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JP7701905B2 - Manufacturing method of wound electrode body and manufacturing method of electric storage device - Google Patents
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JP7701905B2 - Manufacturing method of wound electrode body and manufacturing method of electric storage device - Google Patents

Manufacturing method of wound electrode body and manufacturing method of electric storage device Download PDF

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JP7701905B2
JP7701905B2 JP2022201752A JP2022201752A JP7701905B2 JP 7701905 B2 JP7701905 B2 JP 7701905B2 JP 2022201752 A JP2022201752 A JP 2022201752A JP 2022201752 A JP2022201752 A JP 2022201752A JP 7701905 B2 JP7701905 B2 JP 7701905B2
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curvature
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篤志 前田
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Prime Planet Energy and Solutions Inc
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Description

本発明は、各々帯状をなす第1セパレータ、負極板、第2セパレータ及び正極板を重ねて捲回してなる捲回電極体の製造方法、及び、上記捲回電極体を備える蓄電デバイスの製造方法に関する。 The present invention relates to a method for manufacturing a wound electrode assembly in which a first separator, a negative electrode plate, a second separator, and a positive electrode plate, each of which is strip-shaped, are stacked and wound, and a method for manufacturing an electric storage device including the wound electrode assembly.

電池やキャパシタなどの蓄電デバイス内に収容される電極体として、各々帯状をなす第1セパレータ、負極板、第2セパレータ及び正極板を重ねて捲回した、円筒状や扁平状の捲回電極体が知られている。この捲回電極体の製造において、巻き芯の周りに、第1セパレータ、負極板、第2セパレータ及び正極板を重ねて捲回する際、正極板及び負極板のうち、一方の電極板または両方の電極板で巻きズレが生じ得る。 As an electrode body to be housed in an electricity storage device such as a battery or a capacitor, a cylindrical or flat wound electrode body is known, in which a first separator, a negative electrode plate, a second separator, and a positive electrode plate, each of which is in the shape of a strip, are stacked and wound. In manufacturing this wound electrode body, when the first separator, the negative electrode plate, the second separator, and the positive electrode plate are stacked and wound around the winding core, a winding misalignment may occur in one or both of the positive and negative electrode plates.

この問題に対して従来は、エッジセンサにより、搬送中の電極板のうち、幅方向の一端縁(エッジ)の幅方向位置を検知し、この検知した幅方向位置に基づいて、幅方向位置が予め定めた基準幅方向位置となるように当該電極板の幅方向位置をエッジポジションコントロール(EPC)により調整しつつ、電極板等の捲回を行っていた。これにより、電極板の巻きズレを抑制していた。関連する従来技術として、例えば特許文献1が挙げられる(特許文献1の図1等を参照)。 To address this problem, conventionally, an edge sensor is used to detect the widthwise position of one edge (edge) of the electrode plate being transported, and based on this detected widthwise position, the widthwise position of the electrode plate is adjusted by edge position control (EPC) so that the widthwise position becomes a predetermined reference widthwise position while winding the electrode plate. This prevents the electrode plate from being misaligned when wound. For example, Patent Document 1 is an example of related prior art (see Figure 1 of Patent Document 1, etc.).

特開2003-297412号公報JP 2003-297412 A

しかしながら、上述の捲回工程に用いる帯状の電極板は、その幅方向に湾曲している場合がある。電極板が湾曲していると、その湾曲量が大きいほど電極板の巻きズレが大きくなるため、上述のエッジセンサ及びEPCを用いた電極板の位置制御だけでは、電極板の巻きズレを十分に抑制できない場合がある。特に生産性を向上させるために電極板の搬送速度を上げると、制御が追い付かず、電極板の巻きズレを抑制できなくなる。 However, the belt-shaped electrode plate used in the winding process described above may be curved in its width direction. If the electrode plate is curved, the greater the amount of curvature, the greater the winding misalignment of the electrode plate. Therefore, the position control of the electrode plate using the edge sensor and EPC described above may not be enough to suppress the winding misalignment of the electrode plate. In particular, if the conveying speed of the electrode plate is increased to improve productivity, the control cannot keep up, and the winding misalignment of the electrode plate cannot be suppressed.

本発明は、かかる現状に鑑みてなされたものであって、捲回工程で生じ得る電極板の巻きズレを適切に抑制できる捲回電極体の製造方法、及び、上記捲回電極体を備える蓄電デバイスの製造方法を提供する。 The present invention has been made in consideration of the current situation, and provides a method for manufacturing a wound electrode assembly that can appropriately suppress misalignment of the electrode plate during the winding process, and a method for manufacturing an electricity storage device that includes the wound electrode assembly.

(1)上記課題を解決するための本発明の一態様は、各々帯状をなす第1セパレータ、負極板、第2セパレータ及び正極板を重ねて捲回してなる捲回電極体の製造方法であって、巻き芯の周りに、上記第1セパレータ、上記負極板、上記第2セパレータ及び上記正極板を重ねて捲回する捲回工程を備え、上記捲回工程は、上記正極板及び上記負極板の少なくとも一方の電極板について、搬送中の上記電極板の幅方向位置を検知し、この検知した幅方向位置と、当該電極体について実際に測定された実測湾曲量ではなく、当該電極板の推定された推定湾曲量とに基づいて、上記幅方向位置が基準幅方向位置となるように当該電極板の上記幅方向位置を制御しつつ捲回する捲回電極体の製造方法である。 (1) One aspect of the present invention for solving the above problem is a manufacturing method for a wound electrode body obtained by stacking and winding a first separator, a negative electrode plate, a second separator, and a positive electrode plate, each of which is in the shape of a strip, the manufacturing method including a winding step of stacking and winding the first separator, the negative electrode plate, the second separator, and the positive electrode plate around a winding core, the winding step detecting a width direction position of at least one of the electrode plates, the positive electrode plate and the negative electrode plate, during transport, and winding the electrode plate while controlling the width direction position of the electrode plate based on the detected width direction position and an estimated amount of curvature of the electrode plate, rather than an actual measured amount of curvature of the electrode body, so that the width direction position becomes a reference width direction position.

上述の捲回電極体の製造方法では、捲回工程において、検知した電極板の幅方向位置と、この電極板の推定湾曲量とに基づいて、幅方向位置が基準幅方向位置となるように電極板の幅方向位置を制御しつつ、電極板等の捲回を行う。このため、従来のように電極板の湾曲量を加味せずに、単に検知した幅方向位置に基づいて電極板の幅方向位置を制御する場合に比べて、捲回工程で生じ得る電極板の巻きズレを適切に抑制できる。
また当該捲回工程で用いる個々の電極板の湾曲量を実際に測定するのは、測定精度や生産コストの観点から難しい場合がある。これに対し、上述の製造方法では、当該電極体について実際に測定された実測湾曲量ではなく、推定された推定湾曲量を用いるので、当該電極体の実測湾曲量を得る必要がない。
In the above-mentioned method for manufacturing a wound electrode body, in the winding step, the width direction position of the electrode plate is controlled based on the detected width direction position of the electrode plate and the estimated curvature amount of the electrode plate so that the width direction position becomes a reference width direction position, while the electrode plate is wound. Therefore, compared to the conventional case in which the width direction position of the electrode plate is controlled simply based on the detected width direction position without taking into account the curvature amount of the electrode plate, it is possible to appropriately suppress winding deviation of the electrode plate that may occur in the winding step.
In addition, it may be difficult to actually measure the amount of curvature of each electrode plate used in the winding process from the viewpoints of measurement accuracy and production costs. In contrast, in the above-mentioned manufacturing method, an estimated amount of curvature is used instead of an actual measured amount of curvature of the electrode body, so there is no need to obtain an actual measured amount of curvature of the electrode body.

なお、電極板の「幅方向位置」とは、電極板のうち、幅方向の一端縁、幅方向の中央など、幅方向の特定位置をいう。また電極板の幅方向位置を検知する手法としては、例えば、レーザを利用して電極板の幅方向位置を検知する手法や、カメラを利用して電極板の幅方向位置を検知する手法などが挙げられる。
電極板の幅方向位置が基準幅方向位置となるように電極板の幅方向位置を制御する手法としては、例えば、電極板を搬送する位置調整ロールを、そのロール軸線方向に沿って移動(スライド)させたり、位置調整ロールの傾きを変えることにより、電極板の幅方向位置を移動させて、幅方向位置を基準幅方向位置とする手法が挙げられる。
The "width direction position" of the electrode plate refers to a specific position in the width direction of the electrode plate, such as one edge in the width direction, the center in the width direction, etc. Examples of a method for detecting the width direction position of the electrode plate include a method for detecting the width direction position of the electrode plate using a laser, and a method for detecting the width direction position of the electrode plate using a camera.
Examples of a method for controlling the width direction position of the electrode plate so that the width direction position of the electrode plate becomes the reference width direction position include a method in which the position adjustment roll that transports the electrode plate is moved (slid) along the roll axis direction or the inclination of the position adjustment roll is changed to move the width direction position of the electrode plate and set the width direction position to the reference width direction position.

