JPS5838227B2 - High-speed dehydration treatment method and equipment for industrial waste - Google Patents
High-speed dehydration treatment method and equipment for industrial wasteInfo
- Publication number
- JPS5838227B2 JPS5838227B2 JP54096104A JP9610479A JPS5838227B2 JP S5838227 B2 JPS5838227 B2 JP S5838227B2 JP 54096104 A JP54096104 A JP 54096104A JP 9610479 A JP9610479 A JP 9610479A JP S5838227 B2 JPS5838227 B2 JP S5838227B2
- Authority
- JP
- Japan
- Prior art keywords
- industrial waste
- dehydration treatment
- speed dehydration
- shaped
- paddle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Fertilizers (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Description
【発明の詳細な説明】
本発明は有機質産業廃棄物(以下有機質産廃物と称する
)及び油脂系産業廃棄物(以下油脂系産廃物と称する)
を高速脱水処理剤に添加し、外部から熱を加えないで上
記産廃物中の肥料的戒分又は高カロリーエネルギーを損
うことな<100℃以下の温度で、これを撹拌すること
により直接脱水粉体化する高速脱水処理法とこの方法に
使用される連続式脱水処理装置に関連する。Detailed Description of the Invention The present invention deals with organic industrial waste (hereinafter referred to as organic industrial waste) and oil-based industrial waste (hereinafter referred to as oil-based industrial waste).
is added to a high-speed dehydration treatment agent, and the mixture is directly dehydrated by stirring at a temperature of <100℃ or less without applying heat from the outside and without damaging the fertilizer components or high-calorie energy in the industrial waste. It relates to a high-speed dehydration treatment method for pulverization and a continuous dehydration treatment device used in this method.
従来有機質産廃物についての水処理技術に基く無公害化
処理は、技術的に困難が多く、大量の水で希釈してこれ
を下水処理場に排出するか又は土中に埋没させている状
況である。Conventional decontamination treatment based on water treatment technology for organic industrial waste has been technically difficult, and it has been diluted with a large amount of water and then discharged to a sewage treatment plant or buried in the soil. be.
又油脂系産廃物も同様でアスファルテンナンバーが高い
にもかかわらず塩素、フェノール、有機溶媒等の混在の
ため熱量回収は困難で、該産廃物はそのまま焼却されて
いる。The same goes for oil and fat industrial waste, which is difficult to recover due to the presence of chlorine, phenol, organic solvents, etc., even though it has a high asphaltene number, and is therefore incinerated as is.
又豚糞、鶏糞については、昭和52年に公布された「石
灰処理肥料」にしたがって再資源化の方法が開発された
ものの生戒物は実質的には作られていない。Although methods for recycling pig manure and chicken manure have been developed in accordance with the ``lime-treated fertilizer'' promulgated in 1972, virtually no raw materials have been produced.
豚糞等を生石灰で脱水処理した場合、一瞬にして200
’l後の高温となるが、熱の持続性がなく、脱水効果は
低く、この高温によりアンモニア、燐酸の分解が生じ、
得られた生威物は肥料効果の乏しい強アルカリ性体とな
り、これは土質改良剤として使用することも困難である
。When pig manure, etc. is dehydrated with quicklime, 200
Although the temperature is high after 'l, the heat is not sustainable and the dehydration effect is low.This high temperature causes the decomposition of ammonia and phosphoric acid.
The resulting biomass becomes a strongly alkaline substance with poor fertilizer effect, making it difficult to use as a soil conditioner.
上記のものは、固形分が少くとも40饅以上で、外観的
に流動性の乏しい状態のものか又は水分の少いスラツジ
状のものに対してのみ有効であって醗酵(醸造)産廃物
のように液状のものには適用できない。The above products are effective only for products with a solid content of at least 40 moss or more and poor fluidity in appearance or sludge-like products with little moisture, and are effective only for fermentation (brewing) waste products. It cannot be applied to liquid substances.
本発明の目的は、有機質産廃物及び油脂系産廃物を粉末
生石灰等からなる高速脱水処理剤に添加し、有効成分を
損うことなく100℃以下の温度でこれを撹拌すること
により直接脱水処理が行われて低水分量の粉体に変換す
る産業廃棄物の高速脱水処理法とこの方法に使用される
連続式脱水処理装置を提供することにある
本発明の高速脱水処理法とその装置は、有機質産廃物及
び油脂系産廃物を、粉末生石灰、珪酸苦土石灰、炭酸石
灰、滑石粉及び中性陶土からなる高速脱水処理剤に添加
し、有効或分を損うことなく100℃以下の温度で、こ
れを撹拌することにより直接脱水処理が行われて肥料的
要素のあるかつほぼ中性の低水分土質改良剤又は高カロ
リーの粉体或は戊型化燃料に変換するものである。The purpose of the present invention is to directly dehydrate organic industrial waste and oil-based industrial waste by adding it to a high-speed dehydrating agent made of powdered quicklime, etc., and stirring it at a temperature of 100°C or less without damaging the active ingredients. The purpose of the present invention is to provide a high-speed dehydration treatment method for industrial waste that converts it into powder with a low moisture content, and a continuous dehydration treatment device for use in this method. , organic industrial wastes and oil-based industrial wastes are added to a high-speed dehydration treatment agent consisting of powdered quicklime, magnesium silicate lime, carbonated lime, talc powder, and neutral china clay, and then heated at 100°C or less without losing effectiveness. It is directly dehydrated by stirring at high temperature and converted into a nearly neutral, low-moisture soil conditioner with fertilizer elements, or into a high-calorie powder or molten fuel.
本発明の実施に使用する高速脱水処理剤は、粉末生石灰
53.0〜71.0重量饅、珪酸苦土石灰6.0〜13
.3重量φ、炭酸石灰17.3〜24.0重量饅、滑石
粉4,0〜6.0重量饅及び中性陶土2.3〜3.2重
量φを混合撹拌し、混合中に生じる粉末生石灰と珪酸苦
土石灰との発熱反応を滑石粉により抑制し、又二次的に
生じる可能性のある炭酸石灰の熱分解を中性陶土で防止
しつつ混合物の色相が均一になるまで混合を続けたもの
である。The high-speed dehydration treatment agent used in the implementation of the present invention includes powdered quicklime 53.0 to 71.0% by weight and silicate magnesium lime 6.0 to 13% by weight.
.. 3 weight φ, carbonate lime 17.3 to 24.0 weight cake, talc powder 4.0 to 6.0 weight cake, and neutral china clay 2.3 to 3.2 weight φ are mixed and stirred, and the powder produced during mixing is The exothermic reaction between quicklime and silicate lime is suppressed by talcum powder, and neutral china clay prevents thermal decomposition of carbonate lime that may occur as a secondary product, while mixing until the mixture becomes uniform in hue. It continued.
