JPS5857474B2 - cleaning composition - Google Patents
cleaning compositionInfo
- Publication number
- JPS5857474B2 JPS5857474B2 JP9001276A JP9001276A JPS5857474B2 JP S5857474 B2 JPS5857474 B2 JP S5857474B2 JP 9001276 A JP9001276 A JP 9001276A JP 9001276 A JP9001276 A JP 9001276A JP S5857474 B2 JPS5857474 B2 JP S5857474B2
- Authority
- JP
- Japan
- Prior art keywords
- glass
- water
- weight
- parts
- cleaning agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 12
- 238000004140 cleaning Methods 0.000 title claims description 9
- -1 alkyl ether sulfate amine salts Chemical class 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- 239000011521 glass Substances 0.000 description 17
- 239000012459 cleaning agent Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 4
- 239000003599 detergent Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- VXJCGWRIPCFWIB-UHFFFAOYSA-N hexadecasodium tetrasilicate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] VXJCGWRIPCFWIB-UHFFFAOYSA-N 0.000 description 1
- UFFNHUYHCDHKHK-UHFFFAOYSA-N hexapotassium trioxido(trioxidosilyloxy)silane Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] UFFNHUYHCDHKHK-UHFFFAOYSA-N 0.000 description 1
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
【発明の詳細な説明】
本発明は金属、プラスチック、硝子および塗装面等の表
面の洗浄用組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a composition for cleaning surfaces such as metals, plastics, glass and painted surfaces.
従来より種種のイオン系あるいは非イオン系界面活性剤
を配合した洗浄用組成物は数多く知られている。Many cleaning compositions containing various types of ionic or nonionic surfactants have been known.
しかしながら従来の組成物は単に洗浄のみを目的とする
ものが多く、洗浄後は洗浄剤が残留しないように洗い流
す必要があった。However, many of the conventional compositions are used only for cleaning purposes, and after cleaning, it is necessary to rinse the composition so that no cleaning agent remains.
即ち表面に洗浄剤が残留していると乾燥後に洗浄剤の結
晶が析出し表面に曇を生じさせるという欠点があった。That is, if the detergent remains on the surface, crystals of the detergent will precipitate after drying, resulting in a cloudy surface.
本発明は単に洗浄できるのみならず洗浄後に洗浄剤を除
去しなくても曇を生じさせることなく、更に塵埃、湿気
、油煙等の多い場所においても水滴や油滴を生せしめる
ことのない洗浄剤を提供するもので、アルキルエーテル
硫酸エステルアミン塩、アルキル硫酸エステルアミン塩
、アルキルアリルスルホン酸アミン塩からえらばれるア
ニオン界面活性剤１重量部に対し、水溶性硅酸塩０．０
０５〜２重量部およびアルカノールアミン０．５〜１０
重量部からなることを特徴とする組成物を２〜２０重量
係含最多る水溶液洗浄用組成物である。The present invention is a cleaning agent that not only can be cleaned, but also does not cause fogging even if the cleaning agent is not removed after cleaning, and does not generate water or oil droplets even in areas with a lot of dust, humidity, oil smoke, etc. 0.0 part by weight of a water-soluble silicate per 1 part by weight of an anionic surfactant selected from alkyl ether sulfate amine salts, alkyl sulfate ester amine salts, and alkylaryl sulfonic acid amine salts.
05-2 parts by weight and 0.5-10 parts by weight of alkanolamine
This is the largest aqueous cleaning composition containing 2 to 20 parts by weight of the composition.
本発明にいうアニオン界面活性剤としては通常洗浄剤と
して市販されているもので、アルキル基として炭素数１
８以下でありアミン塩となっていればよい。The anionic surfactant referred to in the present invention is one that is commercially available as a detergent and has an alkyl group of 1 carbon atom.
It is sufficient if it is 8 or less and becomes an amine salt.
アミン塩のアミンとしてはエタノールアミン、ジェタノ
ールアミン、トリエタノールアミン等のアルカノールア
ミンが好ましい。As the amine of the amine salt, alkanolamines such as ethanolamine, jetanolamine, and triethanolamine are preferred.
水溶性硅酸塩としてはオルト硅酸ナトリウム、メタ硅酸
ナトリウム、メタ硅酸カリウム、二硅酸ナトリウム、二
硅酸カリウム、四硅酸ナトリウム、水ガラスをあけるこ
とができる。Examples of water-soluble silicates include sodium orthosilicate, sodium metasilicate, potassium metasilicate, sodium disilicate, potassium disilicate, sodium tetrasilicate, and water glass.
