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JP7824366B2 - Method for manufacturing resin molded body - Google Patents
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JP7824366B2 - Method for manufacturing resin molded body - Google Patents

Method for manufacturing resin molded body

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JP7824366B2
JP7824366B2 JP2024124640A JP2024124640A JP7824366B2 JP 7824366 B2 JP7824366 B2 JP 7824366B2 JP 2024124640 A JP2024124640 A JP 2024124640A JP 2024124640 A JP2024124640 A JP 2024124640A JP 7824366 B2 JP7824366 B2 JP 7824366B2
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temperature
resin molded
mold
molded body
resin
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JP2026022981A (en
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昌夫 上野
智大 藤沼
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Kumi Kasei Co Ltd
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Description

本発明は、樹脂成形体の製造方法に関する。 The present invention relates to a method for manufacturing a resin molded product.

セルロース繊維等の天然繊維を含む樹脂成形体が、日用品や家電筐体、建材、車載部品等の幅広い分野に展開されている。樹脂成形体における天然繊維の含有量を増やすことにより、石油由来の材料の使用を削減することができる。 Resin molded products containing natural fibers such as cellulose fibers are used in a wide range of fields, including everyday items, home appliance housings, building materials, and automotive parts. Increasing the natural fiber content in resin molded products can reduce the use of petroleum-derived materials.

天然繊維を含む樹脂成形体は、射出成形で成形することができる(例えば、特許文献1参照)。 Resin molded articles containing natural fibers can be formed by injection molding (see, for example, Patent Document 1).

特許第6839570号公報Patent No. 6839570

天然繊維を含む樹脂組成物で射出成形を行うと、特有の柄が発生した樹脂成形体が得られるものの、樹脂成形体全体に柄が出てしまうという課題がある。 When a resin composition containing natural fibers is injection molded, a resin molded product with a unique pattern is obtained, but there is an issue in that the pattern appears throughout the entire resin molded product.

本発明は、上記事情に鑑みてなされたものであって、任意の箇所に天然繊維に由来する柄を発生させることができる樹脂成形体の製造方法を提供することを目的とする。 The present invention was made in consideration of the above circumstances, and aims to provide a method for manufacturing a resin molded product that can produce patterns derived from natural fibers at any location.

本発明は、以下の態様を有する。
[1]金型内に熱可塑性樹脂と、天然繊維とを含む樹脂組成物を射出して、前記樹脂組成物からなる樹脂成形体を得る樹脂成形体の製造方法であって、
前記金型内において、温度の高い部分と温度の低い部分を設ける、樹脂成形体の製造方法。
[2]前記温度の低い部分の温度が10℃以上30℃以下、前記温度の高い部分の温度が40℃以上である、[1]に記載の樹脂成形体の製造方法。
[3]前記金型内における前記樹脂成形体の厚さ方向に相当する前記樹脂組成物の流路の高さが、1.8mm以下または2.2mm以上である、[1]に記載の樹脂成形体の製造方法。
The present invention has the following aspects.
[1] A method for producing a resin molded article, comprising injecting a resin composition containing a thermoplastic resin and natural fibers into a mold to obtain a resin molded article made of the resin composition,
A method for manufacturing a resin molded article, wherein a high temperature portion and a low temperature portion are provided within the mold.
[2] The method for producing a resin molded body according to [1], wherein the temperature of the low temperature portion is 10°C or higher and 30°C or lower, and the temperature of the high temperature portion is 40°C or higher.
[3] The method for producing a resin molded body described in [1], wherein the height of the flow path of the resin composition corresponding to the thickness direction of the resin molded body in the mold is 1.8 mm or less or 2.2 mm or more.

本発明によれば、任意の箇所に天然繊維に由来する柄を発生させることができる樹脂成形体の製造方法を提供することができる。 The present invention provides a method for producing a resin molded product that can produce patterns derived from natural fibers at any location.

