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JP7749869B2 - Plasma processing equipment - Google Patents
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JP7749869B2 - Plasma processing equipment - Google Patents

Plasma processing equipment

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JP7749869B2
JP7749869B2 JP2024571987A JP2024571987A JP7749869B2 JP 7749869 B2 JP7749869 B2 JP 7749869B2 JP 2024571987 A JP2024571987 A JP 2024571987A JP 2024571987 A JP2024571987 A JP 2024571987A JP 7749869 B2 JP7749869 B2 JP 7749869B2
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waveguide
solid
cutoff
state microwave
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チェンピン スー
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Hitachi High Tech Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32192Microwave generated discharge
    • H01J37/32211Means for coupling power to the plasma
    • H01J37/32229Waveguides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/50Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
    • C23C16/511Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using microwave discharges
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32192Microwave generated discharge
    • H01J37/32211Means for coupling power to the plasma
    • H01J37/3222Antennas
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32192Microwave generated discharge
    • H01J37/32311Circuits specially adapted for controlling the microwave discharge
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01PWAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
    • H01P1/00Auxiliary devices
    • H01P1/16Auxiliary devices for mode selection, e.g. mode suppression or mode promotion; for mode conversion
    • H01P1/163Auxiliary devices for mode selection, e.g. mode suppression or mode promotion; for mode conversion specifically adapted for selection or promotion of the TE01 circular-electric mode
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01PWAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
    • H01P5/00Coupling devices of the waveguide type
    • H01P5/08Coupling devices of the waveguide type for linking dissimilar lines or devices
    • H01P5/10Coupling devices of the waveguide type for linking dissimilar lines or devices for coupling balanced lines or devices with unbalanced lines or devices
    • H01P5/103Hollow-waveguide/coaxial-line transitions
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/46Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P50/00Etching of wafers, substrates or parts of devices
    • H10P50/20Dry etching; Plasma etching; Reactive-ion etching
    • H10P50/24Dry etching; Plasma etching; Reactive-ion etching of semiconductor materials
    • H10P50/242Dry etching; Plasma etching; Reactive-ion etching of semiconductor materials of Group IV materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electromagnetism (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Plasma Technology (AREA)
  • Drying Of Semiconductors (AREA)

Description

本発明は、マイクロ波を用いたECR(Electron Cyclotron Resonance)プラズマ処理装置に関する。 The present invention relates to an ECR (Electron Cyclotron Resonance) plasma processing apparatus using microwaves.

近年では、半導体デバイスの集積度が向上し、微細加工すなわち加工精度の向上が要求されるとともに、エッチングレートの均一性あるいは加工寸法におけるCD値(Critical Dimension)のウェハ面内均一性の向上が厳しくなった。また、被エッチング材料も単層膜から多層膜に変化し、各多層膜の処理中にエッチング条件を変化させる多段ステップエッチングが多用されるようになった。この場合、エッチングの均一性等に影響を与える要因はステップ毎に異なるため、各多層膜のエッチング完了時点でエッチングレートの均一性、軸対称性を得ることは難しい。In recent years, the integration level of semiconductor devices has increased, requiring finer processing, or improved processing accuracy, while also making it more difficult to improve the uniformity of etching rates or the uniformity of critical dimensions (CD) across the wafer surface. Furthermore, the materials being etched have changed from single-layer films to multilayer films, and multi-step etching, in which the etching conditions are changed during the processing of each multilayer film, has become more common. In this case, factors that affect etching uniformity, etc., differ for each step, making it difficult to achieve uniform etching rates and axial symmetry at the completion of etching of each multilayer film.

半導体分野の微細化エッチング技術の一つはドライエッチング技術であり、その中に特にプラズマを用いたドライエッチング加工がよく使われている。プラズマは電子及び処理ガスの分子または原子との衝突を利用して処理ガスの分子または原子を励起し、イオンおよびラジカルを生成する。プラズマ処理装置はイオンによって異方性エッチング、ラジカルによって等方性エッチングを実現している。プラズマ源としては、電子サイクロトロン共鳴ECR(ECR:Electron Cyclotron Resonance)がある。ECRは高密度プラズマを生成できるため、半導体デバイスのDRAMの耐電圧の向上や、高容量コンデンサの作成などに用いられている。 One of the micro-etching techniques used in the semiconductor field is dry etching, with plasma-based dry etching being particularly common. Plasma uses collisions between electrons and the molecules or atoms of the process gas to excite them, generating ions and radicals. Plasma processing equipment achieves anisotropic etching with ions and isotropic etching with radicals. Electron cyclotron resonance (ECR) is one plasma source. Because ECR can generate high-density plasma, it is used to improve the voltage resistance of DRAM in semiconductor devices and to create high-capacity capacitors.

図8に、従来のECRエッチング装置の構成を示す。マグネトロン72から発せられた2.45GHzのマイクロ波は、アイソレーター73、矩形導波管74及びスリースタブチューナー75の順にTE10モードの姿態として伝播し、円矩形導波管変換器76により、その伝播姿態(またはモード)がTE11モードに変換される。円矩形導波管変換器76は、2.45GHzのマイクロ波が基本のTE11モード伝播姿態が通過できるようにφ90mmの直径を有する。軸対称性のあるマイクロ波の放射を形成させるために、石英製の誘電体1/4波長板8を用いて円偏波が形成され、TE11モード伝播姿態のマイクロ波を時間的に回転させることにより、マイクロ波の電界分布は軸対称となり、キャビティ6に放射する。マイクロ波を円形導波管5内に円偏波として伝播させるためには、前述の1/4波長板8をTE11モードの直線偏波の偏波面と45度に傾いた角度で円形導波管5に挿入する。Figure 8 shows the configuration of a conventional ECR etching apparatus. 2.45 GHz microwaves emitted from a magnetron 72 propagate through an isolator 73, a rectangular waveguide 74, and a three-stub tuner 75 in TE10 mode, before being converted to TE11 mode by a circular-to-rectangular waveguide converter 76. The circular-to-rectangular waveguide converter 76 has a diameter of 90 mm so that the 2.45 GHz microwaves can pass through in the fundamental TE11 mode propagation mode. To generate axially symmetric microwave radiation, a quartz dielectric quarter-wave plate 8 is used to form circular polarization. By rotating the microwaves in the TE11 mode propagation mode over time, the microwave electric field distribution becomes axially symmetric and is radiated into the cavity 6. In order to propagate the microwave as a circularly polarized wave within the circular waveguide 5, the aforementioned quarter-wave plate 8 is inserted into the circular waveguide 5 at an angle of 45 degrees to the plane of polarization of the linearly polarized wave in the TE11 mode.

