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JP7785376B2 - Deposit prevention structure for heat exchanger, and heat exchanger having deposit prevention structure - Google Patents
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JP7785376B2 - Deposit prevention structure for heat exchanger, and heat exchanger having deposit prevention structure - Google Patents

Deposit prevention structure for heat exchanger, and heat exchanger having deposit prevention structure

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Publication number
JP7785376B2
JP7785376B2 JP2023530447A JP2023530447A JP7785376B2 JP 7785376 B2 JP7785376 B2 JP 7785376B2 JP 2023530447 A JP2023530447 A JP 2023530447A JP 2023530447 A JP2023530447 A JP 2023530447A JP 7785376 B2 JP7785376 B2 JP 7785376B2
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heat exchanger
heat transfer
heat
tubular member
liquid
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JPWO2022265118A1 (en
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孝志 西村
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Junkosha Co Ltd
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Junkosha Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/04Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
    • F28D1/047Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/06Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with the heat-exchange conduits forming part of, or being attached to, the tank containing the body of fluid
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00Tubular elements; Assemblies of tubular elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • F28F19/04Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of rubber; of plastics material; of varnish
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00Constructions of heat-exchange apparatus characterised by the selection of particular materials

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Description

本発明は、熱交換器の付着物抑制構造、及び付着物抑制構造を有する熱交換器に関する。特に、本発明は、液槽内に浸漬して使用される熱交換器において、液面近傍の伝熱管表面への付着物の堆積を抑制する構造と、その構造を備えた熱交換器に関する。 The present invention relates to a deposit-suppressing structure for a heat exchanger and a heat exchanger having a deposit-suppressing structure. In particular, the present invention relates to a structure that suppresses the accumulation of deposits on the surface of heat transfer tubes near the liquid surface in a heat exchanger that is used by immersing it in a liquid tank, and a heat exchanger equipped with said structure.

化学洗浄、メッキ液温度制御、薬液温度制御、温泉熱利用などの用途に使用される熱交換器として、耐食性に優れた伝熱管で構成された投げ込み式熱交換器が用いられている。投げ込み式熱交換器は、1本または複数本の伝熱管で構成された熱交換器を液槽内で伝熱管のほぼ全体を液体中に浸漬し、伝熱管の一部、つまり熱媒または冷媒配管との接続部分を液体の外(液面より上部)に配置して使用するものである。Immersed-type heat exchangers, made up of corrosion-resistant heat transfer tubes, are used in applications such as chemical cleaning, plating solution temperature control, chemical solution temperature control, and hot spring heat utilization. Immersed-type heat exchangers are made up of one or more heat transfer tubes, and are used by immersing almost the entire heat transfer tube in a liquid tank, with part of the heat transfer tube, i.e., the part that connects to the heat transfer medium or refrigerant piping, outside the liquid (above the liquid surface).

化学洗浄とは脱脂、脱錆、防錆などの目的に合わせて、酸、アルカリ、溶剤などを使用して洗浄対象物の表面の不要物や汚れを化学的に除去する方法であり、薬品を貯めた液槽内に、洗浄対象物を浸漬する方式で行われることが多い。このとき、液槽内の薬品を加温または冷却することを目的に熱交換器が使用される。化学洗浄の中でも酸洗は、鋼板や線材、形鋼やパイプ、ステンレス材またはチタン板などの金属製品を扱う分野で用いられ、圧延や熱処理、溶接などによって生じた酸化皮膜などの金属製品表面の不純物を除去するために行われる洗浄作業である。洗浄には、塩酸、硫酸、硝酸やフッ酸などの酸液が用いられる。例えば、板材や線材などを連続的に処理する場合、酸液を満たした液槽内に板材や線材を連続的に搬送し、洗浄を行う。このとき、酸液は60~110℃程度に加温して用いられることが多く、液槽内には1基または複数基の熱交換器が配置される。液槽内の酸液には、鋼材の表面から脱離した酸化物(スケール片)や油汚れなどが混在している。特に油分が混入したスケール片が熱交換器の表面に付着すると、スケール片の凝集体となり、熱交換器の表面に堆積していく。熱交換器へのスケール片の付着・堆積は、熱交換器の熱交換効率低下を招くだけでなく、そのスケール片の重量により熱交換器が押しつぶされ、熱交換器の破損の原因ともなっていた。さらに、この熱交換器に付着堆積したスケール片を除去する作業は、酸液に接触する危険性があり、酸液による呼吸器官への害もあるため、安全面で問題があった。このような問題を解決するために、特許文献1には、スケール片が堆積・成長しやすい熱交換器のコーナ部に圧縮空気または槽内酸液を吹き付けて、コーナー部に付着したスケール片等を洗い流すことで、スケール片や油などの凝集堆積(以降、スケールと言う)から熱交換器を保護し、熱交換効率低下や変形を防止する発明が開示されている。Chemical cleaning is a method of chemically removing impurities and dirt from the surface of an object using acids, alkalis, solvents, etc. for purposes such as degreasing, derusting, and rust prevention. This method is often performed by immersing the object in a tank containing chemicals. A heat exchanger is used to heat or cool the chemicals in the tank. Among chemical cleaning methods, pickling is used in fields that handle metal products such as steel plates, wire rods, structural steel, pipes, stainless steel, and titanium plates. It is a cleaning process performed to remove impurities from the surface of metal products, such as oxide films formed during rolling, heat treatment, and welding. Acid solutions such as hydrochloric acid, sulfuric acid, nitric acid, and hydrofluoric acid are used for cleaning. For example, when continuously processing plate materials or wire rods, the plate materials or wire rods are continuously transported through a tank filled with acid solution and cleaned. The acid solution is often heated to approximately 60-110°C, and one or more heat exchangers are installed within the tank. The acid solution in the solution tank contains oxides (scale particles) detached from the steel surface and oily contaminants. When scale particles containing oil adhere to the surface of a heat exchanger, they aggregate and accumulate on the heat exchanger surface. The adhesion and accumulation of scale particles on the heat exchanger not only reduces the heat exchange efficiency of the heat exchanger, but also causes the heat exchanger to be crushed by the weight of the scale particles, potentially resulting in damage to the heat exchanger. Furthermore, removing the scale particles from the heat exchanger poses safety issues, as they can come into contact with the acid solution and pose a risk to the respiratory system. To address these issues, Patent Document 1 discloses an invention that sprays compressed air or an acid solution in the tank onto the corners of the heat exchanger where scale particles are likely to accumulate and grow, thereby washing away the scale particles and other particles adhering to the corners. This protects the heat exchanger from the aggregation and accumulation of scale particles and oily contaminants (hereinafter referred to as "scale") and prevents deterioration of heat exchange efficiency and deformation.