本実施形態の樹脂成形体の製造方法で用いられる金型の一例を示す断面図である。FIG. 2 is a cross-sectional view showing an example of a mold used in the method for producing a resin molded body according to the present embodiment. 実験例において、水管に温調器により温度を調節した水を流して金型の温度を31℃にした場合の樹脂成形体の表面、および水管に温調器により温度を調節した水を流して金型の温度を29℃にした場合の樹脂成形体の表面を示す写真である。In an experimental example, photographs show the surface of a resin molded body when water whose temperature has been adjusted by a temperature regulator is flowed through the water pipe to set the temperature of the mold to 31°C, and the surface of a resin molded body when water whose temperature has been adjusted by a temperature regulator is flowed through the water pipe to set the temperature of the mold to 29°C. 実験例において、水管に温調器により温度を調節した水を流して金型の温度を31℃にした場合の樹脂成形体の表面、および水管に温調器により温度を調節した水を流して金型の温度を29℃にした場合の樹脂成形体の表面を示す写真である。In an experimental example, photographs show the surface of a resin molded body when water whose temperature has been adjusted by a temperature regulator is flowed through the water pipe to set the temperature of the mold to 31°C, and the surface of a resin molded body when water whose temperature has been adjusted by a temperature regulator is flowed through the water pipe to set the temperature of the mold to 29°C. 実験例において、主型の温度を15℃、入れ子の温度を35℃にした場合の樹脂成形体の表面、および主型の温度を15℃、入れ子の温度を45℃にした場合の樹脂成形体の表面を示す写真である。In an experimental example, photographs are shown showing the surface of a resin molded body when the temperature of the main mold is 15°C and the temperature of the insert is 35°C, and the surface of a resin molded body when the temperature of the main mold is 15°C and the temperature of the insert is 45°C. 実験例において、主型の温度を15℃、入れ子の温度を35℃にした場合の樹脂成形体の表面を示す写真である。10 is a photograph showing the surface of a resin molded body in an experimental example when the temperature of the main mold is 15° C. and the temperature of the insert is 35° C. 実験例において、主型の温度を15℃、入れ子の温度を45℃にした場合の樹脂成形体の表面を示す写真である。10 is a photograph showing the surface of a resin molded body in an experimental example when the temperature of the main mold is 15° C. and the temperature of the insert is 45° C. 実験例において、主型の温度を15℃、入れ子の温度を45℃にした場合の樹脂成形体の表面の顕微鏡像である。1 is a microscope image of the surface of a resin molded body in an experimental example in which the temperature of the main mold was 15° C. and the temperature of the insert was 45° C.

本発明の樹脂成形体の製造方法の実施の形態について説明する。
なお、本実施の形態は、発明の趣旨をより良く理解させるために具体的に説明するものであり、特に指定のない限り、本発明を限定するものではない。
An embodiment of the method for producing a resin molded article of the present invention will be described.
It should be noted that the present embodiment is specifically described to allow a better understanding of the gist of the invention, and does not limit the present invention unless otherwise specified.

[樹脂成形体の製造方法]
本発明の一実施形態に係る樹脂成形体の製造方法は、金型内に熱可塑性樹脂と、天然繊維とを含む樹脂組成物を射出して、前記樹脂組成物からなる樹脂成形体を得る樹脂成形体の製造方法であって、前記金型内において、温度の高い部分と温度の低い部分を設ける。
[Method of manufacturing resin molded body]
A method for manufacturing a resin molded body according to one embodiment of the present invention is a method for manufacturing a resin molded body in which a resin composition containing a thermoplastic resin and natural fibers is injected into a mold to obtain a resin molded body made of the resin composition, and high-temperature areas and low-temperature areas are provided within the mold.

本実施形態の樹脂成形体の製造方法では、熱可塑性樹脂と、天然繊維とを含む樹脂組成物を用いる。 The method for manufacturing a resin molded body of this embodiment uses a resin composition containing a thermoplastic resin and natural fibers.

熱可塑性樹脂としては、例えば、オレフィン系樹脂、スチレン系樹脂、アクリル系樹脂、ポリカーボネート系樹脂等が挙げられる。 Examples of thermoplastic resins include olefin-based resins, styrene-based resins, acrylic-based resins, polycarbonate-based resins, etc.

天然繊維としては、例えば、セルロース繊維、ジュート繊維、バンブー繊維、ケナフ繊維等が挙げられる。 Examples of natural fibers include cellulose fiber, jute fiber, bamboo fiber, and kenaf fiber.

樹脂組成物の全質量(100質量%)に対する天然繊維の含有量は、35質量%以上55質量%以下が好ましく、40質量%以上50質量%以下がより好ましく、45質量%以上48質量%以下がさらに好ましい。天然繊維の含有量が前記下限値以上であると、天然繊維に由来する、特有の柄が発生する。天然繊維の含有量が前記上限値を超えると、天然繊維を含む樹脂成形体での射出成形を行うことが困難になる。 The natural fiber content relative to the total mass (100% by mass) of the resin composition is preferably 35% by mass or more and 55% by mass or less, more preferably 40% by mass or more and 50% by mass or less, and even more preferably 45% by mass or more and 48% by mass or less. If the natural fiber content is above the lower limit, a distinctive pattern derived from the natural fibers will develop. If the natural fiber content exceeds the upper limit, it will be difficult to perform injection molding with a resin molded product containing natural fibers.