又この高速脱水処理剤を専一的に使用する連続式脱水処
理装置は、添付図面の第1図に示すように、一部を重複
した並列二円の断面を有し、ほぼ水平に配置された横方
向に長い反応筒1、可変速モータに連結された主回転軸
によって駆動されかつ反応筒内に架設される並列平行の
撹拌軸2、高速脱水処理剤用定量フイーダ3、産業廃棄
物用定量フイーダ4、水添加機構5、予熱・保温板6及
び排ガス除去装置7で構成さ札連続的に有機質及び油脂
系の産業廃棄物を脱水処理するため上記反応筒の内部は
6区域に区分され、該撹拌軸は二輪式でそれぞれ反応筒
の中心に向かって逆方向に回転し、第I区域にスクリュ
ー形、第■区域に楔形、第■区域にパドル形とパドルバ
ー形、第■区区域に楔形、第■区域にパドル形とパドル
バー形及び第■区域に楔形の各羽根即ちブレードを設け
ている。Furthermore, as shown in Figure 1 of the attached drawings, the continuous dehydration treatment equipment that exclusively uses this high-speed dehydration treatment agent has a cross section of two parallel circles with partially overlapping parts, and is arranged almost horizontally. a horizontally long reaction tube 1, a parallel stirring shaft 2 driven by a main rotating shaft connected to a variable speed motor and installed inside the reaction tube, a quantitative feeder 3 for high-speed dehydration treatment agent, and a metering feeder 3 for industrial waste. Consisting of a metering feeder 4, a water addition mechanism 5, a preheating/warming plate 6, and an exhaust gas removal device 7, the interior of the reaction tube is divided into six zones to continuously dehydrate organic and oil-based industrial waste. , the stirring shaft is a two-wheeled type that rotates in opposite directions toward the center of the reaction tube, and has a screw shape in the I section, a wedge shape in the II section, a paddle shape and a paddle bar shape in the I section, and a paddle shape and a paddle bar shape in the I section. Wedge-shaped blades, paddle-shaped and paddle-bar-shaped blades are provided in the first area, and wedge-shaped blades are provided in the second area.
撹拌軸2の回転速度は80〜1 2 0 [9@で、物
性の異なる各産業廃棄物と高速脱水処理剤との間で生じ
る反応速度差に対応できるように、この回転速度には可
変機構が採用されている。The rotational speed of the stirring shaft 2 is 80 to 120[9@], and a variable mechanism is used for this rotational speed to accommodate the difference in reaction rate that occurs between industrial wastes with different physical properties and high-speed dehydration treatment agents. has been adopted.
高速脱水処理剤用定量フイーダ3は一般的な粉体フイー
ダで、産業廃棄物用定量フイーダ4は産業廃棄物の性状
に適応するポンプ又はスクリューコンベアを使用する。The metering feeder 3 for high-speed dehydration treatment agent is a general powder feeder, and the metering feeder 4 for industrial waste uses a pump or screw conveyor adapted to the properties of the industrial waste.
両フイーダ共手動操作は可能であるが、実施例では撹拌
軸2の回転に同調した機構が採用されている。Both feeders can be operated manually, but in this embodiment a mechanism synchronized with the rotation of the stirring shaft 2 is adopted.
産業廃棄物の表面張力が大きい場合には高速脱水処理剤
は微粉末で脱水反応開始にやや時間を要するから該装置
を正常作動させるため、反応開始に先立ち微量の水を添
加して強制的に反応を進ませるもので、水添加機構5に
よる水は反応開始剤として働く。When the surface tension of industrial waste is high, the high-speed dehydration treatment agent is a fine powder and takes some time to start the dehydration reaction, so in order to make the device work properly, a small amount of water is forcibly added prior to the start of the reaction. The water from the water addition mechanism 5 acts as a reaction initiator to advance the reaction.
表面張力の小さい産業廃棄物の場合には水の添加は不要
である。In the case of industrial waste having a low surface tension, it is not necessary to add water.
予熱・保温板6は、外気温度の低い場合低温度の反応筒
1を、ニクロム線等で一部分予熱して正常な反応処理を
行わせるもので、発熱を外部に放散させないように保温
板をも業ねでいる。The preheating/thermal insulating plate 6 is used to partially preheat the low temperature reaction tube 1 with a nichrome wire or the like when the outside air temperature is low to allow normal reaction processing. I'm at work.
なおこの装置が正常な脱水処理操作を開始した後は予熱
を停止する。Note that after this device starts normal dehydration processing operations, preheating is stopped.
次に本発明による連続式高速脱水処理装置の操作を説明
する。Next, the operation of the continuous high-speed dehydration treatment apparatus according to the present invention will be explained.
まず予熱・保温板6のヒータに通電し、サーモスタット
を90〜100℃に設定する。First, the heater of the preheating/warming plate 6 is energized, and the thermostat is set to 90 to 100°C.
次に撹拌軸2を時々回転して予熱による熱効率を高め、
サーモスタットが完全に作動する状態に到達したことを
確認した後、予備試験で決定した高速脱水処理剤の毎分
当りの所要量とそれに対応する産業廃棄物の毎分当りの
添加量をそれぞれのフイーダに設定する。Next, the stirring shaft 2 is rotated from time to time to increase thermal efficiency by preheating.
After confirming that the thermostat has reached a state where it is fully operational, the required amount of high-speed dehydration treatment agent per minute and the corresponding amount of industrial waste to be added per minute determined in the preliminary test are added to each feeder. Set to .
次いで撹拌軸2を回転して高速脱水処理剤用フイーダ3
を運転し、高速脱水処理剤を第1区域の該処理剤投入口
に定量供給する。Next, the stirring shaft 2 is rotated to feeder 3 for high-speed dehydration treatment agent.
is operated to supply a fixed amount of the high-speed dehydration treatment agent to the treatment agent input port in the first zone.
この供給開始1/2〜1.0分後に高速脱水処理剤供給
量の3〜5多相当量の水を添加して発熱させ、所要温度
に到達した後は予熱と水添加を停止する。After 1/2 to 1.0 minutes from the start of this supply, an amount of water equivalent to 3 to 5 times the supply amount of the rapid dehydration treatment agent is added to generate heat, and after reaching the required temperature, preheating and water addition are stopped.
次に高速脱水処理剤供給後1.0〜2.0分の間に産業
廃棄物用フイーダ4より産業物を第■区域に投与して処
理中の混合物の外観が絶えずペースト状を呈するように
する。Next, during 1.0 to 2.0 minutes after the high-speed dehydration treatment agent is supplied, the industrial material is administered from the industrial waste feeder 4 to the area (ii) so that the appearance of the mixture being treated is constantly paste-like. do.
