JPS5919017B2 - Method for manufacturing hollow articles - Google Patents
Method for manufacturing hollow articlesInfo
- Publication number
- JPS5919017B2 JPS5919017B2 JP54053396A JP5339679A JPS5919017B2 JP S5919017 B2 JPS5919017 B2 JP S5919017B2 JP 54053396 A JP54053396 A JP 54053396A JP 5339679 A JP5339679 A JP 5339679A JP S5919017 B2 JPS5919017 B2 JP S5919017B2
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- resin
- mold cavity
- injected
- mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/1703—Introducing an auxiliary fluid into the mould
- B29C45/1704—Introducing an auxiliary fluid into the mould the fluid being introduced into the interior of the injected material which is still in a molten state, e.g. for producing hollow articles
- B29C45/1706—Introducing an auxiliary fluid into the mould the fluid being introduced into the interior of the injected material which is still in a molten state, e.g. for producing hollow articles using particular fluids or fluid generating substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/1703—Introducing an auxiliary fluid into the mould
- B29C45/1704—Introducing an auxiliary fluid into the mould the fluid being introduced into the interior of the injected material which is still in a molten state, e.g. for producing hollow articles
- B29C45/1706—Introducing an auxiliary fluid into the mould the fluid being introduced into the interior of the injected material which is still in a molten state, e.g. for producing hollow articles using particular fluids or fluid generating substances
- B29C2045/1707—Introducing an auxiliary fluid into the mould the fluid being introduced into the interior of the injected material which is still in a molten state, e.g. for producing hollow articles using particular fluids or fluid generating substances using a liquid, e.g. water
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
Description
【発明の詳細な説明】 本発明は、合成樹脂製中空物品の製造方法に係る。[Detailed description of the invention] The present invention relates to a method for manufacturing a synthetic resin hollow article.
合成樹脂による中空物品の成形法としては、従来押出パ
リリンを用いる方法が主に使用されており、あるいは2
個以上の部分成形体を接着等によつて結合して目的を達
成していた。As a method for molding hollow articles using synthetic resin, the method using extruded parylin has been mainly used, or
The objective was achieved by joining multiple molded parts together using adhesives or the like.
これ等の方法は、成形品の形状によつては限界があり、
また、成形費も高価となるため、より優れた中空部品の
成形法が要求されている。本出願人は、先に、上記問題
を解決すべくガス体を圧入することによつて中空物品を
成形する方法を特許願昭和48年第120318号によ
つて提案した。この方法によれば、可塑化合成樹脂を型
キャビティに注入した後、ガス体を圧入するか、或は溶
融合成樹脂を注入しつつガス体を圧入することによつて
、成形体の中空部を形成する。しカルながら、この方法
では、溶融合成樹脂とガス体との型キャビティ内の流動
性がかなり異なるため、均一な中空体を製造するには成
形品の形状に制限があつた。例えば、柱状物の成形には
適しているが、平板状物には問題が多い。すなわち、ガ
ス体は溶融合成樹脂中を先へ走りやすく、不均一な中空
体になりやすい。本発明の目的は、複雑な形状の中空物
品を容易かつ安価に成形することのできる製造方法を提
供することにある。木発明の、中空物品の製造方法は、
可塑化合成樹脂を型キャビティ内に注入し、その注入時
又は注入後に上記注入樹脂中に液体を圧入することによ
つて合成樹脂成形体の中空部を形成することを特徴とす
る。These methods have limitations depending on the shape of the molded product.
In addition, since the molding cost is also high, a better method for molding hollow parts is required. In order to solve the above-mentioned problem, the present applicant previously proposed in Patent Application No. 120318 of 1971 a method of molding a hollow article by pressurizing gas. According to this method, after the plasticized synthetic resin is injected into the mold cavity, the hollow part of the molded body is filled by press-fitting the gas, or by press-fitting the gas while injecting the molten synthetic resin. Form. However, in this method, the fluidity of the molten synthetic resin and the gas inside the mold cavity is quite different, so there are restrictions on the shape of the molded product in order to produce a uniform hollow body. For example, it is suitable for forming columnar objects, but has many problems when forming flat objects. That is, the gas body tends to run forward in the molten synthetic resin, and tends to form a non-uniform hollow body. An object of the present invention is to provide a manufacturing method that can easily and inexpensively mold a hollow article with a complicated shape. The method of manufacturing a hollow article invented by Wood is
The method is characterized in that a plasticized synthetic resin is injected into a mold cavity, and a liquid is pressurized into the injected resin during or after the injection to form a hollow portion of the synthetic resin molded body.