また、酸洗の酸液槽内で使用される投げ込み式の熱交換器においては、液面付近の伝熱管表面にスケールが付着することが問題となっていた。特許文献1に記載された技術では、液槽内の液体に完全に浸漬された部分の熱交換器へのスケール片の付着防止には有効であるが、液面の上部を含む液面近傍においては、その効果を発揮することが困難であった。この伝熱管表面と液面とが接触する付近では、例えば鋼板などを酸液槽内に浸漬したときなどに、液面の高さが上下に変動することにより伝熱管表面にスケールが付着することが問題となっている。このスケールは、伝熱管表面に付着した酸液の揮発分が蒸発して固形分が残り、その固形分に酸液が繰り返し付着して再び揮発分が蒸発し、大きな固形分の固まりとなることで形成される。このようなスケールは、堅牢化しつつ、より大きな塊となって、伝熱管が破損する原因となり、また、除去することが困難となる。Furthermore, in immersion-type heat exchangers used in acid baths for pickling, scale buildup on the heat transfer tube surface near the liquid surface has been a problem. While the technology described in Patent Document 1 is effective in preventing scale buildup on the heat exchanger in the portion completely immersed in the liquid in the bath, it is difficult to achieve this effect near the liquid surface, including the upper portion. In areas where the heat transfer tube surface comes into contact with the liquid surface, for example, when a steel plate is immersed in an acid bath, the liquid level fluctuates up and down, causing scale buildup on the heat transfer tube surface. This scale forms when the volatile components of the acid solution that has adhered to the heat transfer tube surface evaporate, leaving behind solid components. The acid solution then repeatedly adheres to these solid components, causing the volatile components to evaporate again, forming large solid masses. This scale hardens and grows into larger masses, which can cause damage to the heat transfer tube and make it difficult to remove.

このような問題に対し、特許文献2には、液面と接触する付近の伝熱管の外周面に生成するスケールの付着を防止する方法として、鋼板などを洗浄する酸液などの溶液中で使用される熱交換器の伝熱管をフッ素樹脂製の熱収縮チューブで被覆する方法が記載されている。具体的には、収縮させた熱収縮チューブが伝熱管のスケールが付着する範囲を覆うように、熱収縮チューブの位置決めを行い、この位置で熱収縮チューブを加熱して、伝熱管を被覆する保護チューブを形成する方法である。この方法を用いると、スケールが伝熱管には直接付着せず、保護チューブに付着するため、伝熱管の損傷を防止することができる、とされている。In response to this problem, Patent Document 2 describes a method for covering heat transfer tubes of heat exchangers used in solutions such as acid solutions used to clean steel plates with fluororesin heat-shrink tubing as a way to prevent scale buildup on the outer surface of heat transfer tubes near the contact point with the liquid surface. Specifically, the method involves positioning the heat-shrink tubing so that it covers the area of the heat transfer tube where scale will buildup, and then heating the heat-shrink tubing in this position to form a protective tube covering the heat transfer tube. This method is said to prevent damage to the heat transfer tube because scale does not buildup directly on the heat transfer tube, but rather on the protective tube.

しかし、引用文献2の技術では、スケールが伝熱管に直接付着することはないが、伝熱管を覆う保護チューブにはスケールが付着することになる。そのため、頻繁に付着物を除去しなければ大きな塊となり、さらに伝熱管と伝熱管の間の付着物同士が伝熱管を巻き込んで一体化すると、付着物の除去はさらに困難になるという問題があった。一体化して大きな塊となった付着物は、その部分の熱伝導を低下させるだけではなく、付着物を除去する際に伝熱管を破損したり、付着物によって伝熱管が折られる、などの重大な問題を引き起こしていた。 However, with the technology of Cited Document 2, although scale does not adhere directly to the heat transfer tubes, it does adhere to the protective tubes that cover the heat transfer tubes. As a result, if the deposits are not removed frequently, they form large clumps. Furthermore, if the deposits between the heat transfer tubes wrap around the heat transfer tubes and become integrated, removing the deposits becomes even more difficult. The large clumps of deposits that have integrated not only reduce the thermal conductivity of the area, but also cause serious problems such as damaging the heat transfer tubes when removing them or causing them to bend.

特開2003-213466号公報Japanese Patent Application Laid-Open No. 2003-213466 特開2011-141080号公報JP 2011-141080 A

本発明は、こうした従来技術の問題点を解決するために成されたものであり、熱交換器の付着物抑制構造と、その付着物抑制構造を有する熱交換器を提供することを目的とする。 The present invention has been made to solve these problems with the prior art, and aims to provide a deposit suppression structure for a heat exchanger and a heat exchanger having such a deposit suppression structure.

上記の課題を鑑み検討した結果、本発明に至った。具体的には、本発明に係る熱交換器の付着物抑制構造は、1本または複数本の伝熱管を備える熱交換器において、前記熱交換器は、前記伝熱管の外部表面に液体が接触して熱交換を行う熱交換器であって、前記熱交換器は前記伝熱管のうち1本または複数本の伝熱管に外挿される筒状部材を備え、前記筒状部材第1端及び第2端を有し、前記筒状部材は前記第1端及び前記第2端の少なくともいずれか一方にシール部材を備えることを特徴とする。また、前記筒状部材は内部表面及び外部表面を有するものであってもよい。 As a result of research and development in consideration of the above-mentioned problems, the present invention was arrived at. Specifically, the deposit prevention structure for a heat exchanger according to the present invention is a heat exchanger including one or more heat transfer tubes, the heat exchanger performing heat exchange by bringing a liquid into contact with the outer surfaces of the heat transfer tubes, the heat exchanger including a tubular member fitted onto one or more of the heat transfer tubes, the tubular member having a first end and a second end, and the tubular member including a seal member on at least one of the first end and the second end. The tubular member may also have an inner surface and an outer surface.

また、上記課題は、前記筒状部材が前記第1端及び前記第2端の両方にシール部材を備えることにより、より好ましく解決される。 Furthermore, the above problem is more preferably solved by providing the tubular member with sealing members at both the first end and the second end.

また、前記筒状部材は、少なくとも外部表面において接触角が90°以上であることが好ましい。 Furthermore, it is preferable that the tubular member has a contact angle of 90° or more on at least the outer surface.

前記筒状部材は、その外部表面上に1層以上の被覆層を備えた構造であることが、好ましい。また、その被覆層は、少なくとも一部に易引き裂き性を付与した層であることが、より好ましい。また、前記被覆層は、少なくとも外部表面において接触角が90°以上であることが好ましい。 The cylindrical member preferably has one or more coating layers on its outer surface. The coating layers are preferably at least partially made tearable. The coating layers preferably have a contact angle of 90° or greater on at least the outer surface.

また、上記課題を解決するため、本発明の付着物抑制構造を有する熱交換器は、1本または複数本の伝熱管を備える熱交換器において、前記熱交換器は液槽内に配置され前記伝熱管の外部表面に液体が接触して熱交換を行う熱交換器であって、前記熱交換器は前記伝熱管のうち1本または複数本の伝熱管に外挿される筒状部材を備え、前記筒状部材第1端及び第2端を有し、前記筒状部材は前記第1端及び前記第2端の少なくともいずれか一方にシール部材を備え、前記筒状部材の一方の端部が液槽の液面より上部に位置するように設置されることを特徴とする。 上記の課題を鑑み検討した結果、本発明に至った。具体的には、本発明に係る熱交換器の付着物抑制構造は、1本または複数本の伝熱管を備える熱交換器において、前記熱交換器は、前記伝熱管の外部表面に液体が接触して熱交換を行う熱交換器であって、前記熱交換器は前記伝熱管のうち1本または複数本の伝熱管に外挿される筒状部材を備え、前記筒状部材は第1端及び第2端を有し、前記筒状部材は前記第1端及び前記第2端の少なくともいずれか一方にシール部材を備えることを特徴とする。また、前記筒状部材は内部表面及び外部表面を有するものであってもよい。 In order to solve the above-mentioned problems, the present invention provides a heat exchanger having a deposit suppression structure, the heat exchanger including one or more heat transfer tubes, the heat exchanger being disposed in a liquid tank and performing heat exchange by bringing a liquid into contact with the outer surfaces of the heat transfer tubes, the heat exchanger including a tubular member fitted onto one or more of the heat transfer tubes, the tubular member having a first end and a second end, the tubular member including a seal member on at least one of the first end and the second end, and the tubular member being installed so that one end of the tubular member is positioned above the liquid level in the liquid tank. Specifically, the deposit suppression structure for a heat exchanger according to the present invention is a heat exchanger having one or more heat transfer tubes, the heat exchanger performing heat exchange by bringing a liquid into contact with the outer surfaces of the heat transfer tubes, the heat exchanger including a tubular member fitted onto one or more of the heat transfer tubes, the tubular member having a first end and a second end, and the tubular member including a seal member on at least one of the first end and the second end. The tubular member may also have an inner surface and an outer surface.

