JP7700461B2 - Electromagnetic wave absorbing particles, electromagnetic wave absorbing particle dispersion, electromagnetic wave absorbing particle dispersion, electromagnetic wave absorbing laminate - Google Patents

Description

The present invention relates to electromagnetic wave absorbing particles, electromagnetic wave absorbing particle dispersions, electromagnetic wave absorbing particle dispersions, and electromagnetic wave absorbing laminates.

According to the 5th edition of the Physics and Chemistry Dictionary, "Electromagnetic waves with wavelengths in the range of approximately 1 nm to 1 mm are called light." This wavelength range includes the visible light and infrared regions.

Near-infrared rays contained in sunlight penetrate window materials and other materials and enter indoor spaces, raising the surface temperature of the walls and floors inside the room and causing the indoor air temperature to rise. In order to create a comfortable indoor thermal environment, it has been customary to use light-shielding materials in window materials and other materials to block the near-infrared rays that enter through the windows and prevent the indoor air temperature from rising.

Patent Document 1 proposes a light-shielding film containing black fine powder including inorganic pigments such as carbon black and titanium black, and organic pigments such as aniline black, as a light-shielding material for use in window materials, etc.

Patent document 2 discloses a thermal insulation sheet made of a woven fabric in which a strip-shaped film having infrared reflectivity and a strip-shaped film having infrared absorbing properties are used as the warp and weft, respectively. It also describes the use of a synthetic resin film that has been subjected to aluminum deposition processing and further laminated with a synthetic resin film as the strip-shaped film having infrared reflectivity.

In Patent Document 3, the applicant proposed infrared absorbing microparticles of antimony-containing tin oxide (ATO), an infrared absorbing microparticle dispersion liquid using the infrared absorbing microparticles, an infrared absorbing microparticle dispersion, an infrared absorbing laminated transparent substrate, an infrared absorbing film, and an infrared absorbing glass, as well as a manufacturing method thereof. The infrared absorbing microparticles of ATO, etc., had excellent solar radiation shielding properties, i.e., visible light transparency and infrared shielding properties.

JP 2003-029314 A Japanese Patent Application Publication No. 9-107815 International Publication No. 2017/057110

In recent years, electromagnetic wave absorbing particles capable of absorbing infrared and other electromagnetic waves have come to be used for a variety of purposes, and new electromagnetic wave absorbing particles are being sought so that the optimum material can be selected according to the application.

Therefore, one aspect of the present invention aims to provide novel electromagnetic wave absorbing particles.

In one aspect of the present invention, there is provided an electromagnetic wave absorbing particle containing a complex oxide,
The composite oxide includes an element A, which is one or more elements selected from H, an alkali metal, Mg, and an alkaline earth metal;
B element, which is one or more elements selected from Cr and Mo, and oxygen,
When the amount of substance of the element A contained in the composite oxide is x and the amount of substance of the element B is y, the relationship of 0.001≦x/y≦1.5 is satisfied ,
The present invention provides electromagnetic wave absorbing particles that absorb near infrared rays and have a volume-based cumulative 50% particle size of 1 nm or more and 50 nm or less, and a cumulative 95% particle size of 5 nm or more and 100 nm or less, as measured by a particle size distribution measuring device.

One aspect of the present invention provides novel electromagnetic wave absorbing particles.

The following will be described in detail in the following order: [1] electromagnetic wave absorbing particles, [2] manufacturing method for electromagnetic wave absorbing particles, [3] electromagnetic wave absorbing particle dispersion, [4] electromagnetic wave absorbing particle dispersion, and [5] electromagnetic wave absorbing laminate.

[1] Electromagnetic wave absorbing particles The inventors of the present invention have conducted research into novel electromagnetic wave absorbing particles. The type of electromagnetic wave absorbed by the electromagnetic wave absorbing particles is not particularly limited, but as described above, electromagnetic wave absorbing particles that absorb infrared rays and near infrared rays are particularly desired. Therefore, the electromagnetic wave absorbing particles of this embodiment are preferably infrared absorbing particles that absorb infrared rays, and more preferably near infrared absorbing particles that absorb near infrared rays.

In examining new electromagnetic wave absorbing particles, the inventors of the present invention focused on oxides of group 6 elements. However, since there are no effective free electrons or holes in the pentoxides of group 6 elements (CrO ₃ , MoO ₃ ), they have little absorption and reflection characteristics in the infrared region and are not effective as infrared absorbing materials. However, when a composite oxide is made by adding an electropositive element to the above oxide, free electrons or holes are generated in the composite oxide, and absorption characteristics derived from the free electrons or holes are expressed in the infrared region. Therefore, it was found that new electromagnetic wave absorbing particles can be made.

Furthermore, the inventors of the present invention have found that there is a specific range of the composition of the complex oxide that is particularly effective as an electromagnetic wave absorbing particle. Specifically, they have found that by setting the composition range of the complex oxide to a specific range, the complex oxide is transparent in the visible light region and absorbs in the infrared region, and have completed the present invention.
(Composition of the composite oxide)
The electromagnetic wave absorbing particle of the present embodiment may contain a composite oxide, which may contain an element A which is one or more elements selected from H, an alkali metal, Mg, and an alkaline earth metal, and an element B which is one or more elements selected from Cr (chromium) and Mo (molybdenum).

When the amount of substance of element A contained in the composite oxide is x and the amount of substance of element B contained in the composite oxide is y, it is preferable that the relationship 0.001≦x/y≦1.5 is satisfied.

The electromagnetic wave absorbing particles of this embodiment may be composed only of the above-mentioned composite oxide. However, even in this case, this does not exclude the case where the electromagnetic wave absorbing particles of this embodiment contain unavoidable impurities that are mixed in during the manufacturing process, etc.

As mentioned above, by adding an element A, which is a positive element, to an oxide containing an element B to form the above composite oxide, it is possible to exhibit electromagnetic wave absorption properties. As mentioned above, the element A is preferably one or more elements selected from H, alkali metals, Mg, and alkaline earth metals. In particular, from the viewpoint of improving the stability of the above composite oxide, the element A is preferably one or more elements selected from alkaline earth metals, i.e., Ca, Sr, Ba, and Ra, and more preferably one or more elements selected from Ca, Sr, and Ba.

As described above, the B element can be one or more elements selected from Cr and Mo, and is preferably Mo.

As for the value of x/y, which indicates the content ratio of the substance amount of the A element to the B element in the complex oxide, if it is 0.001 or more as described above, a sufficient amount of free electrons or holes are generated in the complex oxide, and the desired electromagnetic wave absorption effect can be obtained. And, the higher the content of the A element, the greater the supply of free electrons and the higher the electromagnetic wave absorption efficiency, but the effect saturates at a value of x/y of about 1.5. Also, if the value of x/y is 1.5 or less, it is possible to avoid the generation of an impurity phase in the electromagnetic wave absorbing particles. For this reason, as described above, x/y is preferably 0.001≦x/y≦1.5, more preferably 0.5≦x/y≦1.2, even more preferably 0.8≦x/y≦1.1, and most preferably x/y=1.0.

The composite oxide can be expressed, for example, by the general formula A _x B _y O _z . In the general formula, A represents element A, B represents element B, and O represents oxygen. As shown in the general formula, the composite oxide is preferably composed of, for example, element A, element B, and oxygen.

As described above, by adding element A to an oxide containing element B, free electrons or holes are supplied to the composite oxide, and electromagnetic wave absorption properties can be exhibited, so the amount of oxygen contained in the composite oxide is not particularly limited. However, by setting the amount of oxygen within a specific range, the amount of free electrons or holes in the composite oxide can be set to a particularly suitable range from the viewpoint of enhancing the electromagnetic wave absorption properties. Therefore, z/y, which corresponds to the content ratio of oxygen to element B in terms of the substance amount in the composite oxide, is preferably 1.0<z/y≦5.0, more preferably 2.0<z/y≦4.0, and even more preferably 2.0<z/y≦3.0.

As described above, z/y corresponds to the content ratio of oxygen relative to the amount of B in the composite oxide, and is a value that affects the amount of oxygen deficiency or excess oxygen in the composite oxide. As described above, the amount of oxygen can also be used to control the amount of free electrons or holes in the composite oxide. For this reason, it is preferable to control the value of z/y according to the required electromagnetic wave absorption characteristics, etc. The value of z/y can be easily controlled by the synthesis conditions of the electromagnetic wave absorbing particles, etc.

In the above general formula A _x B _y O _z , x, y, and z preferably satisfy 0≦(2x+6y−2z)/y≦6, more preferably 1≦(2x+6y−2z)/y≦4.5, and even more preferably 1.5≦(2x+6y−2z)/y≦3.5. The above (2x+6y−2z)/y indicates a guideline for the excess or deficiency of electrons per B element, and when the above range is satisfied, a particularly high electromagnetic wave absorption effect can be exhibited.
(Crystal structure of complex oxide)
According to the study by the inventors of the present invention, when a complex oxide has any one of the crystal structures selected from cubic, tetragonal, and orthorhombic, the transmission of light in the visible light region is improved and the absorption of light in the infrared region is improved. However, in order to obtain the effect of improving the transmission of light in the visible light region and improving the absorption of light in the infrared region, it is sufficient that the complex oxide contains a unit structure of a cubic, tetragonal, or orthorhombic crystal structure, and the complex oxide may partially contain amorphous or other structures.