かかる水溶性硅酸塩はアルカノールアミンと共に親水性
であり湿潤状態を保ち乾燥し難いものである。Such water-soluble silicates, together with alkanolamines, are hydrophilic and remain moist and difficult to dry.
本発明におけるアニオン界面活性剤と硅酸塩との配合割
合はアニオン界面活性剤１部に対して硅酸塩は０．００
５〜２重量部であることが必要である。The mixing ratio of anionic surfactant and silicate in the present invention is 0.00 part of silicate to 1 part of anionic surfactant.
It is necessary that the amount is 5 to 2 parts by weight.
またアルカノールアミンとしてはエタノールアミン、ジ
ェタノールアミン、トリエタノールアミン等が必要であ
りアニオン界面活性剤１部に対して０．５〜１０重量部
であることが必要である。Further, as the alkanolamine, ethanolamine, jetanolamine, triethanolamine, etc. are required, and it is necessary that the amount is 0.5 to 10 parts by weight per part of the anionic surfactant.
更に本発明組成物は２〜２０％の水溶液として使用する
ことが必要であり更にグリコール、グリセリン等の慣用
成分を添加してもよい。Furthermore, the composition of the present invention must be used as a 2-20% aqueous solution, and conventional ingredients such as glycol and glycerin may be added.
本発明にかかる洗浄剤を用いて金属、プラスチック、硝
子および塗膜等の表面を洗浄すれば、単に汚れが落ちる
のみならず洗浄後洗い流す必要なくそのまま放置してお
いても曇を生じることもなくまた油滴、水滴が付着する
こともない。If the surfaces of metals, plastics, glass, paint films, etc. are cleaned using the cleaning agent according to the present invention, not only will dirt be removed, but there will be no fogging even if the surfaces are left as they are without the need for rinsing after cleaning. Also, oil droplets and water droplets will not adhere to the surface.
この理由はアルカノールアミンおよび硅酸塩が共に易水
溶性で常に湿潤状態にあり界面活性剤の乾燥を防ぐと共
に微細な水滴や油滴が表面に生じても、それらの中に溶
けこみ水膜状態を形成し、大きな水滴に成長するのを防
ぐものである。The reason for this is that alkanolamines and silicates are both easily water-soluble and always in a wet state, which prevents the surfactant from drying out, and even if minute water droplets or oil droplets form on the surface, they dissolve into them and form a water film. This prevents water droplets from forming and growing into large droplets.
しかしながらかかる水膜は非常に薄いもので表面状態を
損うことがないのでガラス等の透明品において、その透
明性を害することが無い。However, such a water film is very thin and does not impair the surface condition, so it does not impair the transparency of transparent products such as glass.
更に硅酸塩は金属、プラスチック、硝子等と親和性があ
るので、本発明組成物をそれらの表面に強固に付着させ
る作用を示すものである。Furthermore, since silicates have an affinity for metals, plastics, glass, etc., they exhibit the effect of firmly adhering the composition of the present invention to those surfaces.
この作用により本１発明組成物が塗布された表面は長期
間にわたって表面を清浄に保つというすぐれた効果を示
すものである。Due to this action, the surface coated with the composition of the present invention exhibits an excellent effect of keeping the surface clean for a long period of time.
次に実施例によって本発明の詳細な説明する。Next, the present invention will be explained in detail by way of examples.
試験方法
硝子への乗り（密着性）、水滴防止性
清浄な硝子にスピンドル油を塗布し、過剰な油は布で拭
き取った後洗浄剤をガーゼに湿めらせて流れない程度に
塗布する。Test method Adhesion to glass (adhesion), water drop resistance Apply spindle oil to clean glass, wipe off excess oil with a cloth, then dampen gauze with cleaning agent and apply to an extent that it does not run off.
その際洗浄剤が硝子面へ均一に乗るかを調べる。At that time, check to see if the cleaning agent is applied evenly to the glass surface.
次に硝子板を洗浄剤の塗布面が上になる様に６０〜７０
度の傾斜をもたせて立て、霧状の水を散布しながら水滴
の発生する状態を調べる。Next, place the glass plate 60-70cm so that the surface coated with the cleaning agent is facing up.
