JPS5932301B2 - Hatsuposhi Toseizou Yourei Yakling - Google Patents
Hatsuposhi Toseizou Yourei YaklingInfo
- Publication number
- JPS5932301B2 JPS5932301B2 JP50155806A JP15580675A JPS5932301B2 JP S5932301 B2 JPS5932301 B2 JP S5932301B2 JP 50155806 A JP50155806 A JP 50155806A JP 15580675 A JP15580675 A JP 15580675A JP S5932301 B2 JPS5932301 B2 JP S5932301B2
- Authority
- JP
- Japan
- Prior art keywords
- air
- cooling
- cylindrical body
- annular
- resin cylindrical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Extrusion Moulding Of Plastics Or The Like (AREA)
Description
【発明の詳細な説明】
本発明は発泡シート製造用冷却リングに関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a cooling ring for manufacturing foam sheets.
従来、発泡可能な熱可塑性樹脂を押出機に通し、該押出
機の先端に設けた環状スリットダイより筒状態に押出し
て発泡を開始させた後、該筒状体の内部空洞に冷却ドラ
ムもしくは環状スリットダイを通して空気を吹き込み該
筒状体を直径方向に膨張させて冷却ドラムヘ引取り冷却
固化させろことによつて発泡シートを製造する方法に於
て、該発泡シートの表面に発泡を抑えたスキン層を附与
すべく冷却する装置としてエアリシダが提案されていろ
。Conventionally, a foamable thermoplastic resin is passed through an extruder and extruded into a cylindrical shape through an annular slit die provided at the tip of the extruder to start foaming. In a method of producing a foam sheet by blowing air through a slit die to expand the cylindrical body in the diametrical direction, the cylindrical body is taken to a cooling drum, and cooled and solidified. Airicida has been proposed as a cooling device to provide this.
しかし乍ら、上記従来のエアリシダを用いて、発泡シー
トの表面に発泡を抑えたスキン層を附与すべく気泡の成
長力ν」、さい間、即ち環状スリットダイに近い位置に
エアリシダを設置して、該エアリシダより冷却用の空気
を吹きつけた場合に於て、理由は不明確だが、環状スリ
ットダイより押出された筒状体は、発泡を開始した位置
より冷却ドラムヘ引取られる途中の位置で直径方向に゛
波打ち″を発生するので、エアリシダより吹きつけられ
る冷却用空気は丁度前記゛波打ち″部を冷却することに
なり、該゛波打ち″部の波頂部と波底部とではエアリシ
ダよりの距離に差を生じ、従つて、吹きつけられる空気
の効果が異つてくることにより得られた発泡シートは押
出方向にスキン層の厚い部分と薄い部分が押出方向に沿
つて交互に帯状に発生すると云う欠点があつた。However, in order to add a skin layer that suppresses foaming to the surface of the foam sheet by using the conventional air cider, the air cider is installed between the bubble growth force ν', that is, at a position close to the annular slit die. When cooling air is blown from the air slit die, for reasons that are unclear, the cylindrical body extruded from the annular slit die is moved from the position where foaming started to the position on the way to the cooling drum. Since ``undulations'' are generated in the diametrical direction, the cooling air blown from the air ferns cools the ``undulated'' portions, and the distance between the crest and bottom of the ``undulated'' portions from the air ferns is large. As a result, the resulting foam sheet has thick and thin skin layers that alternate in the extrusion direction in the form of bands. There were flaws.
一方、上記゛波打ち″の発生をみる場合に於て、エアリ
シダを該゛波打ち″が消滅した位置に設置しても空気を
吹きつけるだけでは冷却効果が乏しく、得られた発泡シ
ートは前記したスキン層の厚薄による帯の発生はみられ
ないが表面の気泡が大きく、スキン層も極めて薄く非常
に割れ易いものであつた。On the other hand, when observing the occurrence of the above-mentioned "waving", even if the air cider is installed in a position where the "waving" has disappeared, simply blowing air has a poor cooling effect, and the resulting foam sheet does not have the same effect as the above-mentioned skin. Although no bands were observed due to the thickness of the layer, the bubbles on the surface were large, and the skin layer was extremely thin and easily broken.