When x/y, which indicates the content ratio of the substance amount of the A element to the substance amount of the B element in the complex oxide, is 1.0, and z/y, which indicates the content ratio of the substance amount of oxygen to the substance amount of the B element in the complex oxide, is 3.0, the crystal structure of the complex oxide becomes a cubic perovskite structure. Specifically, SrMoO ₃ , BaMoO ₃ , etc. become cubic perovskite structures. With this as the basic structure, when the value of x/y is less than 1.0, it may become a cubic perovskite structure having a deficiency of the A element. In addition, when the value of z/y is less than 4.0, it may become a cubic perovskite structure having an oxygen deficiency. Furthermore, when the ABO ₃ block and the BO block are regularly stacked, it may become a tetragonal or orthorhombic crystal structure. In addition, when the value of z/y is greater than 3.0 and less than 3.5, planar lattice defects may be inserted into the cubic perovskite structure, resulting in a tetragonal or orthorhombic crystal structure.

Electromagnetic wave absorbing particles are often required to have a material that has high electromagnetic wave absorption in the infrared region and low electromagnetic wave absorption in the visible light region, but since the performance required differs depending on the application, it is not possible to determine which of the above crystal structures is preferable.

The absorption wavelength of the electromagnetic wave absorbing particles of this embodiment is often around 780 nm, which is the border between the visible light region and the infrared light region. However, depending on the crystal structure of the complex oxide contained and the presence or absence of element deficiency, the electromagnetic wave absorption wavelength may shift to the short wavelength side or electromagnetic wave absorption may increase, resulting in a decrease in visible light transparency.

As such, the relationship between the crystal structure and the electromagnetic wave absorption characteristics changes depending on the composition of the complex oxide, so the crystal structure of the complex oxide contained in the electromagnetic wave absorbing particles of this embodiment is not particularly limited and can be selected depending on the composition of the complex oxide, the required electromagnetic wave absorption characteristics, etc.
(Particle characteristics of electromagnetic wave absorbing particles)
The particle characteristics such as particle diameter of the electromagnetic wave absorbing particles of this embodiment are not particularly limited, and can be selected arbitrarily depending on the required electromagnetic wave absorbing characteristics, etc.

The electromagnetic wave absorbing particles of this embodiment preferably have a volume-based cumulative 50% particle diameter of 1 nm or more and 50 nm or less, and a cumulative 95% particle diameter of 5 nm or more and 100 nm or less, as measured by a particle size distribution measuring device.

In general, materials containing free electrons or holes are known to show a reflection/absorption response to electromagnetic waves around the range of sunlight with wavelengths of 200 nm to 2600 nm due to plasma oscillations. It is also known that when powder particles of such materials are made smaller than the wavelength of light, geometric scattering in the visible light range (wavelengths of 380 nm to 780 nm) is reduced, resulting in transparency in the visible light range.

In this specification, "transparency" is used to mean "high transmittance with little scattering of light in the visible light range."

Therefore, when the electromagnetic wave absorbing particles of this embodiment are used in applications requiring transparency in the visible light region, it is preferable that the volume-based cumulative 95% particle diameter measured by a particle size distribution measuring device is 100 nm or less. This is because particles with a cumulative 95% particle diameter of 100 nm or less do not completely block light due to scattering, and can maintain visibility in the visible light region while at the same time efficiently maintaining transparency. In particular, when transparency in the visible light region is important, it is preferable to further consider scattering by the particles.

When further reduction in scattering by the electromagnetic wave absorbing particles is required, the cumulative 95% particle size is more preferably 70 nm or less, and even more preferably 50 nm or less. If the particle size of the electromagnetic wave absorbing particles is small, scattering of light in the visible light region with wavelengths of 400 nm to 780 nm is reduced due to geometric scattering or Mie scattering. For this reason, by setting the cumulative 95% particle size of the electromagnetic wave absorbing particles to the above range, it is possible to more reliably prevent, for example, an electromagnetic wave absorbing particle dispersion using the electromagnetic wave absorbing particles from becoming like cloudy glass and losing clear transparency. When the cumulative 95% particle size is 70 nm or less, the geometric scattering or Mie scattering is reduced, and the Rayleigh scattering region is reached. In the Rayleigh scattering region, scattered light is proportional to the sixth power of the particle size, so that scattering is reduced and transparency is improved as the particle size decreases.

Furthermore, if the cumulative 95% particle diameter is 50 nm or less, scattered light becomes very small, which is preferable. From the viewpoint of avoiding light scattering, it is preferable that the cumulative 95% particle diameter is small, so the lower limit of the cumulative 95% particle diameter is not particularly limited, but it is preferable that the cumulative 95% particle diameter is 5 nm or more. This is because industrial production is easy if the cumulative 95% particle diameter is 5 nm or more.

As explained above, by setting the cumulative 95% particle size to 100 nm or less, for example, the haze value of an electromagnetic wave absorbing particle dispersion in which the electromagnetic wave absorbing particles of this embodiment are dispersed in a solid medium can be set to 30% or less with a visible light transmittance of 85% or less. By setting the haze to 30% or less, particularly clear transparency can be obtained.

From the viewpoint of obtaining particularly excellent electromagnetic wave absorption properties, it is preferable that the cumulative 50% particle diameter of the volume-based electromagnetic wave absorbing particles measured by a particle size distribution measuring device is 1 nm or more. However, from the viewpoint of increasing transparency in the visible light region, for the same reason as the cumulative 95% particle diameter, it is preferable that the cumulative 50% particle diameter is 50 nm or less.

The cumulative 50% particle size and cumulative 95% particle size of electromagnetic wave absorbing particles can be measured using a particle size distribution measuring device (such as the UPA-150 manufactured by Nikkiso Co., Ltd.) based on the principle of dynamic light scattering method analyzed by frequency analysis.

Particle size distribution data is expressed as cumulative % or frequency % on a particle size scale, but conversely, it may be expressed as particle size on a cumulative % scale. For example, the particle size at the point where the distribution curve expressed as particle size on a cumulative % scale intersects with the horizontal axis of 10% is called cumulative 10% particle size, the particle size at the point where the distribution curve intersects with the horizontal axis of 50% is called cumulative 50% particle size, and the particle size at the point where the distribution curve intersects with the horizontal axis of 95% is called cumulative 95% particle size. It is not particularly fixed to 10%, 50%, or 95%, and any cumulative % is used as necessary. The 50% particle size is also called the median size and is very commonly used. When comparing the size of the particle size distribution of multiple samples, this median size is often used because it is necessary to represent the size of the measurement target with a single numerical value. For this reason, the median size is often confused with the average particle size, but the definitions are different and the two sizes do not usually match. These two diameters will only coincide if the particle size distribution is symmetric about the center (50% diameter).
[2] Manufacturing method of electromagnetic wave absorbing particles Next, a manufacturing method of the electromagnetic wave absorbing particles of this embodiment will be described. Since the electromagnetic wave absorbing particles already described can be manufactured by the manufacturing method of the electromagnetic wave absorbing particles of this embodiment, some of the matters already described will not be described.

The electromagnetic wave absorbing particles of this embodiment can be manufactured by a solid-state reaction method. When synthesizing by the solid-state reaction method, a compound of element A and a compound of element B can be used as raw materials.

The method for producing electromagnetic wave absorbing particles of this embodiment can include a mixed powder preparation step (first mixed powder preparation step) for preparing a mixed powder of an A element compound or an A element alone and a B element compound or an B element alone.

As the source of element A, an element A compound or element A alone can be used. The element A compound used as the raw material is preferably one or more selected from oxides, hydroxides, carbonates, nitrates, sulfates, oxalates, organic compounds, sulfides, and chlorides of element A.

Note that since the preferred A elements have already been explained, we will not repeat the explanation here.

The B element compound or element B as the B element source is preferably one or more selected from the group consisting of trioxide ( _CrO3 , _MoO3 ), dioxide ( _MoO2 ), sesquioxide ( _Cr2O3 ), elemental metal (Cr, _Mo ), hydroxide, carbonate, nitrate, sulfate, acetate, oxalate, ammonium salt, organic compound, sulfide, chloride, and oxide hydrate obtained by dissolving the chloride in a liquid such as alcohol, adding water to hydrolyze the solution, and evaporating the solvent. Note that suitable B elements have already been described, and therefore will not be described here.

In the mixed powder preparation process, the specific procedure for obtaining a mixed powder of an A element compound or an A element alone and a B element compound or an A element alone is not particularly limited. For example, a method of obtaining a mixed powder by dry-mixing the A element compound etc. and the B element compound etc. in a powder state can be mentioned. In addition, a mixed powder can also be obtained by dissolving the A element compound etc. in water, wet-mixing it with the B element compound etc., and then drying it.

In the mixed powder preparation process, it is preferable to mix the A element and the B element in the resulting mixed powder so that the ratio of the substance amount of the A element to the B element in the target composite oxide is the same as the ratio of the A element to the B element in the target composite oxide. In other words, it is preferable to mix them so that the ratio of the substance amount of the A element (A) to the substance amount of the B element (B) in the composite oxide, A:B = x:y, is satisfied. As described above, x and y are preferably 0.001 ≦ x/y ≦ 1.5, more preferably 0.5 ≦ x/y ≦ 1.2, even more preferably 0.8 ≦ x/y ≦ 1.1, and most preferably x/y = 1.0. For this reason, it is preferable to mix the A element compound and the B element compound so that the above-mentioned preferred range is satisfied.

The electromagnetic wave absorbing particles of this embodiment can also be synthesized in multiple stages to produce electromagnetic wave absorbing particles containing a complex oxide of the desired composition. In this case, in the first mixed powder preparation step, the A element compound and the B element compound, etc. can be mixed to obtain the composition of the intermediate product.

The method for producing electromagnetic wave absorbing particles of this embodiment can include a firing step (first firing step) for firing the mixed powder obtained in the mixed powder preparation step.

