JP7587393B2 - Method for producing egg yolk-like composition and egg yolk-like composition - Google Patents
Method for producing egg yolk-like composition and egg yolk-like composition Download PDFInfo
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- JP7587393B2 JP7587393B2 JP2020183562A JP2020183562A JP7587393B2 JP 7587393 B2 JP7587393 B2 JP 7587393B2 JP 2020183562 A JP2020183562 A JP 2020183562A JP 2020183562 A JP2020183562 A JP 2020183562A JP 7587393 B2 JP7587393 B2 JP 7587393B2
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Landscapes
- Meat, Egg Or Seafood Products (AREA)
Description
本発明は、卵黄様組成物の製造方法及び卵黄様組成物に関する。 The present invention relates to a method for producing an egg yolk-like composition and to an egg yolk-like composition.
卵黄はその機能、栄養価等に優れた特徴を有することから、調味料、惣菜、菓子など様々な食品に幅広く利用されている。また卵黄・液卵はその色彩や食感が好まれ、従来より、卵黄又は液卵様の組成物が提案されている。
例えば特許文献1には、乾物あたりの蛋白質含量が25重量%以上、脂質含量が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物を卵黄代替用組成物として使用することが記載されている。また、特許文献2には、液卵様の外観を有するものであり、タンパク質含量が5%以下であり、加工澱粉含量が1~10%である、液状組成物が記載されている。
Egg yolk has excellent properties such as functionality and nutritional value, and is therefore widely used in a variety of foods such as seasonings, side dishes, confectioneries, etc. In addition, egg yolk and liquid egg are popular for their color and texture, and egg yolk or liquid egg-like compositions have been proposed.
For example, Patent Document 1 describes the use of a soybean emulsion composition having a protein content of 25% by weight or more per dry matter, a lipid content of 100% by weight or more relative to the protein content, and an LCI value of 55% or more as an egg yolk substitute composition. Patent Document 2 describes a liquid composition that has an appearance similar to liquid egg, a protein content of 5% or less, and a modified starch content of 1 to 10%.
卵黄の中でも、生卵黄の鮮やかな色とトロトロした性状を好む人は多い。一方で卵黄の凝固点は68℃であるのに対し、一般に食品にはその安全性の点から、殺菌に68℃超、望ましくは85℃以上の加熱が求められる。このため、卵黄を生の状態で有する食品を提供することには衛生上の制限があり、加熱しても凝固しにくく、生の卵黄のような外観及び物性、特に色味及び粘度を有する組成物が求められている。
上記の課題に関し、特許文献1に記載の大豆乳化組成物は、卵黄様のコクを与えることが同文献に記載されているものの、それ自体で卵黄様の色及び粘度を有するものではない。また特許文献2に記載の液状組成物も、加熱凝固した卵料理に用いられ、加熱凝固した卵をふんわりとした食感で彩りを高めるものであり、生卵黄様の色と粘度を有することは何ら同文献に記載されていない。
Among egg yolks, many people prefer the vivid color and thick texture of raw egg yolk. On the other hand, while the coagulation point of egg yolk is 68°C, food generally requires heating to a temperature above 68°C, preferably 85°C or higher, for sterilization in terms of safety. For this reason, there are hygiene restrictions on providing foods containing raw egg yolk, and there is a demand for a composition that does not coagulate easily even when heated and has the appearance and physical properties, particularly color and viscosity, of raw egg yolk.
Regarding the above-mentioned problems, the soybean emulsion composition described in Patent Document 1 is described in the same document as imparting a rich flavor similar to that of egg yolk, but does not have egg yolk-like color and viscosity by itself. Also, the liquid composition described in Patent Document 2 is used in heat-coagulated egg dishes, and enhances the color of the heat-coagulated eggs by giving them a fluffy texture, but there is no description in the same document of the composition having raw egg yolk-like color and viscosity.
したがって本発明の課題は、加熱によって凝固しにくく、且つ生卵黄様の色と粘度を有する卵黄様組成物及びその製造方法を提供することにある。 The object of the present invention is therefore to provide an egg yolk-like composition that is not easily coagulated by heating and has a color and viscosity similar to that of raw egg yolk, and a method for producing the same.
本発明は、卵黄、卵に由来しない酵素及び水を加熱しながら、混合する第1混合工程と、
前記第1混合工程を経た混合物に対して、加熱せずに、混合する第2混合工程と、
前記第2混合工程を経た混合物に対して、澱粉を添加し、加熱しながら、混合する第3混合工程と、を有し、
全原料中、水を90質量%以上97質量%以下用いる、卵黄様組成物の製造方法を提供するものである。
The present invention relates to a method for preparing a food product comprising the steps of: a first mixing step of mixing egg yolk, an enzyme not derived from an egg, and water while heating;
a second mixing step of mixing the mixture obtained in the first mixing step without heating;
A third mixing step of adding starch to the mixture that has been subjected to the second mixing step and mixing the mixture while heating,
The present invention provides a method for producing an egg yolk-like composition, in which water is used in an amount of 90% by mass or more and 97% by mass or less of all raw materials.
また本発明は、卵黄、卵に由来しない酵素、澱粉及び水を含有し、
30℃における粘度が100mPa・s以上1000mPa・s以下である卵黄様組成物を提供するものである。
The present invention also provides a food product comprising egg yolk, an enzyme not derived from an egg, starch and water,
The egg yolk-like composition has a viscosity at 30°C of 100 mPa·s or more and 1000 mPa·s or less.
本発明によれば、加熱しても固まりにくく、生卵黄様の粘度及び色を有する卵黄様組成物を提供することができる。本発明による卵黄様組成物は水分量が多く、カロリーが少ない点でも優れている。 According to the present invention, it is possible to provide an egg yolk-like composition that does not solidify easily even when heated and has a viscosity and color similar to that of raw egg yolk. The egg yolk-like composition according to the present invention is also excellent in that it has a high water content and is low in calories.
まず本発明の卵黄様組成物の製造方法を説明する。
本製造方法は、卵黄、卵に由来しない酵素及び水を加熱しながら、混合する第1混合工程と、
前記第1混合工程を経た混合物を加熱せずに、混合する第2混合工程と、
前記第2混合工程を経た混合物に対して、澱粉を添加し、加熱しながら、混合する第3混合工程と、を有し、
全原料中、水を90質量%以上97質量%以下用いる。
本明細書において「卵黄様組成物」の卵黄様とは、生の卵黄と同様の粘度および色調を有することを意味する。
First, a method for producing the egg yolk-like composition of the present invention will be described.
The present production method includes a first mixing step of mixing egg yolk, an enzyme not derived from an egg, and water while heating;
a second mixing step of mixing the mixture obtained through the first mixing step without heating;
A third mixing step of adding starch to the mixture that has been subjected to the second mixing step and mixing the mixture while heating,
Of all the raw materials, water is used in an amount of 90% by mass or more and 97% by mass or less.
As used herein, the term "egg yolk-like composition" means that it has a viscosity and color similar to that of raw egg yolk.