また、従来のエアリングを用いた方法に於て、得られた
発泡シートはエアリングによつて冷却される面と冷却ド
ラムによつて冷却される面とでシート表面の平滑性が異
ると云う欠点もあつた。In addition, in the conventional method using an air ring, the surface smoothness of the obtained foam sheet differs between the surface cooled by the air ring and the surface cooled by the cooling drum. There were also some drawbacks.
また、従来のエアリングを用いた方法に於て、得られた
発泡シートは帯電性が大きく可燃性ガスを発泡剤に用い
る製造方法では、その発泡シートと製造設備又は作業者
との間に発生する放電火花により火災を生じる危険があ
ると共にその発泡シートには埃か附着し易いという欠点
があつた。本発明者等はこれらの欠点に鑑み工夫の結果
、単なるエアリングよりも冷却効果か大きく、その使用
によつて前記した如き欠点のない発泡シートを得ること
が出来る新規な冷却リングを発明した。即ち、本発明は
(1)発泡体用押出機の先端に設けられた環状スリツト
と該環状スリツトより押出された樹脂筒状体を膨張させ
冷却する目的で設けられた冷却ドラムとの間に、該樹脂
筒状体に外接する様に設置した冷却リングに於て、該樹
脂筒状体と接する面が平滑であつて、温度調節用流体が
通過可能な環状流路を有し、且つ空気供給口、該空気供
給口に連繋された環状の空気溜り及び該空気溜りに直結
した空気吹出口を有すことを特徴とする発泡シート製造
用冷却リング、(2)上記(1)の発泡シート製造用冷
却リングに於て、空気供給口に噴霧ノズルを連結し、該
噴霧ノズルに空気導入口と水導入口とを配した冷却リン
グである。In addition, in the conventional method using an air ring, the obtained foam sheet has a high chargeability, and in the production method using flammable gas as a blowing agent, generation of electricity between the foam sheet and manufacturing equipment or workers There is a risk of fire caused by sparks caused by the discharge, and the foam sheet has the disadvantage that dust tends to adhere to it. In view of these drawbacks, the present inventors have devised a novel cooling ring that has a greater cooling effect than a simple air ring, and by its use, it is possible to obtain a foamed sheet free of the above-mentioned drawbacks. That is, the present invention provides (1) between an annular slit provided at the tip of a foam extruder and a cooling drum provided for the purpose of expanding and cooling the resin cylindrical body extruded from the annular slit; In the cooling ring installed so as to circumscribe the resin cylindrical body, the surface in contact with the resin cylindrical body is smooth, has an annular flow path through which a temperature regulating fluid can pass, and has an air supply. A cooling ring for manufacturing a foamed sheet, characterized by having a port, an annular air reservoir connected to the air supply port, and an air outlet directly connected to the air reservoir, (2) manufacturing the foamed sheet according to (1) above. In this cooling ring, a spray nozzle is connected to an air supply port, and an air introduction port and a water introduction port are arranged on the spray nozzle.
本発明による冷却リングに於て、樹脂筒状体に直接接触
する平滑な面の押出軸に対する角度は冷却ドラムに向つ
てや\開いているかまたはその面は円壌体の内側面の一
部である形状が好ましく、空気吹出口には、噴霧ノズル
によつて霧状に分散された水滴が空気溜りに於て凝集し
て大粒の水滴となり、該水滴が筒状体表面にそのま\吹
きつけられない様に該水滴の案内溝を有したものが好適
であり、また該空気溜りに吹出す空気量を吹出口全周に
亘り均一にする目的で邪魔板を設けることも効果がある
。但し、エアリングより吹き出す空気中に分散せしめら
れた水の量が少ない場合は前記した案内溝を設けなくて
も差支えない。In the cooling ring according to the present invention, the angle of the smooth surface in direct contact with the resin cylinder with respect to the extrusion axis is slightly open toward the cooling drum, or the surface is a part of the inner surface of the cylinder. A certain shape is preferable, and the air outlet has a shape in which water droplets dispersed in a mist form by a spray nozzle aggregate in an air pool to form large water droplets, and the water droplets are sprayed as they are onto the surface of the cylindrical body. It is preferable to have a guide groove for the water droplets so as not to cause the water droplets to flow, and it is also effective to provide a baffle plate for the purpose of making the amount of air blown into the air pocket uniform over the entire circumference of the outlet. However, if the amount of water dispersed in the air blown out from the air ring is small, the guide groove described above may not be provided.