The conditions for the firing process are not particularly limited. In the firing process, for example, the mixed powder can be fired in any atmosphere selected from an inert gas atmosphere, a reducing gas atmosphere, a vacuum atmosphere, a mixed gas atmosphere of an inert gas and a reducing gas, and an oxidizing atmosphere containing oxygen.

For example, in the case of a composite oxide, when oxygen vacancies are introduced and z/y in the general formula described above is made smaller than the stoichiometric ratio, the firing atmosphere is preferably a mixed gas atmosphere of an inert gas and a reducing gas. The reducing gas is not particularly limited, but is preferably, for example, hydrogen gas. In addition, when hydrogen gas is used as the reducing gas, the volume ratio of hydrogen gas is preferably 1% or more, and more preferably 3% or more. There is no particular upper limit on the volume ratio of hydrogen gas, and since it can be reduced gas alone, it can be up to 100%.

The inert gas is not particularly limited, but one or more types selected from nitrogen gas, rare gases, etc. can be used.

The oxidizing atmosphere may be any atmosphere containing oxygen, for example, an atmosphere containing 18% to 100% oxygen by volume. For example, the atmosphere may be air.

The firing temperature conditions in the firing step are not particularly limited, but the firing temperature is preferably equal to or higher than the temperature at which the generated composite oxide begins to crystallize and equal to or lower than the melting point of the composite oxide. Specifically, for example, the firing temperature is preferably set to 1000°C or higher and 1700°C or lower.

The electromagnetic wave absorbing particles of this embodiment can be synthesized in multiple stages to obtain electromagnetic wave absorbing particles containing a complex oxide of the target composition. When synthesizing in multiple stages, a B element compound or a single B element can be added and mixed with the intermediate product obtained in the above-mentioned firing process (first firing process) (second mixed powder preparation process). The B element compound used in this case is not particularly limited, but for example, the compounds already described in the first mixed powder preparation process can be used. In the second mixed powder preparation process, it is preferable to mix the A element and the B element in the resulting mixed powder so that the ratio of the substance amounts of the A element and the B element is the ratio of the A element and the B element in the target complex oxide. In other words, it is preferable to mix so that the ratio of the substance amount (A) of the A element and the substance amount (B) of the B element in the complex oxide, A:B = x:y, is satisfied. Since the mixing can be performed in the same manner as in the mixed powder preparation process, a description thereof will be omitted here.

The resulting mixed powder is then subjected to a firing process (second firing process) to prepare the electromagnetic wave absorbing particles of this embodiment. The conditions for the second firing process are not particularly limited, but the firing atmosphere and firing temperature can be performed in the same manner as described in the firing process (first firing process) described above, and therefore will not be described here. The firing conditions for the first firing process and the second firing process may be the same or different.

By carrying out the steps described above, the electromagnetic wave absorbing particles of this embodiment can be obtained. After the firing step is completed, the obtained electromagnetic wave absorbing particles can be crushed, pulverized, sieved, or the like, as necessary, to obtain a desired particle size distribution.
[3] Electromagnetic wave absorbing particle dispersion liquid Next, the electromagnetic wave absorbing particle dispersion liquid of this embodiment will be described.

The electromagnetic wave absorbing particle dispersion of this embodiment can contain a liquid medium and the electromagnetic wave absorbing particles described above contained in the liquid medium. It is preferable that the electromagnetic wave absorbing particles are dispersed in the liquid medium.

The electromagnetic wave absorbing particle dispersion of this embodiment can be obtained using the electromagnetic wave absorbing particles already described, in other words, using electromagnetic wave absorbing particles obtained by the electromagnetic wave absorbing particle manufacturing method already described.

The electromagnetic wave absorbing particle dispersion may contain, in addition to the electromagnetic wave absorbing particles and liquid medium, a dispersant and other additives as desired. The electromagnetic wave absorbing particle dispersion can be used as an intermediate product of the electromagnetic wave absorbing particle dispersion or as a coating liquid.

The liquid medium means a medium that is liquid at the temperature of use, and is preferably a medium that is liquid at room temperature (27°C). There are no particular limitations on the liquid medium and it can be selected as desired depending on the application, but the liquid medium can preferably be one or more selected from water, organic solvents, liquid plasticizers, oils and fats, and compounds that are polymerized by curing.

The electromagnetic wave absorbing particle dispersion of this embodiment will be described below in the order of (1) the materials contained therein, (2) a method for producing the electromagnetic wave absorbing particle dispersion, and (3) a method for using the electromagnetic wave absorbing particle dispersion and an article using the same.
(1) Contained Materials (1-1) Electromagnetic Wave Absorbing Particles The electromagnetic wave absorbing particle dispersion liquid of this embodiment can contain the electromagnetic wave absorbing particles described above. The electromagnetic wave absorbing particles have already been described, so a description thereof will be omitted here.
(1-2) Liquid Medium (1-2-1) Organic Solvent The organic solvent used as the liquid medium may be, for example, one or more selected from alcohols, ketones, esters, glycol derivatives, amides, aromatic hydrocarbons, and the like.

Specifically, alcohol-based materials such as methanol, ethanol, 1-propanol, isopropanol, butanol, pentanol, benzyl alcohol, and diacetone alcohol;
Ketone-based materials such as acetone, methyl ethyl ketone, dimethyl ketone, methyl propyl ketone, methyl isobutyl ketone, cyclohexanone, and isophorone;
Ester-based materials such as 3-methyl-methoxy-propionate, n-butyl acetate, etc.;
Glycol derivatives such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol isopropyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monomethyl ether acetate, and propylene glycol monoethyl ether acetate;
Amides such as formamide, N-methylformamide, dimethylformamide, dimethylacetamide, and N-methyl-2-pyrrolidone;
Aromatic hydrocarbons such as toluene and xylene;
The organic solvent may be one or more selected from ethylene chloride, chlorobenzene, and the like.

Among the above organic solvents, one or more selected from dimethyl ketone, methyl ethyl ketone, methyl isobutyl ketone, toluene, propylene glycol monomethyl ether acetate, n-butyl acetate, and the like can be more preferably used.
(1-2-2) Fats and Oils The fats and oils used as the liquid medium are not particularly limited, but vegetable oils or compounds derived from vegetable oils can be preferably used.

As the vegetable oil, one or more types selected from drying oils such as linseed oil, sunflower oil, tung oil, and perilla oil, semi-drying oils such as sesame oil, cottonseed oil, rapeseed oil, soybean oil, rice bran oil, and poppy oil, and non-drying oils such as olive oil, coconut oil, palm oil, and dehydrated castor oil can be preferably used.

As the compound derived from vegetable oil, one or more selected from fatty acid monoesters, ethers, etc., which are obtained by directly esterifying fatty acids of vegetable oil with monoalcohols, can be preferably used.

Commercially available petroleum-based solvents can also be used as oils and fats.

As commercially available petroleum-based solvents, Isopar (registered trademark) E, Exxor (registered trademark) (hereinafter the same), Hexane, Heptane, E, D30, D40, D60, D80, D95, D110, D130 (all manufactured by ExxonMobil), and the like can be used.
(1-2-3) Liquid Plasticizer The liquid plasticizer used as the liquid medium may be one or more selected from, for example, plasticizers that are compounds of monohydric alcohols and organic acid esters, ester-based plasticizers such as polyhydric alcohol organic acid ester compounds, phosphoric acid-based plasticizers such as organic phosphoric acid-based plasticizers, etc. It is preferable that any of these plasticizers is liquid at room temperature.

Among them, a plasticizer that is an ester compound synthesized from a polyhydric alcohol and a fatty acid can be preferably used. The ester compound synthesized from the polyhydric alcohol and the fatty acid is not particularly limited, but for example, a glycol-based ester compound obtained by reacting a glycol with a monobasic organic acid can be preferably used. As the glycol, one or more selected from triethylene glycol, tetraethylene glycol, tripropylene glycol, etc. can be preferably used. In addition, as the monobasic organic acid, one or more selected from butyric acid, isobutyric acid, caproic acid, 2-ethylbutyric acid, heptyl acid, n-octylic acid, 2-ethylhexyl acid, pelargonic acid (n-nonylic acid), decyl acid, etc. can be preferably used.

Also suitable for use are ester compounds of tetraethylene glycol or tripropylene glycol with a monobasic organic solvent. Of these, it is preferable to use one or more selected from fatty acid esters of triethylene glycol, such as triethylene glycol dihexanate, triethylene glycol di-2-ethylbutyrate, triethylene glycol di-octanate, and triethylene glycol di-2-ethylhexanoate. Furthermore, fatty acid esters of triethylene glycol are also preferably used.
(1-2-4) Compound to be Polymerized by Curing As the compound to be polymerized by curing used in the infrared absorbing particle dispersion liquid of this embodiment, a monomer or oligomer that forms a polymer by a polymerization reaction or the like induced by heat, light, or water can be suitably used.

Specific examples of compounds that can be polymerized by curing include methyl methacrylate monomer, acrylate monomer, and styrene resin monomer.

The liquid media described above may be used in combination of two or more kinds. Furthermore, if necessary, an acid or an alkali may be added to these liquid media to adjust the pH.
(1-3) Dispersant In the electromagnetic wave absorbing particle dispersion liquid of this embodiment, in order to further improve the dispersion stability of the electromagnetic wave absorbing particles and to prevent the particle size from increasing due to re-aggregation, the electromagnetic wave absorbing particle dispersion liquid of this embodiment may also contain various dispersants, surfactants, coupling agents, etc.

The dispersant, coupling agent, and surfactant can be selected according to the application, but it is preferable that they are materials having one or more functional groups selected from amine-containing groups, hydroxyl groups, carboxyl groups, phosphate groups, and epoxy groups. These functional groups adsorb to the surface of the electromagnetic wave absorbing particles, preventing aggregation and dispersing them uniformly. Polymer-based dispersants having one or more functional groups selected from these functional groups in the molecule can be more preferably used as the above-mentioned dispersant.

