JPS5917514B2 - sheath heater - Google Patents
sheath heaterInfo
- Publication number
- JPS5917514B2 JPS5917514B2 JP6995776A JP6995776A JPS5917514B2 JP S5917514 B2 JPS5917514 B2 JP S5917514B2 JP 6995776 A JP6995776 A JP 6995776A JP 6995776 A JP6995776 A JP 6995776A JP S5917514 B2 JPS5917514 B2 JP S5917514B2
- Authority
- JP
- Japan
- Prior art keywords
- metal pipe
- sheathed heater
- powder
- magnesia
- heater
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 19
- 239000000395 magnesium oxide Substances 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 230000002209 hydrophobic effect Effects 0.000 claims description 9
- 239000011810 insulating material Substances 0.000 claims description 3
- 229920002050 silicone resin Polymers 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000009413 insulation Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 230000007774 longterm Effects 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- -1 dimethylsiloxane Chemical class 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Landscapes
- Resistance Heating (AREA)
Description
【発明の詳細な説明】
本発明は、吸湿によるシーズヒーターの絶縁抵抗特性の
改良に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to improving the insulation resistance characteristics of a sheathed heater due to moisture absorption.
従来のシーズヒーターは、第1図に示すように金属パイ
プ1と、端子棒2を溶接したコイル状ヒーター3との間
に、電気絶縁材料4を充填した後金属パイプ1ごと減径
したものである。As shown in Fig. 1, a conventional sheathed heater is one in which an electrical insulating material 4 is filled between a metal pipe 1 and a coiled heater 3 to which a terminal bar 2 is welded, and then the diameter of the metal pipe 1 is reduced. be.
この電気絶縁材料としてはマグネシア粉末が最も広く使
用 9されるが、マグネシア粉末は吸湿性があるため、
室内雰囲気で容易に吸湿し絶縁抵抗を劣化させるという
欠点がある。そこで、このマグネシア粉末に、例えばシ
リコン樹脂を混合した後加熱し、マグネシア粉末表面に
シリコン樹脂被膜を形成させ 、3ることにより、充填
材料表面が撥水性を持ち、外部の湿気を各位に吸湿しな
くなり絶縁性能の劣化を防止する方法がある。しかし、
この方法でも溌水性剤にシリコン樹脂を用いるため、長
期間の使用あるいは異常高温使用後において、シリコン
樹脂中に含まれる有機基ヌ が分解、あるいは徐々に炭
化をおこし、それらが導電路を形成し、絶縁特性の劣化
をおこしやすいという欠点があつた。Magnesia powder is the most widely used electrically insulating material9, but since magnesia powder is hygroscopic,
It has the disadvantage that it easily absorbs moisture in the indoor atmosphere and deteriorates insulation resistance. Therefore, this magnesia powder is mixed with, for example, silicone resin and then heated to form a silicone resin film on the surface of the magnesia powder.3 By doing so, the surface of the filling material becomes water repellent and absorbs moisture from the outside. There are ways to prevent the deterioration of insulation performance. but,
This method also uses silicone resin as the water repellent agent, so after long-term use or use at abnormally high temperatures, the organic groups contained in the silicone resin decompose or gradually carbonize, forming conductive paths. However, the disadvantage was that the insulation properties tended to deteriorate.
本発明はかかる欠点を克服するもので、すなわち、シー
ズヒーターの絶縁特性が長期間の使用、o 異常温度で
の使用によつても劣化しないように、電気絶縁材料に用
いるマグネシア粉末など自体の吸湿性を改善し、かつ長
期間の使用によつても変質しないシーズヒーターを提供
するものである。The present invention overcomes these drawbacks, namely, to prevent the insulating properties of the sheathed heater from deteriorating even after long-term use or use at abnormal temperatures, magnesia powder used as an electrical insulating material absorbs moisture. To provide a sheathed heater that has improved properties and does not deteriorate even after long-term use.
以下本発明の一実施例を示す図面にもとづいて5 説明
すると、第2図において5はシーズヒーターの金属パイ
プで、その中央にはヒーター6を有し、かつこのヒータ
ー6の両端にはそれぞれ金属パイプ5より突出する端子
棒□を設けている。8は金属パイプ5内に充填されたマ
グネシア粉末で、こ0 の充填材8の表面には第3図に
示すように微粉末疎水性シリカ層9が形成されている。Below, based on the drawings showing one embodiment of the present invention, 5 will be explained. In FIG. A terminal bar □ protruding from the pipe 5 is provided. 8 is magnesia powder filled in the metal pipe 5, and a fine powder hydrophobic silica layer 9 is formed on the surface of the filler 8 as shown in FIG.
このシーズヒーターの製法の一例を次に示す。An example of a manufacturing method for this sheathed heater is shown below.
外径10.5mmの金属パイプ1の中心に両端に端子棒
Tがついたヒーター6を置き、金属パイプ1の5 下端
を仮封止して上端からマグネシア粉末と1wt%疎水性
シリカを良く混合したものを充填し、その後、金属パイ
プ1の外径を約8.0mmに減径して完成する。かかる
微粉末疎水性シリカ9は、その粒径が非0 常に細かく
、マグネシア粉末周囲に容易に附着しうる耐熱性物質で
ある。A heater 6 with terminal rods T attached at both ends is placed in the center of a metal pipe 1 with an outer diameter of 10.5 mm, the lower end of the metal pipe 1 is temporarily sealed, and magnesia powder and 1 wt % hydrophobic silica are thoroughly mixed from the upper end. After that, the outer diameter of the metal pipe 1 is reduced to about 8.0 mm, and the pipe is completed. Such finely powdered hydrophobic silica 9 has a very fine particle size and is a heat-resistant substance that can easily adhere to the periphery of the magnesia powder.
