotatably arranged inside the housing, the housing having a double shell structure comprising an inner shell and an outer shell, a spiral flow path from the inlet to the outlet is formed between the inner shell and the outer shell, the rotating shaft is provided with a compression conveying plate that rotates in conjunction with the rotation of the rotating shaft to convey the product, and the product passing inside the inner shell is cooled by cooling water passing through the spiral flow path.
請求項13に記載の発明は、前記冷却装置は、前記炭化装置の生成物の温度が15~85℃の範囲となるよう冷却することを特徴とする。The invention described in claim 13 is characterized in that the cooling device cools the product of the carbonization device so that the temperature of the product is in the range of 15 to 85°C.
請求項14に記載の発明は、前記炭化装置の生成物の温度が15~85℃の範囲となるよう、前記冷却装置による当該生成物に対する冷却量を制御することを特徴とする。The invention described in claim 14 is characterized in that the amount of cooling of the product by the cooling device is controlled so that the temperature of the product of the carbonization device is in the range of 15 to 85°C.

本発明によれば、地熱蒸気や水力といった、常時安定的に得られる再生可能エネルギーから得られる回転駆動力や温冷熱と電力を、直接または間接的に有機物の破砕乾燥や半炭化処理または炭化処理に利用することで、有機物起源の半炭化固形物や固体炭素回収に係わる化石燃料の消費を削減し、二酸化炭素の排出を抑制しながら、容易に輸送や貯留が可能な半炭化固形物や固体炭素を回収したり、炭素を長期固定しながら利用できる炭素系材料を製造する際に必要となる、原料炭素を回収することが可能となる。According to the present invention, by directly or indirectly utilizing the rotational driving force, hot and cold energy, and electricity obtained from renewable energy sources that can be obtained stably at all times, such as geothermal steam and hydraulic power, for the crushing, drying, semi-carbonization, or carbonization of organic matter, it is possible to reduce the consumption of fossil fuels involved in the recovery of semi-carbonized solids and solid carbon originating from organic matter, and to recover semi-carbonized solids and solid carbon that can be easily transported and stored while suppressing carbon dioxide emissions, and to recover raw carbon that is necessary for producing carbon-based materials that can be used while fixing carbon for a long period of time.

本発明に係る第1実施形態である、地熱エネルギー活用型の炭素回収システムを示す模式図である。1 is a schematic diagram showing a geothermal energy-utilizing carbon recovery system according to a first embodiment of the present invention; 本発明に係る第2実施形態である、水力エネルギー活用型の半炭化固形物回収システムを示す模式図である。FIG. 11 is a schematic diagram showing a torrefied solid recovery system that utilizes hydraulic energy according to a second embodiment of the present invention.

以下、図面を参照して本発明を実施するための最良の形態について説明する。なお、本発明の範囲は特許請求の範囲記載のものであって、本実施形態に限定されるものではない。Hereinafter, the best mode for carrying out the present invention will be described with reference to the drawings. Note that the scope of the present invention is defined by the claims and is not limited to the present embodiment.

(第1実施形態)First Embodiment

まず本発明の第1実施形態に係る、地熱エネルギー活用型の炭素回収システムについて、図1に基づいて説明する。First, a geothermal energy-utilizing carbon recovery system according to a first embodiment of the present invention will be described with reference to FIG.

図1に示すように、このシステムには、地熱流体1を100℃~180℃程度の地熱蒸気と、100℃未満の熱水に分離する汽水分離器2と、前記汽水分離器から排出された地熱蒸気で駆動される蒸気タービン3と、この蒸気タービンの回転軸に変速機4を介して接続されて回転する動翼状の破砕板が固定され、投入有機物5の破砕乾燥処理を行う破砕乾燥装置6と、前記破砕乾燥装置で破砕乾燥された有機物が加熱されて半炭化された後に、生成した半炭化物をさらに加熱して炭化させる、破砕乾燥有機物の炭化装置7と、前記炭化装置で生成された有機物起源の炭素を冷却し、常温での回収を可能とする、炭素冷却装置8が構成されている。As shown in FIG. 1, this system includes a steam separator 2 that separates geothermal fluid 1 into geothermal steam of about 100°C to 180°C and hot water of less than 100°C, a steam turbine 3 driven by the geothermal steam discharged from the steam separator, a crushing and drying device 6 having a rotating blade-shaped crushing plate fixed to the rotating shaft of the steam turbine via a transmission 4 and performing a crushing and drying process for input organic matter 5, a crushed and dried organic matter carbonization device 7 that heats and semi-carbonizes the organic matter crushed and dried in the crushing and drying device, and then further heats and carbonizes the semi-carbonized material produced, and a carbon cooling device 8 that cools the organic matter-derived carbon produced in the carbonization device, enabling it to be recovered at room temperature.