Specific examples of preferred commercially available dispersants include SOLSPERSE (registered trademark) 3000, 5000, 9000, 11200, 12000, 13000, 13240, 13650, 13940, 16000, 17000, 18000, 20000, 21000, 24000SC, 24000GR, 26000, 27000, 28000, manufactured by Lubrizol Japan Co., Ltd. 31845, 32000, 32500, 32550, 32600, 33000, 33500, 34750, 35100, 35200, 36600, 37500, 38500, 39000, 41000, 41090, 53095, 55000, 56000, 71000, 76500, J180, J200, M387, etc.; SOLPLUS (registered trademark) (hereinafter the same) D510, D520 , D530, D540, DP310, K500, L300, L400, R700, etc.; Disperbyk (registered trademark) manufactured by BYK Japan (hereinafter the same)-101, 102, 103, 106, 107, 108, 109, 110, 111, 112, 116, 130, 140, 142, 145, 154, 161, 162, 163, 164, 165, 166, 167, 168, 1 70, 171, 174, 180, 181, 182, 183, 184, 185, 190, 191, 192, 2000, 2001, 2009, 2020, 2025, 2050, 2070, 2095, 2096, 2150, 2151, 2152, 2155, 2163, 2164, Anti-Terra (registered trademark) (hereinafter the same)-U, 203, 204, etc.; BYK (registered trademark) (hereinafter the same) )-P104, P104S, P105, P9050, P9051, P9060, P9065, P9080, 051, 052, 053, 054, 055, 057, 063, 065, 066N, 067A, 077, 088, 141, 220S, 300, 302, 306, 307, 310, 315, 320, 322, 323, 325, 330, 331, 333, 337, 340, 345 , 346, 347, 348, 350, 354, 355, 358N, 361N, 370, 375, 377, 378, 380N, 381, 392, 410, 425, 430, 1752, 4510 , 6919, 9076, 9077, W909, W935, W940, W961, W966, W969, W972, W980, W985, W995, W996, W9010, Dynwet80 0, Siclean 3700, UV3500, UV3510, UV3570, etc.; EFKA (registered trademark) manufactured by EFKA Additives (hereinafter the same) 2020, 2025, 3030, 3031, 3236, 4008, 4009, 4010, 4015, 4020, 4046, 4047, 4050, 4055, 4060, 4080, 4300, 4310, 4320, 4330, 4340, 4 400, 4401, 4402, 4403, 4500, 5066, 5220, 6220, 6225, 6230, 6700, 6780, 6782, 7462, 8503, etc.; JONCRYL (registered trademark) manufactured by BASF Japan Ltd. (hereinafter the same) 67, 678, 586, 611, 680, 682, 690, 819, -JDX5050, etc.; TERPLUS (registered trademark) manufactured by Otsuka Chemical Co., Ltd. (hereinafter the same) MD1000, D 1180, D 1130, etc.; Ajinomoto Fine-Techno Co., Ltd. AJISPER (registered trademark) (hereinafter the same) PB-711, PB-821, PB-822, etc.; Kusumoto Chemicals Co., Ltd. DISPARLON (registered trademark) (hereinafter the same) 1751N, 1831, 1850, 1860, 1934, DA-400N, DA-703-50, DA-325, DA-375, DA-550, DA-705, DA-725, DA-1401, DA-7301, DN-900, NS-5210, NVI-8514L, etc.; Toagosei Co., Ltd. ALPHO (registered trademark) (hereinafter the same) UH-2 170, UC-3000, UC-3910, UC-3920, UF-5022, UG-4010, UG-4035, UG-4040, UG-4070, Reseda (registered trademark) (hereinafter the same) GS-1015, GP-301, GP-301S, etc.; Mitsubishi Chemical Corporation's Dianale (registered trademark) (hereinafter the same) BR-50, BR-52, BR-60, BR-73, BR-77, BR80, BR-83, BR-85, BR-87, BR-88, BR-90, BR-96, BR-102, BR-113, BR-116, etc.

A liquid dispersant having a glass transition temperature lower than room temperature can be used instead of the liquid medium. That is, the electromagnetic wave absorbing particle dispersion of this embodiment can contain electromagnetic wave absorbing particles and a liquid dispersant, or can be composed of electromagnetic wave absorbing particles and a liquid dispersant. Preferable specific examples of commercially available liquid dispersants include SOLSPERSE (registered trademark) 20000 manufactured by Lubrizol Japan Co., Ltd., Disparlon (registered trademark) (hereinafter the same) DA234, DA325, DA375 manufactured by Kusumoto Chemicals Co., Ltd.
(1-4) Other Additives The electromagnetic wave absorbing particle dispersion of this embodiment may contain additives such as various surfactants and resin components in order to control the coating property, leveling property, and drying property. When such additives are added, the electromagnetic wave absorbing particle dispersion preferably contains a small amount of the additive in the range of 5 mass % or less of the dispersion. Examples of the surfactant include anionic, cationic, nonionic, and amphoteric surfactants.

In order to impart flexibility to the electromagnetic wave absorbing particle dispersion obtained using the electromagnetic wave absorbing particle dispersion, the dispersion may contain one or more organic resins selected from silicone resins, acrylic resins, polyester resins, polyurethane resins, hydrophilic organic resins containing polyoxyalkylene groups, epoxy resins, etc. When such organic resins are added, it is preferable that the electromagnetic wave absorbing particle dispersion contains a small amount of the organic resin in the range of 5% by mass or less of the electromagnetic wave absorbing particle dispersion.

In addition, in order to impart crack prevention properties to the electromagnetic wave absorbing particle dispersion prepared using the electromagnetic wave absorbing particle dispersion, the electromagnetic wave absorbing particle dispersion may contain one or more resins selected from thermosetting resins, thermoplastic resins, ultraviolet curing resins, etc. When such a resin is added, the electromagnetic wave absorbing particle dispersion preferably contains the resin in an amount of 20 mass% or less of the dispersion. More specifically, examples of the resin include acrylic resins, epoxy resins, polyester resins, amino resins, urethane resins, furan resins, silicone resins, and modified products of these resins.
(2) Manufacturing method of electromagnetic wave absorbing particle dispersion The manufacturing method of the electromagnetic wave absorbing particle dispersion of this embodiment is not particularly limited. The electromagnetic wave absorbing particle dispersion of this embodiment can be prepared, for example, by adding the above-mentioned electromagnetic wave absorbing particles and, if necessary, a dispersant and other additives to the above-mentioned liquid medium and dispersing them. Note that, as described above, a liquid dispersant can also be used instead of the liquid medium.

The method for dispersing electromagnetic wave absorbing particles in a liquid medium is not particularly limited, but examples include grinding and dispersion methods using devices such as bead mills, ball mills, sand mills, paint shakers, and ultrasonic homogenizers. Among these, media agitation mills such as bead mills, ball mills, sand mills, and paint shakers that use media such as beads, balls, and Ottawa sand can be used preferably because they can give the electromagnetic wave absorbing particles the desired particle size in a short period of time.

By using a milling and dispersion process using a media stirring mill, the electromagnetic wave absorbing particles are dispersed into the liquid medium, and at the same time, the particles are atomized due to collisions between the electromagnetic wave absorbing particles and between the medium and the electromagnetic wave absorbing particles, allowing the electromagnetic wave absorbing particles to be dispersed in a more atomized form. In other words, the particles are milled and dispersed.

The dispersion concentration of the electromagnetic wave absorbing particles in the electromagnetic wave absorbing particle dispersion is preferably 0.01% by mass or more and 80% by mass or less. This is because a sufficient electromagnetic wave absorbing characteristic can be exhibited by making the content of the electromagnetic wave absorbing particles 0.01% by mass or more. Also, by making the content 80% by mass or less, the electromagnetic wave absorbing particles can be uniformly dispersed in the liquid medium. By selecting a combination of the liquid medium, dispersant, coupling agent, and surfactant, the electromagnetic wave absorbing particle dispersion of this embodiment can prevent gelation of the dispersion or sedimentation of the particles for more than six months even when placed in a thermostatic bath at a temperature of 40° C., and can suppress an increase in particle size.
(3) Method of Using Electromagnetic Wave Absorbing Particle Dispersion, and Article Using Electromagnetic Wave Absorbing Particle Dispersion The application etc. of the electromagnetic wave absorbing particle dispersion of the present embodiment is not particularly limited, and it can be used for various applications.

The electromagnetic wave absorbing particle dispersion of this embodiment can be used as an electromagnetic wave absorbing substrate by, for example, forming a dispersion film by applying it to the surface of a suitable substrate. The dispersion film is a type of electromagnetic wave absorbing particle dispersion, and is also a type of dried solidified product of the electromagnetic wave absorbing particle dispersion.

The electromagnetic wave absorbing particle dispersion of this embodiment can also be dried and pulverized as necessary to form a powdered electromagnetic wave absorbing particle dispersion (sometimes referred to as "dispersed powder" in this specification). In other words, the dispersed powder is a type of electromagnetic wave absorbing particle dispersion, and also a type of dried solidified electromagnetic wave absorbing particle dispersion. The dispersed powder is a powdered dispersion in which electromagnetic wave absorbing particles are dispersed in a solid medium such as a dispersant. Since the dispersed powder contains a dispersant, it is possible to easily redisperse the electromagnetic wave absorbing particles in the medium by mixing it with an appropriate medium.

