JPS589689B2 - Catalyst packed bed - Google Patents
Catalyst packed bedInfo
- Publication number
- JPS589689B2 JPS589689B2 JP51009278A JP927876A JPS589689B2 JP S589689 B2 JPS589689 B2 JP S589689B2 JP 51009278 A JP51009278 A JP 51009278A JP 927876 A JP927876 A JP 927876A JP S589689 B2 JPS589689 B2 JP S589689B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- wire mesh
- holding frame
- packed bed
- catalyst layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 36
- 230000003014 reinforcing effect Effects 0.000 claims description 11
- 238000005192 partition Methods 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 230000002093 peripheral effect Effects 0.000 description 5
- 230000002787 reinforcement Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00805—Details of the particulate material
- B01J2208/00814—Details of the particulate material the particulate material being provides in prefilled containers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Description
【発明の詳細な説明】
本発明は、各種燃焼装置、たとえばボイラの燃焼装置で
発生する燃焼排ガス中のNOx(窒素酸化物)を、内蔵
する触媒によって除去する脱硝装置における触媒充填層
の支持構造の改良に関する。Detailed Description of the Invention The present invention provides a support structure for a catalyst packed bed in a denitrification device that uses a built-in catalyst to remove NOx (nitrogen oxides) from combustion exhaust gas generated in various combustion devices, such as boiler combustion devices. Regarding the improvement of
一般に、この種の脱硝装置の触媒充填層の支持部材には
、燃焼装置からの排ガス中のダストが付着して脱硝効率
を低下させたり、排ガスの圧力損失が大きくなるという
問題点がある。Generally, the supporting member of the catalyst packed bed of this type of denitrification device has the problem that dust in the exhaust gas from the combustion device adheres to it, reducing the denitrification efficiency and increasing the pressure loss of the exhaust gas.
また使用の経年変化により該支持部材の老朽化を招くほ
か、高い触媒反応温度(350℃〜400℃)による熱
膨脹に耐えられなくなり、支持部材の破損を招くきいう
問題点があるが、従来上記問題点に対処できる触媒充填
層の支持構造は未だ開発されていない実情にある。In addition, there are problems in that the supporting member deteriorates due to changes over time, and it becomes unable to withstand thermal expansion due to high catalytic reaction temperatures (350°C to 400°C), leading to damage to the supporting member. The reality is that a support structure for a catalyst packed bed that can address these problems has not yet been developed.
本発明者は、上記従来の問題点を解決できる触媒充填層
の支持構造を提供することを目的として提案されたもの
で、少なくとも対向する2面を金属パネルまたは多孔板
で形成した平板状の触媒充填層において、対向する2面
が開放された複数個の仕切り区画8,9をもつ保持枠7
と、同保持枠7の各仕切り区画8,9内に、触媒を間に
はさんで取納された各2枚の金網パネル才たは多孔板1
2と、同金網パネルまたは多孔板12の外側に重ねられ
た補強グレーナング13および該補強グレーチング13
を上記保持枠7に保持するストツパ16とを具備するこ
とを特徴とする触媒充填層に係るものである。The present inventor has proposed a support structure for a catalyst packed bed that can solve the above-mentioned conventional problems. A holding frame 7 having a plurality of partition sections 8 and 9 with two opposing sides open in the packed bed.
In each of the partition sections 8 and 9 of the holding frame 7, there are two wire mesh panels or perforated plates 1 each with a catalyst sandwiched therebetween.
2, a reinforcing grating 13 superimposed on the outside of the wire mesh panel or perforated plate 12, and the reinforcing grating 13.
and a stopper 16 for holding the catalyst on the holding frame 7.
以下添付図面を参照しながら本発明につき具体的に説明
する。The present invention will be specifically described below with reference to the accompanying drawings.
第1図および第2図において、1は燃焼排ガス入口ダク
ト、2は反応器入口ダクト、3は反応器本体、4は触媒
層、5は反応器出口ダクト、6は排ガス出口ダクトで、
それら部材で複数の触媒層4を第1図に示す如く配設さ
れた脱硝装置を形成していて、燃焼排ガス入口ダクト1
に図示せざる燃焼装置から排出された燃焼排ガスは、反
応器入口ダクト2を経て反応器本体3に入り、ここで触
媒層4の触媒によってNOxを除去されたのち、反応器
出口ダクト5を経て排ガス出口ダクト6から外部へ排出
されるようになっていることは、従来の脱硝装置とほぼ
同様であるが、本発明における触媒層4は、つぎのよう
な構成となっている点で従来のものとは、その構成を全
く異にしている。1 and 2, 1 is a combustion exhaust gas inlet duct, 2 is a reactor inlet duct, 3 is a reactor main body, 4 is a catalyst layer, 5 is a reactor outlet duct, 6 is an exhaust gas outlet duct,
These members form a denitrification device in which a plurality of catalyst layers 4 are arranged as shown in FIG.