図1は、本実施形態の樹脂成形体の製造方法で用いられる金型の一例を示す断面図である。
図1に示すように、金型1は、主型10と、入れ子20と、水管30と、を有する。主型10の内部に水管30が設けられている。水管30内には水が流れるようになっている。入れ子20は、主型10に嵌合して用いられる。入れ子20は、主型10に接する面側の一部に、主型10と接していない空間(断熱用空間)20Aを有する。主型10において、入れ子20が配置されていない部分が成形時に温度の低い部分10Aとなり、入れ子20が配置されている部分が成形時に温度の高い部分10Bとなる。
FIG. 1 is a cross-sectional view showing an example of a mold used in the method for producing a resin molded article according to this embodiment.
As shown in Figure 1, the mold 1 has a main mold 10, a insert 20, and a water pipe 30. The water pipe 30 is provided inside the main mold 10. Water flows through the water pipe 30. The insert 20 is fitted into the main mold 10 when in use. The insert 20 has a space (heat insulating space) 20A that is not in contact with the main mold 10 on a part of the surface that contacts the main mold 10. In the main mold 10, the portion where the insert 20 is not placed becomes a portion 10A that has a low temperature during molding, and the portion where the insert 20 is placed becomes a portion 10B that has a high temperature during molding.

本実施形態の樹脂成形体の製造方法では、金型1内に上記樹脂組成物を射出する際に、主型10内において、温度の高い部分10Bと温度の低い部分10Aを設ける。主型10はヒーターにより加熱されているが、水管30内に水を流すことにより、温度を下げることができる。温度の高い部分10Bでは、断熱用空間20Aが設けられているため、水管30による冷却作用が抑制され、温度の低い部分10Aよりも温度が高くなる。 In the method for manufacturing a resin molded body of this embodiment, when the resin composition is injected into the mold 1, a high-temperature portion 10B and a low-temperature portion 10A are provided within the main mold 10. The main mold 10 is heated by a heater, but the temperature can be lowered by running water through the water pipe 30. Because the heat-insulating space 20A is provided in the high-temperature portion 10B, the cooling effect of the water pipe 30 is suppressed, and the high-temperature portion 10B becomes hotter than the low-temperature portion 10A.

本実施形態の樹脂成形体の製造方法では、温度の高い部分10Bと温度の低い部分10Aの温度差が20℃以上30℃以下であることが好ましい。前記温度差が前記下限値以上であると、任意の箇所に天然繊維に由来する柄を発生させることができる。 In the method for manufacturing a resin molded body of this embodiment, it is preferable that the temperature difference between the high-temperature portion 10B and the low-temperature portion 10A be 20°C or more and 30°C or less. When this temperature difference is equal to or greater than the lower limit, a pattern derived from natural fibers can be generated at any location.

本実施形態の樹脂成形体の製造方法では、温度の低い部分10Aの温度が10℃以上30℃以下であることが好ましく、15℃以上19℃以下であることがより好ましい。前記温度が前記下限値以上であると、天然繊維を含む樹脂成形体での射出成形を行う事ができる。前記温度が前記上限値を超えると、天然繊維由来の特有の柄が発生しにくくなる。 In the method for manufacturing a resin molded product of this embodiment, the temperature of the low-temperature portion 10A is preferably 10°C or higher and 30°C or lower, and more preferably 15°C or higher and 19°C or lower. If the temperature is above the lower limit, injection molding can be performed on a resin molded product containing natural fibers. If the temperature exceeds the upper limit, it becomes difficult to produce the unique patterns derived from natural fibers.

金型1内へ樹脂組成物を射出(導入)する際の圧力は、120MPa以上170MPa以下であることが好ましい。 The pressure when injecting (introducing) the resin composition into mold 1 is preferably 120 MPa or more and 170 MPa or less.