The above-mentioned dispersion powder can also be used as a raw material for adding the electromagnetic wave absorbing particles in a dispersed state to an electromagnetic wave absorbing product. That is, the dispersion powder in which the electromagnetic wave absorbing particles of this embodiment are dispersed in a solid medium can be dispersed again in a liquid medium and used as a dispersion liquid for an infrared absorbing product, or the dispersion powder can be kneaded into a resin and used as an electromagnetic wave absorbing particle dispersion, as described below.

The electromagnetic wave absorbing particle dispersion of this embodiment can be used for various applications that utilize light-to-heat conversion.

For example, a curable ink composition can be prepared by adding an electromagnetic wave absorbing particle dispersion to an uncured thermosetting resin, or by adding an uncured thermosetting resin to an electromagnetic wave absorbing particle dispersion. The above-mentioned curable ink composition contains the electromagnetic wave absorbing particles described above, which function as an auxiliary agent for increasing the amount of heat generated by irradiation with electromagnetic waves such as infrared rays. Since the curable ink composition contains a thermosetting resin, the electromagnetic wave absorbing particles function as an auxiliary agent for increasing the amount of heat generated by irradiating the curable ink composition with electromagnetic waves such as infrared rays, as described above, and the thermosetting resin can be cured. By providing the curable ink composition on, for example, a substrate, the adhesion between the cured product of the curable ink composition and the substrate can be increased when irradiated with electromagnetic waves such as infrared rays.

Therefore, in addition to its use as a conventional ink, the curable ink composition can be suitably used in applications such as photo-fabrication, in which a three-dimensional object is created by repeatedly applying the ink and curing it by irradiating it with electromagnetic waves such as infrared rays.

In addition, a thermoplastic resin-containing ink composition can be obtained by adding the electromagnetic wave absorbing particles of this embodiment to a thermoplastic resin that has been heated and melted, or by dispersing the electromagnetic wave absorbing particles of this embodiment in a suitable solvent and then adding a thermoplastic resin that is highly soluble in the solvent.

For example, a thermoplastic resin-containing ink composition can be provided on a substrate and irradiated with electromagnetic waves such as infrared rays, and the cured product of the thermoplastic resin-containing ink composition can be adhered to the substrate through removal of the solvent and heat fusion of the resin. In this case, in the thermoplastic resin-containing ink composition, the electromagnetic wave absorbing particles function as an auxiliary agent that increases the amount of heat generated by irradiation with electromagnetic waves such as infrared rays, just as in the case of the curable ink composition described above.

Therefore, in addition to its use as a conventional ink, the thermoplastic resin-containing ink composition can be suitably used in applications such as photolithography, in which a three-dimensional object is created by repeatedly applying the ink, removing the solvent by irradiating it with electromagnetic waves such as infrared rays, and then heating and fusing the resin.

The curable ink composition and the thermoplastic resin-containing ink composition described above are also examples of the electromagnetic wave absorbing particle dispersion liquid of this embodiment.
[4] Electromagnetic Wave Absorbing Particle Dispersion Next, the electromagnetic wave absorbing particle dispersion of this embodiment will be described.

The electromagnetic wave absorbing particle dispersion of this embodiment can contain a solid medium and the electromagnetic wave absorbing particles described above contained in the solid medium. It is preferable that the electromagnetic wave absorbing particles are dispersed in the solid medium.

A solid medium means a medium that is solid at the temperature of use, and is preferably a medium that is solid at room temperature (27°C). Examples of solid media that can be used include resin and glass.

As a solid medium, resins are particularly suitable for use from the standpoint of ease of handling, etc.

When a resin is used as the solid medium, the type of resin is not particularly limited, but the resin can be, for example, one type of resin selected from the group of resins consisting of polyester resin, polycarbonate resin, acrylic resin, styrene resin, polyamide resin, polyethylene resin, vinyl chloride resin, olefin resin, epoxy resin, polyimide resin, fluororesin, ethylene-vinyl acetate copolymer, polyvinyl acetal resin, and ultraviolet-curable resin, or a mixture of two or more types of resins selected from the above group of resins.

The content of the electromagnetic wave absorbing particles in the electromagnetic wave absorbing particle dispersion is not particularly limited, but it is preferable that the electromagnetic wave absorbing particle dispersion contains electromagnetic wave absorbing particles at a ratio of 0.001% by mass or more and 80% by mass or less. This is because the electromagnetic wave absorbing particles contain 0.001% by mass or more, and therefore sufficient infrared shielding function can be exhibited. Furthermore, by making the content of the electromagnetic wave absorbing particles 80% by mass or less, it is possible to suppress the granulation of the electromagnetic wave absorbing particles in the solid medium, and therefore particularly good transparency can be maintained. In addition, it is advantageous in terms of cost because the amount of the electromagnetic wave absorbing particles used can be suppressed. Furthermore, by making the content of the electromagnetic wave absorbing particles 80% by mass or less, the proportion of the solid medium contained in the electromagnetic wave absorbing particle dispersion can be increased, and the strength of the dispersion can be increased.

The shape of the electromagnetic wave absorbing particle dispersion of this embodiment is not particularly limited and can be selected as desired depending on the application. For example, the electromagnetic wave absorbing particle dispersion of this embodiment is preferably in the shape of a sheet, a board, or a film.

The electromagnetic wave absorbing particle dispersion of this embodiment will be described in the following order: (1) a method for producing the electromagnetic wave absorbing particle dispersion, (2) an electromagnetic wave absorbing substrate, and (3) a method for using the electromagnetic wave absorbing particle dispersion and an article using the same.
(1) Method for producing electromagnetic wave absorbing particle dispersion There is no particular limitation on the method for producing the electromagnetic wave absorbing particle dispersion. The electromagnetic wave absorbing particle dispersion can be produced, for example, by kneading the electromagnetic wave absorbing particles described above into a solid medium such as a resin, and molding the mixture into a desired shape such as a film or a board.

The electromagnetic wave absorbing particle dispersion can also be produced by mixing the electromagnetic wave absorbing particle dispersion liquid described above with a solid medium such as resin. It is also possible to produce an electromagnetic wave absorbing particle dispersion by adding a powder dispersion in which electromagnetic wave absorbing particles are dispersed in a solid medium, i.e., the above-mentioned dispersed powder, to a liquid medium and mixing it with a solid medium such as resin.

The shape of the electromagnetic wave absorbing particle dispersion of this embodiment is not particularly limited, but when a resin is used as the solid medium, it can be in the form of a sheet having a thickness of 0.1 μm or more and 50 mm or less, a board shape, or a film shape.

As described above, when the electromagnetic wave absorbing particles described above are kneaded into a solid medium such as a resin to prepare an electromagnetic wave absorbing particle dispersion, the electromagnetic wave absorbing particles and the solid medium are heated and mixed at a temperature near the melting point of the solid medium, e.g., resin (e.g., about 200°C or higher and 300°C or lower), and kneaded together.

The material obtained by kneading the electromagnetic wave absorbing particles into a solid medium can be molded into a desired shape, but it is also possible to first pelletize the material and then mold the pellets into the desired shape, such as a film or board, using various methods.

The molding method is not particularly limited, and for example, extrusion molding, inflation molding, solution casting, casting, etc. can be used.

As mentioned above, when the electromagnetic wave absorbing particle dispersion is in the form of a sheet, board, or film, the thickness is not particularly limited and can be selected according to the application, etc.

The amount of filler relative to the solid medium in the electromagnetic wave absorbing particle dispersion, i.e., the amount of electromagnetic wave absorbing particles, can be selected as desired depending on the thickness of the electromagnetic wave absorbing particle dispersion and the optical and mechanical properties required of the electromagnetic wave absorbing particle dispersion. For example, it is generally preferable that the amount be 80 mass % or less relative to the resin.

If the amount of filler relative to the solid medium is 80% by mass or less, the electromagnetic wave absorbing particles in the solid medium can be prevented from granulating with each other, so that particularly good transparency can be maintained. In addition, the amount of electromagnetic wave absorbing particles used can be reduced, which is also advantageous in terms of cost.

The lower limit of the amount of filler relative to the solid medium is not particularly limited, but it is preferable to set it to, for example, 0.001% by mass or more in order for the electromagnetic wave absorbing particle dispersion to exhibit sufficient infrared shielding function.

The electromagnetic wave absorbing particle dispersion can also be used in a powder state by further pulverizing the electromagnetic wave absorbing particle dispersion in which the electromagnetic wave absorbing particles are dispersed in a solid medium. When this configuration is adopted, the electromagnetic wave absorbing particles are sufficiently dispersed in the solid medium in the powdered electromagnetic wave absorbing particle dispersion. Therefore, the powdered electromagnetic wave absorbing particle dispersion can be dissolved in an appropriate liquid medium as a so-called master batch, or kneaded with resin pellets, etc., to easily produce a liquid or solid electromagnetic wave absorbing particle dispersion.

The solid medium that becomes the matrix of the above-mentioned sheet, board, and film is not particularly limited and can be selected according to the application. As mentioned above, a resin can be preferably used from the viewpoint of handling. When a resin is used as the solid medium, one type of resin selected from the resin group consisting of polyester resin, polycarbonate resin, acrylic resin, styrene resin, polyamide resin, polyethylene resin, vinyl chloride resin, olefin resin, epoxy resin, polyimide resin, fluororesin, ethylene-vinyl acetate copolymer, polyvinyl acetal resin, and ultraviolet curable resin, or a mixture of two or more types of resins selected from the above resin group can be preferably used. In particular, one or more types of resin selected from polyethylene terephthalate resin, acrylic resin, polyamide resin, vinyl chloride resin, polycarbonate resin, olefin resin, epoxy resin, polyimide resin, etc. can be preferably used as a resin that is low cost, highly transparent, and has a wide range of versatility. In addition, a fluororesin can also be used in consideration of weather resistance.
(2) Electromagnetic-wave-absorbing substrate The electromagnetic-wave-absorbing particle dispersion of the present embodiment also includes an electromagnetic-wave-absorbing substrate having a substrate and a dispersion film containing the above-mentioned electromagnetic-wave-absorbing particles disposed on the surface of the substrate.

