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JP7777932B2 - Roll-in margarine - Google Patents
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JP7777932B2 - Roll-in margarine - Google Patents

Roll-in margarine

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JP7777932B2
JP7777932B2 JP2021116230A JP2021116230A JP7777932B2 JP 7777932 B2 JP7777932 B2 JP 7777932B2 JP 2021116230 A JP2021116230 A JP 2021116230A JP 2021116230 A JP2021116230 A JP 2021116230A JP 7777932 B2 JP7777932 B2 JP 7777932B2
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達則 延原
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Kaneka Corp
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Description

本発明は、層状膨化食品に好適に利用し得るロールインマーガリン及びこれを用いた層状膨化食品に関する。 The present invention relates to a roll-in margarine that can be suitably used in layered puffed foods and a layered puffed food product made using the same.

ロールインマーガリンは、生地と共に伸展され折り畳まれる工程を繰り返すことで、クロワッサンやデニッシュのような層状膨化食品特有の層を作り出す。故に、ロールインマーガリンの伸展性は、層状膨化食品の品質に大きく影響する。ロールインマーガリンは通常冷蔵で保管されるが、低温のままで使用すると、油脂が硬いままで伸展性が十分でないため割れが発生する。そこで、ロールインマーガリンの伸展性を良くするために、使用前の温度調整が行われるが、その温度が高過ぎると、油脂が軟らかくなりすぎて生地に練り込まれてしまい、パンの品質低下につながる。従って、限られた温度域への調整が必要であり、温調には時間を要するため生産効率の低下に繋がる。 By repeatedly stretching and folding the roll-in margarine along with the dough, it creates the layers characteristic of layered puffed foods such as croissants and Danish pastries. Therefore, the spreadability of roll-in margarine has a significant impact on the quality of layered puffed foods. Roll-in margarine is usually stored refrigerated, but if used at low temperatures, the fat remains hard and the spreadability is insufficient, causing cracks. Therefore, to improve the spreadability of roll-in margarine, the temperature is adjusted before use, but if the temperature is too high, the fat will become too soft and be kneaded into the dough, resulting in a decrease in bread quality. Therefore, adjustment to a limited temperature range is necessary, and temperature adjustment takes time, leading to reduced production efficiency.

また前記温度調整以外では、結晶状態の観点から、分別油やエステル交換油等を原料油脂として用いるが、それらの油脂は製造コストが上がり、原料コストがアップしてしまう。安価で有用な原料油脂としてはパーム油があるが、そのまま可塑性油脂の原料として用いると、パーム油のトリグリセリド中に約38重量%含まれるSUS(1位及び3位にC16以上の飽和脂肪酸、2位にC16以上の不飽和脂肪酸が結合しているトリグリセリド)は結晶化が遅いため、製造時の結晶量が少なくシート成型性が悪かったり、非常に可塑性の悪い製品になる場合がある。また、POP成分(1位及び3位にパルミチン酸、2位にオレイン酸が結合しているトリグリセリド)が室温付近で経時的に結晶転移することにより物性が変化する場合があり、生地に油脂を折り込んで伸展する際の割れの原因となるため、パーム油はロールインマーガリンの原料油脂としては使い難い。 In addition to the temperature adjustment, fractionated oils, interesterified oils, etc. are used as raw material fats from the viewpoint of crystallization state, but these fats increase production costs and raw material costs. Palm oil is an inexpensive and useful raw material fat, but if used as a raw material for plastic fats as is, SUS (triglycerides containing saturated fatty acids of C16 or more at the 1st and 3rd positions and unsaturated fatty acids of C16 or more at the 2nd position), which is contained in palm oil triglycerides at approximately 38% by weight, crystallizes slowly, resulting in a small amount of crystals during production, poor sheet moldability, or a product with very poor plasticity. Furthermore, POP components (triglycerides containing palmitic acid at the 1st and 3rd positions and oleic acid at the 2nd position) may undergo crystallization transition over time near room temperature, which can change their physical properties and cause cracks when the fat is folded into the dough and spread, making palm oil difficult to use as a raw material fat for roll-in margarine.

特許文献1の比較例5には、パーム油のエステル交換油と液状油を含み、ラウリン酸含量の少ないロールインマーガリンが開示されているが、この配合では製造時の結晶量が少なくシート成型性が悪い。 Comparative Example 5 of Patent Document 1 discloses a roll-in margarine containing transesterified palm oil and liquid oil, and with a low lauric acid content, but this formulation results in a low amount of crystallization during production, making it difficult to mold into sheets.

特開2012-55268号公報JP 2012-55268 A

本発明の目的は、広い使用温度域で良好な伸展性を有し、製造時のシート成型性がよく、且つクロワッサン等の層状膨化食品としたとき口当たりがソフトである、安価なロールインマーガリンを提供することである。 The object of the present invention is to provide an inexpensive roll-in margarine that has good extensibility over a wide temperature range, is easy to form into sheets during production, and has a soft texture when used in layered puffed foods such as croissants.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、ロールインマーガリン全体中、水相及び油相の含有量が特定範囲であり、更に前記油相に含まれる油脂全体中、パーム油のエステル交換油、液状油、及びラウリン系油脂以外の極度硬化油をそれぞれ特定量にすることで、ロールインマーガリンが広い使用温度域で良好な伸展性を有し、製造時のシート成型性がよく、且つ該ロールインマーガリンを用いて作製したクロワッサン等の層状膨化食品の口当たりがソフトであることを見出し、本発明を完成するに至った。 As a result of extensive research to solve the above problems, the inventors discovered that by ensuring that the aqueous phase and oil phase contents of the entire roll-in margarine are within specific ranges, and that the total oils and fats contained in the oil phase contain specific amounts of interesterified palm oil, liquid oil, and extremely hardened oils other than lauric fats, the roll-in margarine has good spreadability over a wide temperature range, good sheet formability during production, and layered puffed foods such as croissants made with this roll-in margarine have a soft texture, leading to the completion of the present invention.

即ち、本発明の第一は、ロールインマーガリン全体中に、水相を1~30重量%、及び油相を99~70重量%を含有するロールインマーガリンであって、前記油相中の油脂全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有する、ロールインマーガリンに関する。好ましい実施態様は、前記油相中の油脂全体の構成脂肪酸におけるパルミチン酸/ラウリン酸(重量比)が4~90である、前記記載のロールインマーガリンに関する。より好ましくは、前記構成脂肪酸であるラウリン酸の由来が、ラウリン系油脂とパーム系油脂とのエステル交換油及び/又はラウリン系油脂の極度硬化油である前記記載のロールインマーガリン、更に好ましくは、前記ラウリン系油脂以外の極度硬化油が、ハイエルシン菜種極度硬化油、ローエルシン菜種極度硬化油、大豆油の極度硬化油及びコーン油の極度硬化油からなる群より選ばれる少なくとも1種である、前記記載のロールインマーガリンに関する。本発明の第二は、前記記載のロールインマーガリンを含有する層状膨化食品用生地に関する。本発明の第三は、前記記載の層状膨化食品用生地が焼成された層状膨化食品に関する。本発明の第四は、油脂混合物全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有する油脂混合物を65~80℃で融解し、65~70℃に保持することで油相を得、該油相を撹拌しているところに、65~70℃で保持する水相を添加して乳化し、急冷捏和することを特徴とするロールインマーガリンの製造方法に関する。好ましい実施態様は、前記油脂混合物中の構成脂肪酸におけるパルミチン酸/ラウリン酸(重量比)が4~90である前記記載のロールインマーガリンの製造方法に関する。 That is, the first aspect of the present invention relates to a roll-in margarine that contains 1 to 30% by weight of an aqueous phase and 99 to 70% by weight of an oil phase, and that contains 35 to 70% by weight of transesterified palm oil, 12 to 35% by weight of liquid oil, and 1 to 5% by weight of an extremely hardened oil other than lauric fats and oils, based on the total fats and oils in the oil phase. A preferred embodiment relates to the above-described roll-in margarine, in which the palmitic acid/lauric acid (weight ratio) of the constituent fatty acids of the total fats and oils in the oil phase is 4 to 90. More preferably, the present invention relates to the aforementioned roll-in margarine in which the constituent fatty acid, lauric acid, is derived from interesterified oil of lauric fat and palm fat and/or extremely hydrogenated oil of lauric fat, and even more preferably, the aforementioned extremely hydrogenated oil other than lauric fat is at least one selected from the group consisting of extremely hydrogenated high-erucine rapeseed oil, extremely hydrogenated low-erucine rapeseed oil, extremely hydrogenated soybean oil, and extremely hydrogenated corn oil. A second aspect of the present invention relates to a dough for layered puffed foods containing the aforementioned roll-in margarine. A third aspect of the present invention relates to a layered puffed food obtained by baking the aforementioned dough for layered puffed foods. The fourth aspect of the present invention relates to a method for producing roll-in margarine, comprising melting an oil and fat mixture containing 35 to 70% by weight of transesterified palm oil, 12 to 35% by weight of liquid oil, and 1 to 5% by weight of an extremely hardened oil other than lauric fats and oils at 65 to 80°C and maintaining the mixture at 65 to 70°C to obtain an oil phase, and while stirring the oil phase, adding an aqueous phase maintained at 65 to 70°C to emulsify the oil phase, followed by rapid cooling and kneading. A preferred embodiment relates to the method for producing the aforementioned roll-in margarine, in which the palmitic acid/lauric acid (weight ratio) of the constituent fatty acids in the oil and fat mixture is 4 to 90.

本発明に従えば、広い使用温度域で良好な伸展性を有し、製造時のシート成型性がよく、且つクロワッサン等の層状膨化食品としたとき口当たりがソフトである、安価なロールインマーガリンを提供することができる。 According to the present invention, it is possible to provide an inexpensive roll-in margarine that has good extensibility over a wide temperature range, is easy to form into sheets during production, and has a soft texture when made into layered puffed foods such as croissants.

以下、本発明につき、さらに詳細に説明する。
本発明のロールインマーガリンは、シート状にして生地に折り込んでいくタイプのマーガリンで、水相及び油相の含有量が特定範囲であり、前記油相にはパーム油のエステル交換油、液状油、及びラウリン系油脂以外の極度硬化油をそれぞれ特定量含有することを特徴とする。なお、JAS規格(Japanese Agricultural Standard)では、油脂含有率が80%以上を「マーガリン」、80%未満は「ファットスプレッド」と定義されているが、本発明では、いずれも「マーガリン」と称する。
The present invention will be described in further detail below.
The roll-in margarine of the present invention is a margarine of the type that is formed into a sheet and folded into dough, characterized in that the contents of the aqueous phase and oil phase are within specific ranges, and the oil phase contains specific amounts of interesterified palm oil, liquid oil, and extremely hardened oil other than lauric fats and oils, respectively. Note that, while the JAS (Japanese Agricultural Standard) defines a margarine with an oil and fat content of 80% or more as "margarine" and a fat content of less than 80% as "fat spread," in the present invention, both are referred to as "margarine."

前記油相は、油脂の他、必要に応じて油溶性原料を含む。
前記油相の含有量は、ロールインマーガリン全体中70~99重量%であることが好ましく、75~97重量%であることがより好ましく、80~95重量%であることが更に好ましい。油相の含有量が70重量%より少なかったり、99重量%を超えると、良好な伸展性を示す使用温度域が狭くなる場合がある。
なお、油相中の油脂の含有量は、油相全体中95~100重量%が好ましく、より好ましくは98~100重量%である。
The oil phase contains an oil-soluble ingredient as required in addition to the fat or oil.
The content of the oil phase in the roll-in margarine is preferably 70 to 99% by weight, more preferably 75 to 97% by weight, and even more preferably 80 to 95% by weight. If the content of the oil phase is less than 70% by weight or more than 99% by weight, the temperature range in which the margarine exhibits good spreadability may become narrow.
The content of the oil or fat in the oil phase is preferably 95 to 100% by weight, more preferably 98 to 100% by weight, based on the total weight of the oil phase.