この間の状態は、産廃物と高速脱水処理剤との練り合わ
せが均一に行われかつ物理的な発熱による余剰水分の蒸
発が行われる。In this state, the industrial waste and the high-speed dehydration treatment agent are uniformly kneaded, and excess water is evaporated by physical heat generation.
次いで被処理物は次のパドルブレードを取り付けた第■
区域に送られ、ここでパドル形の羽根及びパドルバー形
の羽根の回転による協力関係により上記ペースF状物を
強力にせん断撹拌して後述の初期反応を発生させつつ、
次の第■区域の練り合せ部分に送り、そこで再び産廃物
を投与して未反応状態で残留している高速脱水処理剤と
反応させる。Next, the object to be processed is transferred to the second paddle blade equipped with the next paddle blade.
The Pace F-like material is sent to the area, where it is strongly sheared and agitated by the rotation of paddle-shaped blades and paddle-bar-shaped blades to generate the initial reaction described below.
It is sent to the next kneading section in zone (1), where industrial waste is again administered to react with the high-speed dehydration treatment agent remaining in an unreacted state.
更に後方の第V区域のパドルブレード部分でこれを再び
撹拌して脱水反応させ、第■区域では更に完全な撹拌混
合を行い再質源化利用に活用できる適当なサイズ、列え
は胡麻粒ないし鋺豆程度の小粒状又は塊状の固形物とし
て排出口から排出させる。Further, in the paddle blade part of the rear section V, this is stirred again to cause a dehydration reaction, and in the section II, it is further stirred and mixed completely, and the appropriate size and arrangement for recycling use is made of sesame seeds or sesame seeds. It is discharged from the outlet as small granular or lump-like solids about the size of peas.
この排出物は水分40〜50%で50〜60℃の温度を
有し、放冷すると排出物の水分は30〜40%になる。This discharge has a moisture content of 40-50% and a temperature of 50-60°C, and when left to cool, the moisture content of the discharge becomes 30-40%.
なお第■ないし■区域の羽根には高速脱水処理剤と産廃
物との混合物を後方に進めるようにそれぞれテーパを設
けるとよい。Incidentally, it is preferable that the blades in the sections (1) to (2) be provided with a taper so that the mixture of the high-speed dehydration treatment agent and the industrial waste is advanced backward.
この処理間における反応温度の経時変化を第5図に示す
。FIG. 5 shows the change in reaction temperature over time during this treatment.
最初水の添加でほぼ90℃前後に昇温し、産廃物の投与
で該処理物の温度は急速に50〜60℃に下降し、パド
ルブレード部分に移行後実質的脱水反応により再び昇温
する。Initially, the temperature of the treated material rises to around 90°C with the addition of water, then the temperature of the treated material rapidly drops to 50-60°C with the administration of industrial waste, and after moving to the paddle blade section, the temperature rises again due to a substantial dehydration reaction. .
この時2次産廃物投与時点を遅くしたり又は投与量を少
量にした場合には、被処理物の温度が100℃以上にな
り有効戒分の熱分解を生ずる。At this time, if the timing of administering the secondary waste is delayed or the dose is reduced, the temperature of the material to be treated will exceed 100° C., causing thermal decomposition of the effective precepts.
第1図の高速脱水処理装置では、産廃物の種類・性状に
より練り合せ用の楔形羽根の代りに丁字形又はL形の撹
拌ブレードを組合せて使用してもよい。In the high-speed dehydration treatment apparatus shown in FIG. 1, a T-shaped or L-shaped stirring blade may be used in place of the wedge-shaped kneading blade depending on the type and properties of the industrial waste.
又概知の同一形状の羽根を有する撹拌機、例えばスクリ
ュー形のものだけでは発熱反応は発生せず直ちに泥漿化
する。Further, if a known stirrer having blades of the same shape, for example, a screw type stirrer is used alone, no exothermic reaction occurs and the mixture immediately turns into a slurry.
又パドルブレードだけでは発熱反応及びそれに続く反応
は生じるも100℃以上の高温となり、有効戒分の熱分
解が生じ副生した処理物の再資源化利用が困難となる。Furthermore, although an exothermic reaction and subsequent reactions occur when only the paddle blade is used, the temperature reaches a high temperature of 100° C. or higher, resulting in thermal decomposition of effective precepts and making it difficult to recycle and utilize by-products.
又楔形の羽根だけでは、正常な反応が発生するも高速脱
水処理剤の使用比は30%以下におさえることができず
、処理済物の水分匍脚が困難である。Furthermore, although a normal reaction occurs using only wedge-shaped blades, the ratio of high-speed dehydration treatment agent used cannot be kept below 30%, making it difficult to retain water in the treated product.
なお丁字形又はL字形ブレードにおいても同様な結果を
生じる。Note that similar results occur with T-shaped or L-shaped blades.
本発明による4種の羽根即ちブレードの組合わせにおい
て、例えばスクリュー形の羽根を欠いた場合には高速脱
水処理剤の送り込みとその予備混合が充分に行われない
し、又楔形の羽根を欠いた場合には高速脱水処理剤と産
業廃棄物の練り合わせが充分に行われず、更にパドル形
の羽根を欠いた場合にはパドルバー形の羽根の協力が得
られないから高速脱水処理剤と産業廃棄物とが練り合わ
されたペースト状物を強力にせん断撹拌することができ
ないし、なおパドルバー形の羽根を欠いた場合にも同様
に上記ペースト状物を強力にせん断撹拌することができ
ないのである。In the combination of the four types of impellers or blades according to the present invention, for example, if the screw-shaped impeller is missing, the feeding and premixing of the high-speed dehydration agent cannot be carried out sufficiently, and if the wedge-shaped impeller is missing, In this case, the high-speed dehydration agent and industrial waste are not sufficiently mixed together, and if the paddle-shaped blades are missing, the cooperation of the paddle-bar-shaped blades cannot be obtained. The kneaded paste cannot be strongly sheared and stirred, and even if the paddle bar-shaped blades are missing, the paste cannot be strongly sheared and stirred.
従って本発明の装置はそれぞれ形状の異なったブレード
を同一撹拌軸上に取り付け、それぞれのブレードの特徴
を発揮させることによって高速脱水処理剤の供給量を低
率化し、100℃以下の温度で産廃物をほぼ均一の状態
で脱水粉体化するものである。Therefore, the device of the present invention has blades of different shapes mounted on the same stirring shaft, and by utilizing the characteristics of each blade, the supply rate of high-speed dehydration treatment agent can be reduced, and industrial waste can be removed at a temperature of 100°C or less. This process dehydrates and turns into a powder in a nearly uniform state.
