JP7620798B2 - Glass polishing equipment - Google Patents
Glass polishing equipment Download PDFInfo
- Publication number
- JP7620798B2 JP7620798B2 JP2020034375A JP2020034375A JP7620798B2 JP 7620798 B2 JP7620798 B2 JP 7620798B2 JP 2020034375 A JP2020034375 A JP 2020034375A JP 2020034375 A JP2020034375 A JP 2020034375A JP 7620798 B2 JP7620798 B2 JP 7620798B2
- Authority
- JP
- Japan
- Prior art keywords
- tool
- acrylic
- machining
- processing
- workpiece
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005498 polishing Methods 0.000 title claims description 54
- 239000011521 glass Substances 0.000 title claims description 53
- 238000003754 machining Methods 0.000 claims description 99
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 89
- 239000012530 fluid Substances 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 18
- 239000006061 abrasive grain Substances 0.000 claims description 12
- 238000012545 processing Methods 0.000 description 111
- 230000003746 surface roughness Effects 0.000 description 32
- 238000002474 experimental method Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 230000002378 acidificating effect Effects 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 7
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 7
- 239000010453 quartz Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- 239000003082 abrasive agent Substances 0.000 description 5
- 239000000920 calcium hydroxide Substances 0.000 description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 125000004185 ester group Chemical group 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- -1 hydrogen ions Chemical class 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 239000011146 organic particle Substances 0.000 description 3
- RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 3
- 238000012993 chemical processing Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001900 extreme ultraviolet lithography Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000005469 synchrotron radiation Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
Landscapes
- Grinding-Machine Dressing And Accessory Apparatuses (AREA)
- Surface Treatment Of Glass (AREA)
- Grinding Of Cylindrical And Plane Surfaces (AREA)
Description
特許法第30条第2項適用 平成31年3月13日、東京電機大学にて開催された2019年度精密工学会春季大会学術講演会で発表Application of Article 30, Paragraph 2 of the Patent Act. Presented at the 2019 Japan Society of Precision Engineering Spring Meeting Academic Lecture held at Tokyo Denki University on March 13, 2019.
本発明は、ガラス研磨加工方法に関する。 The present invention relates to a glass polishing method.
近年、波長が短い光を用いた光学分野の発展が著しい。次世代半導体露光装置のEUVリソグラフィーでは、波長13.5nmのEUV(Extreme Ultraviolet)光を用い、さらなる集積回路の微細化を目指している。また、SPring8等の大型放射光施設においては、波長0.1nm以下の硬X線を用い、原子・分子レベルの分解能で物質の構造、組成、化学状態を解析している。X線・EUV領域において、優れた光学システムや光学機器を開発するためには、光源性能を損なわない高精度な光学素子(ミラー、レンズ)が不可欠である。 In recent years, there has been remarkable development in the field of optics using short-wavelength light. EUV lithography, a next-generation semiconductor exposure device, aims to further miniaturize integrated circuits by using EUV (Extreme Ultraviolet) light with a wavelength of 13.5 nm. In addition, large-scale synchrotron radiation facilities such as SPring-8 use hard X-rays with wavelengths of 0.1 nm or less to analyze the structure, composition, and chemical state of materials with atomic and molecular level resolution. In order to develop excellent optical systems and optical equipment in the X-ray and EUV range, high-precision optical elements (mirrors, lenses) that do not impair the performance of the light source are essential.
このような光学素子に用いるガラス材料の研磨加工には、酸化セリウムやコロイダルシリカに代表される無機材料を遊離砥粒として用いた研磨加工技術が広く用いられている(例えば、特許文献1参照。)。これらの材料は良好な表面粗さを達成することができるが、密度が大きいため加工液中での分散性に欠け、加工の間、撹拌を続ける必要がある。また、加工後に加工物表面に砥粒が残存し、容易に洗浄できないという問題もある。 In polishing the glass materials used in such optical elements, polishing techniques using inorganic materials such as cerium oxide and colloidal silica as free abrasive grains are widely used (see, for example, Patent Document 1). These materials can achieve good surface roughness, but because of their high density, they lack dispersibility in the processing liquid, and continuous stirring is required during processing. In addition, there is also the problem that abrasive grains remain on the surface of the workpiece after processing, making them difficult to clean.
これに対し、本発明者らは既に、アクリルやウレタンなどの有機粒子を遊離砥粒として用いる研磨加工技術であるOrganic Abrasive Machining(OAM法)を開発している(特許文献2を参照。)。有機粒子を用いるメリットは、水と比重が近いため粒子の分散性が非常に高い、工作物と比べて柔らかく加工傷が付きにくい、有機溶剤に溶解するため加工後の除去が容易、安価で入手し易いといった点が挙げられる。上記OAM法では、アクリル粒子を用いて100μm空間分解能の修正研磨加工が達成されている。 In response to this, the present inventors have already developed Organic Abrasive Machining (OAM method), a polishing technique that uses organic particles such as acrylic or urethane as free abrasive grains (see Patent Document 2). The advantages of using organic particles include that the particles have a specific gravity close to that of water, making them highly dispersible; they are softer than the workpiece and less likely to be scratched during processing; they dissolve in organic solvents, making them easy to remove after processing; and they are inexpensive and readily available. In the OAM method, corrective polishing with a spatial resolution of 100 μm has been achieved using acrylic particles.
しかしながら、このような遊離砥粒を用いた研磨加工技術は、加工中の遊離砥粒の濃度、状態などを常に一定に保つ必要があり、管理が難しく、コスト高になるという課題がある。また、加工後に加工物表面の砥粒の洗浄も必要であり、環境への負荷やコスト高の原因にもなるといった課題もある。 However, such polishing techniques using free abrasive grains require the concentration and state of the free abrasive grains to be kept constant during processing, which makes them difficult to manage and increases costs. In addition, the abrasive grains on the workpiece surface must be cleaned after processing, which can be an environmental burden and a cost increase.
そこで、本発明が前述の状況に鑑み、解決しようとするところは、加工液の管理が容易で、コストを抑えることができ、加工後の加工物表面の砥粒の洗浄も簡易化でき、環境への負荷やコスト高を抑えることが可能なガラス研磨加工方法およびガラス研磨加工装置を提供する点にある。 In view of the above-mentioned situation, the present invention aims to provide a method and apparatus for polishing glass that allows easy management of the processing fluid, reduces costs, simplifies cleaning of the abrasive grains on the workpiece surface after processing, and reduces environmental impact and costs.