前記水相は、水の他、必要に応じて水溶性原料を含む。
前記水相の含有量は、ロールインマーガリン全体中30~1重量%であることが好ましく、25~3重量%であることがより好ましく、20~5重量%であることが更に好ましい。水相の含有量が1重量%より少なかったり、30重量%を超えると、良好な伸展性を示す使用温度域が狭くなる場合がある。
なお、水相中の水の含有量は、水相全体中30~100重量%が好ましく、より好ましくは50~100重量%である。
The aqueous phase contains water and, if necessary, water-soluble ingredients.
The content of the aqueous phase is preferably 30 to 1% by weight, more preferably 25 to 3% by weight, and even more preferably 20 to 5% by weight, of the total amount of the roll-in margarine. If the content of the aqueous phase is less than 1% by weight or exceeds 30% by weight, the temperature range in which the margarine exhibits good extensibility may become narrow.
The content of water in the aqueous phase is preferably 30 to 100% by weight, more preferably 50 to 100% by weight, based on the total weight of the aqueous phase.

前記パーム油のエステル交換油とは、分別していないパーム油をエステル交換してなる油脂、及び、その同等品のことを指す。前記分別していないパーム油は、製造コストが安価になる利点がある。前記エステル交換は常法に従って行えばよい。該エステル交換に使用可能な触媒としては、食品用途に用いられる触媒であれば種類を問わずに使用でき、例えばナトリウムメチラートやリパーゼ等が挙げられる。 The interesterified palm oil refers to fats and oils obtained by interesterifying unfractionated palm oil, and equivalent products. The unfractionated palm oil has the advantage of low production costs. The interesterification can be carried out according to conventional methods. Any catalyst used in food applications can be used for the interesterification, including, for example, sodium methylate and lipase.

前記分別していないパーム油をエステル交換してなる油脂の同等品とは、分別したパーム油や、他の油脂(例えばラード)などを適宜混合して、分別していないパームと同等の脂肪酸組成を有する油脂を調製し、該油脂をエステル交換することで得られる油脂のことをいう。ここで前記分別していないパーム油と同等の脂肪酸組成とは、概ね、構成脂肪酸全体中、ラウリン酸0.0~0.5%、ミリスチン酸0.9~1.5%、パルミチン酸39.2~45.8%、パルミトレイン酸0.0~0.4%、ステアリン酸3.7~5.1%、オレイン酸37.4~44.1%、リノール酸8.7~12.5%、リノレン酸0.0~0.6%、アラキジン酸0.0~0.5%である(出典;Malaysian Standard MS814:2007(Table2))。 The term "equivalents to fats and oils obtained by interesterifying unfractionated palm oil" refers to fats and oils obtained by mixing fractionated palm oil and other fats and oils (e.g., lard) appropriately to prepare fats and oils having a fatty acid composition equivalent to that of unfractionated palm oil, and then interesterifying the resulting fats and oils. Here, the fatty acid composition equivalent to that of unfractionated palm oil is roughly as follows: lauric acid 0.0-0.5%, myristic acid 0.9-1.5%, palmitic acid 39.2-45.8%, palmitoleic acid 0.0-0.4%, stearic acid 3.7-5.1%, oleic acid 37.4-44.1%, linoleic acid 8.7-12.5%, linolenic acid 0.0-0.6%, and arachidic acid 0.0-0.5% of the total fatty acids (Source: Malaysian Standard MS814:2007 (Table 2)).

前記パーム油のエステル交換油の含有量は、前記油相中の油脂全体中35~70重量%であることが好ましく、37~68重量%がより好ましく、40~67重量%が更に好ましい。35重量%より少ないと、良好な伸展性を示す使用温度域が狭くなったり、可塑性が悪くなる場合があり、70重量%を超えると、脆くなったり、伸展性が悪くなる場合がある。 The content of the interesterified palm oil in the total oil and fat content in the oil phase is preferably 35 to 70% by weight, more preferably 37 to 68% by weight, and even more preferably 40 to 67% by weight. If it is less than 35% by weight, the usable temperature range exhibiting good extensibility may become narrower or plasticity may deteriorate, while if it exceeds 70% by weight, the product may become brittle or extensibility may deteriorate.

前記液状油は、20℃で液状状態の油脂のことであり、例えば菜種油、大豆油、パーム油、パーム核油、ヤシ油、コーン油、サフラワー油、綿実油等の植物性油脂、或いは魚油等の動物性油脂、またこれらを水素添加、分別、エステル交換等の手法を用いて適宜処理したものなどが挙げられ、それらの群より選ばれる少なくとも1種を用いることができる。その中でも、菜種油、大豆油、コーン油、サフラワー油、綿実油が好ましく、菜種油、大豆油、コーン油がより好ましい。 The liquid oil refers to an oil or fat that is liquid at 20°C. Examples include vegetable oils such as rapeseed oil, soybean oil, palm oil, palm kernel oil, coconut oil, corn oil, safflower oil, and cottonseed oil, or animal oils such as fish oil, as well as oils obtained by appropriately processing these oils using techniques such as hydrogenation, fractionation, and interesterification. At least one oil selected from this group can be used. Among these, rapeseed oil, soybean oil, corn oil, safflower oil, and cottonseed oil are preferred, with rapeseed oil, soybean oil, and corn oil being more preferred.

前記液状油の含有量は、前記油相中の油脂全体中12~35重量%が好ましく、20~35重量%がより好ましく、23~33重量%が更に好ましい。12重量%より少ないと可塑性や伸展性が悪くなる場合がある。35重量%を超えると、シート成型性が悪くなる場合がある。 The content of the liquid oil is preferably 12 to 35% by weight, more preferably 20 to 35% by weight, and even more preferably 23 to 33% by weight, of the total oil and fat in the oil phase. If it is less than 12% by weight, plasticity and extensibility may be impaired. If it exceeds 35% by weight, sheet moldability may be impaired.

前記ラウリン系油脂以外の極度硬化油は、原料油をヨウ素価が4以下になるまで水素添加を行い、不飽和脂肪酸を殆ど含まない油脂を言い、構成脂肪酸全体中のラウリン酸含有量が5重量%未満である。具体的には、ハイエルシン菜種極度硬化油、ローエルシン菜種極度硬化油、大豆油の極度硬化油及びコーン油の極度硬化油からなる群より選ばれる少なくとも1種であることが好ましい。 The aforementioned highly hydrogenated oils other than lauric fats refer to oils and fats that are obtained by hydrogenating raw oils until the iodine value is 4 or less, and contain almost no unsaturated fatty acids. The lauric acid content of the total constituent fatty acids is less than 5% by weight. Specifically, it is preferable that the oil be at least one oil selected from the group consisting of highly hydrogenated hyercin rapeseed oil, highly hydrogenated ryercin rapeseed oil, highly hydrogenated soybean oil, and highly hydrogenated corn oil.

前記ラウリン系油脂以外の極度硬化油の含有量は、前記油相中の油脂全体中1~5重量%が好ましく、2~5重量%がより好ましく、2~4重量%が更に好ましい。1重量%より少ないと脆くなったり、可塑性や伸展性が悪くなる場合がある。又、5重量%を超えると、層状膨化食品の口あたりのソフトさが悪くなる場合がある。なお、ヨウ素価は、「日本油化学会制定、基準油脂分析試験法2.3.4.1-1996」に準拠して測定できる。 The content of the highly hydrogenated oil other than lauric fats is preferably 1 to 5% by weight, more preferably 2 to 5% by weight, and even more preferably 2 to 4% by weight, of the total oils and fats in the oil phase. If it is less than 1% by weight, the food may become brittle and its plasticity and extensibility may be impaired. If it exceeds 5% by weight, the softness of the layered expanded food may be impaired. The iodine value can be measured in accordance with "Standard Test Methods for the Analysis of Fats, Oils, and Related Materials 2.3.4.1-1996, established by the Japan Oil Chemists' Society."

前記油相に含まれる油脂全体の構成脂肪酸におけるパルミチン酸/ラウリン酸(重量比)は、より良好な伸展性を得る観点から、4~90が好ましく、5~60がより好ましく、7~40が更に好ましく、16~30が特に好ましい。該重量比が4より小さかったり、90を超えると、得られるロールインマーガリンが脆くなる場合がある。なお、パルミチン酸及びラウリン酸の測定は、「日本油化学会制定、基準油脂分析試験法暫11-2003及び暫15-2003」に記載されたメチルエステル化法及びガスクロマトグラフ法に準拠して行える。 The palmitic acid/lauric acid (weight ratio) among the constituent fatty acids of the entire fat and oil contained in the oil phase is preferably 4 to 90, more preferably 5 to 60, even more preferably 7 to 40, and particularly preferably 16 to 30, from the viewpoint of obtaining better spreadability. If the weight ratio is less than 4 or exceeds 90, the resulting roll-in margarine may become brittle. Palmitic acid and lauric acid can be measured in accordance with the methyl esterification method and gas chromatography method described in the "Standard Methods for the Analysis of Fats, Oils, and Related Materials, Provisional Tests Nos. 11-2003 and 15-2003, established by the Japan Oil Chemists' Society."

さらに、前記油相中の油脂の構成脂肪酸として、良好な可塑性を得る観点から、ラウリン酸を含むことが好ましく、該ラウリン酸の由来としては、ラウリン系油脂とパーム系油脂とのエステル交換油及び/又はラウリン系油脂の極度硬化油であることが好ましい。 Furthermore, from the viewpoint of obtaining good plasticity, it is preferable that the constituent fatty acids of the oil in the oil phase contain lauric acid, and the lauric acid is preferably derived from interesterified oil of lauric oil and palm oil and/or extremely hardened oil of lauric oil.

前記ラウリン系油脂は、構成脂肪酸残基中のC12以下の脂肪酸残基を比較的豊富に含有する油脂であり、油脂混合物のC12以下の脂肪酸含有率を所定値にできるものであれば何等制限されず、具体的には、ヤシ油、パーム核油、ババス油、乳脂などが挙げられる。また、それらの分別油、硬化油、エステル交換油脂を単独又は混合して用いることもできる。それらを極度硬化してヨウ素価が4以下にする際は、常法に従って水素添加を行えばよい。 The lauric fats and oils are those that are relatively rich in C12 or less fatty acid residues among their constituent fatty acid residues, and are not particularly limited as long as they can adjust the C12 or less fatty acid content of the oil and fat mixture to a predetermined value. Specific examples include coconut oil, palm kernel oil, babassu oil, and milk fat. Fractionated oils, hardened oils, and interesterified oils and fats thereof can also be used alone or in combination. When these oils and fats are subjected to extreme hardening to reduce the iodine value to 4 or less, hydrogenation can be carried out according to a conventional method.

