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JPS5933469B2 - Method of forming a wear-resistant surface on metal parts - Google Patents
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JPS5933469B2 - Method of forming a wear-resistant surface on metal parts - Google Patents

Method of forming a wear-resistant surface on metal parts

Info

Publication number
JPS5933469B2
JPS5933469B2 JP3398075A JP3398075A JPS5933469B2 JP S5933469 B2 JPS5933469 B2 JP S5933469B2 JP 3398075 A JP3398075 A JP 3398075A JP 3398075 A JP3398075 A JP 3398075A JP S5933469 B2 JPS5933469 B2 JP S5933469B2
Authority
JP
Japan
Prior art keywords
metal
wear
powder
forming
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP3398075A
Other languages
Japanese (ja)
Other versions
JPS51108630A (en
Inventor
卓郎 清水
肇 野村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NTN Corp
Original Assignee
NTN Toyo Bearing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NTN Toyo Bearing Co Ltd filed Critical NTN Toyo Bearing Co Ltd
Priority to JP3398075A priority Critical patent/JPS5933469B2/en
Publication of JPS51108630A publication Critical patent/JPS51108630A/en
Publication of JPS5933469B2 publication Critical patent/JPS5933469B2/en
Expired legal-status Critical Current

Links

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  • Lining Or Joining Of Plastics Or The Like (AREA)

Description

【発明の詳細な説明】 この発明は、加圧鋳造法又はダイカスト法で以つて成形
される金属部材に耐摩性表面を形成する方法、特に未焼
成の自己潤滑性耐摩合成樹脂粉末を金属表面に接合する
と同時に焼成硬化し、更に樹脂のゲル化温度近辺で再焼
成して所定表面硬さを得る方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for forming a wear-resistant surface on a metal member formed by a pressure casting method or a die-casting method, and in particular a method for forming an unfired self-lubricating wear-resistant synthetic resin powder on a metal surface. The present invention relates to a method of baking and hardening the resin at the same time as bonding, and then re-baking it at around the gelling temperature of the resin to obtain a predetermined surface hardness.

従来金属部材の摺動部に、焼成された充填剤入りテフロ
ンシート等を接着して耐摩耗性を改良する方法が採られ
ている。
Conventionally, a method has been adopted to improve wear resistance by adhering a fired Teflon sheet containing a filler to the sliding portion of a metal member.

そしてこれ等のシートの接着にはエポキシ系等の接着剤
や熱可塑性フィルム状接着剤等が用いられている。とこ
ろが前者の場合は、被接着物に対して固定圧を加え、室
温または昇温後、接着に要する時間放置して硬化させる
必要があり、後者の場合は接着剤のフィルムを界面に挟
み、治具を介してボルト締或はホットプレス法により、
フィルムの融点まで加熱し、加熱後冷却して、接着作業
を終了させる必要があつた。即ち、これらの作業には手
作業が多く、接着剤や加熱、加圧のための装置を必要と
し、1回の接着操作に長時間を要し非能率的であつた。
更に、焼成されたシート等を使用しているため表面を複
雑な形状にし難い等の欠点がある。而して、充填剤入り
テフロンシートは未焼成の充填剤入りテフロン等の粉末
を加熱、加圧焼成して作られる。
Epoxy adhesives, thermoplastic film adhesives, and the like are used to bond these sheets together. However, in the former case, it is necessary to apply a fixed pressure to the object to be adhered and leave it to cure for the time required for adhesion at room temperature or after raising the temperature, whereas in the latter case, a film of adhesive is sandwiched between the interface and cure By bolting or hot press method through tools,
It was necessary to heat the film to its melting point and then cool it down to complete the bonding process. That is, these operations required a lot of manual work, required adhesives and equipment for heating and pressurizing, and were inefficient as one bonding operation took a long time.
Furthermore, since a fired sheet or the like is used, there is a drawback that it is difficult to form the surface into a complicated shape. The filler-containing Teflon sheet is made by heating and pressurizing unfired powder of filler-containing Teflon or the like.

