JPS5839850B2 - photoluminescent composition - Google Patents
photoluminescent compositionInfo
- Publication number
- JPS5839850B2 JPS5839850B2 JP20065481A JP20065481A JPS5839850B2 JP S5839850 B2 JPS5839850 B2 JP S5839850B2 JP 20065481 A JP20065481 A JP 20065481A JP 20065481 A JP20065481 A JP 20065481A JP S5839850 B2 JPS5839850 B2 JP S5839850B2
- Authority
- JP
- Japan
- Prior art keywords
- synthetic resin
- glittering
- film
- metal
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 16
- 229920003002 synthetic resin Polymers 0.000 claims description 28
- 239000000057 synthetic resin Substances 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 11
- 239000004816 latex Substances 0.000 claims description 7
- 229920000126 latex Polymers 0.000 claims description 7
- 239000011247 coating layer Substances 0.000 claims description 6
- 229920001187 thermosetting polymer Polymers 0.000 claims description 5
- 239000010410 layer Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 229920006267 polyester film Polymers 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- -1 polyethylene Polymers 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 229910001361 White metal Inorganic materials 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000010969 white metal Substances 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- PQTCMBYFWMFIGM-UHFFFAOYSA-N gold silver Chemical compound [Ag].[Au] PQTCMBYFWMFIGM-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Decoration Of Textiles (AREA)
Description
【発明の詳細な説明】
本発明は布地、織物、靴、帽子などに塗布して光沢を有
する商品を得るための光輝性組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a glitter composition that can be applied to cloth, textiles, shoes, hats, etc. to obtain glossy products.
従来、この種光輝性組成物としては、金属粉末又は金属
箔を合成樹脂エマルジョンと混合してなるものがあげら
れる。Conventionally, glittering compositions of this type include those made by mixing metal powder or metal foil with a synthetic resin emulsion.
しかし、この従来の組成物は金属粉末を採用した場合、
特に金属粒子の表面積が小さいため画一的な光沢を有す
る商品しか得られなく、また、金属箔を採用した場合に
は、被塗布物との接着性が著しく低いという欠点があっ
た。However, when this conventional composition employs metal powder,
In particular, since the surface area of the metal particles is small, only products with uniform gloss can be obtained, and when metal foil is used, there is a drawback that the adhesion to the object to be coated is extremely low.
本発明は上記欠点を解消するためになされたもので、塗
布する商品との接着性が良好で、しかも種々多様な光沢
を有する商品を製造するに好適に採用しうる光輝性組成
物を提供することを目的とする。The present invention has been made in order to eliminate the above-mentioned drawbacks, and provides a glittering composition that has good adhesion to the product to which it is applied and can be suitably employed in manufacturing products with various glosses. The purpose is to
すなわち本発明の要旨は、合成樹脂フィルムに金属を蒸
着して金属被膜層を形成し、この金属被膜層上に顔料を
含有する熱硬化性樹脂塗料を塗布して樹脂層を形成した
光輝性合成樹脂フィルムを切断して得た細片と、合成樹
脂溶液、合成樹脂エマルジョン又はラテックスとを混合
してなる光輝性組成物に存する。That is, the gist of the present invention is to provide a glitter synthetic resin film in which a metal is vapor-deposited on a synthetic resin film to form a metal coating layer, and a thermosetting resin paint containing a pigment is applied on the metal coating layer to form a resin layer. It consists in a glittering composition formed by mixing thin pieces obtained by cutting a resin film with a synthetic resin solution, synthetic resin emulsion, or latex.
そして必要に応じて、架橋剤、架橋反応の触媒、消泡剤
、増粘剤などを混入しうるものである。If necessary, a crosslinking agent, a catalyst for crosslinking reaction, an antifoaming agent, a thickener, etc. may be mixed.
本発明において採用する合成樹脂フィルムとしては、延
伸又は未延伸のポリエステルフィルム、ポリ塩化ビニル
フィルム、ポリ塩化ビニリデンフィルム、ポリアミドフ
ィルム、ポリエチレンフィルム、ポリフロピレンフィル
ム、ポリアクリルフィルム、ポリスチレンフィルムなど
があげられる。Examples of the synthetic resin films employed in the present invention include stretched or unstretched polyester films, polyvinyl chloride films, polyvinylidene chloride films, polyamide films, polyethylene films, polypropylene films, polyacrylic films, and polystyrene films.
商品との接着性、光沢の点からはポリエステルフィルム
が好ましい。Polyester film is preferred from the viewpoint of adhesion to the product and gloss.
