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JP7738840B2 - Baked grain flour foods with good release properties - Google Patents
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JP7738840B2 - Baked grain flour foods with good release properties - Google Patents

Baked grain flour foods with good release properties

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JP7738840B2
JP7738840B2 JP2021001856A JP2021001856A JP7738840B2 JP 7738840 B2 JP7738840 B2 JP 7738840B2 JP 2021001856 A JP2021001856 A JP 2021001856A JP 2021001856 A JP2021001856 A JP 2021001856A JP 7738840 B2 JP7738840 B2 JP 7738840B2
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baked
sugar
grain flour
eggs
psicose
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JP2022107127A (en
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沙紀 西山
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Matsutani Chemical Industries Co Ltd
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Description

本発明は、離型性のよい穀粉焼成食品若しくはその製造方法、穀粉焼成食品の離型用組成物、及び穀粉焼成食品の離型性向上方法に関する。 The present invention relates to a baked grain flour food product with good releasability or a method for producing the same, a release composition for baked grain flour foods, and a method for improving the releasability of baked grain flour foods.

穀粉焼成食品とは、原材料に穀粉(主に小麦粉)を含み、卵、砂糖、牛乳、油脂、ベーキングパウダー、重曹などの副原料を混合してドウ又はバッター生地とし、これを焼成してなる食品をいう。ここでは、イーストによる発酵工程を伴うパン類とは区別し、代表的な形態は、スポンジケーキ、マドレーヌ、フィナンシェなどである。これらはパン類に比して卵と糖質を多く含むことと生地比重が軽いことから、型に焦げ付いて離型しにくいという問題がある。 Flour-based baked foods are foods made by mixing cereal flour (mainly wheat flour) with secondary ingredients such as eggs, sugar, milk, oils and fats, baking powder, and baking soda to form a dough or batter, which is then baked. Here, they are distinguished from breads, which require a leavening process using yeast; typical forms include sponge cakes, madeleines, and financiers. Compared to breads, these contain more eggs and sugars and have a lighter dough density, so they have the problem of sticking to the mold and being difficult to release.

この離型性を向上させるため、油脂や乳化剤がよく利用される。例えば、高融点粉末油脂を利用した離型油(特許文献1)、油脂に対し、レシチン及びワックスを併用する離型油(特許文献2)、レシチン及びカルシウム化合物を併用する離型油(特許文献3)、ポリグリセリン脂肪酸エステル及び二酸化ケイ素(特許文献4)を併用する離型油が提案されている。 To improve this releasability, fats and oils and emulsifiers are often used. For example, release oils using high-melting-point powdered fats and oils (Patent Document 1), release oils using lecithin and wax in combination with fats and oils (Patent Document 2), release oils using lecithin and a calcium compound in combination (Patent Document 3), and release oils using polyglycerin fatty acid esters and silicon dioxide in combination (Patent Document 4) have been proposed.

しかし、油脂や乳化剤(レシチン、脂肪酸エステルなど)は、生地に添加すると独特の好ましくない風味が生じることや、近年の無添加嗜好や低カロリー嗜好の顧客ニーズに合わないという理由から、極力使用を避けたい物質となっている。 However, the use of fats and oils and emulsifiers (lecithin, fatty acid esters, etc.) is something that should be avoided as much as possible because adding them to dough creates a unique, unpleasant flavor and they do not meet the recent customer needs for additive-free and low-calorie foods.

特開2016-214161号公報Japanese Patent Application Laid-Open No. 2016-214161 特開2014-18170号公報JP 2014-18170 A 特開平4-131044号公報Japanese Unexamined Patent Publication No. 4-131044 特開2003-265105号公報Japanese Patent Application Laid-Open No. 2003-265105

本発明の目的は、油脂や乳化剤を多用することなく、離型性のよい穀粉焼成食品を提供することにある。また、同時に、離型性のよい穀粉焼成食品製造方法、穀粉焼成食品の離型用組成物、及び穀粉焼成食品の離型性向上方法を提供することにある。 The object of the present invention is to provide baked grain flour foods with good releasability without using a large amount of fats and oils or emulsifiers. It also aims to provide a method for producing baked grain flour foods with good releasability, a release composition for baked grain flour foods, and a method for improving the releasability of baked grain flour foods.