従つて未焼成の粉末を溶湯によつて加熱、加圧すると、
焼成と同時にシートを成形することができる。更に、未
焼成め充填剤入テフロン粉末などが或る温度で加熱・加
圧されると硬化と同時に金属部材に機械的に接合される
性質を有している。更にまた、シート原料は未焼成の粉
末であるから凹凸を有する金型に充填可能である。この
発明は、上記充填剤入りテフロンシートの製法並びに原
料の性質に着目し、且つ加圧鋳造法又はダイカスト法で
金属部材を成形する過程での温度と圧力を利用し、成形
と同時金属部材の表面に耐摩性を有する充填剤入りテフ
ロン等の層を接着剤なしで且つ1工程で形成する方法を
提供せんとするものであつて、以下、この発明の構成を
第1図及び第2図a、bに示す実施例に従つて説明する
と次の通りである。第1図に於て、1はシリンダ、2は
下型、3は油圧プレスのプランジャ−に取付けられた加
圧のための上型、4は耐摩性及び自己潤滑性を有し、且
つ高温に耐える未焼成の充填剤入りテフロン等の粉末、
5は溶湯の注入により金型内の粉末の飛散を防止すると
共にアルミニウム合金或は亜鉛合金と焼成硬化後の樹脂
層を強固に1本化させるための金属性の円板で、この金
属製円板は溶湯温度以下の低融点で合金化する金属材料
、例えば鉛でつくる。
Therefore, when unfired powder is heated and pressurized with molten metal,
The sheet can be formed at the same time as firing. Furthermore, when unfired filler-containing Teflon powder is heated and pressurized at a certain temperature, it has the property of being hardened and mechanically bonded to a metal member at the same time. Furthermore, since the sheet raw material is an unfired powder, it can be filled into a mold having irregularities. This invention focuses on the manufacturing method of the filler-containing Teflon sheet and the properties of the raw materials, and utilizes the temperature and pressure during the process of forming a metal member by pressure casting or die casting, and simultaneously forms the metal member. It is an object of the present invention to provide a method for forming a layer of filled Teflon or the like having wear resistance on the surface without using an adhesive and in one step. , b is as follows. In Figure 1, 1 is a cylinder, 2 is a lower mold, 3 is an upper mold for pressurization attached to the plunger of a hydraulic press, and 4 is a mold that has wear resistance, self-lubricating properties, and is resistant to high temperatures. Powder such as Teflon with unfired filler that can withstand
5 is a metallic disk that prevents scattering of powder in the mold by pouring molten metal and also firmly integrates the aluminum alloy or zinc alloy and the resin layer after firing and hardening; The plate is made of a metal material that alloys with a low melting point below the temperature of the molten metal, such as lead.

6はアルミニウム合金或は亜鉛合金等の低融点金属、7
は鋳造後の製品と下型2をシリンダ1からとり出すため
のノツクアウト、8はノツクアウトピン、9はシリンダ
1の保温と注入後の溶湯6の冷却速度勾配を緩和するた
めのバンドヒータである。
6 is a low melting point metal such as aluminum alloy or zinc alloy, 7
8 is a knock-out pin for taking out the cast product and the lower mold 2 from the cylinder 1, and 9 is a band heater for keeping the cylinder 1 warm and relaxing the cooling rate gradient of the molten metal 6 after pouring. .

尚、未焼成の粉末4は必要とする層の厚さにより充填量
は任意である。そして、充填粉末としては、テフロン或
は充填剤入りテフロンの外に未焼成のポリイミド樹脂粉
末を用いても良い。この発明は次の要領で実施する。
The amount of unfired powder 4 to be filled is arbitrary depending on the required thickness of the layer. As the filling powder, unfired polyimide resin powder may be used in addition to Teflon or filler-containing Teflon. This invention is carried out in the following manner.

即ち、金型内に未焼成粉末4が充填され、次いで金属製
の円板5が挿入され、溶湯6が注入される。そして溶湯
6が注入されると殆んど同時的に上型3が下降し、加圧
成型する。そして粉末4は溶湯6の熱と上型3の加圧に
より接合され、溶湯6の凝固冷却につれて焼成され、円
板5は溶湯6の熱により溶解し、上記焼成された樹脂層
と機械的に接合され、更に円板の溶湯とアルミニウム合
金等の溶湯とが凝固冷却により合金化され、その結果焼
成された樹脂層が金属面に接合される。次いで、冷却後
、ノツクアウト7が上昇し、製品と下型2をシリンダ1
から取り出し、ノツクアウトピン8により、製品と下型
2を分離する。尚、製品は必要に応じ外径及び表面層を
機械加工する。第2図aは、鋳造される金属製品の表面
に所定の凹凸10を成形と同時に形成し、且つこの凹凸
に沿つて充填剤入りテフロン等の焼成された層を同時に
形成した場合の正面図を示す。
That is, unfired powder 4 is filled into the mold, then a metal disk 5 is inserted, and molten metal 6 is injected. When the molten metal 6 is injected, the upper mold 3 is lowered almost simultaneously to perform pressure molding. Then, the powder 4 is joined by the heat of the molten metal 6 and the pressure of the upper mold 3, and is fired as the molten metal 6 solidifies and cools, and the disk 5 is melted by the heat of the molten metal 6 and mechanically connects with the fired resin layer. The molten metal of the disk and the molten metal of aluminum alloy or the like are solidified and cooled to form an alloy, and as a result, the fired resin layer is bonded to the metal surface. Next, after cooling, the knockout 7 rises and transfers the product and the lower mold 2 to the cylinder 1.
The product and the lower mold 2 are separated using the knockout pin 8. The outer diameter and surface layer of the product will be machined as necessary. Figure 2a shows a front view of a case in which predetermined irregularities 10 are formed on the surface of a metal product to be cast at the same time as the molding, and a fired layer of filler-containing Teflon or the like is simultaneously formed along the irregularities. show.