Combustion exhaust gas discharged from a combustion device (not shown) enters the reactor body 3 via the reactor inlet duct 2, where NOx is removed by the catalyst in the catalyst layer 4, and then passes through the reactor outlet duct 5. The fact that the exhaust gas is discharged to the outside from the outlet duct 6 is almost the same as in conventional denitrification equipment, but the catalyst layer 4 in the present invention is different from the conventional one in that it has the following structure. The structure is completely different from that of the original.
すなわち第2図において、7は互いに平行で等間隔な複
数段の横仕切り枠8および縦仕切り枠9で複数個の等し
い区画10に仕切られ、かつ対向する2面の開放された
長方形の触媒層保持枠で、同保持枠7の各区画10内に
は、つぎのような構成の触媒層単体A.がそれぞれ装着
される。That is, in FIG. 2, 7 is a rectangular catalyst layer partitioned into a plurality of equal compartments 10 by horizontal partition frames 8 and vertical partition frames 9 in parallel and equally spaced stages, and with two opposing sides open. In each compartment 10 of the holding frame 7, a single catalyst layer A. are installed respectively.
第3図および第4図において、11は均一な厚さの層状
触媒、12該層状触媒11の両側面に、これをはさんで
重ねられた金網パネル、13はそれら金網パネル12の
各外側面に重ねられた補強グレーチングで、それら部材
11,12および13で1つの触媒層単体A.を形成し
ている。3 and 4, reference numeral 11 denotes a layered catalyst of uniform thickness, 12 wire mesh panels stacked on both sides of the layered catalyst 11 with these panels in between, and 13 each outer surface of the wire mesh panels 12. With the reinforcing grating superimposed on the A. is formed.
この触媒層単体Aの金網パネル12は横系抜きもしくは
縦糸抜き網目構造となっており、その周縁枠部が第5図
に示す如く保持枠7および仕切り枠8,9の適所に突設
された金網パネル保持用あて板14(ただし仕切り枠8
,9の図示省略)と補強グレーチング13の周縁枠13
a間に挿入され、固定ボルト15によって補強グレーチ
ング13の周縁枠13aに固定されている。The wire mesh panel 12 of this single catalyst layer A has a mesh structure in which horizontal threads are removed or warp threads are removed, and its peripheral frame portions are protruded at appropriate locations on the holding frame 7 and partition frames 8 and 9, as shown in FIG. Wire mesh panel holding plate 14 (however, partition frame 8
, 9 (not shown) and the peripheral frame 13 of the reinforcing grating 13
a, and is fixed to the peripheral frame 13a of the reinforcing grating 13 with fixing bolts 15.
1だ補強グレーチング13は、その周縁枠13aと、該
周縁枠13aの相対する枠間に均一間隔に張られた複数
本の骨部材13bで形成されており、それら骨部材13
bで上記金網パネル12が均等に補強している。The single-sided reinforced grating 13 is formed of a peripheral frame 13a and a plurality of bone members 13b stretched at uniform intervals between opposing frames of the peripheral frame 13a.
In b, the wire mesh panel 12 is evenly reinforced.
16は上記触媒層単体A−を上記区画10内に保持する
ためのストツパで、同ストツパ16は図示の如く保持枠
7、仕切り枠8,9の区画10側適所の両側面に適宜な
固定手段たとえば溶接によって複数個固着されている。Reference numeral 16 denotes a stopper for holding the single catalyst layer A- in the compartment 10, and the stopper 16 is provided with suitable fixing means on both sides of the holding frame 7 and the partition frames 8, 9 at appropriate positions on the compartment 10 side as shown in the figure. For example, multiple pieces are fixed together by welding.
17はこれらストツパ16うちの相対するストツパ16
間に取付けられた補強材で、同補強材17は、上記補強
グレーチング13の外側の任意の個所を押える役割をも
つ。17 is the opposing stopper 16 of these stoppers 16.
This reinforcing material 17 is a reinforcing material installed between the reinforcing gratings 13 and has the role of pressing any part on the outside of the reinforcing grating 13.
そして上記構成の触媒層単体Aが、保持枠7の各区画1
0内に、上記のようにして装着されて本発明の触媒層4
を形成しており、該触媒層4が第1図に示す如く脱樋装
置の反応器本体3内に配設される。Then, the single catalyst layer A having the above structure is attached to each section 1 of the holding frame 7.
0, the catalyst layer 4 of the present invention is installed as described above.
The catalyst layer 4 is disposed within the reactor main body 3 of the gutter removal device as shown in FIG.
本発明の触媒層は、上記のように構成されており、従来
のものと同様に燃焼装置から排出される燃焼排ガス中の
NOxを除去する作用を行なうが、本発明によれば、
(1)保持枠7を複数個の等しい大きさの区画10に仕
切り、それら区画10内にそれぞれ触媒層単体Aを組込
む構成となっているため、製作容易で、設計標準化が可
能となり、ひいてはコストの低減をはかれる。The catalyst layer of the present invention is configured as described above, and performs the function of removing NOx in the combustion exhaust gas discharged from a combustion device in the same manner as the conventional catalyst layer.According to the present invention, (1) Since the holding frame 7 is divided into a plurality of equal-sized sections 10 and each of the catalyst layers A is incorporated in each section 10, manufacturing is easy, design standardization is possible, and costs can be reduced. It is measured.
