JP7649464B2 - Vapor-deposited resin film, laminate comprising said vapor-deposited resin film, and packaging container comprising said laminate - Google Patents

Description

The present invention relates to a vapor-deposited resin film, a laminate comprising the vapor-deposited resin film, and a packaging container comprising the laminate.

Conventionally, films made of resin materials (resin films) have been used as the substrates (hereinafter referred to as substrates for packaging materials) constituting the laminates used in the manufacture of packaging containers such as packaging bags. For example, polyester films are widely used as such films because they are inexpensive and have excellent mechanical properties, chemical stability, heat resistance, and transparency.

The fossil fuel polyesters used in the manufacture of polyester film are copolymers of dicarboxylic acids and diols, which are produced from the fossil fuel petroleum.
In recent years, with the aim of reducing the environmental burden, such as by reducing carbon dioxide emissions, packaging containers have been produced using polyester obtained by mechanically recycling polyester contained in used packaging containers (hereinafter referred to as mechanically recycled polyester) instead of fossil fuel polyester (see Patent Document 1).

However, the degree of contamination of packaging containers varies depending on the contents filled in them and the storage environment. Consumers may be concerned about hygiene when using packaging containers made from mechanically recycled polyester. For this reason, the use of chemically recycled polyester is being considered from the perspective of hygiene. Chemically recycled polyester is obtained by breaking down the polyester contained in used packaging containers down to the monomer level, removing contaminants, and then polymerizing it again, making it more hygienic.

JP 2017-007175 A

The laminate used to manufacture the above-mentioned packaging container comprises at least a base material made of a polyester film and a sealant layer, and is stored in a rolled-up state. The inventors have found a new problem that if the polyester film used as the base material contains low molecular weight polymers, the low molecular weight polymers may migrate to the sealant layer side during storage of the rolled laminate, and may be mixed into the contents filled in the packaging container, compromising the hygiene of the contents.

The present invention has been made to solve the above problems. The problem that the present invention aims to solve is to provide a vapor-deposited resin film that can reduce the environmental load and enable the production of packaging containers that are extremely hygienic.
Another problem to be solved by the present invention is to provide a laminate comprising the vapor-deposited resin film.
Another problem to be solved by the present invention is to provide a packaging container including the laminate.

The vapor-deposited resin film of the present invention comprises a polyester film and a vapor-deposited film,
The polyester film contains a chemically recycled polyester and at least one selected from the group consisting of a mechanically recycled polyester, a fossil fuel polyester, and a biomass polyester,
The polyester film is characterized in that the area ratio of the region having a molecular weight of 1,000 or less in a molecular weight distribution curve obtained by GPC measurement of the polyester film is 1.8% or less of the total peak area.

In the vapor-deposited resin film of the present invention, the melting point of the polyester film may be 250°C or less.

In the vapor-deposited resin film of the present invention, the crystallization temperature of the polyester film may be 196°C or lower.

In the vapor-deposited resin film of the present invention, the static friction coefficient of the surface of the polyester film on which the vapor-deposited film is not formed may be 0.35 or more.

In the vapor-deposited resin film of the present invention, the polyester content in the polyester film may be 90% by mass or more and 100% by mass or less.

In the vapor-deposited resin film of the present invention, the chemically recycled polyester, the mechanically recycled polyester, the fossil fuel polyester, and the biomass polyester may be polyethylene terephthalate.

The laminate of the present invention comprises the above-mentioned vapor-deposited resin film and
and a sealant layer or an adhesive layer provided on the inner side of the vapor-deposited resin film.

The laminate of the present invention comprises a base layer, a vapor-deposited film, an intermediate layer, and a sealant layer or an adhesive layer,
The substrate layer and the vapor-deposited film may be composed of the vapor-deposited resin film.

The laminate of the present invention comprises a base layer, a vapor-deposited film, an intermediate layer, and a sealant layer or an adhesive layer,
the intermediate layer comprises a support layer;
The support layer and the vapor-deposited film may be composed of the vapor-deposited resin film.

The packaging container of the present invention is characterized by comprising the above laminate.

According to the present invention, it is possible to provide a vapor-deposited resin film that can reduce the environmental load and enable the production of packaging containers that are extremely hygienic.
According to the present invention, a laminate including the vapor-deposited resin film can be provided.
According to the present invention, a packaging container including the laminate can be provided.

FIG. 1 is a schematic cross-sectional view showing one embodiment of a vapor-deposited resin film 10 of the present invention. FIG. 1 is a schematic cross-sectional view showing one embodiment of a laminate 20 of the present invention. FIG. 1 is a schematic cross-sectional view showing one embodiment of a laminate 20 of the present invention. FIG. 1 is a schematic cross-sectional view showing one embodiment of a laminate 20 of the present invention. FIG. 2 is a perspective view showing one embodiment of a standing pouch 30 produced using the laminate 20 of the present invention. 1 is a front view showing one embodiment of a pillow bag 40 manufactured using a laminate 20 of the present invention. FIG. 1 is a front view showing one embodiment of a three-sided sealed bag 50 manufactured using a laminate 20 of the present invention. FIG. 1 is a front view showing one embodiment of a four-sided sealed bag 60 produced using the laminate 20 of the present invention. FIG. 2 is a schematic cross-sectional view showing one embodiment of a lid material 70 produced using the laminate 20 of the present invention. 1 is a partial cross-sectional view showing one embodiment of a laminate tube 80 produced using the laminate 20 of the present invention. 1 is a perspective view showing one embodiment of a paper container 90 manufactured using the laminate 20 of the present invention. 1 is a perspective view showing one embodiment of a paper cup 100 manufactured using the laminate 20 of the present invention. 13 is a schematic diagram for explaining a method of manufacturing the paper cup 100 shown in FIG. 12. FIG. 2 is a diagram showing a molecular weight distribution curve in the region of molecular weight of 1,000 or less obtained in the examples.

One embodiment of the present invention will be described with reference to Figures 1 to 14. Note that in the drawings attached to this specification, the scale and aspect ratios have been appropriately altered and exaggerated from those of the actual product for the sake of ease of illustration and understanding.

In addition, terms used in this specification that specify shapes, geometric conditions, and the degree of those conditions, such as "parallel," "orthogonal," and "same," as well as values of lengths and angles, are to be interpreted without being bound by strict meanings, but rather to include the range in which similar functions can be expected.

In this specification, "inside" refers to the side of the package that contains the contents when the package is manufactured, and "outside" refers to the side opposite the inside.

(Deposition Resin Film 10)
As shown in FIG. 1, a vapor-deposited resin film 10 of the present invention comprises a polyester film 11 and a vapor-deposited film 12 .
In one embodiment, the vapor-deposited resin film 10 may have a gas barrier coating film (not shown) adjacent to the vapor-deposited film 12 on the side opposite to the polyester film 11 side.

(Polyester film 11)
The polyester film 11 contains a chemically recycled polyester and at least one selected from the group consisting of a mechanically recycled polyester, a fossil fuel polyester, and a biomass polyester. This improves the environmental load reduction of the vapor-deposited resin film 10 and the laminate 20 including the vapor-deposited resin film 10, and also makes it possible to provide gas barrier properties equivalent to those of conventional fossil fuel polyester films. The polyester film 11 is preferably a single layer.
In this specification, the term "polyester" refers to a material obtained by a polycondensation reaction between a diol compound and a dicarboxylic acid compound.
Examples of the dicarboxylic acid compound include malonic acid, succinic acid, glutaric acid, adipic acid, suberic acid, sebacic acid, dodecanedioic acid, eicosanedioic acid, pimelic acid, azelaic acid, methylmalonic acid, ethylmalonic acid, adamantanedicarboxylic acid, norbornenedicarboxylic acid, cyclohexanedicarboxylic acid, decalindicarboxylic acid, terephthalic acid, isophthalic acid, phthalic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 1,8-naphthalenedicarboxylic acid, 4,4'-diphenyldicarboxylic acid, 4,4'-diphenyletherdicarboxylic acid, 5-sodiumsulfoisophthalic acid, phenylendanedicarboxylic acid, anthracenedicarboxylic acid, phenanthrenedicarboxylic acid, 9,9'-bis(4-carboxyphenyl)fluorene acid, and ester derivatives thereof.
Examples of the diol compound include ethylene glycol, 1,2-propanediol, 1,3-propanediol, butanediol, 2-methyl-1,3-propanediol, hexanediol, neopentyl glycol, cyclohexanedimethanol, cyclohexanediethanol, decahydronaphthalenedimethanol, decahydronaphthalenediethanol, norbornanedimethanol, norbornanediethanol, tricyclodecanedimethanol, tricyclodecaneethanol, tetracyclododecanedimethanol, tetracyclododecanediethanol, decalindimethanol, decalindiethanol, Examples of the copolymer include 5-methylol-5-ethyl-2-(1,1-dimethyl-2-hydroxyethyl)-1,3-dioxane, cyclohexanediol, bicyclohexyl-4,4'-diol, 2,2-bis(4-hydroxycyclohexylpropane), 2,2-bis(4-(2-hydroxyethoxy)cyclohexyl)propane, cyclopentanediol, 3-methyl-1,2-cyclopentadiol, 4-cyclopentene-1,3-diol, adamantanediol, paraxylene glycol, bisphenol A, bisphenol S, styrene glycol, trimethylolpropane, and pentaerythritol.
Furthermore, the polyester may contain a monomer other than the dicarboxylic acid compound and the diol compound, so long as the characteristics of the present invention are not impaired.