本実施形態の樹脂成形体の製造方法では、主型10における温度の低い部分10Aにて、得られる樹脂成形体の厚さ方向に相当する樹脂組成物の流路11の高さ(金型1の厚み方向の高さ)d1が1.8mmの部分(第1の部分)100Aと、得られる樹脂成形体の厚さ方向に相当する樹脂組成物の流路11の高さ(金型1の厚み方向の高さ)d2が2.2mmの部分(第2の部分)100Bとを設定する。第1の部分100Aと第2の部分100Bで柄(マーブル模様)の発生を検証した結果、第1の部分100Aと第2の部分100Bでは、柄の出やすさが異なることが分かった。すなわち、第1の部分100Aは、柄の発生が制限された部分であり、柄が発生しにくい部分である。第2の部分100Bは、柄の発生する部分であり、柄が発生しやすい部分である。流路11の高さが小さい部分(第1の部分100A)では樹脂組成物の射出速度は上がり、樹脂成形体が薄肉化することによりスキン層ができやすい。そのため、柄が発生する前に成形されてしまい柄が出にくい傾向がある。一方、流路11の高さが大きい部分(第2の部分100B)では樹脂組成物の射出速度は下がり、樹脂成形体が厚肉化することによりスキン層ができにくく、ゆっくり樹脂が意匠面に反映されることで柄ができているものと考えられる。
なお、主型10における温度の高い部分10Bは、柄の発生が抑制された部分である(第3の部分100C)。
In the method for manufacturing a resin molded body of this embodiment, in the low-temperature portion 10A of the main mold 10, a portion (first portion) 100A is set where the height d1 (height in the thickness direction of the mold 1) of the resin composition flow path 11, which corresponds to the thickness direction of the resulting resin molded body, is 1.8 mm, and a portion (second portion) 100B is set where the height d2 (height in the thickness direction of the mold 1) of the resin composition flow path 11, which corresponds to the thickness direction of the resulting resin molded body, is 2.2 mm. As a result of verifying the occurrence of a pattern (marble pattern) in the first portion 100A and the second portion 100B, it was found that the likelihood of a pattern occurring differs between the first portion 100A and the second portion 100B. That is, the first portion 100A is a portion where the occurrence of a pattern is limited and where the pattern is unlikely to occur. The second portion 100B is a portion where the pattern occurs and where the pattern is likely to occur. In the portion (first portion 100A) where the height of the flow path 11 is small, the injection speed of the resin composition increases, and the resin molded body becomes thinner, making it more likely that a skin layer will form. Therefore, molding is completed before the pattern appears, making it difficult for the pattern to appear. On the other hand, in the portion where the height of the flow path 11 is large (second portion 100B), the injection speed of the resin composition is reduced, and the resin molding becomes thicker, making it difficult for a skin layer to form, and it is thought that the resin is slowly reflected in the design surface, resulting in the pattern.
The high-temperature portion 10B of the main mold 10 is a portion where the generation of a pattern is suppressed (third portion 100C).

本実施形態の樹脂成形体の製造方法によれば、金型1内において、温度の高い部分10Bと温度の低い部分10Aを設けることにより、温度の高い部分10Bでは天然繊維に由来する柄の発生を抑制し、温度の低い部分10Aでは天然繊維に由来する柄の発生を促進することができる。これにより、樹脂成形体の任意の箇所に天然繊維に由来する柄を発生させることができる。 According to the method for manufacturing a resin molded body of this embodiment, by providing high-temperature portions 10B and low-temperature portions 10A within the mold 1, it is possible to suppress the development of patterns derived from natural fibers in the high-temperature portions 10B and promote the development of patterns derived from natural fibers in the low-temperature portions 10A. This makes it possible to develop patterns derived from natural fibers at any location on the resin molded body.

以下、実験例により本発明をさらに具体的に説明するが、本発明は以下の実験例に限定されるものではない。 The present invention will be explained in more detail below using experimental examples, but the present invention is not limited to these examples.

[実験例]
表1に示す条件で、射出成形により、樹脂成形体を成形した。
熱可塑性樹脂としては、ポリプロピレンを用いた。
[Experimental Example]
Under the conditions shown in Table 1, a resin molded body was formed by injection molding.
As the thermoplastic resin, polypropylene was used.

図2、図3に示すように、水管に温調器により温度を調節した水を流して金型の温度を31℃にした場合、樹脂成形体の表面において、マーブル柄が目立ちにくくなる(図2の上側、図3の上側)。また、水管に温調器により温度を調節した水を流して金型の温度を29℃にした場合、樹脂成形体の表面において、マーブル柄が発生する(図2の下側、図3の下側)。 As shown in Figures 2 and 3, when water whose temperature has been adjusted by a temperature regulator is run through the water pipe and the temperature of the mold is set to 31°C, the marble pattern becomes less noticeable on the surface of the resin molded body (top of Figure 2, top of Figure 3). Furthermore, when water whose temperature has been adjusted by a temperature regulator is run through the water pipe and the temperature of the mold is set to 29°C, the marble pattern appears on the surface of the resin molded body (bottom of Figure 2, bottom of Figure 3).

