JP7618196B2 - Aerosol type foam temporary coloring composition - Google Patents

Description

The present invention relates to an aerosol type foam temporary colorant composition, and in particular to an aerosol type foam temporary colorant composition that is free of flaking and stickiness, and has good coloring properties, water resistance, abrasion resistance, and foam retention.

In recent years, there has been an increasing need for products that allow users to change their hair color simply and easily without the need for complicated operations. Among these, temporary hair coloring compositions that allow users to easily change the color tone of their hair have been attracting attention.

Temporary hair coloring compositions generally color hair by attaching a coloring agent such as a pigment or organic dye to the hair. Compared to so-called oxidative hair dyes that utilize a chemical reaction (oxidative polymerization) using an oxidative dye and an oxidizing agent, they cause little damage to hair and are easy to wash off with a single wash, making them widely used. In particular, aerosol-type temporary hair coloring agents that use a propellant are in high demand in the market because they are easy to apply over a wide area and are simple to use.

Conventionally, some aerosol-type temporary colorants use anionic film-forming agents or polymeric thickeners to fix the colorant on the hair in order to improve abrasion resistance and water resistance after drying (Patent Document 1).

Furthermore, a color hair cosmetic containing an amphoteric polymer resin, an acid dye, and a pigment has been disclosed as a cosmetic that has high coloring properties on hair but causes little secondary adhesion (Patent Document 2).

Furthermore, as a type of aerosol temporary coloring agent, aerosol cosmetics containing coloring materials that are sprayed in a mist form using a spray nozzle have been disclosed (Patent Document 3).

JP 2003-26553 A Japanese Patent Application Publication No. 11-124319 JP 2003-81762 A

However, in Patent Document 1, when applying an aerosol type temporary hair coloring composition to hair, the anionic film-forming agent and polymer thickener that are blended to improve friction resistance and water resistance after drying not only fix the coloring agent to the hair, but also cause the hair strands to stick together, making the hair stiff and forming thick clumps that result in an unnatural finish with no movement, and can easily become sticky, making the hair difficult to run your fingers through and difficult to feel.

In addition, although Patent Document 2 achieves both high coloring properties and suppression of secondary adhesion to hair, it does not focus on the degree of stickiness or flaking of the hair at the time of finishing, and there is still room for improvement in terms of achieving a natural finish without stickiness or flaking.

Furthermore, as in Patent Document 3, a method is known in which a spray-type aerosol cosmetic containing a coloring material, which is a type of aerosol-type temporary coloring composition, is sprayed in mist form; however, since the mist is sprayed over a wide area, it is difficult to apply the cosmetic evenly on the hair, and the original liquid may adhere to unintended areas, resulting in contamination of the surrounding area.

As a result of intensive research into solving the above problems, the present inventors discovered that an aerosol type foam temporary colorant composition can be obtained that is discharged in foam form (foam) from an aerosol container, the aerosol type foam temporary colorant composition containing (A) a polyoxyethylene alkyl ether type nonionic surfactant, (B) an acrylic resin alkanolamine, (C) a nonionic film-forming resin, (D) an alkyl acrylate copolymer emulsion, (E) an aerosol concentrate containing a colorant, and (F) a propellant, and thus completed the present invention.

The present invention provides an aerosol type foam temporary colorant composition that is free of flaking and stickiness, and has good coloring properties, water resistance, abrasion resistance, and foam retention.

The present invention will be described in detail below. Note that all units indicating content are mass% unless otherwise specified.

In this invention, flaking refers to the peeling off of the film-forming resin attached to the hair and the falling off of the colorant fixed to the hair by the formed film together with the film-forming resin, and means that the hair whose color has been changed by the aerosol type foam temporary colorant composition becomes exposed.

The aerosol type foam temporary colorant composition of the present invention contains an aerosol concentrate and a propellant.

The aerosol concentrate of the present invention contains (A) a polyoxyethylene alkyl ether type nonionic surfactant from the viewpoint of foam retention.