In addition, in this specification, "chemically recycled polyester" refers to a product obtained by collecting used polyester (for example, at least one polyester selected from the group consisting of fossil fuel polyester, biomass polyester, chemically recycled polyester, and mechanically recycled polyester) containers, etc., crushing, washing, separating foreign matter, etc., and then forming them into flakes or pellets, which are then depolymerized using, for example, ethylene glycol to decompose them into bis-β-hydroxyethyl terephthalate (BHET), and polyester is polymerized again using the BHET as a raw material. Note that the decomposition method, etc. are not limited to the above.
In addition, in this specification, "mechanically recycled polyester" refers to polyester that has been recycled by collecting used polyester (e.g., at least one polyester selected from the group consisting of fossil fuel polyester, biomass polyester, chemically recycled polyester, and mechanically recycled polyester) containers, etc., and then crushing, washing, separating foreign matter, etc., and regenerating the polyester into flakes or pellets.
"Fossil fuel polyester" is one in which a diol derived from a fossil fuel is used as a diol unit and a dicarboxylic acid derived from a fossil fuel is used as a dicarboxylic acid unit.
The term "biomass polyester" refers to a polyester that contains ethylene glycol derived from biomass as a diol unit and a dicarboxylic acid derived from a fossil fuel as a dicarboxylic acid unit, or that contains ethylene glycol derived from biomass and a diol derived from a fossil fuel as diol units and a dicarboxylic acid derived from a fossil fuel as a dicarboxylic acid unit.
Carbon dioxide in the atmosphere contains a certain percentage of C14 (105.5 pMC), so it is known that the C14 content in plants that grow by absorbing carbon dioxide from the atmosphere, such as corn, is also about 105.5 pMC. It is also known that fossil fuels contain almost no C14. Therefore, the percentage of carbon derived from biomass can be calculated by measuring the percentage of C14 in the total carbon atoms in polyester. Taking polyethylene terephthalate as an example, polyethylene terephthalate is a polymer of ethylene glycol containing 2 carbon atoms and terephthalic acid containing 8 carbon atoms in a molar ratio of 1:1. Therefore, if only biomass-derived ethylene glycol is used, the weight ratio of biomass-derived components in polyester is 31.25%, so the theoretical value of the biomass degree is 31.25%.

The content of the chemically recycled polyester in the polyester film 11 is not particularly limited as long as it satisfies the area ratio of the region of molecular weight of 1,000 or less in the molecular weight distribution curve obtained by GPC measurement of the polyester film 11 described later, but is preferably 20% by mass or more and 99% by mass or less, more preferably 30% by mass or more and 95% by mass or less, and even more preferably 50% by mass or more and 90% by mass or less.
The polyester film 11 may contain two or more types of chemically recycled polyester.

The sum of the contents of mechanically recycled polyester, fossil fuel polyester, and biomass polyester in polyester film 11 is not particularly limited as long as it satisfies the area ratio of the region with a molecular weight of 1,000 or less in the molecular weight distribution curve obtained from the GPC measurement of polyester film 11 described below, but is preferably 1% by mass or more and 80% by mass or less, more preferably 5% by mass or more and 70% by mass or less, and even more preferably 10% by mass or more and 50% by mass or less.

It is preferable that the polyester film 11 contains polyester in an amount of 90% by mass or more and 100% by mass or less, and more preferably 95% by mass or more and 100% by mass or less.

The chemically recycled polyester and at least one polyester selected from the group consisting of mechanically recycled polyester, fossil fuel polyester, and biomass polyester contained in the polyester film 11 is preferably polyethylene terephthalate. This improves the transparency of the polyester film 11 and makes it easy to collect used containers.

As long as the characteristics of the present invention are not impaired, the polyester film 11 may contain resin materials other than polyester, such as (meth)acrylic resins, polyolefins, vinyl resins, cellulose resins, and ionomer resins.

In the polyester film 11, the content of resin materials other than polyester is preferably 10% by mass or less, more preferably 5% by mass or less, more preferably 1% by mass or less, and particularly preferably none.

The polyester film 11 may contain additives, provided that the properties of the present invention are not impaired. Examples of additives include oxygen absorbers, plasticizers, UV stabilizers, antioxidants, color inhibitors, matting agents, deodorants, flame retardants, weather resistance agents, antistatic agents, friction reducers, slip agents, release agents, antioxidants, ion exchange agents, antiblocking agents, and colorants.

The polyester film 11 is characterized in that the area ratio of the region having a molecular weight of 1,000 or less in a molecular weight distribution curve obtained by measurement of GPC (gel permeation chromatography) is 1.8% or less of the total peak area. Since such polyester film 11 has a reduced content of components having a molecular weight of 1,000 or less (hereinafter also referred to as low molecular weight components), it is possible to suppress the inclusion of low molecular weight components in the contents filled in the packaging container, and to improve the hygiene of the packaging container manufactured using the vapor-deposited resin film of the present invention.
The area ratio of the region having a molecular weight of 1,000 or less is more preferably 1.5% or less, and even more preferably 1.35% or less, of the total peak area.
From the viewpoint of hygiene, it is preferable that the area ratio of the region having a molecular weight of 1,000 or less is smaller relative to the total peak area, but the area ratio of the region having a molecular weight of 1,000 or less may be, for example, 0.01% or more of the total peak area.

The GPC measurement of the polyester film 11 is performed in accordance with JIS K 7252-1:2008.
Specifically, 10 g of the polyester film 11 is cut out and weighed in a 30 mL vial, and a HFIP/chloroform mixture is added to the vial, and the mixture is allowed to stand for 12 hours to dissolve.
After standing, chloroform is added to dilute the solution to prepare a 0.1% solution.
This solution is filtered using a 0.45 μm hydrophilic PTFE membrane filter cartridge (Millex-LH manufactured by Merck Millipore), and the obtained filtrate is subjected to GPC measurement under the following conditions.
(Measurement conditions)
Columns used: Agilent Technologies, 2 PLgel 5μ MIXED (7.5 mm x 300 mm)
Column temperature: 40°C
Mobile phase: Chloroform (Fujifilm Wako Pure Chemical Industries, Ltd., for liquid chromatography)
・Flow rate: 1.0mL/min
Injection volume: 2.5 μL
Detection: 254 nm (UV-Vis detector)
Molecular weight calibration: monodisperse polystyrene (Agilent Technologies, PS-1)
Equipment: 515 HPLC pump, 717plus automatic injection device, UV-visible detector (Waters)

The melting point of the polyester film 11 is preferably 250°C or less, and more preferably 248.5°C or less. This allows the polyester film 11 to be produced at a high speed, i.e., improves film production properties.

The melting point of the polyester film 11 is preferably 230°C or higher, and more preferably 240°C or higher. This improves the heat resistance of the polyester film 11.

The crystallization temperature of the polyester film 11 is preferably 196° C. or lower, and more preferably 195° C. or lower, so that the stretching stability of the polyester film 11 can be improved, that is, the film formability can be improved.
The crystallization temperature of the polyester film 11 is preferably 185° C. or higher, and more preferably 190° C. or higher, so that the heat resistance of the polyester film 11 can be improved.

In this specification, the "melting point" and "crystallization temperature" are measured by differential scanning calorimetry (DSC) in accordance with JIS K 7121:2012 as follows.
First, (1) a polyester film sample (5 mg) is heated from 20°C to 300°C at a rate of 10°C/min. (2) The sample is then held at 300°C for 5 minutes. (3) The sample is then cooled from 300°C to 20°C at a rate of -10°C/min. (4) The sample is then held at 20°C for 5 minutes. (5) The sample is again heated from 20°C to 300°C at a rate of 10°C/min. This gives a melting curve.
The main peak in the temperature-lowering stage of this melting curve was taken as the crystallization temperature, and the main peak in the second temperature-up stage was taken as the melting point.

The static friction coefficient of the surface of the polyester film 11 on which the vapor-deposited film is not formed is preferably 0.35 or more, and more preferably 0.40 or more, which can suppress excessive slippage on the surface of the packaging container produced using the vapor-deposited resin film of the present invention and improve the stacking stability when stacked.
The static friction coefficient of the surface of the polyester film 11 on which the vapor-deposited film is not formed is preferably 0.60 or less, and more preferably 0.50 or less, which stabilizes the running performance in a packaging machine and improves the high-speed filling and packaging performance.
The static friction coefficient of the polyester film 11 can be measured in accordance with JIS K 7125:1999 as follows.

First, the deposited resin film 10 is cut to prepare a test piece of 200 mm×150 mm.
Next, the test piece is fixed to the sliding table of the tester with cellophane tape so that the polyester film 11 faces upward.
Next, the evaporated resin film 10 is cut into a size of 70 mm x 100 mm to prepare a test piece.
Next, the test piece is wrapped around a metal thread (weight: 200 g) of 63 mm×63 mm×6.3 mm, with the vapor-deposited film on the inside and the polyester film 11 on the outside.
Next, the polyester films 11 are placed on the fixed vapor-deposited resin film 10 so that the polyester films 11 are in contact with each other.
Next, in an environment of 23° C. and a relative humidity of 50%, the metal thread around which the test piece is wound is slid at a speed of 100 mm/min, and the friction is measured using a friction measuring device.

In the vapor-deposited resin film 10 according to the present invention, the content of the cyclic trimer in the polyester film 11 is preferably 0.510% by mass or more and 1.030% by mass or less, more preferably 0.600% by mass or more and 1.010% by mass or less, and even more preferably 0.650% by mass or more and 1.000% by mass or less. By setting the content of the cyclic trimer within this range, it is possible to suitably produce a polyester film 11 having the above-mentioned melting point and crystallization temperature, and a vapor-deposited resin film having the above-mentioned static friction coefficient.

The content of the cyclic trimer in the polyester film 11 can be measured by the following method.
Approximately 0.1 g of a sample is taken from the polyester film 11 and dissolved in a mixture of hexafluoroisopropanol (HFIP) and chloroform. Acetonitrile is added to this solution to precipitate the polymer, and the precipitate is then filtered. The filtrate is evaporated to dryness, and the resulting residue is dissolved in dimethylformamide (DMF). This solution is analyzed by high performance liquid chromatography (HPLC) to measure the content of cyclic trimers. The measurement conditions are as follows:
(Measurement conditions)
Equipment: Shimadzu Corporation, LC-20
Column used: Develosil ODS-HG-3 3μ (4.6×150 mm), manufactured by Nomura Chemical Co., Ltd.
Column temperature: 40°C
Mobile phase: 0.5% by volume aqueous acetic acid/acetonitrile (gradient)
・Flow rate: 1.0mL/min
Injection volume: 15 μL
Detection: 254 nm (UV-Vis detector)
Equipment: Shimadzu Corporation, LC-20

The polyester film 11 may be a stretched film or an unstretched film. From the viewpoints of heat resistance, strength, and transparency, it is preferable that the polyester film 11 is a stretched film. The stretched film may be a uniaxially stretched film or a biaxially stretched film. From the viewpoint of dimensional stability, it is preferable that the stretched film is a biaxially stretched film.

The polyester film 11 may be surface-treated. This can improve adhesion to adjacent layers. The surface treatment method is not particularly limited, and examples include corona treatment, ozone treatment, and frame treatment.