(2)更に(1)に記載の捲回電極体の製造方法であって、前記電極板は、長尺の長尺電極板を予めロール状に巻き取った電極ロールから、上記長尺電極板を巻き出して切断した電極板であり、前記捲回工程は、上記電極ロールの巻き出し当初から、当該捲回工程で用いる部分まで巻き出した、上記長尺電極板の巻き出し長さを検知する巻出長検知工程と、検知した上記巻き出し長さと、上記長尺電極板のうち、上記電極ロールの最内周に位置する最内周部における湾曲量である最内周湾曲量と、上記長尺電極板のうち、上記電極ロールの当初の最外周に位置する最外周部における湾曲量である最外周湾曲量とに基づいて、当該捲回工程で用いる上記電極板の湾曲量を推定して前記推定湾曲量を得る湾曲量推定工程と、を有する捲回電極体の製造方法とすると良い。 (2) Further, in the method for manufacturing the wound electrode body described in (1), the electrode plate is an electrode plate obtained by unwinding and cutting a long electrode plate from an electrode roll in which a long electrode plate has been wound in a roll shape in advance, and the winding process may include a winding length detection process for detecting the unwound length of the long electrode plate unwound from the beginning of unwinding the electrode roll to the part used in the winding process, and a curvature amount estimation process for estimating the curvature amount of the electrode plate used in the winding process based on the detected unwound length, an innermost curvature amount which is the curvature amount at the innermost part of the long electrode plate located at the innermost part of the electrode roll, and an outermost curvature amount which is the curvature amount at the outermost part of the long electrode plate located at the initial outermost part of the electrode roll, to obtain the estimated curvature amount.

長尺電極板をロール状に巻き取った電極ロールでは、内周側と外周側とで長尺電極板の湾曲量が異なる。具体的には、長尺電極板の湾曲量は、最内周で最も小さく、外周ほど大きく、最外周で最も大きいことが判ってきた。長尺電極板をロール状に巻き取る際や、電極ロールの保存期間中における経時的な変化により、電極ロールの外周ほど長尺電極板の湾曲量が大きくなると考えられる。従って、同じ電極ロールから長尺電極板を巻き出して切断した電極板同士でも、電極板毎に湾曲量が異なる。 In an electrode roll made by winding a long electrode plate into a roll, the amount of curvature of the long electrode plate differs between the inner and outer circumferences. Specifically, it has been found that the amount of curvature of the long electrode plate is smallest at the innermost circumference, larger toward the outer circumference, and largest at the outermost circumference. It is thought that the amount of curvature of the long electrode plate becomes greater toward the outer circumference of the electrode roll when the long electrode plate is wound into a roll and due to changes over time during the storage period of the electrode roll. Therefore, even electrode plates that are unwound and cut from the same electrode roll have different amounts of curvature for each electrode plate.

これに対し、上述の捲回電極体の製造方法では、長尺電極板の電極ロールからの巻き出し長さを検知して、この巻き出し長さと、長尺電極板の最内周部の最内周湾曲量と、長尺電極板の最外周部の最外周湾曲量とに基づいて、当該捲回工程で用いる電極板の湾曲量を推定する。これにより、個々の電極板の湾曲量を適切に推定できるので、この推定湾曲量を用いて捲回工程を行うことで、より適切に電極板の巻きズレを抑制できる。 In contrast, in the above-mentioned method for manufacturing a wound electrode body, the unwound length of the long electrode plate from the electrode roll is detected, and the amount of curvature of the electrode plate to be used in the winding process is estimated based on this unwound length, the amount of innermost curvature of the innermost part of the long electrode plate, and the amount of outermost curvature of the outermost part of the long electrode plate. This allows the amount of curvature of each electrode plate to be appropriately estimated, and by performing the winding process using this estimated amount of curvature, it is possible to more appropriately suppress winding misalignment of the electrode plate.

なお、「巻き出し長さ」は、例えば、電極ロールから長尺電極板を巻き出し始めた時点からの電極ロールの回転角度に基づいて算出できる。また巻き出し長さは、長尺電極板の搬送速度と、電極ロールから長尺電極板を巻き出し始めた時点からの長尺電極板の搬送時間とに基づいて算出することもできる。
「最内周湾曲量」には、長尺電極板を電極ロールとして巻き取り始める前に予め測定した、長尺電極板の巻き取り始め部における湾曲量を用いるのが好ましい。
また「最外周湾曲量」には、捲回工程を行うのに先立って測定した、電極ロールから最初に巻き出した長尺電極板の巻き出し始め部における湾曲量を用いるのが好ましい。
The "unrolling length" can be calculated, for example, based on the rotation angle of the electrode roll from the point when the long electrode plate starts to be unrolled from the electrode roll. The unrolling length can also be calculated based on the transport speed of the long electrode plate and the transport time of the long electrode plate from the point when the long electrode plate starts to be unrolled from the electrode roll.
The "amount of curvature at the innermost periphery" is preferably the amount of curvature at the start of winding the long electrode plate, which is measured in advance before starting to wind the long electrode plate into an electrode roll.
Furthermore, for the "outermost circumference curvature amount", it is preferable to use the curvature amount at the start of unwinding of the long electrode plate first unwound from the electrode roll, measured prior to the winding step.

(3)また他の態様は、各々帯状をなす第1セパレータ、負極板、第2セパレータ及び正極板を重ねて捲回してなる捲回電極体を備える蓄電デバイスの製造方法であって、(1)または(2)に記載の捲回電極体の製造方法により、上記捲回電極体を製造する電極体製造工程と、上記捲回電極体を用いて、上記蓄電デバイスを組み立てるデバイス組立工程と、を備える蓄電デバイスの製造方法である。 (3) Yet another aspect is a method for manufacturing an electric storage device having a wound electrode body formed by stacking and winding a first separator, a negative electrode plate, a second separator, and a positive electrode plate, each of which is in the shape of a strip, the method comprising: an electrode body manufacturing process for manufacturing the wound electrode body by the wound electrode body manufacturing process described in (1) or (2); and a device assembly process for assembling the electric storage device using the wound electrode body.

上述の蓄電デバイスの製造方法では、電極体製造工程で電極板の巻きズレが抑制された捲回電極体を形成できるので、電極板の巻きズレが抑制された捲回電極体を備えた蓄電デバイスを製造できる。 The manufacturing method for the electricity storage device described above makes it possible to form a wound electrode body in which the winding misalignment of the electrode plate is suppressed during the electrode body manufacturing process, and therefore makes it possible to manufacture an electricity storage device equipped with a wound electrode body in which the winding misalignment of the electrode plate is suppressed.

なお、「蓄電デバイス」としては、例えば、リチウムイオン二次電池等の二次電池や、リチウムイオンキャパシタ等のキャパシタ、全固体電池などが挙げられる。また蓄電デバイスは、捲回電極体を単数備えていても複数備えていてもよい。 The "electricity storage device" may be, for example, a secondary battery such as a lithium ion secondary battery, a capacitor such as a lithium ion capacitor, or an all-solid-state battery. The electricity storage device may include a single or multiple wound electrode bodies.

実施形態に係る電池の斜視図である。FIG. 1 is a perspective view of a battery according to an embodiment. 実施形態に係る捲回電極体の斜視図である。FIG. 2 is a perspective view of a wound electrode body according to the embodiment. 実施形態に係る捲回電極体の展開図である。FIG. 2 is a development view of a wound electrode body according to the embodiment. 実施形態に係り、捲回電極体の製造方法を含む電池の製造方法のフローチャートである。4 is a flowchart of a method for manufacturing a battery including a method for manufacturing a wound electrode assembly according to an embodiment. 実施形態に係り、捲回工程を行う捲回装置の説明図である。FIG. 2 is an explanatory diagram of a winding device that performs a winding step in the embodiment. 実施形態に係り、正極板の幅方向位置の調整を示す説明図である。10A to 10C are explanatory diagrams illustrating adjustment of the width direction position of the positive electrode plate in the embodiment. 実施形態に係り、正極ロールの説明図である。FIG. 2 is an explanatory diagram of a positive electrode roll in the embodiment. 電極板の湾曲量Wを示す説明図である。11 is an explanatory diagram showing a bending amount W of an electrode plate. FIG. 正極ロールをなす長尺正極板の巻き出し長さLと湾曲量Wとの関係を示すグラフである。1 is a graph showing the relationship between the unwound length L and the amount of curvature W of a long positive electrode plate that constitutes a positive electrode roll. 変形形態に係り、正極板の幅方向位置の調整を示す説明図である。13A and 13B are explanatory diagrams showing adjustment of the width direction position of the positive electrode plate according to a modified embodiment.