The component (A) used in the present invention is not particularly limited, but examples thereof include polyoxyethylene (hereinafter referred to as POE) (2) lauryl ether (HLB: 9.5), POE (4) lauryl ether (HLB: 11.5), POE (9) lauryl ether (HLB: 14.5), POE (21) lauryl ether (HLB: 19.0), POE (25) lauryl ether (HLB: 19.5), POE (2) cetyl ether (HLB: 8.0), POE (6) cetyl ether (HLB: 10.5), POE (7 ) cetyl ether (HLB: 11.5), POE (10) cetyl ether (HLB: 13.5), POE (15) cetyl ether (HLB: 15.5), POE (20) cetyl ether (HLB: 17.0), POE (23) cetyl ether (HLB: 18.0), POE (25) cetyl ether (HLB: 18.5), POE (30) cetyl ether (HLB: 19.5), POE (40) cetyl ether (HLB: 20.0), POE (2) stearyl ether (HLB: 8.0), POE (4) stearyl ether (HLB: 10.0), POE (5) stearyl ether (HLB: 11.5), POE (6) stearyl ether (HLB: 12.0), POE (7) stearyl ether (HLB: 13.5), POE (8) stearyl ether (HLB: 14.0), POE (9) stearyl ether (HLB: 15.5), POE (10) cetyl ether (HLB: 13.5), POE (15) cetyl ether (HLB: 15.5), POE (20) cetyl ether (HLB: 17.0), POE (23) cetyl ether (HLB: 18.0), POE (25) cetyl ether (HLB: 18.5), POE (30) cetyl ether (HLB: 19.5), POE (40) cetyl ether (HLB: 20.0), POE (2) stearyl ether (HLB: 14.0), POE (10) stearyl ether (HLB: 15 POE(20) stearyl ether (HLB: 18.0), POE(2) oleyl ether (HLB: 7.5), POE(7) oleyl ether (HLB: 10.5), POE(10) oleyl ether (HLB: 14.5), POE(15) oleyl ether (HLB: 16.0), POE(20) oleyl ether (HLB: 17.0), POE(50) oleyl ether (HLB: 18.0), POE(5) behenyl ether (HLB: 7.0), POE(10) behenyl ether (HLB: 10.0), POE(20) behenyl ether (HLB: 16.5), POE(30) behenyl ether (HLB: 18.0), POE(3) alkyl(12-14) ether (HLB: 8.0), POE(5) alkyl(12-14) ether (HLB: 10.5), POE(7) alkyl(12-14) ether (HLB: 12.0), POE(9) alkyl(12-14) ether (HLB: 13.5), POE(12) alkyl(12-14) ether (HLB: 14.5), and the like. Among these, from the viewpoint of forming foam when discharged from an aerosol container, POE(2) lauryl ether (HLB: 9.5), POE(4) lauryl ether (HLB: 11.5), POE(9) lauryl ether (HLB: 14.5), POE(21) lauryl ether (HLB: 19.0), POE(25) lauryl ether (HLB: 19.5), POE(2) cetyl ether (HLB: 8.0), POE(6) cetyl ether (HLB: 8.0), POE(7) cetyl ether (HLB: 9.0), POE(8) cetyl ether (HLB: 10.0), POE(9) lauryl ether (HLB: 14.5), POE(21) lauryl ether (HLB: 19.0), POE(25) lauryl ether (HLB: 19.5), POE(2) cetyl ether (HLB: 8.0), POE(6) cetyl ether (HLB: 10.0), POE(7 ... Cetyl ether (HLB: 10.5), POE(7) cetyl ether (HLB: 11.5), POE(10) cetyl ether (HLB: 13.5), POE(15) cetyl ether (HLB: 15.5), POE(20) cetyl ether (HLB: 17.0), POE(23) cetyl ether (HLB: 18.0), POE(25) cetyl ether (HLB: 18.5), POE(30) cetyl ether (HLB: 19.5), P POE(40) cetyl ether (HLB: 20.0), POE(3) alkyl(12-14) ether (HLB: 8.0), POE(5) alkyl(12-14) ether (HLB: 10.5), POE(7) alkyl(12-14) ether (HLB: 12.0), POE(9) alkyl(12-14) ether (HLB: 13.5), POE(12) alkyl(12-14) ether (HLB: 14.5) are preferred, and POE (3) alkyl (12-14) ether (HLB: 8.0), POE (12) alkyl (12-14) ether (HLB: 14.5), POE (2) cetyl ether (HLB: 8.0), POE (40) cetyl ether (HLB: 20.0), POE (4) lauryl ether (HLB: 11.5), POE (9) lauryl ether (HLB: 14.5), and POE (25) lauryl ether (HLB: 19.5) are more preferred. The component (A) may contain one or more types.