The thickness of the polyester film 11 is preferably 3 μm or more and 25 μm or less, more preferably 6 μm or more and 25 μm or less, even more preferably 7 μm or more and 16 μm or less, and even more preferably 9 μm or more and 16 μm or less. This improves the suitability of the polyester film 11 for forming a vapor deposition film, as well as its heat resistance and strength.

(Method for producing polyester film 11)
The polyester film 11, in which the area ratio of the region of molecular weight of 1,000 or less in the molecular weight distribution curve obtained by GPC measurement is 1.8% or less of the total peak area, can be produced by appropriately selecting the types of monomers and oligomers as raw materials and/or appropriately adjusting the contents of the monomers and oligomers as raw materials. In addition, since the low molecular weight component plays a role as a wax, the friction of the polyester film 11 can be adjusted by adjusting the content of the low molecular weight component.
In one embodiment, the crystallization temperature and melting point of the polyester film 11 can be adjusted by using, for example, a compound containing isophthalic acid as the dicarboxylic acid compound.
The method for producing the film is not particularly limited, and the film can be produced by utilizing a conventionally known method, for example, a T-die method.

(Deposition film 12)
The vapor-deposited resin film 10 of the present invention has a vapor-deposited film 12 on at least one surface of a polyester film 11 .
The vapor-deposited film 12 may be provided on the inside or outside of the polyester film 11 .
By providing the vapor-deposited resin film 10 of the present invention with the vapor-deposited film 12, the gas barrier properties, specifically the oxygen barrier properties and water vapor barrier properties, can be improved.

The deposited film 12 can be a deposited film of one or more inorganic substances or inorganic oxides, such as silicon (Si), aluminum (Al), magnesium (Mg), calcium (Ca), potassium (K), tin (Sn), sodium (Na), boron (B), titanium (Ti), lead (Pb), zirconium (Zr), and yttrium (Y). The deposited film 12 can also be configured with two or more layers, which may be made of the same material or different materials.

The thickness of the deposition film 12 is preferably 10 nm or more and 200 nm or less, and more preferably 20 nm or more and 100 nm or less.

The method for forming the vapor deposition film 12 is not particularly limited, and examples of the method include physical vapor deposition methods (PVD methods) such as vacuum deposition, sputtering, and ion plating, or chemical vapor deposition methods (CVD methods) such as plasma chemical vapor deposition, thermal chemical vapor deposition, and photochemical vapor deposition.

(Gas barrier coating film)
The vapor-deposited resin film 10 of the present invention may be provided with a gas barrier coating film adjacent to one side of the vapor-deposited film 12. The gas barrier coating film functions as a layer that suppresses the transmission of oxygen gas, water vapor, etc. This effect is particularly pronounced when the vapor-deposited film 12 is a transparent vapor-deposited film made of a metal oxide such as silicon oxide.

The gas barrier coating film is obtained from a gas barrier composition which contains at least one alkoxide represented by the general formula R ¹ _n M(OR ² ) _m (wherein R ¹ and R ² represent an organic group having 1 to 8 carbon atoms, M represents a metal atom, n represents an integer of 0 or more, m represents an integer of 1 or more, and n+m represents the atomic valence of M) and the above-mentioned polyvinyl alcohol resin and/or ethylene-vinyl alcohol copolymer, and which is further polycondensed by a sol-gel process in the presence of a sol-gel process catalyst, an acid, water, and an organic solvent.

As the alkoxide represented by the general formula R ¹ _n M(OR ² ) _m , at least one of a partial hydrolyzate of an alkoxide and a condensate of hydrolysis of an alkoxide can be used. In addition, as the partial hydrolyzate of an alkoxide, it is not necessary that all of the alkoxy groups are hydrolyzed, and one in which one or more are hydrolyzed, or a mixture thereof may be used. As the condensate of hydrolysis of an alkoxide, a dimer or higher of a partially hydrolyzed alkoxide, specifically a dimer to hexamer, is used.

In the alkoxide represented by the general formula R ¹ _n M(OR ² ) _m , silicon, zirconium, titanium, aluminum, and the like can be used as the metal atom represented by M. In this embodiment, preferred metals include, for example, silicon and titanium. In the present invention, the alkoxide can be used alone or in the form of a mixture of two or more different metal atoms in the same solution.

In the alkoxide represented by the above general formula R ¹ _n M(OR ² ) _m , specific examples of the organic group represented by R ¹ include alkyl groups such as methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, sec-butyl, t-butyl, n-hexyl, n-octyl, etc. In the alkoxide represented by the above general formula R ¹ _n M(OR ² ) _m , specific examples of the organic group represented by R ² include methyl, ethyl, n-propyl, i-propyl, n-butyl, sec-butyl, etc. These alkyl groups may be the same or different in the same molecule.

When preparing the gas barrier composition, for example, a silane coupling agent or the like may be added. As the silane coupling agent, a known organoalkoxysilane containing an organic reactive group can be used. In this embodiment, in particular, an organoalkoxysilane having an epoxy group is preferably used, and specifically, for example, γ-glycidoxypropyltrimethoxysilane, γ-glycidoxypropylmethyldiethoxysilane, or β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane can be used. The above-mentioned silane coupling agents may be used alone or in a mixture of two or more kinds.

(Laminate 20)
As shown in Fig. 2, the laminate 20 of the present invention comprises the above-mentioned vapor-deposited resin film 10 and a sealant layer 21 located on the inner side of the vapor-deposited resin film 10. The sealant layer 21 may constitute the innermost layer of the laminate 20. The vapor-deposited resin film 10 may constitute the outermost layer of the laminate 20. The laminate 20 may comprise a polyester film 11 as the outermost layer (Fig. 2), or a vapor-deposited film 12 as the outermost layer (not shown). When the vapor-deposited resin film 10 comprises a gas barrier coating film, the gas barrier coating film may constitute the outermost layer of the laminate 20 (not shown).
3 , the laminate 20 of the present invention may include a first sealant layer 22 on the inner side of the vapor-deposited resin film 10, and a second sealant layer 23 on the outer side of the vapor-deposited resin film 10. The first sealant layer 22 may constitute the innermost layer or the outermost layer of the laminate 20. The second sealant layer 23 may constitute the innermost layer or the outermost layer of the laminate 20.
4, the laminate 20 of the present invention includes a base layer 24, a vapor-deposited film 12, an intermediate layer 25, and a sealant layer 21. The sealant layer 21 may constitute the innermost layer of the laminate 20, and the base layer may constitute the outermost layer. The laminate 20 may include an adhesive layer between the vapor-deposited film 12 and the intermediate layer 25.
In one embodiment, the intermediate layer 25 may comprise a support, a gas barrier layer, or a metal foil (not shown).
In one embodiment, the laminate 20 of the present invention may include a printed layer (not shown) on any of the layers, such as the polyester film 11, the vapor-deposited film 12, the base layer 24, and the support layer.
The laminate 20 of the present invention may have one or more adhesive layers, such as an adhesive layer, an adhesive resin layer or an anchor coat layer, between any of the layers (not shown).
The laminate 20 of the present invention may have any layer (not shown) between the vapor-deposited resin film 10 and the sealant layer 21 and on the outside of the vapor-deposited resin film 10 .
In the laminate of the present invention and the packaging container including the laminate of the present invention, the number of layers does not need to include the printed layer, the vapor deposition film, the gas barrier coating film, the adhesive layer, the adhesive resin layer, and the anchor coat layer. That is, Fig. 2 may be a schematic cross-sectional view showing a laminate 20 having a two-layer structure, and Figs. 3 and 4 may be schematic cross-sectional views showing a laminate 20 having a three-layer structure.
Each layer of the laminate of the present invention will be described below. However, since the evaporated resin film 10 has been described above, a description thereof will be omitted here.

(Sealant layer 21)
The sealant layer 21 includes a resin material that exhibits heat fusion properties, such as low density polyethylene (LDPE: density 0.910 to 0.925), medium density polyethylene (MDPE: 0.926 to 0.940), high density polyethylene (HDPE: density 0.941 or higher), linear low density polyethylene (LLDPE: density 0.910 to 0.925), ethylene-α-olefin copolymer, polypropylene (homopolymer, block polymer, random polymer), ethylene-vinyl acetate copolymer (EVA), ethylene-acrylic acid copolymer (EAA), ethylene-ethyl acrylate copolymer (EEA), ethylene-methacrylic acid copolymer, etc. Examples of the resin material include copolymers (EMAA), ethylene-methyl methacrylate copolymers (EMMA), ionomer resins, heat-sealable ethylene-vinyl alcohol resins, or copolymerized resins, polyolefin resins such as methylpentene resins, ethylene-propylene copolymers, methylpentene polymers, polybutene polymers, polyethylene, polypropylene, and cyclic olefin copolymers, acid-modified polyolefin resins obtained by modifying polyolefin resins with unsaturated carboxylic acids such as acrylic acid, methacrylic acid, maleic acid, maleic anhydride, fumaric acid, and itaconic acid, vinyl resins, and (meth)acrylic resins. The sealant layer 21 may contain two or more of the above resin materials.
Examples of the sealant layer 21 include a heat seal layer and a hot melt layer using a hot melt adhesive containing the above-mentioned resin material.

When polyethylene is used for the sealant layer 21, biomass polyethylene may be used as the polyethylene. This can further reduce the environmental impact in the production of the laminate 20 of the present invention.
Here, biomass polyethylene is produced using biomass ethanol as a raw material. The method for producing biomass polyethylene is not particularly limited, and it can be obtained by a conventionally known method. Biomass polyethylene can be produced using biomass ethanol as a raw material, and it is particularly preferable to use fermented ethanol derived from biomass obtained from a plant raw material. The plant raw material is not particularly limited, and conventionally known plants can be used. Examples include corn, sugar cane, beet, and manioc.

The sealant layer 21 may contain additives as long as they do not impair the properties of the present invention. Examples of additives include oxygen absorbers, plasticizers, UV stabilizers, antioxidants, color inhibitors, matting agents, deodorants, flame retardants, weather resistance agents, antistatic agents, friction reducers, slip agents, release agents, antioxidants, ion exchange agents, antiblocking agents, and colorants.

The thickness of the sealant layer 21 is preferably adjusted appropriately depending on the application of the laminate 20, and can be, for example, 7 μm or more and 50 μm or less.
The sealant layer 21 may be a single layer or a multilayer.

