Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP7668657B2 - Ferritic free-cutting stainless steel with excellent precision cutting properties - Google Patents
[go: Go Back, main page]

JP7668657B2 - Ferritic free-cutting stainless steel with excellent precision cutting properties - Google Patents

Ferritic free-cutting stainless steel with excellent precision cutting properties Download PDF

Info

Publication number
JP7668657B2
JP7668657B2 JP2021041271A JP2021041271A JP7668657B2 JP 7668657 B2 JP7668657 B2 JP 7668657B2 JP 2021041271 A JP2021041271 A JP 2021041271A JP 2021041271 A JP2021041271 A JP 2021041271A JP 7668657 B2 JP7668657 B2 JP 7668657B2
Authority
JP
Japan
Prior art keywords
less
cutting
stainless steel
ferritic free
ferritic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2021041271A
Other languages
Japanese (ja)
Other versions
JP2022141117A (en
Inventor
光司 高野
義洋 岡
利治 間曽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Stainless Steel Corp
Original Assignee
Nippon Steel Stainless Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Stainless Steel Corp filed Critical Nippon Steel Stainless Steel Corp
Priority to JP2021041271A priority Critical patent/JP7668657B2/en
Publication of JP2022141117A publication Critical patent/JP2022141117A/en
Application granted granted Critical
Publication of JP7668657B2 publication Critical patent/JP7668657B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Heat Treatment Of Steel (AREA)

Description

本発明は、耐食性が必要な小型部品に切削される材料に関して、構成刃先の生成を抑制した精密切削性に優れるフェライト系ステンレス鋼に関するものである。 The present invention relates to a ferritic stainless steel that has excellent precision cutting properties and suppresses the formation of built-up edges, for use as a material cut into small parts that require corrosion resistance.

フェライト系ステンレス鋼は、耐食性,低熱膨張率等の観点から、耐久性を要する精密機器部品に使用される。特に棒線を素材とする磨棒から切削加工される精密機器部品では、回転体に使用されることが多く、とりわけ精密な切削加工性が必要になる。具体的には、切削加工時の工具寿命に優れ、かつ、構成刃先の脱落痕のない非常に平滑な切削表面が求められる。構成刃先は切削工具先端上に母材が凝着により生成・成長する堆積物であり、切削途中に工具先端から脱落することで切削表面上に圧着されて表面性状を劣化させる。 Ferritic stainless steels are used for precision equipment parts that require durability due to their corrosion resistance and low thermal expansion coefficient. In particular, precision equipment parts that are cut from polished bars made from wire rods are often used for rotating bodies, and require particularly precise cutting workability. Specifically, they require excellent tool life during cutting work and an extremely smooth cutting surface with no traces of the built-up cutting edge. Built-up edges are deposits that form and grow on the tip of a cutting tool due to adhesion of the base material; they fall off the tip of the tool during cutting and are pressed onto the cutting surface, degrading the surface properties.

これまで、高耐食性フェライト系ステンレス鋼において、Bを添加して酸素とBの比率を制御することでBを含む酸化物系介在物を析出させ、Pb並みの切削性を有するフェライト系快削ステンレス鋼の提案がある(特許文献1)。 So far, there has been a proposal to add B to highly corrosion-resistant ferritic stainless steel and control the ratio of oxygen to B to precipitate oxide-based inclusions containing B, resulting in a ferritic free-cutting stainless steel with machinability comparable to that of Pb (Patent Document 1).

また、PbやMnSの切削粒子の代替として窒化ホウ素粒子を0.1%以上分散したフェライト系快削ステンレス鋼の提案がある(特許文献2)。快削性付与材を添加してなるオーステナイト系ステンレス鋼にBを添加してh-BN(六方昌系窒化ホウ素)粒子を鋼中に均一に分散して切削性を付与することも提案されている(特許文献3)。 Furthermore, a ferritic free-cutting stainless steel with 0.1% or more of boron nitride particles dispersed therein as an alternative to cutting particles of Pb or MnS has been proposed (Patent Document 2). It has also been proposed to add B to an austenitic stainless steel to which a machinability-imparting material has been added, thereby dispersing h-BN (hexagonal boron nitride) particles uniformly throughout the steel to impart machinability (Patent Document 3).

さらに、Pb等の代替としてS添加のフェライト系ステンレス鋼にBとNを添加し、B,N,Sを含む金属間化合物のサイズと個数密度を制御したフェライト系快削ステンレス鋼が提案されている(特許文献4)。 Furthermore, a ferritic free-cutting stainless steel has been proposed in which B and N have been added to ferritic stainless steel containing S as a replacement for Pb, etc., and the size and number density of the intermetallic compounds containing B, N, and S have been controlled (Patent Document 4).

特開2008-274361号公報JP 2008-274361 A 特開2003-129191号公報JP 2003-129191 A 特許第5142289号公報Patent No. 5142289 特許第5957241号公報Patent No. 5957241

特許文献1~4には、構成刃先痕の抑制が十分でなく、平滑な切削表面性状の課題が解決できずに精密な切削表面性状の観点から課題がある。 Patent documents 1 to 4 do not adequately suppress built-up cutting edge marks, and the problem of smooth cutting surface properties cannot be solved, which poses problems from the perspective of precise cutting surface properties.

本発明者らは、上記の背景技術に記載の公知の技術又は組み合わせでは、優れた切削性を付与した高耐食フェライト系快削ステンレス鋼において、優れた工具寿命と、構成刃先痕を抑制した優れた平滑な表面性状の両立ができないことを知見した。 The inventors have found that the known techniques or combinations described in the Background Art above are unable to achieve both excellent tool life and excellent smooth surface properties with reduced built-up edge marks in highly corrosion-resistant ferritic free-cutting stainless steels that have excellent machinability.

本発明の解決すべき課題は、腐食環境の厳しく、精度が求められる環境下で使用されるフェライト系ステンレス鋼の精密部品用として、切削加工時の工具寿命に優れ、切削加工で優れた平坦度を有する切削表面性状を得ることができる、高耐食性のフェライト系快削ステンレス鋼を提供することである。 The problem to be solved by the present invention is to provide a highly corrosion-resistant ferritic free-cutting stainless steel that can provide excellent tool life during cutting and excellent flatness in the cutting surface properties, for use in precision ferritic stainless steel parts used in highly corrosive environments where precision is required.

本発明者らは、上記課題を解決するためにS含有のフェライト系快削ステンレス鋼において種々検討した結果、快削元素のS含有系にB、Nを添加し、N固溶化軟化処理によりBNを微細析出させて固溶N量を制御することで精密切削加工時の構成刃先痕を抑制して切削加工で平滑性に優れる表面性状が得られる知見を得た。 In order to solve the above problems, the inventors conducted various studies on S-containing ferritic free-cutting stainless steels, and discovered that by adding B and N to the S-containing free-cutting element system and controlling the amount of dissolved N by finely precipitating BN through N solution softening treatment, it is possible to suppress built-up cutting edge marks during precision cutting and obtain surface properties with excellent smoothness during cutting.

本発明は、上記知見に基づいてなされたものであり、その要旨とするところは以下のとおりである。 The present invention was made based on the above findings, and its gist is as follows:

(1)質量%で、C:0.10%未満、Si:0.1~2.0%、Mn:0.1~3.0%、S:0.02~0.40%、P:0.10%以下、Cr:13.0~22.0%、B:0.001~0.01%、N:0.015~0.08%、Al:0.008%以下、及びO:0.015%以下を含有し、残部Fe及び不純物からなる化学成分を有し、固溶N量が0.010~0.060%であり、0.5μm以下のBN系金属間化合物が100μm2中に20個以上あることを特徴とするフェライト系快削ステンレス鋼。 (1) A ferritic free-cutting stainless steel containing, by mass%, C: less than 0.10%, Si: 0.1-2.0%, Mn: 0.1-3.0%, S: 0.02-0.40%, P: 0.10% or less, Cr: 13.0-22.0%, B: 0.001-0.01%, N: 0.015-0.08%, Al: 0.008% or less, and O: 0.015% or less, with the balance being Fe and impurities, with a solute N content of 0.010-0.060%, and with 20 or more BN-based intermetallic compounds of 0.5 μm or less per 100 μm2 .

