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JPS5844447B2 - Compression mold for flexible graphite particles - Google Patents
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JPS5844447B2 - Compression mold for flexible graphite particles - Google Patents

Compression mold for flexible graphite particles

Info

Publication number
JPS5844447B2
JPS5844447B2 JP56155504A JP15550481A JPS5844447B2 JP S5844447 B2 JPS5844447 B2 JP S5844447B2 JP 56155504 A JP56155504 A JP 56155504A JP 15550481 A JP15550481 A JP 15550481A JP S5844447 B2 JPS5844447 B2 JP S5844447B2
Authority
JP
Japan
Prior art keywords
mold
graphite particles
flexible graphite
compression
molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP56155504A
Other languages
Japanese (ja)
Other versions
JPS5856814A (en
Inventor
一夫 丸矢
明男 川口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fukubi Kagaku Kogyo KK
Original Assignee
Fukubi Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fukubi Kagaku Kogyo KK filed Critical Fukubi Kagaku Kogyo KK
Priority to JP56155504A priority Critical patent/JPS5844447B2/en
Publication of JPS5856814A publication Critical patent/JPS5856814A/en
Publication of JPS5844447B2 publication Critical patent/JPS5844447B2/en
Expired legal-status Critical Current

Links

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  • Carbon And Carbon Compounds (AREA)
  • Moulds, Cores, Or Mandrels (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)
  • Ceramic Products (AREA)

Description

【発明の詳細な説明】 本発明は可撓性黒鉛粒子の圧縮成形金型に関する。[Detailed description of the invention] The present invention relates to a compression mold for flexible graphite particles.

更に詳細には、金型に充填される可撓性黒鉛粒子の嵩密
度を均一にすることのできる可撓性黒鉛粒子の圧縮成形
金型に関する。
More specifically, the present invention relates to a compression molding mold for flexible graphite particles that can make the bulk density of flexible graphite particles filled into the mold uniform.

従来、黒鉛を酸処理して黒鉛層間化合物を生成させ、高
温下で急速に加熱することにより該黒鉛層面に垂直な方
向すなわちC方向に膨張せしめた軽量の芋虫状可撓性黒
鉛粒子(以下、しばしば単に黒鉛粒子と呼ぶ)は、圧縮
成形性に富み、単独又は結合剤と混合して加圧すると容
易にシート状あるいはブロック状成形体が得られること
が知られている。
Conventionally, lightweight caterpillar-shaped flexible graphite particles (hereinafter referred to as It is known that graphite particles (often referred to simply as graphite particles) have excellent compression moldability and can easily be formed into sheet-like or block-like molded products when pressed alone or mixed with a binder.

モして又それらの黒鉛成形体は耐熱性、耐薬品性、潤滑
性に優れ、各種機械装置、自動車などにおけるガスケッ
トやバッキングなどとして広く実用に供されている。
Moreover, these graphite molded bodies have excellent heat resistance, chemical resistance, and lubricity, and are widely used as gaskets and backings in various mechanical devices, automobiles, and the like.

しかしながら一般に黒鉛粒子は嵩密度Q、Qig/cc
以下の軽量な粒子であり、又数9/crit以下のわず
かな圧力でも塊状となるため、成形時の材料充填が難し
く不均一な成形体となりやすい。
However, in general, graphite particles have a bulk density Q, Qig/cc
They are lightweight particles, and they become lumpy even under a slight pressure of several 9/crit or less, making it difficult to fill them with material during molding, which tends to result in non-uniform molded products.

更に圧縮されやすいために、肉厚品を成形する際相当深
い金型が必要となり、加工の上での制約が生じたり又金
型製作費用が高くなるという不利な点を有していた。
Furthermore, since it is easily compressed, a considerably deep mold is required when molding thick-walled products, which has the disadvantage of causing restrictions in processing and increasing mold production costs.