The laminate 20 of the present invention may have a sealant layer 21 on the inner surface of the vapor-deposited resin film 10, or may have sealant layers (a first sealant layer 22 and a second sealant layer 23) on both the inner and outer surfaces of the vapor-deposited resin film 10.
By providing the sealant layer 21 on both sides of the evaporated resin film, it becomes possible to produce packaging containers such as laminated tubes, labels, and paper containers.
The composition and thickness of the first sealant layer 22 and the second sealant layer 23 may be the same or different.

The sealant layer 21 can be formed by melt-extruding the above-mentioned resin material onto the vapor-deposited resin film 10 and then cooling it. An anchor coat layer may be formed on the vapor-deposited resin film 10, and the above-mentioned resin material may be melt-extruded onto the anchor coat layer.
The sealant layer 21 can be formed by laminating a film made of the above-mentioned resin material onto the vapor-deposited resin film 10 via an adhesive layer by using a dry lamination method.
The sealant layer 21 can be formed by laminating a film made of the above-mentioned resin material onto the vapor-deposited resin film 10 via an adhesive resin layer by utilizing a melt extrusion lamination method.
The sealant layer 21 can be formed on the vapor-deposited resin film 10 using a hot melt adhesive or a pressure sensitive adhesive.

The sealant layer 21 can be formed by melt-extruding the resin material onto the base material layer 24 or the support layer, and then cooling the same. Alternatively, an anchor coat layer may be formed on the base material layer 24 or the support layer, and the resin material may be melt-extruded onto the anchor coat layer.
The sealant layer 21 can be formed by laminating a film made of the above-mentioned resin material to the base layer 24 or support layer via an adhesive layer or anchor coat layer using a dry lamination method.
The sealant layer 21 can be formed by laminating a film made of the above-mentioned resin material to the base material layer 24 or the support layer via an adhesive resin layer by utilizing a melt extrusion lamination method.
The sealant layer 21 can be formed on the vapor-deposited resin film 10 using a hot melt adhesive or a pressure sensitive adhesive.

The laminate of the present invention may include an adhesive layer instead of the sealant layer 21. The adhesive layer contains an adhesive. Examples of the adhesive contained in the adhesive layer include natural rubber, synthetic rubber such as styrene-butadiene rubber, acrylonitrile-butadiene rubber, and polyisobutylene rubber, acrylic resin, silicone resin, and polypropylene.
The adhesive layer may contain two or more types of the adhesives.

(Base material layer 24)
The base layer 24 serves to hold each layer, and is preferably capable of imparting strength as a packaging container to the laminate 20. As the base layer 24, a resin film (which may be a stretched film or an unstretched film) containing at least one or two or more resin materials such as polyester (chemically recycled polyester, mechanically recycled polyester, fossil fuel polyester, biomass polyester), (meth)acrylic resin, polyolefin such as polyethylene, polypropylene, and polymethylpentene, vinyl resin, cellulose resin, ionomer resin, and polyamide such as nylon 6, nylon 6,6, and polymetaxylylene adipamide (MXD6) can be used. The resin film is preferably a stretched film. The stretched film may be a uniaxially stretched film or a biaxially stretched film. From the viewpoint of dimensional stability, a biaxially stretched film is preferable. A laminated film of the above-mentioned materials may be used as the base layer 24.

In one embodiment, the base layer 24 is a resin film containing polyester.
In one embodiment, the base layer 24 is a resin film containing polyester as a main constituent, and the polyester content is preferably 90% by mass or more, and more preferably 95% by mass or more.
The base material layer 24 preferably contains recycled polyester as the polyester, which can further reduce the environmental impact of the packaging container formed of the laminate 20 of the present invention.
The above-mentioned polyester film 11 may be used as the base layer 24. This can further reduce the environmental load and effectively prevent migration of low molecular weight polymers to the sealant layer 21, thereby further improving the hygiene of the packaging container produced from the laminate 20 of the present invention.

The laminate 20 of the present invention may have the above-mentioned vapor deposition film 12 on one side of the base layer 24, and may further have a gas barrier coating film on the vapor deposition film 12. The base layer 24 and the vapor deposition film 12 may be composed of the above-mentioned vapor deposition resin film 10.

A paper base material may be used as the base material layer 24. This makes it possible to manufacture packaging containers such as paper containers and paper cups.

As the paper base material, fine paper, art paper, coated paper, resin-coated paper, cast-coated paper, paperboard, synthetic paper, impregnated paper, etc. can be appropriately selected and used depending on the application.

The thickness of the paper base material is preferably changed appropriately depending on the application, but can be, for example, from 30 g/m ² to 400 g/m ² .

As long as the characteristics of the present invention are not impaired, the base layer 24 may contain additives, such as oxygen absorbers, plasticizers, ultraviolet stabilizers, antioxidants, coloring inhibitors, matting agents, deodorants, flame retardants, weather resistance agents, antistatic agents, friction reducers, slip agents, mold release agents, antioxidants, ion exchange agents, antiblocking agents, and colorants.
The thickness of the support layer is not particularly limited, and is preferably changed appropriately depending on the application of the laminate 20 .

The laminate 20 of the present invention may have a printed layer on one side of the base layer 24.

The substrate layer 24 can be laminated via an adhesive layer.

(Printing layer)
The laminate 20 of the present invention includes a printed layer on any layer, for example, the polyester film 11, the vapor-deposited film 12, the base layer 24, the support layer, or the like.

The image formed as the print layer is not particularly limited, and may represent characters, patterns, symbols, combinations thereof, or the like.
The printed layer may be formed on a part of the surface of any layer or on the entire surface of the layer, and the printed layer may be formed on a plurality of layers.

The printing layer can be formed by appropriately selecting and using a conventionally known ink. In consideration of the environmental load, ink made from raw materials derived from biomass may be used.
As the ink containing a raw material derived from biomass, commercially available inks can be used, for example, LP Bio Series manufactured by Toyo Ink Co., Ltd. and Finart BM Series manufactured by DIC Graphics Corporation.

The method for forming the printing layer is not particularly limited, and examples include conventionally known printing methods such as gravure printing, offset printing, and flexographic printing.

(Adhesive Layer)
The adhesive layer is a layer provided between any layers of the laminate 20 of the present invention. The adhesive layer can be formed by applying a conventionally known adhesive (laminating adhesive) and drying it.

The laminating adhesive may be a one-component curing type or a two-component curing type. The laminating adhesive may be any of a solvent-based, water-based, and emulsion-based adhesive.
Examples of adhesives for lamination include vinyl-based adhesives, (meth)acrylic-based adhesives, polyamide-based adhesives, polyester-based adhesives, polyether-based adhesives, polyurethane-based adhesives, epoxy-based adhesives, and rubber-based adhesives.

The coating method is not particularly limited, and examples include direct gravure roll coating, gravure roll coating, kiss coating, reverse roll coating, Fontaine method, and transfer roll coating.

The thickness of the adhesive layer is preferably 0.1 μm or more and 10 μm or less, and more preferably 1 μm or more and 5 μm or less.

(Adhesive resin layer)
The adhesive resin layer is a layer provided between any layers of the laminate 20 of the present invention. The adhesive resin layer is a layer formed by melt extrusion lamination using a thermoplastic resin. Examples of the thermoplastic resin include low density polyethylene, medium density polyethylene, high density polyethylene, linear low density polyethylene, ethylene-acrylic acid copolymer, ethylene-ethyl acrylate copolymer, ethylene-methacrylic acid copolymer, ethylene-methyl methacrylate copolymer, ethylene-maleic acid copolymer, ionomer resin, resin obtained by graft polymerizing or copolymerizing an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride, or an ester monomer with a polyolefin resin, and resin obtained by graft-modifying maleic anhydride with a polyolefin resin. The adhesive resin layer may contain two or more types of thermoplastic resin.

In one embodiment, the thickness of the adhesive resin layer is preferably 0.1 μm or more and 10 μm or less, and more preferably 1 μm or more and 5 μm or less.
In one embodiment, the thickness of the adhesive resin layer is preferably 5 μm or more and 100 μm or less, and more preferably 10 μm or more and 50 μm or less.

(Anchor coat layer)
The anchor coat layer is a layer provided between any layers of the laminate 20 of the present invention. The anchor coat layer can be formed by applying a conventionally known anchor coat agent and drying it.

The anchor coating agent may be any resin with a heat resistance of 135°C or higher, such as a vinyl modified resin, an epoxy resin, a urethane resin, or a polyester resin. In particular, an anchor coating agent made of a polyacrylic or polymethacrylic resin having two or more hydroxyl groups in the structure and an isocyanate compound as a curing agent is preferably used. A silane coupling agent may be added as an additive to the anchor coating agent. Nitrocellulose may be added to the anchor coating agent to increase heat resistance.

The thickness of the anchor coat layer is preferably 0.1 μm or more and 2 μm or less, and more preferably 0.2 μm or more and 1 μm or less.

(Intermediate layer 25)
The laminate 20 of the present invention may include an intermediate layer 25 between the base layer 24 and the sealant layer 21. The intermediate layer 25 is a layer including a support layer intended to improve the strength, etc., of the laminate 20, a gas barrier layer intended to improve the gas barrier properties of the laminate 20, and a metal foil, etc. It is preferable that the intermediate layer 25 includes a support layer.

(Support Layer)
The support layer is a layer provided for the purpose of improving the strength and stiffness of the laminate 20 .
As the support layer, for example, a resin film (which may be a stretched film or an unstretched film) containing one or more resin materials such as polyester (chemically recycled polyester, mechanically recycled polyester, fossil fuel polyester, biomass polyester), (meth)acrylic resin, polyolefin such as polyethylene, polypropylene, and polymethylpentene, vinyl resin, cellulose resin, ionomer resin, and polyamide such as nylon 6, nylon 6,6, and polymetaxylylene adipamide (MXD6) can be used. The resin film is preferably a stretched film. The stretched film may be a uniaxially stretched film or a biaxially stretched film. From the viewpoint of dimensional stability, a biaxially stretched film is preferable. A laminated film of the above-mentioned material may be used as the support layer.
The support layer may be made of the above-mentioned paper base material.

