JPS58386B2 - Asphalt waterproof base material - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention uses a composite obtained by bonding a non-woven fabric layer and a woven fabric layer together by a needle punch method as a core material of an asphalt waterproofing base material. The present invention relates to an asphalt waterproofing base material which is made by dipping and impregnating asphalt.

Among the various waterproofing methods that have existed in the past, the asphalt waterproofing method is superior in its waterproofness, reliability and durability resulting from the quality of the material and workability, and is also easy to install and economical. For reasons such as advantageous, sheet waterproofing (
It is widely used compared to other methods (which tend to leave air bubbles in the joints and have flaws in economical waterproofing due to peeling and other problems), coating, and coating film waterproofing (which have flaws such as difficulty in achieving thickness and unevenness). ing.

For example, in architecture, roofs of various buildings, indoor kitchens,
It is used for waterproofing toilets, etc., and in civil engineering, for internal and external waterproofing of underground structures, and for creating unexcavated ponds, drainage, and irrigation canals.

Asphalt waterproofing is a method in which several pieces of asphalt roofing are sequentially laminated using molten asphalt to form a waterproof layer, and is based on utilizing the waterproof properties of asphalt.

Asphalt alone has defects that can cause cracks that occur due to drying or shrinkage of the underlying surface, such as a concrete slab surface, and also cause the asphalt to break due to fatigue due to repeated movement of the cracked portion.

In addition, it becomes hard at low humidity and tends to flow at high temperatures, so in order to solve this problem, we use reinforcing materials such as porous paper or nonwoven fabrics made of fibers (natural, synthetic, glass) as a core material and melt them into the core material. Roofing impregnated with asphalt is used.

The usual method for paper as a core material is to impregnate straight asphalt and then coat it with prone asphalt, but it has no stretchability and can easily break due to small cracks in the base and its vertical behavior. The reliability of its ability to maintain waterproofness is extremely low.

Adhesive (
Asphalt roofing, in which the core material is a non-woven fabric treated with a synthetic resin emulsion (mostly a synthetic resin emulsion) and fixed at the intersections of the fibers, is called stretch roofing, and as mentioned above, the fibers are fixed with adhesives. Therefore, the tensile strength at initial and maximum elongation is generally large.
Because it has a property of low stretchability, it has high rigidity, is weak against rolling, and lacks restoration resistance.Although it is more flexible than asphalt roofing made of paper core material against foundation cracks, It has poor fatigue resistance, and the durability of the waterproof layer is still far from perfect.

In contrast to these asphalt roofings, thicker (4 mm) asphalt roofing is known, which is made of a bulky nonwoven fabric made by needle-punching endless polypropylene fibers and intertwining the fibers in a three-dimensional manner (
Patent No. 876715).

This has a tensile strength of 15. It is large, with a width of over 100 kg/10 mm, has an elongation rate that is over 5.0 times that of conventional asphalt roofing, and has excellent crack resistance and resistance to rolling.

However, depending on the purpose and application, a thinner asphalt roofing is required, and in such cases, if the nonwoven fabric used as the core material is made thinner (for example, 1.5 mm thick),
Needle punching had defects such as insufficient intertwining of the fibers, causing shrinkage and wrinkles during asphalt impregnation, and the resulting products had high elongation but lacked tensile strength.

The present invention solves these problems and improves workability during manufacturing.
The purpose is to provide a base material with excellent productivity and performance as a base material for asphalt waterproofing.

That is, the present invention has developed a composite core material in which a knitted fabric is overlaid on a nonwoven fabric made of a random layered web of long fibers, and the two are bonded and integrated by the fibers that make up the nonwoven fabric by applying needle punching. , we have succeeded in obtaining an asphalt waterproofing base material that eliminates the various defects mentioned above.

The nonwoven fabric layer is formed by randomly arranging long polyester fibers (including continuous fibers), preferably intertwined in advance by a needle punch method.