そのため本発明者らは先に、黒鉛粒子を圧縮比1.0〜
3.5のスクリューを装備した押出成形機によって当該
押出機の先端に取り付けられた金型に搬送圧入した後、
その金型に充填された黒鉛粒子を再圧縮することによっ
て肉厚成形品を簡単に成形する方法を提案した。
Therefore, the present inventors first developed graphite particles with a compression ratio of 1.0 to
After being conveyed and press-fitted into a mold attached to the tip of the extruder by an extrusion molding machine equipped with a 3.5 screw,
We proposed a method to easily form thick molded products by recompressing the graphite particles filled in the mold.

←特開昭56−42613)。しかしながらこの方法δ
こおいても金型へ充填された黒鉛粒子はいまだ嵩密度が
小さく大量の空気を含んでいるという欠点がある。
← Japanese Patent Publication No. 56-42613). However, this method δ
Even in this case, there is a disadvantage that the graphite particles filled into the mold still have a small bulk density and contain a large amount of air.

そのためにスクリューによって金型へ搬送圧入された黒
鉛粒子は、スクリューからの充填口に近い部分ではスク
リューからの圧力がよく伝わり黒鉛粒子がよく圧縮され
て嵩密度が大きくなるが、該充填口から離れた部分では
スクリューからの圧力伝達が不充分なため充填口に近い
部分と比べて嵩密度は小さい。
For this reason, the graphite particles that are conveyed and press-fitted into the mold by the screw are well-transmitted to the part near the filling port from the screw, which compresses the graphite particles well and increases the bulk density. Because pressure transmission from the screw is insufficient in this area, the bulk density is smaller than in the area near the filling port.

その結果その充填された黒鉛粒子を再圧縮して得られた
成形体においても物性が不均一であるという問題が未解
決のまま残っていた。
As a result, even in the molded body obtained by recompressing the filled graphite particles, the problem of nonuniform physical properties remained unsolved.

更にスクリューからの充填口から離れた部分には空気が
かなり含まれており、圧縮成形時にその空気が逃げるこ
とができないので成形体内にその空気が残り剥離現象を
起こしたり、またスクリューからの充填口に近い部分で
は、圧縮成形工程前にスクリューの圧力によって黒鉛粒
子が摩砕圧縮され、可撓性黒鉛粒子の特長である圧縮成
形性が圧縮成形工程前に損なわれてしまうため、でき上
がった成形体の強度が弱くなるという欠点があった。
Furthermore, a considerable amount of air is contained in the area away from the filling port from the screw, and this air cannot escape during compression molding, so it may remain inside the molded object and cause peeling phenomenon. In areas close to the compression molding process, the graphite particles are crushed and compressed by the pressure of the screw before the compression molding process, and the compression moldability, which is a feature of flexible graphite particles, is lost before the compression molding process. The disadvantage was that the strength was weakened.

又金型内に空気が残留していると、一定量の黒鉛粒子を
金型内へ充填する際にスクリューの先端部分でスリップ
が起きるため充填に時間がかかり生産効率も悪かった。
Furthermore, if air remained in the mold, slippage would occur at the tip of the screw when filling a certain amount of graphite particles into the mold, resulting in a time-consuming filling process and poor production efficiency.

本発明者らは、均一な物性をもち且つ残留空気によるふ
くれや剥離のない黒鉛成形体を得ることかでき更に金型
の長さが短かい経済的な成形金型について鋭意研究した
結果、本発明に到達したものである。
The inventors of the present invention have conducted intensive research into an economical molding die that has uniform physical properties and is capable of producing a graphite molded body without blistering or peeling due to residual air, and has a short mold length. This invention has been achieved.

従って、本発明の一つの目的は、成形金型に充填された
圧縮される前の可撓性黒鉛粒子の圧縮成形性が保たれた
状態で可撓性黒鉛粒子の嵩密度を均一に増加させること
により、均一な物性をもった成形体を効率よく生産する
ことのできる可撓性黒鉛粒子の成型金型を提供すること
である。
Therefore, one object of the present invention is to uniformly increase the bulk density of flexible graphite particles filled in a mold while maintaining compression moldability of the flexible graphite particles before being compressed. Accordingly, it is an object of the present invention to provide a mold for molding flexible graphite particles, which can efficiently produce a molded article having uniform physical properties.