本発明者らは、かかる課題を解決すべく種々検討したところ、添加物の範疇にない、しかも焦げ付く原因とされる糖のひとつであるD-プシコース(D-アルロース)を特定量添加することにより、上記課題が解決されることを見出し、本発明を完成するに至った。本発明によれば、離型油のように型にあらかじめ塗布しておくなどの手間を要さず、穀粉焼成食品の生地に配合しておくだけで簡便に離型性を改善することができる。 The inventors conducted extensive research to solve this problem, and discovered that the problem could be solved by adding a specific amount of D-psicose (D-allulose), a sugar that is not classified as an additive and is believed to cause sticking, leading to the completion of the present invention. According to the present invention, release properties can be easily improved by simply adding the additive to the dough of a baked grain flour food, without the need to apply the additive to the mold beforehand, as is the case with release oil.

本発明は、主に4つの発明からなり、第一の発明は、以下[1]~[3]の穀粉焼成食品である。
[1]穀粉、砂糖、卵及びD-プシコースを含む生地が型充填及び焼成されてなる、以下の(A)及び(B)を満たす穀粉焼成食品:
(A)D-プシコースが生地原料中0.02~15質量%、
(B)砂糖と卵の配合量が、砂糖≧卵。
[2]さらに以下の(C)を満たす、上記[1]記載の穀粉焼成食品:
(C)砂糖100質量部に対し、D-プシコースが0.07~71質量部。
[3]穀粉焼成食品が、スポンジケーキ、マドレーヌ、フィナンシェのいずれかである、上記[1]又は[2]に記載の穀粉焼成食品。
The present invention mainly consists of four inventions, and the first invention is a baked grain flour food product as described below in [1] to [3].
[1] A baked grain flour food product that satisfies the following (A) and (B), which is obtained by filling a dough containing grain flour, sugar, eggs, and D-psicose into a mold and baking it:
(A) D-psicose is 0.02 to 15% by mass in the dough ingredients,
(B) The ratio of sugar to eggs is sugar >= eggs.
[2] The baked grain flour food according to [1] above, further satisfying the following (C):
(C) 0.07 to 71 parts by mass of D-psicose per 100 parts by mass of sugar.
[3] The grain flour baked food according to [1] or [2] above, wherein the grain flour baked food is a sponge cake, a madeleine, or a financier.

第二の発明は、以下[4]及び[5]の穀粉焼成食品の製造方法である。
[4]穀粉、砂糖、卵及びD-プシコースを含んでなる穀粉焼成食品の製造方法であって、以下の(A)及び(B)を満たす生地を調製する工程、型に充填する工程、及び焼成する工程を含む、穀粉焼成食品の製造方法:
(A)D-プシコースが生地原料中0.02~15質量%、
(B)砂糖と卵の配合量が、砂糖≧卵。
[5]さらに以下の(C)を満たす、上記[4]記載の穀粉焼成食品の製造方法:
(C)砂糖100質量部に対し、D-プシコースが0.07~71質量部。
The second invention is a method for producing baked grain flour foods as described below in [4] and [5].
[4] A method for producing a cereal flour baked food comprising cereal flour, sugar, eggs, and D-psicose, the method comprising the steps of preparing a dough that satisfies the following (A) and (B), filling the dough into a mold, and baking the dough:
(A) D-psicose is 0.02 to 15% by mass in the dough ingredients,
(B) The ratio of sugar to eggs is sugar >= eggs.
[5] The method for producing a baked grain flour food according to the above [4], further satisfying the following (C):
(C) 0.07 to 71 parts by mass of D-psicose per 100 parts by mass of sugar.

第三の発明は、以下[6]及び[7]の穀粉焼成食品の離型用組成物である。
[6]D-プシコースを有効成分として含む、穀粉焼成食品の離型用組成物。
[7]穀粉焼成食品が以下(A)及び(B)を満たす、上記[6]記載の穀粉焼成食品の離型用組成物:
(A)D-プシコースが生地原料中0.02~15質量%、
(B)砂糖と卵の使用量が、砂糖≧卵。
The third invention is a release composition for baked grain flour foods as set forth in [6] and [7] below.
[6] A release composition for baked grain flour foods, containing D-psicose as an active ingredient.
[7] The release composition for a cereal flour baked food according to [6] above, wherein the cereal flour baked food satisfies the following (A) and (B):
(A) D-psicose is 0.02 to 15% by mass in the dough ingredients,
(B) The amount of sugar and eggs used is sugar > eggs.