In one embodiment, the support layer is a resin film comprising polyester.
In one embodiment, the support layer is a resin film containing polyester as a main component, and the content of polyester is preferably 90% by mass or more, and more preferably 95% by mass or more.
The support layer preferably contains recycled polyester as the polyester, which can further reduce the environmental impact of the packaging container formed of the laminate 20 of the present invention.
The above-mentioned polyester film 11 may be used as the support layer. This can further reduce the environmental load and effectively prevent migration of low molecular weight polymers to the sealant layer 21, thereby further improving the hygiene of the packaging container manufactured from the laminate 20 of the present invention.

The laminate 20 of the present invention may have the above-mentioned vapor deposition film 12 on one side of the support layer, and may further have a gas barrier coating film on the vapor deposition film 12. The support layer and the vapor deposition film 12 may be composed of the above-mentioned vapor deposition resin film 10.

The support layer may contain additives, as long as they do not impair the properties of the present invention. Examples of the additives include oxygen absorbers, plasticizers, ultraviolet stabilizers, antioxidants, coloring inhibitors, matting agents, deodorants, flame retardants, weather resistance agents, antistatic agents, friction reducers, slip agents, mold release agents, antioxidants, ion exchange agents, antiblocking agents, and colorants.
The thickness of the support layer is not particularly limited, and is preferably changed appropriately depending on the application of the laminate 20 .

The laminate 20 of the present invention may have a printing layer on one side of the support layer.

The support layer can be laminated via an adhesive layer.

(Gas Barrier Layer)
In one embodiment, the gas barrier layer contains a gas barrier resin. Examples of the gas barrier resin include ethylene-vinyl alcohol copolymer (EVOH), polyvinyl alcohol, polyacrylonitrile, polyamides such as nylon 6, nylon 6,6, and polymetaxylylene adipamide (MXD6), polyesters, polyurethanes, and (meth)acrylic resins. The gas barrier layer may contain two or more types of gas barrier resins.
The gas barrier layer may contain a resin other than the gas barrier resin, and may contain the above-mentioned additives.
The thickness of the gas barrier layer made of the gas barrier resin is preferably 3 μm to 30 μm, more preferably 5 μm to 20 μm. By making the thickness of the gas barrier layer 7 μm or more, the oxygen barrier property and water vapor barrier property of the laminate 20 of the present invention can be further improved.
The gas barrier layer can be formed by laminating a film made of the above-mentioned gas barrier resin via an adhesive layer.

(Metal foil)
The laminate 20 of the present invention may include a metal foil, which can further improve the oxygen barrier property and water vapor barrier property.
The metal constituting the metal foil is not particularly limited, and metal foils made of aluminum, magnesium, etc. can be used.
The thickness of the metal foil is preferably 3 μm or more and 100 μm or less, and more preferably 6 μm or more and 25 μm or less. By making the thickness of the metal foil 3 μm or more, the oxygen barrier property and water vapor barrier property of the laminate 20 of the present invention can be further improved.
The metal foil can be laminated via an adhesive layer.

(Example of layer structure)
An example of the layer structure of the laminate is shown below. In the following example, the left side means the outside, and the right side means the inside. In the following example, the symbol "/" means the boundary between layers. In the following example, "sub" means the base layer, "ad" means the adhesive resin layer, "Ad" means the adhesive layer, "AC" means the anchor coat layer, "A" means the vapor deposition film, "H" means the heat seal layer, "A" means the adhesive layer, "H" means the hot melt layer, "C" means the gas barrier coating film, "S" means the support layer, and "S" means the print layer. In the following example, "CR-PEs" means the polyester film 11, "PET" means polyethylene terephthalate, "ONY" means oriented nylon, "OPP" means oriented polypropylene, "CPP" means unoriented polypropylene, "PE" means polyethylene, "PEF" means polyethylene film, "Al" means aluminum, "MO" means metal oxide, and "MOR" means metal alkoxide.

The two-layer laminate may have, for example, the following structure.
(1) (CR-PEs)/(MO)/(MOR)/Ad/(PEF)
(2) Base (CR-PEs) / Steam (MO) / Coating (MOR) / Heat (PE)
(3) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / AC / Hi (PE)
(4) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / AC / Contacted (PE) / Hi (PEF)
(5) Group (CR-PEs) / Steam (Al) / Adhesive (Adhesive)
(6) Group (CR-PEs)/vaporization (Al)/AC/hi (PE)
(7) Group (CR-PEs) / Steamed (MO / Painted (MOR) / Marked / Ad / Hi (PEF)
(8) Base (CR-PEs) / Steam (MO) / Coating (MOR) / Printing (PE)
(9) Group (CR-PEs) / Steamed (MO / Painted (MOR) / Marked / AC / Hi (PE)
(10) Group (CR-PEs) / Steamed (MO / Painted (MOR) / Marked / AC / Contacted (PE) / Hi (PEF)
(11) Mark / Base (CR-PEs) / Steam (Al) / Adhesive (Adhesive)
(12) Mark/Group (CR-PEs)/Steamed (Al)/Hi (PE)
(13) Mark/Group (CR-PEs)/Steamed (Al)/AC/Hi (PE)

Examples of the laminate having three or more layers include the following structure: In the following structure, the base layer is a polyester film 11 .
(1) Group (CR-PEs) / MO / MOR / Ad / ONY / Ad / PEF
(2) Group (CR-PEs) / Steamed (MO) / Coated (MOR) / Ad / Coated (MOR) / Steamed (MO) / Support (PET) / Ad / Hi (CPP)
(3) Base (CR-PEs) / Steamed (MO) / Coated (MOR) / Ad / Steamed (Al) / Support (PET) / Ad / Hi (CPP)
(4) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / Ad / Support (ONY) / Ad / Hi (CPP)
(5) H(PEF)/Ad/MOR/MO/CR-PEs/Ad/H(PEF)
(6) Base (CR-PEs) / Steam (MO) / Coating (MOR) / Ad / Support (PET) / Ad / H (PEF) / H (hot melt adhesive)
(7) Base (CR-PEs) / Steam (MO) / Coating (MOR) / Ad / Support (ONY) / Hi (PE)
(8) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / Ad / Supported (ONY) / AC / Hi (PE)
(9) PEG (PEF)/Ad/substrate (CR-PEs)/MO/coating (MOR)/Ad/PEG (PEF)
(10) Group (CR-PEs) / MO / MOR / Ink / Ad / ONY / Ad / PEF
(11) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / Marked / Ad / Painted (MOR) / Steamed (MO) / Supported (PET) / Ad / Hi (CPP)
(12) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / Seal / Ad / Steamed (Al) / Support (PET) / Ad / Hi (CPP)
(13) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / Seal / Ad / Support (ONY) / Ad / Hi (CPP)
(14) Base (CR-PEs) / Steam (MO) / Coating (MOR) / Printing / Ad / Support (PET) / Ad / H (PEF) / H (hot melt adhesive)
(15) H(PEF)/Ad/MOR/MO/Cr(CR-PEs)/Ad/H(PEF)
(16) Group (CR-PEs) / Steam (MO) / Coating (MOR) / Ink / Ad / Support (ONY) / Hi (PE)
(17) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / Seal / Ad / Support (ONY) / AC / Hi (PE)
(18) PEG (PEF)/Ad/substrate (CR-PEs)/MO/coating (MOR)/printing/Ad/PEG (PEF)

