JP7590139B2 - Method for producing sauce, method for glaze-finishing sauce and method for producing sauce - Google Patents
Method for producing sauce, method for glaze-finishing sauce and method for producing sauce Download PDFInfo
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- 235000015067 sauces Nutrition 0.000 title claims description 198
- 238000000034 method Methods 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 166
- 229930195729 fatty acid Natural products 0.000 claims description 166
- 239000000194 fatty acid Substances 0.000 claims description 166
- 239000003995 emulsifying agent Substances 0.000 claims description 141
- 239000000203 mixture Substances 0.000 claims description 106
- -1 fatty acid ester Chemical class 0.000 claims description 86
- 150000004665 fatty acids Chemical class 0.000 claims description 81
- 239000000470 constituent Substances 0.000 claims description 62
- 125000004432 carbon atom Chemical group C* 0.000 claims description 49
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 48
- 229920000223 polyglycerol Polymers 0.000 claims description 44
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 42
- 230000032050 esterification Effects 0.000 claims description 36
- 238000005886 esterification reaction Methods 0.000 claims description 36
- 125000005480 straight-chain fatty acid group Chemical group 0.000 claims description 32
- 238000006116 polymerization reaction Methods 0.000 claims description 27
- 235000021357 Behenic acid Nutrition 0.000 claims description 21
- 229940116226 behenic acid Drugs 0.000 claims description 21
- 240000008415 Lactuca sativa Species 0.000 claims description 15
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- 238000005498 polishing Methods 0.000 claims description 7
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 6
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 6
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- 239000003925 fat Substances 0.000 description 94
- 235000019197 fats Nutrition 0.000 description 93
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- 230000000694 effects Effects 0.000 description 20
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- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 8
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- 239000007788 liquid Substances 0.000 description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 7
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- 239000008117 stearic acid Substances 0.000 description 7
- 239000002932 luster Substances 0.000 description 6
- 235000013555 soy sauce Nutrition 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 5
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- 238000007127 saponification reaction Methods 0.000 description 5
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- 238000000576 coating method Methods 0.000 description 4
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- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
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- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
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- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
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- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 2
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- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
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- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- SFUVLEGIZGPPNN-UHFFFAOYSA-N (2-pyridin-2-ylacetyl) 2-pyridin-2-ylacetate Chemical compound C=1C=CC=NC=1CC(=O)OC(=O)CC1=CC=CC=N1 SFUVLEGIZGPPNN-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- PHDVPEOLXYBNJY-KTKRTIGZSA-N 2-(2-hydroxyethoxy)ethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCOCCO PHDVPEOLXYBNJY-KTKRTIGZSA-N 0.000 description 1
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- 240000002791 Brassica napus Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 1
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
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- 235000019864 coconut oil Nutrition 0.000 description 1
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- 230000006866 deterioration Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical group OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
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- 230000002708 enhancing effect Effects 0.000 description 1
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Landscapes
- Edible Oils And Fats (AREA)
- Seeds, Soups, And Other Foods (AREA)
Description
本発明は、ソースの製造方法、ソースの艶だし方法及びソースに関する。 The present invention relates to a method for producing sauce, a method for glaze-making a sauce, and a sauce.
艶(光沢)を有する食品は食欲をそそる。また、食品の艶は、劣化とも相関があるとの認識があるため、艶を長期間維持することで食品の商品価値を高めることができる。 Foods that have a glossy finish are appetizing. In addition, it is believed that the gloss of food is correlated with deterioration, so maintaining the gloss for a long period of time can increase the commercial value of the food.
例えば、特許文献1には、食品に対する付着性を有し、冷蔵保存時も表面の光沢が保持される香味油を提供するために、構成脂肪酸として炭素数16~22の飽和脂肪酸と炭素数16~22の不飽和脂肪酸の構成脂肪酸のモル比率が0.3~0.9:0.1~0.7のポリグリセリン脂肪酸エステルを用いた香味油が提案されている。 For example, Patent Document 1 proposes a flavor oil that uses a polyglycerol fatty acid ester in which the constituent fatty acids are saturated fatty acids with 16 to 22 carbon atoms and unsaturated fatty acids with 16 to 22 carbon atoms in a molar ratio of 0.3 to 0.9:0.1 to 0.7, in order to provide a flavor oil that adheres to food and retains its surface gloss even when stored in a refrigerator.
しかし、特許文献1の方法は、固形状の食品表面をコーティングすることで食品への艶の付与を達成することを想定したものであるが、ソースのように液体あるいはペースト状であり、表面に水相がある食品の場合、コーティングした油滴が集合(合一)して大きな油滴のある表面と油滴の少ない表面が混在するようになり、艶(光沢)のある十分な表面積を得ることができなくなる。さらに、コーティングする方法は、食品に上掛けされるソースの場合、食品にソースを上掛けした後にスプレー等で艶出し剤をコーティングする工程が必要になり、さらに、食品の凹凸によりコーティングした艶出し成分が流れることで、艶が維持できない問題もあった。
本発明の課題は、艶を有するソースの製造方法、容易にソースの艶を出す方法、及び艶を有するソースを提供することである。
However, the method of Patent Document 1 is intended to impart gloss to food by coating the surface of solid food, but in the case of liquid or paste-like foods such as sauces that have an aqueous phase on the surface, the coated oil droplets gather (coalesce) to form a mixture of surfaces with large oil droplets and surfaces with few oil droplets, making it impossible to obtain a sufficient glossy (shiny) surface area. Furthermore, in the case of sauces to be poured on top of food, the coating method requires a step of coating the food with a glossing agent by spray or the like after the sauce has been poured on top, and there is also the problem that the gloss cannot be maintained because the coated glossing component flows away due to the unevenness of the food.
An object of the present invention is to provide a method for producing a glossy sauce, a method for easily imparting gloss to a sauce, and a glossy sauce.
本発明者らは、鋭意検討を行った結果、油脂と特定の乳化剤を含有する油脂組成物をソースに配合することで、上記の課題を解決することを見出し、本発明を完成させた。 As a result of intensive research, the inventors discovered that the above problems could be solved by blending an oil composition containing an oil and a specific emulsifier into a sauce, and thus completed the present invention.
すなわち、本発明は、下記の[1]~[11]を提供する。
[1] 油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)の製造方法であって、
下記の乳化剤A1を0.5~8.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
又は、下記の乳化剤A2を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
ソースの製造方法。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル
[2] 前記油脂組成物が、乳化剤A1を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有するものである、
[1]のソースの製造方法。
[3] 前記乳化剤Bが、構成脂肪酸の20質量%以上がベヘン酸であり、構成脂肪酸の50質量%未満が不飽和脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルである、
[1]又は[2]のソースの製造方法。
[4] 前記油脂組成物の25℃における粘度が100~3000mPa・sである、
[1]~[3]のいずれかのソースの製造方法。
[5] 油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)の艶だし方法であって、
下記の乳化剤A1を0.5~8.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
又は、下記の乳化剤A2を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
ソースの艶だし方法。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル
[6] 前記油脂組成物が、乳化剤A1を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有するものである、
[5]のソースの艶だし方法。
[7] 前記乳化剤Bが、構成脂肪酸の20質量%以上がベヘン酸であり、構成脂肪酸の50質量%未満が不飽和脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルである、
[5]又は[6]のソースの艶だし方法。
[8] 前記油脂組成物の25℃における粘度が100~3000mPa・sである、
[5]~[8]のいずれか1項に記載のソースの艶だし方法。
[9] 油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)であって、
油脂組成物をソース中に0.5~12質量%含有し、
該油脂組成物が、下記の乳化剤A1を0.5~8.0質量%、又は乳化剤A2を0.5~8.0質量%と乳化剤Bを0.03~2.0質量%含有する、
ソース。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル
[10] 前記油脂組成物が、乳化剤A1を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有するものである、
[9]に記載のソース。
[11] ソース中に前記油脂組成物が分散しているものである、
[9]又は[10]のソース。
That is, the present invention provides the following [1] to [11].
[1] A method for producing a sauce having an oil and fat content of 25% by mass or less (excluding sauce for salads), comprising the steps of:
An oil and fat composition containing 0.5 to 8.0% by mass of the following emulsifier A1 is mixed into the sauce so that the emulsifier A1 is contained in an amount of 0.5 to 12% by mass.
Alternatively, an oil and fat composition containing 0.5 to 8.0% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B is mixed into the sauce so that the oil and fat composition contains 0.5 to 12% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B.
Method of producing sauce.
(Emulsifier A1) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is 1.5 to 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier A2) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is more than 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier B) A polyglycerin fatty acid ester and/or glycerin fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated linear fatty acids having 16 to 22 carbon atoms.