前記パーム系油脂としては、パーム油に由来する油脂であれば特に限定されず、具体的には、パーム油、パームステアリン、パーム中融点部、パームオレイン、パームダブルオレイン、パームスーパーオレイン、パームトップオレイン、パームハードステアリン等のパーム分別油等が挙げられる。また、それらの分別油、硬化油、エステル交換油脂を単独又は混合して用いることもできる。ここで、前記ラウリン系油脂とパーム系油脂とのエステル交換油は、ラウリン系油脂とパーム系油脂の混合油脂を常法に従ってエステル交換を行えばよい。 The palm-based fats and oils are not particularly limited as long as they are derived from palm oil. Specific examples include palm oil, palm stearin, palm mid-melting point fraction, palm olein, palm double olein, palm superolein, palm top olein, palm hard stearin, and other palm fractionated oils. These fractionated oils, hardened oils, and interesterified fats can also be used alone or in combination. The interesterified oil of lauric fat and palm-based fat can be obtained by interesterifying a mixture of lauric fat and palm-based fat according to conventional methods.

前記ラウリン系油脂とパーム系油脂とのエステル交換油及び/又はラウリン系油脂の極度硬化油の含有量は、前記油相中の油脂全体中2~20重量%が好ましく、3~18重量%がより好ましく、4~17重量%が更に好ましく、4~16.5重量%が特に好ましい。含有量が上記範囲内であれば、前記油相中の油脂全体の構成脂肪酸におけるパルミチン酸/ラウリン酸(重量比)を容易にコントロールできる。 The content of the interesterified oil of lauric fat and palm fat and/or the extremely hardened oil of lauric fat is preferably 2 to 20% by weight, more preferably 3 to 18% by weight, even more preferably 4 to 17% by weight, and particularly preferably 4 to 16.5% by weight, of the total fats and oils in the oil phase. If the content is within the above range, the palmitic acid/lauric acid (weight ratio) of the constituent fatty acids of the total fats and oils in the oil phase can be easily controlled.

本発明のロールインマーガリンの油相には、前記記載の原材料の他に、必要に応じて油溶性原料を添加することができる。前記油溶性原料としては、油溶性の乳化剤、香料、酸化防止剤などが挙げられる。 In addition to the raw materials described above, oil-soluble ingredients can be added to the oil phase of the roll-in margarine of the present invention as needed. Examples of oil-soluble ingredients include oil-soluble emulsifiers, flavorings, and antioxidants.

前記油溶性の乳化剤としては、HLBが0~8の乳化剤であればよく、例えば大豆レシチン、卵黄レシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、縮合リシノレイン脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステルなどが挙げられる。 The oil-soluble emulsifier may be one with an HLB of 0 to 8, and examples include soybean lecithin, egg yolk lecithin, glycerin fatty acid esters, polyglycerin fatty acid esters, condensed ricinolein fatty acid esters, sorbitan fatty acid esters, and sucrose fatty acid esters.

前記油溶性の香料としては、例えばバターフレーバー、ミルクフレーバーなどが挙げられる。 Examples of the oil-soluble flavorings include butter flavor and milk flavor.

前記油溶性の酸化防止剤としては、例えばトコフェロール、β-カロテン、ルチンなどが挙げられる。 Examples of the oil-soluble antioxidant include tocopherol, β-carotene, and rutin.

本発明のロールインマーガリンの水相には、前記記載の原材料の他に、必要に応じて水溶性原料などを含むが、例えば、糖類、水溶性の乳化剤、増粘安定剤、食塩、塩化カリウム等の塩味剤、酢酸、乳酸、グルコン酸等の酸味料、糖アルコール類、ステビア、アスパルテーム等の甘味料、水溶性のβ-カロテン、カラメル、紅麹色素等の着色料、茶抽出物(カテキン等)、水溶性のルチン等の酸化防止剤、小麦蛋白や大豆蛋白といった植物蛋白、卵及び各種卵加工品、香料、調味料、pH調整剤、食品保存料、果実、果汁、コーヒー、ナッツペースト、香辛料、ココアマス、ココアパウダー、穀類、豆類、野菜類、肉類、魚介類等の食品素材や食品添加物などを添加することもできる。 In addition to the raw materials described above, the aqueous phase of the roll-in margarine of the present invention may contain water-soluble ingredients as needed. For example, sugars, water-soluble emulsifiers, thickening stabilizers, salt seasonings such as salt and potassium chloride, acidulants such as acetic acid, lactic acid, and gluconic acid, sugar alcohols, sweeteners such as stevia and aspartame, colorings such as water-soluble beta-carotene, caramel, and red koji pigment, tea extracts (catechin, etc.), water-soluble antioxidants such as rutin, plant proteins such as wheat protein and soy protein, eggs and various egg products, flavorings, seasonings, pH adjusters, food preservatives, fruits, fruit juices, coffee, nut paste, spices, cocoa mass, cocoa powder, grains, beans, vegetables, meat, seafood, and other food ingredients and food additives may also be added.

前記糖類としては、砂糖、果糖、ブドウ糖、水飴、還元水飴、はちみつ、異性化糖、転化糖、オリゴ糖(イソマルトオリゴ糖、還元キシロオリゴ糖、還元ゲンチオオリゴ糖、キシロオリゴ糖、ゲンチチオオリゴ糖、ニゲロオリゴ糖、テアンデオリゴ糖、大豆オリゴ糖等)、トレハロース、糖アルコール(マルチトール、エリスリトール、ソルビトール、パラチニット、キシリトール、ラクチトール等)、砂糖結合水飴等を挙げることができ、粉糖でも液糖でも構わない。また甘味成分も糖類の代わりに用いることができる。具体的にはアスパルテーム、アセスルファムカリウム、スクラロース、アリテーム、ネオテーム、カンゾウ抽出物(グリチルリチン)、サッカリン、サッカリンナトリウム、ステビア抽出物、ステビア粉末等の甘味成分などが挙げられ、これらの群より選ばれる少なくとも1種を使用できる。 Examples of the sugars include sugar, fructose, glucose, starch syrup, reduced starch syrup, honey, isomerized sugar, invert sugar, oligosaccharides (isomaltooligosaccharides, reduced xylooligosaccharides, reduced gentiooligosaccharides, xylooligosaccharides, gentiooligosaccharides, nigerooligosaccharides, theandeooligosaccharides, soybean oligosaccharides, etc.), trehalose, sugar alcohols (maltitol, erythritol, sorbitol, palatinit, xylitol, lactitol, etc.), and sugar-bound starch syrup. Powdered sugar or liquid sugar may also be used. Sweetening ingredients can also be used in place of sugars. Specific examples include aspartame, acesulfame potassium, sucralose, alitame, neotame, licorice extract (glycyrrhizin), saccharin, saccharin sodium, stevia extract, and stevia powder. At least one selected from this group can be used.

前記水溶性の乳化剤としては、HLBが7~20の乳化剤であればよく、例えばポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ポリソルベート等の合成乳化剤や、大豆リゾレシチン、卵黄リゾレシチン、酵素処理卵黄、サポニン、植物ステロール類、乳脂肪球皮膜等の合成乳化剤でない乳化剤が挙げられ、これらの群より選ばれる少なくとも1種を使用できる。前記水溶性の乳化剤の含有量は、風味の観点から少ないほど好ましく、ロールインマーガリン全体中5重量%以下であることが好ましく、2重量以下%がより好ましく、1重量以下%が更に好ましい。前記乳化剤の含有量が5重量%を超えると乳化剤の苦味が感じられる場合がある。 The water-soluble emulsifier may be any emulsifier with an HLB of 7 to 20, and examples include synthetic emulsifiers such as polyglycerol fatty acid esters, sucrose fatty acid esters, and polysorbates, as well as non-synthetic emulsifiers such as soybean lysolecithin, egg yolk lysolecithin, enzyme-treated egg yolk, saponin, plant sterols, and milk fat globule membranes. At least one emulsifier selected from this group can be used. From the perspective of flavor, the lower the content of the water-soluble emulsifier, the better, and it is preferably 5% by weight or less of the total roll-in margarine, more preferably 2% by weight or less, and even more preferably 1% by weight or less. If the content of the emulsifier exceeds 5% by weight, the bitter taste of the emulsifier may be perceived.

前記増粘安定剤としては、グアーガム、ローカストビーンガム、カラギーナン、アラビアガム、アルギン酸類、ペクチン、キサンタンガム、プルラン、タマリンドシードガム、サイリウムシードガム、結晶セルロース、カルボキシメチルセルロース、メチルセルロース、寒天、グルコマンナン、ゼラチン、澱粉、化工澱粉等が挙げられ、これらの群より選ばれる少なくとも1種を使用できる。 Examples of the thickening stabilizer include guar gum, locust bean gum, carrageenan, gum arabic, alginic acids, pectin, xanthan gum, pullulan, tamarind seed gum, psyllium seed gum, crystalline cellulose, carboxymethyl cellulose, methyl cellulose, agar, glucomannan, gelatin, starch, and modified starch, and at least one selected from this group can be used.

本発明の層状膨化食品用生地は、穀粉からなる捏ね粉生地(デトランプ)と、前記ロールインマーガリンとを交互に積層した生地を言う。 The layered puffed food dough of the present invention refers to a dough in which a kneaded dough (detramp) made from cereal flour and the roll-in margarine are layered alternately.

前記穀粉は、食用であれば特に限定はないが、例えば、小麦、米、とうもろこし、馬鈴薯、タピオカ、甘藷などの穀物を挽いたり粉砕したりして作った粉で、それらの群より選ばれる少なくとも1種を使用することができる。そして、該穀粉中には、小麦粉を80重量%以上含有することが好ましい。前記小麦粉は、例えば、強力粉、中力粉、薄力粉等が挙げられ、それらの群より選ばれる少なくとも1種を使用することができるが、蛋白質含量の多い強力粉が望ましい。また、前記穀粉中には、80重量%以下であれば、前記穀物由来の澱粉及びその加工澱粉を含んでいても良い。 The cereal flour is not particularly limited as long as it is edible, but it can be, for example, flour made by grinding or pulverizing cereals such as wheat, rice, corn, potato, tapioca, and sweet potato, and at least one type selected from this group can be used. It is preferable that the cereal flour contains 80% or more by weight of wheat flour. Examples of the wheat flour include strong flour, medium-strength flour, and weak flour, and at least one type selected from these groups can be used, with strong flour having a high protein content being preferable. The cereal flour may also contain starch derived from the cereals and modified starches thereof, as long as it is 80% or less by weight.

前記層状膨化食品用生地中における前記ロールインマーガリンの含有量は、層状膨化食品の種類により異なるが、一般的には層状膨化食品用生地中の穀粉100重量部に対して、20~180重量部が好ましく、30~150重量部がより好ましく、40~130重量部が更に好ましく、50~100重量部が特に好ましい。前記ロールインマーガリンの含有量が20重量部より少ないと生地の伸展性が低下する場合があり、180重量部より多いと、生地作製時にダレが生じたり、焼成後の層状膨化食品から油のしみ出しが見られたり、食感が劣る場合がある。 The content of the roll-in margarine in the dough for layered puffed food varies depending on the type of layered puffed food, but is generally preferably 20 to 180 parts by weight, more preferably 30 to 150 parts by weight, even more preferably 40 to 130 parts by weight, and particularly preferably 50 to 100 parts by weight, per 100 parts by weight of the grain flour in the dough for layered puffed food. If the content of the roll-in margarine is less than 20 parts by weight, the extensibility of the dough may decrease, while if it is more than 180 parts by weight, sagging may occur during dough preparation, oil may ooze from the layered puffed food after baking, and the texture may be inferior.

前記層状膨化食品用生地は、常法に従って焼成されることで、層状膨化食品が得られる。 The layered puffed food dough is baked in a conventional manner to produce a layered puffed food.