また、地熱蒸気タービン3の回転軸には、地熱蒸気で発電を行う蒸気タービン発電機9が接続され、この発電機で得られた電力は、有機物の加熱乾燥を確実かつ均一に行うために、破砕乾燥装置の出口部分に設置された電熱ヒータ10と、破砕乾燥有機物を確実かつ均一に炭化するために炭化装置の出口部分に設置された電熱ヒータ11に電力を供給するとともに、有機物の加熱乾燥時に有機物から発生する水蒸気含有ガスの臭気成分を除去する、オゾナイザ等のガス浄化装置12と、破砕乾燥装置内を減圧化するために水蒸気含有ガスを強制排気するための排気ブロワ13や、有機物を加熱して半炭化および炭化させる過程で有機物から発生する熱分解ガスを燃焼させるための空気を吸い込み、熱分解ガス燃焼装置14で燃焼させた高温の燃焼ガスを炭化装置に送出させる、空気ブロワ15に供給されるよう構成されている。In addition, a steam turbine generator 9 that generates electricity using geothermal steam is connected to the rotating shaft of the geothermal steam turbine 3, and the electricity generated by this generator is supplied to an electric heater 10 installed at the outlet of the crushing and drying apparatus to ensure uniform heating and drying of the organic matter, and an electric heater 11 installed at the outlet of the carbonization apparatus to ensure uniform carbonization of the crushed and dried organic matter, as well as to a gas purifying device 12 such as an ozonizer that removes odorous components from the water vapor-containing gas generated from the organic matter when the organic matter is heated and dried, an exhaust blower 13 that forcibly exhausts the water vapor-containing gas to reduce the pressure inside the crushing and drying apparatus, and an air blower 15 that draws in air for burning the pyrolysis gas generated from the organic matter in the process of heating the organic matter to semi-carbonize and carbonize it, and sends the high-temperature combustion gas burned in the pyrolysis gas combustion device 14 to the carbonization apparatus.

さらに、蒸気タービン発電機9から得られる電力は、炭素冷却装置8で炭素を冷却する冷却水の循環ポンプ16や、循環冷却水の冷熱を得るために、汽水分離器2で分離された熱水を利用して駆動する吸収式冷凍機17と、その附帯設備となる冷却塔18や、冷却塔用冷却水の循環ポンプ19のほか、破砕乾燥装置における有機物の加熱乾燥熱源として供給する地熱発電後の蒸気から、加熱乾燥熱交換時に発生するドレン水を排水するポンプ20や、炭化装置において破砕乾燥有機物を加熱する熱源として供給する燃焼ガスを利用した熱交換時に発生するドレン水を浄化する排水浄化装置21と、浄化したドレン水を排水するポンプ22と、破砕乾燥装置と炭化装置の電熱ヒータへの電力供給量や、冷却装置に循環する冷却水の温度や流量を調整する運転制御装置23にも供給されている。Furthermore, the electricity obtained from the steam turbine generator 9 is also supplied to a cooling water circulation pump 16 that cools carbon in the carbon cooling device 8, an absorption chiller 17 that is driven by using the hot water separated in the steam separator 2 to obtain cold heat for the circulating cooling water, a cooling tower 18 that is ancillary equipment for the cooling chiller, and a circulation pump 19 for cooling water for the cooling tower. In addition, the electricity obtained from the steam turbine generator 9 is also supplied to a pump 20 that drains drain water generated during heat exchange for heating and drying from the steam after geothermal power generation that is supplied as a heat source for heating and drying organic matter in the crushing and drying device, a wastewater purification device 21 that purifies drain water generated during heat exchange using combustion gas that is supplied as a heat source for heating the crushed and dried organic matter in the carbonization device, a pump 22 that drains the purified drain water, and an operation control device 23 that adjusts the amount of power supplied to the electric heaters of the crushing and drying device and the carbonization device, and the temperature and flow rate of the cooling water circulated to the cooling device.

このうち、未破砕で含水率の高い有機物5を破砕および粉砕しながら加熱乾燥し、含水率を低下させた乾燥粉末とする破砕乾燥装置6は、地熱蒸気で駆動する蒸気タービンの回転駆動力によって筐体内で回転する破砕搬送板が固定された回転軸と、前記の蒸気タービンを駆動した後の高温地熱蒸気で加熱される破砕加熱板が筐体内壁に固定された筐体によって構成された、多段翼型コンプレッサのような態様で構成されている。Of these, the crushing and drying device 6, which heats and dries the uncrushed organic matter 5 with a high moisture content while crushing and pulverizing it to produce a dry powder with a reduced moisture content, is configured in a manner similar to a multi-stage blade type compressor, consisting of a rotating shaft to which a crushing and conveying plate is fixed, which rotates inside the housing by the rotational driving force of a steam turbine driven by geothermal steam, and a housing to which a crushing and heating plate, which is heated by the high-temperature geothermal steam after driving the steam turbine, is fixed to the inner wall of the housing.

ただし、本装置の筐体は二重殻構造となっており、前記の破砕加熱板が固定されている内殻の外側には、外側表面を断熱材で覆われた外殻筐体があり、この外殻筐体と内殻との間には、螺旋流路壁24が構成されており、蒸気タービン駆動後の高温地熱蒸気が螺旋流路内を流れて筐体内殻を通じた熱伝導によって破砕加熱板を加熱し、有機物を破砕乾燥する構成としている。また、破砕乾燥装置を構成する、内殻壁における破砕加熱板間の一部には、有機物から発生する蒸気やガスだけが通過できる、フィルターつきの蒸気抽気口25が設置されており、有機物を乾燥させた際に発生する蒸気含有ガス抽気されて集約され、浄化された後に排気ブロワ13を介して大気に放散されるとともに、排気ブロワによる強制排気によって、破砕乾燥装置内が減圧されて有機物の気化乾燥が促される。However, the housing of this device has a double shell structure, and outside the inner shell to which the crushing and heating plate is fixed, there is an outer shell housing whose outer surface is covered with a heat insulating material, and between this outer shell housing and the inner shell, a spiral flow path wall 24 is formed, and high-temperature geothermal steam after the steam turbine is driven flows through the spiral flow path and heats the crushing and heating plate by thermal conduction through the inner shell of the housing, thereby crushing and drying the organic matter. In addition, a steam extraction port 25 with a filter that allows only steam and gas generated from the organic matter to pass is installed in a part between the crushing and heating plates of the inner shell wall that constitutes the crushing and drying device, and the steam-containing gas generated when the organic matter is dried is extracted, collected, purified, and released into the atmosphere via the exhaust blower 13, and the pressure inside the crushing and drying device is reduced by the forced exhaust by the exhaust blower, facilitating the evaporation and drying of the organic matter.