次に、図面によりながら本発明の代表的な実施態様を説
明する。Next, typical embodiments of the present invention will be described with reference to the drawings.
第1図に於て、冷却リング1は冷却媒体を通す環状流路
2、及び空気供給口3より供給された空気を溜め、吹出
口5に直結し空気の流れを均一化する邪魔板6を備えた
空気溜り4を有しており、且つ環状流路2の隔壁に中心
軸を通り内面が平滑である空洞10を有したものである
。In FIG. 1, a cooling ring 1 has an annular flow path 2 through which a cooling medium passes, and a baffle plate 6 that stores air supplied from an air supply port 3 and is directly connected to an air outlet 5 to equalize the flow of air. In addition, the annular flow path 2 has a partition wall with a cavity 10 passing through the central axis and having a smooth inner surface.
また、第2図に於て、冷却リング1は、冷却媒体を通す
環状流路2を有すと共に、空気供給口3に空気導入孔8
と水導人孔9とを有す噴霧ノズルを備え、空気溜り4と
空気の吹出口5を繋ぐ部分に該空気溜4の内壁面に附着
した水滴を排出する為の溝11を有し、且つ環状流路2
の隔壁に中心軸を通り内面が平滑である空洞を有したも
のである。In addition, in FIG. 2, the cooling ring 1 has an annular flow path 2 through which a cooling medium passes, and an air introduction hole 8 at an air supply port 3.
and a water guide hole 9, and a groove 11 for discharging water droplets adhering to the inner wall surface of the air reservoir 4 at a portion connecting the air reservoir 4 and the air outlet 5, and annular flow path 2
The partition wall has a cavity that passes through the central axis and has a smooth inner surface.
次に第1図に示した冷却リングを用いた発泡シートの製
造について述べる。Next, the production of a foam sheet using the cooling ring shown in FIG. 1 will be described.
第3図に於てダイ32の環状スリツト部33より押出さ
れた樹脂筒状体20は発泡を開始すると共に、第4図に
示す如く直径方向にゞ波打ち7を生じる。In FIG. 3, the resin cylindrical body 20 extruded from the annular slit portion 33 of the die 32 starts foaming, and at the same time generates undulations 7 in the diametrical direction as shown in FIG.
ここで、該樹脂筒状体20を環状スリツト33より押出
すと同時に該樹脂筒状体20の内部空洞21に冷却ドラ
ム15の中を通る空気導管16の先端に設けた吹出孔1
7より空気を吹き込み、該樹脂筒状体20を直径方向に
膨張せしめ冷却ドラム15への引取りを容易にすると同
時に前記ゞ波打ち7をいくらかでも減少させる。上記状
態に於て、樹脂筒状体20を環状流路2を通る水の如き
冷却媒体によつて温度調節された前記冷却リング1の内
側の平滑な面に接触させて表面の気泡の成長を抑えると
共に平滑性を与え、次いで空気溜り4に供給した空気を
吹出口5より吹きつけつつ冷却ドラム15を覆う様に引
取る。Here, at the same time as the resin cylindrical body 20 is extruded from the annular slit 33, a blow-off hole 1 is provided at the tip of an air conduit 16 passing through the cooling drum 15 into the internal cavity 21 of the resin cylindrical body 20.
Air is blown through 7 to expand the resin cylindrical body 20 in the diametrical direction, making it easier to take it into the cooling drum 15 and at the same time reducing the waving 7 to some extent. In the above state, the resin cylindrical body 20 is brought into contact with the inner smooth surface of the cooling ring 1 whose temperature is controlled by a cooling medium such as water passing through the annular flow path 2 to prevent the growth of air bubbles on the surface. Then, the air supplied to the air pocket 4 is blown from the air outlet 5 and taken over so as to cover the cooling drum 15.