本発明のロールインマーガリンの製造方法は、常法に従えばよいが、以下に例示する。まず、油脂混合物全体中、原材料の含有量がそれぞれ前記パーム油のエステル交換油35~70重量%、前記液状油12~35重量%、及び前記ラウリン系油脂以外の極度硬化油1~5重量%になるように調製した油脂混合物を65~80℃に加温融解したところに、必要に応じて油溶性原料を混合し、65~70℃に保持することで油相を得る。一方、50~70℃の温水に、必要に応じて水溶性原料を撹拌溶解し、65~70℃で保持することで水相を得る。前記油相を撹拌しているところに前記水相を添加し、乳化した乳化液を急冷捏和して製造することができる。 The roll-in margarine of the present invention may be produced according to conventional methods, but is exemplified below. First, an oil and fat mixture is prepared so that the total oil and fat mixture contains 35 to 70% by weight of the interesterified palm oil, 12 to 35% by weight of the liquid oil, and 1 to 5% by weight of the extremely hardened oil other than lauric fats and oils. The mixture is then heated and melted to 65 to 80°C, and oil-soluble ingredients are added as needed. The mixture is then maintained at 65 to 70°C to obtain an oil phase. Meanwhile, water-soluble ingredients are dissolved in warm water at 50 to 70°C with stirring as needed, and the mixture is maintained at 65 to 70°C to obtain an aqueous phase. The aqueous phase is added while the oil phase is being stirred, and the resulting emulsion is then rapidly cooled and kneaded to produce the margarine.

前記急冷捏和における冷却速度条件は、好ましくは-0.5℃/分以上、より好ましくは-5℃/分以上である。この際、徐冷却より急冷却の方が好ましい。冷却する機器としては、密閉型連続式チューブ冷却機、例えば、ボテーター、コンビネーター、パーフェクター等のマーガリン製造機やプレート型熱交換機等が挙げられる。また、冷却する機器としては、開放型のダイアクーラーとコンプレクターとの組合せも挙げられる。また、油相の溶解後又は混合乳化後は、殺菌処理することが望ましい。殺菌方法は、タンクでのバッチ式でも、プレート型熱交換機や掻き取り式熱交換機を用いた連続式でも構わない。 The cooling rate during the rapid cooling and kneading is preferably -0.5°C/min or higher, more preferably -5°C/min or higher. Rapid cooling is preferable to gradual cooling. Examples of cooling equipment include closed-type continuous tube coolers, such as margarine manufacturing machines such as Votator, Combinator, and Perfector, and plate-type heat exchangers. Examples of cooling equipment include a combination of an open-type diacooler and a complexor. It is also desirable to sterilize the oil phase after dissolution or mixing and emulsification. Sterilization may be performed batchwise in a tank, or continuously using a plate-type heat exchanger or scraped-surface heat exchanger.

本発明のロールインマーガリンは、その形状として、シート状、スティック状、サイコロ状、短冊状等様々な形状とすることができる。その中でも、加工の容易性の観点から、シート状とすることが好ましい。シート状とした場合は、その幅は50~1000mm、その長さは50~1000mm、その厚さは1~50mmが好ましい。 The roll-in margarine of the present invention can be formed into various shapes, such as sheets, sticks, cubes, and strips. Among these, a sheet shape is preferred from the viewpoint of ease of processing. When formed into a sheet, the width is preferably 50 to 1000 mm, the length is preferably 50 to 1000 mm, and the thickness is preferably 1 to 50 mm.

前記ロールインマーガリンを用いた層状膨化食品用生地の製造方法を以下に例示する。まず、前記穀粉と水、及び必要に応じて練り込み用油脂、卵、糖類、イーストなどの原料を混捏した後、得られる生地を薄く延ばし、そこに前記ロールインマーガリンを載せて折りたたむことで前記層状膨化食品用生地が得られる。原料の投入順序は何れでもよく、また各原料投入タイミングやハンドリング温度などについては、公知の方法に準ずれば良い。 An example of a method for producing dough for layered puffed food using the roll-in margarine is given below. First, the grain flour and water, and optionally other ingredients such as oils and fats for kneading, eggs, sugars, and yeast, are mixed and kneaded together. The resulting dough is then thinly rolled out, and the roll-in margarine is placed on top and folded to obtain the dough for layered puffed food. The order in which the ingredients are added is not critical, and the timing of adding each ingredient and the handling temperature may follow known methods.

なお、前記練り込み用油脂は、ロールインマーガリンとは異なり層状膨化食品の層の形成に直接寄与せず、容積の拡大やすだちの改良、クラムやクラストのソフト化、機械耐性の向上や老化の遅延などを目的として、穀粉と一緒にミキシングして使用する油脂を言う。該練り込み用油脂の含有量は、前記層状膨化食品用生地中の穀粉100重量部に対して、5~50重量部が好ましく、5~20重量部がより好ましい。 Unlike roll-in margarine, the oil for kneading does not directly contribute to the formation of layers in the layered puffed food, but is instead mixed with the grain flour for purposes such as increasing volume, improving the texture, softening the crumb and crust, improving mechanical resistance, and delaying aging. The content of the oil for kneading is preferably 5 to 50 parts by weight, more preferably 5 to 20 parts by weight, per 100 parts by weight of grain flour in the dough for the layered puffed food.

前記層状膨化食品用生地を、通常の方法に従って焼成することで、口当たりがソフトな層状膨化食品が得られる。本発明の層状膨化食品用生地を焼成した層状膨化食品としては、例えば、デニッシュ、クロワッサン、パイ等が挙げられる。 By baking the layered puffed food dough according to a conventional method, a layered puffed food with a soft texture can be obtained. Examples of layered puffed foods baked using the layered puffed food dough of the present invention include Danish pastries, croissants, pies, etc.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 The present invention will be explained in more detail below using examples, but the present invention is in no way limited to these examples. Note that in the examples, "parts" and "%" are by weight.

また、実施例及び比較例で使用した原料は以下の通りである。
1)(株)カネカ製「菜種油」
2)(株)カネカ製「ローエルシンン菜種極度硬化油」
3)(株)カネカ製「ハイエルシン菜種極度硬化油」
4)(株)カネカ製「パーム極度硬化油」
5)(株)カネカ製「パーム核油極度硬化油」
6)理研ビタミン(株)製「エマルジーMS」
7)J-オイルミルズ(株)製「大豆レシチン」
8)高砂香料(株)製「バターフレーバー」
9)財団法人塩事業センター製「精製塩」
10)日清製粉(株)製「ミリオン」
11)日清製粉(株)製「バイオレット」
12)(株)カネカ製「カネカイーストGK」
13)日新製糖(株)製「上白糖P」
14)(株)赤城鶏卵GPセンター製「卵」
15)(株)カネカ製「エバーライトG」
16)雪印メグミルク(株)製「脱脂粉乳」
17)(株)カネカ製「ニューフードC」
The raw materials used in the examples and comparative examples are as follows:
1) Kaneka Corporation "Rapeseed Oil"
2) Kaneka Corporation's "Lower Shinn Hardened Rapeseed Oil"
3) Kaneka Corporation "High-Elsine Rapeseed Hardened Oil"
4) Kaneka Corporation's "Extremely Hardened Palm Oil"
5) Kaneka Corporation "Extremely Hardened Palm Kernel Oil"
6) "Emulgy MS" manufactured by Riken Vitamin Co., Ltd.
7) "Soybean lecithin" manufactured by J-Oil Mills Co., Ltd.
8) "Butter Flavor" manufactured by Takasago International Corporation
9) "Refined Salt" manufactured by the Salt Industry Center Foundation
10) "Million" by Nisshin Flour Milling Co., Ltd.
11) Nisshin Flour Milling Co., Ltd. "Violet"
12) Kaneka Corporation "Kaneka East GK"
13) “Jyuhakuto P” manufactured by Nisshin Sugar Co., Ltd.
14) Eggs produced by Akagi Egg GP Center Co., Ltd.
15) Kaneka Corporation "Everlight G"
16) Megmilk Snow Brand Co., Ltd. "Skimmed Milk Powder"
17) Kaneka Corporation "New Food C"

<シート成型性の評価>
実施例及び比較例で作製したロールインマーガリンの成型装置出口における状態を、直接手で触った感触で評価した。その際の評価基準は、以下の通りであった。
5点:直接手で触った感触が実施例6よりも良く、可塑性があり且つしっかりとした感触で、シート成型性が極めて良好である
4点:直接手で触った感触が実施例6と同等で、可塑性があり且つしっかりとした感触で、シート成型性が良好である
3点:直接手で触った感触が実施例6よりも劣り、可塑性はあるもののやや軟らかい触感であるが、シート成型性は良好である
2点:直接手で触った感触が実施例6よりも悪く、可塑性が軟らかい又は硬い触感で、シート成型性が悪い
1点:直接手で触った感触が実施例6よりも非常に悪く、可塑性が非常に軟らかい又は硬い触感で、シート成型性が極めて悪い
<Evaluation of sheet formability>
The condition of the roll-in margarines produced in the Examples and Comparative Examples at the outlet of the molding device was evaluated by touching them directly with the hand. The evaluation criteria were as follows:
5 points: The feel when touched with the hand is better than that of Example 6, with a plasticity and firm feel, and excellent sheet moldability. 4 points: The feel when touched with the hand is equivalent to that of Example 6, with a plasticity and firm feel, and excellent sheet moldability. 3 points: The feel when touched with the hand is inferior to that of Example 6, with a plasticity but somewhat soft feel, but excellent sheet moldability. 2 points: The feel when touched with the hand is worse than that of Example 6, with a plasticity that is soft or hard to the touch, and poor sheet moldability. 1 point: The feel when touched with the hand is much worse than that of Example 6, with a plasticity that is very soft or hard to the touch, and extremely poor sheet moldability.

<ロールインマーガリンの10℃での伸展性の評価>
実施例及び比較例で作製したロールインマーガリンを10℃で3時間温調した後、捏ね粉生地(デトランプ)に折り込んだ際の伸展性を、以下の基準で評価した。
5点:実施例5よりも良く、生地の中でロールインマーガリンが極めて均一に伸びる
4点:実施例5と同等で、生地の中でロールインマーガリンに僅かに偏りが見られるものの均一に伸びる
3点:実施例5よりも劣り、生地の中でロールインマーガリンに偏りが見られるもののほぼ均一に伸びる
2点:実施例5よりも悪く、生地の中でロールインマーガリンが明らかに均一に伸びていない部分が見られる
1点:実施例5よりも非常に悪く、生地の中でロールインマーガリンが伸びずに塊になったり、ロールインマーガリンに割れが見られる
<Evaluation of spreadability of roll-in margarine at 10°C>
The roll-in margarines produced in the Examples and Comparative Examples were kept at 10°C for 3 hours, and then folded into a dough (detramp), and the extensibility was evaluated according to the following criteria.
5 points: Better than Example 5, roll-in margarine spreads extremely evenly in the dough. 4 points: Equivalent to Example 5, roll-in margarine spreads evenly in the dough, although there is slight unevenness. 3 points: Inferior to Example 5, roll-in margarine spreads almost evenly in the dough, although there is unevenness. 2 points: Worse than Example 5, there are clearly areas in the dough where the roll-in margarine does not spread evenly. 1 point: Much worse than Example 5, roll-in margarine does not spread in the dough, forming lumps, or cracks are observed in the roll-in margarine.

