JPS5811393B2 - Manufacturing method for cosmetic cement products - Google Patents
Manufacturing method for cosmetic cement productsInfo
- Publication number
- JPS5811393B2 JPS5811393B2 JP51133339A JP13333976A JPS5811393B2 JP S5811393 B2 JPS5811393 B2 JP S5811393B2 JP 51133339 A JP51133339 A JP 51133339A JP 13333976 A JP13333976 A JP 13333976A JP S5811393 B2 JPS5811393 B2 JP S5811393B2
- Authority
- JP
- Japan
- Prior art keywords
- cement
- molded product
- colored
- cosmetic
- manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
- C04B41/63—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/65—Coating or impregnation with inorganic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
Description
【発明の詳細な説明】
本発明は化粧セメント製品の製造方法に関し、特に屋根
瓦の製造に有用なものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing decorative cement products, and is particularly useful for manufacturing roof tiles.
日本瓦としてセメント瓦が公知であり、この瓦を製造す
るには、セメント:砂止(重量比)を1:3に調合した
比較的硬練りのモルタルを製瓦機の型板上に盛り、この
モルタルをローラにより型板にた〜き込むと共に余分の
モルタルをかき取り、かくして成形した成形品を型板ご
と製瓦機から取りはずし、これをある程度、自然乾燥し
たのち、加熱により強制養生している。Cement tiles are well known as Japanese tiles. To manufacture these tiles, a relatively hard mortar made of a 1:3 ratio of cement to sandstone (by weight) is placed on the template of a tile making machine. This mortar is rolled into the template using rollers, and the excess mortar is scraped off.The molded product thus formed is removed from the tile making machine along with the template, and after being air-dried to some extent, it is forcedly cured by heating. There is.
しかしながら、この瓦の製造においては、成形品の自然
乾燥時にクラックが生じ易く、特に、鬼瓦、棟端飾瓦、
軒瓦、すみ瓦等の形状の複雑な瓦において、このクラッ
ク発生が顕著である。However, in the production of this tile, cracks are likely to occur when the molded product is naturally dried, and this is especially true for onigawa tiles, ridge end decorative tiles, etc.
This cracking is noticeable in tiles with complicated shapes, such as eave tiles and corner tiles.
このクラック発生の原因は、乾燥時での水分の蒸発が成
形品の表面のみから生じ、乾燥が成形品全体に対して一
様に行われ難いことによると考えられる。The cause of this cracking is thought to be that moisture evaporates only from the surface of the molded product during drying, making it difficult to dry the entire molded product uniformly.
か瓦る現状に鑑み、本願出願人は、先に、無機質発泡骨
材例えば、天然軽石、発泡珪砂等をセメントに混合し、
これを重量比で3〜10%の水分で硬練し、このセメン
ト混合物を瓦の形状に200〜600kg/cm2の圧
力でプレス成形し、この成形体を自然乾燥後、強制養生
することを提案した。In view of the current situation, the applicant of this application first mixed inorganic foamed aggregate such as natural pumice, foamed silica sand, etc. into cement.
It is proposed to harden this with a water content of 3 to 10% by weight, press-form this cement mixture into the shape of a roof tile at a pressure of 200 to 600 kg/cm2, dry this molded product naturally, and then force curing it. did.
この瓦の製造方法においては、水の添加量が3〜10%
とされ、セメントの流動性が充分に制限されていること
、並びに成形圧力が200〜600kg/cm2とされ
、セメントペーストの無機質発泡骨材への含浸が充分に
抑制されること等により、プレス後の成形体には、無機
質発泡骨材が、セメントペーストで含浸されていない多
孔状態で含有される。In this tile manufacturing method, the amount of water added is 3 to 10%.
After pressing, the fluidity of cement is sufficiently restricted, and the molding pressure is 200 to 600 kg/cm2, which sufficiently suppresses the impregnation of the cement paste into the inorganic foamed aggregate. The molded body contains inorganic foamed aggregate in a porous state that is not impregnated with cement paste.
従って、成形体乾燥時の水分の蒸発は、無機質発泡骨材
の気孔性のために、成形体の内部からも行われ、成形体
全体が一様に乾燥される結果、上記のクラック発生は解
消される。Therefore, due to the porosity of the inorganic foam aggregate, moisture evaporates from the inside of the molded product when drying the molded product, and as a result, the entire molded product dries uniformly, eliminating the occurrence of cracks mentioned above. be done.