又これにより本発明の装置は産廃物が液体、固体、流動
体等倒れの形態を示すものでもこれを均一的な粉体に変
換して再資源化する方法を実施する唯一の装置である。Furthermore, the apparatus of the present invention is the only apparatus that can carry out a method of recycling industrial waste by converting it into uniform powder even if it is in a collapsed form such as liquid, solid, or fluid.
次に産廃物と高速脱水処理剤とを適切な撹拌作用のもと
で、正常な脱水反応が行われる場合に、ガスクロマトグ
ラフィー及び赤外線吸収スペクトル法による反応状態の
分析結果から反応過程は下記のように推定される。Next, when a normal dehydration reaction occurs between the industrial waste and the high-speed dehydration treatment agent under appropriate stirring action, the reaction process is determined as follows based on the analysis results of the reaction state by gas chromatography and infrared absorption spectroscopy. It is estimated that
第5図において経過時間O〜4.5分と4.5〜10分
とでは化学反応的には基本的に類似であるが発熱温度に
若干の差異がある。In FIG. 5, the chemical reaction is basically similar between the elapsed times of 0~4.5 minutes and 4.5~10 minutes, but there is a slight difference in the exothermic temperature.
図中Wは水添加時点、Mは産廃物添加時点を示し、数字
は添加の順序を示す。In the figure, W indicates the time point of water addition, M indicates the time point of industrial waste addition, and the numbers indicate the order of addition.
初期反応
第5図においてO〜1.1/29間にほぼ初期反応が完
了する。Initial reaction In FIG. 5, the initial reaction is almost completed between 0 and 1.1/29.
最初高速脱水処理剤に微量の水を添加すると短時間にほ
ぼ90℃±5℃に昇温し、それに伴って珪酸苦土石灰、
滑石粉、中性陶土の相互反応で擬似シラノール体が生成
する。When a small amount of water is initially added to the high-speed dehydration treatment agent, the temperature rises to approximately 90°C ± 5°C in a short time, and as a result, silicate lime,
Pseudo-silanol bodies are generated by the interaction of talcum powder and neutral china clay.
これに産廃物を投与すると、産廃物中に存在するアルキ
ル化合物、塩素化合物等からアルキル基、塩素を選択的
に分子吸着の形で取り入れ、オルガノアルキルシラノー
ル又はオルガノクロルシラノールが生或する。When industrial waste is administered to this, alkyl groups and chlorine are selectively absorbed from alkyl compounds, chlorine compounds, etc. present in the industrial waste in the form of molecular adsorption, and organoalkylsilanol or organochlorosilanol is produced.
このオルガノアルキルシラノール等がオルガノアルキル
モノシロキサン等に変換し、更にアルカリ領域及び高温
高湿下で縮合してオルガノアルキルポリシロキサン又は
オルガノクロルポリシロキサンが生成する。This organoalkylsilanol and the like are converted into organoalkylmonosiloxane and the like, and further condensed in an alkaline region and under high temperature and high humidity to produce organoalkylpolysiloxane or organochloropolysiloxane.
概ねオルガノアルキルモノシロキサンに変換後、約1.
1/2〜3分の間にオルガノアルキルポリシロキサンの
生成が完了する。Approximately after conversion to organoalkylmonosiloxane, approximately 1.
The formation of organoalkylpolysiloxane is completed within 1/2 to 3 minutes.
又各種化合物の二重結合の切断、開環反応等が行われる
。Also, cleavage of double bonds of various compounds, ring-opening reactions, etc. are performed.
終未反応
オルガノアルキルポリシロキサン又はオルガノクロルポ
リシロキサンの構造は立体的な格子状で、初期反応で単
量体に分解した産廃物中の元素及び七ノマーは上記オル
ガノポリシロキサンに対しイオン交換吸着や非イオン体
の分子吸着が生じ、この結果被吸着物の表面帯電状態が
変わり、これに伴って再結合、再解離が活発化して凝集
状態が現1
われる。The structure of the final unreacted organoalkylpolysiloxane or organochloropolysiloxane is a three-dimensional lattice-like structure, and the elements and heptamers in the industrial waste decomposed into monomers in the initial reaction are ion-exchange adsorbed and absorbed by the organopolysiloxane. Molecule adsorption of nonionic substances occurs, and as a result, the surface charge state of the adsorbed substance changes, and as a result, recombination and redissociation become active, resulting in an agglomerated state.
この反応は1〜17分間でほぼ完了する。他方、過剰に
存在させた珪酸苦土石灰は上記反応にもかかわらず、カ
ルシウム、アルミニウム、マグネシウムと反応してコロ
イダルカルシウム、コロイダルアルミン酸、コロイダル
マグネシウムを生威し、これらはゲーレナイト水和物(
Ca2A l O a S t 0 2・6H20)
に変換する。This reaction is almost complete in 1-17 minutes. On the other hand, despite the above-mentioned reaction, the excessively present magnesium silicate reacts with calcium, aluminum, and magnesium to produce colloidal calcium, colloidal aluminate, and colloidal magnesium, which form gehlenite hydrate (
Ca2A l O a S t 0 2・6H20)
Convert to
更に反応が進むとゲーレナイト水和物は次第に水分を消
失し、即ちポゾラン反応を生じて水に不溶性の固い粒子
に変わるが、過剰に存在する炭酸石灰で水に不溶性には
ならず水に遅溶性の粒子になる。As the reaction progresses further, Gehlenite hydrate gradually loses its water content, causing a pozzolanic reaction and turning into hard particles that are insoluble in water. However, due to the excessive presence of lime carbonate, it does not become insoluble in water, but becomes slowly soluble in water. particles.
このゲーレナイト水和物の生成反応は初期反応の後段で
は発生しないが終末反応の後段のみに見出される。This gehlenite hydrate formation reaction does not occur after the initial reaction, but is found only after the final reaction.
第5図においてゲーレナイト水和物の生或反応は1 経過時間87〜10分の間に活発に行われる。In Figure 5, the production or reaction of gehlenite hydrate is 1 It is active during the elapsed time of 87 to 10 minutes.
本発明の装置は、高速脱水処理剤に産廃物を投与して混
合撹拌し、100℃以下の温度で主として化学反応でこ
れを強力に脱水固化し、産廃物の原体より溶積・重量共
に著しく減少した低水分量の粉体又は塊状物に変換する
装置である。The apparatus of the present invention mixes and stirs industrial waste by adding it to a high-speed dehydration treatment agent, and strongly dehydrates and solidifies it mainly through a chemical reaction at a temperature of 100 degrees Celsius or less. Equipment for converting into powders or agglomerates with significantly reduced moisture content.