(2)前記Feの一部に変えて、さらに質量%で、Ni:1.5%以下、Mo:2.5%以下、Cu:1.5%以下、Co:1.5%以下、及びW:2.5%以下の内、1種類以上を含有することを特徴とする前記(1)のフェライト系快削ステンレス鋼。 (2) The ferritic free-cutting stainless steel of (1) above, characterized in that it contains, in place of a portion of the Fe, one or more of the following elements by mass: Ni: 1.5% or less, Mo: 2.5% or less, Cu: 1.5% or less, Co: 1.5% or less, and W: 2.5% or less.

(3)前記Feの一部に変えて、さらに質量%で、Bi:0.20%以下、Sn:0.30%以下、Sb:0.30%以下、Ag:0.30%以下、及びTe:0.10%以下の内、1種類以上を含有することを特徴とする前記(1)又は(2)のフェライト系快削ステンレス鋼。 (3) The ferritic free-cutting stainless steel according to (1) or (2), characterized in that it contains, in place of a portion of the Fe, one or more of the following elements by mass: Bi: 0.20% or less, Sn: 0.30% or less, Sb: 0.30% or less, Ag: 0.30% or less, and Te: 0.10% or less.

(4)前記Feの一部に変えて、さらに質量%で、V:0.8%以下、Nb:0.5%以下、Ti:0.5%以下、及びTa:0.5%以下の内、1種類以上を含有することを特徴とする前記(1)~(3)のいずれかのフェライト系快削ステンレス鋼。 (4) A ferritic free-cutting stainless steel according to any one of (1) to (3), characterized in that, in place of a portion of the Fe, it further contains, by mass%, one or more of V: 0.8% or less, Nb: 0.5% or less, Ti: 0.5% or less, and Ta: 0.5% or less.

(5)前記Feの一部に変えて、さらに質量%で、Mg:0.010%以下、Ca:0.010%以下、Hf:0.010%以下、及びREM:0.050%以下の内、1種類以上を含有することを特徴とする前記(1)~(4)のいずれかのフェライト系快削ステンレス鋼。 (5) A ferritic free-cutting stainless steel according to any one of (1) to (4), characterized in that, in place of a portion of the Fe, it further contains, by mass%, one or more of Mg: 0.010% or less, Ca: 0.010% or less, Hf: 0.010% or less, and REM: 0.050% or less.

(6)前記(1)~(5)のいずれかの化学成分を有する鋳片を1150~1330℃に加熱する加熱工程、加熱した上記鋳片に熱間圧延又は熱間加工を施す加工工程、700~900℃で60~300分保定するバッチ焼鈍工程、700~900℃の温度域で保定し、1℃/s以上の冷却速度で冷却するストランド焼鈍を備えることを特徴とする本発明のフェライト系快削ステンレス鋼の製造方法。 (6) A method for producing ferritic free-cutting stainless steel according to the present invention, comprising a heating step of heating a slab having any one of the chemical compositions described in (1) to (5) to 1150 to 1330°C, a processing step of subjecting the heated slab to hot rolling or hot working, a batch annealing step of holding the slab at 700 to 900°C for 60 to 300 minutes, and strand annealing, holding the slab in the temperature range of 700 to 900°C and cooling at a cooling rate of 1°C/s or more.

本発明によれば、フェライト系快削ステンレス鋼において、金属組織と金属間化合物の制御のために適正な成分調整と熱処理を施すことで、良好な切削工具寿命と構成刃先痕を抑制した優れた平坦な切削表面性状が得られ、耐食性に優れた精密部品に好適な材料を提供する。 According to the present invention, by appropriately adjusting the components and applying heat treatment to control the metal structure and intermetallic compounds in ferritic free-cutting stainless steel, it is possible to obtain a good cutting tool life and excellent flat cutting surface properties with reduced built-up cutting edge marks, providing a material with excellent corrosion resistance that is suitable for precision parts.

以下に本発明の各要件について説明する。なお、以下の説明における「%」は特に断りのない限り、「質量%」である。 Each of the requirements of the present invention will be explained below. In the following explanation, "%" means "mass %" unless otherwise specified.

《鋼の必須成分組成》
本発明の高耐食性フェライト系快削ステンレス鋼は、一般的に耐久性と低熱膨張率を必要とする部品が対象であり、高耐食性フェライト系ステンレス鋼がベースとなる。
<Essential composition of steel>
The highly corrosion-resistant ferritic free-cutting stainless steel of the present invention is intended for parts that generally require durability and a low coefficient of thermal expansion, and is based on highly corrosion-resistant ferritic stainless steel.

Cは、母材の強度を確保するためにため0.10%未満含有できる。しかしながら、0.10%以上を添加するとCr炭化物が多量に生成して、耐食性が劣化するばかりか、切削表面性状,工具寿命が劣化する。そのため、0.10%未満に限定する。好ましくは、0.08%以下である。 C can be contained in an amount of less than 0.10% to ensure the strength of the base material. However, adding more than 0.10% produces a large amount of Cr carbide, which not only deteriorates corrosion resistance but also deteriorates the cutting surface properties and tool life. Therefore, it is limited to less than 0.10%. Preferably, it is 0.08% or less.

Nは、後述するN固溶軟化処理でBN系金属間化合物を得て、また、固溶N量を確保して構成刃先痕の生成を抑制するために0.015%添加する。しかしながら、0.08%を超えて含有させるとCr窒化物による耐食性劣化が生じるばかりか、切削表面性状が劣化する。そのため、0.08%以下に限定する。好ましくは、0.02~0.06%の範囲である。 0.015% N is added to obtain BN-based intermetallic compounds in the N solid solution softening treatment described below, and to ensure the amount of dissolved N and suppress the formation of built-up cutting edge marks. However, if it is added in excess of 0.08%, not only will corrosion resistance deteriorate due to Cr nitrides, but the cutting surface properties will also deteriorate. For this reason, it is limited to 0.08% or less. The preferred range is 0.02-0.06%.

Siは、脱酸を行って切削表面性状を劣化させる粗大な介在物の生成を抑制するため、0.1%以上含有させる。しかしながら、2.0%を超えて含有させると硬質化して工具への母材の凝着を促進して構成刃先痕の生成を助長する。そのため、2.0%以下に限定する。好ましくは、0.2~1.0%の範囲である。 Si is contained at 0.1% or more to suppress the formation of coarse inclusions that deoxidize and deteriorate the cutting surface properties. However, if it is contained at more than 2.0%, it hardens and promotes adhesion of the base material to the tool, promoting the formation of built-up cutting edge marks. Therefore, it is limited to 2.0% or less. The range of 0.2 to 1.0% is preferable.

Mnは、脱酸を行って切削表面性状を劣化させる粗大な介在物の生成を抑制し、硫化物を形成して良好な工具寿命を確保するため、0.1%以上含有させる。しかしながら、3.0%を超えて含有させると固溶硬化で硬化して工具寿命が劣化する。そのため、3.0%以下に限定する。好ましくは、0.2~2.0%の範囲である。 Mn is added at 0.1% or more to suppress the formation of coarse inclusions that degrade the cutting surface properties by deoxidizing, and to form sulfides to ensure good tool life. However, if it is added at more than 3.0%, it will harden by solid solution hardening and the tool life will deteriorate. Therefore, it is limited to 3.0% or less. The preferred range is 0.2 to 2.0%.