更に本発明のもう−つの目的は可撓性黒鉛粒子を圧縮成
形するに際して金型の長さの短かい経済的な圧縮成形金
型を提供することである。
Another object of the present invention is to provide an economical compression molding mold having a short mold length for compression molding flexible graphite particles.

本発明によれば可撓性黒鉛粒子の圧縮成形を行なう成形
金型1こして、該金型の内部壁面の圧縮成形後の成形体
に接しない部分に対応する該金型の壁部に金型の内部と
外部とを連通ずる少なくとも1個の孔を設けたことを特
徴とする可撓性黒鉛粒子の圧縮成形金型が提供される。
According to the present invention, a molding die for compression molding flexible graphite particles is passed through a molding die, and a mold is placed on the wall portion of the mold corresponding to a portion of the inner wall surface of the mold that is not in contact with a molded article after compression molding. A mold for compression molding flexible graphite particles is provided, the mold being characterized by having at least one hole communicating between the inside and outside of the mold.

次に、添付図面を参照しながら本発明の一実施態様の構
成を説明する。
Next, the configuration of one embodiment of the present invention will be described with reference to the accompanying drawings.

第1図は可撓性黒鉛粒子の成形装置の全体図である。FIG. 1 is an overall view of a flexible graphite particle forming apparatus.

1はホッパー、2は竪型スクリュー押出機、3はプレス
シリンダー、4は取出しシリンダー 5は固定盤、6は
回転盤、7は本発明の成形金型、8は下パンチシリンダ
ー9は支柱、10は回転盤駆動モーターである。
1 is a hopper, 2 is a vertical screw extruder, 3 is a press cylinder, 4 is a take-out cylinder, 5 is a fixed plate, 6 is a rotary plate, 7 is a molding die of the present invention, 8 is a lower punch cylinder, 9 is a support column, 10 is a rotating disk drive motor.

該成形金型7にはその内部壁面の圧縮成形後の成形体に
接しない部分に対応する該金型の壁部に金型の内部と外
部とを連通ずる少なくとも1個の孔が設けられである。
The molding die 7 is provided with at least one hole that communicates the inside and outside of the mold in a wall portion of the mold corresponding to a portion of the inner wall surface that does not come into contact with the molded product after compression molding. be.

第2図は本発明の実施態様の一例を示す断面図であり、
竪型スクリュー押出機2から本発明の成形金型7へ可撓
性黒鉛粒子14が充填されている状態を示す。
FIG. 2 is a sectional view showing an example of an embodiment of the present invention,
A state in which flexible graphite particles 14 are filled from a vertical screw extruder 2 into a mold 7 of the present invention is shown.

11はスクリュー、12はシリンダー 13は孔である
11 is a screw, 12 is a cylinder, and 13 is a hole.

該成形金型7に設けられた孔13により、充填の際((
可撓性黒鉛粒子の脱気が行なわれ、可撓性黒鉛粒子の嵩
密度が均一に増大し、かつ黒鉛成形体への空気の残留が
防止される。
The holes 13 provided in the molding die 7 allow the filling ((
The flexible graphite particles are deaerated, the bulk density of the flexible graphite particles is uniformly increased, and air is prevented from remaining in the graphite molded body.

さらにまた、その孔の効果として充填の際にスリップが
起らず、充填効率がよくなる。
Furthermore, as a result of the holes, no slip occurs during filling, improving filling efficiency.

第1図及び第2図には竪型スクリュー押出機が示されて
いるが、横型スクリュー押出機でもよくスクリュー押出
機の型には依存せずに本発明の成形金型を用いることが
できる。
Although a vertical screw extruder is shown in FIGS. 1 and 2, a horizontal screw extruder may also be used, and the molding die of the present invention can be used regardless of the type of the screw extruder.