[2] The oil and fat composition contains 0.5 to 8.0% by mass of emulsifier A1 and 0.03 to 2.0% by mass of emulsifier B.
[1] Manufacturing method of the sauce.
[3] The emulsifier B is a polyglycerol fatty acid ester and/or a glycerol fatty acid ester, in which 20% by mass or more of the constituent fatty acids are behenic acid and less than 50% by mass of the constituent fatty acids are unsaturated fatty acids.
A method for producing the sauce of [1] or [2].
[4] The viscosity of the oil composition at 25°C is 100 to 3000 mPa·s,
A method for producing any one of the sauces [1] to [3].
[5] A method for polishing a sauce having an oil and fat content of 25% by mass or less (excluding sauces for salads), comprising the steps of:
An oil and fat composition containing 0.5 to 8.0% by mass of the following emulsifier A1 is mixed into the sauce so that the emulsifier A1 is contained in an amount of 0.5 to 12% by mass.
Alternatively, an oil and fat composition containing 0.5 to 8.0% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B is mixed into the sauce so that the oil and fat composition contains 0.5 to 12% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B.
How to deglaze the sauce.
(Emulsifier A1) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is 1.5 to 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier A2) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is more than 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier B) A polyglycerin fatty acid ester and/or glycerin fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated linear fatty acids having 16 to 22 carbon atoms.
[6] The oil and fat composition contains 0.5 to 8.0% by mass of emulsifier A1 and 0.03 to 2.0% by mass of emulsifier B.
[5] How to make the sauce glossy.
[7] The emulsifier B is a polyglycerol fatty acid ester and/or a glycerol fatty acid ester, in which 20% by mass or more of the constituent fatty acids are behenic acid and less than 50% by mass of the constituent fatty acids are unsaturated fatty acids.
[5] or [6] How to make the sauce glossy.
[8] The viscosity of the oil composition at 25°C is 100 to 3000 mPa·s,
A method for polishing a sauce according to any one of [5] to [8].
[9] A sauce having an oil and fat content of 25% by mass or less (excluding sauces for salads),
The oil and fat composition is contained in the sauce in an amount of 0.5 to 12% by mass,
The oil and fat composition contains 0.5 to 8.0 mass% of the following emulsifier A1, or 0.5 to 8.0 mass% of the following emulsifier A2 and 0.03 to 2.0 mass% of the following emulsifier B,
sauce.
(Emulsifier A1) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is 1.5 to 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier A2) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is more than 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier B) A polyglycerin fatty acid ester and/or glycerin fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated linear fatty acids having 16 to 22 carbon atoms.
[10] The oil and fat composition contains 0.5 to 8.0% by mass of emulsifier A1 and 0.03 to 2.0% by mass of emulsifier B.
Source: [9]
[11] The oil and fat composition is dispersed in a sauce.
Source of [9] or [10].
本発明のソースの製造方法を用いることで、艶(光沢)のあるソースを得ることができる。また、ソースの艶だし方法を用いることで、コーティング工程を経ずに簡便にソース表面に艶(光沢)が発生する。また、本発明のソースは、艶(光沢)があり、ソース中に光沢成分となる油脂組成物が分散しており、仮にソース表面の流動性によりソース表面の油脂組成物が流れても、ソース中から油脂組成物が供給されるので、艶も長期間維持できる。 By using the method for producing sauce of the present invention, it is possible to obtain a glossy sauce. In addition, by using the method for polishing a sauce, a glossy surface can be easily generated without a coating process. In addition, the sauce of the present invention has a glossy surface, and an oil and fat composition that serves as a gloss component is dispersed in the sauce. Even if the oil and fat composition on the surface of the sauce flows due to the fluidity of the sauce surface, the oil and fat composition is supplied from within the sauce, so the gloss can be maintained for a long period of time.
以下、本発明について詳細に例示説明する。なお、本発明の実施の形態において、A(数値)~B(数値)は、A以上B以下を意味する。なお、以下で例示する好ましい態様やより好ましい態様等は、「好ましい」や「より好ましい」等の表現にかかわらず適宜相互に組み合わせて使用することができる。また、数値範囲の記載は例示であって、好ましい」や「より好ましい」等の表現にかかわらず各範囲の上限と下限並びに実施例の数値とを適宜組み合わせた範囲も好ましく使用することができる。さらに、「含有する」又は「含む」等の用語は、適宜「本質的になる」や「のみからなる」と読み替えてもよい。 The present invention will be described in detail below. In the embodiment of the present invention, A (numerical value) to B (numerical value) means A or more and B or less. The preferred and more preferred aspects exemplified below can be used in appropriate combination with each other regardless of the expressions such as "preferred" and "more preferred". Furthermore, the descriptions of numerical ranges are merely examples, and ranges obtained by appropriately combining the upper and lower limits of each range and the numerical values of the examples can also be preferably used regardless of the expressions such as "preferred" and "more preferred". Furthermore, terms such as "contain" or "include" may be read as "essentially consisting of" or "consisting only of", as appropriate.
[ソースの製造方法]
本発明のソースの製造方法は、艶だし効果を有する油脂組成物をソース中に混合させることで、ソースに艶を付与することができる。これは、艶だし効果を有する油脂組成物をソース中に混合させることで、ソース表面に存在する油脂組成物の油滴が集合し難くなり、ソース表面に均一に油滴が分散している状態を維持できるためと考えられる。また、流動性のあるソース中に油脂組成物が分散しているために、常時、ソース表面に油脂組成物が供給できるため、ソース表面の艶だし効果を高め、且つ、維持することができると考えらえる。
[Sauce manufacturing method]
The method for producing sauce of the present invention can impart luster to a sauce by mixing an oil and fat composition having a luster-imparting effect into the sauce. This is believed to be because, by mixing an oil and fat composition having a luster-imparting effect into the sauce, the oil droplets of the oil and fat composition present on the surface of the sauce are less likely to gather, and the state in which the oil droplets are uniformly dispersed on the surface of the sauce can be maintained. In addition, since the oil and fat composition is dispersed in a fluid sauce, the oil and fat composition can be constantly supplied to the surface of the sauce, and therefore the luster-imparting effect on the surface of the sauce can be enhanced and maintained.
本発明のソースの製造方法は、油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)の製造方法であって、
ソース中に、下記の乳化剤A1、又は、乳化剤A2と乳化剤Bを特定量含有する油脂組成物を、ソースに対して0.5~12質量%となるように混合する、ソースの艶だし方法である。
The method for producing a sauce of the present invention is a method for producing a sauce having an oil/fat content of 25% by mass or less (excluding sauces for salads), comprising the steps of:
This method for enhancing the luster of a sauce comprises mixing an oil and fat composition containing specific amounts of emulsifier A1 or emulsifier A2 and emulsifier B described below into the sauce so that the amount of the oil and fat composition is 0.5 to 12% by mass relative to the sauce.
なお、油脂含有量が25質量%以下のソースにおいて、油脂組成物中の油脂は油脂含有量に含まれるものとする。 In addition, for sauces with an oil and fat content of 25% by mass or less, the oil and fat in the oil and fat composition is considered to be included in the oil and fat content.
本発明のソースの製造方法が対象とするソースはペースト状又は液体状の調味料であり、他の食品に添える、あるいは調理等に用いられるものである。一般的に、サラダ向けソース(マヨネーズやドレッシング類)のように油脂含有量が25質量%を超えるソースは油脂含有量が多いため、ある程度の艶を有し、本発明の効果が弱い。そのため、本発明が適用されるソースは、油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)であり、好ましくは油脂含有量が20質量%以下のソースであり、より好ましくは油脂含有量が5~18質量%のソースであり、さらに好ましくは油脂含有量が5~15質量%のソースである。このようなソースとして、例えば、パスタ用のソース、ケチャップ、ウスターソース、みそ、醤油、醤油ベースの和風タレ、中華料理等のあんかけ用のあん等が挙げられる。また、ペースト状あるいは固形分を含むソースは、後述する油脂組成物を均一に保持する効果が見込めるため、好ましい。 The sauces targeted by the method for producing sauces of the present invention are paste-like or liquid seasonings that are added to other foods or used in cooking. Generally, sauces with an oil content of more than 25% by mass, such as salad sauces (mayonnaise and dressings), have a high oil content and therefore have a certain degree of gloss, and the effects of the present invention are weak. Therefore, the sauces to which the present invention is applied are sauces with an oil content of 25% by mass or less (excluding salad sauces), preferably sauces with an oil content of 20% by mass or less, more preferably sauces with an oil content of 5 to 18% by mass, and even more preferably sauces with an oil content of 5 to 15% by mass. Examples of such sauces include sauces for pasta, ketchup, Worcestershire sauce, miso, soy sauce, soy sauce-based Japanese-style sauces, and thickened sauces for Chinese cuisine. In addition, sauces in a paste form or containing solids are preferred because they are expected to have the effect of maintaining the oil composition described below uniformly.