Sは、硫化物を形成して良好な工具寿命を確保するために0.02%以上添加する。しかしながら、0.40%を超えて含有させると精密切削加工時の工具上の構成刃先痕の生成が顕著となり、切削表面上への構成刃先の脱落痕を防止できなくなる。そのため、0.40%以下に限定する。好ましくは、0.03~0.30%の範囲である。 S is added at 0.02% or more to form sulfides and ensure good tool life. However, if the content exceeds 0.40%, the formation of built-up cutting edge marks on the tool during precision cutting processing becomes significant, and it becomes impossible to prevent built-up cutting edge detachment marks on the cutting surface. Therefore, it is limited to 0.40% or less. The preferred range is 0.03 to 0.30%.

Pは、原料から不可避的不純物として混入するが、0.10%を超えて含有すると粒界偏析により耐食性が劣化するばかりか製造性が著しく低下する。そのため、0.10%以下に限定する。好ましくは、0.05%以下である。 P is mixed in as an unavoidable impurity from the raw materials, but if it is contained in excess of 0.10%, not only does it deteriorate corrosion resistance due to grain boundary segregation, but it also significantly reduces manufacturability. For this reason, it is limited to 0.10% or less. Preferably, it is 0.05% or less.

Crは、ステンレス鋼の耐食性の機能を得て低熱膨張率で軟質な切削性の良好なフェライト組織を得るために、13.0%以上を含有させる。しかしながら、20.0%を超えて含有させると、工具との焼き付きが激しくなり、切削表面性状を確保できなくなる。そのため、22.0%以下に限定する。好ましくは、15.0~20.0%である。 Cr is contained in an amount of 13.0% or more in order to obtain the corrosion resistance of stainless steel, a low thermal expansion coefficient, and a soft ferritic structure with good machinability. However, if it is contained in an amount exceeding 20.0%, it becomes prone to seizure with the tool, and it becomes impossible to ensure the cutting surface properties. Therefore, it is limited to 22.0% or less. The preferred range is 15.0 to 20.0%.

Bは、Nとともに添加することでN固溶軟化処理時に微細なBNを形成して工具表面での母材の凝着を抑制し、切削表面での構成刃先痕を防止する。そのため、0.001%以上添加する。しかしながら、0.0100%を超えて添加すると粗大なボライドが生成して逆に構成刃先の生成を促進させるばかりか製造性を著しく劣化させる。そのため0.0100%以下に限定する。好ましくは、0.0020~0.0070%である。 When added together with N, B forms fine BN during N solution softening treatment, suppressing adhesion of the base material to the tool surface and preventing built-up edge marks on the cutting surface. For this reason, 0.001% or more is added. However, adding more than 0.0100% generates coarse borides, which not only promotes the formation of built-up edges but also significantly deteriorates manufacturability. For this reason, it is limited to 0.0100% or less. The preferred range is 0.0020-0.0070%.

Alは、脱酸のために添加してもよいが、0.008%を超えて含有すると粗大介在物が生成して表面性状が劣化する。そのため、0.008%以下に限定する。好ましくは、0.006%以下である。 Aluminum may be added for deoxidation, but if it is added in excess of 0.008%, coarse inclusions will form and the surface properties will deteriorate. Therefore, it is limited to 0.008% or less. Preferably, it is 0.006% or less.

Oは、不可避的不純物として混入するが、0.015%を超えて含有すると粗大介在物が生成して切削表面性状が劣化する。そのため、0.015%以下に限定する。好ましくは、0.012%以下である。 O is mixed in as an unavoidable impurity, but if it is contained in excess of 0.015%, coarse inclusions are generated, degrading the cutting surface properties. Therefore, it is limited to 0.015% or less. Preferably, it is 0.012% or less.

発明のフェライト系快削ステンレス鋼が含有するNのうち、固溶N量が0.01~0.06%である。 The amount of dissolved N contained in the ferritic free-cutting stainless steel of the invention is 0.01 to 0.06%.

フェライト母相への固溶Nは、切削加工時の母材を脆化させて構成刃先の生成を抑制して良好な表面性状を得るのに有効である。そのため、固溶N量を0.01%以上に限定する。しかしながら、0.060%を超えてNを固溶させると、効果して逆に工具寿命が劣化する。そのため、固溶N量の上限を0.06%とした。本発明では後述するようにストランド焼鈍(急冷)でNをフェライト母相に固溶させる。 Solution of N into the ferrite matrix is effective in embrittling the base material during cutting, suppressing the formation of built-up edges, and obtaining good surface properties. For this reason, the amount of solute N is limited to 0.01% or more. However, if N is dissolved in an amount exceeding 0.060%, the tool life will be adversely affected and deteriorated. For this reason, the upper limit of the amount of solute N is set at 0.06%. In the present invention, N is dissolved into the ferrite matrix by strand annealing (rapid cooling), as described below.

本発明のフェライト系快削ステンレス鋼の金属組織は、0.5μm以下のBN系金属間化合物を100μm2中に20個以上含む。 The metal structure of the ferritic free-cutting stainless steel of the present invention contains 20 or more BN-based intermetallic compounds of 0.5 μm or less per 100 μm 2 .

BNは、自己潤滑作用により工具上への母材の凝着を抑制して構成刃先の生成を防止して優れた切削表面性状を得るのに有効である。ただし、0.5μmサイズを超える粗大なBNが分散していると、工具先端で塑性変形した母材とBNが層状に積層・堆積されて構成刃先が生成・成長する。そのため、長径0.5μmサイズ以下のBNを微細分散させて積層・堆積を抑制する。なお、100μm2中に20個以上の数密度でBNが微細分散しているとその効果は顕著になる。好ましくは、100μm2中に30個以上である。 BN is effective in obtaining excellent cutting surface properties by suppressing adhesion of the base material to the tool through its self-lubricating action, preventing the formation of a built-up edge. However, if coarse BN particles exceeding 0.5 μm in size are dispersed, the base material plastically deformed at the tip of the tool and BN are laminated and deposited in layers, generating and growing a built-up edge. Therefore, BN particles with a major axis of 0.5 μm or less are finely dispersed to suppress lamination and deposition. The effect is remarkable when BN particles are finely dispersed at a number density of 20 or more per 100 μm2 . Preferably, the number is 30 or more per 100 μm2 .

《選択的含有成分》
本発明のステンレス鋼は、上述してきた元素以外は、Fe及び不純物からなる化学成分から構成される。さらに、前記成分組成に加え、Feの一部に替えて、選択的に以下に示す元素を含有してもよい。
Optional Ingredients
The stainless steel of the present invention is composed of chemical components consisting of Fe and impurities other than the elements described above. Furthermore, in addition to the above-mentioned composition, the stainless steel may selectively contain the following elements in place of a portion of Fe.

Ni、CuやCoの元素は添加しなくてもよい。添加すれば製品の耐食性や靭性を向上させる効果を有する。しかしながら、1.5%を超えて添加すると、焼鈍で軟化しにくくなり、工具寿命が劣化する。そのため、含有量を1.5%以下とする。上記効果を確実に得るには、各元素の含有量を0.01%以上、1.0%以下とすることが好ましい。 The elements Ni, Cu and Co do not have to be added. Addition has the effect of improving the corrosion resistance and toughness of the product. However, if added in excess of 1.5%, it becomes difficult to soften during annealing, and tool life deteriorates. For this reason, the content is set to 1.5% or less. To ensure the above effects, it is preferable to set the content of each element to 0.01% or more and 1.0% or less.