第四の発明は、以下[8]の穀粉焼成食品の離型性を向上させる方法である。
[8]以下(B)を満たす穀粉焼成食品において(A)を満たすことにより、穀粉焼成食品の離型性を向上させる方法:
(A)D-プシコースが生地原料中0.02~15質量%、
(B)砂糖と卵の使用量が、砂糖≧卵。
The fourth invention is a method for improving the releasability of baked grain flour foods as described below in [8].
[8] A method for improving the releasability of a grain flour baked food by satisfying (A) in a grain flour baked food that satisfies the following (B):
(A) D-psicose is 0.02 to 15% by mass in the dough ingredients,
(B) The amount of sugar and eggs used is sugar > eggs.

本発明によれば、離型性のよい穀粉焼成食品を提供することができる。 The present invention makes it possible to provide baked grain flour foods with good releasability.

本発明にいう「穀粉焼成食品」は、主成分である穀粉、卵及び砂糖のほか、牛乳、油脂、塩、調味料などの副原料を混合し、バッター生地又はドウ生地として焼成されてなるものをいい、イースト発酵を伴うパン類とは区別される。穀粉焼成食品の具体例は、スポンジケーキ、シフォンケーキ、パウンドケーキ、バターケーキ、カップケーキ、マフィン、マドレーヌ、フィナンシェ、ホットケーキ、どら焼き、蒸しどら、たい焼き、人形焼、鈴カステラ、ワッフル、バームクーヘン、クッキー、パイ、タルトなどであるが、本発明の効果がよく発揮される形態は、スポンジケーキ、シフォンケーキ、パウンドケーキ、バターケーキ、カップケーキ、マフィン、マドレーヌ、フィナンシェ、板バーム、タルトなどである。穀粉焼成食品の製造手順は定法に従えばよく、とくに限定されるものではないが、焼成工程に用いるオーブンなどの器具が100℃を超える場合に離型性の問題をよく生じるため、本発明の効果がより明確にみられる。 As used herein, "baked flour foods" refer to foods made by mixing the primary ingredients of flour, eggs, and sugar with secondary ingredients such as milk, oils and fats, salt, and seasonings, and baking them as batter or dough. These foods are distinct from breads that require yeast fermentation. Specific examples of baked flour foods include sponge cake, chiffon cake, pound cake, butter cake, cupcakes, muffins, madeleines, financiers, pancakes, dorayaki, steamed dorayaki, taiyaki, ningyoyaki, bell castella, waffles, baumkuchen, cookies, pies, and tarts. The effects of the present invention are best demonstrated in sponge cake, chiffon cake, pound cake, butter cake, cupcakes, muffins, madeleines, financiers, baumkuchen sheets, and tarts. While the manufacturing procedures for baked flour foods are not particularly limited and may follow standard methods, the effects of the present invention are more clearly evident when ovens and other baking equipment used in the baking process exceed 100°C, as this often results in mold release problems.

上記の「穀粉」は、小麦粉に限定されず、米粉、コーンフラワー、大豆粉、ライ麦粉、大麦粉、あわ粉、ひえ粉、澱粉などを併用してもよく、澱粉には加工澱粉が含まれる。加工澱粉の具体例は、架橋澱粉(例えば、リン酸架橋澱粉)、エーテル化澱粉(例えば、ヒドロキシプロピル澱粉)、エステル化澱粉(例えば、酢酸澱粉)、これら加工を組合せた加工澱粉(例えば、アセチル化アジピン酸架橋澱粉やヒドロキシプロピル化リン酸架橋澱粉)、オクテニルコハク酸ナトリウム澱粉、酸化澱粉、酸処理澱粉などが挙げられる。 The above-mentioned "cereal flour" is not limited to wheat flour, but may also be rice flour, corn flour, soy flour, rye flour, barley flour, millet flour, barnyard millet flour, starch, etc., which may include modified starch. Specific examples of modified starch include cross-linked starch (e.g., phosphate cross-linked starch), etherified starch (e.g., hydroxypropyl starch), esterified starch (e.g., acetate starch), modified starch that combines these processes (e.g., acetylated adipate cross-linked starch and hydroxypropylated phosphate cross-linked starch), sodium octenyl succinate starch, oxidized starch, acid-treated starch, etc.