合成樹脂フィルムに蒸着させる金属としては、アルミニ
ウム、アルミニウム合金、マグネシウム、マグネシウム
合金、チタン、チタン合金、ホワイトメタル、ホワイト
メタル合金、ニッケル、ニッケル合金、銀金、白金など
ほとんどの金属を採用することができるが、光沢性、施
工性、経済性、軽重性の点からはアルミニウムが特に好
ましい。Most metals can be used to deposit on the synthetic resin film, including aluminum, aluminum alloy, magnesium, magnesium alloy, titanium, titanium alloy, white metal, white metal alloy, nickel, nickel alloy, silver gold, and platinum. However, aluminum is particularly preferred from the viewpoints of gloss, workability, economy, and light weight.
熱硬化性樹脂塗料としては、たとえば不飽和ポリエステ
ル系のものを採用することができる。As the thermosetting resin coating, for example, one based on unsaturated polyester can be used.
この塗料に含有させる顔料としては無機、有機のいずれ
であってもよい。The pigment contained in this paint may be either inorganic or organic.
金属被覆層および熱硬化性樹脂層は合成樹脂フィルムの
片面だけでも、また両面に設けてもよい。The metal coating layer and the thermosetting resin layer may be provided on only one side of the synthetic resin film or on both sides.
また金属被覆層および熱硬化性樹脂層を設けてなる光輝
性合成樹脂フィルムの細片の形状は三角形、四角形、多
角形、円形などいずれであってもよく、その寸法も製造
する商品にどのような光沢を付与するかにより決定され
るが、切断性および応用範囲の広さを考慮すれば約０．
２朋〜０．５ ｍｍ角のものが好ましい。Furthermore, the shape of the strips of the glittering synthetic resin film provided with the metal coating layer and the thermosetting resin layer may be triangular, square, polygonal, circular, etc., and the dimensions may also be determined depending on the product being manufactured. It is determined by whether it imparts a glossy luster, but considering cuttability and a wide range of applications, it should be approximately 0.
2 to 0.5 mm square is preferred.
この光輝性合成樹脂フィルムの細片化は種々の方法によ
り行なうことができる。This glittering synthetic resin film can be cut into pieces by various methods.
たとえばスリッターにかげたのち、いわゆるギロチンカ
ットして行なってもよい。For example, it may be cut using a slitter and then cut using a so-called guillotine.
合成樹脂溶液または合成樹脂エマルジョンとしてはアク
リル系樹脂、スチレン−ブタジョン樹脂、酢酸ビニル樹
脂、塩化ビニル樹脂、塩化ビニリデン樹脂、ポリウレタ
ン樹脂又はこれらのブレンド物などを溶液状またはエマ
ルジョン状で用いることができる。As the synthetic resin solution or synthetic resin emulsion, acrylic resin, styrene-butajon resin, vinyl acetate resin, vinyl chloride resin, vinylidene chloride resin, polyurethane resin, or a blend thereof can be used in the form of a solution or emulsion.
またラテックスとしては天然ゴムラテックス、アクリル
エステル系ラテックス、酢酸ビニル系ラテックスなどを
用いることができる。Further, as the latex, natural rubber latex, acrylic ester latex, vinyl acetate latex, etc. can be used.
以上本発明においては種々の合成樹脂溶液、エマルジョ
ンまたはラテックスを用いることができるが、感触、風
合および商品との接着力の点からはアクリル系合成樹脂
エマルジョンが好ましい。As described above, various synthetic resin solutions, emulsions, or latexes can be used in the present invention, but acrylic synthetic resin emulsions are preferred from the viewpoint of feel, texture, and adhesive strength to products.
この合成樹脂溶液、合成樹脂エマルジョンまたはラテッ
クスに対し、任意の割合で光輝性合成樹脂フィルムの細
片を混合してもよいが、前者が１００重量部に対し後者
を１０〜５０重量部とするのが加工性、応用範囲の広さ
からも好ましい。The glittering synthetic resin film strips may be mixed with this synthetic resin solution, synthetic resin emulsion, or latex in any proportion, but the former should be 100 parts by weight and the latter should be 10 to 50 parts by weight. is preferable from the viewpoint of processability and wide range of applications.
以上のような構成要件からなる本発明の組成物に、必要
に応じて架橋剤、触媒、消泡剤、増粘剤などを加えて実
際の使用に供する。A crosslinking agent, a catalyst, an antifoaming agent, a thickening agent, etc. are added to the composition of the present invention having the above-mentioned constituent elements as required, and the composition is subjected to actual use.
すなわち本発明の組成物を布地、織物、靴、帽子などに
塗布して人工乾燥または自然乾燥を施すと、極めて微妙
かつ多種多様な光沢を有する商品を得ることができる。That is, by applying the composition of the present invention to cloth, textiles, shoes, hats, etc. and subjecting it to artificial drying or natural drying, it is possible to obtain products with extremely subtle and diverse glosses.