(第1混合工程)
第1混合工程では、卵黄、卵に由来しない酵素及び水を加熱しながら、混合する。卵に由来しない酵素としてはプロテアーゼやホスホリパーゼが挙げられ、プロテアーゼを用いることが加熱により変性して凝固する蛋白質を分解することで、加熱により凝固しにくい卵黄様組成物が得られる点で好ましい。第1混合工程は、卵黄とプロテアーゼ及び水を混合しながら加熱することでプロテアーゼにより卵黄の蛋白質を分解する工程であることが好ましい。
(First mixing step)
In the first mixing step, egg yolk, an enzyme not derived from an egg, and water are mixed while being heated. Examples of the enzyme not derived from an egg include protease and phospholipase. The use of protease is preferred in that it degrades proteins that denature and coagulate when heated, thereby obtaining an egg yolk-like composition that is less likely to coagulate when heated. The first mixing step is preferably a step in which egg yolk, protease, and water are mixed and heated while being heated, thereby degrading egg yolk proteins with the protease.
卵黄としては、例えば、鶏等の鳥類の卵を割卵し、卵白を分離したものであり工業的に得られるもの、またこれを殺菌、凍結したもの、濃縮または希釈したもの、特定の成分(脂質等)を除去したもの、乾燥させたものやそれを水戻ししたもの等が挙げられる。つまり生卵黄、殺菌液卵黄、凍結卵黄、粉末卵黄やその水戻し品、リパーゼ等の酵素で処理した卵黄などを使用できる。卵黄として全卵は用いないことが得られる卵黄様組成物の外観をより卵黄らしくする点で好ましいが、卵黄様組成物の色及び粘度に影響を及ぼさない程であれば、卵黄は、卵白やその他の卵由来の成分を含んでいても差し支えない。卵黄としては凍結卵黄、殺菌液卵黄、生卵黄を用いることが生卵黄様の外観を容易に実現できる点で好ましく、凍結卵黄を用いることが特に好ましい。 Examples of egg yolk include those obtained industrially by breaking eggs of birds such as chickens and separating the egg white, as well as those obtained by sterilizing, freezing, concentrating or diluting them, removing certain components (such as lipids), drying, or rehydrating them. In other words, raw egg yolk, sterilized liquid egg yolk, frozen egg yolk, powdered egg yolk or its rehydration product, and egg yolk treated with an enzyme such as lipase can be used. It is preferable not to use a whole egg as the egg yolk in order to make the appearance of the obtained egg yolk-like composition more egg yolk-like, but the egg yolk may contain egg white or other egg-derived components as long as the color and viscosity of the egg yolk-like composition are not affected. As the egg yolk, it is preferable to use frozen egg yolk, sterilized liquid egg yolk, or raw egg yolk in order to easily achieve an appearance similar to that of raw egg yolk, and it is particularly preferable to use frozen egg yolk.
第1混合工程で使用する卵黄の量は、卵黄様組成物の全原料中、1質量%以上であることが、得られる卵黄様組成物の色を生卵黄様にしやすい点で好ましく、2質量%以上であることがより好ましい。前記の卵黄の量は全原料中、10質量%以下であることが、他の原料の量を確保しやすい点から好ましく、5質量%以下であることがより好ましい。 The amount of egg yolk used in the first mixing step is preferably 1% by mass or more of the total raw materials for the egg yolk-like composition, since this makes it easier to make the color of the resulting egg yolk-like composition resemble that of raw egg yolk, and more preferably 2% by mass or more. The amount of egg yolk is preferably 10% by mass or less of the total raw materials, since this makes it easier to secure the amounts of other raw materials, and more preferably 5% by mass or less.
上述した通り、卵に由来しない酵素としては、プロテアーゼを用いることが65℃超、特に食品衛生において通常必要とされる85℃以上への加熱においても固まりにくい卵黄様組成物を得る点で好ましい。
プロテアーゼとしては、その由来として、ペプシン、トリプシン、キモトリプシン、カテプシン等の動物起源の酵素、パパイン、ブロメリン、フィシン等の植物起源の酵素、サーモリシン等の各種微生物由来のプロテアーゼ等の既知の酵素が知られている。これらのプロテアーゼは構造から、セリン残基を活性中心に含むセリンプロテアーゼ(トリプシン,キモトリプシンなど),システイン残基を含むチオールプロテアーゼ(パパインなど),酸性アミノ酸を活性中心に含む酸性プロテアーゼ(ペプシンなど),補酵素として金属イオンを含む金属プロテアーゼ(サーモライシンやカルボキシペプチダーゼAなど)などに分類される。これらの酵素は1種又は2種以上組み合わせて用いることができる。
As described above, as the enzyme not derived from eggs, it is preferable to use a protease in order to obtain an egg yolk-like composition that does not easily solidify even when heated to a temperature above 65°C, particularly 85°C or higher which is usually required in terms of food hygiene.
Known proteases include enzymes of animal origin such as pepsin, trypsin, chymotrypsin, cathepsin, etc., enzymes of plant origin such as papain, bromelain, ficin, etc., and proteases of various microorganisms such as thermolysin. Based on their structure, these proteases are classified into serine proteases (trypsin, chymotrypsin, etc.) containing a serine residue in the active center, thiol proteases (papain, etc.) containing a cysteine residue, acidic proteases (pepsin, etc.) containing an acidic amino acid in the active center, and metalloproteases (thermolysin, carboxypeptidase A, etc.) containing a metal ion as a coenzyme. These enzymes can be used alone or in combination of two or more.
中でも50℃~70℃で酵素活性が高い耐熱性プロテアーゼの利用が好ましい。具体的には本製造方法で用いるプロテアーゼは至適温度が50℃~70℃であることが好ましく、55℃~65℃であることがより好ましい。 Among these, it is preferable to use a heat-resistant protease that has high enzymatic activity at 50°C to 70°C. Specifically, the optimum temperature for the protease used in this production method is preferably 50°C to 70°C, and more preferably 55°C to 65°C.
上記の観点から、微生物由来のプロテアーゼが好ましく、Bacillus属の菌体より抽出された耐熱性プロテアーゼがより好ましい。耐熱性プロテアーゼの例としては、バチルス・サブティリス(Bacillus subtilis)由来の中性プロテアーゼや、バチルス・アミロリケファシエンス(Bacillus amyloliquefaciens)由来のプロテアーゼや、バチルス・ステアロサーモフィルス(Bacillus stearothermophilus)由来のプロテアーゼ等が挙げられる。
これらのプロテアーゼの多くは至適pHが中性付近(例えばpH5.0~8.5、特にpH6.5~7.5)である金属プロテアーゼである。
From the above viewpoint, proteases derived from microorganisms are preferred, and thermostable proteases extracted from Bacillus genus bacteria are more preferred. Examples of thermostable proteases include neutral proteases derived from Bacillus subtilis, proteases derived from Bacillus amyloliquefaciens, and proteases derived from Bacillus stearothermophilus.
Many of these proteases are metalloproteases whose optimum pH is near neutral (eg, pH 5.0 to 8.5, particularly pH 6.5 to 7.5).
またプロテアーゼにはエンド型ペプチダーゼ及びエキソ型ペプチダーゼが存在するが、エンド型ペプチダーゼを用いることが目的とする加熱により凝固しにくい卵黄様組成物を得やすい点で好ましい。 Proteases include endo- and exo-peptidases, and the use of endo-peptidases is preferred in that it is easier to obtain the desired egg yolk-like composition that is less likely to coagulate when heated.