熱可塑性樹脂を用いて本発明を更に詳しく説明する。The present invention will be explained in more detail using a thermoplastic resin.
加熱可塑化された合成樹脂を、冷却された金型で形成さ
れた型キャビティに射出すると、射出中あるいは射出直
後では型キャビティに射出された合成樹脂の型壁面に接
する表層部が冷却されて固化し、射出された合成樹脂の
内核部は力l熱可塑化状態にある。この状態で、型キヤ
ビテイヘの同一注入口(ゲート)等から合成樹脂内核部
へ液体を圧入すると、液体は未だ可塑化状態にある内核
部の合成樹脂を先へ押し出して内核部へ入り、表層が合
成樹脂、内核が液体からなる中空体を形成する。圧入さ
れた液体は冷却固化された合成樹脂表層を破ることなく
、合成樹脂内部へ圧入されて良好な中空体を形成する。
本発明において合成樹脂としては、一般に使用されてい
るいかなる熱可塑性樹脂も使用することができ、また必
要に応じて熱硬化性樹脂も使用できる。When heat-plasticized synthetic resin is injected into a mold cavity formed by a cooled mold, during or immediately after injection, the surface layer of the synthetic resin in contact with the mold wall cools and solidifies. However, the inner core of the injected synthetic resin is in a thermoplastic state. In this state, when liquid is pressurized into the synthetic resin inner core from the same injection port (gate) etc. to the mold cavity, the liquid pushes out the synthetic resin in the inner core, which is still in a plasticized state, and enters the inner core, causing the surface layer to Forms a hollow body whose inner core is made of synthetic resin and liquid. The injected liquid is injected into the synthetic resin without breaking the surface layer of the cooled and solidified synthetic resin, forming a good hollow body.
In the present invention, any commonly used thermoplastic resin can be used as the synthetic resin, and if necessary, a thermosetting resin can also be used.
樹脂には染顔料、増量剤、ガラス繊維等の各種添加剤を
添加し得る。本発明において液体とは、常温で液状の物
質を意味し、例えば水、グリセリン、流動パラフイン、
作動油等を包含し、特に水が好ましい。Various additives such as dyes and pigments, extenders, and glass fibers may be added to the resin. In the present invention, liquid means a substance that is liquid at room temperature, such as water, glycerin, liquid paraffin,
This includes hydraulic oil and the like, with water being particularly preferred.
液体は、圧入時に、注入樹脂の成形温度附近に加熱され
ていることが好ましく、水を使用した場合は、加熱状態
で液相を維持するに十分な加圧状態、すなわち高温高圧
の液体として型内に圧入することが好ましい。本発明の
製造方法を以下添附図面を参照しながら説明する。It is preferable that the liquid be heated to around the molding temperature of the injected resin at the time of press-fitting. If water is used, the liquid should be heated to a sufficient pressure to maintain the liquid phase in the heated state, that is, as a high-temperature, high-pressure liquid. It is preferable to press fit into the inside. The manufacturing method of the present invention will be explained below with reference to the accompanying drawings.
第1図において、射出シリンダ1内に、樹脂の可塑化及
び射出を行なう公知構造のスクリユ一2によつて可塑化
された樹脂9を貯め、型11及び12で作られた型キヤ
ビテイ13を満たすには不充分な量の可塑化樹脂9を型
キヤビテイ13に注入した後、引続きノズル部8に設け
られた液体注 二人管4から液体を型キヤビテイ13内
の可塑化樹脂中に圧入する。In FIG. 1, plasticized resin 9 is stored in an injection cylinder 1 by a screw 2 having a known structure for plasticizing and injecting the resin, and fills a mold cavity 13 made of molds 11 and 12. After injecting an insufficient amount of plasticized resin 9 into the mold cavity 13, liquid is subsequently pressurized into the plasticized resin in the mold cavity 13 from the liquid injection tube 4 provided in the nozzle portion 8.
液体注入管4は、ノズル部の中央に設置された支持部材
3に固定されている。圧入された液体は、可塑化樹脂内
に侵入して、中空部を構成する内壁面を形成する。別に
設けた液体 工圧入用ピストンシリンダ装置5のピスト
ン6の前進により、弁7を通して管路7Aからシリンダ
前部10内に供給された液体が注入管4を通して送られ
る。第2図は、本発明の方法を実施するための装置3の
別の例を示しており、金型の本発明に係る部分のみを示
す。The liquid injection tube 4 is fixed to a support member 3 installed at the center of the nozzle section. The injected liquid enters the plasticized resin and forms an inner wall surface constituting the hollow portion. Due to the advance of the piston 6 of the separately provided liquid press-fitting piston-cylinder device 5, the liquid supplied into the cylinder front part 10 from the pipe 7A through the valve 7 is sent through the injection pipe 4. FIG. 2 shows another example of a device 3 for implementing the method of the invention, showing only the inventive part of the mold.