(実施形態)
以下、本発明の実施形態を、図面を参照しつつ説明する。図1に本実施形態に係る電池(蓄電デバイス)1の斜視図を、図2に電池1が備える捲回電極体20の斜視図を、図3に捲回電極体20の展開図を示す。なお、以下では、電池1の電池高さ方向AH、電池幅方向BH及び電池厚み方向CHを、図1に示す方向と定めて説明する。この電池1は、ハイブリッドカーやプラグインハイブリッドカー、電気自動車等の車両などに搭載される角型(直方体状)で密閉型のリチウムイオン二次電池である。
(Embodiment)
Hereinafter, an embodiment of the present invention will be described with reference to the drawings. Fig. 1 shows a perspective view of a battery (electricity storage device) 1 according to this embodiment, Fig. 2 shows a perspective view of a wound electrode body 20 provided in the battery 1, and Fig. 3 shows a developed view of the wound electrode body 20. In the following, the battery height direction AH, battery width direction BH, and battery thickness direction CH of the battery 1 are defined as the directions shown in Fig. 1. The battery 1 is a rectangular (rectangular) sealed lithium ion secondary battery that is mounted on vehicles such as hybrid cars, plug-in hybrid cars, and electric cars.

電池1は、ケース10と、ケース10内に収容された扁平状の捲回電極体20と、ケース10のケース上部11にそれぞれ支持された正極端子40及び負極端子50等から構成されている。捲回電極体20は、ケース10内で、絶縁フィルムからなる袋状の図示しない絶縁ホルダに覆われている。またケース10内には、電解液3が収容されており、その一部は捲回電極体20内に含浸され、残りはケース10のケース底部12上に溜まっている。 The battery 1 is composed of a case 10, a flat wound electrode body 20 housed in the case 10, and a positive electrode terminal 40 and a negative electrode terminal 50 each supported on the case top 11 of the case 10. Inside the case 10, the wound electrode body 20 is covered by a bag-shaped insulating holder (not shown) made of insulating film. Also, the case 10 contains an electrolyte 3, a part of which is impregnated in the wound electrode body 20 and the remainder is stored on the case bottom 12 of the case 10.

このうちケース10は、金属(本実施形態ではアルミニウム)からなる直方体箱状であり、電池高さ方向AHの上側AH1に矩形環状の開口部15cを有する有底角筒状の本体部材15と、開口部15cを閉塞する形態で本体部材15に全周にわたりレーザ溶接された矩形板状の蓋部材16とから構成されている。
ケース上部11をなす蓋部材16には、ケース10の内圧が開弁圧を超えたときに破断して開弁する安全弁17が設けられている。またケース上部11には、ケース10の内外を連通する注液孔16kが設けられており、アルミニウムからなる円板状の封止部材18で気密に封止されている。
Of these, the case 10 is a rectangular box made of metal (aluminum in this embodiment) and is composed of a bottomed, square cylindrical main body member 15 having a rectangular annular opening 15c on the upper side AH1 in the battery height direction AH, and a rectangular plate-shaped cover member 16 that is laser welded to the main body member 15 around its entire circumference in a manner that closes the opening 15c.
A cover member 16 constituting the case upper portion 11 is provided with a safety valve 17 that breaks and opens when the internal pressure of the case 10 exceeds a valve opening pressure. A liquid injection hole 16k that communicates between the inside and outside of the case 10 is also provided in the case upper portion 11, and is airtightly sealed with a disk-shaped sealing member 18 made of aluminum.

更にケース上部11のうち、電池幅方向BHの一方側BH1の端部近傍には、アルミニウムからなる正極端子40が、樹脂部材45を介してケース上部11と絶縁された状態で固設されている。この正極端子40は、ケース10内で、捲回電極体20のうち正極板21の集電部21dに接続し導通する一方、ケース上部11を貫通して電池外部まで延びている。
またケース上部11のうち、電池幅方向BHの他方側BH2の端部近傍には、銅からなる負極端子50が、樹脂部材55を介してケース上部11と絶縁された状態で固設されている。この負極端子50は、ケース10内で、捲回電極体20のうち負極板25の集電部25dに接続し導通する一方、ケース上部11を貫通して電池外部まで延びている。
Furthermore, a positive electrode terminal 40 made of aluminum is fixed to the case upper portion 11 near an end portion on one side BH1 in the width direction BH of the battery, insulated from the case upper portion 11 via a resin member 45. This positive electrode terminal 40 is connected to and conductively connected to the current collecting portion 21d of the positive electrode plate 21 of the wound electrode body 20 within the case 10, and also extends through the case upper portion 11 to the outside of the battery.
A negative electrode terminal 50 made of copper is fixed to the case upper portion 11 near the end portion on the other side BH2 in the width direction BH of the battery, insulated from the case upper portion 11 via a resin member 55. This negative electrode terminal 50 is connected to and conductive with the current collecting portion 25d of the negative electrode plate 25 of the wound electrode body 20 within the case 10, and also extends through the case upper portion 11 to the outside of the battery.

次に捲回電極体20について説明する。この捲回電極体20は、帯状の第1セパレータ31と、帯状の負極板(電極板)25と、帯状の第2セパレータ35と、帯状の正極板(電極板)21とを重ねて円筒状に捲回した後に、扁平状にプレスしたものである。捲回電極体20は、横倒しの状態でケース10内に収容されている。
第1セパレータ31及び第2セパレータ35は、それぞれ樹脂製の多孔質膜からなる。
Next, the wound electrode body 20 will be described. The wound electrode body 20 is formed by stacking a strip-shaped first separator 31, a strip-shaped negative electrode plate (electrode plate) 25, a strip-shaped second separator 35, and a strip-shaped positive electrode plate (electrode plate) 21, winding them into a cylindrical shape, and then pressing them into a flat shape. The wound electrode body 20 is housed in the case 10 in a laid-down state.
The first separator 31 and the second separator 35 are each made of a porous resin film.

正極板21は、帯状のアルミニウム箔からなる集電箔22を有する。この集電箔22の両主面上には、それぞれリチウムイオンを吸蔵及び放出可能な正極活物質粒子を含む活物質層23が帯状に形成されている。正極板21のうち、集電箔22上に活物質層23が形成された部位が、活物質部21cである。一方、正極板21のうち、幅方向EHの片方の端部は、集電箔22上に活物質層23が存在せず、集電箔22が露出した集電部21dとなっている。この集電部21dは、捲回電極体20の電池幅方向BHの一方側BH1に渦巻き状をなして突出しており、前述のように正極端子40と接続している。 The positive electrode plate 21 has a current collector foil 22 made of a strip-shaped aluminum foil. On both main surfaces of the current collector foil 22, active material layers 23 containing positive electrode active material particles capable of absorbing and releasing lithium ions are formed in a strip shape. The part of the positive electrode plate 21 where the active material layer 23 is formed on the current collector foil 22 is the active material portion 21c. On the other hand, one end of the positive electrode plate 21 in the width direction EH is a current collector portion 21d where the active material layer 23 is not present on the current collector foil 22 and the current collector foil 22 is exposed. This current collector portion 21d protrudes in a spiral shape on one side BH1 of the wound electrode body 20 in the battery width direction BH, and is connected to the positive electrode terminal 40 as described above.

負極板25は、帯状の銅箔からなる集電箔26を有する。この集電箔26の両主面上には、それぞれリチウムイオンを吸蔵及び放出可能な負極活物質粒子を含む活物質層27が帯状に形成されている。負極板25のうち、集電箔26上に活物質層27が形成された部位が、活物質部25cである。一方、負極板25のうち幅方向EHの片方の端部は、集電箔26上に活物質層27が存在せず、集電箔26が露出した集電部25dとなっている。この集電部25dには、捲回電極体20の電池幅方向BHの他方側BH2に渦巻き状をなして突出しており、前述のように負極端子50と接続している。 The negative electrode plate 25 has a current collector 26 made of a strip-shaped copper foil. On both main surfaces of the current collector 26, a strip-shaped active material layer 27 containing negative active material particles capable of absorbing and releasing lithium ions is formed. The part of the negative electrode plate 25 where the active material layer 27 is formed on the current collector 26 is the active material part 25c. On the other hand, one end of the negative electrode plate 25 in the width direction EH is a current collector 25d where the active material layer 27 is not present on the current collector 26 and the current collector 26 is exposed. This current collector 25d protrudes in a spiral shape to the other side BH2 of the wound electrode body 20 in the battery width direction BH, and is connected to the negative electrode terminal 50 as described above.