第1混合工程で用いる卵に由来しない酵素の量は、卵黄100質量部に対し0.01質量部以上であることが卵黄様組成物の加熱による凝固をより確実に防ぐ点で好ましく、0.05質量部以上であることがより好ましい。前記酵素は卵黄100質量部に対し1質量部以下であることが卵黄様組成物の変質の防止の点で好ましい。特に上記の量は前記酵素がプロテアーゼである場合に好ましい。また上記と同様の理由から第1混合工程で使用するプロテアーゼの量は、卵黄の質量1gに対し、9U以上900U以下であることが好ましく、45U以上800U以下であることがより好ましい。 The amount of the enzyme not derived from eggs used in the first mixing step is preferably 0.01 parts by mass or more per 100 parts by mass of egg yolk in order to more reliably prevent coagulation of the egg yolk-like composition due to heating, and more preferably 0.05 parts by mass or more. The amount of the enzyme is preferably 1 part by mass or less per 100 parts by mass of egg yolk in order to prevent deterioration of the egg yolk-like composition. The above amount is particularly preferred when the enzyme is a protease. For the same reasons as above, the amount of protease used in the first mixing step is preferably 9 U to 900 U per 1 g of egg yolk mass, and more preferably 45 U to 800 U.
本発明では卵黄様組成物の全原料中の水の使用量が90質量%以上であるものであり、これにより、低カロリーながら粘度が生卵黄と同様の卵黄様組成物が得られるほか、生卵黄様の透明感が得られるという利点がある。また卵黄様組成物の全原料中の水の使用量が97質量%以下であることは他の成分量を確保する点や卵黄の風味を完全に失わない点で好ましい。これらの観点から卵黄様組成物の全原料中の水の使用量は90質量%以上97質量%以下であることが好ましく、92質量%以上96質量%以下であることがより好ましい。本発明では、本製造方法のうち、特に第1混合工程において、水を多く用いることが好ましい。これは加熱時の焦げを回避できるという利点があるためである。以上の理由から第1混合工程で用いる水の量は全原料中90質量%以上97質量%以下であることが好ましく、92質量%以上96質量%以下であることがより好ましく、93質量%以上95質量%以下であることが更に好ましい。なお、上記の水の量には、卵黄等の水以外の成分に含まれる水分を含めない。 In the present invention, the amount of water used in all raw materials for the egg yolk-like composition is 90% by mass or more, which has the advantage that an egg yolk-like composition with a viscosity similar to that of raw egg yolk can be obtained while being low in calories, and that a transparency similar to that of raw egg yolk can be obtained. In addition, it is preferable that the amount of water used in all raw materials for the egg yolk-like composition is 97% by mass or less, in terms of ensuring the amount of other ingredients and not completely losing the flavor of egg yolk. From these perspectives, the amount of water used in all raw materials for the egg yolk-like composition is preferably 90% by mass or more and 97% by mass or less, and more preferably 92% by mass or more and 96% by mass or less. In the present invention, it is preferable to use a large amount of water in this production method, especially in the first mixing step. This is because there is an advantage in that scorching during heating can be avoided. For the above reasons, the amount of water used in the first mixing step is preferably 90% by mass or more and 97% by mass or less, more preferably 92% by mass or more and 96% by mass or less, and even more preferably 93% by mass or more and 95% by mass or less, of all raw materials. Note that the above amount of water does not include the moisture contained in ingredients other than water, such as egg yolk.
第1混合工程の加熱は、同工程における品温の最高温度T1として55℃以上69℃以下にまで加熱対象となる混合物を加熱することが好ましい。上記温度まで卵黄及び酵素を水の存在下で加熱することは、卵に含まれるプロテアーゼインヒビターの至適温度外でプロテアーゼを活性させるため好ましく、T1を60℃以上65℃以下とすることがより好ましい。第1混合工程の加熱速度は特に限定されないが、常温からT1までの加熱に掛ける時間は、3分以上であると蛋白質分解がより進行しやすい点で好ましい。また第1混合工程開始から第2混合工程終了までの何れかの間に、混合物の温度が55℃以上69℃以下である状態が、3分以上60分以下継続することが蛋白質分解効率及び製造効率の点で好ましく、5分以上45分以下継続することがより好ましく、更に好ましくは、5分以上30分以下継続する。 In the first mixing step, the mixture to be heated is preferably heated to a maximum product temperature T1 in the step of 55°C to 69°C. Heating the egg yolk and enzymes in the presence of water to the above temperature is preferable because it activates the protease outside the optimal temperature of the protease inhibitor contained in the egg, and it is more preferable to set T1 to 60°C to 65°C. The heating rate in the first mixing step is not particularly limited, but it is preferable that the time taken to heat from room temperature to T1 is 3 minutes or more, since protein decomposition is more likely to proceed. In addition, from the viewpoint of protein decomposition efficiency and production efficiency, it is preferable that the temperature of the mixture is 55°C to 69°C for 3 minutes to 60 minutes at any time between the start of the first mixing step and the end of the second mixing step, and it is more preferable that it is 5 minutes to 45 minutes, and even more preferably 5 minutes to 30 minutes.
第1混合工程の混合速度については特に制限はないが、例えば回転型の撹拌機である場合は10rpm~25rpmの回転数が好適な例として挙げられる。 There are no particular limitations on the mixing speed in the first mixing step, but for example, if a rotary mixer is used, a rotation speed of 10 rpm to 25 rpm is a suitable example.
本製造方法においては第1混合工程~第3混合工程のいずれかにおいて、卵黄、卵に由来しない酵素及び水を含む混合物(以下、単に「混合物」ともいう。)に澱粉以外の成分を含有させてもよい。得られる卵黄様組成物が卵黄に加えて更に色素を含有することで卵黄様組成物の色を更に生卵黄に近いものとすることができる。色素としては、カロチノイド系色素、ベニコウジ色素、ラック色素、コチニール色素、ベニバナ色素、カラメル色素、コチニール色素が挙げられる。カロチノイド系色素としては、α-カロチン、β-カロチン、γ-カロチン、カプサンチン、カプソルビン、アスタキサンチン、カンタキサンチン、ゼアキサンチン、ロドキサンチン、リコピン、クリプトキサンチン、クロセチン、クロシン、ビキシン、ノルビキシン等の化合物、ニンジン、パプリカ、クチナシ、アナトー等のカロチノイド系色素を含有する動植物の溶剤(水、アルコール、アセトン、ヘキサン等)による抽出物(例えば、ニンジンカロチン色素、パプリカ色素、クチナシ黄色素、アナトー色素等)やその合成品等が挙げられる。中でもカロチノイド系色素を用いることが生卵黄様の色調を再現できる点で好ましく、また複数種の色素を組み合わせて用いることが卵黄の色味が一層得やすい点で好ましい。特にアナトー色素及びパプリカ色素を組み合わせて用いることが卵黄に近い色味を得やすい点で好ましい。 In this production method, in any of the first to third mixing steps, the mixture containing egg yolk, enzymes not derived from eggs, and water (hereinafter simply referred to as "mixture") may contain ingredients other than starch. By containing a pigment in addition to egg yolk in the obtained egg yolk-like composition, the color of the egg yolk-like composition can be made even closer to that of raw egg yolk. Examples of pigments include carotenoid pigments, monascus pigment, lac pigment, cochineal pigment, safflower pigment, caramel pigment, and cochineal pigment. Examples of carotenoid pigments include compounds such as α-carotene, β-carotene, γ-carotene, capsanthin, capsorubin, astaxanthin, canthaxanthin, zeaxanthin, rhodoxanthin, lycopene, cryptoxanthin, crocetin, crocin, bixin, and norbixin, and extracts of animals and plants containing carotenoid pigments such as carrot, paprika, gardenia, and annatto using solvents (water, alcohol, acetone, hexane, etc.) (e.g., carrot carotene pigment, paprika pigment, gardenia yellow pigment, annatto pigment, etc.), and synthetic products thereof. Among these, the use of carotenoid pigments is preferred in that a color tone resembling that of raw egg yolk can be reproduced, and the use of a combination of multiple pigments is preferred in that the color of the egg yolk is more easily obtained. In particular, the use of a combination of annatto pigment and paprika pigment is preferred in that a color similar to that of the egg yolk is easily obtained.