可塑化樹脂は、金型14及び15に形成されたスプル一
17、ランナー18、ゲート19を経て、金型15及び
16で構成された型キヤビテイ20内へ注入される。ラ
ンナー18の途 5中には可塑化樹脂中へ液体を圧入す
るための弁21が設けてあり、この弁21は、シリンダ
装置23の、ビストン23Aで分割されたシリンダ室2
3B,23Cに加圧流体を24及び25で示す口より出
し入れすることにより駆動される。型キ 4ヤビテイ2
0を満たすには不充分な量の可塑化樹脂を型キヤビテイ
20内に注入した後、弁21を押し下げて通路26から
液体を圧入することにより、型キヤビテイ20を可塑化
樹脂と液体で満たし、表層が樹脂、内核が液体の成形体
を得ることができる。通路26を通して液体を圧入した
後、引続き切換弁27を液体流入口28からガス体流入
口29に切換え、通路26を通してガス体を型キヤビテ
イ20内に圧入し、排出口22から成形体の内核を構成
している液体を排出させて中空部を得る。なお、これま
で述べてきた実施例では可塑化樹脂注入後液体を圧入し
ているが、液体の圧入は、可塑化樹脂を注入しながら同
時に行なうこともできる。The plasticized resin passes through sprues 17, runners 18, and gates 19 formed in the molds 14 and 15, and is injected into a mold cavity 20 constituted by the molds 15 and 16. A valve 21 for pressurizing liquid into the plasticized resin is provided in the middle 5 of the runner 18, and this valve 21 is connected to the cylinder chamber 2 of the cylinder device 23, which is divided by the piston 23A.
It is driven by supplying and withdrawing pressurized fluid from ports 24 and 25 to 3B and 23C. Type key 4 Yabitei 2
After injecting an insufficient amount of plasticizing resin into the mold cavity 20 to fill the mold cavity 20, the mold cavity 20 is filled with the plasticizing resin and the liquid by pressing down the valve 21 and pressurizing the liquid from the passage 26, A molded article having a resin surface layer and a liquid inner core can be obtained. After injecting the liquid through the passage 26, the switching valve 27 is subsequently switched from the liquid inlet 28 to the gas inlet 29, the gas is injected into the mold cavity 20 through the passage 26, and the inner core of the molded body is discharged from the outlet 22. The constituting liquid is drained to obtain a hollow part. In the embodiments described so far, the liquid is injected after the plasticizing resin is injected, but the liquid can also be injected at the same time as the plasticizing resin is being injected.
可塑化樹脂の大部分を注入した後、残りの可塑化樹脂の
注入と液体の圧入とを同時に行なうことが特に好ましい
。成形すべき物品の形状によつては、液体が表層の樹脂
層を破り、型表面再現性が悪く、成形が困難な場合があ
るが、この様な場合には、型キヤビテイにガス圧をかけ
た状態で形成を行なうと良い。After most of the plasticized resin has been injected, it is particularly preferred to simultaneously inject the remaining plasticized resin and press in the liquid. Depending on the shape of the article to be molded, the liquid may break the surface resin layer, resulting in poor mold surface reproducibility and difficulty in molding.In such cases, apply gas pressure to the mold cavity. It is best to perform the formation in a state where the
成形すべき物品が厚肉の場合、表層の樹脂層が厚くなり
すぎる場合があるが、この様な場合には第1図に12で
示す可動型を液体圧入時に後退させて型キヤビテイを拡
大すると好ましい結果を得ることができる。なお、これ
を樹脂注入時のキヤビテイが薄肉の場合に適用すると、
極めて均一な薄い表層を持つ中空体を得ることができる
。中空体の成形経過を第3図に示す。第3図に於て、型
30,31で形成された型キヤビテイ32に、導管33
、型キヤビテイ32をとりまく溝34より加圧ガスを注
人して型キヤビテイを加圧状態に保つ(3A)。型分割
面には、型キヤビテイを加圧状態に保つためO−リング
35が設置されている。加圧状態に保たれた型キヤピテ
イ32に注入口36より可塑化合成樹脂37を型キヤビ
テイを満たすに不充分な量注入し(3B)、次いで同じ
注入口36より、加熱した液体を型キヤピテイ内の可塑
化樹脂中に注人して、中空体を成形する(3C)。次に
実施例を示す。If the article to be molded is thick, the surface resin layer may become too thick. In such cases, the movable mold shown at 12 in Figure 1 can be moved back during liquid injection to enlarge the mold cavity. Favorable results can be obtained. Furthermore, if this is applied when the cavity during resin injection is thin,
Hollow bodies with extremely uniform and thin surface layers can be obtained. Figure 3 shows the process of forming the hollow body. In FIG. 3, a conduit 33 is inserted into a mold cavity 32 formed by molds 30 and 31.