次いで捲回電極体20の製造方法、この捲回電極体20を用いた電池1の製造方法について説明する(図4~図9参照)。
まず「電極体製造工程S1」(図4参照)において、捲回電極体20(図2参照)を製造する。具体的には、まず、正極ロール(電極ロール)21R(図7及び図5参照)と、負極ロール(電極ロール)25Rと、第1セパレータロール31Rと、第2セパレータロール35Rとをそれぞれ用意する。
Next, a method for manufacturing the wound electrode body 20 and a method for manufacturing the battery 1 using this wound electrode body 20 will be described (see FIGS. 4 to 9).
First, in the "electrode assembly manufacturing process S1" (see FIG. 4), the wound electrode assembly 20 (see FIG. 2) is manufactured. Specifically, first, the positive electrode roll (electrode roll) 21R (see FIGS. 7 and 5), the negative electrode roll (electrode roll) 25R, the first separator roll 31R, and the second separator roll 35R are prepared.

正極ロール21Rは、切断により複数の正極板21(長さ約4m)となる長尺の長尺正極板(長尺電極板)21Z(長さ約4000m)を予めロール状に巻き取ったものである。また負極ロール25R(長さ約4m)は、切断により複数の負極板25となる長尺の長尺負極板(長尺電極板)25Z(長さ約4000m)を予めロール状に巻き取ったものである。また第1セパレータロール31Rは、切断により複数の第1セパレータ31(長さ約4m)となる長尺の長尺第1セパレータ31Z(長さ約4000m)を予めロール状に巻き取ったものである。また第2セパレータロール35Rは、切断により複数の第2セパレータ35(長さ約4m)となる長尺の長尺第2セパレータ35Z(長さ約4000m)を予めロール状に巻き取ったものである。なお、以下では、「長尺正極板21Z」を「長尺電極板21Z」、「長尺負極板25Z」を「長尺電極板25Z」、「正極板21」を「電極板21」、「負極板25」を「電極板25」と言うことがある。 The positive electrode roll 21R is a roll of a long positive electrode plate (long electrode plate) 21Z (length: about 4000 m) that will be cut into a plurality of positive electrode plates 21 (length: about 4 m). The negative electrode roll 25R (length: about 4 m) is a roll of a long negative electrode plate (long electrode plate) 25Z (length: about 4000 m) that will be cut into a plurality of negative electrode plates 25. The first separator roll 31R is a roll of a long first separator 31Z (length: about 4000 m) that will be cut into a plurality of first separators 31 (length: about 4 m). The second separator roll 35R is a roll of a long second separator 35Z (length: about 4000 m) that will be cut into a plurality of second separators 35 (length: about 4 m). In the following, the "long positive electrode plate 21Z" may be referred to as the "long electrode plate 21Z," the "long negative electrode plate 25Z" may be referred to as the "long electrode plate 25Z," the "positive electrode plate 21" may be referred to as the "electrode plate 21," and the "negative electrode plate 25" may be referred to as the "electrode plate 25."

ここで、電極板21,25(長尺電極板21Z,25Z)の湾曲について説明する(図8参照)。電極板21,25は、前述のように、集電箔22,26の両主面上に活物質層23,27が形成された活物質部21c,25cと、集電箔22,26のみからなる集電部21d,25dとを有する。電極板21,25は、活物質層23,27の密度を高めるためにロールプレスされている。このロールプレスの際、集電箔22,26のうち、活物質部21c,25cをなす部位は、ロールプレスにより圧延されて長手方向DHに延びるが、集電部21d,25dをなす部位は、活物質層23,27が存在せず、プレス圧が殆ど掛からないため、殆ど延びない。このため、ロールプレスされた電極板21,25は、幅方向EHに湾曲している。更に長尺電極板21Z,25Zをロール状に巻き取って電極ロール21R,25Rを形成する際に掛かる張力や、巻取り状態の電極ロール21R,25Rの保存期間中に掛かる張力による経時的な変化により、電極ロール21R,25Rの外周ほど、長尺電極板21Z,25Zの湾曲量Wが大きくなることが判ってきた。 Here, the curvature of the electrode plates 21, 25 (long electrode plates 21Z, 25Z) will be described (see FIG. 8). As described above, the electrode plates 21, 25 have active material parts 21c, 25c in which active material layers 23, 27 are formed on both main surfaces of the current collector foils 22, 26, and current collector parts 21d, 25d consisting only of the current collector foils 22, 26. The electrode plates 21, 25 are roll-pressed to increase the density of the active material layers 23, 27. During this roll-pressing, the parts of the current collector foils 22, 26 that form the active material parts 21c, 25c are rolled by the roll press and extend in the longitudinal direction DH, but the parts that form the current collector parts 21d, 25d do not have the active material layers 23, 27 and are hardly subjected to pressing pressure, so they do not extend much. For this reason, the roll-pressed electrode plates 21, 25 are curved in the width direction EH. Furthermore, it has been found that the amount of curvature W of the long electrode plates 21Z, 25Z increases toward the outer periphery of the electrode rolls 21R, 25R due to the tension applied when the long electrode plates 21Z, 25Z are wound into a roll to form the electrode rolls 21R, 25R, and due to changes over time caused by the tension applied during storage of the wound electrode rolls 21R, 25R.

本実施形態では、電極板21,25(長尺電極板21Z,25Z)の湾曲量Wを、以下のように規定する。即ち、電極板21,25の長手方向DHに所定の間隔で並んだ3つのエッジ位置(エッジ位置A、エッジ位置C、エッジ位置B)について、エッジ位置Aからエッジ位置Bまでの長手方向DHの長さを長手方向長さa、エッジ位置Aとエッジ位置Bとを結ぶ仮想直線D(図8中に破線で示す)から、エッジ位置Cまでの幅方向EHの距離を幅方向ズレ量bとし、長手方向長さaに対する幅方向ズレ量bを、湾曲量W(=b/a)とする。例えば、長手方向長さa=2000mm、幅方向ズレ量b=2.0mmの場合、湾曲量W=2.0/2000=0.0010となる。 In this embodiment, the curvature W of the electrode plates 21, 25 (long electrode plates 21Z, 25Z) is defined as follows. That is, for three edge positions (edge position A, edge position C, edge position B) arranged at a predetermined interval in the longitudinal direction DH of the electrode plates 21, 25, the length in the longitudinal direction DH from edge position A to edge position B is the longitudinal length a, the distance in the width direction EH from the virtual straight line D (shown by a dashed line in FIG. 8) connecting edge position A and edge position B to edge position C is the width direction deviation b, and the width direction deviation b relative to the longitudinal length a is the curvature W (= b/a). For example, when the longitudinal length a = 2000 mm and the width direction deviation b = 2.0 mm, the curvature W = 2.0/2000 = 0.0010.

電極体製造工程S1では、まず「捲回工程S11」(図4参照)において、円筒状の巻き芯111の周りに、第1セパレータ31、負極板25、第2セパレータ35及び正極板21を、この順に重ねて円筒状に捲回して、円筒捲回電極体20Yを形成する。この捲回工程S11は、捲回装置100(図5及び図6参照)を用いて行う。捲回装置100は、第1セパレータ供給部101と、負極板供給部102と、第2セパレータ供給部103と、正極板供給部104と、巻取部110とを備える。 In the electrode body manufacturing process S1, first, in the "winding process S11" (see FIG. 4), the first separator 31, the negative electrode plate 25, the second separator 35, and the positive electrode plate 21 are stacked in this order and wound cylindrically around a cylindrical winding core 111 to form a cylindrical wound electrode body 20Y. This winding process S11 is performed using a winding device 100 (see FIG. 5 and FIG. 6). The winding device 100 includes a first separator supply unit 101, a negative electrode plate supply unit 102, a second separator supply unit 103, a positive electrode plate supply unit 104, and a winding unit 110.

このうち各供給部(第1セパレータ供給部101、負極板供給部102、第2セパレータ供給部103及び正極板供給部104)には、前述の各ロール(第1セパレータロール31R、負極ロール25R、第2セパレータロール35R及び正極ロール21R)が取り付けられる。各供給部は、各ロールから、各長尺部材(長尺第1セパレータ31Z、長尺負極板25Z、長尺第2セパレータ35Z及び長尺正極板21Z)を、それぞれ巻取部110に向けて送り出すように構成されている。また各供給部から巻取部110に至る各長尺部材の搬送経路には、それぞれ各長尺部材を搬送する複数の搬送ローラ(不図示)が設けられている。
一方、巻取部110には、巻き芯111が取り付けられる。巻取部110は、この巻き芯111の周りに、第1セパレータ31(長尺第1セパレータ31Z)、負極板25(長尺負極板25Z)、第2セパレータ35(長尺第2セパレータ35Z)及び正極板21(長尺正極板21Z)を重ねて巻き取るように構成されている。
Among these, the aforementioned rolls (first separator roll 31R, negative electrode roll 25R, second separator roll 35R, and positive electrode roll 21R) are attached to each of the supplying parts (first separator supplying part 101, negative electrode plate supplying part 102, second separator supplying part 103, and positive electrode plate supplying part 104). Each supplying part is configured to send out each long member (long first separator 31Z, long negative electrode plate 25Z, long second separator 35Z, and long positive electrode plate 21Z) from each roll toward the winding part 110. In addition, a plurality of conveying rollers (not shown) that convey each long member are provided on the conveying path of each long member from each supplying part to the winding part 110.
On the other hand, a winding core 111 is attached to the winding unit 110. The winding unit 110 is configured to wind up the first separator 31 (long first separator 31Z), the negative electrode plate 25 (long negative electrode plate 25Z), the second separator 35 (long second separator 35Z), and the positive electrode plate 21 (long positive electrode plate 21Z) in a stacked manner around the winding core 111.