MoやWの元素は添加しなくてもよい。劣化すれば製品の耐食性を向上させる効果を有する。しかしながら、2.5%を超えて添加すると、その効果は飽和するし、逆に切削加工時の工具寿命を劣化させる。そのため、含有量を2.0%以下とする。上記効果を確実に得るには、各元素の含有量を0.01%以上、2.0%以下とすることが好ましい。 The elements Mo and W do not need to be added. If they deteriorate, they have the effect of improving the corrosion resistance of the product. However, if they are added in excess of 2.5%, the effect saturates and, conversely, they deteriorate the tool life during cutting processing. For this reason, the content is set to 2.0% or less. To ensure the above effects, it is preferable to set the content of each element to 0.01% or more and 2.0% or less.

Biの元素は添加しなくてもよい。添加すれば、切削加工時に自己潤滑作用として働き、構成刃先の生成を抑制して切削表面性状を向上させる効果を有する。しかしながら、0.20%を超えて添加すると、熱間製造性が著しく劣化して製造できなくなる。そのため、含有量を0.20%以下とする。上記効果を確実に得るには、各元素の含有量を0.01%以上、2.0%以下とすることが好ましい。 The element Bi does not have to be added. If added, it acts as a self-lubricant during cutting, suppressing the formation of built-up edges and improving the cutting surface properties. However, if it is added in an amount exceeding 0.20%, hot manufacturability will be significantly deteriorated and manufacturing will become impossible. Therefore, the content should be 0.20% or less. To ensure the above effects, it is preferable that the content of each element be 0.01% or more and 2.0% or less.

Sn、Sb,Agの元素は添加しなくてもよい。添加すれば、切削加工時に自己潤滑作用として働き、構成刃先の生成を抑制して切削表面性状を向上させる効果を有する。しかしながら、0,30%を超えて添加すると、熱間製造性が著しく劣化して製造できなくなる。そのため、含有量を0.30%以下とする。上記効果を確実に得るには含有量を0.005%以上、0.20%以下とすることが好ましい。 The elements Sn, Sb, and Ag do not need to be added. If added, they act as a self-lubricant during cutting, suppressing the formation of built-up edges and improving the cutting surface properties. However, if added in excess of 0.30%, hot manufacturability is significantly degraded and manufacturing becomes impossible. For this reason, the content is set to 0.30% or less. To reliably obtain the above effects, it is preferable to set the content to 0.005% or more and 0.20% or less.

Teの元素は添加しなくてもよい。添加すれば球状の硫化物を生成して、構成刃先の積層・成長を抑制して切削表面性状を向上させる効果を有する。しかしながら、0.10%を超えて添加すると、熱間製造性が著しく劣化して製造できなくなる。そのため、含有量を0.10%以下とする。上記効果を確実に得るには含有量を0.005%以上、0.05%以下とすることが好ましい。 The element Te does not have to be added. If added, it produces spherical sulfides, which inhibits the stacking and growth of the cutting edge and improves the cutting surface properties. However, if it is added in excess of 0.10%, hot manufacturability is significantly deteriorated and manufacturing becomes impossible. Therefore, the content is set to 0.10% or less. To reliably obtain the above effect, it is preferable to set the content to 0.005% or more and 0.05% or less.

Vの元素は添加しなくてもよい。添加すれば製品の耐食性を向上させる効果を有する。しかしながら、0.8%を超えて添加すると、粗大な炭窒化物が形成して構成刃先の積層・成長を助長して切削表面性状が劣化し、工具寿命も劣化させる。そのため、上限を0.8%以下とする。上記効果を確実に得るには含有量を0.05%以上、0.5%以下とすることが好ましい。 The element V does not have to be added. Addition has the effect of improving the corrosion resistance of the product. However, if added in excess of 0.8%, coarse carbonitrides are formed, promoting the stacking and growth of the cutting edge, deteriorating the cutting surface properties and also deteriorating the tool life. For this reason, the upper limit is set to 0.8%. To reliably obtain the above effect, it is preferable for the content to be 0.05% or more and 0.5% or less.

Nb、Ti、Taの元素は添加しなくてもよい。添加すれば、製品の耐食性を向上させる効果を有する。しかしながら、0.5%を超えて添加すると、粗大な炭窒化物が形成して構成刃先の積層・成長を助長して切削表面性状が劣化し、工具寿命も劣化させる。そのため、上限を0.5%以下とする。上記効果を確実に得るには含有量を0.01%以上、0.4%以下とすることが好ましい。 The elements Nb, Ti, and Ta do not need to be added. Addition has the effect of improving the corrosion resistance of the product. However, if added in excess of 0.5%, coarse carbonitrides are formed, promoting stacking and growth of the cutting edge, deteriorating the cutting surface properties and also deteriorating the tool life. For this reason, the upper limit is set to 0.5% or less. To ensure the above effects, it is preferable to set the content to 0.01% or more and 0.4% or less.

Mg,Ca,Hfの元素は添加しなくてもよい。添加すれば熱間製造性を向上させる効果を有する。しかしながら、それぞれ0.010%を超えて添加しても、その効果は飽和するし、逆に粗大な酸化物を生成して切削表面性状を劣化させる。そのため、含有量を0.010%以下とする。上記効果を確実に得るには含有量を0.001%以上、0.005%以下とすることが好ましい。 The elements Mg, Ca, and Hf do not need to be added. If added, they have the effect of improving hot workability. However, if added in excess of 0.010% of each, the effect saturates, and conversely, coarse oxides are generated, deteriorating the cutting surface properties. For this reason, the content is set to 0.010% or less. To ensure the above effects, it is preferable to set the content to 0.001% or more and 0.005% or less.

REMの元素は添加しなくてもよい。添加すれば熱間製造性を向上させる効果を有する。しかしながら、0.050%を超えて添加しても、その効果は飽和するし、逆に粗大な酸化物を生成して切削表面性状を劣化さえる。そのため、含有量を0.050%以下とする。上記効果を確実に得るには含有量を0.001%以上、0.005%以下とすることが好ましい。REM(希土類元素)は、一般的な定義に従い、スカンジウム(Sc)、イットリウム(Y)の2元素と、ランタン(La)からルテチウム(Lu)までの15元素(ランタノイド)の総称を指す。単独で含有させてもよいし、混合物であってもよい。 REM elements do not have to be added. If they are added, they have the effect of improving hot workability. However, if they are added in excess of 0.050%, the effect saturates, and conversely, coarse oxides are generated, deteriorating the cutting surface properties. Therefore, the content is set to 0.050% or less. To ensure the above effect, it is preferable to set the content to 0.001% or more and 0.005% or less. REM (rare earth elements) is a general term for two elements, scandium (Sc) and yttrium (Y), and 15 elements (lanthanoids) from lanthanum (La) to lutetium (Lu), according to the general definition. They may be added alone or as a mixture.

本発明のステンレス鋼が含有する不純物について、代表的な不純物としては、Zn、Pb、Ge、Se、Ag、Se等が挙げられ、通常、鉄鋼の製造プロセスで不純物として、0.1%程度の範囲で混入する。 Typical impurities contained in the stainless steel of the present invention include Zn, Pb, Ge, Se, Ag, Se, etc., and are usually mixed in at about 0.1% as impurities during the steel manufacturing process.

不純物である酸素は鋼中で主に介在物として存在するが、通常の精錬で製造されるステンレス鋼の酸素含有レベルは0.001~0.015%である。 The impurity oxygen exists mainly as inclusions in steel, but the oxygen content of stainless steel produced by conventional refining is between 0.001 and 0.015%.