公知の混合・撹拌装置では、上記の高速脱水処理剤を使
用しても産廃物を低水分量の粉体又は塊状物に変換でき
ず、単に流動物質にしか変換できゅ1ない。In the known mixing/stirring apparatus, even if the above-mentioned high-speed dehydration treatment agent is used, industrial waste cannot be converted into powder or lumps with a low moisture content, but only into a fluid substance.
これは公知の機械装置が物理的な観点から構或されたも
ので、時間の経過と共に変化する立体化学的反応に対応
できない結果を示すものである。This is due to the fact that the known mechanical devices are constructed from a physical point of view and cannot accommodate stereochemical reactions that change over time.
本発明の装置のように、形状の全く異なった撹拌羽根が
反応所要時間に基づいた流量に対応する長さで取り付け
られ、各区域で生じる立体化学的反応に適確に対応でき
る機能を有することになって始めて脱水処理が行われて
産廃物を粉体又は塊状物に固化できるものである。Like the device of the present invention, stirring blades with completely different shapes are installed at lengths that correspond to the flow rates based on the reaction time, and have the ability to appropriately respond to stereochemical reactions occurring in each zone. Only then can dehydration treatment be performed to solidify the industrial waste into powder or lumps.
又本装置の撹拌羽根の形状・配列方法は、高速脱水処理
剤と産廃物との反応で生じる100℃以上の温度を10
0℃以下に抑える作用をも併せ持っており、この結果反
応時間が長くなり、90〜60℃での処理が可能となり
、産廃物中のアンモニア、燐酸、カリウム塩の分解が大
部分阻止され、処理済生成物に上記3或分を多量に包含
させることが可能となり、これら威分が緩かに水に溶出
するので、該処理済生戒物は土質改良剤として利用でき
る。In addition, the shape and arrangement of the stirring blades of this device is such that the temperature of 100°C or more generated by the reaction between the high-speed dehydration treatment agent and industrial waste can be controlled by 10°C.
It also has the effect of keeping the temperature below 0°C, resulting in a longer reaction time and processing at 90 to 60°C, which largely prevents the decomposition of ammonia, phosphoric acid, and potassium salts in industrial waste. Since the treated product can contain a large amount of the above three components and these components are slowly eluted into water, the treated raw material can be used as a soil conditioner.
なお、油泥又は油処理産廃物は粉体化の上、加圧或型し
て固形燃料とし、含有高エネルギーを再質源化すること
が可能である。Note that oil sludge or oil processing waste can be pulverized and pressurized to form a solid fuel, and the high energy content can be recycled as a regenerating source.
以下実施例によって本発明の前記組或の高速脱水処理剤
と上記連続式高速脱水装置を使用し、産廃物を脱水処理
して再資源化利用に可能な粉体又は塊状物に変換した方
法を説明する。The following examples describe a method of dehydrating industrial waste and converting it into powder or lumps that can be recycled using the above-mentioned high-speed dehydration treatment agent of the present invention and the above-mentioned continuous high-speed dehydration apparatus. explain.
実施例 1
(1)被処理産廃物
豚舎排泄物で、豚毛、石、藁屑を事前に除去し、希釈酸
でpH5.0に調整した。Example 1 (1) Industrial waste to be treated Pig house excrement, pig hair, stones, and straw waste were removed in advance, and the pH was adjusted to 5.0 with diluted acid.
処理前の排泄物の性状は次の通りである。The properties of the excrement before treatment are as follows.
(2)脱水処理方法 第1図の装置を使用した。(2) Dehydration treatment method The apparatus shown in Figure 1 was used.
脱水処理方法は各実施例共同じである。The dehydration treatment method was the same in each example.
■予熱・保温板6に通電し、90±5℃にセットしたサ
ーモスタットの作動を確認した後、■撹拌軸2を回転し
、投入口より2kgの高速脱水処理剤を供給し、水10
0mlを加えそ予備発熱を行って約10分経過後発熱し
た粉体を排出する。■ After energizing the preheating/warming plate 6 and confirming the operation of the thermostat set at 90±5°C, ■ rotate the stirring shaft 2, feed 2 kg of high-speed dehydration treatment agent from the inlet, and add 10 kg of water.
Add 0 ml of powder, generate preliminary heat, and discharge the heated powder after about 10 minutes.
■0.4kg/分の供給量を設定した高速脱水処理剤用
定量フイーダ3を駆動して撹拌軸2の基部に上記処理剤
を供給しつつ5分後に、定時間を区切って被処理産廃物
の投与量を順次増加し、40分後に正規投与量とし、そ
の間を調整期間とした。■ Drive the quantitative feeder 3 for high-speed dehydration treatment agent with a supply rate of 0.4 kg/min, and feed the above treatment agent to the base of the stirring shaft 2. After 5 minutes, the industrial waste to be treated is The dosage was increased sequentially, and the regular dosage was reached after 40 minutes, and the period in between was an adjustment period.
その後産廃物用定量フイーダの投与量を正しく設定して
30分間運転をし、その間に処理した生戒物を対象試料
とした。Thereafter, the dosage of the quantitative feeder for industrial waste was set correctly and the feeder was operated for 30 minutes, and the raw materials processed during that time were used as the target sample.
(3)処理結果
測定条件
処理直後の得られた生或物はほぼ60〜65℃の温度を
有し、風乾で常温とした後試験測定した。(3) Conditions for measuring treatment results The raw material obtained immediately after treatment had a temperature of about 60 to 65°C, and was air-dried to room temperature before being tested and measured.
■ 豚糞尿投与量 1 1 5kg/3 0分
立☆■
■
高速脱水処理剤供給量 12kg/30分(対産廃物
比10.4%)
処理済生或物
(4)処理中の経時温度分布は第6図に示すとおりであ
る。■ Amount of pig manure and urine administered 1 1 5 kg/30 minutes ☆ ■ ■ Amount of high-speed dehydration treatment agent supplied 12 kg/30 minutes (ratio to industrial waste: 10.4%) Treated product (4) Temperature distribution over time during treatment As shown in Figure 6.
実施例 2 ※※(
1)被処理産廃物
アルコール醗酵残液で、
である。Example 2 ※※(
1) The industrial waste to be treated is alcohol fermentation residual liquid, which is as follows.
その性状は次の通り (2) (3) 脱水処理方法 実施飼1の(2)脱水処理方法と同様に行う。Its properties are as follows (2) (3) Dehydration treatment method The same procedure as (2) dehydration treatment method in Experiment 1 is carried out.