Examples of the laminate having three or more layers include the following structure: In the following structure, the support layer of the intermediate layer is a polyester film 11.
(1) Group (PET) / Ad / Evaporation (Al) / Support (CR-PEs) / Ad / Hi (PEF)
(2) Base (ONY) / AC / Contact (PE) / Evaporation (Al) / Support (CR-PEs) / AC / Contact (PE) / Hi (PEF)
(3) Base (paper) / Ad / Coating (MOR) / Steaming (MO) / Support (CR-PEs) / Ad / Hi (CPP)
(4) Base (OPP) / Ad / Painted (MOR) / Steamed (MO) / Supported (CR-PEs) / Ad / Hi (CPP)
(5) Base (PET) / MO / MOR / Ad / MOR / MO / MOR / CR-PEs / Ad / PEF
(6) Base (ONY) / Ad / Painted (MOR) / Steamed (MO) / Supported (CR-PEs) / Ad / Hi (CPP)
(7) Base (PET) / Ad / Coating (MOR) / Steam (MO) / Support (CR-PEs) / Ad / H (PEF) / H (hot melt adhesive)
(8) OPP/Ad/MOR/MO/CR-PEs/Ad/PEF
(9) Base (PET) / Ad / Painted (MOR) / Steamed (MO) / Supported (CR-PEs) / Ad / Hi (CPP)
(10) Base (paper) / Bonding (PE) / Coating (MOR) / Steaming (MO) / Support (CR-PEs) / Heat (PE)
(11) Base (paper) / Contact (PE) / Coating (MOR) / Steaming (MO) / Support (CR-PEs) / AC / Hi (PE)
(12) Base (OPP) / Ad / Coating (MOR) / Steam (MO) / Support (CR-PEs) / Ad / H (OPP)
(13) Base (PET) / Ad / Steam (Al) / Support (CR-PEs) / Hi (PE)
(14) Base (PET) / Ad / Steam (Al) / Support (CR-PEs) / AC / Hi (PE)
(15) Base (PET) / Ad / Coating (MOR) / Steaming (MO) / Support (CR-PEs) / Hi (PE)
(16) Base (PET) / Ad / Painted (MOR) / Steamed (MO) / Supported (CR-PEs) / AC / Hi (PE)
(17) (CR-PEs)/(MO)/(MOR)/Ad/(PEF)
(18) PEG (PEF)/Ad/substrate (PET)/Ad/coating (MOR)/steam (MO)/support (CR-PEs)/Ad/PEG (PEF)
(19) Ar(PEF)/Ad/substrate(PET)/Ad/aluminum(Al)/substrate(CR-PEs)/Ad/Ar(PEF)
(20) Al (PEF)/Ad/base (PET)/Ad/support (PEF)/Ad/support (CR-PEs)/Al (Al)/Ad/Al (PEF)
(21) PEG (PEF)/Ad/substrate (PET)/Ad/support (PEF)/Ad/support (CR-PEs)/molybdenum (MO)/coating (MOR)/Ad/PEG (PEF)
(22) Al(PEF)/Ad/Al(PET)/Ad/Al(PEF)/Ad/Al(Al)/Al(CR-PEs)/Ad/Al(PEF)
(23) PEG (PEF)/Ad/substrate (PET)/Ad/support (PEF)/Ad/coated (MOR)/coated (MO)/support (CR-PEs)/Ad/PEG (PEF)
(24) Aluminum (PE) / Base (paper) / Bond (PE) / Steam (Al) / Support (CR-PEs) / Aluminum (PE)
(25) PE/Base (Paper)/Bond (PE)/Coating (MOR)/Steaming (MO)/Support (CR-PEs)/PE
(26) Aluminum (PE) / Base (paper) / Bond (PE) / Steam (Al) / Support (CR-PEs) / AC / Aluminum (PE)
(27) PE/Base (Paper)/Bond (PE)/Coating (MOR)/Steam (MO)/Support (CR-PEs)/AC/PE
(28) Group (PET) / Mark / Ad / Evaporated (Al) / Group (CR-PEs) / Ad / Hi (PEF)
(29) Base (ONY) / Mark / AC / Contact (PE) / Steam (Al) / Support (CR-PEs) / AC / Contact (PE) / Hi (PEF)
(30) Seal / Base (Paper) / Ad / Coated (MOR) / Steamed (MO) / Support (CR-PEs) / Ad / Hi (CPP)
(31) Group (OPP) / Seal / Ad / Painted (MOR) / Steamed (MO) / Supported (CR-PEs) / Ad / Hi (CPP)
(32) Base (PET) / Steam (MO) / Coating (MOR) / Printing / Ad / Coating (MOR) / Steam (MO) / Support (CR-PEs) / Ad / H (PEF)
(33) Base (ONY) / Seal / Ad / Painted (MOR) / Steamed (MO) / Supported (CR-PEs) / Ad / Hi (CPP)
(34) Base (PET) / Mark / Ad / Coating (MOR) / Steam (MO) / Support (CR-PEs) / Ad / Hi (PE) / Ho (Hot melt adhesive)
(35) OPP/Indium/Ad/MOR/MO/CR-PEs/Ad/H (PEF)
(36) Base (PET) / Seal / Ad / Coated (MOR) / Steamed (MO) / Support (CR-PEs) / Ad / Hi (CPP)
(37) Printing/Base (Paper)/Bonding (PE)/Coating (MOR)/Steaming (MO)/Support (CR-PEs)/H (PE)
(38) Seal / Base (Paper) / Contact (PE) / Coating (MOR) / Steaming (MO) / Support (CR-PEs) / AC / Hi (PE)
(39) Base (OPP) / Indium / Ad / Coating (MOR) / Steam (MO) / Support (CR-PEs) / Ad / Hydrogen (OPP)
(40) Base (PET) / Mark / Ad / Steam (Al) / Support (CR-PEs) / Hi (PE)
(41) Base (PET) / Mark / Ad / Steam (Al) / Support (CR-PEs) / AC / Hi (PE)
(42) Base (PET) / Seal / Ad / Coating (MOR) / Steaming (MO) / Support (CR-PEs) / Hi (PE)
(43) Base (PET) / Mark / Ad / Coating (MOR) / Steaming (MO) / Support (CR-PEs) / AC / Hi (PE)
(44) Group (CR-PEs) / Steamed (MO) / Painted (MOR) / Marked / Ad / Hi (PEF)
(45) PEG (PEF)/Ad/substrate (PET)/implant/Ad/coating (MOR)/steam (MO)/support (CR-PEs)/Ad/PEG (PEF)
(46) Al(PEF)/Ad/Al(PET)/Al/Al(Cr-PEs)/Ad/Al(PEF)
(47) Al(PEF)/Ad/Al(PET)/Al/Ad/Al(PEF)/Ad/Al(CR-PEs)/Al(Al)/Ad/Al(PEF)
(48) PEG (PEF)/Ad/substrate (PET)/Indium/Ad/support (PEF)/Ad/support (CR-PEs)/Modified (MO)/Modified (MOR)/Ad/PEG (PEF)
(49) Al(PEF)/Ad/Al(PET)/Al/Al(PEF)/Al/Al(CR-PEs)/Ad/Al(PEF)
(50) PEG (PEF)/Ad/base (PET)/implant/Ad/support (PEF)/Ad/coating (MOR)/steam (MO)/support (CR-PEs)/Ad/PEG (PEF)
(51) Al (PE) / Print / Base (paper) / Bond (PE) / Steam (Al) / Support (CR-PEs) / Ad / Al (PEF)
(52) PE/printing/base (paper)/bonding (PE)/coating (MOR)/steaming (MO)/support (CR-PEs)/Ad/PEF
(53) H(PE)/Insulation/Base(Paper)/Adhesive(PE)/Steam(Al)/Support(CR-PEs)/AC/H(PE)
(54) H (PE) / mark / base (paper) / bond (PE) / coating (MOR) / steam (MO) / support (CR-PEs) / AC / H (PE)

In the laminate having three or more layers, both the base layer and the intermediate support layer may be polyester film 11.

(Packaging container)
According to the laminate 20 of the present invention, it is possible to produce a packaging container that reduces the environmental load and has high hygienic properties.
Examples of packaging containers include packaging bags (pouches), lids, laminated tubes, paper containers, paper cups, and label materials.
The contents filled in the packaging container are not particularly limited, and may be liquid, powder, or gel. In addition, the contents may be food or non-food.

(Pouch)
Examples of packaging bags include standing pouches, pillow bags (palm-sealed bags), two-sided sealed bags, three-sided sealed bags, four-sided sealed bags, side sealed bags, envelope-sealed bags, pleated sealed bags, flat-bottom sealed bags, square-bottom sealed bags, and gusseted bags.

Fig. 5 is a diagram showing a simplified example of the configuration of the standing pouch 30. As shown in Fig. 5, the standing pouch 30 includes a body portion 31 and a bottom portion 32. The hatched portions indicate the heat-sealed portions (the same applies to the subsequent figures).
The body 31 of the standing pouch 30 is composed of the laminate 20. The bottom 32 of the standing pouch 30 may be composed of the laminate 20 or may be composed of a different material.

In one embodiment, the laminate 20 constituting the body 31 of the standing pouch 30 includes, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, a stretched resin film (support layer), an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the body 31 of the standing pouch 30 includes, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
The above-mentioned vapor deposition film 12 may be a colored vapor deposition film made of aluminum or the like, or a transparent vapor deposition film made of a metal oxide such as silicon oxide. When it is a transparent vapor deposition film, it is preferable to provide a gas barrier coating film adjacent to one side of the vapor deposition film.
The bottom 32 of the standing pouch 30 may also be made of the laminate 20 having the above-mentioned configuration.
The laminate 20 constituting the standing pouch 30 is merely an example and is not limited thereto.

In one embodiment, the body 31 of the standing pouch 30 can be formed by bagging the laminate 20 of the present invention so that the sealant layer 21 is on the inside.

In one embodiment, the bottom 32 of the standing pouch 30 can be formed by inserting the laminate 20 of the present invention between the side sheets of the bag and heat sealing it. More specifically, the laminate 20 can be folded into a V shape so that the sealant layer 21 is on the outside, and inserted between the body 31 of the bag and heat sealing it.

Heat sealing can be performed by known methods such as bar sealing, rotary roll sealing, belt sealing, impulse sealing, high frequency sealing, ultrasonic sealing, etc.

Figure 6 is a schematic front view showing an example of a pillow bag 40, which is one embodiment of a packaging bag. The bag can be produced by forming the laminate 20 into a bag so that the sealant layer 21 is the innermost layer, and then heat sealing two opposing sides.

In one embodiment, the laminate 20 constituting the pillow bag 40 comprises, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the pillow bag 40 comprises, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, and a sealant layer 21 formed by melt extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the pillow bag 40 comprises, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, and a sealant layer 21 formed by melt-extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the pillow bag 40 includes, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, a stretched resin film (support layer), an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
The above-mentioned vapor deposition film 12 may be a colored vapor deposition film made of aluminum or the like, or a transparent vapor deposition film made of a metal oxide such as silicon oxide. When it is a transparent vapor deposition film, it is preferable to provide a gas barrier coating film adjacent to one side of the vapor deposition film.
The above-described laminate 20 constituting the pillow bag 40 is merely an example, and is not limited thereto.

FIG. 7 is a schematic front view showing an example of a three-side sealed bag 50, which can be produced by overlapping two laminates 20 with their sealant layers 21 facing each other, and heat-sealing the three sides.
FIG. 8 is a schematic front view showing an example of a four-side sealed bag 60, which can be produced by overlapping two laminates 20 with their sealant layers 21 facing each other, and heat-sealing the four sides.

In one embodiment, the laminate 20 constituting the three-sided sealed bag 50 or the four-sided sealed bag 60 comprises, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, a stretched resin film (support layer), and a sealant layer 21 formed by melt-extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the three-sided sealed bag 50 or the four-sided sealed bag 60 comprises, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, a stretched resin film (support layer), an adhesive layer, and a sealant layer 21 formed by melt-extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the three-sided sealed bag 50 or the four-sided sealed bag 60 comprises, from the outside to the inside, a polyester film (substrate layer 24), a printed layer, an adhesive layer, a vapor-deposited film 12, a polyester film 11 (support layer), an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
The "polyester film" may have the same structure as the "polyester film 11" or a different structure. The same applies to the subsequent structures.
In one embodiment, the laminate 20 constituting the three-sided sealed bag 50 or the four-sided sealed bag 60 comprises, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
The above-mentioned vapor deposition film 12 may be a colored vapor deposition film made of aluminum or the like, or a transparent vapor deposition film made of a metal oxide such as silicon oxide. When it is a transparent vapor deposition film, it is preferable to provide a gas barrier coating film adjacent to one side of the vapor deposition film.
The above-described laminate 20 constituting the three-side sealed bag 50 or the four-side sealed bag 60 is merely an example, and is not limited thereto.

(Cover material 70)
The laminate 20 of the present invention can be used as a lid material 70 as shown in FIG.
As shown in FIG. 9, the laminate 20 of the present invention is heat-sealed to a container body 71 with the sealant layer 21 facing inside.
The shape of the container body 71 may be a cup shape or a cylindrical shape with a bottom as shown in FIG. 9, but is not limited to this.