こ\で空洞21に吹き込まれた空気は筒状体20の膨張
を助成すると共に該筒状体20を冷却リング1への接触
を強くする様に働き、更には冷却ドラム15の表面と筒
状体20の間の潤滑剤的役割を果す。而して前記潤滑剤
的役割に要す空気量は微量である為冷却ドラム15の後
端に設けた排気弁18によつて調整される。かくして冷
却ドラム15に引取られた樹脂筒状体20は導管19を
通る水の如き冷却媒体によつて間接的に冷却固化させる
と共に内側表面に平滑性を附与され、次いで通常は該冷
却ドラム15の後端に設けた刃(図示せず)によつて切
り開かれ発泡シートとして巻きとられる。The air blown into the cavity 21 in this way assists the expansion of the cylindrical body 20 and works to strengthen the contact between the cylindrical body 20 and the cooling ring 1, and furthermore, the air blown into the cavity 21 acts to strengthen the contact between the cylindrical body 20 and the cooling drum 15 and the cylindrical body. It acts as a lubricant between the bodies 20. Since the amount of air required to act as a lubricant is very small, it is adjusted by an exhaust valve 18 provided at the rear end of the cooling drum 15. The resin cylindrical body 20 thus taken up by the cooling drum 15 is indirectly cooled and solidified by a cooling medium such as water passing through the conduit 19, and smoothness is imparted to the inner surface. It is cut open by a blade (not shown) provided at the rear end and rolled up as a foam sheet.
以上の如き方法で得られた発泡シートはシート全面に亘
りスキン層が均一に附与され、且つ表裏面共平滑な面を
有するものである。The foamed sheet obtained by the above method has a skin layer uniformly applied over the entire surface of the sheet and has smooth surfaces on both the front and back surfaces.
次に、第2図に示した如き冷却リングを用いて発泡シー
トを製造した場合、水滴を含む空気を筒状体に吹きつけ
ることにより更に厚いスキン層を附与し得るばかりでな
く発生した静電気が前記水滴を通して放電される為に帯
電の少い発泡シートが得られる。Next, when a foam sheet is manufactured using a cooling ring as shown in Figure 2, not only can a thicker skin layer be added by blowing air containing water droplets onto the cylindrical body, but also the static electricity generated is discharged through the water droplets, resulting in a foamed sheet with little charge.
次に本発明による冷却リングを用いて発泡シートを製造
した実施例について述べる。Next, an example in which a foamed sheet was manufactured using the cooling ring according to the present invention will be described.
実施例 1
ペンタン6重量%を含むポリスチレンペレツト100部
をタルク1部及び重炭酸ソーダ、タエン酸のそれぞれ0
.5部をスクリユ一径50m1L.L/D24の押出機
にて溶融混練せしめ、該押出機の先端に設けたスリツト
巾0.5mm及びスリツト径60mTfL0環状スリツ
トダイより筒状体に押出した。Example 1 100 parts of polystyrene pellets containing 6% by weight of pentane were mixed with 1 part of talc and 0 each of sodium bicarbonate and taenoic acid.
.. Transfer 5 parts to a screwdriver with a diameter of 50 m and 1 L. The mixture was melt-kneaded in an extruder of L/D24 and extruded into a cylindrical body through a TfL0 annular slit die with a slit width of 0.5 mm and a slit diameter of 60 m provided at the tip of the extruder.