<ロールインマーガリンの20℃での伸展性の評価>
実施例及び比較例で作製したロールインマーガリンを20℃で3時間温調した後、捏ね粉生地(デトランプ)に折り込んだ際の伸展性を、以下の基準で評価した。
5点:実施例5よりも良く、生地の中でロールインマーガリンが極めて均一に伸び、生地にコシが非常に感じられる
4点:実施例5と同等で、生地の中でロールインマーガリンがほぼ均一に伸び、生地にコシが感じられる
3点:実施例5よりもやや悪く、生地の中でロールインマーガリンがほぼ均一に伸びるものの、僅かに練り込まれ、生地のコシがやや劣る
2点:実施例5よりも悪く、生地の中でロールインマーガリンが練り込まれ、生地のコシが弱い
1点:実施例5よりも非常に悪く、生地の中でロールインマーガリンが完全に練り込まれ、生地のコシが感じられない
<Evaluation of spreadability of roll-in margarine at 20°C>
The roll-in margarines produced in the Examples and Comparative Examples were kept at 20°C for 3 hours, and then folded into a dough (detramp), and the extensibility was evaluated according to the following criteria.
5 points: Better than Example 5, the roll-in margarine spreads extremely evenly in the dough, and the dough feels very firm. 4 points: Equivalent to Example 5, the roll-in margarine spreads almost evenly in the dough, and the dough feels firm. 3 points: Slightly worse than Example 5, the roll-in margarine spreads almost evenly in the dough, but is only slightly kneaded into the dough, and the dough feels slightly less firm. 2 points: Worse than Example 5, the roll-in margarine is kneaded into the dough, and the dough feels weak. 1 point: Much worse than Example 5, the roll-in margarine is kneaded completely into the dough, and the dough does not feel firm.

<デニッシュの食感の評価>
実施例及び比較例で得られた層状膨化食品(デニッシュ)を熟練したパネラー10人に食してもらい、以下の基準で評価を行い、その平均を評価値とした。
5点:実施例6よりも良好であり、ソフトさを非常に強く感じ、口どけも非常に良好である
4点:実施例6と同等であり、ソフトさを強く感じ、口どけも良好である
3点:実施例6よりも若干劣るが、ソフトさを感じ、口どけも良好である
2点:実施例6よりも悪く、ソフトさをあまり感じない、又は口どけが劣る
1点:実施例6よりも極めて悪く、ソフトさを感じず、且つ口どけも非常に劣る
<Evaluation of Danish texture>
The layered puffed foods (Danish pastries) obtained in the Examples and Comparative Examples were tasted by 10 experienced panelists, who evaluated them according to the following criteria, and the average was used as the evaluation value.
5 points: Better than Example 6, very strong softness, and very good melt-in-the-mouth feel. 4 points: Equivalent to Example 6, very strong softness, and good melt-in-the-mouth feel. 3 points: Slightly inferior to Example 6, but softness and good melt-in-the-mouth feel. 2 points: Worse than Example 6, not very soft or poor melt-in-the-mouth feel. 1 point: Extremely worse than Example 6, not softness, and very poor melt-in-the-mouth feel.

<総合評価>
シート成型性、10℃での伸展性、20℃での伸展性、及びデニッシュの食感の各評価結果を基に、ロールインマーガリンの総合評価を行った。その際の評価基準は以下の通りである。
A:シート成型性、10℃での伸展性、20℃での伸展性、及び、デニッシュの食感の評価が全て4.0点以上5.0点以下を満たすもの
B:シート成型性、10℃での伸展性、20℃での伸展性、及び、デニッシュの食感の評価が全て3.5点以上5.0点未満であって、且つ3.5以上4.0未満が少なくとも一つあるもの
C:シート成型性、10℃での伸展性、20℃での伸展性、及び、デニッシュの食感の評価が全て3.0点以上5.0点未満であって、且つ3.0以上3.5未満が少なくとも一つあるもの
D:シート成型性、10℃での伸展性、20℃での伸展性、及び、デニッシュの食感の評価が全て2.0点以上5.0点未満であって、且つ2.0以上3.0未満が少なくとも一つあるもの
E:シート成型性、10℃での伸展性、20℃での伸展性、及び、デニッシュの食感の評価において、2.0未満が少なくとも一つあるもの
<Overall rating>
Based on the evaluation results of sheet moldability, spreadability at 10°C, spreadability at 20°C, and Danish texture, the roll-in margarines were comprehensively evaluated. The evaluation criteria were as follows:
A: The evaluations of sheet moldability, extensibility at 10°C, extensibility at 20°C, and Danish texture all satisfy 4.0 points or more and 5.0 points or less. B: The evaluations of sheet moldability, extensibility at 10°C, extensibility at 20°C, and Danish texture all satisfy 3.5 points or more and less than 5.0 points, with at least one being 3.5 points or more and less than 4.0 points. C: The evaluations of sheet moldability, extensibility at 10°C, extensibility at 20°C, and Danish texture all satisfy 4.0 points or more and 5.0 points or less. D: The evaluations of sheet moldability, extensibility at 10°C, extensibility at 20°C, and Danish texture are all 2.0 or more and less than 5.0 points, and at least one is 2.0 or more and less than 3.0. E: The evaluations of sheet moldability, extensibility at 10°C, extensibility at 20°C, and Danish texture are all 2.0 or more and less than 5.0 points, and at least one is 2.0 or more and less than 3.0.

(製造例1) エステル交換油1の作製
分別していないパーム油((株)カネカ製):100重量部を500Paの減圧下90℃に加熱し、それに対してナトリウムメチラート(日本曹達(株)製):0.2重量部を加えて30分間攪拌してランダムエステル交換を行った。水洗した後、500Paの減圧下、90℃で白土(水澤化学工業(株)製):2重量部を加えて脱色し、250℃、200Paの条件で1時間脱臭してエステル交換油1を得た。
(Production Example 1) Preparation of Interesterified Oil 1 100 parts by weight of unfractionated palm oil (manufactured by Kaneka Corporation) was heated to 90°C under a reduced pressure of 500 Pa, and 0.2 parts by weight of sodium methylate (manufactured by Nippon Soda Co., Ltd.) was added thereto and stirred for 30 minutes to carry out random interesterification. After washing with water, 2 parts by weight of white clay (manufactured by Mizusawa Industrial Chemicals) was added at 90°C under a reduced pressure of 500 Pa to decolorize the oil, and deodorized at 250°C and 200 Pa for 1 hour to obtain interesterified oil 1.

(製造例2) エステル交換油2の作製
製造例1において、分別していないパーム油:100重量部を、パーム核油分別軟質部((株)カネカ製):30重量部、パームステアリン((株)カネカ製):54重量部、パーム極度硬化油(太陽油脂(株)製):16重量部の油脂混合物に変更した以外は、製造例1と同様にしてエステル交換油2を得た。
(Production Example 2) Preparation of Interesterified Oil 2 [0123] Interesterified oil 2 was obtained in the same manner as in Production Example 1, except that 100 parts by weight of unfractionated palm oil in Production Example 1 was changed to an oil and fat mixture of 30 parts by weight of palm kernel oil fractionated soft part (manufactured by Kaneka Corporation), 54 parts by weight of palm stearin (manufactured by Kaneka Corporation), and 16 parts by weight of extremely hardened palm oil (manufactured by Taiyo Yushi Co., Ltd.).

(製造例3) エステル交換油3の作製
製造例1において、分別していないパーム油:100重量部を、分別していないパーム油((株)カネカ製):57重量部、パームステアリン((株)カネカ製):2重量部、パーム油分別軟質部(パームオレイン、(株)カネカ製):18重量部、パーム核油分別軟質部((株)カネカ製):23重量部の油脂混合物に変更した以外は、製造例1と同様にしてエステル交換油3を得た。
(Production Example 3) Preparation of Interesterified Oil 3 [0113] Interesterified oil 3 was obtained in the same manner as in Production Example 1, except that 100 parts by weight of unfractionated palm oil in Production Example 1 was changed to an oil and fat mixture of 57 parts by weight of unfractionated palm oil (manufactured by Kaneka Corporation), 2 parts by weight of palm stearin (manufactured by Kaneka Corporation), 18 parts by weight of soft fractionated palm oil (palm olein, manufactured by Kaneka Corporation), and 23 parts by weight of soft fractionated palm kernel oil (manufactured by Kaneka Corporation).

(製造例4) エステル交換油4の作製
製造例1において、分別していないパーム油をパームステアリン((株)カネカ製)に変更した以外は製造例1と同様にしてエステル交換油4を得た。
(Production Example 4) Preparation of Interesterified Oil 4 Interesterified oil 4 was obtained in the same manner as in Production Example 1, except that the unfractionated palm oil in Production Example 1 was changed to palm stearin (manufactured by Kaneka Corporation).

(実施例1) ロールインマーガリン及びデニッシュの作製
表1に示す配合に従って、エステル交換油1(製造例1):45.9重量部、菜種油:20.1重量部、ローエルシン菜種極度硬化油:2.4重量部及び、エステル交換油2(製造例2):12.1重量部を混ぜ合わせて、油脂混合物(パルミチン酸/ラウリン酸(質量比)=16.1):80.5重量部を得た。この油脂混合物を75℃に融解したところに、モノグリセライド0.2重量部、大豆レシチン0.2重量部、バターフレーバー0.1重量部を加え、65~70℃に保持して油相とした。一方、水:18.5重量部に食塩:0.5重量部を加えて攪拌し、80~85℃で20分間殺菌後、65~70℃に保持して水相とした。水相を油相に加えて20分間乳化させた後、急冷捏和機を用いて急冷練り合わせを行い成型装置に導入しロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表1に示した。
Example 1 Preparation of Roll-in Margarine and Danish Pastry According to the formulation shown in Table 1, 45.9 parts by weight of interesterified oil 1 (Production Example 1), 20.1 parts by weight of rapeseed oil, 2.4 parts by weight of Roelcin rapeseed hardened oil, and 12.1 parts by weight of interesterified oil 2 (Production Example 2) were mixed to obtain 80.5 parts by weight of an oil and fat mixture (palmitic acid/lauric acid (mass ratio) = 16.1). This oil and fat mixture was melted at 75°C, to which 0.2 parts by weight of monoglyceride, 0.2 parts by weight of soybean lecithin, and 0.1 parts by weight of butter flavor were added, and the mixture was maintained at 65 to 70°C to obtain an oil phase. Meanwhile, 0.5 parts by weight of salt was added to 18.5 parts by weight of water, and the mixture was stirred. The mixture was sterilized at 80 to 85°C for 20 minutes, and then maintained at 65 to 70°C to obtain an aqueous phase. The aqueous phase was added to the oil phase and emulsified for 20 minutes, after which the mixture was rapidly cooled and kneaded using a rapid-cooling kneader and introduced into a molding machine to obtain roll-in margarine. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 1.