また、任意添加元素について、代表的なものを上記(2)~(5)で規定しているが、本明細書中に記載されていない元素であっても、本発明の効果を損なわない範囲で含有させることができる。 Regarding optional elements, representative ones are specified in (2) to (5) above, but elements not listed in this specification can also be included within the range that does not impair the effects of the present invention.

《フェライト系ステンレス鋼の製造方法》
本発明のフェライト系ステンレス鋼の製造方法について説明する。
<<Method for producing ferritic stainless steel>>
A method for producing the ferritic stainless steel of the present invention will now be described.

0.5μmサイズ以下のBNを100μm2中に20個以上の数密度で微細分散させるためには、上述した成分を有する鋳片を1150~1330℃に一旦高温加熱して、熱間圧延や熱間加工を行ってBNを固溶させた後に、得られた鋼材(線材や鋼線等)に700~900℃で60~300分保定するバッチ焼鈍を施す。 In order to finely disperse BN particles of 0.5 μm or less in size at a number density of 20 or more particles per 100 μm2, a cast piece having the above-mentioned components is once heated to a high temperature of 1150 to 1330°C, and then hot-rolled or hot-worked to dissolve the BN. The resulting steel material (wire material, steel wire, etc.) is then subjected to batch annealing at 700 to 900°C for 60 to 300 minutes.

鋳片の加熱温度が1150℃未満ではBNが固溶せずに上述の数密度を満たさなくなり、1330℃を超えると製造性が劣化する。そのため、加熱温度を1150~1330℃、さらにBNの固溶の観点から1250℃超、1320℃以下とする。 If the heating temperature of the slab is less than 1150°C, the BN will not dissolve and the number density mentioned above will not be met, and if it exceeds 1330°C, manufacturability will deteriorate. Therefore, the heating temperature should be 1150 to 1330°C, and from the viewpoint of dissolving BN, it should be greater than 1250°C and less than 1320°C.

また、バッチ焼鈍温度が700℃よりも低く、60分よりも短時間であるとBN析出量が減少して上述の数密度を満たさなくなる。一方、バッチ焼鈍温度が900℃よりも高く、300分よりも長時間であるとBNサイズが粗大化することで上述の数密度を満たさなくなる。そのため、バッチ焼鈍条件を700~900℃で60~300分保定、好ましくは100~250分保定に限定する。 In addition, if the batch annealing temperature is lower than 700°C and the time is shorter than 60 minutes, the amount of BN precipitation will decrease and the above-mentioned number density will not be met. On the other hand, if the batch annealing temperature is higher than 900°C and the time is longer than 300 minutes, the BN size will become coarse and the above-mentioned number density will not be met. Therefore, the batch annealing conditions are limited to 700 to 900°C and holding for 60 to 300 minutes, preferably 100 to 250 minutes.

上記BNの分散状態を保ったままでフェライト中の固溶N量を確保するためには、前記のバッチ焼鈍の後に、700~900℃の温度域で保定し、500℃以上の温度範囲を1℃/s以上の冷却速度で冷却するストランド焼鈍を施す。 In order to ensure the amount of dissolved N in the ferrite while maintaining the above-mentioned BN dispersion state, after the batch annealing, strand annealing is performed in which the temperature is held in the 700-900°C range and cooled at a rate of 1°C/s or more in the temperature range of 500°C or higher.

通常のフェライト系ステンレス鋼の軟化焼鈍では、線材や鋼線等のコイル全体がバッチ焼鈍により約650~950℃の温度範囲で保定されて炉冷されるため、例えば0.02℃/sオーダーの冷却速度で徐冷される。高温で固溶していたNは徐冷中に窒化物として存在状態を変えるため、通常のバッチ焼鈍では固溶N量は0.01%未満になる。 In normal softening annealing of ferritic stainless steel, the entire coil of wire or steel wire is held at a temperature range of approximately 650 to 950°C by batch annealing and then cooled in the furnace, so it is slowly cooled, for example, at a cooling rate of the order of 0.02°C/s. N that was in solid solution at high temperatures changes its state to nitrides during slow cooling, so in normal batch annealing, the amount of solute N is less than 0.01%.

本発明において、前述の焼鈍後に、フェライト相のN固溶限が0.01~0.06%で、BNが固溶しない700~900℃の温度域で保定し、窒化物が形成する500℃以上の温度範囲を1℃/s以上で急冷するストランド焼鈍を施す。これにより、前記のBNの微細分散状態を保ったままフェライト相中のN固溶を0.01~0.06%に保持できる。 In the present invention, after the above-mentioned annealing, the temperature is held in the 700-900°C range where the N solid solubility limit in the ferrite phase is 0.01-0.06% and BN does not form a solid solution, and strand annealing is performed in which the temperature range of 500°C or higher where nitrides form is quenched at 1°C/s or more. This makes it possible to maintain the N solid solution in the ferrite phase at 0.01-0.06% while maintaining the fine dispersion state of the BN.

ストランド焼鈍とは、リング状に捲かれた線材や鋼線コイルを直線状に展開して1本の直線状態で短時間熱処理(窒素、Arやアンモニア分解ガス等の雰囲気中)し、空冷や間接空冷する焼鈍方法を言う。この方法によれば、リング状コイル全体のバッチ焼鈍に比べて冷却速度を著しく早くすることが可能である。 Strand annealing is an annealing method in which wire or steel coil wound in a ring shape is unrolled into a straight line, heat-treated in a single straight line for a short period of time (in an atmosphere of nitrogen, Ar, ammonia decomposition gas, etc.), and then air-cooled or indirectly air-cooled. This method makes it possible to achieve a significantly faster cooling rate than batch annealing of the entire ring-shaped coil.

この時、保定温度が700℃未満では固溶N量が0.01%よりも低くなり、900℃以上ではオーステナイト相が生成して冷却時に硬質なマルテンサイト組織が生成して、前述するような十分な切削性(切削表面性状,工具寿命)が得られない。そのため、ストランド焼鈍温度は700~900℃の範囲に限定する。好ましくは、750~850℃である。在炉時間は任意であるが、30~1000sの範囲が素材の熱変形もなく、均一に熱が入るので好ましい。 At this time, if the holding temperature is less than 700°C, the amount of solute N will be less than 0.01%, and if it is 900°C or higher, an austenite phase will form and a hard martensite structure will form during cooling, making it difficult to obtain sufficient machinability (cutting surface properties, tool life) as described above. Therefore, the strand annealing temperature is limited to the range of 700 to 900°C. It is preferably 750 to 850°C. The dwell time is arbitrary, but a range of 30 to 1000 seconds is preferable because it causes no thermal deformation of the material and allows heat to be applied uniformly.

また、前述のバッチ焼鈍とストランド焼鈍の工程間に冷間伸線加工等の加工が入っても差し支えない。バッチ焼鈍,ストランド焼鈍を複数回実施してもよいが、最後の熱処理はストランド焼鈍を行う必要がある。 In addition, there is no problem if cold wire drawing or other processing is performed between the batch annealing and strand annealing steps described above. Batch annealing and strand annealing may be performed multiple times, but the final heat treatment must be strand annealing.

以上説明したとおり、本発明によれば、精密切削加工される熱膨張率の小さい精密部品用として、切削加工時の表面切削表面性状を劣化さえる構成刃先の生成・成長を抑制できるフェライト系快削ステンレス鋼を提供できる。 As explained above, the present invention provides a ferritic free-cutting stainless steel that can suppress the formation and growth of built-up edges that deteriorate the cutting surface properties during cutting, and is used for precision parts with a small thermal expansion coefficient that are precision cut.