Such an electromagnetic wave absorbing substrate can be manufactured, for example, by the following procedure.

An electromagnetic wave absorbing particle dispersion is prepared by mixing the electromagnetic wave absorbing particles described above with a liquid medium such as an organic solvent such as alcohol or water, a resin binder, and, if desired, a dispersant (dispersion preparation process).

Next, the electromagnetic wave absorbing particle dispersion is applied to a suitable substrate surface (application process).

The liquid medium is removed or cured to produce an electromagnetic wave absorbing particle dispersion (dispersion preparation process).

Through the above steps, an electromagnetic wave absorbing substrate is obtained in which the electromagnetic wave absorbing particle dispersion is directly laminated onto the substrate surface.

The resin binder components can be selected according to the application, and examples include ultraviolet curable resins, thermosetting resins, room temperature curable resins, thermoplastic resins, etc.

On the other hand, an electromagnetic wave absorbing particle dispersion that does not contain a resin binder component may be applied, and the electromagnetic wave absorbing particle dispersion may be laminated on the surface of the substrate. Also, after applying the electromagnetic wave absorbing particle dispersion that does not contain the resin binder component, a liquid medium that contains a binder component may be applied onto the layer of the electromagnetic wave absorbing particle dispersion.

Specifically, a liquid electromagnetic wave absorbing particle dispersion in which electromagnetic wave absorbing particles are dispersed in one or more liquid media selected from, for example, an organic solvent, an organic solvent in which a resin is dissolved, an organic solvent in which a resin is dispersed, and water is applied to the surface of the substrate. The resulting coating film is then solidified by an appropriate method to produce an electromagnetic wave absorbing substrate.

Also, an electromagnetic wave absorbing substrate can be produced by applying a liquid electromagnetic wave absorbing particle dispersion containing a resin binder component to the surface of a substrate and then solidifying the resulting coating film by an appropriate method.

Furthermore, an electromagnetic wave absorbing substrate can be obtained by mixing an electromagnetic wave absorbing particle dispersion, in which electromagnetic wave absorbing particles are dispersed in a powdered solid medium, with a specified medium, applying the resulting electromagnetic wave absorbing particle dispersion to the surface of a substrate, and solidifying the resulting coating film by an appropriate method.

Of course, it is also possible to prepare an electromagnetic wave absorbing substrate by applying a mixture of two or more of the above-mentioned liquid electromagnetic wave absorbing particle dispersions to the surface of a substrate and solidifying the resulting coating film by an appropriate method.

The material of the substrate used in the electromagnetic wave absorbing substrate is not particularly limited as long as it is transparent, but one or more types selected from glass, resin sheets, resin boards, resin films, etc. are preferably used. Note that a transparent body is a material that transmits light in the visible light range, and the degree of transmission of light in the visible light range can be selected as desired depending on the application of the electromagnetic wave absorbing substrate, etc.

The resin used for the resin sheet, resin board, and resin film is not particularly limited, and can be selected according to the required properties such as the surface condition and durability of the sheet, board, and film. Examples of the resin include polyester polymers such as polyethylene terephthalate and polyethylene naphthalate, cellulose polymers such as diacetyl cellulose and triacetyl cellulose, polycarbonate polymers, acrylic polymers such as polymethyl methacrylate, styrene polymers such as polystyrene and acrylonitrile-styrene copolymers, olefin polymers such as polyethylene, polypropylene, polyolefins having a cyclic or norbornene structure, and ethylene-propylene copolymers, vinyl chloride polymers, amide polymers such as aromatic polyamides, imide polymers, sulfone polymers, polyethersulfone polymers, polyetheretherketone polymers, polyphenylene sulfide polymers, vinyl alcohol polymers, vinylidene chloride polymers, vinyl butyral polymers, arylate polymers, polyoxymethylene polymers, epoxy polymers, and further transparent polymers such as various binary and ternary copolymers, graft copolymers, and blends thereof. In particular, polyester-based biaxially oriented films such as polyethylene terephthalate, polybutylene terephthalate, and polyethylene-2,6-naphthalate are preferred in terms of mechanical properties, optical properties, heat resistance, and economic efficiency. The polyester-based biaxially oriented film may be a copolymer polyester-based film.
(3) Method of using electromagnetic wave absorbing particle dispersion and article using the same The electromagnetic wave absorbing particle dispersion and the electromagnetic wave absorbing substrate of the present embodiment described above can transmit light in the visible light region and block light in the infrared region. Therefore, for example, they can be used in window materials in various buildings and vehicles that allow sufficient visible light to be taken in while blocking light in the infrared region, and suppress the rise in temperature inside the room while maintaining brightness. They can also be suitably used in filters that block infrared rays emitted forward from a PDP (plasma display panel).

In addition, since the electromagnetic wave absorbing particles of this embodiment have absorption in the infrared region, when an infrared laser is irradiated onto a printed surface containing the electromagnetic wave absorbing particles, the particles absorb infrared rays having a specific wavelength. Therefore, an anti-counterfeiting printed matter obtained by printing an anti-counterfeiting ink containing the electromagnetic wave absorbing particles onto one or both sides of a substrate to be printed can be irradiated with infrared rays having a specific wavelength and the reflection or transmission of the infrared rays is read, allowing the authenticity of the printed matter to be determined from the difference in the amount of reflection or transmission. This anti-counterfeiting printed matter is an example of an electromagnetic wave absorbing particle dispersion of this embodiment.

In addition, a light-to-heat conversion layer can be formed by applying an ink obtained by mixing the electromagnetic wave absorbing particle dispersion liquid and a binder component described above onto a substrate, drying the applied ink, and then curing the dried ink. The light-to-heat conversion layer generates heat at the location irradiated with an electromagnetic wave laser such as infrared light, and can heat adjacent materials. Therefore, the light-to-heat conversion layer can generate heat only at the desired location with high positional accuracy by irradiating an electromagnetic wave laser such as infrared light. For this reason, the light-to-heat conversion layer can be applied as a local heating medium in a wide range of fields such as electronics, medicine, agriculture, and machinery. For example, it can be suitably used as a donor sheet used when forming an organic electroluminescence element by a laser transfer method, thermal paper for a thermal printer, or an ink ribbon for a thermal transfer printer. The light-to-heat conversion layer is an example of the electromagnetic wave absorbing particle dispersion of this embodiment.

Infrared absorbing fibers can be made by dispersing the electromagnetic wave absorbing particles described above in a suitable medium and incorporating the dispersion in one or more locations selected from the surface and interior of the fiber. Since the infrared absorbing fiber contains electromagnetic wave absorbing particles, it efficiently absorbs near infrared rays from sunlight and the like, and is an infrared absorbing fiber with excellent heat retention. Since the infrared absorbing fiber transmits light in the visible light range, it is an infrared absorbing fiber with excellent design properties.

As a result, it can be used for various applications such as textile products that require heat retention, such as cold weather clothing, sports clothing, stockings, curtains, and other industrial textile products. The infrared absorbing fiber is an example of the electromagnetic wave absorbing particle dispersion of this embodiment.

The electromagnetic wave absorbing particle dispersion of this embodiment can also be applied to materials such as roofs and exterior wall materials of agricultural and horticultural greenhouses. The electromagnetic wave absorbing particle dispersion of this embodiment transmits visible light, so light necessary for photosynthesis of plants in the agricultural and horticultural greenhouses can be secured. The electromagnetic wave absorbing particles of this embodiment can efficiently absorb light other than visible light, such as near-infrared light contained in sunlight, so they can be used as a heat insulating material for agricultural and horticultural facilities equipped with heat insulating properties. The heat insulating material for agricultural and horticultural facilities is an example of the electromagnetic wave absorbing particle dispersion of this embodiment.
[5] Electromagnetic wave absorbing laminate The electromagnetic wave absorbing laminate of this embodiment can have a laminated structure including the above-mentioned electromagnetic wave absorbing particle dispersion and a transparent substrate. For example, the electromagnetic wave absorbing laminate can be an example in which two or more transparent substrates are laminated with the above-mentioned electromagnetic wave absorbing particle dispersion. In this case, the electromagnetic wave absorbing particle dispersion can be disposed between the transparent substrates, for example, and used as an intermediate film for absorbing electromagnetic waves.

In this case, it is preferable that the electromagnetic wave absorbing intermediate film has a shape of either a sheet, a board, or a film.

The transparent substrate can be one or more selected from glass sheets, plastic sheets, plastic films, etc. that are transparent in the visible light region. The transparent substrate being transparent in the visible light region means that the substrate transmits light in the visible light region. The degree to which the transparent substrate transmits light in the visible light region can be selected as desired depending on the application of the electromagnetic wave absorbing laminate.

When plastic is used as the transparent substrate, the plastic material is not particularly limited and can be selected according to the application. For example, one or more types selected from polycarbonate resin, acrylic resin, polyester resin, polyamide resin, vinyl chloride resin, olefin resin, epoxy resin, polyimide resin, ionomer resin, fluororesin, etc. can be used. As the polyester resin, polyethylene terephthalate resin can be preferably used.

The transparent substrate may contain particles having an electromagnetic wave absorbing function. For example, the above-mentioned electromagnetic wave absorbing particles can be used as the particles having an electromagnetic wave absorbing function.

By using the electromagnetic wave absorbing particle dispersion described above as a constituent member of the intermediate layer sandwiched between multiple transparent substrates, it is possible to obtain a solar radiation shielding laminated structure that is a type of electromagnetic wave absorbing laminate that transmits visible light and has an electromagnetic wave absorbing function.