Note that "HLB" is an abbreviation for Hydrophile-Lipophile Balance, and is generally a parameter that indicates the relative strength of hydrophilicity and lipophilicity of surfactant molecules; the higher the HLB value, the stronger the hydrophilicity, and the lower the HLB value, the stronger the lipophilicity. The HLB described in this invention is an actual measured value. The measurement method was as described in "Handbook - Cosmetics and Pharmaceutical Raw Materials - Revised Edition, Nikko Chemicals Co., Ltd., 1977, pages 854-855".

The content of the (A) component used in the present invention is preferably 0.5 to 3%, more preferably 0.6 to 2%, and even more preferably 0.8 to 1.5%. If the (A) component is less than 0.5%, the foam may not retain as much foam. If the (A) component is more than 3%, the foam may become sticky.

The average HLB of the component (A) used in the present invention is preferably 8.5 or more, more preferably 10 or more. If the average HLB of the component (A) is less than 8.5, the foam retention may decrease.

The aerosol concentrate of the present invention contains (B) an acrylic resin alkanolamine from the viewpoint of water resistance and abrasion resistance.

The (B) component used in the present invention is an acrylic resin neutralized with aminomethylpropanol (hereinafter referred to as AMP), aminomethylpropanediol (AMPD), triethanolamine (TEA), or the like. The (B) component is not particularly limited, but examples thereof include (acrylates/diacetoneacrylamide) copolymer AMP, acrylates copolymer AMP, and (acrylates/alkyl(C1-18)acrylate/alkyl(C1-8)acrylamide) copolymer AMP. Among these, (acrylates/diacetoneacrylamide) copolymer AMP and (acrylates/alkyl(C1-18)acrylate/alkyl(C1-8)acrylamide) copolymer AMP are preferred from the viewpoints of water resistance and abrasion resistance, and (acrylates/diacetoneacrylamide) copolymer AMP is more preferred from the viewpoint of flaking suppression. The (B) component may contain one or more types.

The content of the (B) component used in the present invention is preferably 0.1 to 5%, more preferably 0.5 to 2.5%, and even more preferably 0.7 to 2%. If the (B) component is less than 0.1%, water resistance and abrasion resistance may decrease. If the (B) component is more than 5%, flaking and stickiness may occur.

The aerosol concentrate of the present invention contains (C) a nonionic film-forming resin in order to suppress flaking.

The (C) component used in the present invention is not particularly limited, but examples thereof include (dimethylacrylamide/hydroxyethyl acrylate/methoxyethyl acrylate) copolymer, (hydroxyethyl acrylate/methoxyethyl acrylate) copolymer, (hydroxyethyl acrylate/butyl acrylate/methoxyethyl acrylate) copolymer, vinyl acetate-vinylpyrrolidone copolymer ((vinylpyrrolidone/VA) copolymer), polyvinylpyrrolidone, vinyl methyl ether-ethyl maleate copolymer, (vinylpyrrolidone/methacrylamide/vinylimidazole) copolymer, polyvinyl alcohol, etc. Among them, from the viewpoint of suppressing flaking, (dimethylacrylamide/hydroxyethyl acrylate/methoxyethyl acrylate) copolymer, (hydroxyethyl acrylate/methoxyethyl acrylate) copolymer, (hydroxyethyl acrylate/butyl acrylate/methoxyethyl acrylate) copolymer are preferred, and further, from the viewpoint of natural finish after use, (hydroxyethyl acrylate/methoxyethyl acrylate) copolymer is more preferred. The (C) component may contain one or more types.

The content of the (C) component used in the present invention is preferably 0.05 to 5%, more preferably 0.1 to 2%, and even more preferably 0.2 to 1%. If the (C) component is less than 0.05%, flaking may occur. If the (C) component is more than 5%, stickiness may result.

The aerosol concentrate of the present invention contains (D) an alkyl acrylate copolymer emulsion from the viewpoint of water resistance and abrasion resistance.

The component (D) used in the present invention is not particularly limited, but examples thereof include acrylates copolymer, ammonium acrylates copolymer, sodium acrylates copolymer, ammonium (styrene/alkyl acrylate) copolymer, etc., and ammonium acrylates copolymer is preferred from the viewpoint of suppressing flaking. The component (D) may contain one or more types.