第1混合工程~第3混合工程の何れかにおいて色素を添加する場合、第1混合工程において卵黄、前記酵素及び水とともに色素を混合することが混合ムラを回避する点から好ましい。また第1混合工程~第3混合工程の何れかにおいて色素を添加する場合、色素の添加量は、卵黄様組成物の全原料中、0.01質量%以上1質量%が好ましく挙げられ、0.1質量%以上0.5質量%がより好ましい。アナトー色素及びパプリカ色素を組み合せる場合には、アナトー色素100質量部に対し、パプリカ色素を1質量部以上15質量部以下が用いることが好ましく、3質量部以上10質量部以下が用いることがより好ましい。 When adding a colorant in any of the first to third mixing steps, it is preferable to mix the colorant together with the egg yolk, the enzyme, and water in the first mixing step in order to avoid uneven mixing. When adding a colorant in any of the first to third mixing steps, the amount of colorant added is preferably 0.01% to 1% by mass, and more preferably 0.1% to 0.5% by mass, of the total raw materials of the egg yolk-like composition. When combining annatto colorant and paprika colorant, it is preferable to use 1 part by mass to 15 parts by mass, and more preferably 3 parts by mass to 10 parts by mass, of paprika colorant per 100 parts by mass of annatto colorant.
また第1混合工程~第3混合工程のいずれかにおいて、混合物に更に調味料を含有させてもよい。調味料としては、塩、糖類、みりん、醸造酢、エキス類、酸味料、旨味調味料、糖類以外の甘味料などが挙げられる。糖類としては、ブドウ糖などの単糖類、ショ糖、麦芽糖、果糖などの二糖類、オリゴ糖、デキストリン、ソルビトール、マルチトール、キシリトール等の糖アルコールなどが挙げられる。糖類以外の甘味料としては、アスパルテーム、アセスルファムカリウム、スクラロース、ネオテーム、甘草抽出物、ステビアやその酵素処理物等が挙げられる。酸味料としてはクエン酸、リンゴ酸等が挙げられる。またうま味調味料としてはグルタミン酸ナトリウム等が挙げられる。エキスとしては、昆布、シイタケなどのだし、魚介エキス、鶏、豚、牛等の畜肉エキス等の各種の抽出物が挙げられる。 In addition, in any of the first to third mixing steps, the mixture may further contain a seasoning. Examples of seasonings include salt, sugars, mirin, brewed vinegar, extracts, acidulants, umami seasonings, and sweeteners other than sugars. Examples of sugars include monosaccharides such as glucose, disaccharides such as sucrose, maltose, and fructose, oligosaccharides, dextrin, and sugar alcohols such as sorbitol, maltitol, and xylitol. Examples of sweeteners other than sugars include aspartame, acesulfame potassium, sucralose, neotame, licorice extract, stevia, and enzyme-treated products thereof. Examples of acidulants include citric acid and malic acid. Examples of umami seasonings include sodium glutamate. Examples of extracts include various extracts such as dashi stock from kelp and shiitake mushrooms, seafood extracts, and meat extracts from chicken, pork, and beef.
第1混合工程~第3混合工程の何れかにおいて混合物に調味料を含有させる場合、第1混合工程において卵黄、前記酵素及び水とともに調味料を混合することが混合ムラを回避できる点から好ましい。また第1混合工程~第3混合工程の何れかにおいて調味料を添加する場合、調味料の添加量は特に制限はないが、卵黄様組成物の全原料中、0.01質量%以上15質量%以下であることが好ましく、0.05質量%以上10質量%以下であることがより好ましい。 When a seasoning is added to the mixture in any of the first to third mixing steps, it is preferable to mix the seasoning together with the egg yolk, the enzyme, and water in the first mixing step, since this can avoid uneven mixing. Furthermore, when a seasoning is added in any of the first to third mixing steps, the amount of seasoning added is not particularly limited, but is preferably 0.01% by mass to 15% by mass, and more preferably 0.05% by mass to 10% by mass, of the total raw materials of the egg yolk-like composition.
(第2混合工程)
次いで、第2混合工程について説明する。本製造方法では、第1混合工程で卵黄、卵に由来しない酵素及び水を含む混合物(以下、単に「混合物」ともいう。)に澱粉を添加せず、第2混合工程において混合物を加熱せずに混合した後、第3混合工程で澱粉を添加することに特徴の一つを有する。第1混合工程の当初から前記混合物に澱粉を含有させると、酵素反応が遅くなるという弊害がある。また、第1混合工程において加熱した状態の混合物に澱粉を添加すると、高温下で澱粉を添加することによるダマが生じてしまう。これに対し、本製造方法では、第2混合工程の通り加熱せずに混合する工程から第3混合工程にて澱粉を添加するため、澱粉添加によるダマを防止でき、生卵黄様の組成物を得ることができる。
(Second mixing step)
Next, the second mixing step will be described. One of the features of this production method is that in the first mixing step, starch is not added to a mixture containing egg yolk, non-egg-derived enzymes, and water (hereinafter, simply referred to as "mixture"), the mixture is mixed without heating in the second mixing step, and then starch is added in the third mixing step. If starch is added to the mixture from the beginning of the first mixing step, there is a drawback that the enzyme reaction is slowed down. In addition, if starch is added to a mixture in a heated state in the first mixing step, lumps will occur due to the addition of starch at a high temperature. In contrast, in this production method, starch is added from the step of mixing without heating as in the second mixing step to the third mixing step, so that lumps due to the addition of starch can be prevented and a raw egg yolk-like composition can be obtained.
第2混合工程では、第1混合工程で得られた混合物を加熱せずに混合する。加熱せずに混合するとは、熱を積極的に与えずに混合することを指し、第1混合工程の加熱による余熱が残った状態を許容するものである。第2混合工程の最低温度T2は、第1混合工程の混合物の最高温度(後述するT1)以下であることを前提として、69℃以下であることが酵素反応を進めるうえで好ましく、65℃以下であることがより好ましい。第2混合工程における混合物の最低温度T2は50℃以上であることが酵素反応を進めつつ、第3混合工程の加熱に必要なエネルギーを低減する観点から好ましく、55℃以上であることがより好ましい。 In the second mixing step, the mixture obtained in the first mixing step is mixed without heating. Mixing without heating refers to mixing without actively applying heat, and allows residual heat from the heating in the first mixing step to remain. The minimum temperature T2 in the second mixing step is preferably 69°C or less in order to advance the enzyme reaction, and more preferably 65°C or less, provided that it is equal to or less than the maximum temperature of the mixture in the first mixing step (T1 described below). The minimum temperature T2 of the mixture in the second mixing step is preferably 50°C or more in order to advance the enzyme reaction while reducing the energy required for heating in the third mixing step, and more preferably 55°C or more.
なお第2混合工程において、非加熱状態で混合を停止しないことは、酵素反応を効率的に進められるという利点がある。第2混合工程の混合は第1混合工程の混合と同じ容器又は装置内で行ってもよく、別の容器又は装置内で行ってもよい。同様に第3混合工程の混合は第2混合工程の混合と同じ容器又は装置内で行ってもよく、別の容器又は装置内で行ってもよい。 In the second mixing step, not stopping the mixing in an unheated state has the advantage of allowing the enzyme reaction to proceed efficiently. The mixing in the second mixing step may be performed in the same container or device as the mixing in the first mixing step, or may be performed in a different container or device. Similarly, the mixing in the third mixing step may be performed in the same container or device as the mixing in the second mixing step, or may be performed in a different container or device.