キャビティ6に入射したマイクロ波の円偏波は、アッパー電磁コイル9、ミドル電磁コイル10、ロア電磁コイル11に覆われた処理室1の上部にある石英窓13およびシャワープレート14を通して処理室1に導入される。マイクロ波による電界とそれに対して垂直方向に形成されている磁界により、電子サイクロトロン運動を行うようになる。マイクロ波の周波数が2.45GHzの場合、磁場に垂直する電子がローレンツ力による進行方向が曲げられるため、次第に電子が周回運動を行うようになる。その時の磁束密度Bは式:fc=eB/2πme(eは電子電荷量1.6×10-19C、meは電子質量9.1×10-31Kg、fcは2.45GHz)により、875Gとすると電子サイクロトロン共鳴が起こり、電子と処理室1内のガス分子の衝突確率が増えるため、低圧力下でも高密度なプラズマを生成することができる。 The circularly polarized microwaves entering the cavity 6 are introduced into the processing chamber 1 through a quartz window 13 and a shower plate 14 located at the top of the processing chamber 1, which is covered by an upper electromagnetic coil 9, a middle electromagnetic coil 10, and a lower electromagnetic coil 11. The electric field generated by the microwaves and the magnetic field formed perpendicular to the electric field cause electron cyclotron motion. When the microwave frequency is 2.45 GHz, electrons perpendicular to the magnetic field are deflected by the Lorentz force, gradually causing the electrons to undergo circular motion. The magnetic flux density B at this time is calculated using the formula fc = eB/2πme (e is the electron charge of 1.6×10 −19 C, me is the electron mass of 9.1×10 −31 Kg, and fc is 2.45 GHz). At 875 G, electron cyclotron resonance occurs, increasing the probability of collisions between electrons and gas molecules in the processing chamber 1. This enables high-density plasma to be generated even at low pressures.

処理室1は真空ポンプ17により、エッチング処理時の圧力は1Pa前後に減圧され、この圧力領域で1011cm-3以上の高密度プラズマが得られる。また、被処理基板載台15に印加するRF電源16によりプラズマ形成と独立イオンエネルギーを制御できるようになっているため、精密な形状制御が可能である。更に、被処理基板wの面内均一性を高めるため、1/4波長板8を用いて、処理室1内に円偏波を投入している。 The pressure in the processing chamber 1 is reduced to around 1 Pa during etching by a vacuum pump 17, and high-density plasma of 10 11 cm -3 or higher can be obtained in this pressure range. Furthermore, the RF power supply 16 applied to the substrate stage 15 allows for control of plasma formation and independent ion energy, enabling precise shape control. Furthermore, to improve the in-plane uniformity of the substrate w to be processed, a circularly polarized wave is introduced into the processing chamber 1 using a quarter-wave plate 8.

従来技術の1/4波長板8による円偏波の軸比は処理室1からの反射を考慮していないため、処理室1内のプラズマ密度が一定値になると処理室1から反射波が生じてしまう。この反射波は入射波と定在波を形成してしまうため、円形導波管5内のTE11モード電界の回転を妨げ、処理室1に投入したい円偏波の軸比が低下してしまう。なお、軸比は円偏波の真円度と定義され、1は最も真円率が高い。 The axial ratio of the circularly polarized wave generated by the quarter-wave plate 8 of the prior art does not take into account reflection from the processing chamber 1, so when the plasma density in the processing chamber 1 reaches a certain value, a reflected wave is generated from the processing chamber 1. This reflected wave forms a standing wave with the incident wave, which hinders the rotation of the TE11 mode electric field in the circular waveguide 5 and reduces the axial ratio of the circularly polarized wave to be input into the processing chamber 1. The axial ratio is defined as the circularity of the circularly polarized wave, with 1 being the highest circularity.

被処理基板w上で均一なプラズマ処理を施すには、当然ながら被処理基板w付近でのプラズマの密度や温度などのプラズマ特性の分布が重要であり、プラズマ分布をプラズマ処理均一化の観点から最適化する技術が重要である。 To perform uniform plasma processing on the substrate w to be processed, the distribution of plasma characteristics such as plasma density and temperature near the substrate w to be processed is, of course, important, and technology to optimize the plasma distribution from the perspective of uniform plasma processing is important.

マイクロ波電力によりプラズマを発生させるプラズマ処理装置は低圧力下でも高密度のプラズマを生成でき、静磁界との併用でプラズマの分布を静磁界分布調整で容易に制御できる等の特徴を持ち、半導体処理装置の製造等に広く用いられている。前述の基板大径化の傾向に対応してマイクロ波プラズマ処理装置においても、プラズマ分布の制御が重要である。しかしマイクロ波は波長が数cmから十数cm程度と短く、波長と同等オーダーの寸法の半導体基板上のマイクロ波の電界分布が変わりやすく、広い範囲で均一なプラズマ処理を得るべくマイクロ波の分布を最適化することが課題となる。 Plasma processing equipment that generates plasma using microwave power can generate high-density plasma even under low pressure, and when used in conjunction with a static magnetic field, the plasma distribution can be easily controlled by adjusting the static magnetic field distribution. These features make them widely used in the manufacture of semiconductor processing equipment. In response to the trend toward larger substrate diameters mentioned above, controlling the plasma distribution is also important in microwave plasma processing equipment. However, microwave wavelengths are short, ranging from a few centimeters to several dozen centimeters, and the electric field distribution of microwaves on semiconductor substrates with dimensions on the same order as the wavelength is prone to change. Therefore, optimizing the microwave distribution to achieve uniform plasma processing over a wide area presents a challenge.

マイクロ波を用いてプラズマを発生させるプラズマ源において、円偏波化したマイクロ波を用いる従来技術として、例えば下記の先行技術文献がある。 In plasma sources that generate plasma using microwaves, examples of conventional technology that uses circularly polarized microwaves include the following prior art documents.

特開2010-192750号公報JP 2010-192750 A 特開2003-188152号公報Japanese Patent Application Laid-Open No. 2003-188152 特開2006-339547号公報Japanese Patent Application Laid-Open No. 2006-339547

Michael A. Lieberman et. al, “Principles of Plasma Discharges and Materials Processing”John Wiley & Sons, Inc. (2005)Michael A. Lieberman et. al, “Principles of Plasma Discharges and Materials Processing”John Wiley & Sons, Inc. (2005)

半導体デバイスの構造パターンのエッチング、特に半導体デバイス動作特性を支配するゲート加工の形状精度、エッチングレートの均一性は年々厳しくなってきている。前述の課題を解決するために、ドライエッチングに使われるECRプラズマの分布制御技術が数多く提案されてきた。 Etching of structural patterns in semiconductor devices, particularly the shape accuracy of gate processing, which governs the operating characteristics of semiconductor devices, and the uniformity of etching rates, are becoming increasingly stringent. To solve the aforementioned issues, numerous distribution control technologies for ECR plasma used in dry etching have been proposed.

従来の技術として、特許文献1では、マグネトロンと接続した矩形導波管よりTE10といったシングルモードのマイクロ波を、前述の矩形導波管と接続している円形導波管内に1/4λg(ここに示したλgは2.45GHzにおけるφ90mm円形導波管内の電磁波の波長)の波長板を挿入し、円形導波管内にTE11モードの回転電界を形成し、プラズマ処理装置の処理室に対して放射することで、高いエッチングレートの均一性を実現する。しかしながら特許文献1の位相板は主偏波面となす角度は時計回りの45°となり、エッチングのプロセス中には右回りの電磁波(以降右回りの電磁波をR波、左回りの電磁波をL波と称す)しか放射できない。In the prior art disclosed in Patent Document 1, a single-mode microwave such as TE10 is transmitted from a rectangular waveguide connected to a magnetron by inserting a 1/4λg waveplate (λg shown here is the wavelength of the electromagnetic wave in a φ90 mm circular waveguide at 2.45 GHz) into a circular waveguide connected to the rectangular waveguide. This creates a rotating TE11 mode electric field within the circular waveguide, which is then radiated into the processing chamber of a plasma processing device, thereby achieving a high etching rate uniformity. However, the phase plate in Patent Document 1 forms a 45° clockwise angle with the primary polarization plane, and can only radiate right-handed electromagnetic waves (hereinafter, right-handed electromagnetic waves will be referred to as R-waves and left-handed electromagnetic waves as L-waves) during the etching process.