<油脂組成物>
本発明で用いる油脂組成物は、油脂と乳化剤を含む。乳化剤として、乳化剤A1(構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル)、又は、乳化剤A2(構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル)と乳化剤B(構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル)を含有する。
<Oil and fat composition>
The oil and fat composition used in the present invention contains an oil and fat and an emulsifier. The emulsifier contains emulsifier A1 (a polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is 1.5 to 3.5, and the average degree of esterification is 18.3 to 60.0%), or emulsifier A2 (a polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is more than 3.5, and the average degree of esterification is 18.3 to 60.0%) and emulsifier B (a polyglycerin fatty acid ester and/or a glycerin fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated straight-chain fatty acids having 16 to 22 carbon atoms).
本発明で用いる油脂組成物は、ソース中に、ソースに対して0.5~12質量%となるように混合する。0.5質量%以上あれば、ソースに艶を付与することができる。また、12質量%を超えると油脂組成物が十分混合状態を維持できない恐れがある。油脂組成物の混合量(配合量)は、ソースに対して0.5~10質量%が好ましく、ソースに対して1~8質量%がより好ましく、ソースに対して2~7質量%がさらに好ましい。混合方法としては、特に制限はないが、ソースの原料となる他の成分と同時に添加、撹拌することが好ましい。また、ソースの最後の製造工程において、添加、撹拌することができる。撹拌の程度は、油脂組成物が、ソース中に分散する程度でよい。また、ソースの上澄み等に多量の油相が分離しない程度に分散することが好ましい。 The oil and fat composition used in the present invention is mixed into the sauce so that the amount is 0.5 to 12% by mass relative to the sauce. If the amount is 0.5% by mass or more, it is possible to impart luster to the sauce. If the amount is more than 12% by mass, there is a risk that the oil and fat composition will not be able to maintain a sufficiently mixed state. The amount of the oil and fat composition mixed (blended amount) is preferably 0.5 to 10% by mass relative to the sauce, more preferably 1 to 8% by mass relative to the sauce, and even more preferably 2 to 7% by mass relative to the sauce. There are no particular restrictions on the mixing method, but it is preferable to add and stir the oil and fat composition simultaneously with the other ingredients that are the raw materials for the sauce. It can also be added and stirred in the final manufacturing process of the sauce. The degree of stirring may be such that the oil and fat composition is dispersed in the sauce. It is also preferable that the oil and fat composition is dispersed to such an extent that a large amount of oil phase does not separate into the supernatant of the sauce, etc.
(油脂)
本発明で用いる油脂組成物は、油脂を含む。油脂を含むことで、油脂組成物の粘度を低下させ、艶の付与の一助となる。油脂としては、動植物油脂、グリセリンと脂肪酸から合成した油脂及びそれらの分別油、エステル交換油、水素添加油などを単独あるいは組み合わせて用いることができる。
動植物油脂としては、例えば、大豆油、なたね油、ハイオレイックなたね油、ひまわり油、ハイオレイックひまわり油、オリーブ油、サフラワー油、ハイオレイックサフラワー油、コーン油、綿実油、米油、ゴマ油、エゴマ油、亜麻仁油、落花生油、グレープシード油、牛脂、乳脂、魚油、ヤシ油、パーム油、パーム核油などが挙げられる。
グリセリンと脂肪酸から合成した油脂としては、中鎖脂肪酸トリグリセリド(MCT)などが挙げられる。
分別油としては、パームオレイン、パームスーパーオレイン、パームステアリン、パームミッドフラクションなどのパーム油の分別油が挙げられる。
エステル交換油としては、パーム油あるいはパーム油の分別油と他の液状油脂のエステル交換油、あるいはMCTと植物油などとのエステル交換油を用いることができる。
水素添加油は、動植物油、動植物油の分別油の水素添加油の他、エステル交換油の水素添加油などが挙げられる。
(Oils and fats)
The oil and fat composition used in the present invention contains oil and fat. By containing oil and fat, the viscosity of the oil and fat composition is reduced, which helps to impart luster. As the oil and fat, animal and vegetable oils, oils and fats synthesized from glycerin and fatty acids, and their fractionated oils, transesterified oils, hydrogenated oils, etc. can be used alone or in combination.
Examples of animal and vegetable oils and fats include soybean oil, rapeseed oil, high oleic rapeseed oil, sunflower oil, high oleic sunflower oil, olive oil, safflower oil, high oleic safflower oil, corn oil, cottonseed oil, rice oil, sesame oil, perilla oil, linseed oil, peanut oil, grapeseed oil, beef tallow, milk fat, fish oil, coconut oil, palm oil, and palm kernel oil.
Examples of fats and oils synthesized from glycerin and fatty acids include medium-chain triglycerides (MCTs).
Examples of fractionated oils include fractionated palm oils such as palm olein, palm superolein, palm stearin, and palm midfraction.
As the interesterified oil, an interesterified oil of palm oil or a fractionated palm oil with other liquid fats and oils, or an interesterified oil of MCT with vegetable oil or the like can be used.
Examples of the hydrogenated oil include hydrogenated oils of animal and vegetable oils, fractionated oils of animal and vegetable oils, and hydrogenated oils of interesterified oils.
油脂組成物中の油脂は、室温で流動性を失うものは、ソースあるいはソース原料への添加時に加熱により溶解させる必要があるので、30℃で流動性を有する態様のものが好ましい。油脂の一部が30℃で固体であっても、他の油脂と併用して用いることによって、油脂全体として流動性を有していれば好適に使用できる。25℃で流動性を有する油脂がより好ましく、25℃で液状である油脂がさらに好ましい。特に、融点の低い液状油でありながら、酸化安定性も良好であるという利点を有することから、なたね油、パームオレイン、これらの混合物などを好適に使用することができる。 The fats and oils in the fat and oil composition that lose fluidity at room temperature must be dissolved by heating when added to the sauce or sauce ingredients, and therefore those that have fluidity at 30°C are preferred. Even if a portion of the fat and oil is solid at 30°C, it can be used suitably as long as it is combined with other fats and oils and oils that have fluidity as a whole. Fat and oils that have fluidity at 25°C are more preferred, and fats and oils that are liquid at 25°C are even more preferred. In particular, rapeseed oil, palm olein, and mixtures thereof can be used suitably, as they have the advantage of being liquid oils with low melting points and good oxidation stability.
油脂組成物は、前述の油脂を、油脂組成物中に40.0~99.9質量%含有することが好ましい。油脂組成物は、油脂を90~99.1質量%含有することがより好ましく、95.0~99.8質量%含有することがさらに好ましく、96.0~99.5質量%含有することがことさらに好ましい。 The oil composition preferably contains 40.0 to 99.9% by mass of the above-mentioned oil. The oil composition more preferably contains 90 to 99.1% by mass of the oil, even more preferably contains 95.0 to 99.8% by mass, and even more preferably contains 96.0 to 99.5% by mass.
(乳化剤A1)
本発明において、乳化剤A1は、構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステルである。
(Emulsifier A1)
In the present invention, emulsifier A1 is a polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerol moiety is 1.5 to 3.5, and the average degree of esterification is 18.3 to 60.0%.
油脂組成物は、乳化剤A1を含有する場合、乳化剤A1を0.5~8.0質量%含有する。乳化剤A1が0.5質量%以上で、ソースへ艶が付与される。一方、乳化剤A1が8.0質量%を超えると、油脂組成物の透明性が低下、あるいは、粘度が高くなることでソースへの分散が難しくなり、また、ソース中に存在する油脂組成物がソース表面に移動しにくくなるため、ソースへの艶付与が不十分となる。油脂組成物は、乳化剤Aを0.5~6.0質量%含有することがより好ましく、0.6~3.0質量%含有することがさらに好ましく、0.8~2.0質量%含有することが最も好ましい。 When the oil and fat composition contains emulsifier A1, it contains 0.5 to 8.0 mass% of emulsifier A1. When the emulsifier A1 is 0.5 mass% or more, gloss is imparted to the sauce. On the other hand, when the emulsifier A1 exceeds 8.0 mass%, the transparency of the oil and fat composition decreases, or the viscosity increases, making it difficult to disperse in the sauce, and the oil and fat composition present in the sauce is less likely to move to the surface of the sauce, resulting in insufficient gloss imparted to the sauce. The oil and fat composition more preferably contains 0.5 to 6.0 mass%, even more preferably 0.6 to 3.0 mass%, and most preferably 0.8 to 2.0 mass% of emulsifier A.