ところで、屋根瓦においては着色化粧を施すことが要求
され、この化粧は、艶のない落着のある外観とすること
が必要である。By the way, roof tiles are required to be colored and decorated, and this makeup needs to have a dull and calm appearance.
この化粧方法の一つとして、比較的径の大きな無機質粒
体を含む着色セメント水溶液を吹付ける方法が考えられ
る。One possible method for this cosmetic method is to spray a colored cement aqueous solution containing relatively large diameter inorganic particles.
この化粧方法によれば、化粧表面が凹凸化されるため、
充分に艶消しされた化粧が可能である。According to this makeup method, the makeup surface is made uneven, so
Fully matte makeup is possible.
また、この化粧材にはセメントが含有されているため、
上記の吹付けをセメント未養生品に対して行えば、この
未養生品の養生時に化粧材が養生品に強固に結合され、
剥離強度に秀れた化粧を施すことができる。In addition, since this decorative material contains cement,
If the above spraying is performed on a cement-uncured product, the decorative material will be firmly bonded to the cement-cured product when the uncured product is cured.
Makeup with excellent peel strength can be applied.
本願出願人が先に提案した瓦の製造方法において、瓦に
化粧を施すには、上記スプレー化粧法の使用が考えられ
、このため本発明者等は、プレス成形後の成形品、すな
わち、無機質発泡骨材が多孔状態のま〜で含有されてい
る未硬化セメント成形品に、上記の粒体含有着色セメン
ト水溶液を吹付け、そして成形品を乾燥したところ、着
色セメン溶液が未硬化セメント成形品の多孔表皮に含浸
され、耐剥離性に著しく秀れた化粧を施すことができた
。In the tile manufacturing method previously proposed by the applicant, it is possible to use the spray cosmetic method described above to apply makeup to the tile. When the above colored cement aqueous solution containing granules was sprayed onto an unhardened cement molded product containing foamed aggregate in a porous state and the molded product was dried, the colored cement solution formed into an unhardened cement molded product. It was impregnated into the porous epidermis of the skin, making it possible to apply makeup with outstanding peeling resistance.
しかしながら、立体形状の棟瓦においては、着色セメン
ト水溶液が乾燥するまでの間、棟瓦の両側面において水
溶液中の粒体が、その重量のためにずれ移動し、従って
、粒体による艶消し効果を効果的に発揮させ得ないこと
を見出した。However, in the case of three-dimensional shaped ridge tiles, until the colored cement aqueous solution dries, the particles in the aqueous solution shift due to their weight on both sides of the ridge tile, and therefore the matting effect of the particles is reduced. I discovered that I could not make it work effectively.
本発明に係る化粧セメント製品の製造方法は、粒体含有
着色セメント水溶液の吹付けにより化粧する場合、上記
した粒体のずれ移動を防止し、粒体を均一に付着させて
、全体的に艶のない落着いた化粧を施し得る方法である
。The method for producing a cosmetic cement product according to the present invention prevents the above-mentioned shift and movement of the granules when applying a cosmetic by spraying a colored cement aqueous solution containing granules, allows the granules to adhere uniformly, and gives an overall glossy appearance. This is a method that allows you to apply makeup without any makeup.
更に、本発明によれば、耐剥離性に著しく秀れた化粧を
施すことができる。Furthermore, according to the present invention, it is possible to apply makeup with extremely high peeling resistance.
すなわち、本発明に係る化粧セメント製品の製造方法は
、粒体含有着色塗料の吹付けにより化粧する場合、上記
した粒体のずれ移動を防止し、粒体を均一に付着させて
、全体的に艶のない落着いた化粧を施し得る方法である
。In other words, the method for producing a cosmetic cement product according to the present invention prevents the above-mentioned shift and movement of the granules when applying a cosmetic by spraying a colored paint containing granules, allows the granules to adhere uniformly, and improves the overall appearance. This is a method that allows you to apply makeup that is matte and subdued.
更に、本発明は、著しく秀れた耐剥離性を有する化粧を
施すことを目的とするものである。A further object of the present invention is to provide makeup with outstanding peeling resistance.