非特許文献1に示されるように、R波の電磁波エネルギーは有磁場Bの環境下ではローレンツ力により磁力線に巻き付く電子に連続的に加速するため、マイクロ波のエネルギーが電子に吸収されやすく、電子温度Teが大きくなる。これにより、半導体デバイス構造のFinFET等の微細パターン上部に電子シェルディング効果をもたらす結果、基板上のデバイスパターンの密部と疎部のそれぞれの鰭部の壁面に入射するイオン軌道が電子シェルディング効果の負電界によって曲げられるため、FinFETの鰭部の根本に程度が異なるノーチが形成されてしまう。As shown in Non-Patent Document 1, in a magnetic field B environment, the electromagnetic energy of R waves is continuously accelerated by the Lorentz force into electrons wrapped around the magnetic field lines, which makes it easier for the microwave energy to be absorbed by the electrons, increasing the electron temperature Te. This causes an electron-shelling effect on the top of fine patterns such as FinFETs in semiconductor device structures. As a result, the ion trajectories incident on the wall surfaces of the fins in the dense and sparse portions of the device pattern on the substrate are bent by the negative electric field of the electron-shelling effect, resulting in the formation of notches of varying degrees at the base of the fins of the FinFET.

特許文献2では円形導波管に回転のTE11モード電磁波を放射させるために、矩形導波管と円形導波管の接続部にクロススロットを使用するが、特許文献2も特許文献1と同様にプラズマ処理のプロセス中にはR波またはL波のどちらかしか放射できないのと、決まったプロセス条件に応じたクロススロットの寸法、角度を設計するため、処理室内のインピーダンスが変化した場合には追従できず、放射する円偏波の軸比が低下することがある。また、R波を選択した場合は、投入するマイクロ波電力の増加につれ、電子温度Teが大きくなりすぎ、L波を選択した場合はプラズマ着火困難の課題がある。 In Patent Document 2, a cross slot is used at the connection between the rectangular and circular waveguides to radiate rotational TE11 mode electromagnetic waves into the circular waveguide. However, like Patent Document 1, Patent Document 2 can only radiate either R-waves or L-waves during the plasma processing process. Furthermore, because the dimensions and angle of the cross slot are designed according to specific process conditions, it cannot follow changes in impedance within the processing chamber, which can result in a decrease in the axial ratio of the radiated circularly polarized waves. Furthermore, when R-waves are selected, the electron temperature Te becomes too high as the input microwave power increases, and when L-waves are selected, plasma ignition becomes difficult.

特許文献3は2本の矩形導波管をL字に接続し、L字の直角部に円形導波管と接続する反射抑制部を設けている。2本の矩形導波管のそれぞれの入射端に異なるマグネトロンに接続することで、前述のL字の直角部と接続している合成室にて円偏波を合成している。特許文献3ではプラズマ処理装置のリアクタ内にL波を放射するとの記述はないものの、2台のマグネトロンの出力位相を調整することで、R波またL波を提供可能になると考えられる。しかしながら、前述のL字となった2本の矩形導波管はシングルモードのTE10のマイクロ波を伝搬させられるため、プラズマ処理装置の処理室内のプラズマ負荷による反射波も伝搬でき、円偏波の軸比を維持するのに、矩形導波管部にスリースタブのチューナーを用意することが必要になることと、TE10モードが伝搬することから、リアクタからの反射波も同様に前述の矩形導波管内を伝播することになり、プラズマ処理装置のプロセス条件によって、リアクタ内に放射する円偏波の軸比が変化することになる。Patent Document 3 connects two rectangular waveguides in an L shape, with a reflection suppression section at the right angle of the L shape that connects to a circular waveguide. By connecting different magnetrons to the input ends of each of the two rectangular waveguides, circularly polarized waves are combined in a combining chamber connected to the right angle of the L shape. Patent Document 3 does not mention radiating L waves into the reactor of a plasma processing device, but it is believed that adjusting the output phase of the two magnetrons makes it possible to provide R or L waves. However, because the two L-shaped rectangular waveguides mentioned above can propagate single-mode TE10 microwaves, they can also propagate reflected waves due to the plasma load within the processing chamber of the plasma processing device. Maintaining the axial ratio of the circularly polarized waves requires a three-stub tuner in the rectangular waveguide section. Furthermore, because TE10 mode propagates, reflected waves from the reactor also propagate within the rectangular waveguide. This causes the axial ratio of the circularly polarized waves radiated into the reactor to change depending on the process conditions of the plasma processing device.

本発明の一実施の態様であるプラズマ処理装置は、プラズマ処理を行う処理室と、処理室のキャビティと連結し、TE11モードのマイクロ波電力が伝搬可能な円形導波管と、nを2以上の自然数として、2n個の固体素子マイクロ波源と、固体素子マイクロ波源のそれぞれが出力するマイクロ波電力の位相を制御する位相コントローラーと、固体素子マイクロ波源のそれぞれに接続され、マイクロ波電力をTEMモードからTE10モードに変換する2n個の同軸導波管変換器と、円形導波管の軸方向に垂直な同一平面上で円形導波管に接続される2n個のカットオフ導波管を備え、隣接するカットオフ導波管同士の軸方向のなす角が180°/nとされた偏波合成アンテナと、を有し、2n個のカットオフ導波管は、2n個の同軸導波管変換器と一対一の関係で接続され、カットオフ導波管において、TE10モードのマイクロ波電力は遮断され、円形導波管に向かってエバーネッセント場が励起される。 A plasma processing apparatus according to one embodiment of the present invention comprises a processing chamber for performing plasma processing, a circular waveguide connected to the cavity of the processing chamber and capable of propagating microwave power in TE11 mode, 2n solid-state microwave sources, where n is a natural number greater than or equal to 2, a phase controller for controlling the phase of the microwave power output by each of the solid-state microwave sources, 2n coaxial-waveguide converters connected to each of the solid-state microwave sources and converting the microwave power from TEM mode to TE10 mode, and a polarization combining antenna having 2n cutoff waveguides connected to the circular waveguides on the same plane perpendicular to the axial direction of the circular waveguides, with the angle between adjacent cutoff waveguides in the axial direction being 180°/n. The 2n cutoff waveguides are connected to the 2n coaxial-waveguide converters in a one-to-one relationship, and in the cutoff waveguides, microwave power in TE10 mode is blocked and an evanescent field is excited toward the circular waveguide.

本発明によれば、反射波を抑制して高い軸比の円偏波を放射でき、また、選択的に偏波の放射形態を変えることができるマイクロ波を利用するプラズマ処理装置を提供できる。その他の課題と新規な特徴は、本明細書の記述および添付図面から明らかになるであろう。 The present invention provides a microwave-based plasma processing apparatus that can suppress reflected waves, radiate circularly polarized waves with a high axial ratio, and selectively change the polarization radiation pattern. Other objectives and novel features will become apparent from the description of this specification and the accompanying drawings.