乳化剤A1は、ポリグリセリン脂肪酸エステルの構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸である。好ましくは、構成脂肪酸の75~100質量%が炭素数16~22の不飽和直鎖脂肪酸であり、より好ましくは、構成脂肪酸の80~100質量%が炭素数16~22の不飽和直鎖脂肪酸である。炭素数16~22の不飽和直鎖脂肪酸としては、パルミトオレイン酸、オレイン酸、リノール酸、リノレン酸、エルカ酸などが挙げられ、これらから選ばれる1種、又は2種以上であることが好ましい。ポリグリセリン脂肪酸エステルの融点が低く、酸化安定性が高い点から、構成脂肪酸はパルミトオレイン酸及び/又はオレイン酸がより好ましい。炭素数16~22の不飽和直鎖脂肪酸以外の構成脂肪酸は特に限定するものではないが、炭素数6~22の飽和直鎖脂肪酸を用いることができ、例えば、カプロン酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸などが挙げられ、これらから選ばれる1種、又は2種以上であることが好ましい。より好ましくは、パルミチン酸、ステアリン酸から選ばれる1種、又は2種以上である。 Emulsifier A1 is a polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms. Preferably, 75 to 100% by mass of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, and more preferably, 80 to 100% by mass of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms. Examples of unsaturated straight-chain fatty acids having 16 to 22 carbon atoms include palmitoleic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid, and it is preferable to use one or more types selected from these. In terms of the low melting point and high oxidation stability of the polyglycerol fatty acid ester, the constituent fatty acids are more preferably palmitoleic acid and/or oleic acid. The constituent fatty acids other than the unsaturated straight-chain fatty acids having 16 to 22 carbon atoms are not particularly limited, but saturated straight-chain fatty acids having 6 to 22 carbon atoms can be used, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, and behenic acid, and it is preferable to use one or more types selected from these. More preferably, it is one or more types selected from palmitic acid and stearic acid.
乳化剤A1は、ポリグリセリン脂肪酸エステルのポリグリセリン部の平均重合度が1.5~3.5である。ポリグリセリン部は、種々の重合度の混合物であることを許容するが、ジグリセリン及び/又はトリグリセリンであることが好ましい。 In emulsifier A1, the polyglycerin part of the polyglycerin fatty acid ester has an average degree of polymerization of 1.5 to 3.5. The polyglycerin part may be a mixture of polyglycerin parts with various degrees of polymerization, but is preferably diglycerin and/or triglycerin.
乳化剤A1は、ポリグリセリンと脂肪酸とのエステル化、あるいはポリグリセリンと脂肪酸メチルエステル等とのエステル交換等により製造することができる。得られたポリグリセリン脂肪酸エステルは、そのまま用いることもできるが、蒸留などにより、純度を高めたものを用いることができる。 Emulsifier A1 can be produced by esterification of polyglycerin with a fatty acid, or by transesterification of polyglycerin with a fatty acid methyl ester or the like. The resulting polyglycerin fatty acid ester can be used as is, but it can also be used after increasing the purity by distillation or the like.
本発明の艶だし効果を得るために、乳化剤A1は、油脂組成物の表面に偏在化する必要があり、一定の極性を有する必要がある。そのため、ポリグリセリン脂肪酸エステルの平均エステル化度は、18.3~60.0%である。なお、平均エステル化度(百分率)は、ポリグリセリン及び/又はグリセリンの水酸基がどの程度エステル化されているかを示すもので、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルのけん化価と水酸基価を測定し、(けん化価)÷(けん化価+水酸基価)×100で算出することができる。なお、ケン化価は、基準油脂分析試験法(日本油化学会制定「2.3.2.1-2013 けん化価」)に準じて測定することができる。また、水酸基価は、基準油脂分析試験法(日本油化学会制定「2.3.6.2-1996 ヒドロキシル価(ピリジン-無水酢酸法)」)に準じて測定することができる。
ポリグリセリン脂肪酸エステルの平均エステル化度は、18.3~50.0%であることが好ましく、20~30%であることがより好ましく、22~28%であることがさらに好ましい。また、ポリグリセリン脂肪酸エステルがモノエステル~トリエステルが好ましく、モノエステル及び/又はジエステルが特に好ましい。
In order to obtain the gloss effect of the present invention, the emulsifier A1 needs to be unevenly distributed on the surface of the oil composition and needs to have a certain polarity. Therefore, the average degree of esterification of the polyglycerol fatty acid ester is 18.3 to 60.0%. The average degree of esterification (percentage) indicates the degree to which the hydroxyl groups of polyglycerol and/or glycerol are esterified, and can be calculated by measuring the saponification value and hydroxyl value of the polyglycerol fatty acid ester and/or glycerol fatty acid ester, and calculating (saponification value)÷(saponification value+hydroxyl value)×100. The saponification value can be measured in accordance with the Standard Method for Analysis of Fats, Oils and Related Materials ("2.3.2.1-2013 Saponification Value" established by the Japan Oil Chemists' Society). The hydroxyl value can be measured in accordance with the Standard Method for Analysis of Fats, Oils and Related Materials ("2.3.6.2-1996 Hydroxyl Value (Pyridine-Acetic Anhydride Method)" established by the Japan Oil Chemists' Society.
The average degree of esterification of the polyglycerol fatty acid ester is preferably 18.3 to 50.0%, more preferably 20 to 30%, and even more preferably 22 to 28%. The polyglycerol fatty acid ester is preferably a monoester to a triester, and particularly preferably a monoester and/or a diester.
(乳化剤A2)
本発明において、構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステルである。前述の乳化剤A1との違いは、ポリグリセリン部の平均重合度である。乳化剤A2は、乳化剤A1よりもソースの艶だし効果が劣るため、後述の乳化剤Bとの組合せを必須とする。
(Emulsifier A2)
In the present invention, the polyglycerol fatty acid ester has 71% by mass or more of the constituent fatty acids being unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, an average degree of polymerization of the polyglycerol moiety being more than 3.5, and an average degree of esterification being 18.3 to 60.0%. The difference from the above-mentioned emulsifier A1 is the average degree of polymerization of the polyglycerol moiety. Emulsifier A2 is inferior to emulsifier A1 in the effect of adding gloss to sauces, and therefore must be combined with emulsifier B described below.
油脂組成物は、乳化剤A2を含有する場合、乳化剤A2を0.5~8.0質量%含有する。乳化剤A2が0.5質量%以上で、ソースへ艶が付与される。一方、乳化剤A2が8.0質量%を超えると、油脂組成物の透明性が低下、あるいは、粘度が高くなることでソースへの分散が難しくなり、また、ソース中に存在する油脂組成物がソース表面に移動しにくくなるため、ソースへの艶付与が不十分となる。油脂組成物は、乳化剤Aを0.5~6.0質量%含有することがより好ましく、0.6~3.0質量%含有することがさらに好ましく、0.8~2.0質量%含有することが最も好ましい。 When the oil and fat composition contains emulsifier A2, it contains 0.5 to 8.0 mass% of emulsifier A2. When the amount of emulsifier A2 is 0.5 mass% or more, gloss is imparted to the sauce. On the other hand, when the amount of emulsifier A2 exceeds 8.0 mass%, the transparency of the oil and fat composition decreases, or the viscosity increases, making it difficult to disperse in the sauce, and the oil and fat composition present in the sauce is less likely to move to the surface of the sauce, resulting in insufficient gloss imparted to the sauce. It is more preferable that the oil and fat composition contains 0.5 to 6.0 mass% of emulsifier A, even more preferably 0.6 to 3.0 mass%, and most preferably 0.8 to 2.0 mass%.