又本発明においては、原料として嵩密度0.OL!i’
/(A以下の可撓性膨張黒鉛粒子を液体中に浸漬し、該
黒鉛粒子が圧縮され密度増加すると同時に顆粒化する迄
攪拌し、それを液から分離して得られたものを乾燥して
得られた黒鉛顆粒が好ましく用いられる。
Further, in the present invention, the bulk density of the raw material is 0. OL! i'
/(Flexible expanded graphite particles of A or less are immersed in a liquid, stirred until the graphite particles are compressed and increased in density and simultaneously become granules, separated from the liquid, and the resulting product is dried. The obtained graphite granules are preferably used.

本発明ζこおいては黒鉛粒子とこの黒鉛顆粒を同様に可
撓性黒鉛粒子と呼ぶ。
In the present invention, graphite particles and graphite granules are similarly referred to as flexible graphite particles.

第3図は、第2図のようにして充填された可撓性黒鉛粒
子が圧縮成形された状態を示す図である。
FIG. 3 is a diagram showing a state in which the flexible graphite particles filled as shown in FIG. 2 are compression-molded.

15は圧縮成形された黒鉛成形体である。15 is a compression molded graphite molded body.

なお孔の径は用いられる黒鉛粒子又は黒鉛顆粒の粒度に
よって異なるが、一般には0.5 mm以上3mm以下
、好ましくは1 mm以上2mm以下である。
The diameter of the pores varies depending on the particle size of the graphite particles or graphite granules used, but is generally 0.5 mm or more and 3 mm or less, preferably 1 mm or more and 2 mm or less.

しかし孔の形状は限定されず円形その他どのような形で
もよい。
However, the shape of the hole is not limited and may be circular or any other shape.

又、孔は金型の外部と内部を直線的に貫通していなくて
もよく、曲がりくねった孔でもよい。
Further, the hole does not have to pass straight through the outside and inside of the mold, but may be a meandering hole.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は可撓性黒鉛粒子成形装置の全体図、第2図は可
撓性黒鉛粒子が成形金型へ供給されている状態を示す主
要部の断面図、第3図は可撓性黒鉛粒子が圧縮成形され
た状態を示す圧縮成形金型の断面図である。 7・・・・・・圧縮成形金型、13・・・・・・Li2
・・・・・・可撓性黒鉛粒子、15・・・・・・圧縮成
形された黒鉛成形体。
Figure 1 is an overall view of the flexible graphite particle molding device, Figure 2 is a sectional view of the main part showing the state in which flexible graphite particles are being supplied to the molding die, and Figure 3 is a diagram of the flexible graphite particle forming device. FIG. 2 is a cross-sectional view of a compression molding mold showing a state in which particles are compression molded. 7...Compression mold, 13...Li2
...Flexible graphite particles, 15... Compression molded graphite molded body.

Claims (1)

【特許請求の範囲】[Claims] 1 可撓性黒鉛粒子の圧縮成形を行なう成形金型にして
、該金型の内部壁面の圧縮成形後の成形体に接しない部
分に対応する該金型の壁部に金型の内部と外部とを連通
ずる少なくとも1個の孔を設けたことを特徴とする可撓
性黒鉛粒子の圧縮成形金型。
1. A molding mold for compression molding flexible graphite particles, and a wall portion of the mold corresponding to a portion of the inner wall surface of the mold that does not contact the molded product after compression molding, is provided with a mold inside and outside the mold. A mold for compression molding flexible graphite particles, characterized in that the mold is provided with at least one hole communicating with the two.
JP56155504A 1981-09-30 1981-09-30 Compression mold for flexible graphite particles Expired JPS5844447B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56155504A JPS5844447B2 (en) 1981-09-30 1981-09-30 Compression mold for flexible graphite particles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56155504A JPS5844447B2 (en) 1981-09-30 1981-09-30 Compression mold for flexible graphite particles

Publications (2)

Publication Number Publication Date
JPS5856814A JPS5856814A (en) 1983-04-04
JPS5844447B2 true JPS5844447B2 (en) 1983-10-03

Family

ID=15607484

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56155504A Expired JPS5844447B2 (en) 1981-09-30 1981-09-30 Compression mold for flexible graphite particles

Country Status (1)

Country Link
JP (1) JPS5844447B2 (en)

Also Published As

Publication number Publication date
JPS5856814A (en) 1983-04-04

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