上記の「卵」は、一般に鶏の全卵を指すが、それ以外の卵であってもよく、卵黄又は卵白のみを利用することができ、卵液のほか、その冷凍品、粉末品などの加工品を用いることもできる。 The "eggs" mentioned above generally refer to whole chicken eggs, but other types of eggs may also be used; only the egg yolk or egg white may be used, and processed egg products such as frozen or powdered egg liquid may also be used.

上記の「砂糖」は、ショ糖、スクロースともいい、その粒の大きさや精製度により、グラニュー糖、粉糖、上白糖、三温糖などと名称が異なることがあるが、いずれであっても用いることができる。 The "sugar" mentioned above is also called sucrose, and depending on the particle size and degree of refinement, it may be called granulated sugar, powdered sugar, white sugar, brown sugar, etc., but any of these can be used.

本発明の穀粉焼成食品は、離型性の問題を生じる原料の配合比のときに、とくに離型性の向上効果がみられることとなる。具体的には、主成分である穀粉に加えて、砂糖と卵を含むときに離型の問題を生じ、さらには砂糖が卵と同量又はそれ以上配合されたときに特に離型の問題を顕著に生じるので、その配合において、離型性の改善効果が明確に発現される。 The baked grain flour food products of the present invention exhibit improved release properties, particularly when the ingredients are blended at a ratio that causes release problems. Specifically, release problems occur when sugar and eggs are included in addition to the main ingredient, grain flour, and release problems become particularly pronounced when the amount of sugar is equal to or greater than the amount of eggs. Therefore, the effect of improving release properties is clearly evident in this blend.

本発明の穀粉焼成食品は、上記の原料のほか、D-プシコース(D-アルロース)を必須成分として含む。D-プシコースは、離型性を向上させるために用いられるが、型に塗布するのでなく穀粉焼成食品の原料のひとつとして用いればよく、ミックス粉の調製時、又はバッター若しくはドウ生地の調製時に配合すればよい。D-プシコースは、少なくとも生地原料中に0.02質量%以上配合すればよいが、15%を超えると着色が進行して見た目が悪くなるため、好ましくは0.02~15%、より好ましくは0.04~12%であり、さらに好ましくは0.08~10%配合すればよく、1.5~8%を目安として添加するのがよい。また、砂糖との関係においては、砂糖100質量部に対して、0.07~71質量部を用いるのがよく、好ましくは0.17~55質量部、0.33~45質量部、さらに好ましくは7.1~35質量部を用いるのがよい。 In addition to the above ingredients, the baked grain flour food of the present invention contains D-psicose (D-allulose) as an essential ingredient. D-psicose is used to improve mold release, but it can be used as one of the ingredients of the baked grain flour food rather than being applied to the mold, and can be added when preparing the mixed flour or batter or dough. D-psicose should be added to the dough ingredients at a concentration of at least 0.02% by weight. However, if it exceeds 15%, discoloration will progress and the appearance will deteriorate. Therefore, a concentration of 0.02-15%, more preferably 0.04-12%, and even more preferably 0.08-10%, is preferred, with 1.5-8% being the target. Furthermore, in relation to sugar, it is recommended to use 0.07-71 parts by weight, preferably 0.17-55 parts by weight, 0.33-45 parts by weight, and even more preferably 7.1-35 parts by weight per 100 parts by weight of sugar.

本発明にいう「離型性が向上する」とは、ドウ生地又はバッター生地が型に充填されて焼成された穀粉焼成食品をその型から外したときに、離型せずに型に残った焼成生地が、対照とする穀粉焼成食品のそれより少ない状態をいい、より好ましくは、離型せずに型に残った焼成生地の量が、焼成食品全体の10%未満であることをいう。 In the present invention, "improved releasability" refers to a state in which, when a baked grain flour food product that has been filled with dough or batter in a mold and baked is removed from the mold, the amount of baked dough remaining in the mold without being released is less than that of a control grain flour baked food product; more preferably, the amount of baked dough remaining in the mold without being released is less than 10% of the total baked food product.