本発明者は、有機粒子を遊離砥粒として用いた上述のOAM法のメカニズムの探査を進める中で、アクリル材料が砥粒の存在しない純水の下でガラス面を精度よく研磨することを発見し、アクリル材料を加工ツールとして用いることで、砥粒を含まない純水のみからなる加工液でガラスを精度よく研磨加工できること、とくに大面積を効率よく平坦に研磨できること、これにより上記した遊離砥粒を用いた研磨加工技術の課題(加工液の管理、コスト、環境負荷などの課題)も解決できることを見出し、本発明を完成するに至ったものである。 While exploring the mechanism of the above-mentioned OAM method using organic particles as free abrasives, the inventor discovered that acrylic materials can accurately polish glass surfaces in pure water that does not contain abrasives. He discovered that by using acrylic materials as a processing tool, glass can be accurately polished using a processing fluid consisting only of pure water that does not contain abrasives, and that large areas in particular can be polished flat efficiently, thereby solving the problems with the above-mentioned polishing technology using free abrasives (problems such as management of the processing fluid, costs, and environmental impact), and thus completed the present invention.
すなわち本発明は、以下の発明を包含する。
(1) ガラスの研磨加工方法であって、ガラス製のワークとアクリル製のツールとの間に、純水またはpHを調整した水溶液であり、砥粒を含有しない加工液を供給しながら、互いに加圧接触させた状態で相対運動させて研磨加工を行うことを特徴とする、ガラス研磨加工方法。
That is, the present invention includes the following inventions.
(1) A method for polishing glass, comprising the steps of: supplying a processing liquid, which is pure water or an aqueous solution with an adjusted pH and does not contain abrasive grains, between a glass workpiece and an acrylic tool; and moving the workpiece and acrylic tool relative to each other while bringing them into pressurized contact with each other to perform the polishing process.
(2) 前記ツールをアクリル定盤とし、回転する該アクリル定盤の表面に対し、前記ガラス製のワークを加圧接触させて平坦に研磨加工する、(1)記載のガラス研磨加工方法。 (2) The method for polishing glass described in (1), in which the tool is an acrylic platen, and the glass workpiece is pressed against and polished flat against the surface of the rotating acrylic platen.
(3) 前記ワークを、前記アクリル定盤の回転軸と平行な軸を中心に回転させながら、前記アクリル定盤の表面に対して加圧接触させる、(2)記載のガラス研磨加工方法。 (3) The glass polishing method described in (2), in which the workpiece is brought into pressurized contact with the surface of the acrylic platen while rotating about an axis parallel to the axis of rotation of the acrylic platen.
(4) 前記加工液を、回転する前記アクリル定盤の表面に供給する、(2)又は(3)記載のガラス研磨加工方法。 (4) The method for polishing glass according to (2) or (3), in which the processing liquid is supplied to the surface of the rotating acrylic platen.
(5) アクリル製のツールと、ガラス製のワークとアクリル製のツールとの間に、純水またはpHを調整した水溶液であって砥粒を含有しない加工液を供給する加工液供給手段と、前記ワークと前記ツールを、互いに加圧接触させる加圧手段と、前記加圧手段による加圧接触状態で、前記ワークと前記ツールを相対運動させて研磨加工を行う相対動作手段と、を備えるガラス研磨加工装置。 (5) A glass polishing device comprising: an acrylic tool; a processing fluid supplying means for supplying a processing fluid between a glass workpiece and the acrylic tool, which is pure water or an aqueous solution with an adjusted pH and does not contain abrasive grains; a pressurizing means for bringing the workpiece and the tool into pressurized contact with each other; and a relative movement means for performing polishing by moving the workpiece and the tool relative to each other while in pressurized contact state caused by the pressurizing means.
(6) 前記ツールがアクリル定盤であり、前記相対動作手段が、前記アクリル定盤を回転する回転手段を備え、回転するアクリル定盤の表面に対し、前記ガラス製のワークを加圧接触させて平坦に研磨加工する、(5)記載のガラス研磨加工装置。 (6) The glass polishing device according to (5), in which the tool is an acrylic platen, the relative movement means includes a rotation means for rotating the acrylic platen, and the glass workpiece is pressed into contact with the surface of the rotating acrylic platen to polish it flat.
(7) 前記相対動作手段が、前記ワークを、前記アクリル定盤の回転軸と平行な軸を中心に回転させる第2の回転手段を備え、前記ワークを回転させながら、前記アクリル定盤の表面に対して加圧接触させて平坦に研磨加工する、(6)記載のガラス研磨加工装置。 (7) The glass polishing device according to (6), in which the relative movement means includes a second rotation means for rotating the workpiece around an axis parallel to the rotation axis of the acrylic platen, and the workpiece is pressed against the surface of the acrylic platen while being rotated, thereby polishing the workpiece flat.
(8) 前記加工液供給手段が、前記加工液を回転する前記アクリル定盤の表面に供給してなる、(6)又は(7)記載のガラス研磨加工装置。 (8) The glass polishing device according to (6) or (7), in which the processing liquid supply means supplies the processing liquid to the surface of the rotating acrylic platen.
以上にしてなる本願発明によれば、砥粒の存在しない加工液で精度よくガラス面を研磨できるので、遊離砥粒を用いた研磨加工技術の課題(加工液の管理、コスト、環境負荷などの課題)を解決できるとともに、大面積を効率よく平坦に研磨できる。 According to the present invention, glass surfaces can be polished with high precision using abrasive-free processing fluid, which not only solves the problems associated with polishing techniques that use free abrasives (such as fluid management, costs, and environmental impact), but also enables large areas to be polished efficiently and flat.
次に、本発明の実施形態を添付図面に基づき詳細に説明する。 Next, an embodiment of the present invention will be described in detail with reference to the attached drawings.
図1は、第1実施形態に係る本発明のガラス研磨加工装置1Aの構成を示しており、図中(a)は装置の概略図、(b)はアクリル固定ツール、(c)は加工対象である合成石英を示している。 Figure 1 shows the configuration of a glass polishing device 1A according to the first embodiment of the present invention, where (a) is a schematic diagram of the device, (b) shows the acrylic fixed tool, and (c) shows the synthetic quartz to be processed.