ECRプラズマ処理装置の構成図である。FIG. 1 is a diagram illustrating the configuration of an ECR plasma processing apparatus. 実施例1の偏波合成アンテナの水平断面図である。1 is a horizontal cross-sectional view of a polarization combining antenna according to a first embodiment. 固体素子マイクロ波源の位相制御によるR波結合原理の説明図である。FIG. 1 is an explanatory diagram of the principle of R-wave coupling by phase control of a solid-state microwave source. 固体素子マイクロ波源の位相制御によるR波結合原理の説明図である。FIG. 1 is an explanatory diagram of the principle of R-wave coupling by phase control of a solid-state microwave source. 固体素子マイクロ波源の位相制御によるR波結合原理の説明図である。FIG. 1 is an explanatory diagram of the principle of R-wave coupling by phase control of a solid-state microwave source. 固体素子マイクロ波源出力位相の組み合わせによる円形導波管内の電界強度分布の電磁界シミュレーション結果の図である。10A and 10B are diagrams showing the results of an electromagnetic field simulation of the electric field strength distribution in a circular waveguide according to the combination of the output phases of a solid-state microwave source. 実施例2の偏波合成アンテナの水平断面図である。FIG. 10 is a horizontal cross-sectional view of the polarization combining antenna of the second embodiment. 任意の一定時間内に放射する偏波の組み合わせ例である。This is an example of a combination of polarizations emitted within an arbitrary fixed time period. 処理装置の反射係数の違いによる円形導波管内の軸比の変化についてのシミュレーション結果である。10 shows the results of a simulation of the change in the axial ratio in a circular waveguide due to differences in the reflection coefficient of the processing device. 従来のECRプラズマ処理装置の構成図である。FIG. 1 is a diagram showing the configuration of a conventional ECR plasma processing apparatus.

以下、図面を用いて本発明の実施例を説明する。 Below, an embodiment of the present invention will be described using the drawings.

図1~4を用いて、実施例1の構成を説明する。図1に、実施例1のECRプラズマ処理装置の全体構成を示す。なお、図8と共通する構成については同じ符号を付して、重複する説明については省略する。処理室1は、真空ポンプ17によって約0.1~1Pa程度に減圧された高真空容器となる。本実施例では、位相コントローラー7を備え、複数の固体素子マイクロ波源2の出力位相および電力のON/OFF操作の制御ができる。複数の固体素子マイクロ波源2はそれぞれ同軸導波管変換器3と接続され、同軸導波管変換器3はそれぞれカットオフ導波管4と接続され、固体素子マイクロ波源2からのマイクロ波電力は同軸導波管変換器3からカットオフ導波管4に導入される。 The configuration of Example 1 will be explained using Figures 1 to 4. Figure 1 shows the overall configuration of the ECR plasma processing apparatus of Example 1. Components common to Figure 8 are assigned the same reference numerals, and duplicate explanations will be omitted. The processing chamber 1 is a high-vacuum vessel depressurized to approximately 0.1 to 1 Pa by a vacuum pump 17. In this example, a phase controller 7 is provided, which can control the output phase and power ON/OFF operation of multiple solid-state microwave sources 2. Each of the multiple solid-state microwave sources 2 is connected to a coaxial-waveguide converter 3, and each of the coaxial-waveguide converters 3 is connected to a cutoff waveguide 4, and microwave power from the solid-state microwave source 2 is introduced from the coaxial-waveguide converter 3 to the cutoff waveguide 4.

キャビティ6にマイクロ波を放射させるため、ここでは2.45GHzのTE11モードのマイクロ波が伝搬できる直径90mmの円形導波管5を複数のカットオフ導波管4と接続する。固体素子マイクロ波源2の出力周波数は2.45GHzとなるため、TE10モードのマイクロ波を遮断できるように、カットオフ導波管4の幅は60mm、円形導波管5の最外周r=45mmまでの長さを42.5mmとする。カットオフ導波管4の接続数は2n(ただし、nは2以上の自然数)とする。円形導波管5と複数のカットオフ導波管4との接続部分において偏波合成アンテナが構成される。カットオフ導波管4は矩形導波管を想定するが、円形導波管であってもよい。 To radiate microwaves into the cavity 6, a 90 mm diameter circular waveguide 5 capable of propagating 2.45 GHz TE11 mode microwaves is connected to multiple cutoff waveguides 4. Since the output frequency of the solid-state microwave source 2 is 2.45 GHz, the width of the cutoff waveguide 4 is 60 mm, and the length to the outermost periphery of the circular waveguide 5 (r = 45 mm) is 42.5 mm to block TE10 mode microwaves. The number of connected cutoff waveguides 4 is 2n (where n is a natural number greater than or equal to 2). A polarization combining antenna is formed at the connection between the circular waveguide 5 and multiple cutoff waveguides 4. The cutoff waveguide 4 is assumed to be a rectangular waveguide, but it may also be a circular waveguide.

図2に、実施例1の偏波合成アンテナの水平断面図を示す(図1に示すA-A断面に相当する)。図2に示した偏波合成アンテナのカットオフ導波管4はn=2すなわち4本の構成で、それぞれを円形導波管5の軸方向に垂直な同一平面上に0°、90°、180°、270°の方角に接続する。方角によって、以後は0°方角のカットオフ導波管4を4#1、90°方角のカットオフ導波管4を4#2、180°方角のカットオフ導波管4を4#3、270°方角のカットオフ導波管4を4#4と表記する。また、4本のカットオフ導波管4#1、4#2、4#3、4#4と同軸導波管変換器3と接続する箇所をそれぞれポート1、ポート2、ポート3、ポート4とする。なお、n≧3の場合も、カットオフ導波管は円形導波管5の軸方向に垂直な同一平面上で、隣接するカットオフ導波管同士の軸方向のなす角が180°/nとなるように接続される。 Figure 2 shows a horizontal cross section of the polarization combining antenna of Example 1 (corresponding to the A-A cross section shown in Figure 1). The polarization combining antenna shown in Figure 2 has n=2 cutoff waveguides 4, i.e., four cutoff waveguides, each connected at 0°, 90°, 180°, and 270° directions on the same plane perpendicular to the axial direction of the circular waveguide 5. Depending on the direction, the cutoff waveguide 4 at 0° direction will be referred to as 4#1, the cutoff waveguide 4 at 90° direction as 4#2, the cutoff waveguide 4 at 180° direction as 4#3, and the cutoff waveguide 4 at 270° direction as 4#4. In addition, the points where the four cutoff waveguides 4#1, 4#2, 4#3, and 4#4 are connected to the coaxial waveguide converter 3 will be referred to as port 1, port 2, port 3, and port 4, respectively. Even when n≧3, the cutoff waveguides are connected on the same plane perpendicular to the axial direction of the circular waveguide 5 so that the angle between the axial directions of adjacent cutoff waveguides is 180°/n.