The content of the (D) component used in the present invention is preferably 0.1 to 5%, more preferably 0.5 to 4%, and even more preferably 1 to 3%. If the (D) component is less than 0.1%, water resistance and abrasion resistance may decrease. If the (D) component is more than 5%, flaking and stickiness may occur.

The aerosol concentrate of the present invention contains a colorant (E) from the viewpoint of coloring properties.

The component (E) used in the present invention is not particularly limited, but examples thereof include inorganic pigments, pearl pigments, organic pigments, dye-resin solid solutions, daylight fluorescent pigments, and natural pigments. One or more types of component (E) may be contained. When two or more types of component (E) are contained, it is possible to create a variety of color tones.

Specific examples of the inorganic pigment include ultramarine, chromium oxide, red iron oxide, yellow iron oxide, titanium oxide, aluminum hydroxide, zinc oxide, cobalt oxide, black iron oxide, chromium hydroxide, aluminum hydroxide, Prussian blue, barium sulfate, hydrous silicate, silicic acid anhydride, aluminum silicate, mica, magnesium carbonate, manganese violet, carbon black, aluminum, copper, gold, etc. One or more of these inorganic pigments may be contained.

Specific examples of the pearl pigment include combinations of titanium oxide/iron oxide/mica, titanium oxide/ferric tungsten/mica, red iron oxide/mica, synthetic gold mica/iron oxide, alumina/silica/iron oxide, and synthetic gold mica/titanium oxide/tin oxide/iron oxide composite powders. Generic names for these composite powders include titanium mica, red iron oxide-coated mica, red iron oxide-coated titanium mica, black iron oxide-coated titanium mica, and chromium oxide-coated mica. These pearl pigments may contain one or more types.

Specific examples of the organic pigments include Red No. 202, Red No. 203, Red No. 204, Red No. 205, Red No. 206, Red No. 207, Red No. 208, Red No. 219, Red No. 220, Red No. 221, Red No. 228, Red No. 404, Red No. 405, Orange No. 203, Orange No. 204, Orange No. 401, Yellow No. 205, Yellow No. 401, Blue No. 404, Red No. 104 Aluminum Lake, Yellow No. 4 Aluminum Lake, Yellow No. 203 Aluminum Lake, Blue No. 1 Aluminum Lake, etc. These organic pigments may contain one or more types.

Specific examples of the natural pigments include mineral pigments such as clay, natural dye lakes such as madder lake and cochineal lake, azo pigments, phthalocyanine pigments, etc. One or more of these natural pigments may be contained.

Among the above colorants, inorganic pigments, organic pigments, and pearl pigments are preferred from the viewpoint of good color development on hair.

When the component (E) used in the present invention is an organic pigment or an inorganic pigment, the content is preferably 0.1 to 1%, and more preferably 0.2 to 0.8%. If the content of the (E) pigment is less than 0.1%, the coloring properties may be reduced. If the content of the (E) component is more than 1%, flaking may occur or abrasion resistance may be reduced.

When the component (E) used in the present invention is a pearl pigment, the content is preferably 1 to 10%, and more preferably 3 to 8%. If the content of the (E) pearl pigment is less than 1%, the coloring properties may be reduced. If the content of the (E) pearl pigment is more than 10%, flaking may occur or abrasion resistance may be reduced.

The present invention contains a propellant (F) in order to eject the foam from the aerosol container.

The (F) component used in the present invention is not particularly limited, but examples thereof include dimethyl ether (DME), isobutane, liquefied petroleum gas (LPG), and nitrogen gas. Among these, liquefied petroleum gas or dimethyl ether is preferred from the viewpoint of preventing clogging, and liquefied petroleum gas is more preferred from the viewpoint of good dischargeability. The (E) component may contain one or more types.

The initial internal pressure of the component (F) used in the present invention is preferably in the range of 0.2 to 0.5 MPa at 20°C. The initial internal pressure of liquefied petroleum gas can be adjusted to any desired value by changing the composition, and can also be adjusted by combining liquefied petroleum gas with other types of dimethyl ether, etc.

The mass ratio of the aerosol concentrate used in the present invention to the (F) component (aerosol concentrate:propellant) is preferably 97:3 to 80:20, more preferably 96:4 to 90:10, from the viewpoint of good ejection properties. If the mass ratio of the (F) component is less than 3, it may not be possible to eject the concentrate in the form of foam from the aerosol container. If the mass ratio of the (F) component is more than 20, the concentrate may splash and contaminate the surroundings.