次に、得られたロールインマーガリンを用いてデニッシュを作製した。即ち、表2に示す配合に従って、ロールインマーガリンとショートニングを除いた原料をミキサーで低速3分間、中高速3分間ミキシングした後、ショートニングを混合し、更に低速3分間、中高速3分間ミキシングし、捏ね上げ温度が25℃の生地を得た。得られた生地を室温で30分間発酵させた後、1℃で5時間冷却し、1916gに分割・成形してから、15℃に温調したロールインマーガリン500gを載置し、包み込んだ。それから包み込んだ生地を、リバースシーターを用いて10mm厚になるまでは5mmごとに段階的に伸展し、その後は2mmごとに段階的に伸展し、最後は4mm厚に調整したリバースシーターを用いて、4mm厚に伸展した。続けて4mm厚の生地を3つ折りした後、3mm厚に調整したリバースシーターを用い、3mm厚に伸展した。得られた生地を1℃で10時間冷却後、更に3つ折りした後、2.5mm厚に調整したリバースシーターを用いて2.5mm厚に伸展した。2.5mm厚の生地をデニッシュの形に成形後、35℃、湿度70%のホイロで1時間最終発酵した後、200℃のオーブンで15分間焼成し、デニッシュを得た。得られたデニッシュの食感の評価結果を表1に示した。 Next, Danish pastries were made using the resulting roll-in margarine. Specifically, according to the formulation shown in Table 2, the ingredients, excluding the roll-in margarine and shortening, were mixed in a mixer at low speed for 3 minutes and medium-high speed for 3 minutes, after which the shortening was added and mixed at low speed for another 3 minutes and medium-high speed for 3 minutes, yielding a dough kneaded at 25°C. The resulting dough was fermented at room temperature for 30 minutes, cooled at 1°C for 5 hours, divided and shaped into 1916 g portions, and then wrapped around 500 g of roll-in margarine preheated to 15°C. The wrapped dough was then rolled in 5 mm increments using a reverse sheeter until it reached a thickness of 10 mm, then rolled in 2 mm increments, and finally rolled to a thickness of 4 mm using a reverse sheeter adjusted to a thickness of 4 mm. The 4 mm thick dough was then folded in thirds and rolled to a thickness of 3 mm using a reverse sheeter adjusted to a thickness of 3 mm. The resulting dough was cooled at 1°C for 10 hours, then folded in thirds and rolled out to a thickness of 2.5 mm using a reverse sheeter adjusted to a thickness of 2.5 mm. The 2.5 mm thick dough was shaped into a Danish pastry, and after a final fermentation in a proofer at 35°C and 70% humidity for 1 hour, it was baked in an oven at 200°C for 15 minutes to obtain a Danish pastry. The evaluation results for the texture of the resulting Danish pastry are shown in Table 1.

(実施例2) ロールインマーガリン及びデニッシュの作製
表1の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を32.2重量部に、配合量は同じでラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油をハイエルシン菜種極度硬化油に、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部を16.1重量部に変更し、更にラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):9.7重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表1に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表1に示した。
Example 2 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that an oil and fat mixture was prepared according to the formulation in Table 1 by changing interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 32.2 parts by weight, changing low-elucine rapeseed extremely hydrogenated oil, which is an extremely hydrogenated oil other than lauric fats and oils, to high-elucine rapeseed extremely hydrogenated oil, and interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fats and palm-based fats, from 12.1 parts by weight to 16.1 parts by weight, and further mixing with interesterified oil 4 (Production Example 4), which is an interesterified oil other than an interesterified oil of lauric fats and palm-based fats and palm oil, according to the formulation in Table 1. The sheet moldability and spreadability at 10°C and 20°C of the resulting roll-in margarine were evaluated. Table 1 shows the results.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 1.

(実施例3) ロールインマーガリン及びデニッシュの作製
表1の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を54.0重量部に、菜種油:20.1重量部を18.5重量部に、ローエルシン菜種極度硬化油:2.4重量部を1.6重量部に、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部をラウリン系油脂の極度硬化油であるパーム核油極度硬化油:6.4重量部に変更して油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表1に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表1に示した。
Example 3 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that an oil and fat mixture was prepared according to the formulations in Table 1, changing interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 54.0 parts by weight, rapeseed oil, from 20.1 parts by weight to 18.5 parts by weight, laurelcin rapeseed extremely hardened oil, from 2.4 parts by weight to 1.6 parts by weight, and interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fat and palm fat, from 12.1 parts by weight to 6.4 parts by weight of palm kernel oil, which is an extremely hardened oil of lauric fat. The sheet moldability and spreadability at 10°C and 20°C during the production of the resulting roll-in margarine were evaluated. Table 1 shows the results.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 1.

(実施例4) ロールインマーガリン及びデニッシュの作製
表1の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を50.7重量部に、菜種油:20.1重量部を19.3重量部に変更し、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部に代えて、ラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):8.1重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表1に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表1に示した。
Example 4 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that, according to the formulations in Table 1, interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, was changed from 45.9 parts by weight to 50.7 parts by weight, rapeseed oil was changed from 20.1 parts by weight to 19.3 parts by weight, and interesterified oil 4 (Production Example 4), which is an interesterified oil other than an interesterified oil of lauric fat and palm fat, was mixed in place of 12.1 parts by weight of interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fat and palm fat, to prepare an oil and fat mixture. The sheet moldability and spreadability at 10°C and 20°C during the preparation of the resulting roll-in margarine were evaluated. Table 1 shows the results.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 1.

(比較例1) ロールインマーガリン及びデニッシュの作製
表1の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を24.1重量部に、菜種油:20.1重量部を26.6重量部に変更し、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部の代わりにパーム極度硬化油:1.6重量部、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部の代わりにエステル交換油3(製造例3):20.1重量部、さらにはラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):8.1重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表1に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表1に示した。
Comparative Example 1 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that an oil and fat mixture was prepared according to the formulation in Table 1 by changing interesterified oil 1 (Production Example 1), which was an interesterified oil of palm oil, from 45.9 parts by weight to 24.1 parts by weight, changing rapeseed oil from 20.1 parts by weight to 26.6 parts by weight, using 1.6 parts by weight of extremely hydrogenated palm oil in place of 2.4 parts by weight of extremely hydrogenated laurel rapeseed oil, which is an extremely hydrogenated oil other than lauric fats and oils, using 20.1 parts by weight of interesterified oil 3 (Production Example 3), in place of 12.1 parts by weight of interesterified oil 2 (Production Example 2), which was an interesterified oil of lauric fats and palm-based fats, and further using 8.1 parts by weight of interesterified oil 4 (Production Example 4), which was an interesterified oil other than an interesterified oil of lauric fats and palm-based fats and palm oil. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 1.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 1.

(比較例2) ロールインマーガリン及びデニッシュの作製
表1の配合に従って、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2)を入れずに、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を60.4重量部に、菜種油:20.1重量部を16.1重量部に変更し、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部の代わりにパーム極度硬化油:1.6重量部、パーム核油極度硬化油:2.4重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表1に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表1に示した。
Comparative Example 2 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that, according to the formulation in Table 1, interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fat and palm-based fat, was not added, but interesterified oil 1 (Production Example 1), an interesterified oil of palm oil, was changed from 45.9 parts by weight to 60.4 parts by weight, rapeseed oil was changed from 20.1 parts by weight to 16.1 parts by weight, and an oil and fat mixture was prepared by mixing 1.6 parts by weight of palm extremely hydrogenated oil and 2.4 parts by weight of palm kernel extremely hydrogenated oil instead of 2.4 parts by weight of lauricin extremely hydrogenated rapeseed oil, which is an extremely hydrogenated oil other than lauric fat. The sheet moldability and spreadability at 10°C and 20°C during the preparation of the resulting roll-in margarine are evaluated in Table 1.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 1.

表1から明らかなように、ロールインマーガリンの油相中の油脂全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有する実施例1~4のロールインマーガリンは何れも、シート成型性、10℃及び20℃での伸展性が良好で、得られたデニッシュの食感も良好であり、総合評価も良好であった。特に、ラウリン系油脂とパーム系油脂とのエステル交換油及び/又はラウリン系油脂の極度硬化油を含有する実施例1~3のロールインマーガリンは、総合評価がAと極めて良好であった。 As is clear from Table 1, the roll-in margarines of Examples 1 to 4, which contained 35 to 70% by weight of interesterified palm oil, 12 to 35% by weight of liquid oil, and 1 to 5% by weight of extremely hardened oil other than lauric fats and oils, all exhibited good sheet moldability and spreadability at 10°C and 20°C. The resulting Danish pastries also had a good texture and were given a good overall rating. In particular, the roll-in margarines of Examples 1 to 3, which contained interesterified palm oil and/or extremely hardened lauric fats and oils, received an overall rating of A, which was extremely good.

一方、油相中の油脂全体中、パーム油のエステル交換油が30重量%と少ない比較例1のロールインマーガリンは、シート成型性と10℃での伸展性の評価が悪く、20℃での伸展性の評価が極めて悪く、又得られたデニッシュの食感もソフトさが不十分なものであった。また、油相中の油脂全体中、パーム油のエステル交換油が75重量%と多い比較例2のロールインマーガリンは、10℃及び20℃での伸展性の評価が悪く、又得られたデニッシュの食感もソフトさが劣るものであった。 On the other hand, the roll-in margarine of Comparative Example 1, in which the interesterified palm oil accounted for only 30% by weight of the total fats and oils in the oil phase, received poor evaluations of sheet moldability and spreadability at 10°C and extremely poor evaluations of spreadability at 20°C, and the resulting Danish pastries had an insufficiently soft texture. Furthermore, the roll-in margarine of Comparative Example 2, in which the interesterified palm oil accounted for 75% by weight of the total fats and oils in the oil phase, received poor evaluations of spreadability at 10°C and 20°C, and the resulting Danish pastries also had an inferior soft texture.

(実施例5) ロールインマーガリン及びデニッシュの作製
表3の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を48.3重量部に、菜種油:20.1重量部を12.1重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を1.6重量部に、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部を14.5重量部に変更し、更にラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):4.0重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表3に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表3に示した。
Example 5 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that an oil and fat mixture was prepared by changing the amounts of interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 48.3 parts by weight, rapeseed oil from 20.1 parts by weight to 12.1 parts by weight, laurelsine rapeseed extremely hardened oil, which is an extremely hardened oil other than lauric fats and oils, from 2.4 parts by weight to 1.6 parts by weight, and interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fats and palm-based fats and oils, from 12.1 parts by weight to 14.5 parts by weight, and further mixing with 4.0 parts by weight of interesterified oil 4 (Production Example 4), which is an interesterified oil of lauric fats and palm-based fats and an interesterified oil other than palm oil and oil, according to the formulations in Table 3. The sheet moldability and spreadability at 10°C and 20°C during the preparation of the resulting roll-in margarine were evaluated. Table 3 shows the results.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 3.

(実施例6) ロールインマーガリン及びデニッシュの作製
表3の配合に従って、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2)を入れずに、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を34.6重量部に、菜種油:20.1重量部を26.6重量部に変更し、ラウリン系油脂の極度硬化油であるパーム核油極度硬化油:4.8重量部と、ラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):12.1重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表3に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表3に示した。
Example 6 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fat and palm-based fat, was not added, and interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, was changed from 45.9 parts by weight to 34.6 parts by weight, rapeseed oil was changed from 20.1 parts by weight to 26.6 parts by weight, and an oil and fat mixture was prepared by mixing 4.8 parts by weight of extremely hydrogenated palm kernel oil, which is an extremely hydrogenated oil of lauric fat, with 12.1 parts by weight of interesterified oil 4 (Production Example 4), which is an interesterified oil other than the interesterified oil of lauric fat and palm-based fat and the interesterified oil of palm oil, according to the formulation in Table 3. The sheet moldability and spreadability at 10°C and 20°C during the preparation of the resulting roll-in margarine were evaluated. Table 3 shows the results.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 3.