図1に示した同軸導波管変換器3と固体素子マイクロ波源2は、4本のカットオフ導波管4に対応して、それぞれ4つ設けられている。4つの固体素子マイクロ波源2の出力位相は、例えば図3Aに示すように0π、1/2π、π、3/2πに制御し、同軸導波管変換器3に導入され、TEMモードからTE10モードに変換される。TE10モードのマイクロ波は電磁波の形態のためカットオフ導波管4内で伝搬することなく、そのマイクロ波電力によってカットオフ導波管4の一定な距離内に円形導波管5に向かってエバーネッセント場を励起する。励起されたエバーネッセント場は偏波合成アンテナのカットオフ導波管4と円形導波管5との接続部に電界を形成することで、円形導波管5に改めて電磁波を放射する。この際に放射される電磁波は、円形導波管5内を伝搬するTE11モードとなる。円形導波管5からのTE11モードの電磁波は、エバーネッセント場の電場が形成される周波数と同じ2.45GHzのため、円形導波管5を伝搬するTE11モードの電磁波も2.45GHzとなる。 The coaxial-waveguide converters 3 and solid-state microwave sources 2 shown in Figure 1 are provided in sets of four, corresponding to the four cutoff waveguides 4. The output phases of the four solid-state microwave sources 2 are controlled to, for example, 0π, 1/2π, π, and 3/2π as shown in Figure 3A, and are introduced into the coaxial-waveguide converter 3, where they are converted from TEM mode to TE10 mode. Because TE10 mode microwaves are in the form of electromagnetic waves, they do not propagate within the cutoff waveguide 4. Instead, their microwave power excites an evanescent field toward the circular waveguide 5 within a certain distance of the cutoff waveguide 4. The excited evanescent field forms an electric field at the junction between the cutoff waveguide 4 and the circular waveguide 5 of the polarization combining antenna, thereby radiating electromagnetic waves back into the circular waveguide 5. The radiated electromagnetic waves are in TE11 mode, propagating within the circular waveguide 5. Since the TE11 mode electromagnetic wave from the circular waveguide 5 has the same frequency of 2.45 GHz as the frequency at which the electric field of the evanescent field is formed, the TE11 mode electromagnetic wave propagating through the circular waveguide 5 also has a frequency of 2.45 GHz.

以上の説明のように、結果的に偏波合成アンテナの円形導波管5からキャビティ6に向かってTE11モードのマイクロ波を放射することになるが、直接マイクロ波電源(波源)からの電磁波伝搬を利用することはない。本実施例のマイクロ波電源(固体素子マイクロ波源2)はあくまでもカットオフ導波管4と円形導波管5の接続部にエバーネッセント場を励振するために使用される。As explained above, microwaves in TE11 mode are ultimately radiated from the circular waveguide 5 of the polarization combining antenna toward the cavity 6, but electromagnetic wave propagation from the microwave power source (wave source) is not directly utilized. The microwave power source (solid-state microwave source 2) in this embodiment is used solely to excite an evanescent field at the junction between the cutoff waveguide 4 and the circular waveguide 5.

図3A~Cに、本発明の固体素子マイクロ波源の位相制御によるR波結合原理説明図を示す。図3Aは、位相コントローラー7により4つの固体素子マイクロ波源2をそれぞれ制御し、4本のカットオフ導波管4#1、4#2、4#3、4#4への位相をそれぞれ0°、90°、180°、270°とした例である。図3Bに示すように、時間O1にはポート1とポート3の出力位相によって-Ex方向の電界が結合される。同じく、図3Cに示すように、時間O2にはポート2とポート4の出力位相によって+Ey方向の電界が結合される。前述の時間O1の位相と時間O2の位相の差を1/2πに制御することで、円形導波管5内に円偏波が放射される。図3Aの1周期タイミングチャートは固体素子マイクロ波源2からの出力電力の位相制御によってR波の円偏波が合成される例となる。Figures 3A-3C illustrate the principle of R-wave coupling using phase control of the solid-state microwave source of the present invention. Figure 3A shows an example in which four solid-state microwave sources 2 are controlled by a phase controller 7, with the phases to four cutoff waveguides 4#1, 4#2, 4#3, and 4#4 set to 0°, 90°, 180°, and 270°, respectively. As shown in Figure 3B, at time O1, an electric field in the -Ex direction is coupled by the output phases of ports 1 and 3. Similarly, as shown in Figure 3C, at time O2, an electric field in the +Ey direction is coupled by the output phases of ports 2 and 4. By controlling the phase difference between time O1 and time O2 to 1/2π, circularly polarized waves are radiated into the circular waveguide 5. The one-cycle timing chart in Figure 3A shows an example in which circularly polarized R-waves are synthesized by phase control of the output power from the solid-state microwave source 2.

なお、図3Aのタイミングチャートを逆転すれば、すなわちカットオフ導波管4#1、4#2、4#3、4#4への供給電力位相をそれぞれ270°、180°、90°、0°にすればL波の円偏波が円形導波管5に形成される。さらに、図3Aではポート1とポート3、ポート2とポート4はそれぞれが同じタイミングでエバーネッセント場を励起するが、ポート1とポート4、ポート2とポート3の位相組み合わせであっても円形導波管5に回転電界、すなわち右回り円偏波(R波)を結合できる。ただし、この場合、図3Aに示したポート1とポート3、ポート2とポート4の位相組み合わせよりも放射電力が1/2になる。 Note that if the timing chart in Figure 3A is reversed, i.e., if the phases of the power supplied to cutoff waveguides 4#1, 4#2, 4#3, and 4#4 are set to 270°, 180°, 90°, and 0°, respectively, circularly polarized L-waves will be formed in circular waveguide 5. Furthermore, in Figure 3A, ports 1 and 3, and ports 2 and 4, respectively, excite evanescent fields at the same timing, but even with the phase combinations of ports 1 and 4 and ports 2 and 3, a rotating electric field, i.e., right-handed circularly polarized R-waves, can be coupled into circular waveguide 5. However, in this case, the radiated power will be half that of the phase combinations of ports 1 and 3 and ports 2 and 4 shown in Figure 3A.

図4に、固体素子マイクロ波源出力位相の組み合わせによる円形導波管内の電界強度分布の電磁界シミュレーション結果を示す。図4に示すように、円形導波管5の4方角に接続したカットオフ導波管4に、固体素子マイクロ波源2のマイクロ波放射位相を制御することで、円形導波管5内にR波、L波の円偏波、+Ey方向(+Eyの時計周りを正とし、反時計周りを負とする)の-45°、45°、90°、0°の楕円偏波が放射され、キャビティ6を経由し、処理室1に放射できる。このように、図2の偏波合成アンテナの4本のカットオフ導波管4の空間的配置、および図3の位相制御を用いて位相コントローラー7により固体素子マイクロ波源2の出力位相を制御すれば、処理室1に放射される電磁波の図4のような円偏波、楕円偏波、電力調整が可能になる。Figure 4 shows the results of an electromagnetic field simulation of the electric field strength distribution within a circular waveguide depending on the combination of solid-state microwave source output phases. As shown in Figure 4, by controlling the microwave radiation phase of the solid-state microwave source 2 to the cutoff waveguides 4 connected to the four corners of the circular waveguide 5, circularly polarized R-waves and L-waves, as well as elliptically polarized waves at -45°, 45°, 90°, and 0° in the +Ey direction (clockwise around +Ey is positive, counterclockwise around +Ey is negative), are radiated into the circular waveguide 5, which then travels through the cavity 6 and enters the processing chamber 1. In this way, by controlling the spatial arrangement of the four cutoff waveguides 4 of the polarization combining antenna in Figure 2 and the output phase of the solid-state microwave source 2 with the phase controller 7 using the phase control in Figure 3, it is possible to adjust the circular polarization, elliptically polarized waves, and power of the electromagnetic waves radiated into the processing chamber 1, as shown in Figure 4.