本製造方法は、第2混合工程後、第3混合工程を直ちに開始してもよく、第2混合工程後、第3混合工程の前に別工程、例えば第2混合工程で得られた混合物を冷却する工程を有していてもよい。後者の場合、第2混合工程では、第1混合工程で得られた混合物を冷却しなくてもよい。第2混合工程の後、第3混合工程の前に混合物を冷却させる場合、通常、静置状態または水を添加することにより混合物を冷却させる。 In the present manufacturing method, the third mixing step may be started immediately after the second mixing step, or another step may be performed after the second mixing step and before the third mixing step, for example, a step of cooling the mixture obtained in the second mixing step. In the latter case, the mixture obtained in the first mixing step does not need to be cooled in the second mixing step. When the mixture is cooled after the second mixing step and before the third mixing step, the mixture is usually cooled by leaving it to stand or by adding water.
第1混合工程における混合物の最高温度をT1とし、第1混合工程終了時点から第3混合工程開始時点までの混合物の最低温度をT2’としたときに、T2’は60℃未満であることが好ましく、57℃以下であることがより好ましい。またT2’は50℃以上であることが第3混合工程の加熱に必要なエネルギーを低減する観点から好ましく、55℃以上であることがより好ましい。
また、第1混合工程における混合物の最高温度をT1とし、第1混合工程終了時点から第3混合工程開始時点までの混合物の最低温度をT2’とした場合に、T1-T2’は5℃以上20℃以下であることが、卵黄蛋白質を効率よく分解しながら澱粉のダマを防いで、加熱による凝固が抑制され且つ粘度が生卵黄様である卵黄様組成物を首尾よく得る点で好ましく、5℃以上15℃以下であることがより好ましい。
なお、第2混合工程のT2が、上記のT2’と同様の範囲であることは製造時間を短縮しながら澱粉のダマを防ぐ点で好ましい。この観点からT2は60℃未満であることが好ましく、57℃以下であることがより好ましい。またT1-T2が5℃以上20℃以下であることが好ましく、5℃以上15℃以下であることがより好ましい。
When the maximum temperature of the mixture in the first mixing step is T1 and the minimum temperature of the mixture from the end of the first mixing step to the start of the third mixing step is T2', T2' is preferably less than 60° C., and more preferably not more than 57° C. From the viewpoint of reducing the energy required for heating in the third mixing step, T2' is preferably not less than 50° C., and more preferably not less than 55° C.
Furthermore, if the maximum temperature of the mixture in the first mixing step is T1 and the minimum temperature of the mixture from the end of the first mixing step to the start of the third mixing step is T2', T1-T2' is preferably 5°C or more and 20°C or less in order to efficiently decompose egg yolk protein while preventing starch lumps, thereby successfully obtaining an egg yolk-like composition in which coagulation due to heating is suppressed and which has a viscosity similar to that of raw egg yolk, and is more preferably 5°C or more and 15°C or less.
It is preferable that T2 in the second mixing step is in the same range as T2' described above, in order to prevent starch lumps while shortening the production time. From this viewpoint, T2 is preferably less than 60° C., and more preferably 57° C. or less. Moreover, T1-T2 is preferably 5° C. or more and 20° C. or less, and more preferably 5° C. or more and 15° C. or less.
また第2混合工程における混合速度は特に規定するものではないが、第2混合工程の混合が回転型撹拌機による場合、その回転数は、例えば10rpm以上30rpm以下であることが製造効率や製造時の飛び跳ね防止の点で好ましい。 The mixing speed in the second mixing step is not particularly specified, but if the mixing in the second mixing step is performed using a rotary mixer, the rotation speed is preferably, for example, 10 rpm or more and 30 rpm or less in terms of production efficiency and prevention of splashing during production.
(第3混合工程)
次いで、第3混合工程により、澱粉を添加し、加熱しながら第2混合工程で得られた混合物を加熱する。この工程により澱粉を糊化する。用いる澱粉としては、加工澱粉であることが、糊化温度を低下でき、これにより製造効率を高める点や、加工澱粉の有する各種の特性を卵黄様組成物に付与できる点で好ましく、中でも、澱粉を酸化プロピレンでエーテル化する処理を経た加工澱粉であることが、生卵黄様のとろみを付与できる点で好ましい。澱粉を酸化プロピレンでエーテル化する処理を経た加工澱粉としては、ヒドロキシプロピル澱粉、ヒドロキシプロピル化リン酸架橋澱粉等が挙げられる。特にヒドロキシプロピル化リン酸架橋澱粉を用いることが生卵黄様のとろみを付与できる点で好ましい。ヒドロキシプロピル化リン酸架橋澱粉は、糊化開始温度が低く、耐熱性や冷凍耐性、耐せん断性、耐酸性などに優れるため、卵黄様組成物を種々の形態で用いることができる点でも好ましい。
(Third mixing step)
Next, in the third mixing step, starch is added, and the mixture obtained in the second mixing step is heated while being heated. In this step, the starch is gelatinized. The starch used is preferably a processed starch, since it can lower the gelatinization temperature, thereby increasing the production efficiency, and can impart various properties of the processed starch to the egg yolk-like composition. In particular, processed starch that has undergone a process of etherification with propylene oxide is preferable, since it can impart a raw egg yolk-like viscosity. Examples of processed starch that has undergone a process of etherification with propylene oxide include hydroxypropyl starch and hydroxypropylated phosphate cross-linked starch. In particular, the use of hydroxypropylated phosphate cross-linked starch is preferable, since it can impart a raw egg yolk-like viscosity. Hydroxypropylated phosphate cross-linked starch has a low gelatinization onset temperature and is excellent in heat resistance, freezing resistance, shear resistance, acid resistance, etc., and is therefore also preferable, since the egg yolk-like composition can be used in various forms.
第2混合工程における澱粉の添加量は、卵黄様組成物の全原料中、1質量%以上7質量%以下であることが、生卵黄様の粘度を得る点で好ましく、2質量%以上5質量%以下であることが、より好ましい。 The amount of starch added in the second mixing step is preferably 1% by mass or more and 7% by mass or less of the total raw materials of the egg yolk-like composition in order to obtain a viscosity similar to that of raw egg yolk, and more preferably 2% by mass or more and 5% by mass or less.
第3混合工程において澱粉を添加する温度は加熱開始前又は加熱開始と同時、或いは混合物の温度における第2混合工程の最低温度T2からの温度差が10℃未満の範囲であることが、澱粉のダマを一層確実に防ぐ点で好ましい。 In order to more reliably prevent starch lumps, it is preferable to add the starch in the third mixing step before or simultaneously with the start of heating, or to set the temperature of the mixture so that the temperature difference from the lowest temperature T2 in the second mixing step is less than 10°C.