本発明の穀粉焼成食品は、上記の必須原料以外の原料を含んでもよく、例えば、重曹、ベーキングパウダー、牛乳、乳製品、バター、マーガリンなどの加工油脂、塩などの調味料のほか、調製生地に混ぜ込んで用いるレーズンやナッツなどの具材を含むことができる。また、従前の乳化剤や離型用油脂の使用を排除するものでなく、本発明の効果を阻害しない範囲で適量を用いることができる。 The baked grain flour food product of the present invention may contain ingredients other than the essential ingredients listed above, such as baking soda, baking powder, milk, dairy products, processed fats and oils such as butter and margarine, seasonings such as salt, and ingredients such as raisins and nuts that are mixed into the prepared dough. Furthermore, the use of conventional emulsifiers and release fats and oils can be used in appropriate amounts as long as they do not impair the effects of the present invention.

以下、実験例を提示して本発明を詳細かつ具体的に説明するが、本発明は、これら実験例に限定されるものではない。なお、以下の実験例において、とくに断りのない限り、「部」は質量部を、「%」は質量%を示す。 The present invention will be explained in detail and specifically below using experimental examples, but the present invention is not limited to these experimental examples. In the following experimental examples, unless otherwise specified, "parts" means parts by mass and "%" means % by mass.

<マドレーヌにおける離型性の確認>
以下の[表1]の手順に従い、[表2]の配合で各マドレーヌを焼成した。焼成したマドレーヌを離型させたときに型に残った焼成生地の重量割合(%)は、[表2]下方に示す。
<Confirmation of release properties of madeleines>
Each madeleine was baked according to the procedure in Table 1 below, using the composition in Table 2. The weight percentage (%) of the baked dough remaining in the mold when the baked madeleine was released from the mold is shown at the bottom of Table 2.

上の試験実施前は、油脂の配合割合が多くなるほど離型性が良好になるものと想定していたが、意外にも、油脂の配合割合がもっとも多い試験区4の離型性が最も悪かった。一方、試験区4と油脂の配合割合が同等である試験区3の離型性が最も良かった。また、油脂の配合割合が同等である試験区5と6を比較したときにも、その離型性に顕著な相違があった。そこで、離型性に影響を及ぼす因子が油脂以外にもあるのではないかと考え、詳細に検討したところ(例えば、試験区1、2など)、砂糖と卵の配合量が同等のとき、又は砂糖の配合量が卵より多いときに、離型性の問題を顕著に生じることがわかった。 Before conducting the above tests, it was assumed that the higher the fat/oil ratio, the better the release properties would be, but surprisingly, test plot 4, which had the highest fat/oil ratio, had the worst release properties. On the other hand, test plot 3, which had the same fat/oil ratio as test plot 4, had the best release properties. Furthermore, when comparing test plots 5 and 6, which had the same fat/oil ratio, there was also a significant difference in release properties. Therefore, we wondered if there were factors other than fat/oil that affected release properties, and after further investigation (for example, test plots 1 and 2), we found that release problems became more pronounced when the sugar and egg ratios were the same, or when the amount of sugar was greater than the amount of egg.

<D-プシコースによる離型効果-砂糖と卵が同量の場合->
D-プシコース添加による離型効果を確認するため、上記[表1]の手順に従い、以下[表3]の配合でマドレーヌを焼成した。焼成したマドレーヌを離型させたときに型に残った焼成生地の重量割合(%)は、[表3]下方に示す。
<Release effect of D-psicose - when sugar and eggs are equal amounts>
To confirm the mold release effect of adding D-psicose, madeleines were baked according to the procedure in Table 1 above, with the formulations in Table 3 below. The weight percentage (%) of the baked dough remaining in the mold when the baked madeleines were released from the mold is shown at the bottom of Table 3.

D-プシコースを0.02%添加すると、全く添加しない場合に比べて離型性が若干改善し、0.04、0.08、1.63又は11.06%添加したときに、離型性が顕著に改善した。一方、D-プシコースの異性化体であるD-フラクトースを1.63%添加しても、離型性は全く改善しなかった。 When 0.02% D-psicose was added, demolding properties improved slightly compared to when no D-psicose was added, and when 0.04, 0.08, 1.63, or 11.06% was added, demolding properties improved significantly. On the other hand, adding 1.63% D-fructose, an isomer of D-psicose, did not improve demolding properties at all.