(実施例1)
65kgの真空溶解炉にて表1及び表2に示す化学組成の鋼を1600℃で溶解した後、鋳型に鋳造した。その後、1200℃加熱後にφ9mmの線材に熱間加工して850℃で120分のバッチ焼鈍を施し、φ6.3mmに冷間伸線を行い、850℃で200s保定のストランド焼鈍(アンモニア分解ガス中)を施した。その後、φ6.0mmに抽伸機で磨棒に仕上げ切削用の素材とした。
Example 1
Steels having the chemical compositions shown in Tables 1 and 2 were melted at 1600°C in a 65 kg vacuum melting furnace and then cast into a mold. After heating to 1200°C, the steels were hot worked into wires having a diameter of 9 mm, batch annealed at 850°C for 120 minutes, cold drawn to a diameter of 6.3 mm, and strand annealed at 850°C for 200 seconds (in ammonia decomposition gas). The wires were then drawn into polished bars having a diameter of 6.0 mm using a drawing machine to prepare materials for cutting.

Figure 0007668657000001
Figure 0007668657000001

Figure 0007668657000002
Figure 0007668657000002

このようにして得られた棒材について、以下に示す評価方法により、BN化合物の数密度(単位面積当たりの個数)、外周切削後の表面性状及び工具寿命について評価を実施した。その結果を表3及び表4に示す。表3は本発明鋼の評価結果、表4は比較鋼の評価結果である。 The bars thus obtained were evaluated for the number density of BN compounds (number per unit area), surface properties after peripheral cutting, and tool life using the evaluation methods described below. The results are shown in Tables 3 and 4. Table 3 shows the evaluation results for the steel of the present invention, and Table 4 shows the evaluation results for the comparative steel.

Figure 0007668657000003
Figure 0007668657000003

Figure 0007668657000004
Figure 0007668657000004

「金属間化合物(BN化合物)」
樹脂に埋め込み、鏡面研磨を行った棒線の縦断面をアルコール系腐食液で析出物を電解抽出した後にカーボン蒸着によりレプリカ試料を作製し、その後、透過型電子顕微鏡にて析出物のサイズと分布を調査した。100μm2の面積を5視野観察し、長径が0.5μm以下のBN化合物の100μm2中の数密度を求めた。
"Intermetallic compound (BN compound)"
The longitudinal section of the rod was embedded in resin and mirror-polished, and the precipitates were extracted electrolytically with an alcohol-based etchant, and then a replica sample was made by carbon deposition. The size and distribution of the precipitates were then examined using a transmission electron microscope. Five fields of view were observed over an area of 100 μm2 , and the number density of BN compounds with a major axis of 0.5 μm or less per 100 μm2 was determined.

「切削表面性状」
使用工具:超硬P種、刃先R0.4mm,切削速度:50m/min,送り量:0.02mm/rev.,切込み:0.1mm,切削油(鉱物油):有りの送り量が0.05mm/rev.以下の精密切削加工の条件で、棒線の外周を周方向に切削加工し、切削加工後の表面について、100倍の拡大鏡にて観察して明確な構成刃先痕の有無で評価した。明確な構成刃先痕が認められる場合を×、微小な構成刃先婚が散見される場合を〇、明確に認められない場合を◎として評価した。
"Cutting surface properties"
Tool used: Carbide P type, cutting edge R 0.4 mm, cutting speed: 50 m/min, feed rate: 0.02 mm/rev., depth of cut: 0.1 mm, cutting oil (mineral oil): with feed rate of 0.05 mm/rev. Under the following precision cutting conditions, the outer circumference of the wire rod was cut in the circumferential direction, and the surface after cutting was observed with a 100x magnifying glass and evaluated for the presence or absence of clear built-up edge marks. When clear built-up edge marks were observed, they were evaluated as ×, when minute built-up edge marks were observed, they were evaluated as ◯, and when they were not clearly observed, they were evaluated as ◎.

「工具寿命」
使用工具:超硬P種、刃先R0.4mm,切削速度:200m/min,送り量:0.02mm/rev.,切込み:0.11mm,切削油(鉱物油):有りの送り量が005mm/rev.以下,切込み≦0.3mmの精密切削加工の条件で、棒線の外周を周方向に切削加工し、30分間切削加工した使用後の工具の状態を調べた。使用後の工具のフランク摩耗量が境界摩耗,編摩耗を含めて20μm以下であれば◎、20μm超、50μm以下であれば○、50μm超の場合は×と評価した。
"Tool life"
Tool used: Carbide P type, cutting edge R 0.4 mm, cutting speed: 200 m/min, feed rate: 0.02 mm/rev., depth of cut: 0.11 mm, cutting oil (mineral oil): with feed rate of 0.05 mm/rev. The outer circumference of the wire rod was cut in the circumferential direction under the precision cutting conditions of a depth of cut ≦ 0.3 mm, and the condition of the tool after cutting for 30 minutes was examined. If the flank wear amount of the tool after use, including boundary wear and knitting wear, was 20 μm or less, it was evaluated as ◎, if it was more than 20 μm and less than 50 μm, it was evaluated as ○, and if it was more than 50 μm, it was evaluated as ×.

「固溶N量」
素材1gを無水マレイン酸中で電解して0.2μmメッシュのろ紙により析出物を抽出し、その後、抽出物を酸液で溶解後に原子吸光により析出物中の窒化物として析出しているN量を求め、鋼材のトータル窒素量から析出物中のN量を差し引いて、固溶N量を求めた。
"Solute N content"
1 g of the material was electrolyzed in maleic anhydride, and the precipitate was extracted using 0.2 μm mesh filter paper. The extract was then dissolved in an acid solution and the amount of N precipitated as nitrides in the precipitate was determined by atomic absorption spectrometry. The amount of dissolved N was calculated by subtracting the amount of N in the precipitate from the total nitrogen amount in the steel material.

表3の本発明例1~43は、長径0.5μm以下のBNの数密度が100μm2中20個以上、固溶N量が0.01~0.06%であり、いずれも優れた切削表面性状や工具寿命を示す。 Inventive Examples 1 to 43 in Table 3, the number density of BN with a major axis of 0.5 μm or less is 20 or more per 100 μm2 , the amount of solute N is 0.01 to 0.06%, and all of them show excellent cutting surface properties and tool life.

一方、表4の比較例1~9、11~33は、本発明の成分範囲,BNの数密度範囲、固溶N量範囲から外れており、優れた切削表面性状と工具寿命のすべてを満足することができなかった。比較例10は、Cr量が少なく、BNの数密度範囲、素材硬さ範囲、固溶N量範囲は本発明の範囲内であり、切削表面性状と工具寿命も優れていたが、耐食性が不足した。 On the other hand, Comparative Examples 1 to 9 and 11 to 33 in Table 4 are outside the composition range, BN number density range, and solute N amount range of the present invention, and were unable to satisfy all of the excellent cutting surface properties and tool life. Comparative Example 10 had a low Cr content, and the BN number density range, material hardness range, and solute N amount range were within the range of the present invention, and the cutting surface properties and tool life were excellent, but the corrosion resistance was insufficient.