本実施形態のガラス研磨加工装置1Aは、アクリル製のツール2と、ガラス製のワーク9とアクリル製のツール2との間に加工液を供給する加工液供給手段3と、ワーク9とツール2を、互いに加圧接触させる加圧手段4と、加圧手段4による加圧接触状態で、ワーク9とツール2を相対運動させて研磨加工を行う相対動作手段5とを備えている。 The glass polishing device 1A of this embodiment includes an acrylic tool 2, a processing fluid supplying means 3 for supplying processing fluid between a glass workpiece 9 and the acrylic tool 2, a pressurizing means 4 for bringing the workpiece 9 and the tool 2 into pressurized contact with each other, and a relative movement means 5 for performing polishing by moving the workpiece 9 and the tool 2 relative to each other while in pressurized contact state by the pressurizing means 4.
ワーク9は、合成石英などのガラスである。アクリル製のツール2は、半球状のツールとされている。形状はとくに半球状に限定されるものではない。アクリルツール2は、棒材20の先端に取り付けた冶具21の下に交換可能に固定されている。 The workpiece 9 is glass such as synthetic quartz. The acrylic tool 2 is a hemispherical tool. The shape is not particularly limited to a hemispherical shape. The acrylic tool 2 is replaceably fixed under a jig 21 attached to the tip of a rod 20.
加工液供給手段3は、上記振動装置52の上に加工液を入れる容器30が設けられ、その底部にワーク9が取り付けられることで、ワーク9が加工液中に完全に浸漬された状態となる。加工液は、純水、またはpHを調整した水溶液であり、砥粒を含有しない。ツール2とワーク9は、容器30内の加工液中に浸され、該加工液中で加工が行われる。浸漬以外の方法、たとえばワーク9の被加工面に加工液を吹き付ける手段を設けたものでもよい。「pHを調整した水溶液」としては、pHを6以下の酸性水溶液とすることや、pH10程度のアルカリ性の炭酸ナトリウム水溶液を用いることが良好な表面粗さを維持しつつ加工できる点で好ましい。より優れた表面粗さを得るためには、pH4以下、さらに好ましくは3.5~1の酸性水溶液を用いることが好ましい。ただし、酸性水溶液の場合、pHが低くなるにつれて加工深さが浅くなるので、加工深さも求める場合には、pH3以上のものを用いることが好ましい。また、表面粗さは悪化するが、より優れた加工深さ(加工速度)を得るためには、pH10程度のアルカリ性の水酸化カルシウム水溶液を用いることも好ましい。 The machining fluid supply means 3 is provided with a container 30 for holding the machining fluid on the vibration device 52, and the workpiece 9 is attached to the bottom of the container 30 so that the workpiece 9 is completely immersed in the machining fluid. The machining fluid is pure water or an aqueous solution with an adjusted pH, and does not contain abrasive grains. The tool 2 and the workpiece 9 are immersed in the machining fluid in the container 30, and machining is performed in the machining fluid. Methods other than immersion, such as a means for spraying the machining fluid on the machining surface of the workpiece 9, may also be used. As the "pH-adjusted aqueous solution," an acidic aqueous solution with a pH of 6 or less or an alkaline sodium carbonate aqueous solution with a pH of about 10 is preferable in that machining can be performed while maintaining good surface roughness. In order to obtain a better surface roughness, it is preferable to use an acidic aqueous solution with a pH of 4 or less, more preferably 3.5 to 1. However, in the case of an acidic aqueous solution, the lower the pH, the shallower the machining depth becomes, so if machining depth is also required, it is preferable to use an aqueous solution with a pH of 3 or more. It is also preferable to use an alkaline calcium hydroxide solution with a pH of about 10 to obtain a better machining depth (machining speed), although this will result in a worsening of the surface roughness.
相対動作手段5として、ツール2の鉛直方向に延びる棒材20を棒材の軸を中心に回転させ、ツール2を回転運動させるモータ51と、棒材20の軸と直交する水平方向にワーク9を容器30とともに往復運動させる振動装置(シェーカー)52とが設けられている。容器30の加工液中でツールは回転運動し、ワーク9は容器30とともに一定距離の区間で往復直線運動する。 The relative motion means 5 includes a motor 51 that rotates the vertically extending bar 20 of the tool 2 around the axis of the bar, causing the tool 2 to rotate, and a vibration device (shaker) 52 that causes the workpiece 9 to reciprocate together with the container 30 in a horizontal direction perpendicular to the axis of the bar 20. The tool rotates in the machining fluid in the container 30, and the workpiece 9 reciprocates linearly together with the container 30 over a certain distance.
加圧手段4は、棒材20の上端に皿41を取り付け、重りを載せる。この重りによって、ツール2とワーク9の間にかかる荷重を制御する。また、モータ51は、リニアブッシュ40を介して案内柱に上下移動自在に取り付けられている。これにより、重りと皿41、さらに回転モータ51の総重量が荷重としてツール2とワーク9の間に加える。本実施形態の装置では、回転と往復を組み合わせることで線状のガラス研磨加工を行うことができ、振動装置を止めて回転のみで点状のガラス研磨加工を行うこともできる。 The pressure applying means 4 has a plate 41 attached to the upper end of the rod 20 and a weight placed on it. The weight controls the load applied between the tool 2 and the workpiece 9. The motor 51 is attached to the guide column via a linear bushing 40 so that it can move up and down freely. This means that the total weight of the weight, plate 41, and rotating motor 51 is applied as a load between the tool 2 and the workpiece 9. In the device of this embodiment, linear glass polishing can be performed by combining rotation and reciprocation, and point-shaped glass polishing can also be performed by stopping the vibration device and rotating only.
次に、本発明の加工原理について説明する。後述する各種実験でも明らかなように、アクリル以外の素材のツールではガラスへの研磨加工が進行しなかった。もし加工が機械的な力のみによって引き起こされるのであれば、工具としてより高い硬度を有するPC等により合成石英を加工することができなければならない。 Next, we will explain the processing principle of the present invention. As will be clear from various experiments described later, polishing of glass did not proceed with tools made of materials other than acrylic. If processing were caused by mechanical force alone, synthetic quartz should be processed using tools made of materials with higher hardness, such as PC.
このことは、本発明にかかるアクリルツールによるガラスの研磨加工が、機械的な力に加えて化学的加工効果を持つことを示している。また、加工がガラスの加工液への溶出によってのみ引き起こされる場合、任意の有機材料が加工ツールとして用いることができるはずであるが、図7の結果はそうではなく、アクリル以外の材料は純水中でガラスを加工することができなかった。 This shows that the polishing of glass using the acrylic tool of the present invention has a chemical processing effect in addition to mechanical force. Also, if the processing is caused only by the dissolution of glass into the processing liquid, any organic material should be able to be used as a processing tool, but the results in Figure 7 show that this is not the case, and materials other than acrylic were unable to process glass in pure water.