なお、前記の筐体二重殻構造内に構成される螺旋流路は、破砕乾燥装置の出口側に近い方から入口側にむかって、徐々に流路幅が大きくなるように構成されるとともに、高温地熱蒸気を破砕乾燥装置の出口側の螺旋流路から供給し、破砕乾燥装置の入口側の螺旋流路から排出させることにより、筐体内部の有機物と螺旋流路を流れる地熱蒸気との温度差を保って有機物中の水分蒸発を促すとともに、破砕乾燥装置の出口側における高温加熱を強化することで、有機物を充分に加熱乾燥できるように構成することが望ましい。In addition, the spiral flow path formed within the double shell structure of the housing is configured so that the flow path width gradually increases from the side closer to the outlet side of the crushing and drying device toward the inlet side, and it is desirable to configure the structure so that high-temperature geothermal steam is supplied from the spiral flow path on the outlet side of the crushing and drying device and discharged from the spiral flow path on the inlet side of the crushing and drying device, thereby maintaining a temperature difference between the organic matter inside the housing and the geothermal steam flowing through the spiral flow path, promoting evaporation of water in the organic matter, and by strengthening high-temperature heating on the outlet side of the crushing and drying device, the organic matter can be sufficiently heated and dried.

また、本装置を構成する、動翼状の破砕搬送板と、静翼状の破砕加熱板は多段構成となっており、有機物の投入部に近い上流段側の隙間は大きめとして、大型の未破砕有機物を破砕乾燥させやすい状態にしたうえで、後段の排出部に近い側にむけて徐々に隙間を小さく狭め、最終段では排出される破砕乾燥有機物の寸法が5mm以下で、含水率が10%程度になるように構成されていることが望ましく、破砕乾燥物の寸法や含水率を最適化し、均一化するため、排出口付近にサンプル採取口が設けられ、サンプルの測定結果に応じて地熱蒸気の供給量や、電気ヒータ10への電力供給量が制御されていることが望ましい。In addition, the moving blade-shaped crushing and conveying plates and stationary blade-shaped crushing and heating plates that make up this device are configured in multiple stages, with the gap on the upstream stage close to the organic matter input point being larger to make it easier to crush and dry large uncrushed organic matter, and then the gap gradually narrows toward the subsequent stage closer to the discharge point, so that the crushed and dried organic matter discharged in the final stage has dimensions of 5 mm or less and a moisture content of approximately 10%, and it is desirable that a sample collection port be provided near the discharge outlet in order to optimize and uniform the dimensions and moisture content of the crushed and dried material, and that the amount of geothermal steam supplied and the amount of power supplied to the electric heater 10 be controlled according to the sample measurement results.

すなわち、破砕乾燥有機物の含水率が高い場合には、変速機を制御することで破砕搬送板が固定された回転軸の回転数を低下させ、有機物の搬送速度を低下させて装置内での滞留時間を長期化させるか、地熱蒸気の供給量を増大させるか、電気ヒータへの電力供給量を増量させる制御を通じて熱供給量を増大させることで加熱乾燥を促す一方、破砕乾燥有機物の含水率が低ければ、回転軸の回転数を増加させて有機物の装置内における滞留時間を短縮させるか、地熱蒸気の供給量を削減するか、電気ヒータへの電力供給量を減少させる制御を通じて熱供給量を減少させることで、加熱乾燥を抑制し、破砕乾燥有機物の含水率を最適な範囲に維持することが望ましい。In other words, when the moisture content of the crushed and dried organic matter is high, the speed of the rotating shaft to which the crushing and conveying plate is fixed is controlled by the transmission to reduce the transport speed of the organic matter and lengthen the residence time within the device, or the amount of geothermal steam supplied is increased, or the amount of heat supplied is increased through control to increase the amount of power supplied to the electric heater, thereby promoting heated drying. On the other hand, when the moisture content of the crushed and dried organic matter is low, the speed of the rotating shaft is increased to shorten the residence time of the organic matter within the device, or the amount of geothermal steam supplied is reduced, or the amount of heat supplied is reduced through control to reduce the amount of power supplied to the electric heater, thereby suppressing heated drying and maintaining the moisture content of the crushed and dried organic matter within an optimal range.

また、前記の破砕乾燥装置6から排出された有機物の乾燥粉末を半炭化させた後に炭化させる炭化装置7も、地熱蒸気で駆動する蒸気タービンの回転駆動力によって筐体内で回転する圧縮搬送板が固定された圧縮搬送回転軸と、有機物が熱分解する際に発生する熱分解ガスを燃焼させた燃焼ガスで加熱される圧縮加熱板が内壁に固定された筐体によって、多段翼型コンプレッサのような態様で構成されている。In addition, the carbonization device 7, which semi-carbonizes and then carbonizes the dry powder of the organic matter discharged from the crushing and drying device 6, is configured in a manner similar to a multi-stage blade compressor, with a compression and conveying rotating shaft to which a compression and conveying plate is fixed, which rotates inside a housing by the rotational driving force of a steam turbine driven by geothermal steam, and a housing to whose inner wall a compression heating plate is fixed, which is heated by combustion gas produced by burning pyrolysis gas generated when the organic matter is thermally decomposed.