処理結果 測定条件 実施例1の(3)測定条件と同じ。Processing result Measurement conditions Same as (3) measurement conditions of Example 1.
◇ ■ アルコーノレ醗酵残液投与量 1 2 5kv
3 0分■ 高速脱水処理剤供給量 1 2.0kg
/3 0分(対産廃物比9.6饅)
■ 処理済生或物
(4)処理中の経時温度分布は第7図に示すとおりであ
る。◇ ■ Alcohol fermentation residual liquid dosage 1 2 5 kv
3 0 minutes ■ High-speed dehydration treatment agent supply amount 1 2.0 kg
/30 minutes (ratio to industrial waste: 9.6 rice cakes) ■ Treated raw materials (4) The temperature distribution over time during treatment is as shown in Figure 7.
実施例 3 **(1
)被処理産廃物
魚類加工により生じる油脂状の流動体で、の性状は次の
通りである。Example 3 **(1
) It is an oil-like fluid produced by processing industrial waste fish, and its properties are as follows.
そ (2) (3) 脱水処理方法 実施例1の(2)脱水処理方法と同様に行う。So (2) (3) Dehydration treatment method It is carried out in the same manner as (2) dehydration treatment method of Example 1.
処理結果 測定条件 実施例1の(3)測定条件と同じ。Processing result Measurement conditions Same as (3) measurement conditions of Example 1.
豪 [F] 油脂状流動体投与量 9 2.6kg/3
0分■ 高速脱水処理剤供給量1 2.0 kg/3
0分(対産廃物比12.9係)
■ 処理済生成物
(4)処理中の経時温度分布は第8図に示す通りである
。Australia [F] Oily fluid dosage 9 2.6kg/3
0 minutes ■ High-speed dehydration treatment agent supply amount 1 2.0 kg/3
0 minutes (ratio to industrial waste: 12.9) ■ Treated product (4) The temperature distribution over time during treatment is as shown in Figure 8.
実施例 4 米(1)
被処理産廃物
米
屠殺場で発生する血液、解体内臓産廃物、その他雑混合
物を高速カッターですりつぶしたペースト状のもので、
その性状は次の通りである。Example 4 Rice (1)
Industrial waste to be processed A paste made by grinding blood, disassembled internal organs, and other miscellaneous mixtures generated at American slaughterhouses using a high-speed cutter.
Its properties are as follows.
(2) (3) 脱水処理方法 実施例1の(2)脱水処理方法と同様に行う。(2) (3) Dehydration treatment method It is carried out in the same manner as (2) dehydration treatment method of Example 1.
処理結果 測定条件 実酒例1の(3)測定条件と同じ。Processing result Measurement conditions: Same as measurement conditions (3) in Sake Example 1.
■ 解体混合産廃物供給量 85.0kg730分■
高速脱水処理剤供給量 1 2.0 kg/3− 0分
(4)処理中の経時温度分布は第9図に示す通りである
。■Demolition mixed industrial waste supply amount 85.0kg730 minutes■
Quantity of high-speed dehydration treatment agent supplied: 12.0 kg/3-0 minutes (4) Temperature distribution over time during treatment is as shown in FIG.
実施例 5 **(
1)
被処理産廃物
生床尿、その性状は次の通りである。Example 5 **(
1) The properties of the industrial waste raw urine to be treated are as follows.
(2) (3) 脱水処理方法 実施例1の(2)脱水処理方法と同様に行う。(2) (3) Dehydration treatment method It is carried out in the same manner as (2) dehydration treatment method of Example 1.
処理結果 測定条件 実施例1の(3)測定条件と同じ。Processing result Measurement conditions Same as (3) measurement conditions of Example 1.
※
※ ■ 生尿尿供給量 98.7kg/30分
■ 高速脱水処理剤供給量 1 2.0kg/3 0分
(対産廃物比 12.2饅)
■ 処理済生或物
(4)処理中の経時温度分布は第10図に示す通りであ
る。* * ■ Amount of raw urine supplied: 98.7 kg/30 minutes ■ Amount of high-speed dehydration treatment agent supplied: 1 2.0 kg/30 minutes (ratio to industrial waste: 12.2 rice cakes) ■ Processed raw materials (4) Under processing The temperature distribution over time is as shown in FIG.
実施例 6
(1)被処理産廃物
油脂精製に使用した廃白土の大塊状のものをコーヒーミ
ルで小塊状に粗砕したもので、その性状は次の通りであ
る。Example 6 (1) Industrial waste to be treated A large lump of waste clay used for refining oils and fats was crushed into small lumps using a coffee mill, and its properties are as follows.
(2)脱水処理方法 実施例1の(2)脱水処理方法と同様に行う。(2) Dehydration treatment method It is carried out in the same manner as (2) dehydration treatment method of Example 1.
(3)処理結果 測定条件 実施例1の(3)測定条件と同じ。(3) Processing results Measurement conditions Same as (3) measurement conditions of Example 1.
[F] 廃白土供給量 89.0kg/30分
■ 高速脱水処理剤供給量 12.0kg/30分(対
産廃物比13.5%)
■ 処理済生或物
(4)処理中の経時温度分布は第1
である。[F] Amount of waste clay supplied: 89.0 kg/30 minutes ■ Amount of high-speed dehydration treatment agent supplied: 12.0 kg/30 minutes (ratio to industrial waste: 13.5%) ■ Treated raw material (4) Temperature over time during treatment The distribution is first.
実施例 7
(1)被処理産廃物
1図に示す通り
原油貯槽の基部に沈積したオイルスラッジ中ゲル化を呈
したものと土砂等との微流動性混合体体で、その性状は
次の通りである。Example 7 (1) Industrial waste to be treated As shown in Figure 1, it is a microfluidic mixture of gelled oil sludge deposited at the base of a crude oil storage tank and earth and sand, and its properties are as follows. It is.
(2)脱水処理方法 実施例1の(2)脱水処理方法と同様に行う。(2) Dehydration treatment method It is carried out in the same manner as (2) dehydration treatment method of Example 1.
(3)処理結果 測定条件 実施例1枢3)測定条件と同じ。(3) Processing results Measurement conditions Same as Example 1 (3) Measurement conditions.
■ 産廃物供給量 1 2 2.0kg/3 0
分■ 高速脱水処理剤供給量 1 2.0 kg/3
0分(対産廃物比 饅9.8饅)
■ 処理済生成物
(4)処理中の経時温度分布は第12図に示す通りであ
る。■ Industrial waste supply amount 1 2 2.0kg/3 0
Minutes ■ High-speed dehydration treatment agent supply amount 1 2.0 kg/3
0 minutes (ratio to industrial waste: 9.8 rice cakes) ■ Treated product (4) The temperature distribution over time during treatment is as shown in FIG.