第3混合工程において、澱粉を添加した混合物の温度が75℃以上となるまで加熱することが、澱粉を効率よく糊化させる点、及び衛生的な製造の点で好ましく、80℃以上となるまで加熱することが、より一層好ましく、85℃以上となるまで加熱することが更に一層好ましい。また、第3混合工程において、澱粉を添加した混合物の温度は95℃以上でも問題ないが、95℃以下であることが、釜への焦げ付き防止の点で好ましく、90℃以下であることがより好ましい。 In the third mixing step, it is preferable to heat the mixture to which the starch has been added until the temperature reaches 75°C or higher in terms of efficient gelatinization of the starch and hygienic production, and it is even more preferable to heat it until the temperature reaches 80°C or higher, and it is even more preferable to heat it until the temperature reaches 85°C or higher. In the third mixing step, the temperature of the mixture to which the starch has been added can be 95°C or higher without any problems, but it is preferable that the temperature be 95°C or lower in terms of preventing the mixture from burning in the pot, and it is even more preferable that the temperature be 90°C or lower.
第3混合工程における混合物の最高温度T3と第2混合工程における混合物の最低温度T2との差T3-T2は25℃以上45℃以下であることが、生卵黄に近い粘度が得やすい点及び効率的な製造の点で好ましく、25℃以上35℃以下であることがより好ましい。 The difference T3-T2 between the maximum temperature T3 of the mixture in the third mixing step and the minimum temperature T2 of the mixture in the second mixing step is preferably 25°C or more and 45°C or less, in terms of making it easier to obtain a viscosity close to that of raw egg yolk and for efficient production, and more preferably 25°C or more and 35°C or less.
また第3混合工程における加熱速度に特に制限はないが、例えば75℃以上の状態が3分以上継続することが澱粉を確実に糊化しやすい点で好ましく、75℃以上の状態が5分以上継続することがより好ましい。また、特に好ましくは80℃以上の状態が5分以上継続することで、澱粉が確実に糊化しやすく食品衛生上の点等から好ましい。80℃以上の温度の継続時間に特に制限はないが、例えば45分以下であると製造効率がよいため好ましい。 There is no particular restriction on the heating rate in the third mixing step, but for example, maintaining a temperature of 75°C or higher for 3 minutes or more is preferred in terms of ensuring gelatinization of the starch, and maintaining a temperature of 75°C or higher for 5 minutes or more is even more preferred. It is particularly preferred to maintain a temperature of 80°C or higher for 5 minutes or more, which ensures gelatinization of the starch and is preferred from the standpoint of food hygiene, etc. There is no particular restriction on the duration of the temperature at 80°C or higher, but for example, 45 minutes or less is preferred in terms of production efficiency.
また第3混合工程における撹拌速度は特に規定するものではないが、第3混合工程の混合が回転型の撹拌機による場合、その回転数は、例えば10rpm以上30rpm以下であることが製造効率や適度な粘度が得やすい点で好ましく、20rpm以上25rpm以下であることがより好ましい。 The stirring speed in the third mixing step is not particularly specified, but if the mixing in the third mixing step is performed using a rotary stirrer, the rotation speed is preferably, for example, 10 rpm or more and 30 rpm or less in terms of production efficiency and ease of obtaining a suitable viscosity, and more preferably 20 rpm or more and 25 rpm or less.
第3混合工程にて得られた混合物は、篩を通して加熱によるダマ・焦げ付きを除くことが好ましい。その際の篩の目開きとしては、100μm以上500μm以下であることが操作効率及び得られる篩下品の品質の点で好ましく、100μm以上400μm以下であることがより好ましい。 The mixture obtained in the third mixing step is preferably passed through a sieve to remove lumps and burnt parts caused by heating. In this case, the mesh size of the sieve is preferably 100 μm or more and 500 μm or less in terms of operational efficiency and the quality of the undersized product obtained, and more preferably 100 μm or more and 400 μm or less.
以上の第1混合工程~第3混合工程及び必要に応じて行われる上記篩通しの工程により卵黄様組成物が得られる。 The egg yolk-like composition is obtained by the above first to third mixing steps and the above sieving step, which is performed as necessary.
次いで本発明の卵黄様組成物について説明する。本発明の卵黄様組成物の説明には、上記の卵黄様組成物の製造方法の説明について適用できる点は適宜適用可能である。逆に以下の卵黄様組成物の説明は、本発明の卵黄様組成物の製造方法の説明に適宜適用できる。 Next, the egg yolk-like composition of the present invention will be described. The points applicable to the above description of the method for producing an egg yolk-like composition can be appropriately applied to the description of the egg yolk-like composition of the present invention. Conversely, the following description of the egg yolk-like composition can be appropriately applied to the description of the method for producing an egg yolk-like composition of the present invention.
本発明の卵黄様組成物は、卵黄、卵に由来しない酵素、澱粉及び水を含有し、30℃における粘度が100mPa・s以上1000mPa・s以下である。当該構成の本発明の卵黄様組成物は生卵黄様の粘度及び色を有する。卵黄、前記の酵素、澱粉としては前記の卵黄様組成物の製造方法の説明において上述したものを用いることができる。また卵黄様組成物のおける卵黄の好ましい量としては、粘度及び色として生卵黄様とする点から上述した全原料中の卵黄の好ましい量と同様とすることができ、具体的には1質量%以上10質量%以下であることが好ましく、2質量%以上5質量%以下であることがより好ましい。
また卵に由来しない酵素の好ましい量としては、上述した第1混合工程で用いる卵黄に対する好ましい量と同様の量とすることができる。
The egg yolk-like composition of the present invention contains egg yolk, an enzyme not derived from an egg, starch and water, and has a viscosity at 30°C of 100 mPa·s or more and 1000 mPa·s or less. The egg yolk-like composition of the present invention having such a composition has a viscosity and color similar to that of raw egg yolk. As the egg yolk, the enzyme and the starch, those mentioned above in the explanation of the method for producing the egg yolk-like composition can be used. Furthermore, the preferred amount of egg yolk in the egg yolk-like composition can be the same as the preferred amount of egg yolk in all the raw materials mentioned above in terms of achieving a viscosity and color similar to that of raw egg yolk, and specifically, it is preferably 1% by mass or more and 10% by mass or less, and more preferably 2% by mass or more and 5% by mass or less.
The preferred amount of the enzyme not derived from an egg may be the same as the preferred amount for the egg yolk used in the first mixing step described above.
卵黄様組成物における水の量としては、低カロリーとしながら粘度及び色を生卵黄様とする点から上記全原料中の水の好ましい量と同様の量又はそれに近似した量とすることができ、例えば90質量%以上97質量%以下が好ましく、92質量%以上96質量%以下がより好ましく、93質量%以上95質量%以下が特に好ましい。 The amount of water in the egg yolk-like composition can be the same as or close to the preferred amount of water in all the ingredients listed above, in order to achieve a viscosity and color similar to that of raw egg yolk while being low in calories. For example, 90% by mass or more and 97% by mass or less is preferred, 92% by mass or more and 96% by mass or less is more preferred, and 93% by mass or more and 95% by mass or less is particularly preferred.
卵黄様組成物における澱粉の好ましい量としては、粘度及び色を生卵黄様とする点から上述した全原料中の澱粉の好ましい量と同様の量とすることができ、具体的には1質量%以上7質量%以下であることが好ましく、2質量%以上5質量%以下であることがより好ましい。 The preferred amount of starch in the egg yolk-like composition can be the same as the preferred amount of starch in all the ingredients described above in terms of achieving a viscosity and color similar to that of raw egg yolk, and more specifically, it is preferably 1% by mass or more and 7% by mass or less, and more preferably 2% by mass or more and 5% by mass or less.