乳化剤A2は、ポリグリセリン脂肪酸エステルの構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸である。好ましくは、構成脂肪酸の75~100質量%が炭素数16~22の不飽和直鎖脂肪酸であり、より好ましくは、構成脂肪酸の80~100質量%が炭素数16~22の不飽和直鎖脂肪酸である。炭素数16~22の不飽和直鎖脂肪酸としては、パルミトオレイン酸、オレイン酸、リノール酸、リノレン酸、エルカ酸などが挙げられ、これらから選ばれる1種、又は2種以上であることが好ましい。ポリグリセリン脂肪酸エステルの融点が低く、酸化安定性が高い点から、構成脂肪酸はパルミトオレイン酸及び/又はオレイン酸がより好ましい。炭素数16~22の不飽和直鎖脂肪酸以外の構成脂肪酸は特に限定するものではないが、炭素数6~22の飽和直鎖脂肪酸を用いることができ、例えば、カプロン酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸などが挙げられ、これらから選ばれる1種、又は2種以上であることが好ましい。より好ましくは、パルミチン酸、ステアリン酸から選ばれる1種、又は2種以上である。 Emulsifier A2 is a polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms. Preferably, 75 to 100% by mass of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, and more preferably, 80 to 100% by mass of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms. Examples of unsaturated straight-chain fatty acids having 16 to 22 carbon atoms include palmitoleic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid, and it is preferable to use one or more types selected from these. In terms of the low melting point and high oxidation stability of the polyglycerol fatty acid ester, the constituent fatty acids are more preferably palmitoleic acid and/or oleic acid. The constituent fatty acids other than the unsaturated straight-chain fatty acids having 16 to 22 carbon atoms are not particularly limited, but saturated straight-chain fatty acids having 6 to 22 carbon atoms can be used, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, and behenic acid, and it is preferable to use one or more types selected from these. More preferably, it is one or more types selected from palmitic acid and stearic acid.
乳化剤A2は、ポリグリセリン脂肪酸エステルのポリグリセリン部の平均重合度が3.5超である。平均重合度は、3.5超~20が好ましく、3.5超~12がより好ましく、4~12がさらに好ましい。なお、ポリグリセリン部は、種々の重合度の混合物であることを許容するが、テトラグリセリン、ペンタグリセリン、ヘキサグリセリン、ヘプタグリセリン、オクタグリセリン、ノナグリセリン、デカグリセリンであることが好ましい。 In emulsifier A2, the polyglycerin portion of the polyglycerin fatty acid ester has an average degree of polymerization of more than 3.5. The average degree of polymerization is preferably from more than 3.5 to 20, more preferably from more than 3.5 to 12, and even more preferably from 4 to 12. The polyglycerin portion may be a mixture of various degrees of polymerization, but is preferably tetraglycerin, pentaglycerin, hexaglycerin, heptaglycerin, octaglycerin, nonaglycerin, or decaglycerin.
乳化剤A2は、ポリグリセリンと脂肪酸とのエステル化、あるいはポリグリセリンと脂肪酸メチルエステル等とのエステル交換等により製造することができる。得られたポリグリセリン脂肪酸エステルは、そのまま用いることもできる。 Emulsifier A2 can be produced by esterification of polyglycerin with a fatty acid, or by transesterification of polyglycerin with a fatty acid methyl ester or the like. The resulting polyglycerin fatty acid ester can be used as is.
本発明の艶だし効果を得るために、乳化剤A2は、油脂組成物の表面に偏在化する必要があり、一定の極性を有する必要がある。そのため、ポリグリセリン脂肪酸エステルの平均エステル化度は、18.3~60.0%である。ポリグリセリン脂肪酸エステルの平均エステル化度は、18.3~50.0%であることが好ましく、20~45%であることがより好ましく、30~45%であることがさらに好ましい。また、ポリグリセリン脂肪酸エステルがモノエステル~オクタエステルが好ましく、テトラエステル、ペンタエステル、ヘキサエステルが特に好ましい。 To obtain the gloss effect of the present invention, emulsifier A2 must be unevenly distributed on the surface of the oil composition and must have a certain polarity. Therefore, the average degree of esterification of the polyglycerol fatty acid ester is 18.3 to 60.0%. The average degree of esterification of the polyglycerol fatty acid ester is preferably 18.3 to 50.0%, more preferably 20 to 45%, and even more preferably 30 to 45%. Furthermore, the polyglycerol fatty acid ester is preferably a monoester to an octaester, and particularly preferably a tetraester, a pentaester, or a hexaester.
(乳化剤B)
乳化剤Bは、構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルである。炭素数16~22の飽和直鎖脂肪酸を有するポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルは、室温で固形あるいは粘度が高く、ソース表面の油脂組成物、あるいはソース中の油脂組成物がソース表面に移動した際に、ソース表面から流れ落ちることを抑えることができると考えられる。そのため、乳化剤A1、又は乳化剤A2とことで、艶の付与効果が高まり、食品の艶が一定レベルを維持するのを助けるものと考えられる。
ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルの構成脂肪酸は、好ましくは、50~100質量%が炭素数16~22の飽和直鎖脂肪酸であり、より好ましくは、60~95質量%が炭素数16~22の飽和直鎖脂肪酸であり、さらに好ましくは60~80質量%が炭素数16~22の飽和直鎖脂肪酸である。炭素数16~22の飽和直鎖脂肪酸として、パルミチン酸、ステアリン酸、ベヘン酸などが挙げられ、これらから選ばれる1種、又は2種以上であることが好ましい。より好ましくは、ステアリン酸、ベヘン酸から選ばれる1種、又は2種以上である。特に、ベヘン酸のエステルは、一般的に融点が高く、構成脂肪酸にベヘン酸を有するポリグリセリン及び/又はグリセリン脂肪酸エステルは油脂を室温でゲル化及び/又は増粘する効果が高いのでさらに好ましい。例えば、構成脂肪酸の20質量%以上がベヘン酸であり、構成脂肪酸の50質量%未満が不飽和脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルであることが好ましい。
(Emulsifier B)
Emulsifier B is a polyglycerol fatty acid ester and/or a glycerol fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated straight-chain fatty acids having 16 to 22 carbon atoms. Polyglycerol fatty acid esters and/or glycerol fatty acid esters having saturated straight-chain fatty acids having 16 to 22 carbon atoms are solid or have high viscosity at room temperature, and are considered to be able to prevent the oil and fat composition on the surface of the sauce, or the oil and fat composition in the sauce, from flowing off the surface of the sauce when it moves to the surface of the sauce. Therefore, it is considered that the combination with emulsifier A1 or emulsifier A2 enhances the gloss-imparting effect and helps maintain a constant level of gloss of the food.
The constituent fatty acids of the polyglycerol fatty acid ester and/or glycerol fatty acid ester are preferably 50 to 100% by mass of saturated straight-chain fatty acids having 16 to 22 carbon atoms, more preferably 60 to 95% by mass of saturated straight-chain fatty acids having 16 to 22 carbon atoms, and even more preferably 60 to 80% by mass of saturated straight-chain fatty acids having 16 to 22 carbon atoms. Examples of saturated straight-chain fatty acids having 16 to 22 carbon atoms include palmitic acid, stearic acid, behenic acid, etc., and it is preferable to use one or more types selected from these. It is more preferable to use one or more types selected from stearic acid and behenic acid. In particular, esters of behenic acid generally have a high melting point, and polyglycerol and/or glycerol fatty acid esters having behenic acid as a constituent fatty acid are more preferable because they have a high effect of gelling and/or thickening oils and fats at room temperature. For example, it is preferable that the polyglycerin fatty acid ester and/or the glycerin fatty acid ester are such that 20% by mass or more of the constituent fatty acids are behenic acid and less than 50% by mass of the constituent fatty acids are unsaturated fatty acids.
ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステルは、ポリグリセリンやグリセリンのエステルであるが、油脂組成物中の油脂への溶解性、分散性等から、平均エステル化度が高いものが好ましい。なお、この時のHLBは、HLB8以下となることが油脂への溶解性の点で好ましい。また、HLB1~7.5が好ましく、HLB2~7がより好ましい。
ポリグリセリン脂肪酸エステルの平均エステル化度は、30%以上であることが好ましく、50%以上がより好ましく、70%以上がさらに好ましい。また、ポリグリセリン脂肪酸エステルの平均エステル化度は、99%以下が好ましく、95%以下がより好ましく、90%以下がさらに好ましい。グリセリン脂肪酸エステルの平均エステル化度は、30%以上であることが好ましく、50%以上がより好ましく、70%以上がさらに好ましい。グリセリン脂肪酸エステルの平均エステル化度は、90%以下であることが好ましく、60質量%以下であることが好ましく、50質量%以下であることがより好ましい。グリセリン脂肪酸エステルは、グリセリンモノ脂肪酸エステルが好ましい。
The polyglycerol fatty acid ester and/or glycerol fatty acid ester are esters of polyglycerol or glycerol, and preferably have a high average degree of esterification in terms of solubility and dispersibility in the oils and fats in the oil composition. In this case, the HLB is preferably 8 or less in terms of solubility in the oils and fats. An HLB of 1 to 7.5 is also preferred, and an HLB of 2 to 7 is more preferred.