円形導波管5から放射された電磁波は本実施例のプラズマ処理装置のキャビティ6で共振しながら、石英窓13、シャワープレート14を透過し、処理室1に電磁波電力を供給する。この際にアッパー電磁コイル9、ミドル電磁コイル10、ロア電磁コイル11によって処理室1内の静磁場B(図示なし)が形成され、シャワープレート14のガス穴よりプロセスガスGが供給される。静磁場Bの磁力線に巻き付く電子は供給された電磁波に加速され、電子サイクロトロン共鳴を引き起こし、結果的に電磁波パワーを吸収し、処理室1の減圧された真空容器内に磁束密度が875Gの箇所にプラズマのECR面(共鳴点)が形成され、時間と共にプラズマが広がり、生成される。 The electromagnetic waves emitted from the circular waveguide 5 resonate in the cavity 6 of the plasma processing apparatus of this embodiment, passing through the quartz window 13 and shower plate 14 and supplying electromagnetic power to the processing chamber 1. At this time, a static magnetic field B (not shown) is formed within the processing chamber 1 by the upper electromagnetic coil 9, middle electromagnetic coil 10, and lower electromagnetic coil 11, and process gas G is supplied through the gas holes in the shower plate 14. Electrons wrapped around the magnetic field lines of the static magnetic field B are accelerated by the supplied electromagnetic waves, causing electron cyclotron resonance, which ultimately absorbs the electromagnetic wave power. A plasma ECR surface (resonance point) is formed at a location where the magnetic flux density is 875 G within the reduced-pressure vacuum vessel of the processing chamber 1, and the plasma expands and is generated over time.

図1、図2、図5を用いて、実施例2の構成を説明する。実施例1においては、偏波合成アンテナのカットオフ導波管4は直接円形導波管5に接続しているため、R波の形成メカニズムから説明すると、円形導波管5との接続部において、ポート1とポート3から励起されたエバーネッセント場は±Ex方向の電界を形成する。一方で、ポート2とポート4には±Ey方向の電界を形成する。そのため、円形導波管5からに電界が回転するTE11モードを放射できる。図3B,Cで分かるようにカットオフ導波管4に励起されたエバーネッセント場は円形導波管5内に直線偏波を形成しているため、カットオフ導波管4と円形導波管5との接続部はかならずしも円形に限定する必要性はない。 The configuration of Example 2 will be explained using Figures 1, 2, and 5. In Example 1, the cutoff waveguide 4 of the polarization combining antenna is directly connected to the circular waveguide 5, so explaining the mechanism of R-wave formation, at the connection with the circular waveguide 5, the evanescent fields excited from ports 1 and 3 form an electric field in the ±Ex direction. On the other hand, an electric field in the ±Ey direction is formed at ports 2 and 4. Therefore, the TE11 mode, in which the electric field rotates, can be emitted from the circular waveguide 5. As can be seen in Figures 3B and 3C, the evanescent field excited in the cutoff waveguide 4 forms a linearly polarized wave within the circular waveguide 5, so the connection between the cutoff waveguide 4 and the circular waveguide 5 does not necessarily have to be limited to a circular shape.

そのため、実施例2では、図5のように4方向のカットオフ導波管4との接続部は製造しやすい矩形として、円形導波管5と接続する。図5の矩形結合部501を伝搬するマイクロ波はTE10モードであるが、矩形結合部501の下部に接続する円形導波管5を伝搬するTE11モードの姿態と酷似するため、余計な反射はない。そのため、図5の矩形結合部501を設けても、実施例1のように、固体素子マイクロ波源2の位相を制御することで、処理室1に図4のように円偏波、楕円偏波、電力調整可能なマイクロ波を放射できる。 For this reason, in Example 2, the connection portion with the four-way cutoff waveguide 4 is rectangular, which is easy to manufacture, and is connected to the circular waveguide 5, as shown in Figure 5. The microwaves propagating through the rectangular coupling portion 501 in Figure 5 are in TE10 mode, but since this behavior closely resembles the TE11 mode propagating through the circular waveguide 5 connected to the bottom of the rectangular coupling portion 501, there is no unnecessary reflection. Therefore, even when the rectangular coupling portion 501 in Figure 5 is provided, by controlling the phase of the solid-state microwave source 2, as in Example 1, it is possible to radiate circularly polarized waves, elliptically polarized waves, and power-adjustable microwaves to the processing chamber 1, as shown in Figure 4.

以上を鑑み、エバーネッセント場による結合電界はそれぞれ±Ex方向、±Ey方向に直線偏波を形成することから、前述の直線偏波が伝搬できれば、図5の矩形結合部501は任意の形状でもよい。 In consideration of the above, since the coupled electric field due to the evanescent field forms linear polarization in the ±Ex and ±Ey directions, the rectangular coupling section 501 in Figure 5 may be of any shape as long as the aforementioned linear polarization can be propagated.

図1と図6を用いて実施例3の構成を説明する。従来の円偏波をプラズマ処理装置に放射する手法では、入射波及び反射波は電磁波の形態となっているため、プラズマ処理条件の中から最も円偏波軸比が高い構成、またはターゲットプロセス毎に円偏波器の設計を行ってきた。そのため、放射できる円偏波の選択性がなく、着火性、プラズマ密度の観点から一般的にR波の円偏波として装置が設計されることになる。これに対して、本実施例のプラズマ処理装置が提供できる円偏波の軸比は殆どプロセス条件に依存せず、固体素子マイクロ波源2の出力位相を制御すれば、R波、L波、楕円円偏波を選択的に円形導波管5内に形成できる。前述の特性を利用して、本実施例3では、例えば図6の一定時間t0のうち、位相コントローラー7によって4つの固体素子マイクロ波源2の出力位相やON/OFFの組み合わせを制御し、所望のタイミングによってR波放射やL波放射や楕円円偏波の多種多様なマイクロ波放射形態を放射できる。The configuration of Example 3 is described using Figures 1 and 6. In conventional methods for radiating circularly polarized waves to a plasma processing apparatus, the incident and reflected waves are in the form of electromagnetic waves. Therefore, circular polarizers have been designed for the configuration with the highest circular polarization axial ratio among the plasma processing conditions, or for each target process. As a result, there is no selectivity for the circular polarization that can be radiated, and from the standpoint of ignition and plasma density, the apparatus is generally designed for R-wave circular polarization. In contrast, the axial ratio of the circular polarization that can be provided by the plasma processing apparatus of this example is almost independent of the process conditions. By controlling the output phase of the solid-state microwave source 2, R-wave, L-wave, and elliptical circular polarization can be selectively formed within the circular waveguide 5. Utilizing the above-described characteristics, Example 3 uses the phase controller 7 to control the output phase and ON/OFF combinations of the four solid-state microwave sources 2 during a fixed time t0, for example, as shown in Figure 6, allowing for the desired timing of a wide variety of microwave radiation forms, including R-wave radiation, L-wave radiation, and elliptical circular polarization.