図4、図5に示すように、主型の温度を15℃、入れ子の温度を35℃にした場合、主型に触れていた部分はマーブル柄が発生し、入れ子に触れていた部分はマーブル柄が少し発生していた(図4の上側、図5)。
また、図4、図6に示すように、主型の温度を15℃、入れ子の温度を45℃にした場合、主型に触れていた部分はマーブル柄が発生し、入れ子に触れていた部分はマーブル柄の発生が抑制されていた(図4の下側、図6)。
As shown in Figures 4 and 5, when the temperature of the main mold was 15°C and the temperature of the insert mold was 35°C, a marbled pattern was generated in the area that had been in contact with the main mold, and a slight marbled pattern was generated in the area that had been in contact with the insert mold (upper side of Figure 4, Figure 5).
Furthermore, as shown in Figures 4 and 6, when the temperature of the main mold was 15°C and the temperature of the insert mold was 45°C, a marbled pattern was generated in the area that was in contact with the main mold, while the generation of a marbled pattern was suppressed in the area that was in contact with the insert mold (bottom of Figure 4, Figure 6).

図7に、主型の温度を15℃、入れ子の温度を45℃にした場合の樹脂成形体の表面の顕微鏡像を示す。顕微鏡としては、キーエンス社製のマイクロスコープを用いた。図7に示すように、主型と触れていた部分では、主型に触れていた部分にはマーブル柄となる凹凸が形成され、入れ子に触れていた部分には凹凸が形成されていなかった。 Figure 7 shows a microscope image of the surface of a resin molded body when the temperature of the master mold was 15°C and the temperature of the insert was 45°C. A Keyence microscope was used. As shown in Figure 7, in the part that came into contact with the master mold, irregularities with a marbled pattern were formed, while in the part that came into contact with the insert, no irregularities were formed.

1 金型
10 主型
10A 温度の低い部分
10B 温度の高い部分
11,12 流路
20 入れ子
20A 断熱用空間
30 水管
100A 第1の部分
100B 第2の部分
100C 第3の部分
1 Mold 10 Main mold 10A Low temperature part 10B High temperature part 11, 12 Flow path 20 Insert 20A Heat insulating space 30 Water pipe 100A First part 100B Second part 100C Third part

Claims (2)

金型内に熱可塑性樹脂と、天然繊維とを含む樹脂組成物を射出して、前記樹脂組成物からなる樹脂成形体を得る樹脂成形体の製造方法であって、
前記金型内において、温度の高い部分と温度の低い部分を設け
前記温度の高い部分と前記温度の低い部分の温度差が20℃以上30℃以下、
前記温度の低い部分の温度が10℃以上30℃以下、前記温度の高い部分の温度が40℃以上である、樹脂成形体の製造方法。
A method for producing a resin molded article, comprising injecting a resin composition containing a thermoplastic resin and natural fibers into a mold to obtain a resin molded article made of the resin composition, the method comprising:
A high temperature portion and a low temperature portion are provided in the mold ,
the temperature difference between the high temperature portion and the low temperature portion is 20°C or more and 30°C or less;
The method for producing a resin molded body, wherein the temperature of the low temperature portion is 10°C or higher and 30°C or lower, and the temperature of the high temperature portion is 40°C or higher .
前記金型内における前記樹脂成形体の厚さ方向に相当する前記樹脂組成物の流路の高さが、1.8mm以下または2.2mm以上である、請求項1に記載の樹脂成形体の製造方法。 The method for producing a resin molded body according to claim 1, wherein the height of the flow path of the resin composition in the mold, which corresponds to the thickness direction of the resin molded body, is 1.8 mm or less or 2.2 mm or more.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004330716A (en) 2003-05-09 2004-11-25 Polyplastics Co Polyphenylene sulfide molding method and molding die
JP2012131042A (en) 2010-12-20 2012-07-12 Toyo Mach & Metal Co Ltd Injection molding machine
JP6839570B2 (en) 2017-03-13 2021-03-10 パナソニック株式会社 Molded product and its molding method

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JP3216470B2 (en) * 1995-02-14 2001-10-09 株式会社神戸製鋼所 Fiber-reinforced resin molded product and method for producing the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004330716A (en) 2003-05-09 2004-11-25 Polyplastics Co Polyphenylene sulfide molding method and molding die
JP2012131042A (en) 2010-12-20 2012-07-12 Toyo Mach & Metal Co Ltd Injection molding machine
JP6839570B2 (en) 2017-03-13 2021-03-10 パナソニック株式会社 Molded product and its molding method

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