考察するに、アクリルは、エステル基を含み、そのエステル基が側鎖に位置している。これに対し、ガラスを加工できなかったPBTやPCは、エステル基を含有するが、そのエステル基は主鎖に位置している(図3参照)。側鎖に位置するエステル基は、主鎖に位置する場合に比べて容易に加水分解され、CO-を生成しやすい。したがって、図4に示すように、このCO-に加工液中の水酸化物が結合してヒドロキシル基(-OH)が終端された表面を形成することにより、アクリルツールは、酸素原子を介してガラス内のSiと結合し、ガラス表面からSiがツール側に引き抜かれて除去されると考えられる。 In consideration, acrylic contains ester groups, which are located on the side chain. In contrast, PBT and PC, which could not process glass, contain ester groups, but these ester groups are located on the main chain (see Figure 3). Ester groups located on the side chain are more easily hydrolyzed and more likely to generate CO- than those located on the main chain. Therefore, as shown in Figure 4, hydroxides in the processing liquid bind to this CO-, forming a surface terminated with hydroxyl groups (-OH), and it is believed that the acrylic tool bonds with Si in the glass via oxygen atoms, and Si is pulled out from the glass surface and removed by the tool side.
次に、本発明の第2実施形態を説明する。 Next, we will explain the second embodiment of the present invention.
図5は、第2実施形態に係るガラス研磨加工装置1Bの概略構成を示している。 Figure 5 shows the schematic configuration of the glass polishing device 1B according to the second embodiment.
本実施形態のガラス研磨加工装置1Bは、ガラスの大面積平坦化に適した装置としたものであり、図5に示すように、アクリル定盤の加工ツール2と、ガラス板のワーク9と加工ツール2の間に加工液8を供給する加工液供給手段3と、ワーク9とツール2を互いに加圧接触させる加圧手段4と、加圧手段4による加圧接触状態で、ワーク9とツール2を相対運動させて研磨加工を行う相対動作手段5とを備えている。 The glass polishing device 1B of this embodiment is an apparatus suitable for flattening a large area of glass, and as shown in FIG. 5, it is equipped with an acrylic platen processing tool 2, processing liquid supply means 3 for supplying processing liquid 8 between a glass plate workpiece 9 and the processing tool 2, a pressure means 4 for bringing the workpiece 9 and the tool 2 into pressurized contact with each other, and a relative movement means 5 for performing polishing by moving the workpiece 9 and the tool 2 relative to each other while in pressurized contact state by the pressure means 4.
相対動作手段5は、本実施形態ではアクリル定盤のツール2を回転させる機構を内蔵した第1の回転手段としての回転台53と、ワーク9をアクリル定盤(ツール2)の回転軸と平行な軸を中心に回転させる第2の回転手段としての回転装置54とを備え、ワーク9を回転させつつ、別途回転するアクリル定盤(ツール2)の表面に加圧接触させて平坦に研磨加工するものである。2つの回転は軸位置および回転径が互いに異なっているため、ワーク加工面とツール(アクリル定盤)の間の相対運動が発生する。 In this embodiment, the relative motion means 5 comprises a turntable 53 as a first rotation means incorporating a mechanism for rotating the tool 2 of the acrylic platen, and a rotation device 54 as a second rotation means for rotating the workpiece 9 around an axis parallel to the rotation axis of the acrylic platen (tool 2). While rotating the workpiece 9, it is pressed into contact with the surface of the separately rotating acrylic platen (tool 2) to polish it flat. Since the two rotations have different axial positions and rotational diameters, relative motion occurs between the workpiece machining surface and the tool (acrylic platen).
回転装置54は、ツール2の表面近くで複数のワークを上下に移動可能な状態で保持する保持穴を備えた保持プレート540と、各保持穴に保持されたワークを上方から加圧してツール2表面に押し付ける加圧手段4としての加圧シリンダ42とを下端部に備え、これらを内臓のモータで一体的に回転させるように構成されている。この回転装置54により、複数のワークが回転軸のまわりを回転し、ツール2によって同時に平坦研磨加工される。 The rotating device 54 is equipped with a holding plate 540 with holding holes that hold multiple workpieces near the surface of the tool 2 in a state where they can be moved up and down, and a pressure cylinder 42 at its lower end as a pressure means 4 that applies pressure from above to the workpieces held in each holding hole and presses them against the surface of the tool 2, and is configured to rotate these together with an internal motor. The rotating device 54 rotates the multiple workpieces around the rotation axis, and the tool 2 simultaneously polishes them flat.
加工液供給手段3は、加工液8を回転するツール2(アクリル定盤)の表面に噴霧するポンプとノズルから構成されている。このようにツール2に加工液を吹き付けるものの他、ツール2とワーク9を加工液中に浸すように構成することも可能である。 The machining fluid supplying means 3 is composed of a pump and a nozzle that sprays machining fluid 8 onto the surface of the rotating tool 2 (acrylic platen). In addition to spraying machining fluid onto the tool 2 in this way, it is also possible to configure the tool 2 and the workpiece 9 to be immersed in the machining fluid.
本実施形態の研磨加工装置は、同様の加圧手段4、相対動作手段5、加工液供給手段3を備える公知の平坦研磨加工装置を用いて、加工ツールのみ通常使用される研磨パッドからアクリル定盤に変更して構成することができる。加工液8、ワーク9、その他の構成、加工原理は、基本的に上述の第1実施形態と同じであるので、その説明は省略する。 The polishing device of this embodiment can be constructed using a known flat polishing device equipped with the same pressure means 4, relative movement means 5, and processing liquid supply means 3, with only the processing tool being changed from the normally used polishing pad to an acrylic surface plate. The processing liquid 8, workpiece 9, other configurations, and processing principles are basically the same as those of the first embodiment described above, so their explanation will be omitted.
<ツール材料の比較試験1 点状研磨にて>
第1実施形態の装置を用い、ツールの材料のみ変えて、点状研磨加工(振動装置を停止した加工)の違いを確認する実験を行った結果について説明する。
<Tool material comparison test 1 by spot polishing>
The results of an experiment conducted using the device of the first embodiment to confirm the difference in point polishing (processing with the vibration device stopped) by changing only the material of the tool will be described.
(加工条件)
加工条件を表1に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 1. The tip of the tool was hemispherical with a diameter of 10 mm.