また、本発明の付着物抑制構造を有する熱交換器の伝熱管は、少なくとも外部表面の材質がフッ素樹脂の中から選択される少なくとも1種の樹脂で構成されることが好ましい。 Furthermore, it is preferable that the heat transfer tube of a heat exchanger having the deposit suppression structure of the present invention has at least the outer surface material made of at least one type of resin selected from fluororesins.

本発明によれば、熱交換器の伝熱管表面への付着物の生成自体を、効果的に防止または抑制することが可能である。熱交換器への付着物を除去する保守作業の頻度を大幅に減らすことができ、また、付着物の除去が容易で、伝熱管の損傷を抑えることができる。 This invention makes it possible to effectively prevent or suppress the formation of deposits on the surface of heat exchanger tubes. This significantly reduces the frequency of maintenance work to remove deposits from heat exchangers, and also makes it easier to remove deposits, minimizing damage to the heat exchanger tubes.

本発明の熱交換器の付着物抑制構造を備えた熱交換器の概略図である。1 is a schematic diagram of a heat exchanger equipped with a deposit suppression structure for a heat exchanger of the present invention. 従来の熱交換器の、液面近傍の構造概略図である。FIG. 1 is a schematic diagram of the structure of a conventional heat exchanger near the liquid surface. 従来の熱交換器の、付着物生成の概念図であるA conceptual diagram of deposit formation in a conventional heat exchanger. 本発明の付着物抑制構造を有する熱交換器の、液面近傍の構造概略図である。1 is a schematic diagram of the structure near the liquid surface of a heat exchanger having the deposit suppression structure of the present invention. 本発明の付着物抑制構造を有する熱交換器の、付着物生成の概念図である。1 is a conceptual diagram of deposit formation in a heat exchanger having a deposit suppression structure of the present invention. 本発明の付着物抑制構造を有する熱交換器の別の一例の、液面近傍の構造概略図である。10 is a schematic structural diagram of another example of a heat exchanger having a deposit suppression structure of the present invention, in the vicinity of the liquid surface. 本発明の熱交換器の付着物抑制構造の筒状部材の形状の例である。10A and 10B show examples of the shape of a cylindrical member of the deposit suppression structure of a heat exchanger of the present invention. 本発明の熱交換器の付着物抑制構造の筒状部材に配置するシール部材の一例の概略図である。3 is a schematic diagram of an example of a sealing member to be placed on a cylindrical member of the deposit suppression structure of the heat exchanger of the present invention. FIG. 本発明の熱交換器の付着物抑制構造を有する熱交換器の別の一例の概略図である。1 is a schematic diagram of another example of a heat exchanger having a deposit suppression structure for a heat exchanger of the present invention. 本発明の熱交換器の付着物抑制構造を有する熱交換器の別の一例の概略図である。1 is a schematic diagram of another example of a heat exchanger having a deposit suppression structure for a heat exchanger of the present invention.

本発明による熱交換器の付着物抑制構造、及び付着物抑制構造を有する熱交換器の好適な実施形態について、図を用いて説明する。各図において、同一の要素には同一の符号を付し、同様の説明となる場合には、重複する説明は省略する場合がある。 The following describes preferred embodiments of the deposit suppression structure for a heat exchanger according to the present invention, and a heat exchanger having the deposit suppression structure, using the drawings. In each drawing, identical elements are designated by the same reference numerals, and where similar explanations are given, duplicate explanations may be omitted.

図1は、本発明の熱交換器の付着物抑制構造を有する熱交換器の一例の概略図である。図1に示すように、液槽A内に配置された熱交換器100は、伝熱管110、熱源配管(図示せず)と接続されるコネクタ120とを備え、さらに本発明の付着物抑制構造を構成する筒状部材130を備える。 Figure 1 is a schematic diagram of an example of a heat exchanger having a deposit suppression structure for a heat exchanger of the present invention. As shown in Figure 1, the heat exchanger 100 disposed in the liquid tank A includes a heat transfer tube 110, a connector 120 connected to a heat source pipe (not shown), and a cylindrical member 130 that constitutes the deposit suppression structure of the present invention.

一般的に投げ込み式タイプとも呼ばれる熱交換器100は、伝熱管のほぼ全体を液槽A内の液体に浸漬されて使用される。伝熱管110は、1本または複数本で構成され、液槽A内へ装入するのに都合のよい大きさのループ形状を有するように配置される。伝熱管110の端部は液面Bより高くなる位置に配置される。液面より上部に配置された伝熱管110の端末は、熱源(例えば、図示していない水蒸気供給口)配管に接続され、そこから伝熱管110内部に熱媒(または冷媒)が供給される。Heat exchanger 100, commonly known as the throw-in type, is used with the heat transfer tubes almost entirely immersed in the liquid in liquid tank A. Heat transfer tube 110 consists of one or more tubes, arranged in a loop shape of a size that is convenient for insertion into liquid tank A. The ends of heat transfer tube 110 are positioned higher than liquid level B. The ends of heat transfer tube 110 positioned above the liquid level are connected to a heat source (e.g., a steam supply port, not shown) pipe, from which a heat transfer medium (or refrigerant) is supplied into the heat transfer tube 110.