さらに、本装置の筐体も二重殻構造となっており、前記の圧縮加熱板が固定されている内殻の外側には、外側表面を断熱材で覆われた外殻筐体があり、この外殻筐体と内殻との間には、螺旋流路壁26が構成されていることで、熱分解ガス燃焼後の高温燃焼ガスが螺旋流路内を流れて筐体内殻を通じた熱伝導によって圧縮加熱板を加熱し、有機物を圧縮加熱して半炭化物を生成させた上で、さらに生成させた半炭化物を圧縮加熱して炭化させることで、炭化装置の出口からは、有機物起源の固体炭素粉末が排出されるようになっている。Furthermore, the housing of this device also has a double shell structure, and outside the inner shell to which the compression heating plate is fixed, there is an outer shell housing whose outer surface is covered with insulating material, and a spiral flow path wall 26 is formed between this outer shell housing and the inner shell, so that the high-temperature combustion gas after combustion of the pyrolysis gas flows inside the spiral flow path and heats the compression heating plate by thermal conduction through the inner shell of the housing, compressing and heating the organic matter to generate semi-carbonized material, and the generated semi-carbonized material is further compressed and heated to carbonize it, and solid carbon powder of organic origin is discharged from the outlet of the carbonization device.

なお、前記の炭化装置を構成する筐体内における、圧縮加熱板間の内壁部の一部にも、有機物から発生する熱分解ガスだけが通過できる、フィルターつきの熱分解ガス抽気口27が設置されており、有機物を半炭化および炭化させた際に発生する熱分解ガスが抽気されて集約され、空気吸入と燃焼排ガスの送出を行う吸気ブロワから吸入された空気と燃焼させた後に、前記の筐体二重殻構造部の螺旋流路内を流通させることによって、炭化装置内が加熱され、有機物が無酸素環境下で加熱圧縮されることにより、半炭化反応や炭化反応が促進される。In addition, a pyrolysis gas extraction port 27 with a filter, through which only pyrolysis gas generated from organic matter can pass, is installed in a part of the inner wall between the compression heating plates within the casing that constitutes the carbonization device. The pyrolysis gas generated when the organic matter is semi-carbonized and carbonized is extracted and collected, and after being combusted with air sucked in by the intake blower that sucks in air and sends out combustion exhaust gas, the gas is circulated within the spiral flow path of the double shell structure of the casing. This heats up the inside of the carbonization device, and the organic matter is heated and compressed in an oxygen-free environment, thereby promoting the semi-carbonization and carbonization reactions.

ここで、炭化装置の筐体二重殻構造内に構成される螺旋流路は、炭化装置の出口側に近い方から入口側にむかって、徐々に流路幅が大きくなるように構成されるとともに、燃焼排ガスを炭化装置の出口側の螺旋流路から供給し、破砕乾燥装置の入口側の螺旋流路から排出させることにより、筐体内部の有機物と螺旋流路を流れる燃焼排ガスとの温度差を保って有機物の半炭化と炭化を促すとともに、炭化装置の出口側における高温加熱を強化することで、半炭化物を充分に加熱して炭化できるように構成することが望ましい。Here, the spiral flow path formed within the double-shell structure of the housing of the carbonization device is configured so that the flow path width gradually increases from the side closer to the outlet side of the carbonization device toward the inlet side, and it is desirable to configure the combustion exhaust gas to be supplied from the spiral flow path on the outlet side of the carbonization device and discharged from the spiral flow path on the inlet side of the crushing and drying device, thereby maintaining a temperature difference between the organic matter inside the housing and the combustion exhaust gas flowing through the spiral flow path to promote semi-carbonization and carbonization of the organic matter, and by strengthening high-temperature heating on the outlet side of the carbonization device, the semi-carbonized matter can be sufficiently heated and carbonized.

さらに、本装置を構成する動翼状の圧縮搬送板と、静翼状の圧縮加熱板は多段階構成となっており、破砕乾燥有機物の半炭化や炭化を段階的かつ確実に反応させることで、最終的に排出される炭素の品質が均一化されていることが望ましい。このため、炭化装置の排出口付近には生成した炭素のサンプル採取口が設けられ、サンプルの測定結果に応じて燃焼ガスの供給量や、電気ヒータ11への電力供給量が制御されていることが望ましい。Furthermore, the moving blade-like compression conveying plate and stationary blade-like compression heating plate that constitute this device are configured in multiple stages, and it is desirable to uniformize the quality of the carbon finally discharged by reacting the crushed and dried organic matter semi-carbonized and carbonized in a stepwise and reliable manner. For this reason, it is desirable to provide a sample collection port for the generated carbon near the discharge port of the carbonization device, and to control the amount of combustion gas supplied and the amount of power supplied to the electric heater 11 according to the measurement results of the sample.

すなわち、回収炭素の純度が低い場合には、変速機を制御して圧縮搬送回転軸の回転数を低下させ、装置内での滞留時間を長期化させたり、燃焼ガスの供給量を増大させるか、電気ヒータへの電力供給量を増量させるか、その両方を行う制御を通じて破砕乾燥有機物の半炭化や炭化のための熱供給量を増大させる一方、回収炭素の純度が基準を上回る過剰な状態であれば、圧縮搬送回転軸の回転数を増加させて装置内での滞留時間を短縮したり、燃焼ガスの供給量を削減するか、電気ヒータへの電力供給量を減少させるか、その両方を行う制御を通じて半炭化や炭化のための熱供給量を減少させることで、回収炭素の品質が最適に維持されることが望ましい。In other words, when the purity of the recovered carbon is low, the transmission is controlled to reduce the rotation speed of the compression and conveying rotating shaft to extend the residence time within the device, or to increase the amount of combustion gas supplied, or to increase the amount of power supplied to the electric heater, or both, thereby increasing the amount of heat supplied for semi-carbonization and carbonization of the crushed and dried organic matter. On the other hand, when the purity of the recovered carbon is in an excessive state exceeding the standard, it is desirable to maintain the quality of the recovered carbon at an optimum level by increasing the rotation speed of the compression and conveying rotating shaft to shorten the residence time within the device, or to reduce the amount of combustion gas supplied, or to reduce the amount of power supplied to the electric heater, or both, thereby decreasing the amount of heat supplied for semi-carbonization and carbonization.