(結果)
結果を図6(a)~図6(e)に示す。各図の左側は、各ツールによる点状加工痕の走査型白色干渉計(Zygo社製の白色干渉計NewView 700s)による計測結果、右側は深さプロファイルを示している。加工の結果により、アクリル、PC、ABSツールを用いて明らかな加工痕が得られるが、他は得られなかった。また、最も深い加工痕がアクリルツールによって得られた。PC、ABSツールで加工した加工面は加工スジが多く、アクリルツールで加工した加工面は比較的平滑であった。
(result)
The results are shown in Figures 6(a) to 6(e). The left side of each figure shows the measurement results of the point-like processing marks made by each tool using a scanning white light interferometer (Zygo's NewView 700s white light interferometer), and the right side shows the depth profile. The processing results showed that clear processing marks were obtained using the acrylic, PC, and ABS tools, but not the others. In addition, the deepest processing marks were obtained with the acrylic tool. The surfaces processed with the PC and ABS tools had many processing streaks, while the surfaces processed with the acrylic tool were relatively smooth.
<ツール材料の比較試験2 線状研磨にて>
同じく第1実施形態の装置を用い、ツールの材料のみ変えて線状研磨加工(回転と往復振動の組み合わせ加工)の違いを確認する実験を行った結果について説明する。
<Tool material comparison test 2: Linear polishing>
Similarly, using the apparatus of the first embodiment, an experiment was conducted to confirm the difference in linear polishing (combination of rotation and reciprocating vibration) by changing only the material of the tool. The results will be described.
(加工条件)
加工条件を表2に示す。ツールの先端は、同じく直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 2. The tip of the tool was also hemispherical with a diameter of 10 mm.
(結果)
結果を図7(a)~図7(e)に示す。各図の左側は、各ツールによる線状加工痕の走査型白色干渉計による計測結果である。加工の結果により、アクリルツールを用いて明らかな加工痕が得られ、他の有機材料ツールで加工痕を形成できないことが分かった。
なお、明らかな加工痕が得られたアクリルツールのみ、加工痕全体を計測し、加工痕が得られなかった他のツールは、左端から3.7mm程度の場所のみ測定した。
(result)
The results are shown in Figures 7(a) to 7(e). The left side of each figure shows the measurement results of the linear processing marks made by each tool using a scanning white light interferometer. The processing results show that clear processing marks were obtained using the acrylic tool, but processing marks could not be formed using other organic material tools.
Only for the acrylic tools on which clear processing marks were obtained, the entire processing marks were measured, and for the other tools on which no processing marks were obtained, only a location approximately 3.7 mm from the left end was measured.
<加工時間の比較試験>
第1実施形態の装置、アクリルツールを用い、加工時間のみ変えて線状研磨加工の違いを確認する実験を行った結果について説明する。
<Comparative test of processing time>
The results of an experiment conducted using the apparatus and acrylic tool of the first embodiment to confirm the difference in linear polishing processing by changing only the processing time will be described.
(加工条件)
加工条件を表3に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 3. The tip of the tool was hemispherical with a diameter of 10 mm.
(結果)
結果を図8、図9に示す。図8は走査型白色干渉計(Zygo社製の白色干渉計NewView 700s)による計測結果を示している。また、図9は加工時間と加工深さの関係を示すグラフである。本実験の結果から、加工時間の増加に伴い加工深さが増加することがわかる。
(result)
The results are shown in Figures 8 and 9. Figure 8 shows the measurement results using a scanning white light interferometer (Zygo's NewView 700s white light interferometer). Figure 9 is a graph showing the relationship between processing time and processing depth. From the results of this experiment, it can be seen that the processing depth increases as the processing time increases.
<加工荷重の比較試験>
第1実施形態の装置、アクリルツールを用い、加工荷重のみ変えて線状研磨加工(ここでは回転をさせず、振動装置による往復運動のみとした)の違いを確認する実験を行った結果について説明する。
<Comparative test of processing load>
The results of an experiment conducted using the device and acrylic tool of the first embodiment to confirm the difference in linear polishing (in this case, no rotation was used, only reciprocating motion by the vibration device) by changing only the processing load will be described.
(加工条件)
加工条件を表4に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 4. The tip of the tool was hemispherical with a diameter of 10 mm.
(結果)
結果を図10、図11に示す。図10は走査型白色干渉計(Zygo社製の白色干渉計NewView 700s)による計測結果を示している。また、図11は加工荷重と加工深さの関係を示すグラフである。本実験の結果から、加工荷重を増加させても加工深さは大きな変化がない。物理的摩擦力は荷重に比例するが、本実験の結果は摩擦力が増加しても加工深さにほとんど影響を及ぼさないことから、本発明が化学的な加工であることを示している。
(result)
The results are shown in Figures 10 and 11. Figure 10 shows the results of measurements made using a scanning white light interferometer (Zygo's NewView 700s white light interferometer). Figure 11 is a graph showing the relationship between the processing load and the processing depth. The results of this experiment show that there is no significant change in the processing depth even when the processing load is increased. Although physical frictional force is proportional to the load, the results of this experiment show that an increase in frictional force has almost no effect on the processing depth, indicating that the present invention is a chemical processing method.
<加工液の温度の比較試験>
第1実施形態の装置、アクリルツールを用い、加工液(純水)の温度のみ変えて線状研磨加工の違いを確認する実験を行った結果について説明する。
<Comparative test of machining fluid temperature>
The results of an experiment conducted using the apparatus and acrylic tool of the first embodiment to confirm the difference in linear polishing processing while changing only the temperature of the processing liquid (pure water) will be described.
(加工条件)
加工条件を表5に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 5. The tip of the tool was hemispherical with a diameter of 10 mm.
(結果)
結果を図12に示す。図12は走査型白色干渉計(Zygo社製の白色干渉計NewView 700s)による計測結果を示している。本実験の結果から、40度の加工条件下では、23度の場合に比べて、加工痕がより大きく、より深くなることがわかる。
(result)
The results are shown in Figure 12. Figure 12 shows the measurement results using a scanning white light interferometer (Zygo's NewView 700s white light interferometer). The results of this experiment show that under the machining conditions of 40 degrees, the machining marks are larger and deeper than those under the condition of 23 degrees.