伝熱管110の液面B近傍には、本発明の付着物抑制構造として用いられる筒状部材130が配置される。例えば、鋼板や鋼線材などの酸洗工程では、酸液槽内に洗浄対象物を浸漬する操作、温調操作や液槽内の液体の攪拌操作などの操作により、液槽内の酸液の液面が一定範囲で上下し、揺動する。また、酸液槽内に、鋼板や鋼線材などの洗浄対象物を連続的に高速で搬送するときなどには、酸液の液面上において飛沫が発生する。このとき、液面より上部にある伝熱管表面に酸液が付着し、その揮発分が蒸発して伝熱管表面で固形分が析出する。これを繰り返すと付着物は成長し大きくなる。筒状部材130は、筒状部材内部における液面の揺動を抑制し、また、液面上で発生した飛沫が伝熱管へ付着することを防止できる。さらに、筒状部材の上側端部にシール部材を配置した場合には、筒状部材内部の酸液の揮発分の蒸発を抑える効果も期待できる。このように、筒状部材130は、筒状部材内部の伝熱管110の外部表面への付着物の生成を防止または抑制するものであり、また、筒状部材130の外部表面に付着物が生成した場合であっても、筒状部材130の表面は単純な形状であるために、付着物の除去が非常に容易である。 A cylindrical member 130, used as the deposit-suppressing structure of the present invention, is positioned near the liquid surface B of the heat transfer tube 110. For example, in the pickling process for steel plates, steel wire rods, etc., the acid liquid level in the liquid tank fluctuates within a certain range due to operations such as immersing the object to be cleaned in the acid tank, adjusting the temperature, and stirring the liquid in the tank. Furthermore, when objects to be cleaned, such as steel plates or steel wire rods, are continuously transported through the acid tank at high speed, droplets are generated on the acid liquid surface. When this occurs, the acid liquid adheres to the surface of the heat transfer tube above the liquid surface, and its volatile components evaporate, resulting in the deposition of solids on the heat transfer tube surface. Repeated cycles of this process result in deposits growing larger. The cylindrical member 130 suppresses the liquid surface oscillation within the cylindrical member and also prevents droplets generated on the liquid surface from adhering to the heat transfer tube. Furthermore, when a sealing member is placed at the upper end of the cylindrical member, the effect of suppressing evaporation of volatile components of the acid solution inside the cylindrical member can be expected. In this way, the cylindrical member 130 prevents or suppresses the formation of deposits on the outer surface of the heat transfer tube 110 inside the cylindrical member. Even if deposits do form on the outer surface of the cylindrical member 130, the surface of the cylindrical member 130 has a simple shape, making it very easy to remove the deposits.

図2は、従来の熱交換器の一例の液面近傍の構造概略図であり、図3は従来の熱交換器の付着物生成の概念図である。図4は本発明の付着物抑制構造を備えた熱交換器の一例の液面近傍の構造概略図である。図4は、筒状部材130の下端部にシール部材131を配置した例を示している。また、図5は、本発明の付着物抑制構造を備えた熱交換器の一例の付着物生成の概念図である。図2の従来の熱交換器では、伝熱管110は、外部表面が液中に露出した状態、もしくは伝熱管110の表面が個別に被覆された状態で液中に曝されている。図3に示すように、熱交換器の液面近傍で付着物が生成する領域C1は伝熱管110のそれぞれの外部表面上にあり、生成した付着物を取り除く作業は伝熱管1本1本に対して行う必要がある。さらに、伝熱管110の表面の付着物を頻繁に除去しなければ、伝熱管110の表面の付着物同士が一体化し、付着物が伝熱管を巻き込んだ塊となるため、付着物を除去することが困難になるなど問題が多かった。これに対し、図4の本発明の付着物抑制構造を備えた熱交換器の例では、伝熱管110の束を取り囲むように筒状部材130が配置されている。図5に示すように、液面近傍で付着物が生成する領域C2は筒状部材130の外部表面にあり、付着物が生成した場合でも取り除くのが容易であり、付着物の除去作業により伝熱管を損傷する虞もない。 Figure 2 is a schematic diagram of the structure near the liquid surface of an example of a conventional heat exchanger, and Figure 3 is a conceptual diagram of deposit formation in a conventional heat exchanger. Figure 4 is a schematic diagram of the structure near the liquid surface of an example of a heat exchanger equipped with the deposit prevention structure of the present invention. Figure 4 shows an example in which a seal member 131 is disposed at the lower end of a cylindrical member 130. Figure 5 is a conceptual diagram of deposit formation in an example of a heat exchanger equipped with the deposit prevention structure of the present invention. In the conventional heat exchanger of Figure 2, the heat transfer tubes 110 are exposed to the liquid with their outer surfaces exposed to the liquid, or with the surfaces of the heat transfer tubes 110 individually coated. As shown in Figure 3, region C1, where deposits form near the liquid surface of the heat exchanger, is located on the outer surfaces of each of the heat transfer tubes 110, and the work of removing the formed deposits must be performed on each heat transfer tube individually. Furthermore, if deposits on the surfaces of the heat transfer tubes 110 are not frequently removed, the deposits on the surfaces of the heat transfer tubes 110 will coalesce and form clumps that wrap around the heat transfer tubes, making them difficult to remove. In contrast, in the example of a heat exchanger equipped with the deposit suppression structure of the present invention shown in Figure 4, a cylindrical member 130 is arranged to surround the bundle of heat transfer tubes 110. As shown in Figure 5, region C2 where deposits form near the liquid surface is located on the outer surface of the cylindrical member 130, so that even if deposits form, they can be easily removed and there is no risk of damaging the heat transfer tubes during the process of removing the deposits.

筒状部材は、筒状部材の第1端が液面の上部にあり、第2端が液面の下部にある位置に配置することが好ましい。ここで、液面の下部とは、液面の変動範囲を超えて低い位置であり、筒状部材の第2端は液面が変動した場合でも常に液槽中の液体に浸漬された状態にあることが好ましい。液面の上部とは、液面の変動範囲を超えて高い位置であり、好ましくは液面上で発生する飛沫が届かない位置まで伝熱管を覆うことができる位置である。液槽内の液面と、伝熱管と熱源配管の接続部との間に、支持板やトッププレートなどが配置された熱交換器においては、筒状部材は、支持板またはトッププレートなどに接続、またはそれらを貫通して固定されていることがより好ましい。そのように配置された筒状部材は、液面上で発生する飛沫を、伝熱管から遮断することができる。The tubular member is preferably positioned so that its first end is above the liquid surface and its second end is below the liquid surface. Here, "below the liquid surface" refers to a position lower than the range of liquid surface fluctuations, and it is preferable that the second end of the tubular member is always immersed in the liquid in the liquid tank, even when the liquid surface fluctuates. "Above the liquid surface" refers to a position higher than the range of liquid surface fluctuations, preferably a position that can cover the heat transfer tube to a position that is out of reach of droplets generated on the liquid surface. In a heat exchanger in which a support plate or top plate is disposed between the liquid surface in the liquid tank and the connection between the heat transfer tube and the heat source piping, it is more preferable that the tubular member be connected to or penetrate the support plate or top plate. A tubular member positioned in this manner can block droplets generated on the liquid surface from the heat transfer tube.

図6は、本発明の付着物抑制構造を備えた熱交換器の別の一例の、液面近傍の構造概略図である。筒状部材は、図4のように、熱交換器のすべての伝熱管を一括して外挿されたものであってもよいし、図6(a)のように伝熱管を分割して外挿されたものであってもよく、また、図6(b)のように一部の伝熱管に外挿されたものであってもよい。筒状部材の配置は、熱交換器の配置状況、液面上での飛沫の発生やメンテナンスの状況などに合わせて、適宜決めることができる。 Figure 6 is a structural schematic diagram of the vicinity of the liquid surface of another example of a heat exchanger equipped with the deposit suppression structure of the present invention. The tubular member may be fitted over all of the heat transfer tubes of the heat exchanger as a whole, as in Figure 4, or may be fitted over divided heat transfer tubes as in Figure 6(a), or may be fitted over only a portion of the heat transfer tubes as in Figure 6(b). The arrangement of the tubular member can be determined appropriately depending on the arrangement of the heat exchanger, the occurrence of splashes on the liquid surface, maintenance conditions, etc.