そして第2図bは、その製品の部分切断面である。未焼
成粉末が溶湯により加熱、加圧されると、粉末の塑性流
動か起り、円板の溶湯と粉末が複雑に入り組んだ状態と
なる。即、円板が溶解した溶湯を使用することにより粉
末とのからみ合により機械的接合が可能となる。又、円
板が溶解した溶湯とアルミニウム合金の溶湯との接触面
で合金化して両者を強固に1本化し、その結果樹脂層と
アルミニウム合金とが1本化される。この接合と同時に
、粉末が硬化されるが、この硬化層の硬さは未だ所定の
表面硬さに達していないので、樹脂のゲル化温度近辺で
再び焼成することによつて所定の表面硬さとすることが
必要である。尚11は円板の溶解凝固層である。以上説
明したように、この発明は金属摺動面に自己潤滑性耐摩
合成樹脂表面層を一体形成する方法において、金型内に
ポリテトラフルオロエチレン等の未焼成の自己潤滑性耐
摩合成樹脂粉末を充填し、次いでアルミニウム合金或は
亜鉛合金等からなる低融点合金の溶湯温度以下の低融点
で合金化する材料からなる所定厚さの金属製の板材を挿
入し、次いでアルミニウム合金或は亜鉛合金等からなる
低融点合金の溶湯を注入し、注入後上型で加圧成形する
ことにより、上記未焼成粉末を接合と同時に焼成硬化さ
せ、凝固した金属部材を金型より取出し、最後に上記樹
脂のゲル化温度近辺で再焼成して樹脂表面層を所定の表
面硬さにするから、極めて容易且つ確実に金属部材の成
形と同時にその表面にテフロン或は充填剤入りテフロン
の焼成接合を為すことができる。
FIG. 2b is a partial cross-section of the product. When the unfired powder is heated and pressurized by the molten metal, plastic flow of the powder occurs, resulting in a state in which the molten metal and the powder in the disk are intricately intertwined. That is, by using the molten metal in which the disc is melted, mechanical joining becomes possible through entanglement with the powder. In addition, the disk is alloyed at the contact surface between the molten metal and the molten aluminum alloy to firmly integrate the two into one, and as a result, the resin layer and the aluminum alloy are integrated into one. At the same time as this bonding, the powder is hardened, but since the hardness of this hardened layer has not yet reached the specified surface hardness, it is baked again at around the gelling temperature of the resin to achieve the specified surface hardness. It is necessary to. Note that 11 is the melted and solidified layer of the disk. As explained above, the present invention provides a method for integrally forming a self-lubricating, wear-resistant synthetic resin surface layer on a metal sliding surface, in which unfired self-lubricating, wear-resistant synthetic resin powder such as polytetrafluoroethylene is placed in a mold. Then, a metal plate of a predetermined thickness made of a material that is alloyed at a low melting point below the molten metal temperature of a low melting point alloy such as an aluminum alloy or a zinc alloy is inserted, and then a metal plate material of a predetermined thickness is inserted. The unfired powder is fired and hardened at the same time as bonding by injecting a molten metal of a low melting point alloy consisting of the above resin and press-forming it with an upper mold after injection.The solidified metal member is taken out from the mold, and finally the resin is Since the resin surface layer is re-fired at around the gelation temperature to a predetermined surface hardness, it is extremely easy and reliable to mold Teflon or filled Teflon onto the surface of the metal member at the same time. can.