<加工液の水の有無による比較試験>
純水は水素イオンおよび水酸化物イオンからなる遊離イオンを含んでいる。純水そのものの影響を調べるため、比較対象の加工液として、遊離イオンを含まず、熱伝達能力を有し、不活性で熱的、化学的に安定しているフロリナートを選択し、比較実験を行った。具体的には、第1実施形態の装置、アクリルツールを用い、加工液(純水/フロリナート)のみ変えて線状研磨加工の違いを確認する実験を行った結果について説明する。
<Comparative test with and without water in machining fluid>
Pure water contains free ions consisting of hydrogen ions and hydroxide ions. In order to investigate the influence of pure water itself, Fluorinert, which does not contain free ions, has heat transfer ability, is inactive, and is thermally and chemically stable, was selected as the machining fluid for comparison, and a comparative experiment was performed. Specifically, the results of an experiment to confirm the difference in linear polishing processing by changing only the machining fluid (pure water/Fluorinert) using the device and acrylic tool of the first embodiment will be described.
(加工条件)
加工条件を表6に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 6. The tip of the tool was hemispherical with a diameter of 10 mm.
(結果)
結果を図13に示す。図13は走査型白色干渉計(Zygo社製の白色干渉計NewView 700s)による計測結果を示している。本実験の結果から、純水中の合成石英は加工可能であり、フロリナート中では、加工痕ができなかった。この結果から、水の遊離イオンが加工に作用していることが推測される。
(result)
The results are shown in Figure 13. Figure 13 shows the results of measurements made using a scanning white light interferometer (Zygo's NewView 700s white light interferometer). The results of this experiment show that the synthetic quartz can be machined in pure water, and no machining marks were left in Fluorinert. From these results, it is inferred that the free ions in the water are affecting the machining process.
<加工液を酸性に設定する場合のpHの比較試験1>
第1実施形態の装置、アクリルツールを用い、酸性の加工液のpHのみ変えて線状研磨加工の違いを確認する実験を行った結果について説明する。酸性の加工液は、pHを調整したスルファミン酸水溶液を用いた。
<pH Comparison Test 1 when Machining Fluid is Set to Acidic>
The results of an experiment conducted to confirm the difference in linear polishing by changing only the pH of the acidic machining liquid using the apparatus and acrylic tool of the first embodiment will be described. The acidic machining liquid used was a sulfamic acid solution with an adjusted pH.
(加工条件)
加工条件を表7に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 7. The tip of the tool was a hemisphere with a diameter of 10 mm.
(結果)
結果を図14、図15、図16、図17に示す。図14は走査型白色干渉計(Zygo社製の白色干渉計NewView 700s)による計測結果を示しており、図15は、pHと加工深さの関係を示すグラフである。また、図16は合成石英をアクリルツールで酸性加工液中で加工した後の工作物の表面粗さを示し、図17は、酸性加工液のpHと加工面の表面粗さの関係を示す。
(result)
The results are shown in Figures 14, 15, 16, and 17. Figure 14 shows the results of measurements using a scanning white light interferometer (Zygo's NewView 700s white light interferometer), and Figure 15 is a graph showing the relationship between pH and machining depth. Figure 16 shows the surface roughness of a workpiece after machining synthetic quartz in an acid machining fluid with an acrylic tool, and Figure 17 shows the relationship between the pH of the acid machining fluid and the surface roughness of the machined surface.
図14、図15から、pHが低くなるにつれて、加工深さは浅くなることがわかる。これは、水酸化物イオンの濃度が減少したことによると考えられる。また、図16、図17から、pHが低くなるにつれて、表面粗さは徐々に良好になっていることがわかる。この結果は、pHが低いと加工深さが浅いため、表面粗さが良好であった可能性がある。したがって、次に、加工深さが同じ場合でも、良好な表面粗さとなるかどうか確認する比較実験を行った。 Figures 14 and 15 show that as the pH decreases, the machining depth becomes shallower. This is believed to be due to a decrease in the concentration of hydroxide ions. Figures 16 and 17 also show that as the pH decreases, the surface roughness gradually improves. This result suggests that the surface roughness may be good because the machining depth is shallow when the pH is low. Therefore, next, a comparative experiment was conducted to confirm whether good surface roughness could be achieved even when the machining depth is the same.
<加工液を酸性に設定する場合のpHの比較試験2>
第1実施形態の装置、アクリルツール、加工液としてpH2.7のスルファミン酸水溶液とpH5.6の純水を用い、同じ加工深さとなるように異なる時間で線状研磨加工して、表面粗さの違いを確認する実験を行った。
<pH Comparison Test 2 when Machining Fluid is Set to Acidic>
An experiment was conducted using the apparatus of the first embodiment, an acrylic tool, and a sulfamic acid solution of pH 2.7 and pure water of pH 5.6 as machining liquids, performing line polishing for different times to achieve the same machining depth, and confirming the difference in surface roughness.
(加工条件)
加工条件を表8に示す。ツールの先端は、直径10mmの半球状とした。スルファミン酸水溶液での加工を5時間まで、純水での加工を1時間で行った。
(Processing conditions)
The machining conditions are shown in Table 8. The tip of the tool was a hemisphere with a diameter of 10 mm. Machining was performed in the sulfamic acid aqueous solution for up to 5 hours, and in pure water for 1 hour.
(結果)
加工後の表面粗さの結果を図18、図19に示す。pH2.7のスルファミン酸水溶液での加工の表面粗さは、同じ6nmの加工深さの加工で、pH5.6の純水での加工の表面粗さに比べて良好であった。これにより、同じ加工深さでpHが低いほど表面粗さが良好になることが確認できた。
(result)
The results of the surface roughness after processing are shown in Figures 18 and 19. The surface roughness of the surface processed with the sulfamic acid aqueous solution at pH 2.7 was better than that of the surface roughness of the surface processed with pure water at pH 5.6 at the same processing depth of 6 nm. This confirmed that the lower the pH, the better the surface roughness at the same processing depth.
<加工液を酸性に設定する場合のpHの比較試験3>
次に、同じpHの異なる種類の酸性加工液中で、同じ加工深さと表面粗さを得るかどうか確認する比較試験を行った。第1実施形態の装置、アクリルツール、加工液としてpH2.2のスルファミン酸と酢酸を用い、線状研磨加工の違いを確認する実験を行った結果について説明する。
<pH Comparison Test 3 when Machining Fluid is Set to Acidic>
Next, a comparative test was conducted to confirm whether the same machining depth and surface roughness could be obtained in different types of acidic machining fluids with the same pH. The results of the experiment to confirm the difference in linear polishing processing were described below using the device of the first embodiment, an acrylic tool, and sulfamic acid and acetic acid with pH 2.2 as machining fluids.