図7に、比較例である1/4位相板による円偏波発生装置(図8参照)と本実施例である円偏波発生装置(図1参照)について、処理装置の反射係数の違いによる円形導波管内の軸比の変化についてのシミュレーション(HFSS(High Frequency Simulation Software))結果を示す。本実施例では、固体素子マイクロ波源2の電磁波そのものを直接に偏波合成アンテナの円形導波管5から放射することなく、カットオフ導波管4によるエバーネッセント場によって間接的に円偏波を円形導波管5に導入する。このため、図7に示されるように、プラズマエッチングプロセスまたは成膜の処理条件、例えば材料ガスG、圧力等によるプラズマ負荷の変動による処理室1からの反射波を受けにくいため、プラズマ負荷の変動があっても高い軸比の円偏波を処理室1に放射できる。図7に示されるように、本実施例の構成では従来の1/4位相板マイクロ波プラズマ処理装置と異なり、反射波制御装置であるスリースタブのチューナーを導波路に具備しなくても、反射波を抑制でき(反射波は電磁波の形態となるため、カットオフ導波管4を透過できない)、高い軸比の円偏波を放射できる。Figure 7 shows the results of a simulation (using HFSS (High Frequency Simulation Software)) of the change in axial ratio within the circular waveguide due to differences in the reflection coefficient of the processing equipment for a comparative circularly polarized wave generator using a quarter-wave plate (see Figure 8) and the circularly polarized wave generator of this embodiment (see Figure 1). In this embodiment, the electromagnetic waves from the solid-state microwave source 2 are not directly emitted from the circular waveguide 5 of the polarization combining antenna, but rather the circularly polarized waves are indirectly introduced into the circular waveguide 5 by the evanescent field of the cutoff waveguide 4. Therefore, as shown in Figure 7, the system is less susceptible to reflected waves from the processing chamber 1 due to fluctuations in the plasma load caused by processing conditions during the plasma etching process or film formation, such as the material gas G and pressure, and therefore can radiate circularly polarized waves with a high axial ratio into the processing chamber 1 even if the plasma load fluctuates. As shown in FIG. 7, in the configuration of this embodiment, unlike the conventional quarter-phase plate microwave plasma processing apparatus, reflected waves can be suppressed without providing the waveguide with a three-stub tuner, which is a reflected wave control device (reflected waves are in the form of electromagnetic waves and cannot pass through the cutoff waveguide 4), and circularly polarized waves with a high axial ratio can be radiated.

また、図4のような位相組み合わせによって、円偏波だけでなく、方角の異なる楕円偏波も固体素子マイクロ波源2の出力位相の制御によって放射可能であり、被処理基板w上の膜分布やエッチングレートによって、選択的に偏波の放射形態を変えることができる。上述したように、R波は処理室1内に形成された磁場方向の電子を連続的に加速できるため高いプラズマ密度が得られる一方、マイクロ波供給電力の増加につれ電子温度Teが大きくなることから、FinFETの鰭部上端に負電荷が蓄積してしまい、電子シェルディング効果によって、ゲート形状の精密制御が困難になっていた。 Furthermore, by using phase combinations such as those shown in Figure 4, it is possible to radiate not only circularly polarized waves but also elliptically polarized waves with different directions by controlling the output phase of the solid-state microwave source 2, and the polarization radiation form can be selectively changed depending on the film distribution and etching rate on the substrate to be processed w. As mentioned above, R waves can continuously accelerate electrons in the direction of the magnetic field formed in the processing chamber 1, thereby achieving high plasma density. However, as the microwave supply power increases, the electron temperature Te increases, causing negative charge to accumulate at the top end of the fin of the FinFET, and the electron shielding effect makes precise control of the gate shape difficult.

これに対して本実施例のプラズマ処理装置によれば、位相コントローラー7によって選択的にR波とL波を切り替えることによって、電子温度Teを制御することができ、半導体デバイスのゲート形状を精密に加工可能になる。また、選択的にR波とL波を切り替えることによって、処理室1内に形成されたプラズマ領域の全体また領域的にプラズマの吸収電力を調整できるため、被処理基板wの均一なエッチングレートは勿論、被処理基板載台の温度分布等の用途によって、所望なエッチングレート分布を制御できる。ここではエッチングの例について説明したが、成膜の場合も同様である。In contrast, with the plasma processing apparatus of this embodiment, the electron temperature Te can be controlled by selectively switching between R and L waves using the phase controller 7, enabling precise processing of the gate shape of semiconductor devices. Furthermore, by selectively switching between R and L waves, the plasma absorption power of the plasma region formed within the processing chamber 1 can be adjusted globally or regionally, allowing for the control of the desired etching rate distribution depending on the application, such as the temperature distribution of the substrate support, as well as a uniform etching rate for the substrate w to be processed. While the example of etching has been described here, the same applies to film formation.

なお、本発明は上記した実施例に限定されるものではなく、様々な変形例が含まれる。例えば、上記した実施例は本発明をわかりやすく説明するために詳細に説明したものであり、必ずしも説明した全ての構成を備えるものに限定されるものではない。また、ある実施例の構成の一部を他の実施例の構成に置き換えることが可能であり、また、ある実施例の構成に他の実施例の構成を加えることも可能である。また、各実施例の構成の一部について、他の構成の追加・削除・置換をすることが可能である。 The present invention is not limited to the above-described embodiments and includes various modifications. For example, the above-described embodiments have been described in detail to clearly explain the present invention, and are not necessarily limited to those including all of the described configurations. Furthermore, it is possible to replace part of the configuration of one embodiment with the configuration of another embodiment, and it is also possible to add the configuration of another embodiment to the configuration of one embodiment. Furthermore, it is possible to add, delete, or replace part of the configuration of each embodiment with other configurations.

1…処理室
2…固体素子マイクロ波源
3…同軸導波管変換器
4…カットオフ導波管
5…円形導波管
6…キャビティ
7…位相コントローラー
9…アッパー電磁コイル
10…ミドル電磁コイル
11…ロア電磁コイル
12…ヨーク
13…石英窓
14…シャワープレート
15…被処理基板載台
16…RF電源
17…真空ポンプ
w…被処理基板
G…材料ガス
501…矩形結合部。
1...Processing chamber 2...Solid-state microwave source 3...Coaxial waveguide converter 4...Cutoff waveguide 5...Circular waveguide 6...Cavity 7...Phase controller 9...Upper electromagnetic coil 10...Middle electromagnetic coil 11...Lower electromagnetic coil 12...Yoke 13...Quartz window 14...Shower plate 15...Substrate to be processed stage 16...RF power supply 17...Vacuum pump w...Substrate to be processed G...Material gas 501...Rectangular coupling section.

Claims (9)