尚、この場合、注入される溶湯の温度はいずれも金型内
に充填される樹脂粉末の融点や焼成温度より高いが、金
型内での成形は極く短時間に為されるので樹脂表面層の
熱による損傷の心配はない。また、使用される金属製の
板の厚さを調節することで、溶湯との合金化に要する熱
エネルギーの吸収量が変わり、樹脂粉末の焼成及び金属
表面への接合に供する適温を与えることができる。また
、この発明の方法は、金属表面に凹凸形状を同時成形し
、この凹凸に沿つて樹脂表面層の焼成と接合を為すこと
ができる上、接着剤を必要としない。
In this case, the temperature of the injected molten metal is higher than the melting point and firing temperature of the resin powder filled in the mold, but since the molding in the mold is done in a very short time, the resin surface There is no need to worry about heat damage to the layers. In addition, by adjusting the thickness of the metal plate used, the amount of thermal energy absorbed for alloying with the molten metal changes, making it possible to provide the appropriate temperature for firing the resin powder and bonding it to the metal surface. can. Further, the method of the present invention can simultaneously form an uneven shape on a metal surface, and perform baking and bonding of the resin surface layer along the unevenness, and does not require an adhesive.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明に係る実施例を示す断面図、第2図A
,bは成形と同時に形成される表面の凹凸形状を示す金
属部材の平面図並びに断面図である。 1・・・・・・シリンダ、2・・・・・・下型、3・・
・・・・上型、4・・・・・・未焼成の樹脂粉末、5・
・・・・・金属製の板、6・・・・・・低融合金の溶湯
、1・・・・・・ノツクアウト、8・・・・・・ノツク
アウトピン、9・・・・・・バンドヒータ。
FIG. 1 is a sectional view showing an embodiment of the present invention, FIG. 2A
, b are a plan view and a sectional view of a metal member showing the uneven shape of the surface formed at the same time as molding. 1...Cylinder, 2...Lower die, 3...
... Upper mold, 4... Unfired resin powder, 5.
...Metal plate, 6.. Molten metal of low alloy, 1.. Knock out, 8.. Knock out pin, 9.. band heater.

Claims (1)

【特許請求の範囲】[Claims] 1 金属摺動面に自己潤滑性耐摩合成樹脂表面層を一体
形成する方法において、金型内にポリテトラフルオロエ
チレン等の未焼成の自己潤滑性耐摩合成樹脂粉末を充填
し、次いでアルミニウム合金或いは亜鉛合金等からなる
低融点合金の溶湯温度以下の低融点で合金化する材料か
らなる所定厚さの金属製の板材を挿入し、次いでアルミ
ニウム合金或いは亜鉛合金等からなる低融点合金の溶湯
を注入し、注入後上型で加圧成形することにより、上記
未焼成粉末を接合と同時に焼成硬化させ、凝固した金属
部材を金型より取出し、最後に上記樹脂のゲル化温度近
辺で再焼成して樹脂表面層を所定の表面硬さにすること
を特徴とする金属部材に耐摩性表面を形成する方法。
1. In a method of integrally forming a self-lubricating, wear-resistant synthetic resin surface layer on a metal sliding surface, a mold is filled with unfired self-lubricating, wear-resistant synthetic resin powder such as polytetrafluoroethylene, and then an aluminum alloy or zinc A metal plate of a predetermined thickness made of a material that alloys at a low melting point below the temperature of a molten metal of a low melting point alloy made of an alloy, etc. is inserted, and then a molten metal of a low melting point alloy made of an aluminum alloy, a zinc alloy, etc. is injected. After injection, the unfired powder is baked and hardened at the same time as bonding by pressure molding with an upper mold, the solidified metal member is taken out from the mold, and finally it is refired at around the gelling temperature of the resin to form the resin. 1. A method for forming a wear-resistant surface on a metal member, the method comprising forming a surface layer to a predetermined surface hardness.
JP3398075A 1975-03-20 1975-03-20 Method of forming a wear-resistant surface on metal parts Expired JPS5933469B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3398075A JPS5933469B2 (en) 1975-03-20 1975-03-20 Method of forming a wear-resistant surface on metal parts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3398075A JPS5933469B2 (en) 1975-03-20 1975-03-20 Method of forming a wear-resistant surface on metal parts

Publications (2)

Publication Number Publication Date
JPS51108630A JPS51108630A (en) 1976-09-27
JPS5933469B2 true JPS5933469B2 (en) 1984-08-16

Family

ID=12401622

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3398075A Expired JPS5933469B2 (en) 1975-03-20 1975-03-20 Method of forming a wear-resistant surface on metal parts

Country Status (1)

Country Link
JP (1) JPS5933469B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57202683A (en) * 1981-06-08 1982-12-11 Toshiba Denki Kigu Kk Method of producing heat radiating base for electric heater

Also Published As

Publication number Publication date
JPS51108630A (en) 1976-09-27

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