筒状部材130の形状は、内部表面及び外部表面を有しかつ第1端及び第2端を有するものであれば、断面形状は限定されない。例えば図7(a)に示したような、断面形状が円形のものに限定されず、図7(b)のように断面形状が四角形、または図7(c)のように多角形(図7(c)の例は六角形)であってもよい。また、伝熱管の配置形状に合わせて図7(d)または(e)のように、断面形状が不定形のものであってもよい。筒状部材の形状は、熱交換器の配置状況やメンテナンスの状況などに合わせて、適宜決めることができる。また、第1端と第2端の断面形状や断面積が同じである必要はなく、例えば図7(f)のように、液面の上部にある第1端の断面積の方が大きく、液面の下部にある第2端の断面積の方が小さいものであってもよい。図7(f)のような形状の場合、筒状部材の壁部が傾斜していることで、筒状部材の表面に付着した液滴が落下しやすく、また付着物が成長した場合でも成長した付着物が自重で落下しやすい利点がある。The cross-sectional shape of the tubular member 130 is not limited as long as it has an inner surface, an outer surface, and a first end and a second end. For example, the cross-sectional shape is not limited to a circular shape as shown in FIG. 7(a). It may also be a square shape as shown in FIG. 7(b) or a polygonal shape as shown in FIG. 7(c) (the example in FIG. 7(c) is a hexagon). The cross-sectional shape may also be irregular, as shown in FIG. 7(d) or (e), to match the arrangement of the heat transfer tubes. The shape of the tubular member can be determined appropriately depending on the arrangement and maintenance conditions of the heat exchanger. Furthermore, the cross-sectional shapes and cross-sectional areas of the first and second ends do not need to be the same. For example, the cross-sectional area of the first end above the liquid surface may be larger and the cross-sectional area of the second end below the liquid surface may be smaller, as shown in FIG. 7(f). In the case of a shape such as that shown in Figure 7(f), the wall of the cylindrical member is inclined, which has the advantage that droplets adhering to the surface of the cylindrical member tend to fall off easily, and even if deposits grow, the grown deposits tend to fall off under their own weight.

筒状部材は、熱交換器に配置した後に上述のような形状になっているものであればよく、熱交換器へ配置する前の形状は限定されない。例えば、筒状部材は、1枚の板材を、熱交換器に取り付けるときに伝熱管の周囲を覆うように円筒形に丸めて固定したものであってもよい。また、例えば、筒状部材は、複数枚の板材を、伝熱管の周囲に筒状になるように貼り合わせたものであってもよい。筒状部材の壁部は、できれば隙間が無いものが好ましいが、筒状部材内部における液面の揺動を抑制し、また、発生した飛沫が伝熱管へ付着することを防止する効果が得られるものであれば、筒状部材の壁部がメッシュ状、スリットなどを有するもので構成されていてもよい。そのとき、筒状部材の外部表面は、付着物が生成しにくく、また生成した付着物が除去し易い表面であることが好ましい。The cylindrical member may have any shape as described above after being placed in the heat exchanger; its shape before being placed in the heat exchanger is not limited. For example, the cylindrical member may be a single plate material rolled into a cylindrical shape and fixed so that it surrounds the heat transfer tube when attached to the heat exchanger. Alternatively, the cylindrical member may be a plurality of plates bonded together to form a cylindrical shape around the heat transfer tube. While the wall of the cylindrical member is preferably gap-free, it may also be constructed with a mesh or slits, as long as it suppresses the sloshing of the liquid surface inside the cylindrical member and prevents droplets from adhering to the heat transfer tube. In this case, the outer surface of the cylindrical member is preferably one that is resistant to deposits and allows any deposits that do form to be easily removed.

筒状部材の少なくとも外部表面は、平滑で、接触角が90°以上であることが好ましい。例えば、筒状部材の外部表面を研磨して表面形状を調整する、筒状部材の外部表面に接触角が大きい材質の被膜を設ける、などの方法により、外部表面の状態を調整することが可能である。筒状部材の外部表面を接触角が90°以上であるものにすることで、筒状部材はその外部表面に付着物が生成しにくく、また、生成した付着物を容易に除去することができるものとなる。後述する、筒状部材の外部表面上に被覆層を備えた構造である場合、被覆層の外部表面は、平滑で接触角が90°以上であることが好ましい。 It is preferable that at least the outer surface of the tubular member is smooth and has a contact angle of 90° or more. For example, the condition of the outer surface can be adjusted by polishing the outer surface of the tubular member to adjust the surface shape, or by applying a coating made of a material with a large contact angle to the outer surface of the tubular member. By making the outer surface of the tubular member have a contact angle of 90° or more, the tubular member is less likely to develop deposits on its outer surface, and any deposits that do form can be easily removed. In the case of a structure in which a coating layer is provided on the outer surface of the tubular member, as described below, it is preferable that the outer surface of the coating layer be smooth and have a contact angle of 90° or more.

筒状部材は、その外部表面上に1層以上の被覆層を備えた構造であることが好ましい。被覆層を複数備える場合、被覆層は1層ずつ剥離可能な構造であることが好ましい。筒状部材の表面に被覆層を備えた構造は、筒状部材の表面が汚れたり、筒状部材の表面の付着物の除去を繰り返すことによって付着物の除去がし難くなった場合などに、被覆層を剥離して新しい表面とすることで、再び高い効果を得ることができる。また、被覆層を複数備えている構造では、外側の被覆層から1層ずつ、付着物とともに剥離させることが可能で、簡便に繰り返し新しい表面を得ることができる。また、筒状部材の被覆層は、筒状部材の外部表面上にフィルム形状のものを巻き付けて、筒状に固定した構造であってもよい。その場合は、被覆層の筒状の固定を外してフィルムを剥離し除去することが可能である。また、被覆層は、層の少なくとも一部に易引き裂き性を付与したものであってもよい。被覆層の易引き裂き性は、被覆層の表面に切り込みや傷を設けてその切込みに沿って引き裂き易くする、被覆層の一部の肉厚を薄くして裂き易い部分を設ける、複数の樹脂を混合した材料などを用いて作成した易引き裂き性を有するチューブまたはフィルムを被覆層にする、などの方法により、実現できる。易引き裂き性を付与した被覆層を用いた場合、被覆層を剥離する際に特別な道具が不要であり、作業性が高い。 The tubular member preferably has a structure including one or more coating layers on its outer surface. When multiple coating layers are provided, the coating layers are preferably structured to be peelable one by one. A structure including a coating layer on the surface of a tubular member can be highly effective again by peeling off the coating layer to create a new surface when the surface of the tubular member becomes dirty or when repeated removal of deposits from the surface of the tubular member makes it difficult to remove the deposits. Furthermore, in a structure including multiple coating layers, the outer coating layer can be peeled off one by one along with the deposits, allowing for easy and repeated removal of a new surface. The coating layer of the tubular member may also be structured by wrapping a film-shaped material around the outer surface of the tubular member and fixing it to a cylindrical shape. In this case, the film can be peeled off and removed by undoing the cylindrical fixation of the coating layer. Furthermore, at least a portion of the coating layer may be made easily tearable. The coating layer can be made easy to tear by methods such as making cuts or scratches on the surface of the coating layer to make it easier to tear along the cuts, thinning the thickness of part of the coating layer to make it easier to tear, or using a tube or film with easy tearing properties made from a material that is a mixture of multiple resins as the coating layer. When a coating layer with easy tearing properties is used, no special tools are required to peel off the coating layer, making it easier to work with.