実施例 8
(1) 被処理産廃物
味噌・醤油製造残渣にして流動性に富んだ特有臭気を持
つ汚泥で、その性状は次の通りである。Example 8 (1) Industrial waste to be treated A sludge that is the residue of miso and soy sauce production and is highly fluid and has a unique odor. Its properties are as follows.
(2) (3) 脱水処理方法 実施1の(2)脱水処理方法と同様に行う。(2) (3) Dehydration treatment method It is carried out in the same manner as (2) dehydration treatment method of Example 1.
処理結果 測定条件 実施例1の(3)測定条件と同じ。Processing result Measurement conditions Same as (3) measurement conditions of Example 1.
*■ 産廃物供給量 88.5kg/30分■
高速脱水処理剤供給量 1 2.0kg/3 0分(
対産廃物比 l3.6俸)
■ 処理済生戒物
(4)処理中の経時温度分布は第1
である。*■ Industrial waste supply amount 88.5 kg/30 minutes■
High-speed dehydration treatment agent supply amount 1 2.0 kg/3 0 minutes (
(Ratio to industrial waste: 13.6 yen) ■ Processed raw materials (4) Temperature distribution over time during processing is the first.
実施例 9
(1)被処理産廃物
3図に示す通り
ワ
集塵機により収積されたダストで各種塩類、カーボン及
び油脂類を含んだ粉体で、その性状は次の通りである。Example 9 (1) Industrial waste to be treated 3 As shown in Figure 3, it is dust collected by a dust collector and is a powder containing various salts, carbon, and fats and oils, and its properties are as follows.
(2)脱水処理方法
予めビーカーテストにより塩類、N−ヘキサン抽出物が
トレース程度の溶出値を示すのに必要な高速脱水処理剤
量を実験的に測定する。(2) Dehydration treatment method The amount of high-speed dehydration treatment agent necessary for the salts and N-hexane extract to show an elution value of trace level is experimentally determined in advance by a beaker test.
低速リボンミキサー等で被処理産廃物と高速脱水処理剤
とを事前に混合し、この混合物を第1図の高速脱水処理
剤用定量フイーダ3に入れ、第1図の装置を駆動して該
処理剤用定量フイーダから上記混合物を8 0 0 r
/分の割合で供給し、供給開始3分経過後先端にスプレ
ー噴霧口を取り付けた給水装置から2001rLl/分
で水を散布、※ して撹拌混合する。The industrial waste to be treated and a high-speed dehydration treatment agent are mixed in advance using a low-speed ribbon mixer, etc., and this mixture is put into the quantitative feeder 3 for high-speed dehydration treatment agent shown in Fig. 1, and the apparatus shown in Fig. 1 is driven to carry out the treatment. 800 r of the above mixture from a metering feeder for
After 3 minutes from the start of supply, water is sprayed at a rate of 2001 rL/min from a water supply device equipped with a spray nozzle at the tip,* and the mixture is stirred and mixed.
ほぼ40俸の水分で排出させ、この排出物を別容器に移
して貯え、数分間放置後140〜160の発熱を行わせ
て可溶性或分の封じ込めを行い粉体を得る。Approximately 40 g of water is discharged, the discharged material is transferred to a separate container and stored, and after being left for several minutes, a heat of 140 to 160 °C is generated to confine the soluble portion and obtain a powder.
(3)処理結果 測定条件 実施例1の(3)測定条件と同じ。(3) Processing results Measurement conditions Same as (3) measurement conditions of Example 1.
■ 高速脱水処理剤事前添加比 ダストに対し23重量
φ
■ 高速脱水処理剤一ダスト混合物供給量24kgグ7
30分
■ 処理済生威物
(4)処理中の経時温度分布は第14−1(前段発熱反
応)、1 4−2 (後段発熱反応)図に示す通りであ
る。■ Pre-addition ratio of high-speed dehydration treatment agent 23 weight φ for dust ■ Supply amount of high-speed dehydration treatment agent - dust mixture 24 kg 7
30 minutes ■ Treated biomaterial (4) Temperature distribution over time during treatment is as shown in Figures 14-1 (first stage exothermic reaction) and 14-2 (second stage exothermic reaction).
実施例 1 0 .4
−X(1)被処理産廃物
コミ焼却場で発生したフライアツシュに注水して冷却し
、これを貯溜ピットに貯えた汚泥状物質で、その性状は
次の通りである。Example 1 0. 4
-X (1) Industrial waste to be treated A sludge-like material obtained by pouring water into the fly ash generated at the Komi incineration plant to cool it and storing it in a storage pit. Its properties are as follows.
(2) 脱水処理方法 脱水処理方法は前処理と後処理に分かれる。(2) Dehydration treatment method Dehydration treatment methods are divided into pretreatment and posttreatment.
前処理は実施例1の(2)脱水処理方法と同様に行う。The pretreatment is performed in the same manner as (2) dehydration treatment method of Example 1.
後処理では、前処理で排出した処理済物を縦型遊星ギヤ
ミキサーに導入し、30〜4Qrpmで撹拌して発熱さ
せ、有害物等の封じ込めを行い粉体を得る。In the post-treatment, the treated material discharged in the pre-treatment is introduced into a vertical planetary gear mixer, stirred at 30 to 4 Qrpm to generate heat, contain harmful substances, etc., and obtain powder.
(3)処理結果 測定条件 実施例1の(3)測定条件と同じ。(3) Processing results Measurement conditions Same as (3) measurement conditions of Example 1.
**
■ 産廃物供給量 80kg/30分2 高速
脱水処理剤供給量 18kg/30分(対産廃物比 2
2.5饅)
3 処理済(後処理)生成物
(4)処理゛中の経時温度分布は第15−1(前一処理
反応)、1 5−2 (後処理反応)図に示すとおりで
ある。** ■ Amount of industrial waste supplied: 80 kg/30 minutes2 Amount of high-speed dehydration treatment agent supplied: 18 kg/30 minutes (ratio to industrial waste: 2
2.5) 3 Treated (post-treated) product (4) Temperature distribution over time during treatment is as shown in Figures 15-1 (pre-treatment reaction) and 15-2 (post-treatment reaction). be.
本発明の高速脱水処理法はスクリュー形、楔形、パドル
形及びパドルバー形の羽根、即ち異形ブレード群を組合
わせた反応筒を使用して行われ、高速脱水処理剤と被処
理産廃物の反応筒に対する装入量は予備試験で決定され
る。The high-speed dehydration treatment method of the present invention is carried out using a reaction tube that combines screw-shaped, wedge-shaped, paddle-shaped, and paddle-bar-shaped blades, that is, a group of irregularly shaped blades. The amount to be charged will be determined in preliminary tests.