次に、前記の炭化装置7から排出された高温の炭素粉末は、地熱蒸気で駆動する蒸気タービンの回転駆動力によって筐体内で回転する圧縮搬送板が固定された圧縮搬送回転軸を収納し、高温の炭化物を冷却する冷却水が流れる流路が構成された二重殻筐体の炭素冷却装置8に搬送される。Next, the high-temperature carbon powder discharged from the carbonization device 7 is transported to a carbon cooling device 8, which is a double-shelled housing that houses a compression and conveying rotating shaft to which a compression and conveying plate is fixed, which rotates inside the housing by the rotational driving force of a steam turbine driven by geothermal steam, and has a flow path through which cooling water flows to cool the high-temperature carbonized material.

なお、本装置の筐体も二重殻構造となっており、外殻と内殻との間には螺旋流路壁が構成され、螺旋流路内を冷却水が流れることで筐体内殻を通じた熱伝導によって、内部で圧縮搬送される炭素が冷却されることにより、炭素冷却装置の出口からは、空気中の酸素と接触しても容易に発熱・発火しない、有機物起源の固体炭素粉末28を回収できる。The housing of this device also has a double-shell structure, with a spiral channel wall formed between the outer and inner shells. Cooling water flows inside the spiral channel, and the carbon compressed and transported inside is cooled by thermal conduction through the inner shell of the housing. As a result, solid carbon powder 28 of organic origin that does not easily generate heat or ignite even when in contact with oxygen in the air can be recovered from the outlet of the carbon cooling device.

ここで、本装置によって高温の炭化物を冷却するための冷却水は、地熱蒸気を汽液分離した際に得られる高温の熱水を利用して駆動される吸収式冷凍機17によって得られる、10~15℃の冷却水を循環利用することで、地熱を利用して高温炭素の冷却を行える構成としている。Here, the cooling water used by this device to cool the high-temperature carbide is 10 to 15°C cooling water obtained by an absorption chiller 17 driven by high-temperature hot water obtained when geothermal steam is separated into steam and liquid. This is circulated and used to cool the high-temperature carbon using geothermal energy.

このように、本発明の地熱エネルギー活用型の炭素回収システムでは、昼夜や天候によらず安定的にエネルギー利用が可能な地熱蒸気を活用して、含水率が高い未破砕の有機物であっても、連続的に均質な固体炭素を回収することが可能となり、二酸化炭素の排出源となる炭素の固定化や、高機能材料の原料として利用することが可能となる。In this way, the geothermal energy-utilizing carbon recovery system of the present invention utilizes geothermal steam, which allows for stable energy use regardless of day or night or weather, making it possible to continuously recover homogeneous solid carbon even from uncrushed organic matter with a high moisture content.This can be used to fix carbon, which is a source of carbon dioxide emissions, or as a raw material for high-performance materials.

また本システムでは、廃プラスチックなどの化石燃料起源の有機物から、二酸化炭素発生源となる炭素を回収することで、焼却処理による二酸化炭素の排出を抑制できるが、草木剪定枝や食品廃棄物、農水産品の非可食部分や下水汚泥といったバイオマス有機物を投入して炭素を回収して地中埋設等の固定化を行えば、バイオマスを介して大気中の二酸化炭素を減少させるネガティブエミッションを実現することも可能となる。This system also recovers carbon, which is a source of carbon dioxide, from organic matter of fossil fuel origin such as waste plastic, thereby reducing carbon dioxide emissions from incineration. However, if biomass organic matter such as pruned branches of plants, food waste, inedible parts of agricultural and marine products, and sewage sludge is input, the carbon can be recovered, and then immobilized by burying it underground, making it possible to achieve negative emissions that reduce carbon dioxide in the atmosphere via biomass.

以上の構成とすることで、二酸化炭素の排出を伴わない再生可能エネルギーである地熱蒸気の多段階活用によって、小規模な設備で効率よく、有機物から炭素を回収することが可能となり、豊富な地熱蒸気があっても送配電網への接続供給や熱供給ができない場所であっても、地熱蒸気の有効活用による炭素の固定化や有効利用が可能となる。
(第2実施形態)
With the above configuration, by making multi-stage use of geothermal steam, a renewable energy source that does not involve carbon dioxide emissions, it is possible to efficiently recover carbon from organic matter using small-scale equipment. Even in locations where there is abundant geothermal steam but it is not possible to connect to the power grid or supply heat, it is possible to fix and utilize carbon by effectively using geothermal steam.
Second Embodiment

次に、本発明の第2実施形態に係る、水力エネルギー活用型の半炭化固形物回収システムについて、図2に基づいて説明する。Next, a hydraulic energy-utilizing torrefied solid recovery system according to a second embodiment of the present invention will be described with reference to FIG.

図2に示すように、第2実施形態のシステムでは、炭素回収を行うための再生可能エネルギーとして、落差を伴う河川等の水力を利用する点と、有機物を破砕乾燥して半炭化させた後に圧縮成形と冷却を行って、半炭化固形物29を生成して回収する点が異なる。As shown in Figure 2, the system of the second embodiment differs in that it uses hydropower from a river or the like with a drop in height as renewable energy for carbon recovery, and that it crushes, dries and semi-carbonizes organic matter, and then compresses and cools it to produce and recover semi-carbonized solid matter 29.