The average degree of esterification of the polyglycerin fatty acid ester is preferably 30% or more, more preferably 50% or more, and even more preferably 70% or more. The average degree of esterification of the polyglycerin fatty acid ester is preferably 99% or less, more preferably 95% or less, and even more preferably 90% or less. The average degree of esterification of the glycerin fatty acid ester is preferably 30% or more, more preferably 50% or more, and even more preferably 70% or more. The average degree of esterification of the glycerin fatty acid ester is preferably 90% or less, more preferably 60% by mass or less, and even more preferably 50% by mass or less. The glycerin fatty acid ester is preferably a glycerin mono fatty acid ester.
油脂組成物中の乳化剤A2は、乳化剤Bと組合わせて用いる。一方、乳化剤A1は、乳化剤Bと組みあわせなくても、ある程度のソースの艶が期待できるが、乳化剤Bとの組み合わせにより、ソースの艶がより高まる。また、長期間保持することもできる。したがって、乳化剤Bを用いる場合、油脂組成物中に乳化剤Bを0.03~2.0質量%含有することが好ましい。乳化剤Bの含有量が高いほど、油脂組成物のゲル化及び/又は増粘が期待でき、食品への艶の付与が高まる。一方、2.0質量%超では、乳化剤Bの結晶量が多くなり、油脂組成物の流動性が著しく劣るともに、油脂組成物が白濁し、艶だし効果に劣る。油脂組成物は、乳化剤Bを0.05~1.5質量%含有することが好ましく、0.03~1.0質量%含有することがより好ましく、0.05~0.8質量%含有することがさらに好ましい。 Emulsifier A2 in the oil and fat composition is used in combination with emulsifier B. On the other hand, emulsifier A1 can be expected to give a certain degree of gloss to the sauce even without combining it with emulsifier B, but the combination with emulsifier B enhances the gloss of the sauce. It can also be maintained for a long period of time. Therefore, when emulsifier B is used, it is preferable that the oil and fat composition contains 0.03 to 2.0 mass% of emulsifier B. The higher the content of emulsifier B, the more the oil and fat composition can be expected to gel and/or thicken, and the gloss of the food can be enhanced. On the other hand, if it exceeds 2.0 mass%, the amount of crystals of emulsifier B increases, the fluidity of the oil and fat composition is significantly deteriorated, the oil and fat composition becomes cloudy, and the gloss effect is inferior. The oil and fat composition preferably contains 0.05 to 1.5 mass%, more preferably 0.03 to 1.0 mass%, and even more preferably 0.05 to 0.8 mass% of emulsifier B.
本発明で用いる油脂組成物において、艶を長期間保持するために油脂と乳化剤の組合せが必要であるが、その際に、油脂組成物の25℃における粘度が55mPa・s以上であることが好ましい。油脂組成物は、25℃における粘度が100~3000mPa・sであることがより好ましく、150~2000mPa・sであることがより好ましく、25℃における粘度が150~800mPa・sがさらに好ましい。これらの粘度は、「日本油化学会制定 基準油脂分析試験法:2.2.10.5-2013 粘度(ブルックフィールド法)」に準拠して測定することができる。なお、B形粘度計とデータ互換のある粘度計を用いて分析することもでき、例えば、東機産業株式会社製のTVB-10形粘度計、あるいはTVK-15型粘度計が挙げられる。 In the oil composition used in the present invention, a combination of oil and emulsifier is necessary to maintain gloss for a long period of time, and in this case, it is preferable that the viscosity of the oil composition at 25°C is 55 mPa·s or more. The oil composition preferably has a viscosity at 25°C of 100 to 3000 mPa·s, more preferably 150 to 2000 mPa·s, and even more preferably 150 to 800 mPa·s. These viscosities can be measured in accordance with "Standard Method for Analysis of Fats, Oils and Related Materials: 2.2.10.5-2013 Viscosity (Brookfield Method)" established by the Japan Oil Chemists' Society. Analysis can also be performed using a viscometer with data compatibility with a B-type viscometer, such as the TVB-10 viscometer or TVK-15 viscometer manufactured by Toki Sangyo Co., Ltd.
(その他成分)
本発明で用いる油脂組成物は、本発明の効果に影響を及ぼさない範囲で、適宜、他の成分を含有することができる。例えば、上記乳化剤A及び乳化剤B以外の乳化剤を添加してもよい。乳化剤としては、例えば、ソルビタン脂肪酸エステル、ソルビトール脂肪酸エステル、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、有機酸モノグリセリド、ポリソルベート、レシチン等が挙げられる。また、pH調整剤、調味剤、着色料、香料、酸化防止剤、糖類、糖アルコール類、安定剤等を使用することができる。これらの成分の量は、本発明の効果を損なわない限り任意の量とすることができるが、例えば、油脂組成物中に10質量%以下含有させることができ、好ましくは0~3質量%、より好ましくは0~1質量%含有させることができる。
(Other ingredients)
The oil and fat composition used in the present invention may contain other components as appropriate, as long as the effects of the present invention are not affected. For example, emulsifiers other than the above-mentioned emulsifier A and emulsifier B may be added. Examples of emulsifiers include sorbitan fatty acid esters, sorbitol fatty acid esters, sucrose fatty acid esters, propylene glycol fatty acid esters, organic acid monoglycerides, polysorbates, lecithin, and the like. In addition, pH adjusters, seasonings, colorants, fragrances, antioxidants, sugars, sugar alcohols, stabilizers, and the like may be used. The amount of these components may be any amount as long as the effects of the present invention are not impaired, and for example, they may be contained in the oil and fat composition in an amount of 10% by mass or less, preferably 0 to 3% by mass, and more preferably 0 to 1% by mass.
[ソースの艶だし方法]
本発明のソースの艶だし方法は、艶だし効果を有する油脂組成物をソース中に混合させることで、ソースに艶を付与することができる。これは、艶だし効果を有する油脂組成物をソース中に混合させることで、ソース表面に存在する油脂組成物の油滴が集合し難くなり、ソース表面に均一に油滴が分散している状態を維持できるためと考えられる。また、流動性のあるソース中に油脂組成物が分散しているために、常時、ソース表面に油脂組成物が供給できるため、ソース表面の艶だし効果を高め、且つ、維持することができると考えらえる。
[How to make the sauce glossy]
The sauce glossing method of the present invention can impart gloss to a sauce by mixing an oil and fat composition having a glossing effect into the sauce. This is believed to be because, by mixing the oil and fat composition having a glossing effect into the sauce, the oil droplets of the oil and fat composition present on the surface of the sauce are less likely to gather, and the state in which the oil droplets are uniformly dispersed on the surface of the sauce can be maintained. In addition, since the oil and fat composition is dispersed in a fluid sauce, the oil and fat composition can be constantly supplied to the surface of the sauce, and therefore, the glossing effect on the surface of the sauce can be enhanced and maintained.
本発明のソースの艶だし方法は、油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)の艶だし方法であって、下記の乳化剤A1を0.5~8.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、又は、下記の乳化剤A2を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、ソースの艶だし方法である。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル
The method for polishing a sauce of the present invention is a method for polishing a sauce having an oil and fat content of 25% by mass or less (excluding sauces for salads), which comprises mixing an oil and fat composition containing 0.5 to 8.0% by mass of emulsifier A1 described below into the sauce so that the oil and fat composition is contained in the sauce at 0.5 to 12% by mass, or mixing an oil and fat composition containing 0.5 to 8.0% by mass of emulsifier A2 described below and 0.03 to 2.0% by mass of emulsifier B described below into the sauce so that the oil and fat composition is contained in the sauce at 0.5 to 12% by mass.
(Emulsifier A1) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is 1.5 to 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier A2) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is more than 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier B) A polyglycerin fatty acid ester and/or glycerin fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated linear fatty acids having 16 to 22 carbon atoms.
なお、油脂含有量が25質量%以下のソースにおいて、油脂組成物中の油脂は油脂含有量に含まれるものとする。 In addition, for sauces with an oil and fat content of 25% by mass or less, the oil and fat in the oil and fat composition is considered to be included in the oil and fat content.