In one embodiment, the laminate 20 constituting the lid material 70 comprises, from the outside to the inside, a polyester film (substrate layer 24), an adhesive layer, a vapor deposition film 12, a polyester film 11 (support layer), and a sealant layer 21 formed by melt extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the lid material 70 comprises, from the outside to the inside, a polyester film (substrate layer 24), an adhesive layer, a vapor-deposited film 12, a polyester film 11 (support layer), an adhesive layer, and a sealant layer 21 formed by melt-extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the lid material 70 includes, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, a printing layer, an adhesive layer, a polyester film (support layer), an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the lid material 70 comprises, from the outside to the inside, a polyester film 11 (substrate layer 24), a vapor deposition film 12, a printing layer, an adhesive layer, and a sealant layer 21 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
The above-mentioned vapor deposition film 12 may be a colored vapor deposition film made of aluminum or the like, or a transparent vapor deposition film made of a metal oxide such as silicon oxide. When it is a transparent vapor deposition film, it is preferable to provide a gas barrier coating film adjacent to one side of the vapor deposition film.
The laminate 20 constituting the lid member 70 is merely an example, and is not limited thereto.

(Laminated tube 80)
The laminate 20 of the present invention can be used as a material for forming a laminate tube 80 .
Fig. 10 is a partial cross-sectional view showing an example of a laminate tube 80. As shown in Fig. 10, the laminate tube 80 includes a head portion 81 and a cylindrical body portion 82 formed of the laminate 20 of the present invention.

As shown in FIG. 10 , the head portion 81 includes a spout portion 83 and a shoulder portion 84 .
The cylindrical body 82 is connected to a shoulder 84 of the head 81 .

In one embodiment, the laminate 20 constituting the cylindrical body 82 of the laminate tube 80 includes, from the outside to the inside, a second sealant layer 23 formed by melt-extruding polyethylene, polypropylene, or the like, a polyester film 11 (substrate layer 24), a vapor-deposited film 12, a printed layer, an adhesive layer, and a first sealant layer 22 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the cylindrical body 82 of the laminate tube 80 includes, from the outside to the inside, a second sealant layer 23 which is an unstretched resin film made of polyethylene, polypropylene, or the like, an adhesive layer, a polyester film 11 (substrate layer 24), a vapor-deposited film 12, a printed layer, an adhesive layer, and a first sealant layer 22 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the cylindrical body 82 of the laminate tube 80 includes, from the outside to the inside, a second sealant layer 23 which is an unstretched resin film made of polyethylene, polypropylene, or the like, an adhesive layer, a polyester film (substrate layer 24), a printed layer, an adhesive layer, a vapor-deposited film 12, a polyester film 11 (support layer), an adhesive layer, and a first sealant layer 22 which is an unstretched resin film made of polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the cylindrical body 82 of the laminate tube 80 includes, from the outside to the inside, a second sealant layer 23 which is an unstretched resin film made of polyethylene, polypropylene or the like, an adhesive layer, a polyester film (substrate layer 24), a printed layer, an adhesive layer, a polyethylene film (support layer), an adhesive layer, a polyester film 11 (support layer), a vapor-deposited film 12, an adhesive layer, and a first sealant layer 22 which is an unstretched resin film made of polyethylene, polypropylene or the like.
In one embodiment, the laminate 20 constituting the cylindrical body 82 of the laminate tube 80 includes, from the outside to the inside, a second sealant layer 23 which is an unstretched resin film made of polyethylene, polypropylene or the like, an adhesive layer, a polyester film (substrate layer 24), a printed layer, an adhesive layer, a polyethylene film (support layer), an adhesive layer, a vapor-deposited film 12, a polyester film 11 (support layer), an adhesive layer, and a first sealant layer 22 which is an unstretched resin film made of polyethylene, polypropylene or the like.
The above-mentioned vapor deposition film 12 may be a colored vapor deposition film made of aluminum or the like, or a transparent vapor deposition film made of a metal oxide such as silicon oxide. When it is a transparent vapor deposition film, it is preferable to provide a gas barrier coating film adjacent to one side of the vapor deposition film.
The above-described laminate 20 constituting the cylindrical body 82 of the laminate tube 80 is merely an example, and is not limited thereto.

In one embodiment, the cylindrical body 82 can be manufactured by overlapping the first sealant layer 22 and the second sealant layer 23 at both ends of the laminate 20 and heat sealing the overlapped portions. However, this is not limited to this, and the first sealant layers 22 at both ends or the second sealant layers 23 at both ends may also be heat sealed.

The method for producing the head 81 is not particularly limited, and the head 81 can be produced by a conventionally known method. For example, the head 81 can be produced by a compression molding method or an injection molding method, and can be joined to one open end of the cylindrical body 82.
After joining the head portion 81, the other open end is filled with contents, and the open end is heat sealed to form a bottom seal portion 85, thereby obtaining the laminate tube 80.
The spout portion 83 may be provided with threads for screwing the cap 86 onto it.

(Paper container 90)
The laminate 20 of the present invention can be used as a material for forming a paper container 90. Fig. 11 is a perspective view showing an example of a paper container 90.
The paper container 90 has a body 91 , a bottom 92 , and an upper portion 93 .
FIG. 11 shows a paper container 90 having a rectangular tubular body 91, but the present invention is not limited to this.

In one embodiment, the upper portion 93 includes a pair of opposing inclined plates 94 and a pair of fold-in portions 95 positioned between the inclined plates 94 and folded between the inclined plates 94 .
A margin 96 is provided at the upper end of each of the pair of inclined plates 94, and the plates are bonded to each other.
In one embodiment, one of the inclined plates 94 provided on the upper portion 93 is provided with a pouring outlet 97 and a cap 98 can be attached, but this is not limited to this and the configuration may not include the pouring outlet 97.

In one embodiment, the laminate 20 constituting the paper container 90 comprises, from the outside to the inside, a second sealant layer 23 formed by melt-extruding polyethylene, polypropylene, or the like, a printed layer, a paper base material, an adhesive layer, a vapor-deposited film 12, a polyester film 11 (support layer), an adhesive layer, and a first sealant layer 22 which is an unstretched resin film composed of polyethylene, polypropylene, or the like.
The above-mentioned vapor deposition film 12 may be a colored vapor deposition film made of aluminum or the like, or a transparent vapor deposition film made of a metal oxide such as silicon oxide. When it is a transparent vapor deposition film, it is preferable to provide a gas barrier coating film adjacent to one side of the vapor deposition film.
The laminate 20 constituting the cylindrical body 82 of the paper container 90 is merely an example and is not limited to this.

The paper container 90 can be manufactured by box-making using a conventional method. The shape of the paper container is not limited to the gable-top type shown in FIG. 11, but can be modified as appropriate depending on the contents to be filled, such as a brick type.

(Paper cup 100)
The laminate 20 of the present invention can be used as a material for forming the paper cup 100 .
12 is a perspective view showing an example of a paper cup 100 with a portion cut away.
As shown in Fig. 12, a paper cup 100 includes a body 101 and a bottom 102. Fig. 12 shows a cylindrical body 101 that gradually widens toward the opening, but the present invention is not limited to this.
In one embodiment, as shown in FIG. 12, the body 101 includes a flange portion 103 with an open end that is rounded outward.
In one embodiment, the paper cup 100 may include a lid material (not shown) that is attached along the flange portion 103 .

In one embodiment, the laminate 20 constituting the paper cup 100 comprises, from the outside to the inside, a printed layer, a paper base material, an adhesive layer, a vapor deposition film 12, a polyester film 11 (support layer), and a sealant layer 21 formed by melt extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the paper cup 100 comprises, from the outside to the inside, a printed layer, a paper base material, an adhesive layer, a vapor deposition film 12, a polyester film 11 (support layer), an adhesive layer, and a sealant layer 21 formed by melt extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the paper cup 100 comprises, from the outside to the inside, a second sealant layer 23 formed by melt-extruding polyethylene, polypropylene, or the like, a printed layer, a paper base material, an adhesive layer, a vapor-deposited film 12, a polyester film 11 (support layer), and a first sealant layer 22 formed by melt-extruding polyethylene, polypropylene, or the like.
In one embodiment, the laminate 20 constituting the paper cup 100 comprises, from the outside to the inside, a second sealant layer 23 formed by melt-extruding polyethylene, polypropylene, or the like, a printed layer, a paper base material, an adhesive layer, a vapor-deposited film 12, a polyester film 11 (support layer), an adhesive layer, and a first sealant layer 22 formed by melt-extruding polyethylene, polypropylene, or the like.
The above-mentioned vapor deposition film 12 may be a colored vapor deposition film made of aluminum or the like, or a transparent vapor deposition film made of a metal oxide such as silicon oxide. When it is a transparent vapor deposition film, it is preferable to provide a gas barrier coating film adjacent to one side of the vapor deposition film.
The laminate 20 constituting the paper cup 100 is merely an example and is not limited thereto.

An example of a method for manufacturing the paper cup 100 will now be described with reference to FIG.
First, the laminate 20 of the present invention is cut out to produce a sector-shaped body blank 101', as shown in Fig. 13. Next, the body blank 101' is rolled into a cylindrical shape, and both ends 101'a are overlapped and heat-sealed in multiple states to form the body attachment portion 104.
Next, the laminate 20 of the present invention is cut out to produce a circular bottom blank 102', and then the outer periphery of this blank is bent downward to form a bent portion 102'a.
Next, the bent portion 102'a of the bottom blank 102' is fitted over the lower end of the body blank 101'a so as to be wrapped around it, and then heat-sealed, thereby obtaining the paper cup 100.
If desired, the open end of the body may be rolled outwardly to form a flange 103 .

Next, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to the description of the following examples as long as it does not deviate from the gist of the invention.

(Example 1-1)
Chemically recycled polyethylene terephthalate and fossil fuel polyethylene terephthalate were mixed in a mass ratio of 5:5, and this PET mixture was extruded into a film using a T-die method, after which it was biaxially stretched to produce a polyester film 11 having a thickness of 12 μm.

A vapor-deposited film 12 of aluminum oxide having a thickness of 20 nm was formed on one side of this polyester film 11 by the PVD method, to obtain the vapor-deposited resin film 10 of the present invention.

(Example 1-2)
Chemically recycled polyethylene terephthalate and fossil fuel polyethylene terephthalate were mixed in a mass ratio of 7:3, and this PET mixture was extruded into a film using a T-die method, after which it was biaxially stretched to produce a polyester film 11 having a thickness of 12 μm.