プラズマ処理を行う処理室と、
前記処理室のキャビティと連結し、TE11モードのマイクロ波電力が伝搬可能な円形導波管と、
nを2以上の自然数として、2n個の固体素子マイクロ波源と、
前記固体素子マイクロ波源のそれぞれが出力するマイクロ波電力の位相を制御する位相コントローラーと、
前記固体素子マイクロ波源のそれぞれに接続され、前記マイクロ波電力をTEMモードからTE10モードに変換する2n個の同軸導波管変換器と、
前記円形導波管の軸方向に垂直な同一平面上で前記円形導波管に接続される2n個のカットオフ導波管を備え、隣接する前記カットオフ導波管同士の軸方向のなす角が180°/nとされた偏波合成アンテナと、を有し、
前記2n個のカットオフ導波管は、前記2n個の同軸導波管変換器と一対一の関係で接続され、
前記カットオフ導波管において、TE10モードの前記マイクロ波電力は遮断され、前記円形導波管に向かってエバーネッセント場が励起されるプラズマ処理装置。
a processing chamber for performing plasma processing;
a circular waveguide coupled to the cavity of the processing chamber and capable of propagating microwave power in TE11 mode;
2n solid-state microwave sources, where n is a natural number equal to or greater than 2;
a phase controller for controlling the phase of microwave power output by each of the solid-state microwave sources;
2n coaxial-waveguide converters connected to each of the solid-state microwave sources to convert the microwave power from a TEM mode to a TE10 mode;
a polarization combining antenna including 2n cutoff waveguides connected to the circular waveguide on the same plane perpendicular to the axial direction of the circular waveguide, wherein the angle between adjacent cutoff waveguides in the axial direction is 180°/n,
the 2n cutoff waveguides are connected to the 2n coaxial-waveguide converters in a one-to-one relationship;
In the cutoff waveguide, the microwave power in TE10 mode is cut off, and an evanescent field is excited toward the circular waveguide.
請求項1において、
前記エバーネッセント場は、前記カットオフ導波管と前記円形導波管との接続部に電界を形成し、前記円形導波管にTE11モードのマイクロ波電力を放射するプラズマ処理装置。
In claim 1,
The evanescent field forms an electric field at a connection portion between the cutoff waveguide and the circular waveguide, and radiates microwave power in TE11 mode to the circular waveguide.
請求項1において、
前記2n個のカットオフ導波管は互いに対向するように前記円形導波管に接続される第1のカットオフ導波管と第2のカットオフ導波管とを含み、
前記2n個の固体素子マイクロ波源は第1の固体素子マイクロ波源と第2の固体素子マイクロ波源とを含み、
前記位相コントローラーは、前記第1のカットオフ導波管に接続される前記第1の固体素子マイクロ波源に、前記第2のカットオフ導波管に接続される前記第2の固体素子マイクロ波源に発生させるマイクロ波とは逆位相となるマイクロ波を発生させるプラズマ処理装置。
In claim 1,
the 2n cutoff waveguides include a first cutoff waveguide and a second cutoff waveguide connected to the circular waveguide so as to face each other,
the 2n solid state microwave sources include a first solid state microwave source and a second solid state microwave source;
The phase controller causes the first solid-state microwave source connected to the first cutoff waveguide to generate microwaves that have an opposite phase to microwaves generated by the second solid-state microwave source connected to the second cutoff waveguide.
請求項3において、
n=2として、前記2n個のカットオフ導波管は互いに対向するように前記円形導波管に接続される第3のカットオフ導波管と第4のカットオフ導波管とを含み、前記2n個の固体素子マイクロ波源は第3の固体素子マイクロ波源と第4の固体素子マイクロ波源とを含み、
前記位相コントローラーは、前記第3のカットオフ導波管に接続される前記第3の固体素子マイクロ波源に、前記第1の固体素子マイクロ波源に発生させるマイクロ波とは位相が1/2πずれたマイクロ波を発生させ、前記第4のカットオフ導波管に接続される前記第4の固体素子マイクロ波源に、前記第1の固体素子マイクロ波源に発生させるマイクロ波とは位相が4/2πずれたマイクロ波を発生させるプラズマ処理装置。
In claim 3,
where n=2, the 2n cutoff waveguides include a third cutoff waveguide and a fourth cutoff waveguide connected to the circular waveguide so as to face each other, and the 2n solid-state microwave sources include a third solid-state microwave source and a fourth solid-state microwave source;
the phase controller causes the third solid-state microwave source connected to the third cutoff waveguide to generate microwaves that are 1/2π out of phase with respect to the microwaves generated by the first solid-state microwave source, and causes the fourth solid-state microwave source connected to the fourth cutoff waveguide to generate microwaves that are 4/2π out of phase with respect to the microwaves generated by the first solid-state microwave source.
請求項1において、
n=2として、前記偏波合成アンテナにおける前記2n個のカットオフ導波管と前記円形導波管との接続部が矩形とされたプラズマ処理装置。
In claim 1,
A plasma processing apparatus in which n=2, and a connection portion between the 2n cutoff waveguides and the circular waveguide in the polarization combining antenna is rectangular.
請求項1において、
前記位相コントローラーが、前記2n個の固体素子マイクロ波源が発生させるマイクロ波の位相及び/または前記2n個の固体素子マイクロ波源の出力をON/OFFを切り替えることにより、前記円形導波管を伝搬して前記処理室に放射されるマイクロ波のマイクロ波放射形態を切り替え可能とするプラズマ処理装置。
In claim 1,
The phase controller switches ON/OFF the phases of the microwaves generated by the 2n solid-state microwave sources and/or the outputs of the 2n solid-state microwave sources, thereby enabling switching of the microwave radiation form of the microwaves propagated through the circular waveguide and radiated into the processing chamber.
請求項6において、
前記位相コントローラーが、前記2n個の固体素子マイクロ波源が発生させるマイクロ波の位相及び/または前記2n個の固体素子マイクロ波源の出力をON/OFFを切り替えることにより、右旋円偏波のマイクロ波、左旋円偏波のマイクロ波、前記円形導波管の軸方向に垂直な同一平面に含まれる所定の方角の楕円偏波のマイクロ波のいずれかを前記円形導波管内に結合させるプラズマ処理装置。
In claim 6,
The phase controller switches ON/OFF the phases of the microwaves generated by the 2n solid-state microwave sources and/or the outputs of the 2n solid-state microwave sources, thereby coupling any one of right-handed circularly polarized microwaves, left-handed circularly polarized microwaves, and elliptically polarized microwaves of a predetermined direction contained in the same plane perpendicular to the axial direction of the circular waveguide into the circular waveguide.
請求項7において、
前記処理室におけるプラズマ処理期間中に、前記処理室に放射されるマイクロ波のマイクロ波放射形態を切り替えるプラズマ処理装置。
In claim 7,
A plasma processing apparatus that switches a microwave radiation form of microwaves radiated into the processing chamber during a plasma processing period in the processing chamber.
請求項8において、
前記処理室におけるプラズマ処理は、プラズマエッチング処理または成膜処理であるプラズマ処理装置。
In claim 8,
The plasma processing apparatus in the processing chamber is a plasma etching process or a film forming process.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001358127A (en) 2000-06-14 2001-12-26 Tokyo Electron Ltd Plasma processing equipment
JP2006339547A (en) 2005-06-06 2006-12-14 Hitachi High-Technologies Corp Plasma processing equipment
JP2020004672A (en) 2018-07-02 2020-01-09 株式会社日立ハイテクノロジーズ Plasma processing equipment
JP2023119169A (en) 2022-02-16 2023-08-28 株式会社日立ハイテク Plasma processing apparatus and plasma processing method

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JP4209612B2 (en) 2001-12-19 2009-01-14 東京エレクトロン株式会社 Plasma processing equipment
JP5063626B2 (en) 2009-02-19 2012-10-31 株式会社日立ハイテクノロジーズ Plasma processing equipment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001358127A (en) 2000-06-14 2001-12-26 Tokyo Electron Ltd Plasma processing equipment
JP2006339547A (en) 2005-06-06 2006-12-14 Hitachi High-Technologies Corp Plasma processing equipment
JP2020004672A (en) 2018-07-02 2020-01-09 株式会社日立ハイテクノロジーズ Plasma processing equipment
JP2023119169A (en) 2022-02-16 2023-08-28 株式会社日立ハイテク Plasma processing apparatus and plasma processing method

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