In addition to the components (A) to (F), the aerosol type foam temporary colorant composition of the present invention can contain at least one selected from various components used in ordinary cosmetics, quasi-drugs, pharmaceuticals, etc., such as surfactants other than the component (A), oily components, moisturizers, thickeners, medicinal ingredients, protein derivatives, hydrolyzed proteins, stabilizers, antioxidants, plant extracts, herbal extracts, vitamins, preservatives, dyes, pigments, powders, pH adjusters, UV absorbers, fragrances, etc., within a range that does not impair the effects of the present invention. However, the components are not limited to these examples.

The aerosol type foam temporary colorant composition of the present invention can be used in an aerosol container made of metal, PET, or the like, depending on the application, purpose, method, environment of use, etc. The specifications of the aerosol container are not particularly limited, but examples of the container include pressure-resistant containers made of aluminum, tinplate, or plastic, the inside of which is coated with epoxyphenol or the like. Among these, aluminum is more preferable in terms of moldability and lightness. As the valve, a valve normally used for foams is used, and it is preferable to attach the valve, fill the propellant, and then attach a foam spout (e.g., "FD147W"3": manufactured by Mitani Valve Co., Ltd., etc.).

The aerosol type foam temporary colorant composition of the present invention can be applied to hair with a brush or by hand, with application with a brush being more preferred.

The aerosol type foam temporary colorant composition of the present invention may contain glass beads (12φ) for the purpose of dispersing colorants, etc.

The present invention will be described in more detail below with reference to examples, but these are not intended to limit the present invention in any way.

In the evaluation tests shown in this specification, the components contained in the aerosol type foam temporary colorant composition and their contents were varied. The units showing the contents of each component are all mass %, and the compositions were prepared by conventional methods.

<Evaluation>
In the evaluation test method shown in this specification, the evaluation items were "non-flaking,""non-stickiness,""coloration,""waterresistance," and "abrasion resistance," and the evaluation was conducted by 10 panelists. The evaluation item was "foam retention," and the evaluation was conducted by one panelist.

In the invention shown in this specification, in the evaluation tests for "freedom from flaking," "freedom from stickiness," "colorability," "water resistance," "abrasion resistance," and "foam retention," the obtained aerosol concentrate was filled into an aluminum can (manufactured by Takeuchi Press Kogyo Co., Ltd., outer diameter: 35 mm, total length: 100 mm, inner surface coating: TPL-419), two glass beads (12φ) were placed inside, an aerosol valve and a spout were installed, and then a propellant was filled to prepare 40 g of an aerosol type foam temporary colorant composition and evaluated.

<Lack of flaking>
2 g of the obtained aerosol type foam temporary colorant composition was applied directly and uniformly to a part of the hair of a hair test doll (100% human black hair, manufactured by Beaulax, model number: Queen Cut No. 775N) under conditions of 25°C, and the hair was dried with a hair dryer while being combed for 5 minutes. The hair was then combed 50 times using the V-shaped straight brush attached to the Benezel Straight Perm EX (manufactured by Dariya Co., Ltd.) and the degree of removal of the applied product was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
Almost no peeling of the coated area: 5 points Slight peeling of the coated area: 4 points Peeling of the coated area: 3 points Significant peeling of the coated area: 2 points Almost all peeling of the coated area: 1 point (average score criteria)
[Average score]: [Judgment]
4.5 or higher: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