(比較例3) ロールインマーガリン及びデニッシュの作製
表3の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を52.3重量部に、菜種油:20.1重量部を6.4重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を1.6重量部に、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部を8.1重量部に変更し、更にラウリン系油脂の極度硬化油であるパーム核油極度硬化油:4.0重量部と、ラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):8.1重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表3に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表3に示した。
Comparative Example 3 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that an oil and fat mixture was prepared in accordance with the formulation in Table 3 by changing interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 52.3 parts by weight, rapeseed oil, from 20.1 parts by weight to 6.4 parts by weight, laurelcin rapeseed extremely hardened oil, which is an extremely hardened oil other than lauric fats and oils, from 2.4 parts by weight to 1.6 parts by weight, and interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fats and palm-based fats, from 12.1 parts by weight to 8.1 parts by weight, and further mixing 4.0 parts by weight of palm kernel oil extremely hardened oil, which is an extremely hardened oil of lauric fats and oils, and 8.1 parts by weight of interesterified oil 4 (Production Example 4), which is an interesterified oil other than an interesterified oil of lauric fats and palm-based fats and palm oil. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 3.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 3.

(比較例4) ロールインマーガリン及びデニッシュの作製
表3の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を40.3重量部に、菜種油:20.1重量部を32.2重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を1.6重量部に変更し、ラウリン系油脂とパーム系油脂とのエステル交換油としてはエステル交換油2(製造例2):12.1重量部に代えて、エステル交換油3(製造例3):6.4重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表3に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表3に示した。
Comparative Example 4 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that, according to the formulations in Table 3, the amount of interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, was changed from 45.9 parts by weight to 40.3 parts by weight, the amount of rapeseed oil was changed from 20.1 parts by weight to 32.2 parts by weight, and the amount of extremely hydrogenated lauricine rapeseed oil, which is an extremely hydrogenated oil other than lauric fats and oils, was changed from 2.4 parts by weight to 1.6 parts by weight, and the interesterified oil of lauric fats and palm fats was changed from 12.1 parts by weight to 6.4 parts by weight of interesterified oil 3 (Production Example 3). The sheet moldability and spreadability at 10°C and 20°C during the preparation of the resulting roll-in margarine were evaluated. Table 3 shows the results.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 3.

表3から明らかなように、ロールインマーガリンの油相中の油脂全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有する実施例1,5及び6のロールインマーガリンは何れも、シート成型性、10℃及び20℃での伸展性が良好で、得られたデニッシュの食感も良好であり、総合評価も良好であった。
一方、油相中の油脂全体中、液状油が8重量%と少ない比較例3のロールインマーガリンは、10℃での伸展性の評価が悪く、20℃での伸展性の評価が極めて悪く、又得られたデニッシュの食感もソフトさが不十分なものであった。また、油相中の油脂全体中、液状油が40重量%と多い比較例4のロールインマーガリンは、シート成型性の評価が悪く、20℃での伸展性の評価が極めて悪く、又得られたデニッシュの食感もソフトさが不十分なものであった。
As is clear from Table 3, the roll-in margarines of Examples 1, 5 and 6, which contained 35 to 70% by weight of transesterified palm oil, 12 to 35% by weight of liquid oil, and 1 to 5% by weight of extremely hardened oil other than lauric fats and oils, based on the total fats and oils in the oil phase of the roll-in margarine, all had good sheet moldability and spreadability at 10°C and 20°C, and the texture of the resulting Danish pastries was also good, and the overall evaluation was also good.
On the other hand, the roll-in margarine of Comparative Example 3, in which the liquid oil content was as low as 8% by weight based on the total fats and oils in the oil phase, was evaluated as poor in spreadability at 10° C. and extremely poor in spreadability at 20° C., and the resulting Danish pastries had an insufficiently soft texture. The roll-in margarine of Comparative Example 4, in which the liquid oil content was as high as 40% by weight based on the total fats and oils in the oil phase, was evaluated as poor in sheet moldability and extremely poor in spreadability at 20° C., and the resulting Danish pastries had an insufficiently soft texture.

(比較例5) ロールインマーガリン及びデニッシュの作製
表4の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を44.3重量部に、菜種油:20.1重量部を24.2重量部に変更し、ラウリン系油脂以外の極度硬化油としてはローエルシン菜種極度硬化油2.4重量部をパーム極度硬化油:0.4重量部に変え、ラウリン系油脂とパーム系油脂とのエステル交換油としてはエステル交換油2(製造例2):12.1重量部をエステル交換油3(製造例3):8.0重量部に変え、さらにラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):3.6重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表4に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表4に示した。
Comparative Example 5 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that an oil and fat mixture was prepared in accordance with the formulations in Table 4, by changing interesterified oil 1 (Production Example 1), which was an interesterified oil of palm oil, from 45.9 parts by weight to 44.3 parts by weight, and rapeseed oil from 20.1 parts by weight to 24.2 parts by weight, by changing 2.4 parts by weight of laurelcin rapeseed extremely hydrogenated oil as the extremely hydrogenated oil other than lauric fats and oils, to 0.4 parts by weight of extremely hydrogenated palm oil, by changing 12.1 parts by weight of interesterified oil 2 (Production Example 2), which was the interesterified oil of lauric fats and palm-based fats and oils, to 8.0 parts by weight of interesterified oil 3 (Production Example 3), and by further mixing 3.6 parts by weight of interesterified oil 4 (Production Example 4), which was an interesterified oil other than the interesterified oil of lauric fats and palm-based fats and palm oil. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 4.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 4.

(比較例6) ロールインマーガリン及びデニッシュの作製
表4の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を38.6重量部に、菜種油:20.1重量部を24.2重量部に、ラウリン系油脂以外の極度硬化油としてはローエルシン菜種極度硬化油:2.4重量部をハイエルシン菜種極度硬化油:4.8重量部に変え、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部を6.4重量部に変更し、さらにラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):6.5重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表4に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表4に示した。
Comparative Example 6 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that an oil and fat mixture was prepared in accordance with the formulation in Table 4 by changing interesterified oil 1 (Production Example 1), which was an interesterified oil of palm oil, from 45.9 parts by weight to 38.6 parts by weight, rapeseed oil from 20.1 parts by weight to 24.2 parts by weight, the extremely hardened oil other than lauric fats and oils, low-elucine extremely hardened rapeseed oil from 2.4 parts by weight to 4.8 parts by weight of high-elucine extremely hardened rapeseed oil, and interesterified oil 2 (Production Example 2), which was an interesterified oil of lauric fats and palm-based oils and oils, from 12.1 parts by weight to 6.4 parts by weight, and further mixing with interesterified oil 4 (Production Example 4), which was an interesterified oil of lauric fats and palm-based oils and oils other than palm oil-transfer oil. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 4.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 4.

表4から明らかなように、ロールインマーガリンの油相中の油脂全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有する実施例1のロールインマーガリンは、シート成型性、10℃及び20℃での伸展性が良好で、得られたデニッシュの食感も良好であり、総合評価も良好であった。
一方、油相中の油脂全体中、ラウリン系油脂以外の極度硬化油が0.5重量%と少ない比較例5のロールインマーガリンは、シート成型性の評価が悪く、又得られたデニッシュの食感もソフトさが劣るものであった。また、油相中の油脂全体中、ラウリン系油脂以外の極度硬化油が6重量%と多い比較例6のロールインマーガリンは、20℃での伸展性の評価が極めて悪く、又得られたデニッシュの食感もソフトさが不十分なものであった。
As is clear from Table 4, the roll-in margarine of Example 1, which contained 35 to 70 wt % of transesterified palm oil, 12 to 35 wt % of liquid oil, and 1 to 5 wt % of extremely hardened oil other than lauric fats and oils, based on the total oils and fats in the oil phase of the roll-in margarine, had good sheet moldability and spreadability at 10°C and 20°C, the texture of the resulting Danish pastries was also good, and the overall evaluation was also good.
On the other hand, the roll-in margarine of Comparative Example 5, in which the amount of extremely hardened oils other than lauric fats and oils in the oil phase was as low as 0.5% by weight, was evaluated as poor in sheet moldability, and the texture of the resulting Danish pastries was inferior in softness.Furthermore, the roll-in margarine of Comparative Example 6, in which the amount of extremely hardened oils other than lauric fats and oils in the oil phase was as high as 6% by weight, was evaluated as extremely poor in spreadability at 20°C, and the texture of the resulting Danish pastries was insufficiently soft.

(実施例7) ロールインマーガリン及びデニッシュの作製
表4の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を39.6重量部に、菜種油:20.1重量部を12.5重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を1.4重量部に、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部を12.5重量部に変更し、ラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):3.5重量部を混ぜ合わせて油脂混合物を調製し、更に水相の添加水18.5重量部を29.5重量部に変更した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表4に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表4に示した。
Example 7 Preparation of Roll-in Margarine and Danish Pastry [0073] According to the formulations in Table 4, an oil and fat mixture was prepared by changing interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 39.6 parts by weight, rapeseed oil, from 20.1 parts by weight to 12.5 parts by weight, laurelcin extremely hardened rapeseed oil, which is an extremely hardened oil other than lauric fats and oils, from 2.4 parts by weight to 1.4 parts by weight, interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fats and palm-based fats and oils, from 12.1 parts by weight to 12.5 parts by weight, and interesterified oil 4 (Production Example 4), which is an interesterified oil of lauric fats and palm-based fats and an interesterified oil other than palm oil and oil, from 3.5 parts by weight, and further changing the added water in the aqueous phase from 18.5 parts by weight to 29.5 parts by weight, and a roll-in margarine was obtained in the same manner as in Example 1. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 4.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 4.

(実施例8) ロールインマーガリン及びデニッシュの作製
表4の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を41.1重量部に、菜種油:20.1重量部を31.5重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を2.9重量部に、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部を14.3重量部に変更し、ラウリン系油脂の極度硬化油であるパーム核油極度硬化油:5.7重量部を混ぜ合わせて油脂混合物を調製し、更に水相の添加水18.5重量部を3.5重量部に変更した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表4に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表4に示した。
Example 8 Preparation of Roll-in Margarine and Danish Pastry According to the formulations in Table 4, an oil/fat mixture was prepared by changing the amount of interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 41.1 parts by weight, rapeseed oil from 20.1 parts by weight to 31.5 parts by weight, laurelsine rapeseed extremely hardened oil, which is an extremely hardened oil other than lauric fats and oils, from 2.4 parts by weight to 2.9 parts by weight, interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fats and palm oils, from 12.1 parts by weight to 14.3 parts by weight, and palm kernel oil extremely hardened oil, which is an extremely hardened oil of lauric fats and oils, from 5.7 parts by weight to 3.5 parts by weight, and further mixing the added water in the aqueous phase from 18.5 parts by weight to 3.5 parts by weight, and a roll-in margarine was obtained in the same manner as in Example 1. Table 4 shows the evaluation of sheet moldability and spreadability at 10 ° C. and 20 ° C. during the preparation of the resulting roll-in margarine.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 4.

(比較例7) ロールインマーガリン及びデニッシュの作製
表4の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を28.6重量部に、菜種油:20.1重量部を20.6重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を1.9重量部に変更し、またラウリン系油脂の極度硬化油であるパーム核油極度硬化油:3.8重量部を入れ、さらにエステル交換油2(製造例2):12.1重量部は入れずに、ラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):9.6重量部を混ぜ合わせて油脂混合物を調製し、更に水相の添加水18.5重量部を34.5重量部に変更した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表4に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表4に示した。
Comparative Example 7 Preparation of Roll-in Margarine and Danish Pastry According to the formulations in Table 4, interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, was changed from 45.9 parts by weight to 28.6 parts by weight, rapeseed oil from 20.1 parts by weight to 20.6 parts by weight, extremely hydrogenated lauricine rapeseed oil, which is an extremely hydrogenated oil other than lauric fats and oils, was changed from 2.4 parts by weight to 1.9 parts by weight, and 3.8 parts by weight of extremely hydrogenated palm kernel oil, which is an extremely hydrogenated oil of lauric fats and oils, was added. Furthermore, interesterified oil 2 (Production Example 2), 12.1 parts by weight, was not added, and interesterified oil 4 (Production Example 4), which is an interesterified oil of lauric fats and palm fats and an interesterified oil other than palm oil and oil, was mixed to prepare an oil and fat mixture, and roll-in margarine was obtained in the same manner as in Example 1, except that the added water in the aqueous phase was changed from 18.5 parts by weight to 34.5 parts by weight. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 4.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 4.