(加工条件)
加工条件を表9に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 9. The tip of the tool was hemispherical with a diameter of 10 mm.
加工結果を図20,図21,図22に示す。図20から分かるように、同じpHの異なる種類の酸性液体中で3時間加工され得られた加工痕の幅および深さは実質的に同じであることがわかる。また、図21は、スルファミン酸水溶液での加工前後の表面粗さを示す。図22は、酢酸水溶液での加工前後の表面粗さを示す。 The results of processing are shown in Figures 20, 21, and 22. As can be seen from Figure 20, the width and depth of the processing marks obtained when processing for 3 hours in different types of acid liquids with the same pH are essentially the same. Also, Figure 21 shows the surface roughness before and after processing in an aqueous sulfamic acid solution. Figure 22 shows the surface roughness before and after processing in an aqueous acetic acid solution.
結論として、アクリルによる合成石英の加工のためには、より低いpHを有する酸性液体中で良好な表面粗さを得ることが可能であり、そして酸の種類とは関係ないことがわかる。 In conclusion, it can be seen that for processing synthetic quartz with acrylic, it is possible to obtain good surface roughness in acidic liquids with lower pH and regardless of the type of acid.
<加工液をアルカリ性に設定する場合のpHの比較試験>
第1実施形態の装置、アクリルツールを用い、アルカリ性の加工液としてpH10の炭酸ナトリウム水溶液、水酸化カルシウム水溶液を用い、線状研磨加工の違いを確認する実験を行った結果について説明する。
<Comparative test of pH when machining fluid is set to alkaline>
The results of an experiment conducted to confirm the difference in linear polishing using the apparatus and acrylic tool of the first embodiment and an alkaline machining liquid of sodium carbonate solution and calcium hydroxide solution, each having a pH of 10, will be described.
(加工条件)
加工条件を表10に示す。ツールの先端は、直径10mmの半球状とした。
(Processing conditions)
The processing conditions are shown in Table 10. The tip of the tool was hemispherical with a diameter of 10 mm.
(結果)
結果を図23、図24に示す。図23(a),図23(b)各図の左側は、各ツールによる線状加工痕の走査型白色干渉計(Zygo社製の白色干渉計NewView 700s)による計測結果、右側は深さプロファイルを示している。炭酸ナトリウム水溶液中で加工した結果は、加工痕が深くなく、約8nmであった。水酸化カルシウム水溶液中で加工した結果は、加工痕が70nm以上の深さに達することがわかる。水酸化カルシウムによって合成石英を腐食できるため、加工速度が速くなった可能性がある。
(result)
The results are shown in Figures 23 and 24. The left side of Figures 23(a) and 23(b) shows the measurement results of the linear machining marks made by each tool using a scanning white light interferometer (Zygo's NewView 700s white light interferometer), and the right side shows the depth profile. The result of machining in a sodium carbonate aqueous solution was that the machining marks were not deep, at about 8 nm. It can be seen that the result of machining in a calcium hydroxide aqueous solution was that the machining marks reached a depth of 70 nm or more. It is possible that the machining speed was increased because calcium hydroxide can corrode synthetic quartz.
図24は表面粗さの加工結果を示す。炭酸ナトリウム水溶液で加工した後の表面粗さは、RMS0.275nmで、PV 5.7nmに低下した。水酸化カルシウム加工液で加工した後の表面粗さは非常に悪い。その理由は、水酸化カルシウムはガラスに腐食作用を及ぼすため、深い腐食ピットを引き起こす可能性がある。また強塩基はアクリルに腐食作用を及ぼし、それがアクリルを工作物の表面に付着させる可能性がある。 Figure 24 shows the results of surface roughness processing. After processing with sodium carbonate aqueous solution, the surface roughness was reduced to RMS 0.275 nm and PV 5.7 nm. After processing with calcium hydroxide processing solution, the surface roughness is very poor. The reason is that calcium hydroxide has a corrosive effect on glass, which may cause deep corrosion pits. Also, strong bases have a corrosive effect on acrylic, which may cause the acrylic to adhere to the surface of the workpiece.
<平坦加工試験>
次に、アクリル定盤を備えた第2実施形態の装置を用い、アクリル定盤と純水のみによるガラス基板の平坦化加工を行った結果について説明する。
<Flatness test>
Next, the results of flattening a glass substrate using the apparatus of the second embodiment equipped with an acrylic surface plate and only pure water will be described.
(加工条件)
加工条件を表11に示す。回転速度の「(上)」側は、基板側の回転装置の回転速度であり、「(下)」側は、アクリル定盤側の回転速度である。また、基板表面の計測には、走査型白色干渉計(Zygo, NewView 700S)を用いた。
(Processing conditions)
The processing conditions are shown in Table 11. The "(upper)" side of the rotation speed is the rotation speed of the rotation device on the substrate side, and the "(lower)" side is the rotation speed on the acrylic surface plate side. A scanning white light interferometer (Zygo, NewView 700S) was used to measure the substrate surface.
(結果)
結果を図25(a)~図25(c)に示す。図25(a)は加工前、図25(b)は60時間の加工結果、図25(c)は120時間の加工結果であり、各図の左側は表面粗さ、右側は深さプロファイルを示している。これらの加工結果から、砥粒を含まない純水のみの加工液で、アクリル定盤を用いたガラス基板の大面積平坦化加工が可能であることがわかる。
(result)
The results are shown in Figures 25(a) to 25(c). Figure 25(a) shows the state before processing, Figure 25(b) shows the result after 60 hours of processing, and Figure 25(c) shows the result after 120 hours of processing, with the left side of each figure showing the surface roughness and the right side showing the depth profile. These processing results show that large-area planarization of glass substrates is possible using an acrylic surface plate with a processing fluid consisting only of pure water that does not contain abrasive grains.