<D-プシコースによる離型効果 -砂糖が卵より多い場合->
上記[表1]の手順に沿って、以下[表4]の配合でマドレーヌを焼成した。焼成したマドレーヌを離型させたときに型に残った焼成生地の重量割合(%)は、[表4]下方に示す。
<Release effect of D-psicose – when there is more sugar than eggs –>
Madeleines were baked according to the procedure in Table 1 above, with the composition shown in Table 4 below. The weight percentage (%) of the baked dough remaining in the mold when the baked madeleines were released from the mold is shown at the bottom of Table 4.

離型性が顕著に悪化する条件である、砂糖が卵より多い配合にあっても、D-プシコースを7.66%添加したときには離型性が顕著に改善した。 Even in formulations where the sugar content was higher than the eggs content, a condition that significantly worsens mold release properties, adding 7.66% D-psicose significantly improved mold release properties.

Claims (5)

穀粉、砂糖、卵及びD-プシコースを含んでなる穀粉焼成食品の製造方法であって、以下の(A)及び(B)を満たす生地を調製する工程、離型油を使用せずに型に充填する工程、及び焼成する工程を含む、穀粉焼成食品の製造方法:
(A)D-プシコースが生地原料中0.02~15質量%、
(B)砂糖と卵の配合量が、砂糖≧卵。
A method for producing a cereal flour baked food product comprising cereal flour, sugar, eggs, and D-psicose, the method comprising the steps of preparing a dough that satisfies the following (A) and (B), filling the dough into a mold without using a release oil, and baking the dough:
(A) D-psicose is 0.02 to 15% by mass in the dough ingredients,
(B) The ratio of sugar to eggs is sugar >= eggs.
さらに以下の(C)を満たす、請求項1記載の穀粉焼成食品の製造方法:
(C)砂糖100質量部に対し、D-プシコースが0.07~71質量部。
The method for producing a baked grain flour food according to claim 1, further satisfying the following (C):
(C) 0.07 to 71 parts by mass of D-psicose per 100 parts by mass of sugar.
穀粉焼成食品が、スポンジケーキ、マドレーヌ、フィナンシェのいずれかである、請求項1又は2に記載の穀粉焼成食品の製造方法 3. The method for producing a baked grain flour food according to claim 1 or 2, wherein the baked grain flour food is any one of a sponge cake, a madeleine, and a financier. D-プシコースを有効成分として含む、離型油を使用せずに型に充填及び焼成するための穀粉焼成食品の離型用組成物であって、
穀粉焼成食品が、穀粉、砂糖、卵及びD-プシコースを含む生地が型充填及び焼成されてなり、穀粉焼成食品の砂糖と卵の配合量が、砂糖≧卵であり、
穀粉焼成食品の生地原料中にD-プシコースが0.02~15質量%含有するように添加される、穀粉焼成食品の離型用組成物。
A composition for releasing a flour-based baked food product, which contains D-psicose as an active ingredient and is used for filling and baking a mold without using a release oil,
The baked grain flour food is obtained by filling a dough containing grain flour, sugar, eggs, and D-psicose into a mold and baking it, and the blending amounts of sugar and eggs in the baked grain flour food are such that the sugar is equal to or greater than the egg,
A mold release composition for baked grain flour foods, which is added to the dough ingredients of baked grain flour foods so that D-psicose is contained in an amount of 0.02 to 15 mass %.
以下(B)及び(D)を満たす穀粉焼成食品において(A)を満たすことにより、穀粉焼成食品の離型性を向上させる方法:
(A)D-プシコースが生地原料中0.02~15質量%、
(B)砂糖と卵の使用量が、砂糖≧卵
(D)穀粉焼成食品は、穀粉、砂糖、卵及びD-プシコースを含む生地が離型油を使用せずに型に充填及び焼成されてなる。
A method for improving the releasability of a grain flour baked food by satisfying (A) in a grain flour baked food that satisfies the following (B) and (D):
(A) D-psicose is 0.02 to 15% by mass in the dough ingredients,
(B) The amount of sugar and eggs used is sugar≧eggs. (D) The baked grain flour food is made by filling a dough containing grain flour, sugar, eggs, and D-psicose into a mold and baking it without using a release oil.
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