The polyester of the nonwoven fabric layer may be synthesized from one or more acid components containing aromatic dicarboxylic acid or its lower alkyl group ester and one or more glycols, or may be synthesized from aromatic oxycarboxylic acid or its lower alkyl group ester and one or more glycols. It is a polyester synthesized by self-condensation reaction of one or more acids or lower alkyl esters thereof, or by both of the above.

Aromatic dicarboxylic acids include terephthalic acid and naphthalene-2
, 6-dicarboxylic acid, diphenyl ether carboxylic acid,
Ethylene 1,2-bis(P-carboxyphenoxide)
, P, P-disulfonylbenzoic acid, glycols include polymethylene glycol having 2 to 10 carbon atoms, cyclohexanedimethanol, etc., and aromatic oxynic acids include P-(β-oxyethyne)benzoic acid. There are acids, etc.

In addition, the basic polyester minor components include isophthalic acid, phthalic acid, oxalic acid, adipic acid, cepatic acid, 6゜6'-disulfonylcaproic acid, dimethylconic acid, diethylene glycol, triethylene glycol, neopentyl glycol. , bisphenol A, etc. are usable compounds.

Among these polyesters, polyethylene terephthalate (PET) and polytetramethylene terephthalate (PTMT) are preferred, and copolymers containing more minor components are also included.

These polyesters must have a molecular weight sufficient to form long fibers, that is, the intrinsic viscosity of the resin must be 0.4 dl/g or more, and the intrinsic viscosity of polyethylene terephthalate is 0.
．． The intrinsic viscosity of polytetramethylene terephthalate is preferably 0.5 to 1.2 dl/g.

These long fibers may be formed with various draft ratios and draw ratios, and those with high strength and high elongation are particularly preferred.

The long fibers of the nonwoven fabric layer are usually formed by melt spinning, and the randomized long fibers are collected with a screen or the like to form a web.

Further, heat stabilizers, antioxidants, ultraviolet absorbers, pigments, flame retardants, surfactants, and the like are added or surface treated as necessary during melt spinning, during web formation, and before and after the web formation.

In particular, it is preferable that the long fibers be surface-treated with a surfactant at least before needle punching that penetrates both layers, and a nonionic surfactant such as polyoxyethylene alkyl ether or polyoxyethylene alkyl phenyl ether may be used. used.

The long fibers of the nonwoven fabric layer are 0.5 to 20 deniers, especially 3 to 1
5 denier is preferred.

The formed web is pre-needle punched to a length of 1 cm.
It is preferable to carry out the process 10 to 180 times, preferably 30 to 120 times per 2 d, so that the fibers are intertwined at a large number of locations.

The basis weight of the nonwoven fabric layer is 80 to 1000 g/m2, especially 10
0 to 500 g/m2 is preferable, and the thickness is 0.5 to 4. O
mm, particularly preferably 1.0 to 3.0 mm.

The other layer constituting the core material is a knitted fabric layer made of knitted fabric or woven fabric, and is particularly preferably made of polyester fiber.
Polyethylene terephthalate, polytetramethylene terephthalate, etc., which are the raw materials for the nonwoven fabric layer described above, are used.

The textile fabric layer preferably has low stretchability and high tensile strength at 3% elongation.

Scrim woven with yarns with a count of 5 to 50, especially 10 to 30, at a spacing of 7 to 20 yarns/1 nch, or 100 to 80 yarns.
Most preferred is a scrim made of filaments of 0 denier, especially 120 to 500 denier, woven at a spacing of 3 to 8 filaments/cm.

The basis weight of these scrims is 10 to 100 g/m2, preferably 15 to 75 g/m2.

The scrim can also be made by crossing threads and fixing the intersections with adhesive.

If the spacing between the threads becomes narrower, the scrim tends to break when needle punching is performed to penetrate the non-woven fabric layer and the textile fabric layer, making it impossible to obtain the desired strength, and the asphalt impregnation speed of the textile fabric layer becomes slow, making it difficult to obtain the desired strength. Asphalt waterproofing base materials tend to warp and delaminate.