以上、詳述した如く、本発明の組成物は種々の商品に有
効に適用できるが、合成樹脂フィルムを採用しているの
で、金属と商品は合成樹脂フィルムを介して強固に結合
しており、また種々の顔料を採用することができるので
商品に多様な色合いを付与することができ、それと相俟
って光輝性合成フィルムの寸法を任意に変えることもで
きるので微妙かつ多様な光沢を有する商品を提供でき、
しかも合成樹脂溶液、エマルジョンまたはラテックスの
採用により得られた商品の感触、風合いがよ（なるとい
う優れた効果を奏するものである。As detailed above, the composition of the present invention can be effectively applied to various products, but since a synthetic resin film is used, the metal and the product are firmly bonded via the synthetic resin film. In addition, since various pigments can be used, it is possible to give products a variety of hues, and in conjunction with this, the dimensions of the glitter synthetic film can be arbitrarily changed, allowing products to have subtle and diverse luster. can provide
In addition, the use of synthetic resin solutions, emulsions, or latex provides excellent effects in terms of the feel and texture of products obtained.
Claims (1)
成し、この金属被膜層上に顔料を含有する熱硬化性樹脂
塗料を途布して樹脂層を形成した光輝性合成樹脂フィル
ムを切断して得た細片と合成樹脂溶液、合成樹脂エマル
ジョン又はラテックスとを混合してなる光輝性組成物。 ２ 上記合成樹脂フィルムがポリエステルフィルムであ
る特許請求の範囲第１項記載の光輝性組成物。 ３ 上記金属がアルミニウムである特許請求の範囲第１
項又は第２項記載の光輝性組成物。 ４ 上記光輝性合成樹脂フィルムの細片の寸法が、幅０
．２〜０．５ ｍｍ、長さ０．２〜０．５ ｍｍである
特許請求の範囲第１項、第２項又は第３項記載の光輝性
組成物。 ５ 上記合成樹脂エマルジョンが、アクリル系合成樹脂
エマルジョンである特許請求の範囲第１項、第２項、第
３項又は第４項記載の光輝性組成物。[Claims] 1. A glittering film in which a metal is deposited on a synthetic resin film to form a metal coating layer, and a thermosetting resin paint containing a pigment is applied on the metal coating layer to form a resin layer. A glittering composition obtained by mixing thin pieces obtained by cutting a synthetic resin film with a synthetic resin solution, synthetic resin emulsion, or latex. 2. The glittering composition according to claim 1, wherein the synthetic resin film is a polyester film. 3 Claim 1 in which the metal is aluminum
The glittering composition according to item 1 or 2. 4 The dimensions of the strips of the glittering synthetic resin film are 0 in width.
．． The glitter composition according to claim 1, 2 or 3, which has a diameter of 2 to 0.5 mm and a length of 0.2 to 0.5 mm. 5. The glittering composition according to claim 1, 2, 3, or 4, wherein the synthetic resin emulsion is an acrylic synthetic resin emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20065481A JPS5839850B2 (en) | 1981-12-11 | 1981-12-11 | photoluminescent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20065481A JPS5839850B2 (en) | 1981-12-11 | 1981-12-11 | photoluminescent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58101129A JPS58101129A (en) | 1983-06-16 |
| JPS5839850B2 true JPS5839850B2 (en) | 1983-09-01 |
Family
ID=16427995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20065481A Expired JPS5839850B2 (en) | 1981-12-11 | 1981-12-11 | photoluminescent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5839850B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07115455B2 (en) * | 1986-09-29 | 1995-12-13 | 共和レザ−株式会社 | Method for producing decorative sheet |
| JP2000344918A (en) * | 1999-03-31 | 2000-12-12 | Sekisui Chem Co Ltd | Decorative pattern material, decorative molding compound using the same, and decorative molded product using the same |
| JP4249579B2 (en) * | 2003-09-12 | 2009-04-02 | 大日本印刷株式会社 | Glossy decorative paper and thermosetting resin decorative board |
| WO2005078183A1 (en) * | 2004-02-18 | 2005-08-25 | Nippon Wishborn Corporation | Flame-resistant fabric and textile product |
| DE102004037979A1 (en) * | 2004-08-05 | 2006-03-16 | Tesa Ag | Textiles substrate, useful for preparing decorative bands for tennis or golf racquets, or safety marking bands useful in office and household, comprises polyester based glittering pigment containing coating |
-
1981
- 1981-12-11 JP JP20065481A patent/JPS5839850B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58101129A (en) | 1983-06-16 |
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