更に、また本発明は、耐水性に秀れた化粧を施すことを
目的とするものである。Furthermore, another object of the present invention is to apply makeup with excellent water resistance.
すなわち、本発明に係る化粧セメント製品の製造方法は
、未養生セメント成形品を約40°〜70℃に予熱し、
直径1.5〜0.1mmの無機質粒体を含む、樹脂、セ
メント混合着色液を、上記予熱成形品の表面に吹付け、
而るのちに、成形品を養生することを特徴とする方法で
ある。That is, the method for producing a decorative cement product according to the present invention involves preheating an uncured cement molded product to about 40° to 70°C;
Spraying a colored liquid mixed with resin and cement containing inorganic particles with a diameter of 1.5 to 0.1 mm onto the surface of the preheated molded product,
This method is characterized by curing the molded product afterwards.
本発明において、無機質粒体を含む、樹脂・セメント混
合着色液には、下記配合の着色セメント組成物と直径1
.5〜0.1mmの着色珪砂(着色セメント組成物と同
色)とを1:1で混合し、水分散型樹脂例えばアクリル
系樹脂100部に水65部を添加した樹脂エマルジョン
を、上記の混合物に2〜3:1・の割合で混合したもの
を使用できる。In the present invention, the resin/cement mixed colored liquid containing inorganic particles contains a colored cement composition having the following composition and a diameter of 1.
.. Mix 5 to 0.1 mm of colored silica sand (same color as the colored cement composition) at a ratio of 1:1, and add a resin emulsion made by adding 65 parts of water to 100 parts of a water-dispersible resin, such as an acrylic resin, to the above mixture. A mixture at a ratio of 2 to 3:1 can be used.
着色セメント組成物の配合
シリカフラワー 7 部
ホワイトン 12 〃
セ メ ン ト 9 〃
シリカサンド 3 〃
石 綿 2 〃
顔 料 残 部
本発明において、未養生セメント成形品には、無機質発
泡骨材が多孔状態で含有されている。Compounding of colored cement composition Silica flour 7 parts Whiten 12 parts Cement 9 Silica sand 3 Asbestos 2 Pigment Rest In the present invention, the uncured cement molded product contains porous inorganic foam aggregate. contained in the state.
従って、樹脂・セメント混合着色液を吹付ければ、この
着色液が未養生セメント成形品の多孔表皮に含浸され、
この着色液中のセメント粒体が、養生時に、セメント成
形品の多孔組織に結合するため、耐剥離性に秀れた化粧
を施すことができる。Therefore, if a resin/cement mixed colored liquid is sprayed, this colored liquid will be impregnated into the porous skin of the uncured cement molded product.
Since the cement granules in this colored liquid bond to the porous structure of the cement molded product during curing, a cosmetic with excellent peeling resistance can be applied.
更に、本発明においては、予熱された未養生セメント成
形品に、粒体含有の樹脂・セメント混合着色液が吹付け
られるから、成形品表面に付着された着色液中の水分は
、即座に蒸発飛散され、付着液の粘度が増大されるため
、付着粒体の自重によるずれ落ちがなく、粒体を一様に
付着させ得る。Furthermore, in the present invention, since the resin/cement mixed colored liquid containing granules is sprayed onto the preheated uncured cement molded product, the water in the colored liquid that adheres to the surface of the molded product evaporates immediately. Since the particles are scattered and the viscosity of the adhering liquid is increased, the adhering particles do not fall off due to their own weight, and the particles can be evenly adhered.
従って、全体的に艶のない落着いた化粧を施し得る。Therefore, it is possible to apply makeup that is dull and subdued as a whole.
本発明において、未養生セメント成形品の予熱温度を4
0°〜70℃に限定する理由は、40℃以下では上記し
た水分の蒸発飛散に効果がなく、70℃以上では成形品
のセメントが急速に水和反応し、この水和反応に基づく
内部応力のために成形品にクラック発生する懸念がある
からである。In the present invention, the preheating temperature of the uncured cement molded product is set to 4
The reason for limiting the temperature to 0° to 70°C is that below 40°C there is no effect on the above-mentioned evaporation and scattering of moisture, and above 70°C the cement of the molded product undergoes a rapid hydration reaction, and internal stress due to this hydration reaction occurs. This is because there is a concern that cracks may occur in the molded product.