Stand it upright at a slant, and examine how water droplets are generated while spraying water in the form of a mist.
結晶物析出性
１ 清浄な硝子面
清浄な硝子に洗浄剤を塗布し温度５０℃、湿度１５〜２
０％の恒温恒湿槽に４昼夜放置し、洗浄剤塗布面の白色
結晶物を調べる。Crystal precipitation 1 Clean glass surface Apply cleaning agent to clean glass, temperature 50℃, humidity 15-2
Leave it in a constant temperature and humidity chamber at 0% for 4 days and nights, and examine the surface coated with the cleaning agent for white crystals.
２ 汚染硝子面
清浄な硝子面を牛脂で汚染し、過剰油を布で拭き取った
後洗浄剤を上記と同様な方法で塗布し、上記と同様恒温
恒湿槽に放置して白色結晶物の析出を調べる。2 Contaminated glass surface Contaminate a clean glass surface with beef tallow, wipe off the excess oil with a cloth, apply a cleaning agent in the same manner as above, and leave it in a constant temperature and humidity bath as above to observe the precipitation of white crystals. Find out.
防曇性
硝子面を牛脂で汚塗した後、過剰油は布で拭き取り、上
記と同様な方法で洗浄剤を塗布する。After staining the antifogging glass surface with beef tallow, wipe off excess oil with a cloth and apply a cleaning agent in the same manner as above.
この硝子板を塗布面を下にして３０〜４５度の傾斜をも
たせて、８０〜８５℃の恒温水槽に被せる様に置き、
恒温水槽の水蒸気により、硝子面に水滴
や曇の発生する迄の時間を調べる。Place this glass plate with the coated side facing down at an angle of 30 to 45 degrees over a constant temperature water bath at a temperature of 80 to 85 degrees Celsius. Check the time.
防曇性実車試験
方法 曇が発生し前方が見え難くなった車（小型車、４
人乗車、外温的１８℃、車内温度２３℃、湿度７５係）
の内部硝子Ｏこ上記洗浄剤を塗布し、その時の硝子への
ぬれ易さ、防曇持続性およびハレーション（ヘイズ性自
動車用品工業りモリ止メ剤規格ＪＡＲＰ２１２・１９７
５に準ず）を調べた。Anti-fog test method for actual vehicle A car that has become foggy and difficult to see ahead (small car, 4
Passengers on board, external temperature 18℃, interior temperature 23℃, humidity 75)
The above cleaning agent is applied to the inner glass surface of the glass to determine the ease of wetting the glass, durability of anti-fogging, and haze (haze-related auto parts industry anti-fogging agent standard JARP212/197).
5) was investigated.
Claims (1)
硫酸エステルアミン塩、アルキルアリルスルホン酸アミ
ン塩からえらばれるアニオン界面活性剤１重量部に対し
、水溶性硅酸塩０．００５〜２重量部およびアルカノー
ル７２７０１５〜１０重量部からなることを特徴とする
組成物を２〜２０重量係含最多る水溶液洗浄用組成物。1 0.005 to 2 parts by weight of a water-soluble silicate and 727015 to 10 parts by weight of an anionic surfactant selected from alkyl ether sulfate amine salts, alkyl sulfate ester amine salts, and alkylaryl sulfonic acid amine salts. An aqueous cleaning composition comprising 2 to 20 parts by weight of the composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9001276A JPS5857474B2 (en) | 1976-07-27 | 1976-07-27 | cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9001276A JPS5857474B2 (en) | 1976-07-27 | 1976-07-27 | cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5314709A JPS5314709A (en) | 1978-02-09 |
| JPS5857474B2 true JPS5857474B2 (en) | 1983-12-20 |
Family
ID=13986742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9001276A Expired JPS5857474B2 (en) | 1976-07-27 | 1976-07-27 | cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5857474B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57119999A (en) * | 1981-01-20 | 1982-07-26 | Asahi Glass Co Ltd | Detergent composition |
| JPS5855112A (en) * | 1981-09-29 | 1983-04-01 | Mitsubishi Electric Corp | Controller for driving of plural loopers |
| JPS624890A (en) * | 1985-06-29 | 1987-01-10 | Nippon Foil Mfg Co Ltd | Surface treating agent |
-
1976
- 1976-07-27 JP JP9001276A patent/JPS5857474B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5314709A (en) | 1978-02-09 |
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