, pressurized gas is injected from the groove 34 surrounding the mold cavity 32 to maintain the mold cavity in a pressurized state (3A). An O-ring 35 is installed on the mold dividing surface to keep the mold cavity under pressure. Plasticized synthetic resin 37 is injected into the pressurized mold cavity 32 through the injection port 36 in an amount insufficient to fill the mold cavity (3B), and then heated liquid is injected into the mold cavity through the same injection port 36. The mixture is poured into a plasticized resin to form a hollow body (3C). Next, examples will be shown.
実施例 1
第1図に示した装置を用い、直径1501fr!Ft、
厚さ7Trftの円盤状型物を成形した。Example 1 Using the apparatus shown in Fig. 1, a diameter of 1501 fr! Ft,
A disk-shaped molded product with a thickness of 7 Trft was molded.
熱可塑性樹脂としてポリエチレン「スタイロン470」
(登録商標、旭タウ(株)製品)を用い、液体として2
00℃に加熱した水を用いた。型キヤビテイを5m厚に
して溶融樹脂を満たし、次いで加熱水を150Kg/C
wiの圧力で圧入し、水の注入圧力で可動型12を徐徐
に後退して型キヤビテイを拡大し、7wrm厚とした。
樹脂を型内で冷却後中空な円盤状型物を得た。実施例
2第2図に示した装置を用い、直径20rm、長さ30
0rvnの円柱状型物を成形した。Polyethylene “Stylon 470” as thermoplastic resin
(registered trademark, Asahi Tau Co., Ltd. product) as a liquid.
Water heated to 00°C was used. The mold cavity was made 5m thick and filled with molten resin, then heated water was added at 150kg/C.
The mold cavity was expanded to a thickness of 7 wrm by gradually retracting the movable mold 12 with the water injection pressure.
After cooling the resin in the mold, a hollow disk-shaped mold was obtained. Example
2 Using the device shown in Figure 2, the diameter is 20rm and the length is 30mm.
A cylindrical mold of 0 rvn was molded.
熱可塑性樹脂としてABS樹脂「スターラック◆100
」(登録商標、旭タウ(株)製造品)を用い、液体とし
て200℃に加熱した水を用いて。型キヤビテイを満た
す量の70%の可塑化樹脂を注入し、次いで通路26よ
り弁21を経て加熱水を150Kf/Cdで圧入し、水
の注入圧力で型キヤビテイを満たし樹脂を型内で冷却後
中空な円柱状型物を得た。ABS resin “Starlac◆100” is used as a thermoplastic resin.
” (registered trademark, manufactured by Asahi Tau Co., Ltd.) and water heated to 200°C as the liquid. 70% of the amount of plasticized resin to fill the mold cavity is injected, then heated water is injected from the passage 26 through the valve 21 at 150 Kf/Cd, the mold cavity is filled with water injection pressure, and the resin is cooled in the mold. A hollow cylindrical mold was obtained.
第1図は、本発明を実施するに適した成形装置の一例を
示す断面図、第2図は、本発明を実施するに適した別の
例を示す断面図、第3図は、本発明の方法により中空体
を成形する経過を示す概説図である〇第1図において、
1・・・射出シリンダ、2・・・射出スクリユ一、3・
・・支持部材、4・・・液体注人管、5・・・ピストン
シリンダ装置、6・・・ピストン、7・・・弁、8・・
・ノズル部、9・・・可塑化樹脂、10・・・シリンダ
前部、11,12・・・型、13・・・型キヤビテイ、
第2図において、14,15,16・・・金型、17・
・・スプル一、18・・・ランナー、19・・・ゲート
、20・・・型キヤビテイ、21・・・弁、22・・・
型キヤビテイ入口、23・・・シリンダ装置、23A・
・・ピストン、23B,23C・・・シリンダ室、24
,25・・・加圧流体、26・・樋路、27・・・切換
弁、28・・・液体流入口、29・・・ガス体流入口、
第3図において、30,31・・・型、32・・・型キ
ヤビテイ、33・・・導管、34・・・溝、35・・・
0−リング、36・・・注入口、37・・・可塑化合成
樹脂。FIG. 1 is a cross-sectional view showing an example of a molding apparatus suitable for carrying out the present invention, FIG. 2 is a cross-sectional view showing another example suitable for carrying out the present invention, and FIG. In Figure 1, which is a schematic diagram showing the process of forming a hollow body by the method,
1... Injection cylinder, 2... Injection screw, 3.