＜Non-sticky＞
2 g of the obtained aerosol type foam temporary colorant composition was applied directly and uniformly to a part of the hair of a hair test doll (100% human black hair, manufactured by Bealux, model number: Queen Cut No. 775N) at 25°C, and the hair was dried with a hair dryer while combing for 5 minutes, and the feel of the hair after the heat had disappeared was evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
Not sticky at all: 5 points Not sticky: 4 points Almost not sticky: 3 points Sticky: 2 points Very sticky: 1 point (average score criteria)
[Average score]: [Judgment]
4.5 or higher: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Coloring>
2 g of the obtained aerosol type foam temporary colorant composition was applied directly and uniformly to a part of the hair of a hair test doll (100% human black hair, manufactured by Bealux, model number: Queen Cut No. 775N) at 25°C under conditions of 25°C, and the hair was dried with a hair dryer while being combed for 5 minutes, and the state of hiding of the hair was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
Very good coloring: 5 points Good coloring: 4 points Fairly good coloring: 3 points Fairly poor coloring: 2 points Poor coloring: 1 point (average score criteria)
[Average score]: [Judgment]
4.5 or higher: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Water resistance>
0.25 g of the obtained aerosol type foam temporary colorant composition was applied to 1 g of a 100% black hair bundle (product number: BS-B-A, manufactured by Bealux Co., Ltd.) at 25°C using a V-shaped straight brush attached to "Benezel Straight Perm EX (manufactured by Dariya Co., Ltd.)", and then dried with a hair dryer while combing for 5 minutes. Hot water adjusted to 40°C was sprayed onto the hair bundle from a distance of 20 cm using a spray bottle, and the drops dripping from the hair bundle were collected in a lightweight standard glass bottle No. 5K, and the coloring of the hot water was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
No coloring in the water: 5 points Slight coloring in the water: 4 points Coloring in the water is visible: 3 points Considerable coloring in the water: 2 points Extremely coloring in the water: 1 point (average score criteria)
[Average score]: [Judgment]
4.5 or higher: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Abrasion resistance>
0.25 g of the obtained aerosol type foam temporary colorant composition was applied to 1 g of a 100% black hair bundle (product number: BS-B-A, manufactured by Bealux Co., Ltd.) using a V-shaped straight brush attached to "Venezel Straight Perm EX (manufactured by Dariya Co., Ltd.)" at 25°C and allowed to dry naturally for 24 hours. Next, the hair bundle was fixed to a horizontal stand, and a test white cloth (attached white cloth for JIS L 0803 color fastness test) wrapped around a weight of 850 g was placed on the test hair bundle, which was rubbed three times, and color transfer was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
No transfer at all: 5 points Almost no transfer: 4 points Transfer is visible: 3 points Considerable transfer: 2 points Very much transfer: 1 point (average score criteria)
[Average score]: [Judgment]
4.5 or higher: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Foam mochi>
2 g of the obtained aerosol type foam temporary colorant composition was discharged into a 300 mL tall beaker at 25°C and allowed to stand for 10 minutes. After that, the appearance of the foam remaining in the 300 mL tall beaker was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Judgment]
More than 80% of the foam remains compared to the initial state: ◎
Compared to the initial state, between 50% and 80% of the foam remains: ○
Compared to the initial state, between 20% and 50% of the foam remains: △
Less than 20% of the foam remains compared to the initial state: ×

Examples 1 to 12 shown in Table 1 showed no flaking or stickiness, and showed good results in terms of colorability, water resistance, abrasion resistance, and foam retention.

Examples 13 to 20 shown in Table 2 showed no flaking or stickiness, and showed good results in terms of colorability, water resistance, abrasion resistance, and foam retention.

Examples 21 to 30 shown in Table 3 showed no flaking or stickiness, and showed good results in terms of colorability, water resistance, abrasion resistance, and foam retention.

Examples 31 to 40 shown in Table 4 showed no flaking or stickiness, and showed good results in terms of colorability, water resistance, abrasion resistance, and foam retention.

Examples 41 to 50 shown in Table 5 showed no flaking or stickiness, and showed good results in terms of colorability, water resistance, abrasion resistance, and foam retention.

Examples 51 to 57 shown in Table 6 showed no flaking or stickiness, and showed good results in terms of colorability, water resistance, abrasion resistance, and foam retention.

Examples 58 to 66 shown in Table 7 showed no flaking or stickiness, and showed good results in terms of colorability, water resistance, abrasion resistance, and foam retention.

The aerosol type foam temporary colorant compositions obtained in the following Examples 67 to 70 were free of flaking and stickiness, and gave good results in terms of coloring, water resistance, abrasion resistance, and foam retention.