更に卵黄様組成物には色素を任意で添加可能であり、当該色素としては上記と同様に卵黄様組成物の製造方法で好ましいものとして挙げたものと同様の物が挙げられる。卵黄様組成物における色素の好ましい量としては、卵黄様組成物に全原料中の色素の好ましい量と同様の量が挙げられ、具体的には0.01質量%以上1質量%以下であることが好ましく、0.1質量%以上0.5質量%以下であることがより好ましい。また2種以上の色素を含有する場合の当該色素の比率としても上記で挙げた比率が挙げられる。 Furthermore, a pigment can be added to the egg yolk-like composition as desired, and examples of such pigments include those listed as preferred in the method for producing an egg yolk-like composition as described above. A preferred amount of pigment in the egg yolk-like composition is the same as the preferred amount of pigment in all raw materials in the egg yolk-like composition, and more preferably 0.01% by mass or more and 1% by mass or less, and more preferably 0.1% by mass or more and 0.5% by mass or less. When two or more types of pigments are contained, the ratio of the pigments can also be the ratio listed above.
更に卵黄様組成物には調味料を任意で添加可能であり、当該調味料としては卵黄様組成物の製造方法で好ましいものとして上記で挙げたものと同様の物が挙げられる。卵黄様組成物における調味料の好ましい量としては、卵黄様組成物に全原料中の調味料の好ましい量と同様の量が挙げられ、具体的には0.01質量%以上15質量%以下であることが好ましく、0.05質量%以上10質量%以下であることがより好ましい。 Furthermore, seasonings can be added to the egg yolk-like composition as desired, and examples of such seasonings include those listed above as preferred in the method for producing an egg yolk-like composition. Preferred amounts of seasonings in the egg yolk-like composition include amounts similar to the preferred amounts of seasonings in all ingredients, and specifically, the amount is preferably 0.01% by mass or more and 15% by mass or less, and more preferably 0.05% by mass or more and 10% by mass or less.
卵黄様組成物は、水、卵に由来しない酵素、澱粉、任意成分である調味料及び色素に加え、他の成分を含有していてもよい。当該他の成分の量としては、好ましくは合計で卵黄様組成物中、5質量%以下であることが好ましく、3質量%以下であることがより好ましく、1質量%以下であることが特に好ましい。例えば卵黄様組成物は、澱粉に加えて寒天やキサンタンガム等の増粘多糖類やゼラチンなどをゲル化剤又は増粘剤を適宜含有していてもよい。その場合、澱粉以外の増粘剤及びゲル化剤の量は、特に限定するものではないが、例えば合計で澱粉に対する量が100質量%以下であることがそれらのゲル化剤や増粘剤を用いずに生卵黄様の粘度が得られる効果に一層優れる点で好ましく、50質量%以下であることがより好ましい。 The egg yolk-like composition may contain other ingredients in addition to water, enzymes not derived from eggs, starch, and optional seasonings and colorants. The amount of the other ingredients is preferably 5% by mass or less in total in the egg yolk-like composition, more preferably 3% by mass or less, and particularly preferably 1% by mass or less. For example, the egg yolk-like composition may contain gelling agents or thickeners such as thickening polysaccharides such as agar and xanthan gum, gelatin, etc. in addition to starch. In this case, the amount of thickeners and gelling agents other than starch is not particularly limited, but for example, the total amount relative to starch is preferably 100% by mass or less, in terms of being more effective in obtaining a viscosity similar to that of raw egg yolk without using those gelling agents or thickeners, and more preferably 50% by mass or less.
卵黄様組成物は、30℃における粘度が100mPa・s以上1000mPa・s以下であり生卵黄様の物性を有していることが好ましい。より好ましくは、卵黄様組成物の30℃における粘度は150mPa・s以上800mPa・s以下であり、より好ましくは200mPa・s以上500mPa・s以下である。
更に卵黄様組成物は、冷却時及び/又は加熱時の粘度についても生卵黄様であることが好ましく、10℃における粘度が300mPa・s以上1300mPa・s以下であることが好ましく、400mPa・s以上800mPa・s以下であることがより好ましい。また50℃における粘度が80mPa・s以上500mPa・s以下であることが好ましく、100mPa・s以上300mPa・s以下であることがより好ましい。卵黄様組成物の粘度は後述する実施例に記載の方法にて測定できる。
The egg yolk-like composition preferably has a viscosity of 100 mPa·s or more and 1000 mPa·s or less at 30° C. and has physical properties similar to those of raw egg yolk. More preferably, the viscosity of the egg yolk-like composition at 30° C. is 150 mPa·s or more and 800 mPa·s or less, and more preferably 200 mPa·s or more and 500 mPa·s or less.
Furthermore, the egg yolk-like composition preferably has a viscosity similar to that of raw egg yolk when cooled and/or heated, and the viscosity at 10° C. is preferably from 300 mPa·s to 1,300 mPa·s, and more preferably from 400 mPa·s to 800 mPa·s. The viscosity at 50° C. is preferably from 80 mPa·s to 500 mPa·s, and more preferably from 100 mPa·s to 300 mPa·s. The viscosity of the egg yolk-like composition can be measured by the method described in the Examples below.
卵黄様組成物は、L*a*b*表色系に基づくL*値が50以上60以下であり、a*が、15以上25以下であり、b*値が、65以上80以下であることが、生卵黄様の色調に一層優れる点で好ましい。生卵黄様の色味を更に一層高める点から、L*a*b*表色系に基づくL*値は52以上58以下であることがより好ましい。またa*値が、17以上23以下であることがより好ましい。更にb*値が、70以上75以下であることがより好ましい。 The egg yolk-like composition preferably has an L* value based on the L*a*b* color system of 50 or more and 60 or less, an a* value of 15 or more and 25 or less, and a b* value of 65 or more and 80 or less, in terms of achieving a better raw egg yolk-like color tone. In terms of further enhancing the raw egg yolk-like color tone, it is more preferable that the L* value based on the L*a*b* color system is 52 or more and 58 or less. It is also more preferable that the a* value is 17 or more and 23 or less. It is even more preferable that the b* value is 70 or more and 75 or less.
本発明による卵黄様組成物は、生卵黄様の色及び粘度を有するとともに水分を多く含み低カロリーである。本発明による卵黄様組成物は、ソース、ドレッシングや、親子丼、オムレツ、オムライス、かつ丼などの卵含有食品における卵黄代替品、うどん、パスタ、サラダ、唐揚げ、フライ、パン等の惣菜のトッピング、中華まん、おむすびの具等、種々の用途に使用できる。 The egg yolk-like composition according to the present invention has a color and viscosity similar to that of raw egg yolk, contains a lot of water, and is low in calories. The egg yolk-like composition according to the present invention can be used in a variety of applications, including sauces, dressings, egg substitutes in egg-containing foods such as oyakodon, omelets, omelet rice, and katsudon, toppings for side dishes such as udon, pasta, salads, fried chicken, fries, and bread, and as a filling for Chinese steamed buns and rice balls.