(実施例2)
65kgの真空溶解炉にて1600℃で溶解、鋳型に鋳造した鋼Aについて、1100~1360℃加熱後にφ9mmの線材に熱間加工して650~1000℃で30~500分の軟化焼鈍を施し、φ6.3mmに冷間伸線を行い、650~950℃で30~1500s保定のストランド焼鈍(アンモニア分解ガス中)を施した。その後、φ6.0mmに抽伸機で磨棒に仕上げ切削用の素材とした。その後、BN化合物の数密度(単位面積当たりの個数),外周切削後の表面性状及び工具寿命ついて評価を実施した。その結果を表5に示す。
Example 2
Steel A was melted at 1600°C in a 65 kg vacuum melting furnace and cast into a mold. After heating to 1100-1360°C, it was hot worked into a wire rod of φ9 mm, softened at 650-1000°C for 30-500 minutes, cold drawn to φ6.3 mm, and strand annealed at 650-950°C for 30-1500 seconds (in ammonia decomposition gas). Then, it was drawn into a polished bar of φ6.0 mm using a drawing machine to prepare a material for finish cutting. Then, the number density (number per unit area) of the BN compound, the surface properties after peripheral cutting, and the tool life were evaluated. The results are shown in Table 5.

Figure 0007668657000005
Figure 0007668657000005

表5の本発明例44~51は、長径0.5μm以下のBNの数密度が100μm2中20個以上、固溶N量が0.01~0.06%であり、いずれも優れた切削表面性状や工具寿命を示した。 Inventive Examples 44 to 51 in Table 5, the number density of BN with a major axis of 0.5 μm or less was 20 or more per 100 μm2 , and the amount of solute N was 0.01 to 0.06%, and all of them showed excellent cutting surface properties and tool life.

一方、表5の比較例34~41は、本発明の成分範囲,BNの数密度範囲,固溶N量範囲から外れており、優れた切削表面性状と工具寿命のすべてを満足することができなかった。 On the other hand, Comparative Examples 34 to 41 in Table 5 are outside the composition range, BN number density range, and solute N content range of the present invention, and were unable to satisfy both excellent cutting surface properties and tool life.

以上の各実施例から明らかなように、本発明により、精密切削加工時の優れた平坦度を有する切削表面性状と工具寿命を有するフェライト系快削ステンレス鋼を提供することができ、熱膨張率が小さい精密部品の腐食の厳しい環境下での耐久性を大幅に向上することができ、産業上極めて有用である。 As is clear from the above examples, the present invention can provide a ferritic free-cutting stainless steel that has excellent cutting surface properties with excellent flatness during precision cutting and tool life, and can significantly improve the durability of precision parts with a small thermal expansion coefficient in severe corrosive environments, making it extremely useful in industry.

Claims (6)

質量%で、
C :0.10%未満、
Si:0.1~2.0%、
Mn:0.1~3.0%、
S:0.02~0.40%、
P :0.10%以下、
Cr:13.0~22.0%、
B :0.001~0.01%、
N :0.015~0.08%、
Al:0.008%以下、及び
O :0.015%以下
を含有し、残部がFe及び不純物からなる化学成分を有し、
固溶N量が0.010~0.060%であり、
0.5μm以下のBN系金属間化合物が100μm2中に20個以上ある
ことを特徴とするフェライト系快削ステンレス鋼であって、
前記フェライト系快削ステンレス鋼からなるφ6.0mmの棒線の外周を、
使用工具:超硬P種、刃先R0.4mm,切削速度:50m/min,送り量:0.02mm/rev.,切込み:0.1mm,切削油(鉱物油):有り
の精密切削加工の条件で、周方向に切削加工し、切削加工後の表面について、100倍の拡大鏡にて観察した場合、明確な構成刃先痕が認められず、
前記フェライト系快削ステンレス鋼からなるφ6.0mmの棒線の外周を、
使用工具:超硬P種、刃先R0.4mm、切削速度:200m/min、送り量:0.02mm/rev.、切込み:0.11mm,切削油(鉱物油):有り
の精密切削加工の条件で、周方向に切削加工し、30分間切削加工した使用後の工具のフランク摩耗量が境界摩耗,編摩耗を含めて50μm以下である
ことを特徴とするフェライト系快削ステンレス鋼
In mass percent,
C: less than 0.10%,
Si: 0.1-2.0%,
Mn: 0.1 to 3.0%,
S: 0.02-0.40%,
P: 0.10% or less,
Cr: 13.0-22.0%,
B: 0.001-0.01%,
N: 0.015-0.08%,
Al: 0.008% or less; O: 0.015% or less; and the balance being Fe and impurities.
The amount of solute N is 0.010 to 0.060%;
A ferritic free-cutting stainless steel characterized in that there are 20 or more BN-based intermetallic compounds of 0.5 μm or less per 100 μm2 ,
The outer periphery of the φ6.0 mm wire rod made of the ferritic free-cutting stainless steel is
Tool used: Carbide P type, cutting edge R0.4 mm, cutting speed: 50 m/min, feed rate: 0.02 mm/rev., cutting depth: 0.1 mm, cutting oil (mineral oil): yes
When the cutting process was performed in the circumferential direction under the precision cutting process conditions, and the surface after cutting was observed with a 100x magnifying glass, no clear cutting edge marks were observed.
The outer periphery of the φ6.0 mm wire rod made of the ferritic free-cutting stainless steel is
Tool used: Carbide P type, cutting edge R0.4 mm, cutting speed: 200 m/min, feed rate: 0.02 mm/rev., cutting depth: 0.11 mm, cutting oil (mineral oil): yes
The tool is cut in the circumferential direction under the precision cutting conditions, and the flank wear amount of the tool after cutting for 30 minutes is 50 μm or less, including boundary wear and knot wear.
The present invention relates to a ferritic free-cutting stainless steel .
前記Feの一部に変えて、さらに質量%で、
Ni:1.5%以下、
Mo:2.5%以下、
Cu:1.5%以下、
Co:1.5%以下、及び
W :2.5%以下
の内、1種類以上を含有する
ことを特徴とする請求項1に記載のフェライト系快削ステンレス鋼。
A part of the Fe is replaced with further mass%
Ni: 1.5% or less,
Mo: 2.5% or less,
Cu: 1.5% or less,
The ferritic free-cutting stainless steel according to claim 1, further comprising at least one of Co: 1.5% or less and W: 2.5% or less.
前記Feの一部に変えて、さらに質量%で、
Bi:0.20%以下、
Sn:0.30%以下、
Sb:0.30%以下、
Ag:0.30%以下、及び
Te:0.10%以下
の内、1種類以上を含有する
ことを特徴とする請求項1又は請求項2に記載のフェライト系快削ステンレス鋼。
A part of the Fe is replaced with further mass%
Bi: 0.20% or less,
Sn: 0.30% or less,
Sb: 0.30% or less,
The ferritic free-cutting stainless steel according to claim 1 or 2, further comprising at least one of Ag: 0.30% or less, and Te: 0.10% or less.
前記Feの一部に変えて、さらに質量%で、
V :0.8%以下、
Nb:0.5%以下、
Ti:0.5%以下、及び
Ta:0.5%以下
の内、1種類以上を含有する
ことを特徴とする請求項1~3のいずれか1項に記載のフェライト系快削ステンレス鋼。
A part of the Fe is replaced with further mass%
V: 0.8% or less,
Nb: 0.5% or less,
The ferritic free-cutting stainless steel according to any one of claims 1 to 3, characterized in that it contains one or more of Ti: 0.5% or less, and Ta: 0.5% or less.
前記Feの一部に変えて、さらに質量%で、
Mg:0.010%以下、
Ca:0.010%以下、
Hf:0.010%以下、及び
REM:0.050%以下
の内、1種類以上を含有する
ことを特徴とする請求項1~4のいずれか1項に記載のフェライト系快削ステンレス鋼。
A part of the Fe is replaced with further mass%
Mg: 0.010% or less,
Ca: 0.010% or less,
The ferritic free-cutting stainless steel according to any one of claims 1 to 4, characterized in that it contains one or more of Hf: 0.010% or less, and REM: 0.050% or less.
請求項1~5のいずれか1項に記載のフェライト系快削ステンレス鋼を製造する方法であって、
請求項1~5のいずれか1項に記載の化学成分を有する鋳片を1150~1330℃に加熱する加熱工程、
加熱した上記鋳片に熱間圧延又は熱間加工を施す加工工程、
700~900℃で60~300分保定するバッチ焼鈍工程、
700~900℃の温度域で保定し、1℃/s以上の冷却速度で冷却するストランド焼鈍
を備えることを特徴とする本発明のフェライト系快削ステンレス鋼の製造方法。
A method for producing the ferritic free-cutting stainless steel according to any one of claims 1 to 5, comprising the steps of:
A heating step of heating a slab having the chemical composition according to any one of claims 1 to 5 to 1150 to 1330 ° C.;
a processing step of subjecting the heated cast piece to hot rolling or hot working;
A batch annealing process at 700 to 900°C for 60 to 300 minutes.
The method for producing the ferritic free-cutting stainless steel of the present invention is characterized by comprising strand annealing in which the temperature is maintained in the range of 700 to 900°C and cooled at a cooling rate of 1°C/s or more.
JP2021041271A 2021-03-15 2021-03-15 Ferritic free-cutting stainless steel with excellent precision cutting properties Active JP7668657B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2021041271A JP7668657B2 (en) 2021-03-15 2021-03-15 Ferritic free-cutting stainless steel with excellent precision cutting properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2021041271A JP7668657B2 (en) 2021-03-15 2021-03-15 Ferritic free-cutting stainless steel with excellent precision cutting properties