筒状部材の少なくとも外部表面を構成する材料は、液槽内の液体、および筒状部材の周囲温度によって、容易に破壊されないものであることが好ましい。その材質は金属、樹脂など、多少の応力、衝撃が加えられても破壊されないものであることが好ましい。例えば、腐食性の液体を使用する場合などには、筒状部材の材質は耐腐食性に優れる金、白金、タンタル、ハステロイ、ニッケル合金などの金属であってもよいし、樹脂であってもよい。樹脂製の場合は、例えば、ポリプロピレン(PP)、GF強化PP、ポリ塩化ビニル(PVC)、フッ素樹脂、繊維強化プラスチック(FRP)などを用いることができる。中でも耐薬品性、耐熱性、剥離性に優れる樹脂として、ポリテトラフルオロエチレン(PTFE)、テトラフルオロエチレン―パーフルオロアルキルビニルエーテル共重合体(PFA)、テトラフルオロエチレン―ヘキサフルオロプロピレン(FEP)、ポリクロロトリフルオロエチレン(PCTFE)、ポリフッ化ビニリデン(PVDF)などのフッ素樹脂は適用範囲が広い。The material constituting at least the outer surface of the tubular member is preferably one that is not easily destroyed by the liquid in the liquid tank or the ambient temperature of the tubular member. The material is preferably a metal, resin, or other material that can withstand slight stress or impact. For example, when using a corrosive liquid, the tubular member may be made of a corrosion-resistant metal such as gold, platinum, tantalum, Hastelloy, or nickel alloy, or a resin. Resin materials include polypropylene (PP), glass-reinforced PP, polyvinyl chloride (PVC), fluororesin, and fiber-reinforced plastic (FRP). Among these, fluororesins such as polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), tetrafluoroethylene-hexafluoropropylene (FEP), polychlorotrifluoroethylene (PCTFE), and polyvinylidene fluoride (PVDF) have a wide range of applications due to their excellent chemical resistance, heat resistance, and peelability.

筒状部材は、第1端及び第2端の少なくともいずれか一方にシール部材を備えるものであることが好ましい。筒状部材の下端部(液面より下部)にシール部材を配したものであることがより好ましく、筒状部材の上端部と下端部の両方にシール部材を配したものであることがさらに好ましい。シール部材は、伝熱管が挿通し、筒状部材内部への通液を阻害する構造を有する。また、シール部材は、筒状部材内部への通気を阻害する構造を有するものであることがより好ましく、筒状部材を閉塞することができる構造であることがさらに好ましい。図8は、本発明の熱交換器の付着物抑制構造の筒状部材に配置するシール部材に使用するシールプレート800の一例の概略図である。シールプレート800には、伝熱管が挿通する貫通穴810が設けられている。シールプレートの材質は、液槽内の液体、および筒状部材の周囲温度によって、容易に破壊されないものであることが好ましい。その材質は金属、樹脂など、多少の応力、衝撃が加えられても破壊されないものであればよく、特に限定されない。例えば、腐食性の液体を使用する場合などには、耐腐食性に優れる金、白金、タンタル、ハステロイ、ニッケル合金などの金属であってもよいし、ポリプロピレン(PP)、GF強化PP、ポリ塩化ビニル(PVC)、繊維強化プラスチック(FRP)、先述のようなフッ素樹脂、フッ素ゴム、パーフルオロエラストマー、シリコンゴムなどを用いることができる。貫通穴810の穴径は、伝熱管の外径を考慮して、伝熱管の外径と同じ、または伝熱管の外径より若干大きく設定するとよい。シールプレート800の貫通穴810には、貫通穴810と伝熱管との隙間を低減する充填材を配置することができる。シール部材によって筒状部材を閉塞する構造としたい場合は、例えばシールプレート800の貫通穴810に、貫通穴810と伝熱管との隙間を充填するO-リングなどの充填材を配置するとよい。または、シールプレートをフッ素ゴムのような柔軟性を有する材質で構成し、貫通穴810の穴径を、伝熱管の外径と同じか、伝熱管の外径より若干小さくすることにより、伝熱管を挿通したときに筒状部材が閉塞される構造とすることもできる。また、例えば、2枚のシールプレートを準備し、シールプレートの間にゴムなどの弾性材料で作成したシートを挟み込んで固定する構造とすることもできる。その場合、弾性材料で作成したシートには、シールプレートの貫通穴に適合する位置に、伝熱管の外径と同じか、伝熱管の外径より若干小さな径の穴を設けるとよい。2枚のシールプレートは、固定穴820を利用して固定する構造とすることもできる。2枚のシールプレートの間に配置した弾性材料で作成したシートにより、貫通穴810と伝熱管との隙間が充填され、筒状部材を閉塞することができる。The tubular member preferably has a seal member at at least one of the first and second ends. It is more preferable that the seal member be located at the lower end (below the liquid level) of the tubular member, and even more preferable that seal members be located at both the upper and lower ends of the tubular member. The seal member has a structure through which the heat transfer tube is inserted and prevents liquid from passing through the tubular member. It is also more preferable that the seal member has a structure that prevents airflow into the tubular member, and even more preferable that it has a structure that can close the tubular member. Figure 8 is a schematic diagram of an example of a seal plate 800 used as a seal member placed on the tubular member of the deposit-prevention structure for a heat exchanger of the present invention. The seal plate 800 has a through-hole 810 through which the heat transfer tube passes. It is preferable that the material of the seal plate is resistant to destruction by the liquid in the liquid tank and the ambient temperature of the tubular member. The material may be metal, resin, or any other material that can withstand slight stress and impact, and is not particularly limited. For example, when using a corrosive liquid, metals with excellent corrosion resistance such as gold, platinum, tantalum, Hastelloy, and nickel alloys may be used. Alternatively, polypropylene (PP), GF-reinforced PP, polyvinyl chloride (PVC), fiber-reinforced plastic (FRP), the aforementioned fluororesin, fluororubber, perfluoroelastomer, and silicone rubber may be used. The diameter of the through-hole 810 may be set to be the same as or slightly larger than the outer diameter of the heat transfer tube, taking into account the outer diameter of the heat transfer tube. A filler material may be placed in the through-hole 810 of the seal plate 800 to reduce the gap between the through-hole 810 and the heat transfer tube. If a structure is desired in which the tubular member is blocked by a sealing member, a filler material such as an O-ring may be placed in the through-hole 810 of the seal plate 800 to fill the gap between the through-hole 810 and the heat transfer tube. Alternatively, the seal plate can be made of a flexible material such as fluororubber, and the diameter of the through hole 810 can be set to the same as or slightly smaller than the outer diameter of the heat transfer tube, thereby blocking the tubular member when the heat transfer tube is inserted. Alternatively, for example, two seal plates can be prepared, and a sheet made of an elastic material such as rubber can be sandwiched and fixed between the seal plates. In this case, the sheet made of elastic material can be provided with holes in positions that fit the through holes of the seal plate, with a diameter that is the same as or slightly smaller than the outer diameter of the heat transfer tube. The two seal plates can also be fixed using fixing holes 820. The sheet made of elastic material placed between the two seal plates fills the gap between the through hole 810 and the heat transfer tube, blocking the tubular member.