また捲回装置100は、各供給部(第1セパレータ供給部101、負極板供給部102、第2セパレータ供給部103及び正極板供給部104)と巻取部110との間に、それぞれ切断部(第1セパレータ切断部121、負極板切断部122、第2セパレータ切断部123及び正極板切断部124)を備える。これらの切断部は、それぞれ各長尺部材(長尺第1セパレータ31Z、長尺負極板25Z、長尺第2セパレータ35Z及び長尺正極板21Z)をそれらの幅方向に切断して、各部材(第1セパレータ31、負極板25、第2セパレータ35及び正極板21)を切り出すように構成されている。 The winding device 100 also includes cutting sections (first separator cutting section 121, negative electrode plate cutting section 122, second separator cutting section 123, and positive electrode plate cutting section 124) between each supply section (first separator supply section 101, negative electrode plate supply section 102, second separator supply section 103, and positive electrode plate supply section 104) and the winding section 110. These cutting sections are configured to cut each long member (long first separator 31Z, long negative electrode plate 25Z, long second separator 35Z, and long positive electrode plate 21Z) in their width direction to cut out each member (first separator 31, negative electrode plate 25, second separator 35, and positive electrode plate 21).

更に捲回装置100は、正極板21(長尺正極板21Z)の搬送経路に、エッジセンサ130と、位置調整機構140と、巻出長検知部150とを備える。また捲回装置100は、制御部160を備える。
このうちエッジセンサ130は、位置調整機構140よりも下流側で、正極板切断部124と巻取部110との間に設けられており、搬送中の正極板21の幅方向EHの一端縁(エッジ)の幅方向位置Px(図6参照)を検知する。本実施形態では、エッジセンサ130として、レーザを利用して幅方向位置Pxを検知するエッジセンサを用いている。なお、エッジセンサ130の設置位置は、上記に限定されず、例えば、エッジセンサ130を、位置調整機構140と正極板切断部124との間や、位置調整機構140よりも上流側(位置調整機構140と正極板供給部104との間)に設けることもできる。またエッジセンサ130として、カメラを利用して幅方向位置Pxを検知するエッジセンサを用いてもよい。
The winding device 100 further includes an edge sensor 130, a position adjustment mechanism 140, and an unwinding length detection unit 150 on the transport path of the positive electrode plate 21 (long positive electrode plate 21Z).
Among these, the edge sensor 130 is provided downstream of the position adjustment mechanism 140 between the positive electrode plate cutting section 124 and the winding section 110, and detects the width direction position Px (see FIG. 6) of one end edge (edge) in the width direction EH of the positive electrode plate 21 being transported. In this embodiment, an edge sensor that detects the width direction position Px using a laser is used as the edge sensor 130. Note that the installation position of the edge sensor 130 is not limited to the above, and for example, the edge sensor 130 can be provided between the position adjustment mechanism 140 and the positive electrode plate cutting section 124 or upstream of the position adjustment mechanism 140 (between the position adjustment mechanism 140 and the positive electrode plate supply section 104). Also, an edge sensor that detects the width direction position Px using a camera may be used as the edge sensor 130.

位置調整機構140は、正極板供給部104と正極板切断部124との間に設けられている(図5参照)。位置調整機構140は、正極板21を搬送しつつ、正極板21の幅方向位置Pxを調整する(図6参照)。本実施形態の位置調整機構140は、ロール軸線RXの傾きを変更可能に構成された位置調整ロール141を有している。そして、この位置調整ロール141の傾きを変更することにより、正極板21の幅方向位置Pxを調整できる。 The position adjustment mechanism 140 is provided between the positive electrode plate supply unit 104 and the positive electrode plate cutting unit 124 (see FIG. 5). The position adjustment mechanism 140 adjusts the widthwise position Px of the positive electrode plate 21 while transporting the positive electrode plate 21 (see FIG. 6). In this embodiment, the position adjustment mechanism 140 has a position adjustment roll 141 that is configured to be able to change the inclination of the roll axis RX. The widthwise position Px of the positive electrode plate 21 can be adjusted by changing the inclination of the position adjustment roll 141.

巻出長検知部150は、正極板供給部104の近傍に設けられている(図5参照)。この巻出長検知部150は、正極ロール21Rの巻き出し当初から、当該捲回工程S11で用いる部分まで巻き出した、長尺正極板21Zの巻き出し長さLを検知するように構成されている。本実施形態では、正極ロール21Rから長尺正極板21Zの巻き出しを始めた時点からの正極ロール21Rの回転角度θに基づいて、巻き出し長さLを算出する。なお、長尺正極板21Zの搬送速度と、正極ロール21Rから長尺正極板21Zの巻き出しを始めた時点からの搬送時間とに基づいて、巻き出し長さLを算出する構成を採用してもよい。 The unwinding length detection unit 150 is provided near the positive electrode plate supply unit 104 (see FIG. 5). This unwinding length detection unit 150 is configured to detect the unwinding length L of the long positive electrode plate 21Z unwound from the beginning of unwinding the positive electrode roll 21R to the portion used in the winding process S11. In this embodiment, the unwinding length L is calculated based on the rotation angle θ of the positive electrode roll 21R from the point at which unwinding of the long positive electrode plate 21Z from the positive electrode roll 21R begins. Note that a configuration may be adopted in which the unwinding length L is calculated based on the transport speed of the long positive electrode plate 21Z and the transport time from the point at which unwinding of the long positive electrode plate 21Z from the positive electrode roll 21R begins.

制御部160は、図示しないCPU、ROM及びRAMを含み、ROM等に記憶された所定の制御プログラムによって作動するマイクロコンピュータを有する。制御部160には、エッジセンサ130、位置調整機構140、巻出長検知部150などが接続されており、エッジセンサ130及び巻出長検知部150からそれぞれ入力された検出信号に基づいて、位置調整機構140における位置調整ロール141の傾きを制御する。具体的な制御方法については後述する。 The control unit 160 has a microcomputer including a CPU, ROM, and RAM (not shown), and operates according to a predetermined control program stored in the ROM or the like. The control unit 160 is connected to the edge sensor 130, the position adjustment mechanism 140, the unwinding length detection unit 150, and the like, and controls the inclination of the position adjustment roll 141 in the position adjustment mechanism 140 based on the detection signals input from the edge sensor 130 and the unwinding length detection unit 150, respectively. The specific control method will be described later.

次に上述の捲回装置100を用いた捲回工程S11について説明する。捲回工程S11のうち「巻出長検知工程S111」(図4参照)では、巻出長検知部150により(図5参照)、正極ロール21Rの巻き出し当初から、当該捲回工程S11で用いる部分まで巻き出した、長尺正極板21Zの巻き出し長さLを検知する。例えば、長さ約4000mの長尺正極板21Zを巻き取った正極ロール21Rから、4分の1の長尺正極板21Zが巻き出された状態では、巻き出し長さL=1000mと検知される。 Next, the winding process S11 using the winding device 100 described above will be described. In the "unwinding length detection process S111" (see FIG. 4) of the winding process S11, the unwinding length detection unit 150 (see FIG. 5) detects the unwound length L of the long positive electrode plate 21Z unwound from the beginning of unwinding the positive electrode roll 21R to the portion used in the winding process S11. For example, when a quarter of the long positive electrode plate 21Z is unwound from the positive electrode roll 21R that has wound up a long positive electrode plate 21Z with a length of approximately 4000 m, the unwound length L is detected as 1000 m.