次いで、該筒状体の内部空洞に冷却ドラムを介して空気
を吹き込み該筒状体を直径方向に膨張せしめた後、冷却
水によつて温度調節された内径120m1Lの冷却リン
グの内面に該樹脂筒状体の外面を接触せしめ、且つ冷却
リングより空気を吹きつけて該樹脂筒状体の表面の発泡
を抑えて、外径150關の冷却ドラムへ引取つた。こ\
で該冷却ドラムに冷却水を循環することによつて前記筒
状体を冷却固化せしめ、冷却ドラムの後端に設けた刃に
よつて該筒状体を切り開きロール状に巻き取つた。かく
して得られた発泡シートは厚み1.0m7!L発泡倍率
10倍の両面に厚いスキン層を全面に亘り均一に附与さ
れた発泡シートであつた。実施例 2
実施例1に於て、第2図に示した冷却リングを用い、空
気1立力メートル当り409の水を霧状に分散せしめた
空気を筒状体に吹きつけることによつて発泡シートを製
造した。Next, air is blown into the inner cavity of the cylindrical body through a cooling drum to expand the cylindrical body in the diametrical direction, and then the resin is placed on the inner surface of a cooling ring with an inner diameter of 120 ml whose temperature is controlled by cooling water. The outer surfaces of the cylindrical bodies were brought into contact with each other, and air was blown from a cooling ring to suppress foaming on the surface of the resin cylindrical bodies, and the resin cylindrical bodies were taken to a cooling drum having an outer diameter of 150 mm. child\
The cylindrical body was cooled and solidified by circulating cooling water through the cooling drum, and the cylindrical body was cut open with a blade provided at the rear end of the cooling drum and wound up into a roll. The foam sheet thus obtained has a thickness of 1.0m7! It was a foam sheet with a foaming ratio of 10 times and a thick skin layer uniformly provided on both sides. Example 2 In Example 1, using the cooling ring shown in Figure 2, foaming was carried out by blowing air in which 409 water per cubic meter of air was dispersed in the form of a mist onto the cylindrical body. The sheet was manufactured.
かくして得た発泡シートは製造時に於ける帯電も少く、
従つて該発泡シートと製造設備又は作業者との間に起る
放電もなく、可燃性ガスを発泡剤に使用しても何ら危険
を感じなかつた。The foam sheet obtained in this way has less static electricity during manufacturing,
Therefore, no electrical discharge occurred between the foam sheet and manufacturing equipment or workers, and no danger was felt even when flammable gas was used as a foaming agent.
更に該発泡シートは厚み0.6mm発泡倍率8倍で表裏
共等しい厚みのスキン層を有すと共に平滑な面を有すシ
ートであつた。Furthermore, the foamed sheet had a thickness of 0.6 mm, an expansion ratio of 8 times, skin layers of equal thickness on both sides, and a smooth surface.
また、該発泡シートの表面及び裏面を別々にグラビア式
印刷機にて印刷したところ、両方共印刷時に於る張力や
曲げ等による破断もなく印刷も極めて鮮明なものであつ
た。Furthermore, when the front and back sides of the foamed sheet were printed separately using a gravure printing machine, the printing was extremely clear, with no breakage due to tension or bending during printing on both sides.
以上述べた如く、本発明の発泡シート製造用冷却リング
を用いれば、発泡シートにスキン層が厚く且つ均一に附
与し得ると共に表面の平滑性も優れたものにすることが
出来る。As described above, by using the cooling ring for producing a foamed sheet of the present invention, a thick and uniform skin layer can be provided to the foamed sheet, and the surface can also be made to have excellent smoothness.
また本発明によれば、発泡シートの製造時に於ける静電
気の帯電が少く、これに起因する放電火花による火災の
如き危険性は極めて低いものであり、可燃性ガスを発泡
剤として安全に使用し得るものである。Furthermore, according to the present invention, there is little static electricity during the production of foam sheets, and the risk of fire caused by discharge sparks is extremely low, making it possible to safely use flammable gas as a foaming agent. It's something you get.
第1図は本発明による冷却リングの一例の断面及び側面
をそれぞれ半分づつ示したものであり、第2図は本発明
による別の実施例の主要部のみの断面図である。
第3図は本発明による冷却リングを用いて発泡シートを
製造する装置の一部を半分づつ断面図と側面図で示し、
第4図は第3図中のA−A′線に沿つた断面を示したも
のである。1・・・・・・冷却リング、2・・・・・・
環状流路、3・・・・・・空気供給口、4・・・・・・
空気溜り、5・・・・・・吹出口、6・・・・・・邪魔
板、7・・・・・・噴霧ノズル、8・・・・・・空気導
入孔、9・・・・・・水導入孔、10・・・・・・空洞
、11・・・・・・溝、15・・・・・・冷却ドラム、
16・・・・・・導管、17・・・・・・吹出孔、18
・・・・・・排気弁、19・・・・・・導管、20・・
・・・・樹脂筒状体、21・・・・・・空洞、32・・
・・・・ダイ、33・・・・・・環状スリツト。FIG. 1 shows a cross section and a side surface of an example of a cooling ring according to the present invention in half, and FIG. 2 is a sectional view of only the main part of another embodiment according to the present invention. FIG. 3 shows a part of an apparatus for manufacturing a foam sheet using a cooling ring according to the present invention in a cross-sectional view and a side view, respectively;
FIG. 4 shows a cross section taken along the line AA' in FIG. 3. 1... Cooling ring, 2...