Publications (2)

Publication Number Publication Date
JP2022141117A JP2022141117A (en) 2022-09-29
JP7668657B2 true JP7668657B2 (en) 2025-04-25

Family

ID=83402938

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2021041271A Active JP7668657B2 (en) 2021-03-15 2021-03-15 Ferritic free-cutting stainless steel with excellent precision cutting properties

Country Status (1)

Country Link
JP (1) JP7668657B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4509634A3 (en) * 2023-08-07 2025-12-10 Daido Steel Co., Ltd. Ferritic free-cutting stainless steel
CN118441219B (en) * 2024-04-30 2025-06-24 北京科技大学 Free-cutting ferrite stainless steel and preparation method and application thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080279712A1 (en) 2007-05-11 2008-11-13 Manabu Oku Ferritic stainless steel sheet with excellent thermal fatigue properties, and automotive exhaust-gas path member
JP2012140666A (en) 2010-12-28 2012-07-26 Toshiba Corp Forging heat resistant steel, manufacturing method thereof, forged parts and manufacturing method thereof
JP2012201929A (en) 2011-03-25 2012-10-22 Nippon Steel & Sumikin Stainless Steel Corp Stainless steel wire material and steel wire excellent in corrosion resistance, strength, ductility, and method for producing the same
JP2013173966A (en) 2012-02-23 2013-09-05 Nippon Steel & Sumikin Stainless Steel Corp Ferritic free-cutting stainless steel wire rod and method for manufacturing the same
JP2013185195A (en) 2012-03-07 2013-09-19 Nippon Steel & Sumikin Stainless Steel Corp Free-cutting martensitic stainless steel rod wire and method for producing the same
CN103397257A (en) 2013-07-25 2013-11-20 张家港市胜达钢绳有限公司 Anti-corrosion steel wire
JP2018131670A (en) 2017-02-17 2018-08-23 新日鐵住金ステンレス株式会社 Ferritic free-cutting stainless steel wire
WO2019240209A1 (en) 2018-06-13 2019-12-19 日鉄ステンレス株式会社 Martensitic s free-cutting stainless steel

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080279712A1 (en) 2007-05-11 2008-11-13 Manabu Oku Ferritic stainless steel sheet with excellent thermal fatigue properties, and automotive exhaust-gas path member
JP2012140666A (en) 2010-12-28 2012-07-26 Toshiba Corp Forging heat resistant steel, manufacturing method thereof, forged parts and manufacturing method thereof
JP2012201929A (en) 2011-03-25 2012-10-22 Nippon Steel & Sumikin Stainless Steel Corp Stainless steel wire material and steel wire excellent in corrosion resistance, strength, ductility, and method for producing the same
JP2013173966A (en) 2012-02-23 2013-09-05 Nippon Steel & Sumikin Stainless Steel Corp Ferritic free-cutting stainless steel wire rod and method for manufacturing the same
JP2013185195A (en) 2012-03-07 2013-09-19 Nippon Steel & Sumikin Stainless Steel Corp Free-cutting martensitic stainless steel rod wire and method for producing the same
CN103397257A (en) 2013-07-25 2013-11-20 张家港市胜达钢绳有限公司 Anti-corrosion steel wire
JP2018131670A (en) 2017-02-17 2018-08-23 新日鐵住金ステンレス株式会社 Ferritic free-cutting stainless steel wire
WO2019240209A1 (en) 2018-06-13 2019-12-19 日鉄ステンレス株式会社 Martensitic s free-cutting stainless steel

Also Published As

Publication number Publication date
JP2022141117A (en) 2022-09-29

Similar Documents

Publication Publication Date Title
EP3112487B1 (en) Steel for induction hardening
JP7791491B2 (en) Martensitic free-cutting stainless steel bar and its manufacturing method
CN117396624B (en) Cold-rolled steel sheet, steel member, method for producing cold-rolled steel sheet, and method for producing steel member
JP7267702B2 (en) MARTENSITE STAINLESS STEEL BAR FOR HIGH HARDNESS AND HIGH CORROSION RESISTANCE WITH EXCELLENT COLD WORKABILITY AND METHOD FOR MANUFACTURING SAME
JP7464821B2 (en) Steel for bearing raceways and bearing raceways
JP7719344B2 (en) Martensitic free-cutting stainless steel with excellent precision cutting properties
JP2012246527A (en) Steel component for machine structure with high fatigue strength and high toughness, and method of manufacturing the same
JP6468365B2 (en) Steel, carburized steel parts, and method of manufacturing carburized steel parts
WO2018021452A1 (en) Steel for machine structures
WO2022153790A1 (en) Martensite-based stainless steel material and method for producing same
JP6760375B2 (en) Machine structural steel
JP7668657B2 (en) Ferritic free-cutting stainless steel with excellent precision cutting properties
JP2008127594A (en) High strength hot forged non-heat treated steel component having excellent fatigue limit ratio
JP5370073B2 (en) Alloy steel for machine structural use
JP7560714B2 (en) Steel bars for machine structures
JP4793298B2 (en) Non-tempered steel and manufacturing method thereof
JP5459197B2 (en) Alloy steel for machine structural use
JP2022122483A (en) Hot rolled steel sheet and method for producing the same
JP5443277B2 (en) High-strength steel with excellent machinability and method for producing the same
JP2018035423A (en) Carburizing steel, carburized steel parts, and method of manufacturing carburized steel parts
JP3255611B2 (en) Free-cutting steel rod and wire excellent in drilling workability and method for producing the same
JP4765679B2 (en) Ferritic free-cutting stainless steel
JP5937852B2 (en) Case-hardening steel parts
JP2018035420A (en) Carburizing steel, carburized steel parts, and method of manufacturing carburized steel parts
JP2018035419A (en) Steel for carburization, carburization steel member and manufacturing method of carburization steel member

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20231114

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20241016

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20241022

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20241223

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20250318

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20250415

R150 Certificate of patent or registration of utility model

Ref document number: 7668657

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350