ここで、水力を利用して有機物を半炭化させるうえでは、水車30によって駆動する回転破砕板を回転させつつ、水力発電システム31から得られる電力によって、破砕乾燥半炭化装置の筐体表面に覆われた電気ヒータ32を用いて有機物を加熱乾燥させた後に、110~200℃程度に圧縮加熱して半炭化させながら圧縮成形を行う点が異なる。Here, the difference in using hydraulic power to semi-carbonize the organic matter is that while a rotating crushing plate driven by a water wheel 30 is rotated, the organic matter is heated and dried using an electric heater 32 covered on the surface of the housing of the crushing, drying and semi-carbonization device using electricity obtained from a hydraulic power generation system 31, and then the organic matter is compressed and heated to approximately 110 to 200°C to semi-carbonize it while undergoing compression molding.

また、圧縮成形された高温の半炭化固形物を冷却水を用いて冷却し、長期保管が可能な半炭化固形物として回収させる、半炭化固形物製造装置33が接続されている点が異なる。Another difference is that a semi-carbonized solid production device 33 is connected, which cools the compressed and molded high-temperature semi-carbonized solid using cooling water and recovers it as a semi-carbonized solid that can be stored for a long period of time.

また、前記の半炭化固形物製造装置における高温の半炭化固形物の冷却では、水力発電後の河川水を冷却水汲み上げポンプ34で汲み上げて供給し、水車駆動や水力発電に利用する水が保有する冷熱を、生成させた半炭化物の冷却にも利用する点が異なっている。Another difference is that in the cooling of the high-temperature semi-carbonized solids in the semi-carbonized solids manufacturing equipment, river water after hydroelectric power generation is pumped up and supplied by a cooling water pump 34, and the cold energy contained in the water used to drive the water turbine and generate hydroelectric power is also used to cool the semi-carbonized material produced.

このような構成とすることで、地熱資源がない一方で水力資源に恵まれた地域でも、有機物から二酸化炭素発生源となる炭素の回収と固定化や有効利用を行うことが可能となる。With this configuration, it will be possible to capture, fix, and effectively utilize carbon, which is the source of carbon dioxide, from organic matter, even in areas that lack geothermal resources but are blessed with hydroelectric resources.

以上のように、地域に分散する地熱や水力のエネルギーを利用して、二酸化炭素排出の起源物質となる有機物に含まれる炭素を、固体炭素または半炭化固形物として回収することで、二酸化炭素ガスの固定化よりも容易に輸送と固定化が可能となる固体炭素での固定化や、二酸化炭素起源物質を長期固定しながら環境負荷の低い炭素系材料を製造する際の炭素原料を提供することが可能となる。また本システムは、再生可能エネルギー資源があっても送配電網への接続や熱供給が困難な場所でも適用が可能で、電力 系統で停電が起こっても継続的に有機物から炭素回収が行えるようになり、幅広い地域で有機物から炭素の回収と固定化を行うことが可能となる。As described above, by using geothermal and hydroelectric energy distributed in the region to recover carbon contained in organic matter, which is the source material of carbon dioxide emissions, as solid carbon or semi-carbonized solids, it is possible to provide a carbon feedstock for the manufacture of carbon-based materials with low environmental impact while fixing carbon dioxide source materials for the long term by using solid carbon that can be transported and fixed more easily than carbon dioxide gas fixation, and to fix carbon dioxide source materials in the form of solid carbon that can be transported and fixed more easily than carbon dioxide gas fixation. This system can also be applied in places where it is difficult to connect to the power grid or provide heat, even if there are renewable energy resources, and it can be used to recover carbon from organic matter continuously even if the power grid is blacked out, making it possible to recover and fix carbon from organic matter in a wide area.

なお本発明は、前記の実施形態に限定されるものではなく、例えば図1の実施形態は地熱蒸気の発生地だけでなく、高温の温泉が湧出している場所においても、温泉熱発電による電力や高温源泉がもつ保有熱を活用する形態で適用可能であり、図2の実施形態は落差を有する河川の利用に限らず、上水道施設で落差と流量から水力起源の電力や熱が得られる場所での有機廃棄物処理による炭素回収や、下水処理施設で落差と流量から水力起源の電力や熱が得られる場所において、施設内で発生する下水汚泥を乾燥処理して炭化回収する際にも適用可能であるほか、安定した海流や潮流によって発電や海水冷却が可能な地域においても適用可能である。The present invention is not limited to the above-described embodiments. For example, the embodiment of FIG. 1 can be applied not only to areas where geothermal steam is generated, but also to areas where high-temperature hot springs gush out, in a form that utilizes electricity generated by hot spring thermal power generation and the heat contained in high-temperature hot springs. The embodiment of FIG. 2 is not limited to the use of rivers with a difference in elevation, but can also be applied to carbon recovery by treating organic waste at places where hydroelectric electricity and heat can be obtained from the elevation and flow rate at water supply facilities, and to drying and carbonizing sewage sludge generated within facilities at places where hydroelectric electricity and heat can be obtained from the elevation and flow rate at sewage treatment facilities. It can also be applied in areas where electricity can be generated and seawater can be cooled by stable ocean currents and tidal currents.

このように、前記の実施形態は例示であり、本発明の特許請求範囲に記載された技術的思想と実質的に同一な構成を有し、同様な作用効果を奏するものは、いかなるものであっても本発明の技術的範囲に包含される。As such, the above-described embodiments are merely illustrative, and anything that has substantially the same configuration as the technical idea described in the claims of the present invention and exhibits similar effects is included within the technical scope of the present invention.