シール部材は、伝熱管を挿通する前に図8の例のような形状に成形したものを準備し、貫通穴810に伝熱管を挿通して筒状部材に固定するものであってもよいし、伝熱管と筒状部材を配置した後に図8の例のような形状になるように、筒状部材と伝熱管の間にシール部材の材料を充填することによって形成したものであってもよい。 The sealing member may be prepared by forming it into a shape like the example in Figure 8 before inserting the heat transfer tube, and then inserting the heat transfer tube into the through hole 810 and fixing it to the tubular member, or it may be formed by filling the space between the tubular member and the heat transfer tube with sealing member material after arranging the heat transfer tube and tubular member so that it has a shape like the example in Figure 8.

筒状部材またはシール部材は、その構造体を分割することができるものであることがより好ましい。それにより、熱交換器へ取り付けた状態から伝熱管やコネクタなどの熱交換器部品を取り外すことなく、筒状部材を除去することが可能であり、筒状部材のみの交換が可能になる。It is more preferable that the tubular member or sealing member has a structure that can be separated. This allows the tubular member to be removed from the heat exchanger without removing heat exchanger parts such as heat transfer tubes and connectors, making it possible to replace just the tubular member.

シール部材を備えた筒状部材は、シール部材と伝熱管の隙間などから気体または液体を供給し、筒状部材の内外で差圧を設け、筒状部材の内部を微正圧とすることができる。微正圧とすることで、シール部材と伝熱管との隙間から液相内の液体が筒状部材内部へ侵入するのを抑制することができる。筒状部材内部に供給する液体は、水などでもよいが、液相内の液体と同種の液体であることが濃度コントロール上、より好ましい。また、状部材内部に供給する液体が酸液である場合、スケール付着などに対するセルフクリーニング効果が期待できる。 A cylindrical member equipped with a sealing member can supply gas or liquid through the gap between the sealing member and the heat transfer tube, creating a pressure difference between the inside and outside of the cylindrical member and creating a slight positive pressure inside the cylindrical member. Creating a slight positive pressure can prevent the liquid in the liquid phase from entering the cylindrical member through the gap between the sealing member and the heat transfer tube. The liquid supplied to the cylindrical member can be water, but it is more preferable for concentration control that the liquid be the same type as the liquid in the liquid phase. Furthermore, if the liquid supplied to the cylindrical member is an acid solution, a self-cleaning effect against scale buildup can be expected.

熱交換器100は、伝熱管110と熱源配管とを接続するコネクタ120、筒状部材130の他に、液槽A内の伝熱管110の配置を保持するスペーサ140やスペーサ同士を連結して形状を維持する固定部材150、伝熱管110が浮き上がるのを抑えるロッド160などを備えていてもよい(図1参照)。 In addition to the connector 120 that connects the heat transfer tube 110 to the heat source piping and the cylindrical member 130, the heat exchanger 100 may also include a spacer 140 that maintains the position of the heat transfer tube 110 in the liquid tank A, a fixing member 150 that connects the spacers together to maintain their shape, and a rod 160 that prevents the heat transfer tube 110 from floating up (see Figure 1).

図9は、本発明の熱交換器の付着物抑制構造を備えた熱交換器の別の一例の概略図である。
ループ形状で固定した伝熱管110が複数本並列で配置され、それぞれの伝熱管110の端部は、それぞれが熱源配管につながるコネクタ(図示せず)に接続されている。伝熱管の接続部近くで、熱媒の入口側、出口側のそれぞれで伝熱管が1か所に集められ、その集められた伝熱管110の液面近傍にあたる部分を覆うように筒状部材130が配置されている。筒状部材の上端部(液面の上部)は、液槽の蓋の機能を有するトッププレート160に接続されており、液面の上部の伝熱管は、液面の揺動や液面上で発生する飛沫から遮断される構造となっている。
FIG. 9 is a schematic diagram of another example of a heat exchanger equipped with a deposit suppression structure for a heat exchanger of the present invention.
A plurality of heat transfer tubes 110 fixed in a loop shape are arranged in parallel, and the end of each heat transfer tube 110 is connected to a connector (not shown) that connects to the heat source piping. Near the joints of the heat transfer tubes, the heat transfer tubes are gathered in one location on both the inlet and outlet sides of the heat medium, and a cylindrical member 130 is arranged to cover the portion of the gathered heat transfer tubes 110 that is near the liquid surface. The upper end of the cylindrical member (above the liquid surface) is connected to a top plate 160 that functions as a lid for the liquid tank, so that the heat transfer tubes above the liquid surface are shielded from fluctuations in the liquid surface and splashes generated on the liquid surface.

図10は、本発明の熱交換器の付着物抑制構造を備えた熱交換器の別の一例の概略図である。伝熱管110は、複数本束ねられてU字形状に配置され、伝熱管110の端部は、熱源配管につながるコネクタ120に接続されている。伝熱管の束は、熱媒の入口側端部及び出口側端部が隣接して配置され、その伝熱管110の液面近傍にあたる部分は、一括して筒状部材130に外挿されている。熱交換器は、伝熱管110がループ形状に配置されるものでもよいし、図10の例のように、
U字形状に配置されるものであってもよい。
10 is a schematic diagram of another example of a heat exchanger equipped with a deposit suppression structure for a heat exchanger of the present invention. A plurality of heat transfer tubes 110 are bundled and arranged in a U-shape, and the ends of the heat transfer tubes 110 are connected to a connector 120 that leads to a heat source pipe. The bundle of heat transfer tubes is arranged so that the inlet end and outlet end of the heat medium are adjacent to each other, and the portions of the heat transfer tubes 110 near the liquid surface are collectively inserted into a cylindrical member 130. The heat exchanger may be one in which the heat transfer tubes 110 are arranged in a loop shape, or, as in the example of FIG. 10,
It may be arranged in a U-shape.

本発明の熱交換器の付着物抑制構造を有する熱交換器において、伝熱管は、少なくとも外部表面の材質がフッ素樹脂の中から選択される少なくとも1種で構成されることが好ましい。液槽内の液体、および筒状部材の周囲温度によって、容易に破壊されないものであればよい。その材質は金属であってもよいが、液槽の形状に合わせて自在に形状を変えることができる樹脂であるとより好ましい。樹脂製の場合は、例えば、ポリプロピレン(PP)、GF強化PP、ポリ塩化ビニル(PVC)、フッ素樹脂、繊維強化プラスチック(FRP)などを用いることができる。中でも耐薬品性、耐熱性、剥離性に優れる樹脂として、ポリテトラフルオロエチレン(PTFE)、テトラフルオロエチレン―パーフルオロアルキルビニルエーテル共重合体(PFA)、テトラフルオロエチレン―ヘキサフルオロプロピレン(FEP)、ポリクロロトリフルオロエチレン(PCTFE)、ポリフッ化ビニリデン(PVDF)などのフッ素樹脂の中から選択される少なくとも1種から構成されることがより好ましい。フッ素樹脂は、熱伝導性、導電性、バリア性または機械的強度などの付与または向上のために、フィラーを含むものであってもよい。フッ素樹脂に含まれるフィラーの一例は、例えば非結晶炭素粒子、黒鉛粒子、ガラス繊維などである。In the heat exchanger having the deposit suppression structure of the present invention, the heat transfer tube preferably has at least one outer surface made of a material selected from fluororesins. Any material is sufficient as long as it is not easily damaged by the liquid in the liquid tank or the ambient temperature of the tubular member. While the material may be metal, a resin that can be easily shaped to fit the shape of the liquid tank is preferable. For resin, examples that can be used include polypropylene (PP), GF-reinforced PP, polyvinyl chloride (PVC), fluororesin, and fiber-reinforced plastic (FRP). Among these, resins with excellent chemical resistance, heat resistance, and peelability are preferably made of at least one selected from fluororesins such as polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), tetrafluoroethylene-hexafluoropropylene (FEP), polychlorotrifluoroethylene (PCTFE), and polyvinylidene fluoride (PVDF). The fluororesin may contain fillers to impart or improve thermal conductivity, electrical conductivity, barrier properties, or mechanical strength. Examples of the filler contained in the fluororesin include amorphous carbon particles, graphite particles, and glass fibers.