(2)各触媒層単体Aの補強グレーチング13の骨部材
13bを縦または横方向とし、金網パネル12も横糸抜
きもしくは縦糸抜きの網目構造としているため、燃焼排
ガス中のダクトが付着しに<<、従って排ガスの圧力損
失も小さくてすみ、脱硝効率の低下を招くおそれがない
。(2) Since the frame members 13b of the reinforcing grating 13 of each catalyst layer unit A are oriented vertically or horizontally, and the wire mesh panel 12 also has a mesh structure with no weft threads or warp threads, the ducts in the combustion exhaust gas will not adhere. Therefore, the pressure loss of the exhaust gas can be small, and there is no risk of deterioration in denitrification efficiency.
(3)各触媒層単体A.は、その補強グレーチング13
がストツパ16により、また金網パネルがボルト取付け
となって各区画10内に装着されているので、経年変化
による取替えが簡単である。(3) Each catalyst layer alone A. The reinforcement grating 13
Since the wire mesh panels are mounted in each compartment 10 by the stoppers 16 and by bolts, replacement due to deterioration over time is easy.
(4)各触媒層単体A.の金網パネル12をボルト締め
構造としているため、高温での熱膨脹を金網パネル12
の金網で十分吸収できる。(4) Each catalyst layer alone A. Since the wire mesh panel 12 has a bolted structure, the wire mesh panel 12 can prevent thermal expansion at high temperatures.
A wire mesh can absorb enough water.
(5)触媒11を金網パネル12で挟持し、かつ均一間
隔の骨部材13bを有する補強グレーチング13で補強
しているので、均等な補強が得られ、触媒圧に対しても
十分に耐える構造となっており、耐久性が向上する。(5) Since the catalyst 11 is sandwiched between the wire mesh panels 12 and reinforced with the reinforcing grating 13 having rib members 13b at uniform intervals, uniform reinforcement can be obtained and the structure can sufficiently withstand catalyst pressure. This improves durability.
などの実用的効果を挙げることができる。The following practical effects can be mentioned.
なお上記例では、触媒11の両面に金網パネル12を用
いているが、これは多孔板としてもよい。In the above example, the wire mesh panels 12 are used on both sides of the catalyst 11, but these may be perforated plates.
図面は本発明の一実施例の概略説明図で、第1図は縦断
面図、第2図は第1図の■−■線断面図、第3図は保持
枠の1区画の正面図、第4図は第3図のIV−IV線矢
視図、第5図は第4図のV部拡大図である。
4……触媒充填層、7……保持枠、8,9……仕切り枠
、10……区画、11……触媒、12……金網パネル、
13……補強グレーチング、16……ストツパ。The drawings are schematic illustrations of an embodiment of the present invention, in which FIG. 1 is a longitudinal sectional view, FIG. 2 is a sectional view taken along the line ■-■ in FIG. 1, and FIG. 3 is a front view of one section of the holding frame. FIG. 4 is a view taken along the line IV--IV in FIG. 3, and FIG. 5 is an enlarged view of section V in FIG. 4... Catalyst packed bed, 7... Holding frame, 8, 9... Partition frame, 10... Compartment, 11... Catalyst, 12... Wire mesh panel,
13... Reinforcement grating, 16... Stoppa.
Claims (1)
で形成した平板状の触媒充填層において、対向する2面
が開放された複数個の仕切り区画8,9をもつ保持枠7
と、同保持枠7の各仕切り区画8,9内に、触媒を間に
はさんで収納された各2枚の金網パネルまたは多孔板1
2と、同金網パネルまたは多孔板12の外側に重ねられ
た補強グレーチング13および該補強グレーチング13
を上記保持枠7に保持するストツパ16とを具備するこ
とを特徴さする触媒充填層。1 A holding frame 7 having a plurality of partition sections 8 and 9 with open two opposing sides in a flat catalyst packed bed with at least two opposing sides formed of metal panels or perforated plates.
and two wire mesh panels or perforated plates 1 each housed in each of the partition sections 8 and 9 of the holding frame 7 with the catalyst sandwiched therebetween.
2, a reinforcing grating 13 stacked on the outside of the same wire mesh panel or perforated plate 12, and the reinforcing grating 13
and a stopper 16 for holding the catalyst in the holding frame 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51009278A JPS589689B2 (en) | 1976-02-02 | 1976-02-02 | Catalyst packed bed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51009278A JPS589689B2 (en) | 1976-02-02 | 1976-02-02 | Catalyst packed bed |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5292867A JPS5292867A (en) | 1977-08-04 |
| JPS589689B2 true JPS589689B2 (en) | 1983-02-22 |
Family
ID=11715991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51009278A Expired JPS589689B2 (en) | 1976-02-02 | 1976-02-02 | Catalyst packed bed |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS589689B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7125529B2 (en) * | 2002-11-12 | 2006-10-24 | Uop Llc | Apparatus and process for reacting over two catalyst beds |
-
1976
- 1976-02-02 JP JP51009278A patent/JPS589689B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5292867A (en) | 1977-08-04 |
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