The electromagnetic wave absorbing laminate described above can also be obtained by bonding and integrating multiple transparent substrates facing each other with an electromagnetic wave absorbing particle dispersion sandwiched therebetween using a known method.

When the electromagnetic wave absorbing particle dispersion described above is used as an electromagnetic wave absorbing intermediate film, the solid medium may be the same as that described for the electromagnetic wave absorbing particle dispersion. However, from the viewpoint of increasing the adhesive strength between the electromagnetic wave absorbing intermediate film and the transparent substrate, it is preferable that the solid medium is a polyvinyl acetal resin.

The electromagnetic wave absorbing intermediate film can be manufactured by the manufacturing method of the electromagnetic wave absorbing particle dispersion described above, and can be, for example, an electromagnetic wave absorbing intermediate film having any of the shapes of a sheet, board, or film.

If the electromagnetic wave absorbing intermediate film does not have sufficient flexibility or adhesion to the transparent substrate, it is preferable to add a liquid plasticizer for the medium resin. For example, if the medium resin used in the electromagnetic wave absorbing intermediate film is polyvinyl acetal resin, the addition of a liquid plasticizer for polyacetal resin is beneficial for improving adhesion to the transparent substrate.

As the plasticizer, a substance that is used as a plasticizer for the medium resin can be used. For example, examples of plasticizers that can be used in an infrared shielding film made of polyvinyl acetal resin include plasticizers that are compounds of monohydric alcohols and organic acid esters, ester-based plasticizers such as polyhydric alcohol organic acid ester compounds, and phosphoric acid-based plasticizers such as organic phosphoric acid-based plasticizers. It is preferable that any of these plasticizers be liquid at room temperature. Of these, plasticizers that are ester compounds synthesized from polyhydric alcohols and fatty acids are preferred.

The electromagnetic wave absorbing intermediate film may also contain at least one selected from the group consisting of a silane coupling agent, a metal salt of a carboxylic acid, a metal hydroxide, and a metal carbonate. The metal constituting the metal salt of a carboxylic acid, the metal hydroxide, and the metal carbonate is not particularly limited, but is preferably at least one selected from sodium, potassium, magnesium, calcium, manganese, cesium, lithium, rubidium, and zinc. In the near-infrared absorbing intermediate film, the content of at least one selected from the group consisting of a metal salt of a carboxylic acid, a metal hydroxide, and a metal carbonate is preferably 1% by mass or more and 100% by mass or less relative to the electromagnetic wave absorbing particles.

Furthermore, the electromagnetic wave absorbing intermediate film may contain, in addition to the electromagnetic wave absorbing particles described above, at least one of oxide particles, composite oxide particles, and boride particles containing two or more elements selected from the group consisting of Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, and Ca, if necessary. The electromagnetic wave absorbing intermediate film may contain such particles in a range of 5% by mass to 95% by mass, assuming that the total of such particles and the electromagnetic wave absorbing particles is 100% by mass.

The electromagnetic wave absorbing laminate may contain an ultraviolet absorbing agent in at least one layer of the intermediate film disposed between the transparent substrates. Examples of the ultraviolet absorbing agent include one or more types selected from a compound having a malonic acid ester structure, a compound having an oxalic acid anilide structure, a compound having a benzotriazole structure, a compound having a benzophenone structure, a compound having a triazine structure, a compound having a benzoate structure, a compound having a hindered amine structure, and the like.

Of course, the intermediate layer of the electromagnetic wave absorbing laminate may be composed of only the electromagnetic wave absorbing intermediate film.

The electromagnetic wave absorbing intermediate film described here is also an example of an electromagnetic wave absorbing particle dispersion. Furthermore, the electromagnetic wave absorbing laminate of this embodiment is not limited to the above-mentioned form in which an electromagnetic wave absorbing particle dispersion is disposed between transparent substrates, and can have any configuration as long as it has a laminate structure including an electromagnetic wave absorbing particle dispersion and a transparent substrate.

The present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto.
(Evaluation Method)
First, the evaluation methods used in the following Examples and Reference Examples will be described.
(Cumulative 50% particle size, cumulative 95% particle size)
The particle size distribution of the electromagnetic wave absorbing particles in the examples and reference examples was measured using a particle size distribution measuring device (UPA-150 manufactured by Nikkiso Co., Ltd.) based on the principle of dynamic light scattering method analyzed by frequency analysis. The measurement conditions used were a particle refractive index of 1.81 and a non-spherical particle shape. The background was measured using methyl isobutyl ketone, and the solvent refractive index was 1.40. The cumulative 50% particle size and cumulative 95% particle size were then calculated from the obtained particle size distribution.
(Crystal Structure)
The crystal structure of the composite oxide contained in the electromagnetic wave absorbing particles was measured using the electromagnetic wave absorbing particles obtained by removing the solvent from the electromagnetic wave absorbing particle dispersion liquid.

The X-ray diffraction pattern of the electromagnetic wave absorbing particles was measured by powder X-ray diffraction method (θ-2θ method) using a powder X-ray diffractometer (X'Pert-PRO/MPD manufactured by PANalytical Spectris Co., Ltd.). The crystal structure contained in the particles was identified from the obtained X-ray diffraction pattern.

(Optical Properties of Dispersion)
The optical properties of the electromagnetic wave absorbing particle dispersion in the examples and reference examples were measured as follows. First, the electromagnetic wave absorbing particle dispersion was diluted with methyl isobutyl ketone as a solvent in a glass cell for measuring a spectrophotometer. At this time, the dilution ratio was set so that the visible light transmittance after dilution was 70%. Next, a spectrophotometer (UH4150 manufactured by Hitachi High-Tech Science) was used to measure the transmitted light profile at intervals of 5 nm in the wavelength range of 200 nm to 2600 nm, and the visible light transmittance and solar transmittance were calculated in the wavelength range of 300 nm to 2100 nm based on JIS R 3106 (2019). At this time, in this measurement, the incident direction of the light of the spectrophotometer was set to a direction perpendicular to the glass cell for measuring. In addition, a blank solution in which only the solvent methyl isobutyl ketone was put into the glass cell for measuring was used as the baseline of the light transmittance.
(Optical properties of electromagnetic wave absorbing substrate)
The optical properties of the electromagnetic wave absorbing substrate in the examples and reference examples were measured using a spectrophotometer (UH4150 manufactured by Hitachi High-Tech Science Co., Ltd.). The transmitted light profile was measured at intervals of 5 nm in the wavelength range of 200 nm to 2600 nm, and the visible light transmittance and solar radiation transmittance were calculated based on JIS R 3106 (2019) in the wavelength range of 300 nm to 2100 nm.
(Hayes)
The haze value of the electromagnetic wave absorbing substrate was measured using a haze meter (HM-150N manufactured by Murakami Color Research Laboratory Co., Ltd.) and calculated based on JIS K 7136 (2000).
[Example 1]
(Electromagnetic wave absorbing particles)
8.65 g of strontium oxide (SrO, Fujifilm Wako Pure Chemical Industries, Ltd., purity 96.8%) and 11.58 g of molybdenum oxide ( _MoO3 , Kanto Chemical Co., Ltd., purity 100.0%) were thoroughly mixed to obtain a homogeneous mixture. The resulting mixed powder was placed in an alumina boat and fired at 1300°C for 2 hours in an air atmosphere to obtain strontium molybdate of the composition formula _SrMoO4 as an intermediate product.

6.05 _g of the obtained SrMoO4, 1.31 g of SrO, and 1.18 g of molybdenum powder (Mo, Fujifilm Wako Pure Chemical Industries, Ltd., purity 99.3%) were mixed thoroughly to be homogeneous. At this time, the Sr:Mo material ratio after mixing was 1:1. 4 g of the obtained mixed powder was taken out, placed in an alumina crucible, and fired at a temperature of 1300°C for 3 hours under a 3 volume % _H2 gas flow with Ar gas as a carrier, to obtain strontium molybdate of the composition formula _SrMoOz (2.0<z≦3.0) according to Example 1.

(Electromagnetic wave absorbing particle dispersion liquid)
A mixed liquid (slurry) was obtained by mixing 6% by mass of strontium molybdate according to Example 1, 6% by mass of an acrylic polymer dispersant having an amine-containing group as a functional group (an acrylic dispersant with an amine value of 48 mg KOH/g and a decomposition temperature of 250°C), and 88% by mass of methyl isobutyl ketone. The mixed liquid obtained was placed in a glass bottle together with φ0.3 _mm ZrO2 beads, and loaded into a paint shaker and subjected to a pulverization and dispersion treatment for 5 hours, thereby obtaining an electromagnetic wave absorbing particle dispersion liquid according to Example 1. At this time, the strontium molybdate particles become the electromagnetic wave absorbing particles.

When the particle size distribution of the electromagnetic wave absorbing particle dispersion of Example 1 was measured, the cumulative 50% particle diameter was 34 nm and the cumulative 95% particle diameter was 48 nm.

In addition, when the solvent (dispersion medium) was removed from the electromagnetic wave absorbing particle dispersion liquid and the powder X-ray diffraction pattern of the strontium molybdate according to Example 1 was measured, a diffraction peak attributed to the crystal phase of _SrMoO3 having a cubic perovskite structure was confirmed.