Naturally, other materials that meet the above conditions can also be used as materials for knitting and woven fabrics, such as rayon, polyacrylonitrile, and vinylon. Rayon includes viscose rayon, copper ammonia rayon, and improved rayon of these. It will be done.

The composite is obtained by laminating a non-woven fabric layer and a woven fabric layer and punching a needle through both layers.

The structure of the composite is preferably a two-layer structure of a non-woven fabric layer and a knitted fabric layer, or a three-layer structure of a non-woven fabric layer/knitted fabric layer/non-woven fabric layer.
Of course, more than one layer is also possible.

The needle punch that penetrates both layers is 20 to 150 times/cm.
2. In particular, those with 60 times/cm2 or more have good interlayer bonding, and the needle depth is 4 to 20 mm, especially 10 to 20 mm.
16 mm is preferred.

The composite thus obtained has a tensile strength (JIS-A-6022-1977) of 6k in the longitudinal direction at 3% elongation.
It has a value of 4 kg/10 mm width or more in the horizontal direction and 4 kg/10 mm width or more in the horizontal direction, and has a large elongation rate of 50% or more, which is desirable as a core material.

The properties will be described in more detail.

FIG. 1 shows the relationship between the tensile strength and elongation of the core material of the asphalt waterproofing base material.

A highly rigid nonwoven fabric (2) in which fibers are bonded together using a conventional adhesive exhibits the properties shown in Figure 1 in a tensile test, with high tensile strength but low elongation.

On the other hand, a thin nonwoven fabric (2), for example, around 200 g/m2, made by interlacing fibers by the needle punching method has extremely high elongation but low tensile strength.

However, the composite material (2), which is the core material of the present invention, has the characteristic that it has a significantly high tensile strength while retaining the high elongation of the needle-punched nonwoven fabric.

Table 1 shows the properties of various composites. These properties are due to the fact that the tensile strength of the textile fabric is effective at the initial stage of tension, and after the fibers of the textile fabric loosen or break, the properties of the nonwoven fabric are This shows that as the fibers approach each other, the tensile strength increases and a large elongation is exhibited.

This is a major feature not found in conventional core materials, and the asphalt waterproofing base material using this composite as a core material has better resistance to sub-base cracks and crack behavior than conventional asphalt roofing. This is a factor contributing to the extremely excellent durability and waterproofness, which will be described later.

These composites are continuously immersed in molten asphalt as a long product and cooled to produce an asphalt waterproofing base material.

The asphalt to be impregnated includes various asphalts such as blown asphalt and catalyzed asphalt, as well as improved asphalts that are blended with these asphalts and various rubbers, latexes, synthetic resins, aggregates, additives, etc.

In the present invention, after the composite is impregnated with asphalt, different or similar asphalts are further laminated on one or both sides to form a waterproof base material.

These waterproof base materials are usually covered with a release sheet that can be easily removed during construction.

When this composite was immersed in molten asphalt, the thermal shrinkage was small, no wrinkles occurred, and no peeling was observed between the nonwoven fabric layer and the woven fabric layer, proving that the bonding between the two by the needle punch method was strong. It was found that continuous production was possible.

Furthermore, the obtained base material for asphalt waterproofing clearly exhibits the above-mentioned characteristics of the composite, and it is clear that a base material for asphalt waterproofing that meets the objective of having high tensile strength and remarkable extensibility can be obtained. Ta.

That is, their properties are shown in FIGS. 2 and 3.

Furthermore, Table 3 shows the comparative test results.

In Figures 2 and 3, the vertical axis represents the tensile strength of the asphalt waterproofing base material, and the horizontal axis represents the elongation rate, and the behavior of the base material in the vertical direction is expressed as a second graph.
The behavior of the base material in the horizontal direction is shown in FIG. 3.

Stretch roofing (2) has a high initial tensile strength, but has defects that cause it to break quickly.