続いて、捲回工程S11のうち「湾曲量推定工程S112」(図4参照)では、制御部160において(図5参照)、当該捲回工程S11で用いる正極板21の湾曲量Wを推定して推定湾曲量Wnを得る。
具体的には、正極ロール21Rを捲回装置100に取り付けるのに先立ち、長尺正極板21Zのうち、正極ロール21Rの最内周に位置する最内周部21Za(図7参照)における湾曲量Wである最内周湾曲量Waと、長尺正極板21Zのうち、正極ロール21Rの当初の最外周に位置する最外周部21Zbにおける湾曲量Wである最外周湾曲量Wbとをそれぞれ測定しておく。
Subsequently, in a "curve amount estimation step S112" (see FIG. 4) of the winding step S11, the control unit 160 (see FIG. 5) estimates the curvature amount W of the positive electrode plate 21 used in the winding step S11 to obtain an estimated curvature amount Wn.
Specifically, prior to mounting the positive electrode roll 21R to the winding device 100, the innermost circumference curvature amount Wa, which is the curvature amount W of the innermost circumference portion 21Za (see FIG. 7) located at the innermost circumference of the positive electrode roll 21R, of the long positive electrode plate 21Z, and the outermost circumference curvature amount Wb, which is the curvature W of the outermost circumference portion 21Zb located at the initial outermost circumference of the positive electrode roll 21R, of the long positive electrode plate 21Z, are measured.

本実施形態では、最内周湾曲量Waは、ロールプレス後の長尺正極板21Zを正極ロール21Rとして巻き取り始める前に、長尺正極板21Zの巻き取り始め部における湾曲量Wを実際に測定し、この湾曲量Wを最内周部21Zaの最内周湾曲量Waとしている。具体的には、長尺正極板21Zの巻き取り始め部について、長手方向長さa=2000mmにおける幅方向ズレ量bを測定し(図8参照)、最内周湾曲量WaをWa=b/aにより求める。例えば、幅方向ズレ量b=0.5mmの場合、最内周湾曲量Wa=0.5/2000=0.00025となる。 In this embodiment, the amount of curvature Wa at the innermost periphery is determined by actually measuring the amount of curvature W at the start of winding the long positive electrode plate 21Z after roll pressing before starting to wind the long positive electrode plate 21Z into the positive electrode roll 21R, and this amount of curvature W is set as the amount of curvature Wa at the innermost periphery of the innermost periphery. Specifically, for the start of winding the long positive electrode plate 21Z, the amount of widthwise deviation b at a longitudinal length a = 2000 mm is measured (see Figure 8), and the amount of curvature Wa at the innermost periphery is calculated by Wa = b/a. For example, when the amount of widthwise deviation b = 0.5 mm, the amount of curvature Wa at the innermost periphery is 0.5/2000 = 0.00025.

また最外周湾曲量Wbは、捲回装置100に正極ロール21Rを取り付ける直前に、正極ロール21Rから最初に巻き出した長尺正極板21Zの巻き出し始め部における湾曲量Wを実際に測定し、この湾曲量Wを最外周部21Zbの最外周湾曲量Wbとしている。具体的には、長尺正極板21Zの巻き出し始め部について、長手方向長さa=2000mmにおける幅方向ズレ量bを測定し(図8参照)、最外周湾曲量WbをWb=b/aにより求める。例えば、幅方向ズレ量b=3.0mmの場合、最内周湾曲量Wa=3.0/2000=0.0015となる。
そして、捲回装置100を用いて捲回工程S11を行うのに先立ち、上述の最内周湾曲量Wa及び最外周湾曲量Wbの各値(上の例では、Wa=0.00025、Wb=0.0015)を捲回装置100に入力し、これらの値を制御部160に記憶させておく。
The outermost curvature Wb is determined by actually measuring the curvature W at the start of unwinding of the long positive electrode plate 21Z that is first unwound from the positive electrode roll 21R immediately before mounting the positive electrode roll 21R on the winding device 100, and using this curvature W as the outermost curvature Wb of the outermost portion 21Zb. Specifically, the widthwise deviation b at the longitudinal length a=2000 mm of the start of unwinding of the long positive electrode plate 21Z is measured (see FIG. 8), and the outermost curvature Wb is calculated by Wb=b/a. For example, when the widthwise deviation b=3.0 mm, the innermost curvature Wa=3.0/2000=0.0015.
Then, prior to performing the winding process S11 using the winding device 100, the values of the innermost circumference curvature amount Wa and the outermost circumference curvature amount Wb described above (in the above example, Wa = 0.00025, Wb = 0.0015) are input to the winding device 100, and these values are stored in the control unit 160.

湾曲量推定工程S112では、制御部160において、巻出長検知部150で検知された長尺正極板21Zの巻き出し長さLと、予め制御部160に記憶させておいた最内周湾曲量Wa及び最外周湾曲量Wbとに基づいて、当該捲回工程S11で用いる正極板21の湾曲量Wを推定し、推定湾曲量Wnを得る。
具体的には、本実施形態では、最内周湾曲量Wa及び最外周湾曲量Wbの各値が異なる複数の正極ロール21Rを用いて、予め予備実験を行うことにより、長尺正極板21Zの巻き出し長さLと湾曲量Wとの関係式(近似曲線)REを得ておく(図9参照)。そして、この関係式REに、巻き出し長さL、最内周湾曲量Wa及び最外周湾曲量Wbをそれぞれ代入することで、当該正極板21の推定湾曲量Wnを算出する。例えば、巻き出し長さL=1000mにおいて、推定湾曲量Wn=0.00075と求まる。
In the curvature amount estimation process S112, the control unit 160 estimates the curvature amount W of the positive electrode plate 21 to be used in the winding process S11 based on the unwinding length L of the long positive electrode plate 21Z detected by the unwinding length detection unit 150 and the innermost circumference curvature amount Wa and the outermost circumference curvature amount Wb that have been stored in advance in the control unit 160, and obtains an estimated curvature amount Wn.
Specifically, in this embodiment, a preliminary experiment is performed in advance using a plurality of positive electrode rolls 21R having different values of the innermost periphery curvature Wa and the outermost periphery curvature Wb to obtain a relational expression (approximate curve) RE between the unwound length L and the curvature W of the long positive electrode plate 21Z (see FIG. 9 ). Then, the unwound length L, the innermost periphery curvature Wa, and the outermost periphery curvature Wb are respectively substituted into this relational expression RE to calculate the estimated curvature Wn of the positive electrode plate 21. For example, when the unwound length L is 1000 m, the estimated curvature Wn is calculated as 0.00075.

捲回工程S11では、搬送中の正極板21の幅方向位置Pxを検知し、この検知した幅方向位置Pxと、正極板21の推定湾曲量Wnとに基づいて、正極板21の幅方向位置Pxが予め定めた基準幅方向位置Psとなるように、正極板21の幅方向位置Pxを制御しつつ捲回する(図5及び図6参照)。具体的には、制御部160には、基準幅方向位置Psが記憶されているので、エッジセンサ130により検知された正極板21の幅方向位置Pxと基準幅方向位置Psとの差分(Px-Ps)を求める。そして、この差分(Px-Ps)と、制御部160で推定された上述の推定湾曲量Wnの大きさとに基づいて、幅方向位置Pxが基準幅方向位置Psとなるように、位置調整機構140において位置調整ロール141の傾きを変化させて(図6参照)、正極板21の幅方向位置Pxを制御(PID制御)する。
なお、このPID制御の各パラメータについては、予め予備実験を行って適切な値を得ておく。このようにして捲回工程S11を行うことで、正極板21の幅方向位置Pxを基準幅方向位置Psとしながら、正極板21を負極板25等と共に巻き芯111に捲回できるので、正極板21の巻きズレを適切に抑制できる。
In the winding step S11, the width direction position Px of the positive electrode plate 21 during transport is detected, and the positive electrode plate 21 is wound while controlling the width direction position Px based on the detected width direction position Px and the estimated curvature amount Wn of the positive electrode plate 21 so that the width direction position Px of the positive electrode plate 21 becomes a predetermined reference width direction position Ps (see FIGS. 5 and 6). Specifically, since the reference width direction position Ps is stored in the control unit 160, the difference (Px-Ps) between the width direction position Px of the positive electrode plate 21 detected by the edge sensor 130 and the reference width direction position Ps is obtained. Then, based on this difference (Px-Ps) and the magnitude of the estimated curvature amount Wn estimated by the control unit 160, the inclination of the position adjustment roll 141 is changed in the position adjustment mechanism 140 so that the width direction position Px becomes the reference width direction position Ps (see FIG. 6), and the width direction position Px of the positive electrode plate 21 is controlled (PID control).
For each parameter of the PID control, a preliminary experiment is performed in advance to obtain an appropriate value. By performing the winding step S11 in this manner, the positive electrode plate 21 can be wound around the winding core 111 together with the negative electrode plate 25 and the like while the width direction position Px of the positive electrode plate 21 is set to the reference width direction position Ps, so that the winding deviation of the positive electrode plate 21 can be appropriately suppressed.