1・・・・地熱流体
2・・・・汽水分離器
3・・・・蒸気タービン
4・・・・変速機
5・・・・未破砕高含水率有機物
6・・・・有機物破砕乾燥装置
7・・・・破砕乾燥有機物炭化装置
8・・・・炭素冷却装置
9・・・・蒸気タービン発電機
10・・・有機物破砕乾燥装置用電熱ヒータ
11・・・破砕乾燥有機物炭化装置用電熱ヒータ
12・・・蒸気含有ガス浄化装置
13・・・蒸気含有ガス排気ブロワ
14・・・熱分解ガス燃焼装置
15・・・熱分解ガス燃焼用空気ブロワ
16・・・冷却水循環ポンプ
17・・・吸収式冷凍機
18・・・冷却塔
19・・・冷却塔循環ポンプ
20・・・地熱蒸気ドレン水排水ポンプ
21・・・燃焼ガスドレン水浄化装置
22・・・燃焼ガスドレン水排水ポンプ
23・・・有機物炭化回収システム制御装置
24・・・地熱蒸気螺旋流路
25・・・蒸気抽気口
26・・・燃焼排ガス螺旋流路
27・・・熱分解ガス抽気口
28・・・固体炭素粉末
29・・・半炭化固形物
30・・・水車
31・・・水力発電システム
32・・・有機物破砕乾燥半炭化装置用電熱ヒータ
33・・・半炭化固形物製造装置
34・・・冷却水汲み上げポンプ
1. Geothermal fluid 2. Steam separator 3. Steam turbine 4. Transmission 5. Uncrushed high moisture content organic matter 6. Organic matter crushing and drying device 7. Crushed and dried organic matter carbonization device 8. Carbon cooling device 9. Steam turbine generator 10. Electric heater for organic matter crushing and drying device 11. Electric heater for crushed and dried organic matter carbonization device 12. Steam-containing gas purification device 13. Steam-containing gas exhaust blower 14. Pyrolysis gas combustion device 15. Air blower for pyrolysis gas combustion 16. Cooling water circulation pump 17. Absorption chiller 1 8...Cooling tower 19...Cooling tower circulation pump 20...Geothermal steam drain water drainage pump 21...Combustion gas drain water purification device 22...Combustion gas drain water drainage pump 23...Organic matter carbonization and recovery system control device 24...Geothermal steam spiral passage 25...Steam extraction port 26...Combustion exhaust gas spiral passage 27...Pyrolysis gas extraction port 28...Solid carbon powder 29...Semi-carbonized solids 30...Water wheel 31...Hydroelectric power generation system 32...Electric heater for organic matter crushing, drying and semi-carbonization device 33...Semi-carbonized solids production device 34...Cooling water pumping pump

Claims (14)