In roofing ■ using needle-punched nonwoven fabric as a core material, as the elongation increases, the tensile strength also increases, and although the elongation rate is several orders of magnitude higher than that of stretch roofing, the initial tensile strength is small and the overall Because it is soft and lacks stiffness, it is softened by molten asphalt during installation, causing wrinkles and meandering, which poses practical problems except in laboratory scale applications.

However, in the tensile test, the asphalt waterproofing base material (2) of the present invention shows that the strength rapidly increases until reaching point A after the start of tension, and at point A, the threads of the textile fabric loosen or partially When the fibers break, the tensile strength decreases slightly and reaches point B.

From point B, as the fibers of the nonwoven fabric become closer together, the tensile strength increases again, and it expands significantly, passing through the 0 point and reaching the 9 point.The entanglement of the nonwoven fabric fibers gradually separates, the tensile strength decreases, and it breaks. Follow the process of doing so.

In this way, the asphalt waterproofing base material of the present invention has a high initial tensile strength like commercially available stretch roofings, and a high elongation rate like roofings made of needle-punched nonwoven fabric as a core material. It turned out to be a combination of the best features of both.

Its characteristic properties are that the initial tensile strength increases due to the effect of the woven fabric in the composite, and the elongation rate is extremely large due to the effect of the nonwoven fabric in the needle punch method. Due to this mechanism, an ideal base material for asphalt waterproofing that has excellent durability and highly reliable waterproofing construction was obtained.

Table 2 shows the properties of the asphalt waterproofing base material.

Below, various tests and test results will be described.

Generally, in asphalt waterproofing, the cause of water leakage is cracks that occur in the underlying surface, such as concrete slabs, and since asphalt roofing does not have stretchability, it cannot adapt to the cracks and breaks.

In addition, small cracks occur on the slab surface, and as the temperature rises and falls and the building behaves, the cracks expand and contract horizontally or vertically, causing a phenomenon of rubbing and loosening for asphalt roofing, which accumulates fatigue and causes damage to the asphalt roof. It is thought that the ing will break.

As a method to reproduce these phenomena, a vertical shear cyclic test and a rupture test were conducted in the laboratory as follows.

Place a test piece of asphalt waterproofing base material across both plates on a fixed plate and a movable plate that is installed in close contact with the fixed plate and moves up and down, and then place the test piece of asphalt waterproofing base material on both plates from the center of the contact area between the two plates to the left and right. After fixing the test piece to each plate using a support at each 10 mm distance, the test piece was rubbed by moving the movable plate upward and downward by 5 mm per second with a relative step of 10 mm. Causes fatigue.

The number of times of vertical shearing was stopped at a certain number of times using an automatic counting machine, and the presence or absence of water permeation was observed by applying a certain water pressure for 10 minutes.

In addition, in the rupture test, instead of moving the moving plate horizontally at a constant speed (5 m
The test piece was pulled at a speed of 100 m/m1n) and visually observed to see if it broke, and when a certain amount of cracking occurred, the test piece was taken out and a certain water pressure was applied for 10 minutes to observe whether or not water permeated.

The asphalt waterproofing base material of the present invention has unique properties and physical properties by overlapping a nonwoven fabric layer and a knitted fabric layer in which long fibers are intertwined three-dimensionally, and then applying needle punching to integrate the two. It was first obtained by obtaining a composite and impregnating and saturating it with asphalt.

The high initial tensile strength of the composite prevents wrinkles and shrinkage during asphalt dipping, makes asphalt dipping easy and efficient, and prevents deformation and shrinkage during waterproofing. did it.

Furthermore, various asphalts can be used alone or in combination, or different types of asphalt can be used on the front and back surfaces of the composite.

The asphalt used for impregnation can be changed depending on the material of the composite and the use of the asphalt waterproofing base material.

i.e. blown asphalt, catalyzed asphalt,
Rubberized asphalt, improved asphalt blended with synthetic resin, etc. are used.

In addition, it is naturally possible to use the present asphalt waterproofing base material by impregnating the composite with asphalt and then applying the same or different types of asphalt on one or both sides to obtain an asphalt waterproofing base material.

By changing the composition of the composite or selecting the asphalt, it is possible to obtain an asphalt waterproofing base material suitable for the purpose of use, location, and environmental conditions. Waterproofing, waterproofing of various underground structures, construction of dug ponds, fish ponds, wastewater treatment ponds, drainage, and irrigation canals.

Since it is used for bank protection construction, etc., it is of great importance as an industrial material.

Examples are shown below.

However, the intrinsic viscosity [η] of the resin is a value measured at 30° C. using a solvent of tetrachloroethane/phenol=l/1 (volume ratio).

Example 1 Nonwoven fabric (thickness 1.3 to 1.5 denier) made of long fibers (5 denier) of polyethylene terephthalate ([η] = 0.68).
5mm, needle punch 45 times/cm2. Needle depth 10m
m) and a woven fabric made of polyethylene terephthalate fibers woven with 250 denier filaments both vertically and horizontally at an interval of 3 filaments per lcm, and after spraying 1 g/mm2 of nonionic surfactant on the nonwoven fabric side, Needle punch through both layers 100 times/cm2. needle depth 1
It was made into a composite by 4 mm.

This composite was placed in compound asphalt (softening point 102°C, penetration degree 32 at 25°C) melted at 190°C.
After being immersed for 0 seconds, it was cooled to obtain an asphalt waterproof base material with a thickness of 1.6 mm.

The shrinkage rate in this case was 5% or less.

Other physical properties are shown in Table 2.

Example 2 A composite was prepared using the materials shown in Table 1 under the same conditions as in Example 1, and rubberized asphalt (
After being immersed for 60 seconds in water with a softening point of 96° C. and a penetration degree of 38° C. and 125° C., it was cooled to obtain an asphalt waterproofing base material with a thickness of 1.8 mm.

The shrinkage rate in this case was 5% or less.

Other physical properties are shown in Table 2.

Examples 3 to 6 Composites were prepared using the materials shown in Table 4 under the same conditions as in Example 1, and impregnated with the asphalt of Example 1 to obtain asphalt waterproofing base materials.

The shrinkage rate of each base material was 5% or less.

Other physical properties are shown in Table 2.

Comparative Examples 1 to 2 A base material for asphalt waterproofing was prepared under the same conditions as in Example 1 in the case where only the nonwoven fabric used in the above example was used as a core material.

[Brief explanation of the drawing]

FIG. 1 shows the results of a tensile test of the core material of the asphalt waterproofing base material, where ■ and ■ are the curves of the conventional product, and ■ is the curve of the composite according to the present invention. Figures 2 and 3 show the results of a tensile test of the asphalt waterproofing base material, where ■ and ■ are the curves of the conventional product, and ■ are the curves of the product of the present invention. FIG. 2 shows the test results in the vertical direction of the base material, and FIG. 3 shows the test results in the horizontal direction.

Claims (1)

[Claims] 1. It is characterized by being made by impregnating asphalt into a composite formed by bonding a nonwoven fabric layer formed by randomly arranging long polyester fibers and a knitted fabric layer by needle punching. Base material for asphalt waterproofing. 2 The tensile strength of the composite and/or asphalt waterproofing base material at the time of 3-fold elongation is 6 kg/10 mm width or more in the vertical direction and 4 kg/10 mm width or more in the horizontal direction, and further 50
The asphalt waterproof base material according to claim 1, which has good fatigue resistance such as rubbing resistance, shrinkage resistance, restoring resistance, and cracking resistance, and is characterized by having an elongation rate of % or more. 3. The asphalt waterproofing base material according to claim 1, wherein the nonwoven fabric layer has a basis weight of 100 to 500 g/m2, and the textile fabric layer has a basis weight of 15 to 75 g/m2. 4 The knitting fabric layer has 7 to 20 yarns/1n with a count of 10 to 30.
The asphalt waterproofing base material according to claim 1, wherein the asphalt waterproofing base material is a scrim woven with a spacing of 120 to 150 denier at a spacing of 3 to 8 filaments/cm.