すなわち、ジメチルシロキサンなどで代表されるシリコ
ン樹脂のようにすべてのシリコン原子に1個またはそれ
以上の有機基が結合したものでなく、例えばSiO2を
母体と5 しその酸素原子の一部のみをメチル基などで
置換したもので、かつその粒径は0.1μ以下の微粉末
である。シリコン原子に結合した有機基は、単位面積あ
たりでは少いが、微粉末であるため表面積が大きく、微
粉末疎水性シリカ層として大きな疎水性を示す物質であ
る。さらに表面積が大きく吸着能力の大きい微粉末であ
るため、金属パイプ1の減径工程や、加熱冷却サイクル
でマグネシアが破砕した場合、破砕部の新らしいマグネ
シア結晶面に疎水性シリカの微粉末が移行附着し、その
面も溌水性を保持する。In other words, it is not a resin in which one or more organic groups are bonded to all silicon atoms as in silicone resins such as dimethylsiloxane, but, for example, SiO2 is used as a base material and only some of its oxygen atoms are methyl. It is substituted with a group, etc., and is a fine powder with a particle size of 0.1μ or less. Although the number of organic groups bonded to silicon atoms is small per unit area, since it is a fine powder, it has a large surface area and is a substance that exhibits great hydrophobicity as a fine powder hydrophobic silica layer. Furthermore, since it is a fine powder with a large surface area and high adsorption capacity, if magnesia is crushed during the diameter reduction process of the metal pipe 1 or during the heating and cooling cycle, the fine hydrophobic silica powder will migrate to new magnesia crystal surfaces in the crushed part. It adheres to the surface and maintains water repellency.
以上のように本発明シーズヒータ一は、金属パイプ内に
ヒーターおよび端子部を絶縁保持する充填材料の粒子表
面に疎水性微粉末シリカ層が形成されているため撥水性
を持ち、外部の湿気を容易に吸湿することはなくなる。
また、製造過程や、使用中の冷熱サイクルによるマグネ
シアの破砕があつても、その破砕面に疎水性シリカ層を
形成して撥水性を保持して吸湿による絶縁劣化を防止す
ることができる。また異常高温で充填材が加熱された場
合も疎水性微粉末シリカは、シリコン樹脂に較べ炭化速
度が遅く、かつ0.1μ以下の小さな粒子の集合体であ
るため炭化してもその炭素原子相互の密着が悪く電気絶
縁特性は保持されるなどの特長を有し、その工業的価値
は大である。As described above, the sheathed heater of the present invention has water repellency because a hydrophobic fine powder silica layer is formed on the surface of the particles of the filling material that insulates and holds the heater and terminals inside the metal pipe, and has water repellency and prevents external moisture. It no longer absorbs moisture easily.
Furthermore, even if magnesia is crushed during the manufacturing process or during the cooling and heating cycle during use, a hydrophobic silica layer is formed on the crushed surface to maintain water repellency and prevent insulation deterioration due to moisture absorption. Furthermore, even if the filler is heated to an abnormally high temperature, hydrophobic fine powder silica has a slower carbonization rate than silicone resin, and since it is an aggregate of small particles of 0.1μ or less, even if it is carbonized, the carbon atoms will not interact with each other. It has features such as poor adhesion and retained electrical insulation properties, and its industrial value is great.
第1図は従来例のシーズヒータ一の断面図、第2図は本
発明の一実施例を示すシーズヒータ一の断面図、第3図
は同要部の拡大図である。
5・・・・・・金属パイプ、6・・・・・・ヒーター
7・・・・・・端子棒、8・・・・・・充填材、9・・
・・・・シリカ層。FIG. 1 is a cross-sectional view of a conventional sheathed heater, FIG. 2 is a cross-sectional view of a sheathed heater according to an embodiment of the present invention, and FIG. 3 is an enlarged view of the essential parts thereof. 5...Metal pipe, 6...Heater
7...Terminal bar, 8...Filling material, 9...
...Silica layer.
Claims (1)
の間にマグネシア粉末などの電気絶縁材料を充填し、前
記金属パイプを減径してなるシーズヒーターにおいて、
前記マグネシア粉末と疎水性微粉末シリカを混合して前
記金属パイプ内に充填することを特徴とするシーズヒー
ター。1. In a sheathed heater formed by filling an electrical insulating material such as magnesia powder between a coiled heater equipped with a terminal bar and a metal pipe, and reducing the diameter of the metal pipe,
A sheathed heater characterized in that the magnesia powder and hydrophobic fine powder silica are mixed and filled into the metal pipe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6995776A JPS5917514B2 (en) | 1976-06-14 | 1976-06-14 | sheath heater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6995776A JPS5917514B2 (en) | 1976-06-14 | 1976-06-14 | sheath heater |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52153258A JPS52153258A (en) | 1977-12-20 |
| JPS5917514B2 true JPS5917514B2 (en) | 1984-04-21 |
Family
ID=13417632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6995776A Expired JPS5917514B2 (en) | 1976-06-14 | 1976-06-14 | sheath heater |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5917514B2 (en) |
-
1976
- 1976-06-14 JP JP6995776A patent/JPS5917514B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS52153258A (en) | 1977-12-20 |
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