有機物を破砕乾燥すると共に加熱して半炭化する破砕乾燥装置であって、A crushing and drying device that crushes and dries organic matter and heats it to carbonize it,
有機物が投入される投入部と半炭化された当該有機物が排出される排出部とを有する筐体と、a housing having an input section into which organic matter is input and an output section from which the semi-carbonized organic matter is output;
前記筐体内部で回転可能に設けられた回転軸と、を備え、A rotating shaft rotatably provided inside the housing,
前記筐体は、The housing includes:
破砕加熱板が設けられた内殻と、an inner shell provided with a crushing heating plate;
前記内殻の外側に設けられた外殻と、を備えた二重殻構造であり、An outer shell provided on the outside of the inner shell,
前記内殻と前記外殻との間に、前記投入部から前記排出部へ至り前記有機物が通る螺旋流路が形成され、A spiral flow path through which the organic matter passes from the input portion to the discharge portion is formed between the inner shell and the outer shell,
前記螺旋流路は、前記排出部側から前記投入部側へ向かって徐々に流路幅が大きくなるように構成され、The spiral flow path is configured such that a flow path width gradually increases from the discharge portion side to the input portion side,
前記回転軸には、当該回転軸の回転に伴って回転することにより前記有機物を搬送する破砕搬送板が設けられていることを特徴とする、破砕乾燥装置。The crushing and drying apparatus is characterized in that the rotating shaft is provided with a crushing and conveying plate that rotates in conjunction with the rotation of the rotating shaft to convey the organic matter.
前記破砕加熱板と前記破砕搬送板との隙間が、前記螺旋流路における前記投入部側ほど大きく、前記排出部側ほど小さくなるように、当該破砕加熱板および当該破砕搬送板が配置されていることを特徴とする、請求項1に記載の破砕乾燥装置。The crushing and drying device according to claim 1, characterized in that the crushing and heating plate and the crushing and conveying plate are arranged so that a gap between them is larger toward the input section side in the spiral flow path and smaller toward the discharge section side. 高温蒸気を、前記螺旋流路における前記排出部側から供給し、前記投入部側から排出させることにより、当該螺旋流路を通る前記有機物を加熱することを特徴とする、請求項1に記載の破砕乾燥装置。2. The crushing and drying apparatus according to claim 1, characterized in that high-temperature steam is supplied from the discharge portion side of the spiral flow path and discharged from the input portion side, thereby heating the organic matter passing through the spiral flow path. 排出する前記有機物を、最終粒子径を5mm以下とし、含水率を15%以下とすることを特徴とする、請求項1に記載の破砕乾燥装置。2. The crushing and drying apparatus according to claim 1, wherein the organic matter to be discharged has a final particle size of 5 mm or less and a moisture content of 15% or less. 排出する前記有機物の含水率が15%以下となるよう、当該有機物への加熱量を制御することを特徴とする、請求項1に記載の破砕乾燥装置。2. The crushing and drying apparatus according to claim 1, wherein the amount of heat applied to the organic matter to be discharged is controlled so that the moisture content of the organic matter to be discharged is 15% or less. 前記有機物を5~30MPaの範囲で圧縮するとともに、100~450℃の範囲で加熱することを特徴とする、請求項1に記載の破砕乾燥装置。2. The crushing and drying apparatus according to claim 1, wherein the organic matter is compressed in a range of 5 to 30 MPa and heated in a range of 100 to 450°C. 前記有機物の温度が100~450℃となるよう、当該有機物への加熱量を制御することを特徴とする、請求項1に記載の破砕乾燥装置。2. The crushing and drying apparatus according to claim 1, wherein the amount of heat applied to the organic matter is controlled so that the temperature of the organic matter is 100 to 450° C. 半炭化された有機物を加熱して炭化する炭化装置であって、A carbonization device for heating and carbonizing semi-carbonized organic matter,
前記半炭化された有機物の入口と加熱後の炭化物の出口とを有する筐体と、a housing having an inlet for the torrefied organic matter and an outlet for the heated carbonized matter;
前記筐体内部で回転可能に設けられた回転軸と、を備え、A rotating shaft rotatably provided inside the housing,
前記筐体は、The housing includes:
圧縮加熱板が設けられた内殻と、an inner shell provided with a compression heating plate;
前記内殻の外側に設けられた外殻と、を備えた二重殻構造であり、An outer shell provided on the outside of the inner shell,
前記内殻と前記外殻との間に、前記入口から前記出口へ至り前記半炭化された有機物が通る螺旋流路が形成され、A spiral flow path is formed between the inner shell and the outer shell, through which the torrefied organic matter passes from the inlet to the outlet,
前記螺旋流路は、前記出口側から前記入口側へ向かって徐々に流路幅が大きくなるように構成され、The spiral flow path is configured such that a flow path width gradually increases from the outlet side to the inlet side,
前記回転軸には、当該回転軸の回転に伴って回転することにより前記半炭化された有機物を搬送する圧縮搬送板が設けられていることを特徴とする、炭化装置。A carbonization apparatus, characterized in that the rotating shaft is provided with a compression and conveying plate that rotates in conjunction with the rotation of the rotating shaft to convey the semi-carbonized organic matter.
高温蒸気を、前記螺旋流路における前記出口側から供給し、前記入口側から排出させることにより、当該螺旋流路を通る前記半炭化された有機物を加熱することを特徴とする、請求項8に記載の炭化装置。The carbonization apparatus according to claim 8, characterized in that high-temperature steam is supplied from the outlet side of the spiral flow path and discharged from the inlet side, thereby heating the torrefied organic matter passing through the spiral flow path. 前記半炭化された有機物を450~700℃の範囲で加熱することを特徴とする、請求項8に記載の炭化装置 The carbonization apparatus according to claim 8, wherein the semi-carbonized organic matter is heated at a temperature in the range of 450 to 700°C . 前記半炭化された有機物の温度が450~700℃となるよう、当該半炭化された有機物への加熱量を制御することを特徴とする、請求項8に記載の炭化装置。The carbonization apparatus according to claim 8, characterized in that the amount of heat applied to the semi-carbonized organic matter is controlled so that the temperature of the semi-carbonized organic matter is 450 to 700°C. 請求項1から請求項3のいずれか一つに記載された破砕乾燥装置と、A crushing and drying device according to any one of claims 1 to 3,
前記破砕乾燥装置により半炭化された有機物を炭化する請求項8または請求項9に記載された炭化装置と、A carbonization apparatus according to claim 8 or 9, which carbonizes the organic matter semi-carbonized by the crushing and drying apparatus;
前記炭化装置により炭化された生成物を冷却する冷却装置と、を備え、A cooling device that cools the product carbonized by the carbonization device,
前記冷却装置は、The cooling device includes:
前記炭化装置の生成物の入口と冷却後の当該生成物の出口とを有する筐体と、a housing having an inlet for the product of the carbonizer and an outlet for the product after cooling;
前記筐体内部で回転可能に設けられた回転軸と、を備え、A rotating shaft rotatably provided inside the housing,
前記筐体は、The housing includes:
内殻と外殻とを備えた二重殻構造であり、It has a double shell structure with an inner shell and an outer shell,
前記内殻と前記外殻との間に、前記入口から前記出口へ至る螺旋流路が形成され、A spiral flow path is formed between the inner shell and the outer shell from the inlet to the outlet,
前記回転軸には、当該回転軸の回転に伴って回転することにより前記生成物を搬送する圧縮搬送板が設けられており、The rotating shaft is provided with a compression conveying plate that rotates with the rotation of the rotating shaft to convey the product,
前記螺旋流路を冷却水が通ることにより、前記内殻の内部を通る前記生成物を冷却することを特徴とする、システム。A system comprising: a spiral passage through which cooling water passes to cool the product passing through the interior of the inner shell.
前記冷却装置は、前記炭化装置の生成物の温度が15~85℃の範囲となるよう冷却することを特徴とする、請求項12に記載のシステム。The system of claim 12, wherein the cooling device cools the product of the carbonizer to a temperature in the range of 15 to 85°C. 前記炭化装置の生成物の温度が15~85℃の範囲となるよう、前記冷却装置による当該生成物に対する冷却量を制御することを特徴とする、請求項12に記載のシステム。The system according to claim 12, characterized in that the amount of cooling applied to the product by the cooling device is controlled so that the temperature of the product of the carbonization device is in the range of 15 to 85°C.
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