1A、1B ガラス研磨加工装置
2 加工ツール
20 棒材
21 冶具
3 加工液供給手段
30 容器
4 加圧手段
40 リニアブッシュ
41 皿
42 加圧シリンダ
5 相対動作手段
51 回転モータ
52 振動装置
53 回転台
54 回転装置
540 保持プレート
8 加工液
9 ワーク
Reference Signs List 1A, 1B Glass polishing device 2 Processing tool 20 Bar 21 Jig 3 Processing liquid supply means 30 Container 4 Pressurizing means 40 Linear bush 41 Plate 42 Pressurizing cylinder 5 Relative movement means 51 Rotation motor 52 Vibration device 53 Rotation table 54 Rotation device 540 Holding plate 8 Processing liquid 9 Workpiece
Claims (4)
ガラス製のワークと前記アクリル製のツールとの間に、純水またはpHを調整した水溶液であって砥粒を含有しない加工液を供給する加工液供給手段と、
前記ワークと前記ツールを、互いに加圧接触させる加圧手段と、
前記加圧手段による加圧接触状態で、前記ワークと前記ツールを相対運動させて研磨加工を行う相対動作手段と、
を備えるガラス研磨加工装置。 An acrylic tool having an abrasive grain-free surface on which acrylic is positioned ;
A machining fluid supplying means for supplying a machining fluid, which is pure water or an aqueous solution with an adjusted pH and does not contain abrasive grains, between the glass workpiece and the acrylic tool;
A pressurizing means for pressing the workpiece and the tool into contact with each other;
a relative movement means for performing polishing by moving the workpiece and the tool relative to each other while the workpiece and the tool are in a pressurized contact state by the pressurizing means;
A glass polishing apparatus comprising:
前記相対動作手段が、前記アクリル定盤を回転する回転手段を備え、
回転するアクリル定盤の表面に対し、前記ガラス製のワークを加圧接触させて平坦に研磨加工する、請求項1記載のガラス研磨加工装置。 the tool is an acrylic platen;
The relative movement means includes a rotation means for rotating the acrylic base plate,
2. The glass polishing apparatus according to claim 1 , wherein the glass workpiece is polished flat by being brought into pressure contact with the surface of a rotating acrylic platen.
前記ワークを回転させながら、前記アクリル定盤の表面に対して加圧接触させて平坦に研磨加工する、請求項2記載のガラス研磨加工装置。 The relative movement means includes a second rotation means for rotating the workpiece around an axis parallel to the rotation axis of the acrylic surface plate,
3. The glass polishing apparatus according to claim 2 , wherein the workpiece is polished flat by being pressed against the surface of the acrylic platen while being rotated.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020034375A JP7620798B2 (en) | 2020-02-28 | 2020-02-28 | Glass polishing equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020034375A JP7620798B2 (en) | 2020-02-28 | 2020-02-28 | Glass polishing equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2021133491A JP2021133491A (en) | 2021-09-13 |
| JP7620798B2 true JP7620798B2 (en) | 2025-01-24 |
Family
ID=77659743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020034375A Active JP7620798B2 (en) | 2020-02-28 | 2020-02-28 | Glass polishing equipment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP7620798B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2024043555A (en) * | 2022-09-19 | 2024-04-01 | 株式会社ディスコ | Polishing device and polishing method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003011066A (en) | 2000-07-25 | 2003-01-15 | Ebara Corp | Polishing tool and manufacturing method thereof |
| JP2003260658A (en) | 2003-01-31 | 2003-09-16 | Rodel Nitta Co | Polishing pad |
| JP2005007520A (en) | 2003-06-19 | 2005-01-13 | Nihon Micro Coating Co Ltd | Abrasive pad, manufacturing method thereof, and grinding method thereof |
| JP2019025575A (en) | 2017-07-28 | 2019-02-21 | 不二越機械工業株式会社 | Work polishing device and work polishing method |
-
2020
- 2020-02-28 JP JP2020034375A patent/JP7620798B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003011066A (en) | 2000-07-25 | 2003-01-15 | Ebara Corp | Polishing tool and manufacturing method thereof |
| JP2003260658A (en) | 2003-01-31 | 2003-09-16 | Rodel Nitta Co | Polishing pad |
| JP2005007520A (en) | 2003-06-19 | 2005-01-13 | Nihon Micro Coating Co Ltd | Abrasive pad, manufacturing method thereof, and grinding method thereof |
| JP2019025575A (en) | 2017-07-28 | 2019-02-21 | 不二越機械工業株式会社 | Work polishing device and work polishing method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2021133491A (en) | 2021-09-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI569315B (en) | Method for manufacturing synthetic quartz glass substrate for semiconductor | |
| JP5123329B2 (en) | Semiconductor substrate planarization processing apparatus and planarization processing method | |
| KR101704811B1 (en) | Method of processing synthetic quartz glass substrate for semiconductor | |
| JP6291026B2 (en) | How to polish the surface of sapphire | |
| US20100285723A1 (en) | Polishing apparatus | |
| KR20130045188A (en) | Electronic grade glass substrate and making method | |
| KR20160022260A (en) | Rectangular substrate for imprint lithography and making method | |
| JP6375166B2 (en) | Double-sided buff module for post-CMP cleaning | |
| JP2010199581A (en) | Lithographic apparatus, method for removing material of one or more protrusions on support surface, and article support system | |
| TW201209002A (en) | Synthetic quartz glass substrate and making method | |
| Zhou et al. | Function of liquid and tool wear in ultrasonic bound-abrasive polishing of fused silica with different polishing tools | |
| US20210053177A1 (en) | System, device and method for reconditioning a substrate support | |
| JP7620798B2 (en) | Glass polishing equipment | |
| JP2011224758A (en) | Polishing method | |
| TW544365B (en) | Process for reducing surface variations for polished wafer | |
| US20200381262A1 (en) | Atmospheric plasma in wafer processing system optimization | |
| JP2010074119A (en) | Evaluating method of chemical mechanical polish property of chemical mechanical polish equipment, intra-surface-uniformity evaluating method of material surface, and property evaluating method of slurry chemical | |
| JP6757011B2 (en) | Catalyst reference device | |
| JP7118417B2 (en) | Light irradiation catalyst standard etching system | |
| JPH07161669A (en) | Compound semiconductor polishing fluid and compound semiconductor polishing method using this fluid | |
| JPH1034525A (en) | Polishing equipment for CMP | |
| JP7426898B2 (en) | Cleaning body, cleaning device and cleaning method | |
| Dumas et al. | Ultra-low roughness magneto-rheological finishing for EUV mask substrates | |
| JP7464216B2 (en) | Processing method using organic fine particles | |
| JP2023531205A (en) | Semiconductor substrate polishing with polishing pad temperature control |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A80 | Written request to apply exceptions to lack of novelty of invention |
Free format text: JAPANESE INTERMEDIATE CODE: A80 Effective date: 20200319 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20230216 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20231211 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20240123 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20240702 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20240829 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20241203 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20241210 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7620798 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |