JPS5839198B2 - Transparent gel cleaning agent - Google Patents
Transparent gel cleaning agentInfo
- Publication number
- JPS5839198B2 JPS5839198B2 JP6274576A JP6274576A JPS5839198B2 JP S5839198 B2 JPS5839198 B2 JP S5839198B2 JP 6274576 A JP6274576 A JP 6274576A JP 6274576 A JP6274576 A JP 6274576A JP S5839198 B2 JPS5839198 B2 JP S5839198B2
- Authority
- JP
- Japan
- Prior art keywords
- transparent gel
- cleaning agent
- diesters
- weight
- malate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012459 cleaning agent Substances 0.000 title claims description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 17
- 229930195729 fatty acid Natural products 0.000 claims description 17
- 239000000194 fatty acid Substances 0.000 claims description 17
- 150000004665 fatty acids Chemical class 0.000 claims description 17
- -1 alcohol ethylene oxide adducts Chemical class 0.000 claims description 14
- 150000005690 diesters Chemical class 0.000 claims description 13
- 239000011538 cleaning material Substances 0.000 claims description 8
- 238000005187 foaming Methods 0.000 claims description 8
- 229940049920 malate Drugs 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003599 detergent Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- OOCBIZIRIHNNGC-UHFFFAOYSA-N bis(2-octyldodecyl) 2-hydroxybutanedioate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CC(O)C(=O)OCC(CCCCCCCC)CCCCCCCCCC OOCBIZIRIHNNGC-UHFFFAOYSA-N 0.000 claims description 2
- 230000003020 moisturizing effect Effects 0.000 claims description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 235000019864 coconut oil Nutrition 0.000 description 10
- 239000003240 coconut oil Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 239000002562 thickening agent Substances 0.000 description 6
- 238000004040 coloring Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
- 229960002989 glutamic acid Drugs 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- MBCIDCHPJQLZKI-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;2-oxopyrrolidine-1-carboxylic acid Chemical compound OC(=O)N1CCCC1=O.OCCN(CCO)CCO MBCIDCHPJQLZKI-UHFFFAOYSA-N 0.000 description 1
- WLMZUANPXHJWCH-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;dodecanoic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(O)=O WLMZUANPXHJWCH-UHFFFAOYSA-N 0.000 description 1
- XPRMMEIVDKUMSK-UHFFFAOYSA-N 2-aminoethanol;1-dodecoxydodecane;sulfuric acid Chemical compound NCCO.OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC XPRMMEIVDKUMSK-UHFFFAOYSA-N 0.000 description 1
- FRPAVHFNOFSNDR-UHFFFAOYSA-N 3-(2,4-dioxo-1,3-thiazolidin-3-yl)propanoic acid Chemical compound OC(=O)CCN1C(=O)CSC1=O FRPAVHFNOFSNDR-UHFFFAOYSA-N 0.000 description 1
- 101100227322 Caenorhabditis elegans fli-1 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 101100281205 Mus musculus Fli1 gene Proteins 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】
本発明は透明ゲル状（半固状；飯尾電機製カードメータ
ーで硬度１０以上；測定条件は重錘１００ｇ、感圧軸３
ｍｍφ）洗浄料に関するものである。Detailed Description of the Invention The present invention uses a transparent gel (semi-solid) with a hardness of 10 or more using a card meter manufactured by Iio Electric; measurement conditions are a weight of 100 g, a pressure-sensitive axis of 3
mmφ) This relates to cleaning materials.
水溶性高分子増粘剤などの添加されている周知の透明ゲ
ル状洗浄料は、透明性は良いが粘度が低く高分子増粘剤
特有のぬるぬる感がある。Well-known transparent gel-like detergents containing water-soluble polymer thickeners have good transparency, but low viscosity and a slimy feel characteristic of polymer thickeners.
また、脂肪酸石鹸系のゲル洗浄料については、せいぜい
半透明であって透明性に問題があり、白残（指で製品を
取ったあと、取り痕部分が指でこねられることにより、
白濁不透明化する現象）現象を起こすという欠点がある
。In addition, fatty acid soap-based gel cleansers are translucent at best, and there are problems with transparency, leaving white residue (after removing the product with one's fingers, the remaining area may be kneaded with one's fingers).
It has the disadvantage of causing a phenomenon of clouding and opacity.
本発明者等は、ある種のジエステル（例えば、ジー５，
７，７’−トリーメチル−２−（１、３、３’−トリー
メチルブチル）−オクチル−マレート）を透明洗浄料基
剤に配合させることにより、著しく透明性が良く、高粘
度ゲル状あるいは半固状であり、且つ高分子増粘剤添加
などによる使用時のぬるぬる感もなく、しかも、脂肪酸
石鹸添加時でも白残現象がない。The inventors have discovered that certain diesters (e.g., di-5,
By incorporating 7,7'-trimethyl-2-(1,3,3'-trimethylbutyl)-octyl-malate) into a transparent detergent base, it has extremely good transparency and is highly viscous gel-like or It is semi-solid and does not have a slimy feel during use due to the addition of a polymeric thickener, and does not leave a white residue even when a fatty acid soap is added.
安定性のすぐれた洗浄料が得られることを見出し、本発
明を完成したものである。It was discovered that a cleaning agent with excellent stability could be obtained, and the present invention was completed.
従来から市販または製造されているゲル状洗浄料の製造
法は、大別すると次の２方法である。Methods for producing gel-like cleaning products that have been commercially available or manufactured can be broadly classified into the following two methods.
第１の方法は各種水溶性高分子増粘剤と界面活性剤の組
合せである。The first method is the combination of various water-soluble polymer thickeners and surfactants.
この方法の欠点は起泡性良好のアニオン界面活性剤を加
えて泡立ちを向上させると、著しく粘度が低下し液化し
やすいことである。The disadvantage of this method is that when an anionic surfactant with good foaming properties is added to improve foaming, the viscosity decreases significantly and liquefaction tends to occur.
また高分子増粘剤特有の使用時のぬるぬる感もある。There is also a slimy feeling that is characteristic of polymeric thickeners when used.
第２の方法は、高分子増粘剤を加えることなく界面活性
剤の組合せ（例えば、アルキルサルフェートとアルキロ
ールアマイドの組合せ、石鹸とアルキルサルフェートの
組合せ、石鹸とアルキロールアマイドの組合せあるいは
無機塩の添加）によりゲル化する方法である。The second method is to combine surfactants (e.g., alkyl sulfates and alkylolamides, soaps and alkyl sulfates, soaps and alkylolamides, or inorganic salts) without adding polymeric thickeners. This is a method of gelling by adding
この方法の欠点は、白残現象があり温度安定性が悪く透
明性が悪いことである。The disadvantages of this method are that there is a white residue phenomenon, the temperature stability is poor, and the transparency is poor.
従来のこれらの方法で製造されたゲル状あるいは半固状
の洗浄料は透明性、使用感（ぬるぬる感）安定性、外観
（白残現象）起泡性のいずれかに大きな欠点を持ってい
る。Gel-like or semi-solid cleaning products manufactured by these conventional methods have major drawbacks in transparency, feel (slimy feeling), stability, appearance (white residue phenomenon), and foaming properties. .
本発明は、高級アルコールエチレンオキサイド付加体３
〜１０重量部、脂肪酸ジェタノールアマイド５〜１０重
量部、及び一般式
（ただし、Ｒ，Ｒ’は炭素数１８〜２０のアルキル基）
で示されるジエステルの１種又は２種以上４〜６重量部
からなる基剤に、起泡洗浄剤、保湿斉鳴水等を加えて１
００重量部としたことを特徴とする透明ゲル状洗浄料で
ある。The present invention provides higher alcohol ethylene oxide adduct 3
~10 parts by weight, 5 to 10 parts by weight of fatty acid jetanolamide, and the general formula (where R and R' are alkyl groups having 18 to 20 carbon atoms)
A foaming cleansing agent, moisturizing Qimei water, etc. are added to a base consisting of 4 to 6 parts by weight of one or more diesters shown by 1.
00 parts by weight of a transparent gel-like cleaning agent.
本発明に使用される高級アルコールエチレンオキサイド
付加体としては、炭素数１２〜１８の高級アルコールに
８モル以下のエチレンオキサイドを付加したものが好ま
しく、脂肪酸ジェタノールアマイドとしては、椰子油脂
肪酸または炭素数１２〜１６の単−若しくは混合脂肪酸
のジェタノールアマイドが好ましい。The higher alcohol ethylene oxide adduct used in the present invention is preferably one in which 8 moles or less of ethylene oxide is added to a higher alcohol having 12 to 18 carbon atoms, and the fatty acid jetanolamide is preferably a coconut oil fatty acid or a carbon number Preferred are jetanolamides of 12 to 16 mono- or mixed fatty acids.
本発明に使用されるジエステルは、
（ｆｄ：ｌ、 １Ｒ、Ｒ’は炭素数１８〜２０のアルキ
ル数基）で示されるものであるが、Ｒ，Ｒ’が分岐を有
するアルキル基であることが好ましく、就中、グリセロ
ール−ジー２−へブチルウンデカノエート、ジー５．７
．７’−トリメチル−２−（１，３゜３１ ）、ＩＪ
メチル−ブチル）オクチル−マレート、ジー２−オクチ
ル−ドデシル−マレート、ジ−２＝ヘフチルーウンデシ
ルーマレート等を使用したときに、特に良好な透明ゲル
が得られる。The diester used in the present invention is represented by (fd:l, 1R, R' are alkyl groups having 18 to 20 carbon atoms), and R and R' are alkyl groups having a branch. is preferred, especially glycerol-di-2-hebutyl undecanoate, di-5.7
．． 7'-trimethyl-2-(1,3°31), IJ
Particularly good transparent gels are obtained when methyl-butyl)octyl-malate, di-2-octyl-dodecyl-malate, di-2-hephthyl-undecyl malate, and the like are used.
また、高級アルコールエチレンオキサイド付加体、脂肪
酸ジェタノールアマイドおよびジエステルの配合割合は
前記の範囲であることが必要で、これ以外では所望の硬
度の透明ゲルが得られない。Further, the blending ratio of the higher alcohol ethylene oxide adduct, fatty acid jetanolamide, and diester must be within the above-mentioned range; otherwise, a transparent gel with the desired hardness cannot be obtained.
なお、本発明の透明ゲル状洗浄料には、一般の洗浄料に
使用されている起泡洗浄剤、保湿剤、その他の添加剤を
配合することができ、これらによって本発明が限定され
るものではない。Note that the transparent gel-like cleaning agent of the present invention may contain foaming cleaning agents, humectants, and other additives that are used in general cleaning agents, and the present invention is not limited by these. isn't it.
本発明によると、前記ジエステルを処方系に４〜６φ添
加することにより、製品の透明性が著しく向上し、しか
もゲル状（半固体）となり、第１の従来方法の欠点（粘
度低下、使用時のぬるぬる感）はすべて解決される。According to the present invention, by adding 4 to 6 φ of the diester to the formulation system, the transparency of the product is significantly improved, and the product becomes gel-like (semi-solid). (slimy feeling) are all resolved.
また、第２の従来方法である界面活性剤ゲルの欠点（白
残現象、透明性が悪い、安定性が悪い）もすべて解決で
きる。In addition, all the drawbacks of the surfactant gel, which is the second conventional method (white residue phenomenon, poor transparency, poor stability), can be solved.
また、ジエステル（油分）の添加にも拘らず、洗浄力は
低下しない。Furthermore, despite the addition of diester (oil), the detergency does not decrease.
また、配合されたジエステルはエモリエント剤でもある
ため使用感も良く、本発明により得られた製品は、洗浄
料としての良好な特質（泡だち、使用性、安全性、安定
性）も備えている。In addition, the blended diester is also an emollient, so it feels good when used, and the product obtained by the present invention also has good properties as a cleaning agent (foaming, ease of use, safety, stability). There is.
なお、これらジエステルの配合による透明ゲル化効果に
ついては、Ｘ線回折図の変化から、透明性良好な面心立
方構造への変化に起因するものと推定される。The transparent gelling effect caused by blending these diesters is presumed to be due to a change to a face-centered cubic structure with good transparency, based on changes in the X-ray diffraction pattern.
第１図、第２図に本発明の透明ゲル状洗浄料（実施例１
）と従来のゲル状洗浄料（参考例１）のＸ線回折図を示
す。Figures 1 and 2 show the transparent gel-like cleaning material of the present invention (Example 1).
) and a conventional gel-like cleaning agent (Reference Example 1).
また、洗浄料における種々の特性値について、従来法に
よる洗浄料と本発明による洗浄料とを比較したところ、
下記に示した如く、本発明による洗浄料は従来法による
洗浄料よりも、各々の特性値について優れていることが
確認された。In addition, when comparing various characteristic values of the cleaning agent between the cleaning agent obtained by the conventional method and the cleaning agent according to the present invention,
As shown below, it was confirmed that the cleaning agent according to the present invention was superior to the cleaning agent according to the conventional method in terms of each characteristic value.
（１）温度安定性（透明性、粘度）
本発明品（実施例１）と従来品（参考例１）との温度安
定性を比較したところ、下表に示したような結果となり
、本発明品は従来品よりも温度安定性の良いことが確認
された。(1) Temperature stability (transparency, viscosity) When the temperature stability of the product of the present invention (Example 1) and the conventional product (Reference example 1) was compared, the results were as shown in the table below. It was confirmed that the product has better temperature stability than conventional products.
（２）透明性
本発明品（実施例１）と従来品（参考例１）との透明性
を比較したところ、本発明品は従来品よりも明らかに透
明性が優れていることが確※※ 認された。(2) Transparency When we compared the transparency of the product of the present invention (Example 1) and the conventional product (Reference Example 1), it was confirmed that the product of the present invention clearly has better transparency than the conventional product.* ※ It has been certified.
（参考写真１に、実施例１ （ＡＩ ）と参考例１（Ａ
２）の透明ゲル状洗浄料の透明性の比較を示す）
（３）０残現象
本発明品（実施例１）と従来品（参考例１）との０残現
象を比較したところ、本発明品は従来品よりも明らかに
、０残現象が改善されていることが確認された。(Reference photo 1 shows Example 1 (AI) and Reference Example 1 (A
(2) Comparison of the transparency of the transparent gel-like cleaning agent) (3) Zero residue phenomenon When comparing the zero residue phenomenon between the product of the present invention (Example 1) and the conventional product (Reference Example 1), it was found that the product of the present invention It was confirmed that the zero residual phenomenon was clearly improved in this product compared to the conventional product.
（参考写真２に、実施例１（ＡＩ）と参考例１（Ａ２）
の透明ゲル状洗浄料の０残現象の比較を示す。(Reference photo 2 shows Example 1 (AI) and Reference Example 1 (A2)
A comparison of the zero-residue phenomenon of transparent gel-like cleaning materials is shown.
）（４）使用テスト
本発明品（実施ｆｌｉ１）と従来品（参考例１）との比
較判定のため、使用テストを２０人のパネル（男子１０
人子女子１０人）を使用して実施したところ本発明品は
従来品の欠点を改善した特徴のある洗浄料であることが
確認された。) (4) Usage test In order to compare and judge the product of the present invention (implementation fli 1) and the conventional product (reference example 1), a usage test was conducted on a panel of 20 people (10 men).
It was confirmed that the product of the present invention is a unique cleaning agent that improves the drawbacks of conventional products.
実施例 １
椰子油脂肪酸アシル−Ｌ−グルタミン酸モノトリエタノ
ールアミン３０．９１ ラウリン酸トリエタノールアミ
ン石鹸１５ｇおよびポリオキシエチレン（１，５モル）
ラウリルエーテル硫酸エタノールアミン酸１８ｇ１グリ
セリン１３ｇをフラスコ中に仕込み７０〜８０℃に加温
攪拌する。Example 1 Coconut oil fatty acid acyl-L-glutamic acid monotriethanolamine 30.91 lauric acid triethanolamine soap 15 g and polyoxyethylene (1.5 mol)
18 g of lauryl ether sulfate ethanolamine acid and 13 g of glycerin were charged into a flask and heated to 70 to 80°C with stirring.
これにあらかじめ加温したポリオキシエチレン（１７モ
ル）還元ラノリン１ｇ１ラウリン酸ジエタノールアマイ
ド７．５ｇ、およびポリオキシエチレン（８モル）オレ
イルアルコールエーテル６ｇを加え、７０〜８０℃に保
ち攪拌する。To this are added 1 g of polyoxyethylene (17 mol), reduced lanolin, 7.5 g of lauric acid diethanolamide, and 6 g of polyoxyethylene (8 mol) oleyl alcohol ether, which have been warmed in advance, and the mixture is kept at 70 to 80° C. and stirred.
次に、ジー５ 、７ 、７’トリーメチル−２−（１、
３、３’−トリーメチルーフチル）−、ｔ りｆルーマ
レート５．５ｇを加え、約２０分攪拌後適当量の色素お
よび香料を添加し水で１００ｇに補正する。Next, di5,7,7'trimethyl-2-(1,
Add 5.5 g of 3,3'-trimethyl-phthyl)-, triflumalate and stir for about 20 minutes, then add appropriate amounts of coloring matter and fragrance, and adjust to 100 g with water.
これを急冷あるいは徐冷することにより透明ゲル状（半
固状）の洗浄料が得られる。By rapidly or slowly cooling this, a transparent gel-like (semi-solid) cleaning agent can be obtained.
実施例 ２
椰子油脂肪酸アシル−Ｌ−グルタミン酸モノトリエタノ
ールアミン３０ｇ、ラウリン酸トリエタノールアミン石
鹸３７９およびグリセリン１３ｇをフラスコ中に仕込み
、７０〜８０℃に加温攪拌する。Example 2 30 g of coconut oil fatty acid acyl-L-glutamate monotriethanolamine, 379 g of triethanolamine laurate soap, and 13 g of glycerin are placed in a flask, and heated to 70 to 80°C with stirring.
これにあらかじめ加温したポリ−オキシエチレン（１７
モル）還元ラノリン１ｇ、椰子油脂肪酸ジェタノールア
マイド７．５ｇおよびポリオキシエチレン（５モル）ラ
ウリルアルコールエーテル５ｇを加え、７０〜８０℃に
保ち攪拌する。This was pre-warmed poly-oxyethylene (17
mol) 1 g of reduced lanolin, 7.5 g of coconut oil fatty acid jetanolamide, and 5 g of polyoxyethylene (5 mol) lauryl alcohol ether are added and stirred while maintaining the temperature at 70-80°C.
次にグリセロール−ジー２−ヘプチル−ウンデカノエー
ト５．！ｌを加え、約２０分間攪拌後、適当量の色素お
よび香料を添加し水で１００ｇに補正する。Next, glycerol-di-2-heptyl-undecanoate5. ! After stirring for about 20 minutes, appropriate amounts of coloring matter and fragrance were added, and the total amount was adjusted to 100 g with water.
これを急冷あるいは徐冷することにより透明ゲル状（半
固状）洗浄料が得られる。By rapidly or slowly cooling this, a transparent gel-like (semi-solid) cleaning agent can be obtained.
実施例 ３
椰子油脂肪酸アシル−Ｌ−グルタミン酸モノトリエタノ
ールアミン６３ｇ、グリセリン１３ｇをフラスコ中に仕
込み７０〜８０℃に加温攪拌する。Example 3 63 g of coconut oil fatty acid acyl-L-glutamic acid monotriethanolamine and 13 g of glycerin are placed in a flask and heated to 70 to 80°C with stirring.
これにあらかじめ加温した、ラウリン酸ジェタノールア
マイド７．５ｇ、ポリオキシエチレン（２モル）椰子油
脂肪酸モノエタノールアマイド２．５ｇ、ポリオキシエ
チレン（５モル）ラウリルアルコールエーテル６ｇを加
え、７０〜８０℃に保ち攪拌する。To this were added 7.5 g of lauric acid jetanolamide, 2.5 g of polyoxyethylene (2 mol) coconut oil fatty acid monoethanolamide, and 6 g of polyoxyethylene (5 mol) lauryl alcohol ether, which had been heated in advance, and Keep at ℃ and stir.
次に、ジー５，７，７’−トリーメチル２−（１、３、
３’−トリーメチル−ブチル）−オクチル−マレート５
ｇを加え、約２０分攪拌後適当量の色素および香料を添
加し、水で１００ｇに補正する。Next, di-5,7,7'-trimethyl2-(1,3,
3'-trimethyl-butyl)-octyl-malate 5
After stirring for about 20 minutes, appropriate amounts of coloring matter and fragrance were added, and the total amount was adjusted to 100 g with water.
これを急冷あるいは徐冷することにより、透明ゲル状（
半固状）洗浄料が得られる。By rapidly or slowly cooling this, a transparent gel-like (
A semi-solid) cleaning agent is obtained.
実施例 ４
グリセリン１３ｇ、ジー５．７．７’−１リ−メチル−
２−（１、３、３’−１−リーメチルーブチル）−オク
チル−マレート５．９をフラスコ中に仕込み、７０−８
０℃で攪拌する。Example 4 13 g of glycerin, 5.7.7'-1-methyl-
5.9 of 2-(1,3,3'-1-lymethyl-butyl)-octyl-malate was charged into a flask, and 70-8
Stir at 0°C.
次にあらかじめ加温したポリオキシエチレン（５モル）
ラウリルアルコールエーテル６ｇ、ラウリン酸ジェタノ
ールアマイド７、５ 、ｐ、ポリオキシエチレン（２モ
ル）椰子油脂肪酸モノエタノールアマ不下２．５ｇを加
え攪拌する。Next, pre-warmed polyoxyethylene (5 mol)
Add 6 g of lauryl alcohol ether, 7.5 g of lauric acid jetanolamide, 2 moles of polyoxyethylene, and 2.5 g of coconut oil fatty acid monoethanol linseed and stir.
次に起泡洗浄剤である椰子油脂肪酸アシル−Ｌ−グルタ
ミン酸モノ−トリエタノールアミン６３ｇおよびピロリ
ドンカルボン酸トリエタノールアミン０．５ｇを加えて
さらに攪拌し適当量の色素および香料を添加し、水で１
００９に補正する。Next, 63g of coconut oil fatty acid acyl-L-glutamic acid mono-triethanolamine and 0.5g of pyrrolidonecarboxylic acid triethanolamine, which are foaming detergents, are added, stirred further, and an appropriate amount of coloring matter and fragrance are added. 1
Correct to 009.
これを急冷あるいは徐冷することにより、透明ゲル状（
半固状）洗浄料が得られる。By rapidly or slowly cooling this, a transparent gel-like (
A semi-solid) cleaning agent is obtained.
参考例 １
椰子油脂肪酸アシル−Ｌ−グルタミン酸モノエタノール
アミン６３ｇをフラスコ中に仕込み、７０℃に加熱し攪
拌する。Reference Example 1 63 g of coconut oil fatty acid acyl-L-glutamic acid monoethanolamine is placed in a flask, heated to 70°C, and stirred.
グリセリン１２ｇ、ポリオキシエチレン（３モル）オレ
イルアルコールエーテル３．５ｇ、ポリオキシエチレン
（５モル）ラウリルアルコールエーテル３．５ｇを加え
て攪拌する。12 g of glycerin, 3.5 g of polyoxyethylene (3 moles) oleyl alcohol ether, and 3.5 g of polyoxyethylene (5 moles) lauryl alcohol ether are added and stirred.
次にラウリン酸ジェタノールアマイド１２．５ｇ、ポリ
オキシエチレン（２モル）椰子油脂肪酸モノエタノール
アマイド２．５ｇを加えて攪拌する。Next, 12.5 g of lauric acid jetanolamide and 2.5 g of polyoxyethylene (2 mol) coconut oil fatty acid monoethanolamide are added and stirred.
次に適当量の色素および香料を添加し水で１００ｇに補
正する。Next, add appropriate amounts of coloring matter and fragrance, and adjust to 100 g with water.
これを急冷あるいは徐冷することにより、透明ゲル状洗
浄料が得られる。By rapidly or slowly cooling this, a transparent gel-like cleaning agent can be obtained.
第１図、第２図は、それぞれ実施例１と参考例１の透明
ゲル状洗浄料のＸ線回折図を示す。FIG. 1 and FIG. 2 show X-ray diffraction patterns of the transparent gel-like cleaning materials of Example 1 and Reference Example 1, respectively.
Claims (1)
重量部、脂肪酸ジェタノールアマイド５〜１０重量部、
及び一般式 （カ九、Ｒ，Ｒ’は炭素数１８〜２０のアルキル基）で
示されるジエステルの１種又は２種以上４〜６重量部か
らなる基剤に、起泡洗浄剤、保湿Ｊｌｌ。 水等を加えて１００重量部としたことを特徴とする透明
ゲル状洗浄料。 ２ ジエステルの１種がグリセロール−ジー２へブチル
ウンデカノエートである特許請求の範囲第１項記載の透
明ゲル状洗浄料。 ３ ジエステルの１種がジー５．７．７’−トリメチル
−２−（１，３，３’−トリメチルーフ゛チル）オクチ
ル−マレートである特許請求の範囲第１項記載の透明ゲ
ル状洗浄料。 ４ ジエステルの１種が、ジー２−オクチル−ドデシル
−マレートである特許請求の範囲第１項記載の透明ゲル
状洗浄料。 ５ ジエステルの１種が、ジー２−ヘプチル−ウンデシ
ル−マレートである特許請求の範囲第１項記載の透明ゲ
ル状洗浄料。[Claims] 1. Higher alcohol ethylene oxide adducts 3 to 10
parts by weight, 5 to 10 parts by weight of fatty acid jetanolamide,
and a base consisting of 4 to 6 parts by weight of one or more diesters represented by the general formula (where R and R' are alkyl groups having 18 to 20 carbon atoms), a foaming detergent, and a moisturizing agent. . A transparent gel-like cleaning agent characterized by adding water or the like to make up to 100 parts by weight. 2. The transparent gel-like cleaning material according to claim 1, wherein one of the diesters is glycerol-di-2-hebutyl undecanoate. 3. The transparent gel-like cleaning material according to claim 1, wherein one of the diesters is di-5.7.7'-trimethyl-2-(1,3,3'-trimethyl-methyl)octyl-malate. 4. The transparent gel-like cleaning material according to claim 1, wherein one of the diesters is di-2-octyl-dodecyl-malate. 5. The transparent gel-like cleaning material according to claim 1, wherein one of the diesters is di-2-heptyl-undecyl-malate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6274576A JPS5839198B2 (en) | 1976-05-29 | 1976-05-29 | Transparent gel cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6274576A JPS5839198B2 (en) | 1976-05-29 | 1976-05-29 | Transparent gel cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52145412A JPS52145412A (en) | 1977-12-03 |
| JPS5839198B2 true JPS5839198B2 (en) | 1983-08-27 |
Family
ID=13209227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6274576A Expired JPS5839198B2 (en) | 1976-05-29 | 1976-05-29 | Transparent gel cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5839198B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6284719A (en) * | 1985-10-11 | 1987-04-18 | 松下電器産業株式会社 | toilet seat device |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ202128A (en) * | 1981-10-24 | 1985-02-28 | Beecham Group Plc | Detergent composition containing translucent gels |
-
1976
- 1976-05-29 JP JP6274576A patent/JPS5839198B2/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6284719A (en) * | 1985-10-11 | 1987-04-18 | 松下電器産業株式会社 | toilet seat device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS52145412A (en) | 1977-12-03 |
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