The electromagnetic wave absorbing particle dispersion liquid according to Example 1 was diluted with a solvent, methyl isobutyl ketone, and the optical properties were measured, revealing that the visible light transmittance was 70% and the solar radiation transmittance was 43%.
(Electromagnetic Wave Absorbing Particle Dispersion)
The electromagnetic wave absorbing particle dispersion according to Example 1 and a UV curable resin (Aronix UV-3701 manufactured by Toagosei Co., Ltd.) were weighed out so that the mass ratio was 1:1, and mixed and stirred to prepare a dispersion for forming an electromagnetic wave absorbing base material. Then, using a bar coater with bar No. 10, the dispersion for forming an electromagnetic wave absorbing base material was applied onto a clear glass having a thickness of 3 mm, and then dried under conditions of 70°C for 1 minute and irradiated with a high-pressure mercury lamp to obtain an electromagnetic wave absorbing base material according to Example 1. The electromagnetic wave absorbing base material is an example of an electromagnetic wave absorbing fine particle dispersion.

The optical properties of the electromagnetic wave absorbing substrate of Example 1 obtained were measured, and the visible light transmittance was 68% and the solar radiation transmittance was 44%. In addition, the haze was measured and found to be 0.3%.

The production conditions for Example 1 are shown in Table 1, and the results are shown in Tables 1 and 2.
[Example 2]
An intermediate product represented by the composition formula _BaMoO4 was obtained by using barium carbonate ( _BaCO3 , Fujifilm Wako Pure Chemical Industries, Ltd., purity 99.9%) instead of strontium oxide. Then, _BaMoO4 was used instead of _SrMoO4 , and the ratio of the amounts of Ba and Mo after mixing _BaMoO4 , _BaCO3 , and molybdenum powder, Ba:Mo, was set to 1:1. Electromagnetic wave absorbing particles were prepared in the same manner as in Example 1 except for the above points.

By the above procedure, barium molybdate represented by the composition formula BaMoO _z (2.0<z≦3.0), which is an electromagnetic wave absorbing particle, was prepared.

Moreover, except for using the electromagnetic wave absorbing particles, an electromagnetic wave absorbing particle dispersion and an electromagnetic wave absorbing base material were prepared in the same manner as in Example 1, and evaluations were carried out in the same manner as in Example 1. The evaluation results are shown in Tables 1 and 2.
[Example 3]
An intermediate product represented by the composition formula _SrCrO4 was obtained by using chromium oxide ( _CrO3 , manufactured by Fuji Film Wako Pure Chemical Industries, Ltd., purity 98%) instead of molybdenum oxide. Then, _SrCrO4 was used instead of _SrMoO4 , and the ratio of the amounts of Sr and Cr after mixing _SrCrO4 , SrO, and chromium powder (Cr, manufactured by Fuji Film Wako Pure Chemical Industries, Ltd., purity 99.5%) was set to 1:1, i.e., Sr:Cr. Except for the above points, electromagnetic wave absorbing particles were prepared in the same manner as in Example 1.

By the above procedure, strontium chromate represented by the composition formula SrCrO _z (2.0<z≦3.0), which is an electromagnetic wave absorbing particle, was prepared.

Moreover, except for using the electromagnetic wave absorbing particles, an electromagnetic wave absorbing particle dispersion and an electromagnetic wave absorbing base material were prepared in the same manner as in Example 1, and evaluations were carried out in the same manner as in Example 1. The evaluation results are shown in Tables 1 and 2.
[Reference example 1]
54.9 g _{of SnCl4.5H2O} (Wako Pure Chemical Industries, Wako special grade, purity 98% or more) was dissolved in 340 g of water at 25°C to prepare a tin compound solution. 12.7 ml of a methanol solution (Yoneyama Chemical Industries, reagent special grade, purity 99.8% or more) in which 4.2 g of an antimony compound _SbCl3 (Wako Pure Chemical Industries, JIS special grade, purity 98% or more) was dissolved, and an aqueous _NH4OH solution (Wako Pure Chemical Industries, reagent special grade, concentration 30%) diluted to a concentration of 16% was dropped in parallel into the tin compound solution. Then, by the parallel dropping, a hydroxide containing tin and antimony, which is a precursor of antimony-doped tin oxide (hereinafter abbreviated as ATO) electromagnetic wave absorbing particles, was generated and precipitated.

From the viewpoint of the desired optical properties, the amount of antimony compound added to the tin compound solution was set to 9.5 parts by mass of antimony element per 100 parts by mass of tin (IV) oxide. By adding this amount, ATO electromagnetic wave absorbing particles with approximately 68% by mass of Sn element and approximately 8% by mass of Sb element can be produced.

As mentioned above, ammonia water was used as the alkaline solution used as the precipitant, and the alkaline concentration was 16%, which is 1.6 times the chemical equivalent required for the tin compound and antimony compound to become hydroxides.

The parallel dripping of the methanol solution and the alkaline solution was continued for 25 minutes until the pH of the solution obtained by dripping reached 7.5. After the dripping was completed, the solution was stirred for 10 minutes to ensure homogenization of the system. The temperature of the solution at that time was the same as that during the parallel dripping, 65°C.

Next, the precipitate was washed by repeatedly decanting. It was thoroughly washed until the conductivity of the supernatant liquid from the decantation was 1 mS/cm or less, and then filtered.

The washed precipitate was then wetted with anhydrous ethyl alcohol solution (special grade reagent, purity 99.5% or higher, manufactured by Wako Pure Chemical Industries, Ltd.). During the wet treatment, the mass ratio of the filtered precipitate to the anhydrous ethyl alcohol solution was set to 1:4 (corresponding to an alcohol content of 80%), and the filtered precipitate and the anhydrous ethyl alcohol solution were stirred at room temperature for 1 hour to obtain a precursor. After completion of the wet treatment, the precursor was dried at 90°C for 10 hours to obtain a dried product.

The ATO electromagnetic wave absorbing particle precursor that had been subjected to the moistening treatment was then heated to 700°C in an air atmosphere and calcined for 2 hours to produce the ATO electromagnetic wave absorbing particles of Reference Example 1.

Except for using the ATO electromagnetic wave absorbing particles according to Reference Example 1 instead of the SrMoO2 particles as the electromagnetic _wave absorbing particles, an electromagnetic wave absorbing particle dispersion liquid and an electromagnetic wave absorbing base material according to Reference Example 1 were prepared in the same manner as in Example 1, and evaluations were carried out in the same manner as in Example 1. The evaluation results in Reference Example 1 are shown in Tables 1 and 2.

表１、表２に示した結果によると、実施例１～実施例３で得られた電磁波吸収粒子を用いた、電磁波吸収粒子分散液、電磁波吸収粒子分散体は、可視光透過率が高く、日射透過率を抑制できていることを確認できた。すなわち、可視光領域の透過率が高く、赤外線領域の透過率を抑制できていることを確認できた。

According to the results shown in Tables 1 and 2, it was confirmed that the electromagnetic wave absorbing particle dispersion liquid and the electromagnetic wave absorbing particle dispersion using the electromagnetic wave absorbing particles obtained in Examples 1 to 3 had high visible light transmittance and were able to suppress solar radiation transmittance. In other words, it was confirmed that the transmittance in the visible light region was high and the transmittance in the infrared region was suppressed.

It was also confirmed that the visible light transmittance and solar radiation transmittance were similar to or even superior to ATO, which has traditionally been used as an electromagnetic wave absorbing particle. Therefore, it was confirmed that the electromagnetic wave absorbing particles obtained in Examples 1 to 3 are novel electromagnetic wave absorbing particles that can be used in practical applications.

Claims (10)

An electromagnetic wave absorbing particle containing a complex oxide,
The composite oxide includes an element A, which is one or more elements selected from H, an alkali metal, Mg, and an alkaline earth metal;
B element, which is one or more elements selected from Cr and Mo, and oxygen,
When the amount of substance of the element A contained in the composite oxide is x and the amount of substance of the element B is y, the relationship of 0.001≦x/y≦1.5 is satisfied ,
Electromagnetic wave absorbing particles that absorb near infrared rays and have a volume-based cumulative 50% particle diameter of 1 nm or more and 50 nm or less, and a cumulative 95% particle diameter of 5 nm or more and 100 nm or less, as measured by a particle size distribution measuring device. 2. The electromagnetic wave absorbing particle according to claim 1 , wherein the element A is one or more elements selected from the group consisting of Ca, Sr, Ba and Ra. The A element is one or more elements selected from Ca, Sr, and Ba,
The B element is Mo,
3. The electromagnetic wave absorbing particle according to claim 1, wherein 0.5≦x/y≦1.2 is satisfied. A liquid medium;
4. An electromagnetic wave absorbing particle dispersion comprising: the electromagnetic wave absorbing particles according to claim 1 contained in a liquid medium. 5. The electromagnetic wave absorbing particle dispersion liquid according to claim 4 , wherein the liquid medium contains at least one selected from the group consisting of water, an organic solvent, a liquid plasticizer, an oil or fat, and a compound that is polymerized by curing. A solid medium;
4. An electromagnetic wave absorbing particle dispersion comprising: the electromagnetic wave absorbing particle according to claim 1 contained in the solid medium. 7. The electromagnetic wave absorbing particle dispersion according to claim 6 , wherein the solid medium is a resin. 8. The electromagnetic wave absorbing particle dispersion according to claim 7, wherein the resin is one type of resin selected from the group consisting of polyester resin, polycarbonate resin, acrylic resin, styrene resin, polyamide resin, polyethylene resin, vinyl chloride resin, olefin resin, epoxy resin, polyimide resin, fluororesin, ethylene-vinyl acetate copolymer, polyvinyl acetal resin, and ultraviolet curable resin, or a mixture of two or more types of resins selected from the group . 9. The electromagnetic wave absorbing particle dispersion according to claim 6 , which has a sheet, board or film shape. An electromagnetic wave absorbing particle dispersion according to any one of claims 6 to 9 ,
An electromagnetic wave absorbing laminate having a laminated structure including a transparent substrate.