(実施例1)
<第1混合工程>
釜に、凍結卵黄2質量部、食塩0.15質量部、水95質量部、アナトー色素0.3質量部、パプリカ色素0.02質量部及びプロテアーゼ(至適温度が55℃~65℃、至適pHが6.5~7.5であるバチルス属細菌由来のエンド型金属プロテアーゼ)0.0015質量部(卵黄の質量1gにつき67.5U)を入れて加熱しながら13rpmにて混合した。この工程において、品温を常温(25℃)から3分以上30分以下の時間をかけて60℃まで昇温させて、加熱を止めた。
<第2混合工程>
加熱を止めた状態で、第1混合工程で得られた混合物を13rpmにて混合し、55℃まで品温を下げた。第1混合工程開始から第2混合工程終了までの間における品温が55℃以上69℃以下であった継続時間は5分以上30分以下の範囲内とした。
<第3混合工程>
第2混合工程で得られた混合物に加工澱粉(ヒドロキシプロピル化リン酸架橋澱粉)を3質量部加えて再び釜を加熱しながら13rpmにて混合し、85℃にまで昇温した。80℃以上の継続時間は5分以上45分以下の範囲内とした。
得られた混合物について、水合わせとして蒸発分の水を加えた後、目開き212μmの網目を通して透過物を卵黄様組成物として得た。
Example 1
<First mixing step>
2 parts by mass of frozen egg yolk, 0.15 parts by mass of salt, 95 parts by mass of water, 0.3 parts by mass of annatto colorant, 0.02 parts by mass of paprika colorant, and 0.0015 parts by mass (67.5 U per 1 g of egg yolk mass) of protease (an endo-type metalloprotease derived from Bacillus bacteria having an optimum temperature of 55° C. to 65° C. and an optimum pH of 6.5 to 7.5) were placed in a kettle and mixed at 13 rpm while heating. In this process, the product temperature was raised from room temperature (25° C.) to 60° C. over a period of 3 to 30 minutes, and then heating was stopped.
<Second mixing step>
With the heating turned off, the mixture obtained in the first mixing step was mixed at 13 rpm and the product temperature was lowered to 55° C. The duration during which the product temperature was 55° C. or higher and 69° C. or lower from the start of the first mixing step to the end of the second mixing step was set to be within the range of 5 minutes to 30 minutes.
<Third mixing step>
To the mixture obtained in the second mixing step, 3 parts by mass of processed starch (hydroxypropylated phosphate cross-linked starch) was added, and the mixture was mixed again at 13 rpm while heating the kettle, and the temperature was raised to 85° C. The duration of the temperature at 80° C. or higher was set to be within a range of 5 to 45 minutes.
The mixture thus obtained was mixed with water equivalent to the amount of evaporated water, and then passed through a mesh having an opening of 212 μm to obtain a permeate as an egg yolk-like composition.
得られた実施例1の卵黄様組成物について、10℃、20℃、30℃、40℃及び50℃それぞれにおける粘度を測定した。粘度はVISCOMETER TV-25(東機産業)を用い、回転速度50rpm、治具HH1の条件で測定した。得られた粘度を下記表1に示す。なお、表1には生卵黄について同様に粘度を測定した結果を合わせて示す。
更に、得られた卵黄様組成物について、色差計(コニカミノルタ社製色彩色差計CR-5)を用い、常温(25℃)でのL*値、a*値及びb*値を測定した。その結果を表2に示す。また図1には得られたL*値、a*値及びb*値に基づき、L*値を円の大きさとしたときの実施例1の卵黄様組成物と生卵黄との関係を示すグラフを記載する。
The viscosities of the obtained egg yolk-like composition of Example 1 were measured at 10°C, 20°C, 30°C, 40°C and 50°C. The viscosity was measured using a VISCOMETER TV-25 (Toki Sangyo Co., Ltd.) at a rotation speed of 50 rpm and a jig HH1. The obtained viscosities are shown in Table 1 below. Table 1 also shows the results of similar viscosity measurements of raw egg yolk.
Furthermore, the L* value, a* value and b* value of the obtained egg yolk-like composition were measured at room temperature (25° C.) using a color difference meter (Konica Minolta CR-5 color difference meter). The results are shown in Table 2. Also, Figure 1 shows a graph showing the relationship between the egg yolk-like composition of Example 1 and raw egg yolk, when the L* value is expressed as the size of a circle, based on the obtained L* value, a* value and b* value.
表1より、実施例1で得られた卵黄様組成物が生卵黄と10~50℃の粘度が同様であることが判る。また表2及び図1より、実施例1で得られた卵黄様組成物について、生卵黄と色味が同様であることが判る。 From Table 1, it can be seen that the egg yolk-like composition obtained in Example 1 has a similar viscosity at 10 to 50°C as raw egg yolk. In addition, from Table 2 and Figure 1, it can be seen that the egg yolk-like composition obtained in Example 1 has a similar color to raw egg yolk.
Claims (8)
前記第1混合工程を経た混合物に対して、加熱せずに、混合する第2混合工程と、
前記第2混合工程を経た混合物に対して、澱粉を添加し、加熱しながら、混合する第3混合工程と、を有し、
全原料中、水を90質量%以上97質量%以下用いる、卵黄様組成物の製造方法。 A first mixing step of mixing egg yolk, a protease not derived from an egg, and water while heating;
a second mixing step of mixing the mixture obtained in the first mixing step without heating;
A third mixing step of adding starch to the mixture that has been subjected to the second mixing step and mixing the mixture while heating,
A method for producing an egg yolk-like composition, comprising using water at 90% by mass or more and 97% by mass or less of all raw materials.
前記第1混合工程を経た混合物を第3混合工程の開始までに60℃未満まで冷却する請求項1又は2に記載の卵黄様組成物の製造方法。 In the first mixing step, a mixture containing egg yolk, the protease and water is heated to 60° C. or higher;
3. The method for producing an egg yolk-like composition according to claim 1, wherein the mixture after the first mixing step is cooled to less than 60° C. before the start of the third mixing step.
30℃における粘度が100mPa・s以上1000mPa・s以下である卵黄様組成物を製造する、請求項1に記載の卵黄様組成物の製造方法。 Contains egg yolk, non-egg-derived protease , starch and water;
The method for producing an egg yolk-like composition according to claim 1, wherein the produced egg yolk-like composition has a viscosity at 30°C of 100 mPa·s or more and 1000 mPa·s or less.
L*値が、50以上60以下、
a*値が、15以上25以下、
b*値が、65以上80以下、である卵黄様組成物を製造する、請求項7に記載の卵黄様組成物の製造方法。 Based on the L*a*b* color system,
The L* value is 50 or more and 60 or less,
a* value is 15 or more and 25 or less,
The method for producing an egg yolk-like composition according to claim 7, wherein the produced egg yolk-like composition has a b* value of 65 or more and 80 or less.
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| JP2000217552A (en) | 1999-02-01 | 2000-08-08 | Nichirei Corp | Composition for frozen egg processed food, method for producing the same, and frozen egg processed food |
| JP2002325559A (en) | 2001-05-01 | 2002-11-12 | Knorr Foods Co Ltd | Processed egg food and method for producing the same |
| JP2005052124A (en) | 2003-08-07 | 2005-03-03 | Q P Corp | Heat-coagulated egg yolk and processed food using the same |
| JP2005052052A (en) | 2003-08-04 | 2005-03-03 | Asahi Denka Kogyo Kk | Method for producing enzyme-treated egg yolk |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000217552A (en) | 1999-02-01 | 2000-08-08 | Nichirei Corp | Composition for frozen egg processed food, method for producing the same, and frozen egg processed food |
| JP2002325559A (en) | 2001-05-01 | 2002-11-12 | Knorr Foods Co Ltd | Processed egg food and method for producing the same |
| JP2005052052A (en) | 2003-08-04 | 2005-03-03 | Asahi Denka Kogyo Kk | Method for producing enzyme-treated egg yolk |
| JP2005052124A (en) | 2003-08-07 | 2005-03-03 | Q P Corp | Heat-coagulated egg yolk and processed food using the same |
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