なお、円筒捲回電極体20Yの巻き終わりについては、正極板切断部124により長尺正極板21Zを切断し正極板21を切り出すと共に、正極板21の巻き終わり端よりも負極板25の巻き終わり端が長くなるように、負極板切断部122により長尺負極板25Zを切断し負極板25を切り出す。更に負極板25の巻き終わり端よりも第1セパレータ31及び第2セパレータ35の巻き終わり端がそれぞれ長くなるように、第1セパレータ切断部121により長尺第1セパレータ31Zを切断し第1セパレータ31を切り出すと共に、第2セパレータ切断部123により長尺第2セパレータ35Zを切断し第2セパレータ35を切り出す。また円筒捲回電極体20Yの巻き終わった後には、図示しない粘着テープにより、円筒捲回電極体20Yの最外周に位置する第1セパレータ31の巻き終わり端を、円筒捲回電極体20Yに固定する。 At the end of the winding of the cylindrical wound electrode body 20Y, the positive plate cutting section 124 cuts the long positive plate 21Z to cut out the positive plate 21, and the negative plate cutting section 122 cuts the long negative plate 25Z to cut out the negative plate 25 so that the end of the winding of the negative plate 25 is longer than the end of the winding of the positive plate 21. Furthermore, the first separator cutting section 121 cuts the long first separator 31Z to cut out the first separator 31, and the second separator cutting section 123 cuts the long second separator 35Z to cut out the second separator 35 so that the end of the winding of the first separator 31 and the end of the second separator 35 are each longer than the end of the winding of the negative plate 25. After the cylindrically wound electrode body 20Y has been wound, the end of the first separator 31 located on the outermost periphery of the cylindrically wound electrode body 20Y is fixed to the cylindrically wound electrode body 20Y with adhesive tape (not shown).

次に電極体製造工程S1の「プレス工程S12」(図4参照)において、捲回装置100から取り出した円筒捲回電極体20Yを、図示しないプレス装置を用いて、プレスし潰して、扁平状の捲回電極体20(図2参照)を形成する。 Next, in the "pressing step S12" (see FIG. 4) of the electrode body manufacturing process S1, the cylindrical wound electrode body 20Y removed from the winding device 100 is pressed and crushed using a press device (not shown) to form a flat wound electrode body 20 (see FIG. 2).

次に「デバイス組立工程S2」(図4参照)において、上述の捲回電極体20を用いて、電池1を組み立てる。まず蓋部材16、正極端子40及び負極端子50を用いたインサート成形により、樹脂部材45,55を成形して、蓋部材16に樹脂部材45,55を介して正極端子40及び負極端子50を固設する(図1参照)。次にこの正極端子40及び負極端子50を、捲回電極体20の正負の集電部21d,25dにそれぞれ超音波溶接する。 Next, in the "device assembly process S2" (see FIG. 4), the battery 1 is assembled using the wound electrode body 20 described above. First, the resin members 45, 55 are molded by insert molding using the cover member 16, the positive terminal 40, and the negative terminal 50, and the positive terminal 40 and the negative terminal 50 are fixed to the cover member 16 via the resin members 45, 55 (see FIG. 1). Next, the positive terminal 40 and the negative terminal 50 are ultrasonically welded to the positive and negative current collecting parts 21d, 25d of the wound electrode body 20, respectively.

次にこの捲回電極体20を袋状の図示しない絶縁ホルダで包んで、これらを本体部材15内に挿入し、蓋部材16で本体部材15の開口部15cを塞ぐ。そして、本体部材15の開口部15cと蓋部材16とを全周にわたりレーザ溶接して、ケース10を形成する。
次に電解液3を注液孔16kを通じてケース10内に注液し、電解液3を捲回電極体20内に含浸させる。その後、注液孔16kを外部から封止部材18で覆い、封止部材18をケース10にレーザ溶接する。その後は、この電池1について、初充電やエージング、各種検査等を行う。かくして、電池1が完成する。
Next, this wound electrode body 20 is wrapped in a bag-shaped insulating holder (not shown), and these are inserted into the main body member 15, and the opening 15c of the main body member 15 is closed with the lid member 16. Then, the opening 15c of the main body member 15 and the lid member 16 are laser welded together around the entire periphery to form the case 10.
Next, the electrolyte 3 is injected into the case 10 through the injection hole 16k, and the electrolyte 3 is impregnated into the wound electrode body 20. Thereafter, the injection hole 16k is covered from the outside with a sealing member 18, and the sealing member 18 is laser welded to the case 10. Thereafter, the battery 1 is subjected to initial charging, aging, various inspections, etc. In this manner, the battery 1 is completed.

以上で説明したように、捲回電極体20の製造方法では、捲回工程S11において、検知した正極板21の幅方向位置Pxと、この正極板21の推定湾曲量Wnとに基づいて、幅方向位置Pxが基準幅方向位置Psとなるように正極板21の幅方向位置Pxを制御しつつ捲回を行う。このため、従来のように正極板21の湾曲量を加味せずに、単に検知した幅方向位置Pxに基づいて正極板21の幅方向位置Pxを制御する場合に比べて、捲回工程S11で生じ得る正極板21の巻きズレを適切に抑制できる。また当該捲回工程S11で用いる個々の正極板21について、実際に測定された実測湾曲量ではなく、推定された推定湾曲量Wnを用いているので、当該正極板21の実測湾曲量を得る必要がない。 As described above, in the manufacturing method of the wound electrode body 20, in the winding process S11, the widthwise position Px of the positive electrode plate 21 is controlled so that the widthwise position Px becomes the reference widthwise position Ps based on the detected widthwise position Px of the positive electrode plate 21 and the estimated curvature Wn of the positive electrode plate 21. Therefore, compared to the conventional case in which the widthwise position Px of the positive electrode plate 21 is controlled simply based on the detected widthwise position Px without taking into account the curvature of the positive electrode plate 21, the winding deviation of the positive electrode plate 21 that may occur in the winding process S11 can be appropriately suppressed. In addition, for each positive electrode plate 21 used in the winding process S11, the estimated curvature Wn is used instead of the actual measured curvature, so there is no need to obtain the actual measured curvature of the positive electrode plate 21.

更に本実施形態では、長尺正極板21Zの正極ロール21Rからの巻き出し長さLを検知して、この巻き出し長さLと、長尺正極板21Zの最内周部21Zaの最内周湾曲量Waと、長尺正極板21Zの最外周部21Zbの最外周湾曲量Wbとに基づいて、当該捲回工程S11で用いる正極板21の推定湾曲量Wrを推定している。これにより、個々の正極板21の湾曲量Wを適切に推定できるので、この推定湾曲量Wnを用いて捲回工程S11を行うことで、より適切に正極板21の巻きズレを抑制できる。 Furthermore, in this embodiment, the unwound length L of the long positive electrode plate 21Z from the positive electrode roll 21R is detected, and an estimated curvature Wr of the positive electrode plate 21 used in the winding process S11 is estimated based on this unwound length L, the innermost curvature Wa of the innermost portion 21Za of the long positive electrode plate 21Z, and the outermost curvature Wb of the outermost portion 21Zb of the long positive electrode plate 21Z. This allows the curvature W of each positive electrode plate 21 to be appropriately estimated, so that the winding misalignment of the positive electrode plate 21 can be more appropriately suppressed by performing the winding process S11 using this estimated curvature Wn.

また電池1の製造方法では、電極体製造工程S1で正極板21の巻きズレが抑制された捲回電極体20を形成できるので、正極板21の巻きズレが抑制された捲回電極体20を備えた電池1を製造できる。 In addition, in the manufacturing method of the battery 1, the wound electrode body 20 in which the winding misalignment of the positive electrode plate 21 is suppressed can be formed in the electrode body manufacturing process S1, so that the battery 1 can be manufactured with the wound electrode body 20 in which the winding misalignment of the positive electrode plate 21 is suppressed.

(変形形態)
次いで、上記実施形態の変形形態について説明する(図10参照)。なお、実施形態と同様な部分の説明は、省略または簡略化する。
実施形態に係る捲回装置100の位置調整機構140では、傾きを変更可能な位置調整ロール141により、正極板21の幅方向位置Pxを調整していた。これに対し、本変形形態に係る捲回装置200の位置調整機構240では、ロール軸線RXに沿って移動(スライド)可能な位置調整ロール241により、正極板21の幅方向位置Pxを調整する点が異なる。
(Modifications)
Next, a variation of the above embodiment will be described (see FIG. 10). Note that the description of the same parts as the embodiment will be omitted or simplified.
In the position adjustment mechanism 140 of the winding device 100 according to the embodiment, the width direction position Px of the positive electrode plate 21 is adjusted by a position adjustment roll 141 whose inclination can be changed. In contrast, the position adjustment mechanism 240 of the winding device 200 according to the present modified embodiment differs in that the width direction position Px of the positive electrode plate 21 is adjusted by a position adjustment roll 241 that can move (slide) along the roll axis RX.