Example 67
Component Content (mass%)
(A) POE (2) cetyl ether (HLB: 8.0) 0.20%
(A) POE (40) cetyl ether (HLB: 20.0) 1.00%
(B) (Acrylates/diacetone acrylamide) copolymer AMP 2.00%
(C) (hydroxyethyl acrylate/methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylates copolymer ammonium 1.44%
(E) Red iron oxide 0.20%
(E) Bengala/mica *3 4.80%
(E) Synthetic gold mica/iron oxide *4 1.60%
Concentrated glycerin 0.20%
Bentonite 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-pantothenyl alcohol 0.20%
Polyoxyethylene coconut oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance: 0.01%
Highly polymerized methylpolysiloxane (1) 1.25%
Purified water 74.49%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol concentrate (average HLB: 18.0) 95.00%
Liquefied petroleum gas (20℃, 0.39MPa) 5.00%
Total 100.00%

Example 68
Component Content (mass%)
(A) POE (7) alkyl (12-14) ether (HLB: 12.0) 1.00%
(B) (Acrylates/diacetone acrylamide) copolymer AMP 2.00%
(C) (hydroxyethyl acrylate/methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylates copolymer ammonium 1.44%
(E) Red iron oxide 0.20%
(E) Bengala/mica *3 3.20%
(E) Synthetic gold mica/iron oxide *4 3.20%
Concentrated glycerin 0.20%
Bentonite 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-pantothenyl alcohol 0.20%
Polyoxyethylene coconut oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance: 0.01%
Highly polymerized methylpolysiloxane (1) 1.25%
Purified water 74.69%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol concentrate 95.00%
Liquefied petroleum gas (20℃, 0.39MPa) 5.00%
Total 100.00%

Example 69
Component Content (mass%)
(A) POE (4) lauryl ether (HLB: 11.5) 0.83%
(A) POE (9) lauryl ether (HLB: 14.5) 0.17%
(B) (Acrylates/diacetone acrylamide) copolymer AMP 2.00%
(C) (hydroxyethyl acrylate/methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylates copolymer ammonium 1.44%
(E) Red iron oxide 0.20%
(E) Bengala/mica *3 3.20%
(E) Synthetic gold mica/iron oxide *4 3.20%
Concentrated glycerin 0.20%
Bentonite 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-pantothenyl alcohol 0.20%
Polyoxyethylene coconut oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance: 0.01%
Highly polymerized methylpolysiloxane (1) 1.25%
Purified water 74.69%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol concentrate (average HLB: 12.0) 95.00%
Liquefied petroleum gas (20℃, 0.39MPa) 5.00%
Total 100.00%

Example 70
Component Content (mass%)
(A) POE (4) lauryl ether (HLB: 11.5) 0.83%
(A) POE (9) lauryl ether (HLB: 14.5) 0.17%
(B) (Acrylates/diacetone acrylamide) copolymer AMP 2.00%
(C) (hydroxyethyl acrylate/methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylates copolymer ammonium 1.44%
(E) Red iron oxide 0.20%
(E) Bengala/mica *3 3.20%
(E) Synthetic gold mica/iron oxide *4 3.20%
POE(10) sodium lauryl ether phosphate 0.50%
Concentrated glycerin 0.20%
Bentonite 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-pantothenyl alcohol 0.20%
Polyoxyethylene coconut oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance: 0.01%
Highly polymerized methylpolysiloxane (1) 1.25%
Purified water 74.19%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol concentrate (average HLB: 12.0) 95.00%
Liquefied petroleum gas (20℃, 0.39MPa) 5.00%
Total 100.00%

The present invention makes it possible to obtain an aerosol type foam temporary colorant composition that is free of flaking and stickiness, and has good coloring properties, water resistance, abrasion resistance, and foam retention.

Claims (1)

An aerosol type foam temporary colorant composition which is discharged in a foam form from an aerosol container,
(A) Polyoxyethylene alkyl ether type nonionic surfactant (B) (acrylates/diacetone acrylamide) copolymer AMP
(C) (hydroxyethyl acrylate/methoxyethyl acrylate) copolymer; (D) ammonium acrylate copolymer; (E) one or more selected from organic pigments, inorganic pigments and pearl pigments;
and (F) a propellant,
An aerosol type foam temporary colorant composition, characterized in that the average HLB of the component (A) in the aerosol concentrate is 10 or more, the content of the component (A) is 0.8 to 1.5 mass%, the content of the component (B) is 0.7 to 2 mass%, the content of the component (C) is 0.2 to 1 mass%, the content of the component (D) is 1 to 3 mass%, the content of the component (E) is 0.2 to 0.8 mass% when the component (E) is an organic pigment or an inorganic pigment, and the content of the component (E) is 3 to 8 mass% when the component (E) is a pearl pigment, and the mass ratio of the aerosol concentrate to the component (F) is 96:4 to 80:20 .