Annular flow path, 3...Air supply port, 4...
Air pocket, 5...Blowout port, 6...Baffle plate, 7...Spray nozzle, 8...Air introduction hole, 9...・Water introduction hole, 10...Cavity, 11...Groove, 15...Cooling drum,
16...Conduit, 17...Blowout hole, 18
... Exhaust valve, 19 ... Conduit, 20 ...
... Resin cylindrical body, 21 ... Cavity, 32 ...
...Die, 33...Annular slit.
Claims (1)
該環状スリットより押出された樹脂筒状体を膨張させ、
冷却する目的で設けられた冷却ドラムとの間に、該樹脂
筒状体に外装する様に設置した冷却リングに於て、該樹
脂筒状体に接する面が平滑であつて、温度調節用流体が
通過可能な環状流路を有し、且つ空気供給口、該空気供
給口に連繋された環状の空気溜り及び該空気溜りに直給
した空気吹出口を有すことを特徴とする発泡シート製造
用冷却リング。 2 発泡体用押出機の先端に設けられた環状スリットと
該環状スリットより押出された樹脂筒状体を膨張させ、
冷却する目的で設けられた冷却ドラムとの間に、該樹脂
筒状体に外接する様に設置した冷却リングに於て、該樹
脂筒状体に接する面が平滑であつて、温度調節用流体が
通過可能な環状流路を有し、且つ空気供給口、該空気供
給口に連繋された環状の空気溜り及び該空気溜りに直結
した空気吹出口を有し、該空気供給口に噴霧ノズルを連
結し、該噴霧ノズルに空気導入孔と水導入孔とを配した
ことを特徴とする発泡シート製造用冷却リング。[Claims] 1. Expanding an annular slit provided at the tip of a foam extruder and a resin cylindrical body extruded through the annular slit,
A cooling ring installed externally on the resin cylindrical body between the cooling drum provided for the purpose of cooling, and having a smooth surface in contact with the resin cylindrical body, manufacturing a foamed sheet characterized by having an annular flow path through which air can pass, an air supply port, an annular air pocket connected to the air supply port, and an air outlet directly supplied to the air pocket. cooling ring. 2 Expanding the annular slit provided at the tip of the foam extruder and the resin cylindrical body extruded through the annular slit,
A cooling ring installed between a cooling drum provided for the purpose of cooling and circumscribing the resin cylindrical body has a smooth surface in contact with the resin cylindrical body, and has a temperature regulating fluid. has an annular flow path through which air can pass, and has an air supply port, an annular air reservoir connected to the air supply port, and an air outlet directly connected to the air reservoir, and a spray nozzle is connected to the air supply port. 1. A cooling ring for producing a foamed sheet, characterized in that the spray nozzle is connected with an air introduction hole and a water introduction hole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP50155806A JPS5932301B2 (en) | 1975-12-27 | 1975-12-27 | Hatsuposhi Toseizou Yourei Yakling |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP50155806A JPS5932301B2 (en) | 1975-12-27 | 1975-12-27 | Hatsuposhi Toseizou Yourei Yakling |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5280362A JPS5280362A (en) | 1977-07-06 |
| JPS5932301B2 true JPS5932301B2 (en) | 1984-08-08 |
Family
ID=15613850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50155806A Expired JPS5932301B2 (en) | 1975-12-27 | 1975-12-27 | Hatsuposhi Toseizou Yourei Yakling |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5932301B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5640528A (en) * | 1979-09-11 | 1981-04-16 | Mitsui Toatsu Chem Inc | Foamed polystylene sheet and manufacture thereof |
| JP5688247B2 (en) * | 2010-08-10 | 2015-03-25 | 積水化成品工業株式会社 | Method for producing resin foam sheet and method for repairing extrusion equipment |
-
1975
- 1975-12-27 JP JP50155806A patent/JPS5932301B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5280362A (en) | 1977-07-06 |
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