本発明において、成形品は、1日間の自然養生で一次養
生したのち、オートクレープにより最終養生される。In the present invention, the molded article is firstly cured by natural curing for one day, and then finally cured by autoclaving.
このオートクレープ養生は、通常、5〜8気圧の飽和水
蒸気で約10時間加熱することにより行われる。This autoclave curing is usually performed by heating with saturated steam at 5 to 8 atmospheres for about 10 hours.
このオートクレープの養生時に、成形品表面の付着液中
の樹脂が焼付けられ、化粧被膜の水密性が増大されると
共に、化粧被膜の耐剥離性がより一層に向上される。During this autoclave curing, the resin in the liquid adhering to the surface of the molded product is baked, increasing the watertightness of the decorative film and further improving the peeling resistance of the decorative film.
上述の説明から明らかなように、本発明によれば、セメ
ント製品に耐剥離性に秀れ、しかも全体的に落着いた耐
水密性の着色化粧を施すことができ、本発明は瓦特に棟
瓦の製造に極めて有用である。As is clear from the above description, according to the present invention, it is possible to apply a coloring to a cement product that has excellent peeling resistance and is water-tight overall. Extremely useful in manufacturing.
Claims (1)
直径1.5〜0.1mmの無機質粒体を含む、樹脂、セ
メント混合着色液を、上記予熱成形品の表面に吹付け、
而るのちに、成形品を養生することを特徴とする化粧セ
メント製品の製造方法。1 Preheat the uncured cement molded product to approximately 40° to 70°C,
Spraying a colored liquid mixed with resin and cement containing inorganic particles with a diameter of 1.5 to 0.1 mm onto the surface of the preheated molded product,
A method for producing a cosmetic cement product, which is characterized in that the molded product is then cured.
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51133339A JPS5811393B2 (en) | 1976-11-05 | 1976-11-05 | Manufacturing method for cosmetic cement products |
| NZ185576A NZ185576A (en) | 1976-11-05 | 1977-10-31 | Preparing cement product |
| NLAANVRAGE7712139,A NL176163C (en) | 1976-11-05 | 1977-11-03 | METHOD FOR MANUFACTURING A MOLDED CEMENT PRODUCT |
| US05/848,315 US4152168A (en) | 1976-11-05 | 1977-11-03 | Process for preparing cement product |
| FR7733309A FR2370010A1 (en) | 1976-11-05 | 1977-11-04 | PROCESS FOR THE PREPARATION OF CEMENT PRODUCTS AND NEW PRODUCTS THUS OBTAINED |
| DK491177A DK491177A (en) | 1976-11-05 | 1977-11-04 | T PROCEDURE FOR PRODUCING ARTICLES OF REINFORCED CEMEN |
| BE2056404A BE860465A (en) | 1976-11-05 | 1977-11-04 | PROCESS FOR PREPARING A CEMENT-BASED PRODUCT |
| AU30340/77A AU507144B2 (en) | 1976-11-05 | 1977-11-04 | Preparing cement product |
| DE2749432A DE2749432C3 (en) | 1976-11-05 | 1977-11-04 | Process for the manufacture of cement products and their use |
| GB46095/77A GB1590662A (en) | 1976-11-05 | 1977-11-04 | Process for preparing cement product |
| PH20405A PH15178A (en) | 1976-11-05 | 1977-11-08 | Process for preparing cement product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51133339A JPS5811393B2 (en) | 1976-11-05 | 1976-11-05 | Manufacturing method for cosmetic cement products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5357222A JPS5357222A (en) | 1978-05-24 |
| JPS5811393B2 true JPS5811393B2 (en) | 1983-03-02 |
Family
ID=15102395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51133339A Expired JPS5811393B2 (en) | 1976-11-05 | 1976-11-05 | Manufacturing method for cosmetic cement products |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS5811393B2 (en) |
| BE (1) | BE860465A (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5327735B2 (en) * | 1972-11-14 | 1978-08-10 |
-
1976
- 1976-11-05 JP JP51133339A patent/JPS5811393B2/en not_active Expired
-
1977
- 1977-11-04 BE BE2056404A patent/BE860465A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BE860465A (en) | 1978-03-01 |
| JPS5357222A (en) | 1978-05-24 |
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