本発明のソースの艶だし方法が対象とするソースはペースト状又は液体状の調味料であり、他の食品に添える、あるいは調理等に用いられるものである。一般的に、サラダ向けソース(マヨネーズやドレッシング類)のように油脂含有量が25質量%を超えるソースは油脂含有量が多いため、ある程度の艶を有し、本発明の効果が弱い。そのため、本発明が適用されるソースは、油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)であり、好ましくは油脂含有量が20質量%以下のソースであり、より好ましくは油脂含有量が5~18質量%のソースであり、さらに好ましくは油脂含有量が5~15質量%のソースである。このようなソースとして、例えば、パスタ用のソース、ケチャップ、ウスターソース、みそ、醤油、醤油ベースの和風タレ、中華料理等のあんかけ用のあん等が挙げられる。また、ペースト状あるいは固形分を含むソースは、後述する油脂組成物を均一に保持する効果が見込めるため、好ましい。 The sauce targeted by the sauce polishing method of the present invention is a paste-like or liquid seasoning that is added to other foods or used in cooking. In general, sauces with an oil content of more than 25% by mass, such as salad sauces (mayonnaise and dressings), have a certain degree of luster due to the high oil content, and the effect of the present invention is weak. Therefore, the sauce to which the present invention is applied is a sauce with an oil content of 25% by mass or less (excluding salad sauces), preferably a sauce with an oil content of 20% by mass or less, more preferably a sauce with an oil content of 5 to 18% by mass, and even more preferably a sauce with an oil content of 5 to 15% by mass. Examples of such sauces include sauces for pasta, ketchup, Worcestershire sauce, miso, soy sauce, soy sauce-based Japanese-style sauces, and thickened sauces for Chinese cuisine. In addition, sauces in a paste form or containing solids are preferable because they are expected to have the effect of maintaining the oil composition described below uniformly.
本発明のソースの艶だし方法において、用いる油脂組成物、該油脂組成物中の油脂、乳化剤A1、乳化剤A2、乳化剤B、その他成分は、前述の[ソースの製造方法]に記載された通りである。 In the method for glazed sauce of the present invention, the oil composition, the oil in the oil composition, emulsifier A1, emulsifier A2, emulsifier B, and other components are as described in the above-mentioned [Method for producing sauce].
なお、本発明のソースの艶だし方法において、油脂組成物をソースに混合する方法は、特に制限はないが、ソースの製造工程において、原料となる他の成分と同時に添加、撹拌することができる。また、ソースの最後の製造工程において、あるいは、市販のソースに対して添加、撹拌してもよい。撹拌の程度は、油脂組成物が、ソース中に分散する程度でよい。また、ソースの上澄み等に多量の油相が分離しない程度に分散することが好ましい。 In the sauce glazing method of the present invention, the method of mixing the oil and fat composition into the sauce is not particularly limited, but it can be added and stirred simultaneously with other ingredients in the sauce production process. It can also be added and stirred in the final sauce production process, or to a commercially available sauce. The degree of stirring should be such that the oil and fat composition is dispersed in the sauce. It is also preferable to disperse the oil and fat composition to such an extent that a large amount of oil phase does not separate into the supernatant of the sauce, etc.
[ソース]
本発明のソースは、油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)であって、油脂組成物をソース中に0.5~12質量%含有し、該油脂組成物が、下記の乳化剤A1を0.5~8.0質量%、又は乳化剤A2を0.5~8.0質量%と乳化剤Bを0.03~2.0質量%含有する、ソースである。
ソース。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル
[sauce]
The sauce of the present invention is a sauce having an oil and fat content of 25% by mass or less (excluding sauces for salads), which contains an oil and fat composition in an amount of 0.5 to 12% by mass, and which contains 0.5 to 8.0% by mass of emulsifier A1, or 0.5 to 8.0% by mass of emulsifier A2 and 0.03 to 2.0% by mass of emulsifier B described below.
sauce.
(Emulsifier A1) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is 1.5 to 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier A2) A polyglycerin fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated linear fatty acids having 16 to 22 carbon atoms, the average degree of polymerization of the polyglycerin moiety is more than 3.5, and the average degree of esterification is 18.3 to 60.0%. (Emulsifier B) A polyglycerin fatty acid ester and/or glycerin fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated linear fatty acids having 16 to 22 carbon atoms.
なお、油脂含有量が25質量%以下のソースにおいて、油脂組成物中の油脂は油脂含有量に含まれるものとする。 In addition, for sauces with an oil and fat content of 25% by mass or less, the oil and fat in the oil and fat composition is considered to be included in the oil and fat content.
本発明のソースはペースト状又は液体状の調味料であり、他の食品に添える、あるいは調理等に用いられるものである。一般的に、サラダ向けソース(マヨネーズやドレッシング類)のように油脂含有量が25質量%を超えるソースは油脂含有量が多いため、ある程度の艶を有し、本発明の効果が弱い。そのため、本発明が適用されるソースは、油脂含有量が25質量%以下のソース(ただし、サラダ向けソースは除く)であり、好ましくは油脂含有量が20質量%以下のソースであり、より好ましくは油脂含有量が5~18質量%のソースであり、さらに好ましくは油脂含有量が5~15質量%のソースである。このようなソースとして、例えば、パスタ用のソース、ケチャップ、ウスターソース、みそ、醤油、醤油ベースの和風タレ、中華料理等のあんかけ用のあん等が挙げられる。また、ペースト状あるいは固形分を含むソースは、油脂組成物を均一に分散する効果を長期に保持することが見込めるため、好ましい。 The sauce of the present invention is a seasoning in a paste or liquid form, which is added to other foods or used in cooking. In general, sauces with an oil content of more than 25% by mass, such as salad sauces (mayonnaise and dressings), have a high oil content and therefore have a certain degree of gloss, and the effect of the present invention is weak. Therefore, the sauce to which the present invention is applied is a sauce with an oil content of 25% by mass or less (excluding salad sauces), preferably a sauce with an oil content of 20% by mass or less, more preferably a sauce with an oil content of 5 to 18% by mass, and even more preferably a sauce with an oil content of 5 to 15% by mass. Examples of such sauces include sauces for pasta, ketchup, Worcestershire sauce, miso, soy sauce, soy sauce-based Japanese-style sauces, and thickened sauces for Chinese cuisine. In addition, sauces in a paste form or containing solids are preferable because they are expected to maintain the effect of uniformly dispersing the oil composition for a long period of time.
本発明のソースは、前述の[ソースの製造方法]に記載されて製造方法で製造されたソース、あるいは前述の[ソースの艶だし方法]に記載されて得られたソースである。ソース中の油脂組成物、該油脂組成物中の油脂、乳化剤A、乳化剤B、その他成分は、前述の通りである。 The sauce of the present invention is a sauce produced by the method described in the above-mentioned [Sauce Production Method], or a sauce obtained by the method described in the above-mentioned [Sauce Glazing Method]. The oil and fat composition in the sauce, the oil and fat in the oil and fat composition, emulsifier A, emulsifier B, and other components are as described above.
次に、実施例、比較例を挙げ、本発明を更に詳しく説明するが、本発明はこれらに何ら制限されるものではない。また。以下において「%」とは、特別な記載がない場合、質量%を示す。 The present invention will now be described in more detail with reference to examples and comparative examples, but the present invention is in no way limited to these. In the following, "%" refers to mass % unless otherwise specified.
[試料(油脂組成物)]
油脂1を試料1とした。また、表1の配合にて60℃で均一溶解するまで加熱混合し、試料(油脂組成物)2~9を得た。なお、使用した原材料は以下の通りである。
油脂1(精製菜種(キャノーラ)油)、
乳化剤A1a(ジグリセリンモノオレイン酸エステル:エステル化度 25%)
乳化剤A1‘(テトラグリセリンモノオレイン酸エステル:エステル化度 約16%)
乳化剤A2a(デカグリセリンペンタオレイン酸エステル:エステル化度 約42%)
乳化剤Ba(ポリグリセリン脂肪酸エステル:ベヘン酸45%、ステアリン酸45%、オレイン酸6%、エステル化度84%)
(粘度の測定)
各試料120gを25℃で、スピンドル型粘度計(VISCOMETER TVB-15M:東機産業株式会社 25℃)で測定した。なお、試料1、2、4、5は、ローターM1を用い、試料3、6はローターM2を用い、それぞれ12rpmで測定した。試料1~6の粘度を表1に示した。
[Sample (oil and fat composition)]
The oil and fat 1 was used as sample 1. The ingredients in Table 1 were mixed at 60° C. until uniformly dissolved, to obtain samples (oil and fat compositions) 2 to 9. The raw materials used are as follows:
Fats and oils 1 (refined rapeseed (canola) oil),
Emulsifier A1a (diglycerol monooleate: esterification degree 25%)
Emulsifier A1' (tetraglycerin monooleate: degree of esterification approx. 16%)
Emulsifier A2a (decaglycerin pentaoleic acid ester: esterification degree approx. 42%)
Emulsifier Ba (Polyglycerol fatty acid ester: behenic acid 45%, stearic acid 45%, oleic acid 6%, esterification degree 84%)
(Viscosity Measurement)
120 g of each sample was measured at 25° C. using a spindle type viscometer (VISCOMETER TVB-15M: Toki Sangyo Co., Ltd., 25° C.). Samples 1, 2, 4, and 5 were measured using rotor M1, and samples 3 and 6 were measured using rotor M2, each at 12 rpm. The viscosities of samples 1 to 6 are shown in Table 1.