上記各実施例に示される被処理産廃物の性状と処理済生
或物分析値の対比から本発明の処理法及び処理装置で得
られる経済的効果は明らかであろう。The economic effects obtained by the treatment method and treatment apparatus of the present invention will be clear from the comparison between the properties of the treated industrial waste and the analytical values of the treated product shown in the above examples.
又本発明は現在重要な環境上及び省エネルギー上の問題
点となっている有機質及び油脂系産業廃棄物の処理を、
公害源となる生成物を発生することなく、簡単かつ経済
的に実施できるばかりでなく、処理済生成物が土質改良
剤又は成型化燃料として再資源化利用できる点にも格別
の効果を奏するものである。The present invention also addresses the problem of processing organic and oil-based industrial waste, which is currently an important environmental and energy saving problem.
Not only can it be carried out easily and economically without producing products that cause pollution, but it is also particularly effective in that the treated product can be recycled and used as a soil conditioner or molded fuel. It is.
第1図は本発明の高速脱水処理装置を略示すると共に特
に外周壁のない反応筒の内部を示し、第2,3及び4図
はそれぞれ矢印A=A,B−B及びC−Cによる反応筒
の端面図を示し、第5図は産廃物の脱水処理間における
経時温度変化の一例を示し、第6,7,8,9,10,
11 ,12,1 3 , 1 4−1 . 1 4−
2 . 1 5−1及び15−2図はそれぞれ実施例1
,2,3,4,5,6,7,8,9及び10の脱水処
理間における経時温度変化を示す。Fig. 1 schematically shows the high-speed dehydration treatment apparatus of the present invention and particularly shows the inside of the reaction cylinder without an outer peripheral wall, and Fig. 2, 3 and 4 are indicated by arrows A=A, BB and CC, respectively. FIG. 5 shows an example of temperature change over time during dehydration treatment of industrial waste;
11, 12, 1 3, 1 4-1. 1 4-
2. 1 Figures 5-1 and 15-2 are Example 1, respectively.
, 2, 3, 4, 5, 6, 7, 8, 9 and 10.
Claims (1)
灰6.0〜13.3重量饅、炭酸石灰17.3〜24.
0重量饅、滑石粉4.0〜6.0重量饅、及び中性陶土
2.3〜3.2重量饅を配合した高速脱水処理剤で、家
畜糞、酸造汚泥等の有機質産業廃棄物及び油脂系産業廃
棄物を、脱水粉体化することを特徴とする、有機質及び
油脂系の産業廃棄物の高速脱水処理法。 2 一部を重複した並列二円の断面を有する横方向に長
いほぼ水平の反応筒、可変速モータに連結された主回転
軸によって駆動されかつ該反応筒内に架設される並列平
行の二撹拌軸、高速脱水処理剤用定量フイーダ、産業廃
棄物用定量フイーダ、及び排ガス除去装置で構威され、
高速脱水処理剤で連続的に有機質及び油脂系の産業廃棄
物を脱水処理するために上記反応筒の内部は6区域に区
分さへ各区域の該撹拌軸には第1区域ではスクリュー形
、第2区域では楔形、第3区域ではパドル形とパドルバ
ー形、第4区域では楔形、第5区域ではパドル形とパド
ルバー形、及び第6区域では楔形の各羽根がそれぞれ設
けられることを特徴とする、有機質及び油脂系の産業廃
棄物の連続式高速脱水処理装置。 3 上記第2項記載の装置で、更に水添加機構及び予熱
・保温装置を具備することを特徴とする、連続式高速脱
水処理装置。[Claims] 1. Powdered quicklime 53.0 to 71.0% by weight, silicate lime 6.0 to 13.3% by weight, carbonate lime 17.3 to 24% by weight.
A high-speed dehydration treatment agent containing 0 weight rice cake, talcum powder 4.0~6.0 weight rice cake, and neutral china clay 2.3~3.2 weight rice cake, and is suitable for organic industrial waste such as livestock manure, acid sludge, etc. A high-speed dehydration treatment method for organic and oil-based industrial waste, characterized by dehydrating and powdering the oil-based industrial waste. 2. A transversely long, almost horizontal reaction tube with a cross section of two parallel circles that partially overlap, and two parallel and parallel agitation tubes that are driven by a main rotating shaft connected to a variable speed motor and installed within the reaction tube. It consists of a shaft, a quantitative feeder for high-speed dehydration processing agents, a quantitative feeder for industrial waste, and an exhaust gas removal device.
In order to continuously dehydrate organic and oil-based industrial waste using a high-speed dehydration treatment agent, the interior of the reaction column is divided into six zones. The blades are wedge-shaped in the second area, paddle-shaped and paddle-bar shaped in the third area, wedge-shaped in the fourth area, paddle-shaped and paddle-bar shaped in the fifth area, and wedge-shaped in the sixth area. Continuous high-speed dehydration equipment for organic and oil-based industrial waste. 3. A continuous high-speed dehydration treatment device according to item 2 above, further comprising a water addition mechanism and a preheating/warming device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54096104A JPS5838227B2 (en) | 1979-07-30 | 1979-07-30 | High-speed dehydration treatment method and equipment for industrial waste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54096104A JPS5838227B2 (en) | 1979-07-30 | 1979-07-30 | High-speed dehydration treatment method and equipment for industrial waste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5621680A JPS5621680A (en) | 1981-02-28 |
| JPS5838227B2 true JPS5838227B2 (en) | 1983-08-22 |
Family
ID=14156074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54096104A Expired JPS5838227B2 (en) | 1979-07-30 | 1979-07-30 | High-speed dehydration treatment method and equipment for industrial waste |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5838227B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57174250A (en) * | 1981-04-20 | 1982-10-26 | Toppan Printing Co Ltd | One surface vapor volatile sheet |
| KR100388346B1 (en) * | 2000-07-29 | 2003-06-25 | 정길룡 | A fertilizer from the waste of agricultural, marine and stock raising products and sludge and its preparing method |
| WO2005080296A1 (en) * | 2004-02-23 | 2005-09-01 | Kazutoshi Noguchi | Compost, and method and apparatus for producing the same |
| KR101272874B1 (en) * | 2011-11-17 | 2013-06-11 | 수도권매립지관리공사 | a method for hard float oils in food rubbish waste water |
-
1979
- 1979-07-30 JP JP54096104A patent/JPS5838227B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5621680A (en) | 1981-02-28 |
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