...Support member, 4...Liquid injection pipe, 5...Piston cylinder device, 6...Piston, 7...Valve, 8...
・Nozzle part, 9... Plasticized resin, 10... Cylinder front part, 11, 12... Mold, 13... Mold cavity,
In Fig. 2, 14, 15, 16...mold, 17...
...Sprue, 18...Runner, 19...Gate, 20...Type cavity, 21...Valve, 22...
Mold cavity inlet, 23... Cylinder device, 23A.
...Piston, 23B, 23C...Cylinder chamber, 24
, 25... Pressurized fluid, 26... Gutter passage, 27... Switching valve, 28... Liquid inlet, 29... Gas body inlet,
In Fig. 3, 30, 31... type, 32... type cavity, 33... conduit, 34... groove, 35...
0-ring, 36... Inlet, 37... Plasticized synthetic resin.
Claims (1)
入時又は注入後に上記注入樹脂中に液体を圧入すること
によつて合成樹脂成形体の中空部を形成することを特徴
とする中空物品の製造方法。1. A hollow article characterized in that a plasticized synthetic resin is injected into a mold cavity and a liquid is pressurized into the injected resin during or after the injection to form a hollow part of a synthetic resin molded body. Production method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54053396A JPS5919017B2 (en) | 1979-05-02 | 1979-05-02 | Method for manufacturing hollow articles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54053396A JPS5919017B2 (en) | 1979-05-02 | 1979-05-02 | Method for manufacturing hollow articles |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58137496A Division JPS6059847B2 (en) | 1983-07-29 | 1983-07-29 | Method for manufacturing molded articles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55291A JPS55291A (en) | 1980-01-05 |
| JPS5919017B2 true JPS5919017B2 (en) | 1984-05-02 |
Family
ID=12941656
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54053396A Expired JPS5919017B2 (en) | 1979-05-02 | 1979-05-02 | Method for manufacturing hollow articles |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5919017B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6414318U (en) * | 1987-07-14 | 1989-01-25 | ||
| JPH06270239A (en) * | 1993-03-19 | 1994-09-27 | Toyoda Gosei Co Ltd | Injection hollow mold |
| JPH08500301A (en) * | 1992-05-18 | 1996-01-16 | シンプレス リミテッド | Injection molding method and apparatus |
| WO2018101433A1 (en) * | 2016-12-01 | 2018-06-07 | パナソニックIpマネジメント株式会社 | Molding device, method for producing molded article using molding device, and method for producing molding device |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6265781A (en) * | 1985-09-14 | 1987-03-25 | 株式会社 シスコ | Selector usable to not only powdered and granular body, etc.employed in plastic molding machine but also various material having specific gravity difference |
| WO1992003273A1 (en) * | 1990-08-23 | 1992-03-05 | Rema Industries & Services Pty. Ltd. | A machine to form articles from thermoplastic plastics materials |
| JP2541569Y2 (en) * | 1991-11-09 | 1997-07-16 | 有限会社阿興産業 | Powder input device |
| JP2884455B2 (en) * | 1991-12-27 | 1999-04-19 | 旭化成工業株式会社 | Hollow injection molding method and pressurized fluid press-in / discharge device used therefor |
| JP5658186B2 (en) * | 2012-02-23 | 2015-01-21 | 株式会社クニムネ | Method for producing hollow injection molded body |
-
1979
- 1979-05-02 JP JP54053396A patent/JPS5919017B2/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6414318U (en) * | 1987-07-14 | 1989-01-25 | ||
| JPH08500301A (en) * | 1992-05-18 | 1996-01-16 | シンプレス リミテッド | Injection molding method and apparatus |
| JPH06270239A (en) * | 1993-03-19 | 1994-09-27 | Toyoda Gosei Co Ltd | Injection hollow mold |
| WO2018101433A1 (en) * | 2016-12-01 | 2018-06-07 | パナソニックIpマネジメント株式会社 | Molding device, method for producing molded article using molding device, and method for producing molding device |
| JPWO2018101433A1 (en) * | 2016-12-01 | 2019-10-24 | パナソニックIpマネジメント株式会社 | Mold apparatus, method for manufacturing molded product using mold apparatus, and method for manufacturing mold apparatus |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55291A (en) | 1980-01-05 |
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