A vapor-deposited film 12 of aluminum oxide having a thickness of 20 nm was formed on one side of this polyester film 11 by the PVD method, to obtain the vapor-deposited resin film 10 of the present invention.

(Comparative Example 1-1)
Fossil fuel polyethylene terephthalate was extruded by the T-die method and then biaxially stretched to produce a polyester film having a thickness of 12 μm.

A 20 nm thick aluminum oxide film was formed on one side of the polyester film by PVD to obtain a vapor-deposited resin film.

<<Measurement of the composition ratio of low molecular weight components>>
The polyester films obtained in the above Examples and Comparative Examples were prepared, and 10 g of each was cut out and weighed in a 30 mL vial. A HFIP/chloroform mixture was added to the vial, and the mixture was allowed to stand for 12 hours to dissolve.
After standing, chloroform was added to dilute the solution to prepare a 0.1% solution.
This solution was filtered using a 0.45 μm hydrophilic PTFE membrane filter cartridge (Millex-LH manufactured by Merck Millipore), and the obtained filtrate was subjected to GPC measurement under the following conditions.
In the obtained molecular weight distribution curve, the area ratio of the region of molecular weight of 1,000 or less was determined. The area ratio of the region of molecular weight of 1,000 or less is shown in Table 1. Note that the molecular weight distribution curve in the region of molecular weight of 1,000 or less is shown in FIG.
(Measurement conditions)
Column used: Agilent Technologies, 2x PLgel 5μ MIXED (7.5 mm x 300 mm)
Column temperature: 40°C
Mobile phase: Chloroform (Fujifilm Wako Pure Chemical Industries, Ltd., for liquid chromatography)
・Flow rate: 1.0mL/min
Injection volume: 2.5 μL
Detection: 254 nm (UV-Vis detector)
Molecular weight calibration: monodisperse polystyrene (Agilent Technologies, PS-1)
Equipment: 515 HPLC pump, 717plus automatic injection device, UV-visible detector (Waters)

<<Measurement of Cyclic Trimer Content>>
The polyester films obtained in the above examples and comparative examples were prepared. Approximately 0.1 g of a sample was taken from the polyester film, and the sample was dissolved in a mixture of hexafluoroisopropanol (HFIP) and chloroform. Acetonitrile was added to the solution to precipitate the polymer, and the precipitate was then filtered. The filtrate was evaporated to dryness, and the resulting residue was dissolved in dimethylformamide (DMF). The solution was analyzed by high performance liquid chromatography (HPLC) to measure the content of cyclic trimers. The measurement results are shown in Table 1. The measurement conditions were as follows.
(Measurement conditions)
Equipment: Shimadzu Corporation, LC-20
Column used: Develosil ODS-HG-3 3μ (4.6×150 mm), manufactured by Nomura Chemical Co., Ltd.
Column temperature: 40°C
Mobile phase: 0.5% by volume aqueous acetic acid/acetonitrile (gradient)
・Flow rate: 1.0mL/min
Injection volume: 15 μL
Detection: 254 nm (UV-Vis detector)
Equipment: Shimadzu Corporation, LC-20

<<Measurement of crystallization temperature and melting point>>
The polyester films obtained in the above Examples and Comparative Examples were prepared, and 5 mg of each film was cut out to obtain samples.
The temperature of this sample was raised from 20° C. to 300° C. at a rate of 10° C./min, and held at 300° C. for 5 minutes. The temperature was then lowered from 300° C. to 20° C. at a rate of −10° C./min. The sample was then held at 20° C. for 5 minutes. The temperature was then raised again from 20° C. to 300° C. at a rate of 10° C./min. This gave a melting curve.
The main peak in the temperature-lowering stage of this melting curve was taken as the crystallization temperature, and the main peak in the second temperature-up stage was taken as the melting point. The crystallization temperature and melting point are shown in Table 1.

<<Measurement of static friction coefficient>>
The deposited resin films obtained in the above Examples and Comparative Examples were prepared, and each deposited resin film was cut to prepare a test piece of 200 mm x 150 mm.
The test piece was then fixed to the sliding table of the testing machine with cellophane tape, with the polyester film facing upward.
Next, a test piece of 70 mm x 100 mm was cut from the vapor-deposited resin film and wrapped around a 63 mm x 63 mm x 6.3 mm metal thread (weight 200 g) with the vapor-deposited film on the inside and the polyester film on the outside.
Next, the polyester films were placed on the fixed vapor-deposited resin film so that the polyester films were in contact with each other.
Next, the metal thread around which the test piece was wound was slid at a speed of 100 mm/min in an environment of 23° C. and 50% relative humidity, and the friction was measured using a friction measuring device (TR-2, manufactured by Toyo Seiki Co., Ltd.). The measurement results are shown in Table 1.

<<Hygiene evaluation>>
The polyester films obtained in the above Examples and Comparative Examples were prepared, and each of the deposited resin films was cut to prepare test pieces of 200 mm x 200 mm.
Next, 80 mL of ion-exchanged water was placed in a 100 mL glass flask, and the above test piece was placed therein.
The opening of the glass flask was then covered with aluminum foil, and the glass flask was placed in a water bath and heated at 80° C. for 60 minutes.
After the glass flask was cooled to room temperature, three panelists confirmed the change in the taste of the ion-exchanged water before and after the above treatment. Since the taste of ion-exchanged water changes when low molecular weight components are mixed in, the polyester film, which did not change the taste of the ion-exchanged water, can suppress the mixing of low molecular weight components into the ion-exchanged water and is therefore excellent in hygiene. Hygiene was evaluated based on the following evaluation criteria. The evaluation results are shown in Table 2. Note that Reference Example 1-1 was performed as described above without using a test piece.
<Evaluation criteria>
A: None of the three people noticed any change in taste.
B: Two out of three people did not notice any change in taste.
NG: More than two out of three people noticed a change in taste.

(Example 2-1)
A vapor-deposited resin film 10 was prepared in the same manner as in Example 1-1. The vapor-deposited resin film 10 and a biaxially oriented nylon film were bonded together by a dry lamination method using a two-component curing adhesive (manufactured by Toyo-Morton: base agent TM556/curing agent CAT56). The biaxially oriented nylon film of this dry laminate film was bonded to an unstretched polyethylene film by a dry lamination method using the two-component curing adhesive.
This resulted in a laminate 20 in which the deposited resin film 10, the adhesive layer, the biaxially oriented nylon film, the adhesive layer, and the sealant layer were laminated in this order. Note that the deposited film 12 of the deposited resin film 10 was located on the adhesive layer side.

(Comparative Example 2-1)
A deposited resin film was prepared in the same manner as in Comparative Example 1-1. A laminate was obtained in the same manner as in Example 2-1, except that this deposited resin film was used as the deposited resin film 10.

<<Oxygen permeability measurement>>
The oxygen permeability was measured using the laminates obtained in Example 2-1 and Comparative Example 2-1. The oxygen permeability was measured in accordance with JIS K7126 under an environment of a temperature of 23° C. and a relative humidity of 90%, using an oxygen permeability measuring device (manufactured by Modern Control (MOCON) [model name: OX-TRAN 2/21]) as the measuring device. The measurement results are shown in Table 3.

<<Measurement of water vapor transmission rate>>
The water vapor permeability was measured using the laminates obtained in Example 2-1 and Comparative Example 2-1. The water vapor permeability was measured in accordance with JIS K7129 at a temperature of 40° C. and a relative humidity of 90%, using a water vapor permeability measuring device (a measuring device manufactured by MOCON [model name: PERMATRAN 3/33]). The measurement results are shown in Table 3.

Reference Signs List 10: Vapor-deposited resin film 11: Polyester film 12: Vapor-deposited film 20: Laminate 21: Sealant layer 22: First sealant layer 23: Second sealant layer 24: Base material layer 25: Intermediate layer 30: Standing pouch 31: Body 32: Bottom 40: Pillow bag 50: Three-sided sealed bag 60: Four-sided sealed bag 70: Lid 71: Container body 80: Laminated tube 81: Head 82: Cylinder Body 83: spout 84: shoulder 85: bottom seal 86: cap 90: paper container 91: body 92: bottom 93: upper part 94: inclined plate 95: folded part 96: margin 97: spout 98: cap 100: paper cup 101: body 101': body blank 101'a: both ends of body blank 102: bottom 102': bottom blank 102'a: bent part 103: flange 104: body pasting part

Claims (10)

A vapor-deposited resin film comprising a polyester film and a vapor-deposited film,
The polyester film contains at least one selected from the group consisting of chemically recycled polyester, mechanically recycled polyester, fossil fuel polyester, and biomass polyester,
the area ratio of a region of a molecular weight of 1,000 or less in a molecular weight distribution curve obtained by GPC measurement of the polyester film is 1.8% or less of a total peak area;
The vapor-deposited resin film , wherein the content of cyclic trimers in the polyester film is 0.510% by mass or more . The vapor-deposited resin film according to claim 1, wherein the melting point of the polyester film is 250°C or less. The vapor-deposited resin film according to claim 1 or 2, wherein the crystallization temperature of the polyester film is 196°C or lower. The vapor-deposited resin film according to any one of claims 1 to 3, wherein the static friction coefficient of the surface of the polyester film on which the vapor-deposited film is not formed is 0.35 or more. The vapor-deposited resin film according to any one of claims 1 to 4, wherein the polyester content in the polyester film is 90% by mass or more and 100% by mass or less. The vapor-deposited resin film according to any one of claims 1 to 5, wherein the chemically recycled polyester, the mechanically recycled polyester, the fossil fuel polyester, and the biomass polyester are polyethylene terephthalate. A vapor-deposited resin film according to any one of claims 1 to 6,
a sealant layer or an adhesive layer provided on the inner side of the vapor-deposited resin film;
A laminate comprising: the laminate comprises a base layer, a vapor-deposited film, an intermediate layer, and the sealant layer or the adhesive layer,
The laminate according to claim 7 , wherein the base layer and the vapor-deposited film are constituted by the vapor-deposited resin film. the laminate comprises a base layer, a vapor-deposited film, an intermediate layer, and the sealant layer or the adhesive layer,
the intermediate layer comprises a support layer;
The laminate according to claim 7 , wherein the support layer and the vapor-deposited film are constituted by the vapor-deposited resin film. A packaging container comprising the laminate according to any one of claims 7 to 9.

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