本発明によれば、熱交換器の伝熱管表面への付着物の生成を効果的に防止または抑制することが可能であり、呼吸器への害や酸液との接触の危険性がある、伝熱管に付着堆積したスケール片を除去する過酷な保守作業の頻度を、大幅に減らすことができる。また、付着物の除去が容易で、付着物除去作業によって伝熱管を損傷することもないため、熱交換器は高い性能を維持した状態で使用することが可能である。 This invention effectively prevents or inhibits the formation of deposits on the surfaces of heat exchanger heat transfer tubes, significantly reducing the frequency of the arduous maintenance work of removing scale particles that have accumulated on heat transfer tubes, which poses a risk of respiratory harm and contact with acidic solutions. Furthermore, because deposits are easily removed and the work of removing them does not damage the heat transfer tubes, the heat exchanger can be used while maintaining high performance.

A 液槽、 B 液面、 C 付着物が生成する領域
100 熱交換器、 110 伝熱管、 120 コネクタ、 130 筒状部材、 131 シール部材、 140 スペーサ、 150 固定部材、 160 ロッド
シールプレート 800、 貫通穴 810、 固定穴 820


A: Liquid tank; B: Liquid surface; C: Area where deposits are formed; 100: Heat exchanger; 110: Heat transfer tube; 120: Connector; 130: Cylindrical member; 131: Seal member; 140: Spacer; 150: Fixing member; 160: Rod seal plate; 800: Through hole; 810: Fixing hole; 820


Claims (8)

数本の伝熱管を備える熱交換器において、

前記熱交換器は前記伝熱管の外部表面に液体が接触して熱交換を行う熱交換器であって、

前記熱交換器は、複数本の前記伝熱管に外挿される筒状部材を備え、

前記筒状部材は第1端及び第2端を有し、

前記筒状部材は前記第1端及び前記第2端の少なくともいずれか一方にシール部材を備える、

熱交換器の付着物抑制構造。
In a heat exchanger having a plurality of heat transfer tubes,

The heat exchanger is a heat exchanger in which a liquid comes into contact with an outer surface of the heat transfer tube to exchange heat,

the heat exchanger includes a cylindrical member that is fitted onto the heat transfer tubes;

the tubular member has a first end and a second end ;

the tubular member is provided with a sealing member at at least one of the first end and the second end;

Heat exchanger structure to prevent deposits.
前記筒状部材は、前記第1端及び前記第2端の両方にシール部材を備える、

請求項1に記載の熱交換器の付着物抑制構造。
the tubular member includes a sealing member at both the first end and the second end;

The deposit suppression structure for a heat exchanger according to claim 1.
前記筒状部材は、少なくとも外部表面において、接触角が90°以上である、

請求項1または2のいずれか一項に記載の熱交換器の付着物抑制構造。
The cylindrical member has a contact angle of 90° or more on at least the outer surface.

3. The deposit suppression structure for a heat exchanger according to claim 1 or 2.
前記筒状部材は、外部表面上に1層以上の被覆層を備える、

請求項1または2のいずれか一項に記載の熱交換器の付着物抑制構造。
The tubular member has one or more coating layers on an exterior surface thereof.

3. The deposit suppression structure for a heat exchanger according to claim 1 or 2.
前記筒状部材の前記被覆層は、少なくとも一部に易引き裂き性を付与した層である、

請求項4に記載の熱交換器の付着物抑制構造。
The coating layer of the tubular member is a layer having easy-tear properties imparted to at least a portion thereof.

The deposit suppression structure for a heat exchanger according to claim 4.
前記筒状部材の前記被覆層は、少なくとも外部表面において、接触角が90°以上である、

請求項4に記載の熱交換器の付着物抑制構造。
The coating layer of the cylindrical member has a contact angle of 90° or more at least on the outer surface.

The deposit suppression structure for a heat exchanger according to claim 4.
数本の伝熱管を備える熱交換器において、

前記熱交換器は液槽内に配置され前記伝熱管の外部表面に液体が接触して熱交換を行う熱交換器であって、

前記熱交換器は、複数本の前記伝熱管に外挿される筒状部材を備え、

前記筒状部材は、第1端及び第2端を有し、

前記筒状部材は前記第1端及び前記第2端の少なくともいずれか一方にシール部材を備え、

前記筒状部材の一方の端部が液槽の液面より上部に位置するように設置される、

付着物抑制構造を有する熱交換器。
In a heat exchanger having a plurality of heat transfer tubes,

The heat exchanger is a heat exchanger that is placed in a liquid tank and performs heat exchange by bringing liquid into contact with the outer surfaces of the heat transfer tubes,

the heat exchanger includes a cylindrical member that is fitted onto the heat transfer tubes;

the tubular member has a first end and a second end;

the cylindrical member includes a seal member at at least one of the first end and the second end;

The cylindrical member is installed so that one end thereof is located above the liquid surface of the liquid tank.

A heat exchanger with a structure that suppresses deposits.
前記伝熱管は、少なくとも外部表面の材質がフッ素樹脂の中から選択される少なくとも1種の樹脂で構成される、請求項7に記載の熱交換器。 The heat exchanger according to claim 7, wherein at least the outer surface of the heat transfer tube is made of at least one type of resin selected from fluororesins.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090279880A1 (en) 2007-02-22 2009-11-12 Belkin Lev Scale-Inhibiting Electrical Heater And Method Of Fabrication Thereof
JP2010151402A (en) 2008-11-20 2010-07-08 Daikin Ind Ltd Heat exchanger
JP2011141080A (en) 2010-01-07 2011-07-21 Kansetsu Sangyo Kk Method of preventing build-up of scale to heat exchanger
WO2014136527A1 (en) 2013-03-08 2014-09-12 住友重機械工業株式会社 Corrosion control method for heat exchanger and corrosion control structure for heat exchanger
JP2017185539A (en) 2016-04-07 2017-10-12 株式会社Spf Device supplied to use in corrosive atmosphere

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Publication number Priority date Publication date Assignee Title
US20090279880A1 (en) 2007-02-22 2009-11-12 Belkin Lev Scale-Inhibiting Electrical Heater And Method Of Fabrication Thereof
JP2010151402A (en) 2008-11-20 2010-07-08 Daikin Ind Ltd Heat exchanger
JP2011141080A (en) 2010-01-07 2011-07-21 Kansetsu Sangyo Kk Method of preventing build-up of scale to heat exchanger
WO2014136527A1 (en) 2013-03-08 2014-09-12 住友重機械工業株式会社 Corrosion control method for heat exchanger and corrosion control structure for heat exchanger
JP2017185539A (en) 2016-04-07 2017-10-12 株式会社Spf Device supplied to use in corrosive atmosphere

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