(比較例8) ロールインマーガリン及びデニッシュの作製
表4の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を42.8重量部に、菜種油:20.1重量部を16.9重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を2.0重量部に変更し、またラウリン系油脂の極度硬化油であるパーム核油極度硬化油:17.9重量部を入れ、さらにエステル交換油2(製造例2):12.1重量部は入れずに、ラウリン系油脂とパーム系油脂とのエステル交換油及びパーム油のエステル交換油以外のエステル交換油であるエステル交換油4(製造例4):19.9重量部を混ぜ合わせて油脂混合物を調製し、更に水相を添加しない以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表4に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表4に示した。
Comparative Example 8 Preparation of Roll-in Margarine and Danish Pastry According to the formulations in Table 4, an oil and fat mixture was prepared by changing interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 42.8 parts by weight, rapeseed oil, from 20.1 parts by weight to 16.9 parts by weight, and laurelcin rapeseed extremely hydrogenated oil, which is an extremely hydrogenated oil other than lauric fats and oils, from 2.4 parts by weight to 2.0 parts by weight, and also adding 17.9 parts by weight of extremely hydrogenated palm kernel oil, which is an extremely hydrogenated oil of lauric fats and oils, and further mixing 19.9 parts by weight of interesterified oil 4 (Production Example 4), which is an interesterified oil of lauric fats and palm-based fats and an interesterified oil other than palm oil and oil, without adding 12.1 parts by weight of interesterified oil 2 (Production Example 2). Roll-in margarine was obtained in the same manner as in Example 1, except that no aqueous phase was added. The sheet moldability and extensibility at 10°C and 20°C during the preparation of the resulting roll-in margarine are shown in Table 4.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 4.

表4から明らかなように、ロールインマーガリン全体中、水相を1~30重量%、及び油相を99~70重量%を含有する実施例1、7及び8のロールインマーガリンは、シート成型性、10℃及び20℃での伸展性が良好で、得られたデニッシュの食感も良好であり、総合評価も良好であった。
一方、油相が65重量%と少ない比較例7のロールインマーガリンは、シート成型性の評価が悪く、20℃での伸展性の評価が極めて悪く、又得られたデニッシュの食感もソフトさが劣るものであった。また、油相が100重量%と多い比較例8のロールインマーガリンは、10℃での伸展性の評価が悪く、又得られたデニッシュの食感もソフトさも不十分なものであった。
As is clear from Table 4, the roll-in margarines of Examples 1, 7 and 8, which contained 1 to 30% by weight of an aqueous phase and 99 to 70% by weight of an oil phase based on the total weight of the roll-in margarine, had good sheet moldability and spreadability at 10°C and 20°C, and the texture of the resulting Danish pastries was also good, and the overall evaluation was also good.
On the other hand, the roll-in margarine of Comparative Example 7, which contained only 65% by weight of the oil phase, was evaluated as having poor sheet moldability and extremely poor spreadability at 20°C, and the resulting Danish pastries had an inferior softness in texture. The roll-in margarine of Comparative Example 8, which contained a high oil phase of 100% by weight, was evaluated as having poor spreadability at 10°C, and the resulting Danish pastries had an insufficient texture and softness.

(実施例9) ロールインマーガリン及びデニッシュの作製
表5の配合に従って、パーム油のエステル交換油であるエステル交換油1(製造例1):45.9重量部を36.2重量部に、菜種油:20.1重量部を18.5重量部に、ラウリン系油脂以外の極度硬化油であるローエルシン菜種極度硬化油:2.4重量部を1.6重量部に、ラウリン系油脂とパーム系油脂とのエステル交換油であるエステル交換油2(製造例2):12.1重量部を16.1重量部に変更し、更にラウリン系油脂の極度硬化油であるパーム核油極度硬化油:8.1重量部を混ぜ合わせて油脂混合物を調製した以外は、実施例1と同様にしてロールインマーガリンを得た。得られたロールインマーガリン作製時のシート成型性、10℃及び20℃での伸展性の評価を表5に示した。
次に、得られたロールインマーガリンを用いて実施例1と同様にして、デニッシュを作製した。得られたデニッシュの食感の評価結果を表5に示した。
Example 9 Preparation of Roll-in Margarine and Danish Pastry Roll-in margarine was obtained in the same manner as in Example 1, except that the oil and fat mixture was prepared by changing the amount of interesterified oil 1 (Production Example 1), which is an interesterified oil of palm oil, from 45.9 parts by weight to 36.2 parts by weight, the amount of rapeseed oil from 20.1 parts by weight to 18.5 parts by weight, the amount of laurelsine rapeseed extremely hardened oil, which is an extremely hardened oil other than lauric fats and oils, from 2.4 parts by weight to 1.6 parts by weight, and the amount of interesterified oil 2 (Production Example 2), which is an interesterified oil of lauric fats and palm oils, from 12.1 parts by weight to 16.1 parts by weight, and further mixing in 8.1 parts by weight of extremely hardened palm kernel oil, which is an extremely hardened oil of lauric fats and oils, according to the formulations in Table 5. The sheet moldability and spreadability at 10°C and 20°C during the preparation of the resulting roll-in margarine were evaluated. Table 5 shows the results.
Next, Danish pastries were made using the obtained roll-in margarine in the same manner as in Example 1. The evaluation results of the texture of the obtained Danish pastries are shown in Table 5.

表5から明らかなように、ロールインマーガリンの油相中の油脂全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有する実施例1~6及び9のロールインマーガリンは何れも、シート成型性、10℃及び20℃での伸展性が良好で、得られたデニッシュの食感も良好であり、総合評価も良好であった。特に、油相中の油脂全体の構成脂肪酸におけるパルミチン酸/ラウリン酸(重量比)が4~90にある実施例1~3、5、6及び9のロールインマーガリンの評価が総じて良好であった。
As is clear from Table 5, the roll-in margarines of Examples 1 to 6 and 9, which contained 35 to 70% by weight of transesterified palm oil, 12 to 35% by weight of liquid oil, and 1 to 5% by weight of extremely hardened oil other than lauric fats and oils, based on the total fats and oils in the oil phase of the roll-in margarines, all had good sheet moldability and spreadability at 10°C and 20°C, the texture of the resulting Danish pastries was also good, and the overall evaluation was also good. In particular, the evaluation of the roll-in margarines of Examples 1 to 3, 5, 6 and 9, in which the palmitic acid/lauric acid (weight ratio) in the constituent fatty acids of the total fats and oils in the oil phase was 4 to 90, was generally good.

Claims (7)

ロールインマーガリン全体中に、水相を1~30重量%、及び油相を99~70重量%を含有するロールインマーガリンであって、
前記油相中の油脂全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有し、
前記パーム油のエステル交換油が、分別していないパーム油をエステル交換してなる油脂であり、
前記ラウリン系油脂以外の極度硬化油が、ハイエルシン菜種極度硬化油、ローエルシン菜種極度硬化油、大豆油の極度硬化油及びコーン油の極度硬化油からなる群より選ばれる少なくとも1種である、ロールインマーガリン。
A roll-in margarine containing 1 to 30% by weight of an aqueous phase and 99 to 70% by weight of an oil phase in the entire roll-in margarine,
The oil phase contains 35 to 70% by weight of transesterified palm oil, 12 to 35% by weight of liquid oil, and 1 to 5% by weight of extremely hardened oil other than lauric fats and oils, based on the total amount of oils and fats in the oil phase ;
The interesterified palm oil is an oil obtained by interesterifying unfractionated palm oil,
The roll- in margarine, wherein the extremely hardened oil other than lauric fats and oils is at least one selected from the group consisting of high erucine rapeseed extremely hardened oil, low erucine rapeseed extremely hardened oil, soybean oil extremely hardened oil, and corn oil extremely hardened oil .
前記油相中の油脂全体の構成脂肪酸におけるパルミチン酸/ラウリン酸(重量比)が4~90である、請求項1に記載のロールインマーガリン。 The roll-in margarine according to claim 1, wherein the palmitic acid/lauric acid (weight ratio) among the constituent fatty acids of all the fats and oils in the oil phase is 4 to 90. 前記構成脂肪酸であるラウリン酸の由来が、ラウリン系油脂とパーム系油脂とのエステル交換油及び/又はラウリン系油脂の極度硬化油である、請求項2に記載のロールインマーガリン。 The roll-in margarine according to claim 2, wherein the constituent fatty acid, lauric acid, is derived from interesterified oil of lauric fat and palm fat and/or highly hydrogenated oil of lauric fat. 請求項1~の何れか1項に記載のロールインマーガリンを含有する層状膨化食品用生地。 A layered puffed food dough containing the roll-in margarine according to any one of claims 1 to 3 . 請求項に記載の層状膨化食品用生地が焼成された層状膨化食品。 A layered puffed food product obtained by baking the dough for layered puffed food according to claim 4 . ロールインマーガリン全体中に、水相を1~30重量%、及び油相を99~70重量%を含有するロールインマーガリンの製造方法であって、
油脂混合物全体中、パーム油のエステル交換油35~70重量%、液状油12~35重量%、及びラウリン系油脂以外の極度硬化油1~5重量%を含有する油脂混合物を65~80℃で融解し、65~70℃に保持することで油相を得、該油相を撹拌しているところに、65~70℃で保持する水相を添加して乳化し、急冷捏和することを特徴とし、
前記パーム油のエステル交換油が、分別していないパーム油をエステル交換してなる油脂であり、
前記ラウリン系油脂以外の極度硬化油が、ハイエルシン菜種極度硬化油、ローエルシン菜種極度硬化油、大豆油の極度硬化油及びコーン油の極度硬化油からなる群より選ばれる少なくとも1種である、ロールインマーガリンの製造方法。
A method for producing roll-in margarine, the roll-in margarine containing 1 to 30% by weight of an aqueous phase and 99 to 70% by weight of an oil phase,
The method is characterized in that an oil and fat mixture containing 35 to 70% by weight of transesterified palm oil, 12 to 35% by weight of liquid oil, and 1 to 5% by weight of an extremely hardened oil other than lauric fats and oils is melted at 65 to 80°C and maintained at 65 to 70°C to obtain an oil phase, and while the oil phase is being stirred, an aqueous phase maintained at 65 to 70°C is added to emulsify the oil phase, and the water phase is rapidly cooled and kneaded;
The interesterified palm oil is an oil obtained by interesterifying unfractionated palm oil,
The method for producing roll- in margarine, wherein the extremely hardened oil other than lauric fats and oils is at least one selected from the group consisting of high erucine rapeseed extremely hardened oil, low erucine rapeseed extremely hardened oil, soybean oil extremely hardened oil, and corn oil extremely hardened oil.
前記油脂混合物中の構成脂肪酸におけるパルミチン酸/ラウリン酸(重量比)が4~90である、請求項に記載のロールインマーガリンの製造方法。 7. The method for producing roll-in margarine according to claim 6 , wherein the palmitic acid/lauric acid (weight ratio) in the constituent fatty acids of the oil/fat mixture is 4 to 90.
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