具体的には、図10に示すように、本変形形態の位置調整機構240は、ロール軸線RXに沿って移動可能に構成された位置調整ロール241を有している。そして、この位置調整ロール241をロール軸線RXに沿って移動させることにより、正極板21の幅方向位置Pxを調整し、幅方向位置Pxを基準幅方向位置Psとする。本変形形態でも、従来のように正極板21の湾曲量Wを加味せずに、単に検知した幅方向位置Pxに基づいて正極板21の幅方向位置Pxを制御する場合に比べて、捲回工程S11で生じ得る正極板21の巻きズレを適切に抑制できる。その他、実施形態と同様な部分は、実施形態と同様な作用効果を奏する。 Specifically, as shown in FIG. 10, the position adjustment mechanism 240 of this modified embodiment has a position adjustment roll 241 configured to be movable along the roll axis RX. The position adjustment roll 241 is moved along the roll axis RX to adjust the widthwise position Px of the positive electrode plate 21, and the widthwise position Px is set to the reference widthwise position Ps. This modified embodiment can also appropriately suppress winding misalignment of the positive electrode plate 21 that may occur in the winding process S11, compared to the conventional case in which the widthwise position Px of the positive electrode plate 21 is controlled simply based on the detected widthwise position Px without taking into account the amount of curvature W of the positive electrode plate 21. Other parts similar to those of the embodiment provide the same effects as those of the embodiment.

以上において、本発明を実施形態及び変形形態に即して説明したが、本発明は実施形態及び変形形態に限定されるものではなく、その要旨を逸脱しない範囲で、適宜変更して適用できることは言うまでもない。
例えば実施形態では、捲回工程S11での正極板21の巻きズレを抑制するべく、正極板21の搬送にのみ本発明を適用した。負極板25の集電箔26(銅箔)は、正極板21の集電箔22(アルミニウム箔)に比して、硬く変形し難いため、負極板25は、湾曲量Wが小さく、捲回工程S11での巻きズレも小さいからである。但し、負極板25の巻きズレをより適切に抑制するべく、負極板25の搬送に本発明を適用してもよい。
Although the present invention has been described above with reference to the embodiments and modified forms, it goes without saying that the present invention is not limited to the embodiments and modified forms, and can be appropriately modified and applied without departing from the spirit of the present invention.
For example, in the embodiment, in order to suppress the winding misalignment of the positive electrode plate 21 in the winding step S11, the present invention is applied only to the transportation of the positive electrode plate 21. This is because the current collector foil 26 (copper foil) of the negative electrode plate 25 is harder and less likely to deform than the current collector foil 22 (aluminum foil) of the positive electrode plate 21, and therefore the negative electrode plate 25 has a smaller amount of curvature W and thus the winding misalignment in the winding step S11 is also small. However, in order to more appropriately suppress the winding misalignment of the negative electrode plate 25, the present invention may also be applied to the transportation of the negative electrode plate 25.

1 電池(蓄電デバイス)
20 捲回電極体
20Y 円筒捲回電極体
21 正極板(電極板)
21Z 長尺正極板(長尺電極板)
21Za (長尺正極板の)最内周部
21Zb (長尺正極板の)最外周部
21R 正極ロール(電極ロール)
25 負極板(電極板)
25Z 長尺負極板(長尺電極板)
25R 負極ロール(電極ロール)
31 第1セパレータ
35 第2セパレータ
100,200 捲回装置
S1 電極板製造工程
S11 捲回工程
S111 巻出長検知工程
S112 湾曲量推定工程
S2 デバイス組立工程
L 巻き出し長さ
W 湾曲量
Wa 最内周湾曲量
Wb 最外周湾曲量
Wn 推定湾曲量
Px 幅方向位置
Ps 基準幅方向位置
1 Battery (energy storage device)
20 Wound electrode body 20Y Cylindrical wound electrode body 21 Positive electrode plate (electrode plate)
21Z Long positive electrode plate (long electrode plate)
21Za: innermost circumferential portion (of a long positive electrode plate); 21Zb: outermost circumferential portion (of a long positive electrode plate); 21R: positive electrode roll (electrode roll)
25 Negative electrode plate (electrode plate)
25Z Long negative electrode plate (long electrode plate)
25R Negative electrode roll (electrode roll)
31 First separator 35 Second separator 100, 200 Winding device S1 Electrode plate manufacturing process S11 Winding process S111 Unwound length detection process S112 Curvature amount estimation process S2 Device assembly process L Unwound length W Curvature amount Wa Innermost circumference curvature amount Wb Outermost circumference curvature amount Wn Estimated curvature amount Px Width direction position Ps Reference width direction position

Claims (3)

各々帯状をなす第1セパレータ、負極板、第2セパレータ及び正極板を重ねて捲回してなる捲回電極体の製造方法であって、
巻き芯の周りに、上記第1セパレータ、上記負極板、上記第2セパレータ及び上記正極板を重ねて捲回する捲回工程を備え、
上記捲回工程は、
上記正極板及び上記負極板の少なくとも一方の電極板について、搬送中の上記電極板の幅方向位置を検知し、
この検知した幅方向位置と、当該電極体について実際に測定された実測湾曲量ではなく、当該電極板の推定された推定湾曲量とに基づいて、上記幅方向位置が基準幅方向位置となるように当該電極板の上記幅方向位置を制御しつつ捲回する
捲回電極体の製造方法。
A method for manufacturing a wound electrode assembly obtained by stacking and winding a first separator, a negative electrode plate, a second separator, and a positive electrode plate, each of which is in the shape of a strip, comprising the steps of:
a winding step of overlapping and winding the first separator, the negative electrode plate, the second separator, and the positive electrode plate around a winding core,
The winding process includes:
Detecting a width direction position of at least one of the positive electrode plate and the negative electrode plate during transportation;
A manufacturing method for a wound electrode body in which the electrode plate is wound while controlling the widthwise position of the electrode plate so that the widthwise position becomes a reference widthwise position based on the detected widthwise position and an estimated amount of curvature of the electrode plate, rather than an actual measured amount of curvature of the electrode body.
請求項1に記載の捲回電極体の製造方法であって、
前記電極板は、
長尺の長尺電極板を予めロール状に巻き取った電極ロールから、上記長尺電極板を巻き出して切断した電極板であり、
前記捲回工程は、
上記電極ロールの巻き出し当初から、当該捲回工程で用いる部分まで巻き出した、上記長尺電極板の巻き出し長さを検知する巻出長検知工程と、
検知した上記巻き出し長さと、
上記長尺電極板のうち、上記電極ロールの最内周に位置する最内周部における湾曲量である最内周湾曲量と、
上記長尺電極板のうち、上記電極ロールの当初の最外周に位置する最外周部における湾曲量である最外周湾曲量とに基づいて、
当該捲回工程で用いる上記電極板の湾曲量を推定して前記推定湾曲量を得る
湾曲量推定工程と、を有する
捲回電極体の製造方法。
A method for manufacturing a wound electrode assembly according to claim 1,
The electrode plate is
The long electrode plate is obtained by unwinding and cutting a long electrode plate from an electrode roll in which the long electrode plate has been wound in advance into a roll shape,
The winding step includes:
a winding length detection step of detecting the unwound length of the long electrode plate from the beginning of unwinding of the electrode roll to the portion to be used in the winding step;
The detected unwinding length,
an innermost periphery curvature amount, which is an amount of curvature at an innermost periphery portion of the long electrode plate that is located at the innermost periphery of the electrode roll;
Based on an outermost periphery curvature amount, which is an amount of curvature at an outermost periphery portion of the long electrode plate that is located at the initial outermost periphery of the electrode roll,
and a curvature amount estimating step of estimating the curvature amount of the electrode plate used in the winding step to obtain the estimated curvature amount.
各々帯状をなす第1セパレータ、負極板、第2セパレータ及び正極板を重ねて捲回してなる捲回電極体を備える蓄電デバイスの製造方法であって、
請求項1または請求項2に記載の捲回電極体の製造方法により、上記捲回電極体を製造する電極体製造工程と、
上記捲回電極体を用いて、上記蓄電デバイスを組み立てるデバイス組立工程と、を備える
蓄電デバイスの製造方法。
A method for manufacturing an electricity storage device including a wound electrode body formed by stacking and winding a first separator, a negative electrode plate, a second separator, and a positive electrode plate, each of which is in the form of a strip, comprising:
an electrode assembly manufacturing process for manufacturing the wound electrode assembly by the method for manufacturing the wound electrode assembly according to claim 1 or 2;
and a device assembling step of assembling the electricity storage device using the wound electrode body.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001202986A (en) 1999-11-08 2001-07-27 Matsushita Electric Ind Co Ltd Spiral electrode group winding method and apparatus and battery using the same
JP2021103611A (en) 2019-12-24 2021-07-15 トヨタ自動車株式会社 Winding-up device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001202986A (en) 1999-11-08 2001-07-27 Matsushita Electric Ind Co Ltd Spiral electrode group winding method and apparatus and battery using the same
JP2021103611A (en) 2019-12-24 2021-07-15 トヨタ自動車株式会社 Winding-up device

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