[油脂組成物の評価1]
(ソースの製造)
パスタ用ソース(「マ・マー トマトの果肉たっぷりのミートソース マッシュルーム入り」日清フーズ株式会社製、脂質2.3g/130g当り)95質量部に、各試料(油脂組成物)5質量部を添加し、混合・分散させた。
(光沢の測定)
ソースをタッパーに充填し、光沢を測定した。測定は、ソースの上から光沢計(日本電色工業株式会社製 HANDY GLOSS METER PG-1M:測定入射角 85°)を用いて測定した。測定値は、基準値(ガラス)に対する相対値(Gloss Unit)で、数値の大きい方が光沢(艶)を有することを示す。
[Evaluation of oil and fat composition 1]
(Sauce production)
Five parts by mass of each sample (oil and fat composition) was added to 95 parts by mass of pasta sauce ("MaMa Tomato Pulp Meat Sauce with Mushrooms" manufactured by Nissin Foods Inc., lipid content 2.3 g/130 g), and mixed and dispersed.
(Gloss Measurement)
The sauce was filled into a Tupperware and the gloss was measured. The measurement was performed from above the sauce using a gloss meter (HANDY GLOSS METER PG-1M, manufactured by Nippon Denshoku Industries Co., Ltd.: measurement incident angle 85°). The measured value is a relative value (Gloss Unit) to the reference value (glass), and a larger value indicates a higher gloss (luster).
実施例1~5は、参考例、比較例に比べて、光沢があることが確認できた。また、乳化剤A1aと乳化剤A1‘を配合した試料7(乳化剤の平均重合度は約3)であるが、試料2に比べて、光沢度合いが高くなっている。また、試料4と5、試料5と6、試料7と8の比較から、乳化剤Baを添加したサンプルの光沢が増加していることが確認できた。 It was confirmed that Examples 1 to 5 had a higher gloss than the Reference Example and Comparative Example. Also, Sample 7, which contains Emulsifier A1a and Emulsifier A1' (the average degree of polymerization of the emulsifiers is about 3), had a higher gloss than Sample 2. Also, a comparison of Samples 4 and 5, Samples 5 and 6, and Samples 7 and 8 confirmed that the gloss of the sample to which Emulsifier Ba was added was increased.
Claims (8)
下記の乳化剤A1を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
又は、下記の乳化剤A2を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
ソースの製造方法。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含まない)
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含まない)
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含む) A method for producing a sauce having an oil/fat content of 25% by mass or less (excluding sauces for salads), comprising the steps of:
An oil and fat composition containing 0.5 to 8.0 mass% of the following emulsifier A1 and 0.03 to 2.0 mass% of the following emulsifier B is mixed into the sauce so that the oil and fat composition contains 0.5 to 12 mass% of the following emulsifier A1 and 0.03 to 2.0 mass% of the following emulsifier B.
Alternatively, an oil and fat composition containing 0.5 to 8.0% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B is mixed into the sauce so that the oil and fat composition contains 0.5 to 12% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B.
Method of producing sauce.
(Emulsifier A1) A polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average polymerization degree of the polyglycerol portion is 1.5 to 3.5, and the average esterification degree is 18.3 to 60.0% (however, the constituent fatty acids do not contain behenic acid).
(Emulsifier A2) A polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average polymerization degree of the polyglycerol portion is more than 3.5, and the average esterification degree is 18.3 to 60.0% (however, the constituent fatty acids do not contain behenic acid).
(Emulsifier B) Polyglycerol fatty acid ester and/or glycerol fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated straight-chain fatty acids having 16 to 22 carbon atoms (provided that the constituent fatty acids contain behenic acid)
請求項1に記載のソースの製造方法。 The emulsifier B is a polyglycerol fatty acid ester and/or a glycerol fatty acid ester, in which 20% by mass or more of the constituent fatty acids are behenic acid and less than 50% by mass of the constituent fatty acids are unsaturated fatty acids.
A method for producing the sauce according to claim 1 .
請求項1又は2に記載のソースの製造方法。 The viscosity of the oil composition at 25°C is 100 to 3000 mPa·s;
A method for producing the sauce according to claim 1 or 2 .
下記の乳化剤A1を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
又は、下記の乳化剤A2を0.5~8.0質量%、乳化剤Bを0.03~2.0質量%含有する油脂組成物を、ソース中に0.5~12質量%含まれるように混合する、
ソースの艶だし方法。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含まない)
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含まない)
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含む) A method for polishing a sauce having an oil and fat content of 25% by mass or less (excluding sauces for salads), comprising the steps of:
An oil and fat composition containing 0.5 to 8.0 mass% of the following emulsifier A1 and 0.03 to 2.0 mass% of the following emulsifier B is mixed into the sauce so that the oil and fat composition contains 0.5 to 12 mass% of the following emulsifier A1 and 0.03 to 2.0 mass% of the following emulsifier B.
Alternatively, an oil and fat composition containing 0.5 to 8.0% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B is mixed into the sauce so that the oil and fat composition contains 0.5 to 12% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B.
How to deglaze the sauce.
(Emulsifier A1) A polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average polymerization degree of the polyglycerol portion is 1.5 to 3.5, and the average esterification degree is 18.3 to 60.0% (however, the constituent fatty acids do not contain behenic acid).
(Emulsifier A2) A polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average polymerization degree of the polyglycerol portion is more than 3.5, and the average esterification degree is 18.3 to 60.0% (however, the constituent fatty acids do not contain behenic acid).
(Emulsifier B) Polyglycerol fatty acid ester and/or glycerol fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated straight-chain fatty acids having 16 to 22 carbon atoms (provided that the constituent fatty acids contain behenic acid)
請求項4に記載のソースの艶だし方法。 The emulsifier B is a polyglycerol fatty acid ester and/or a glycerol fatty acid ester, in which 20% by mass or more of the constituent fatty acids are behenic acid and less than 50% by mass of the constituent fatty acids are unsaturated fatty acids.
A method for glaze a sauce according to claim 4 .
請求項4又は5に記載のソースの艶だし方法。 The viscosity of the oil composition at 25°C is 100 to 3000 mPa·s;
A method for glaze a sauce according to claim 4 or 5 .
油脂組成物をソース中に0.5~12質量%含有し、
該油脂組成物が、下記の乳化剤A1を0.5~8.0質量%と乳化剤Bを0.03~2.0質量%、又は乳化剤A2を0.5~8.0質量%と乳化剤Bを0.03~2.0質量%含有する、
ソース。
(乳化剤A1)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が1.5~3.5であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含まない)
(乳化剤A2)構成脂肪酸の71質量%以上が炭素数16~22の不飽和直鎖脂肪酸であり、ポリグリセリン部の平均重合度が3.5超であり、平均エステル化度は、18.3~60.0%である、ポリグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含まない)
(乳化剤B)構成脂肪酸の50質量%以上が炭素数16~22の飽和直鎖脂肪酸である、ポリグリセリン脂肪酸エステル及び/又はグリセリン脂肪酸エステル(ただし、構成脂肪酸にベヘン酸を含む) A sauce having an oil and fat content of 25% by mass or less (excluding sauces for salads),
The oil and fat composition is contained in the sauce in an amount of 0.5 to 12% by mass,
The oil and fat composition contains 0.5 to 8.0% by mass of the following emulsifier A1 and 0.03 to 2.0% by mass of the following emulsifier B , or 0.5 to 8.0% by mass of the following emulsifier A2 and 0.03 to 2.0% by mass of the following emulsifier B.
sauce.
(Emulsifier A1) A polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average polymerization degree of the polyglycerol portion is 1.5 to 3.5, and the average esterification degree is 18.3 to 60.0% (however, the constituent fatty acids do not contain behenic acid).
(Emulsifier A2) A polyglycerol fatty acid ester in which 71% by mass or more of the constituent fatty acids are unsaturated straight-chain fatty acids having 16 to 22 carbon atoms, the average polymerization degree of the polyglycerol portion is more than 3.5, and the average esterification degree is 18.3 to 60.0% (however, the constituent fatty acids do not contain behenic acid).
(Emulsifier B) Polyglycerol fatty acid ester and/or glycerol fatty acid ester in which 50% by mass or more of the constituent fatty acids are saturated straight-chain fatty acids having 16 to 22 carbon atoms (provided that the constituent fatty acids contain behenic acid)
請求項7に記載のソース。 The oil and fat composition is dispersed in a sauce.
The sauce of claim 7 .
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