JPS5945352B2 - Method for producing granular capsules containing liquid food - Google Patents
Method for producing granular capsules containing liquid foodInfo
- Publication number
- JPS5945352B2 JPS5945352B2 JP56160246A JP16024681A JPS5945352B2 JP S5945352 B2 JPS5945352 B2 JP S5945352B2 JP 56160246 A JP56160246 A JP 56160246A JP 16024681 A JP16024681 A JP 16024681A JP S5945352 B2 JPS5945352 B2 JP S5945352B2
- Authority
- JP
- Japan
- Prior art keywords
- food
- granular
- coagulated
- capsule
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002775 capsule Substances 0.000 title claims description 90
- 235000021056 liquid food Nutrition 0.000 title claims description 54
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 235000013305 food Nutrition 0.000 claims description 174
- 239000000701 coagulant Substances 0.000 claims description 77
- 238000000034 method Methods 0.000 claims description 69
- 239000002994 raw material Substances 0.000 claims description 40
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 239000007788 liquid Substances 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 25
- 150000003839 salts Chemical class 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- 230000002378 acidificating effect Effects 0.000 claims description 16
- 159000000007 calcium salts Chemical class 0.000 claims description 12
- 240000004584 Tamarindus indica Species 0.000 claims description 7
- 235000004298 Tamarindus indica Nutrition 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 239000000126 substance Substances 0.000 description 13
- 239000012530 fluid Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 10
- 229920001817 Agar Polymers 0.000 description 10
- 239000008272 agar Substances 0.000 description 10
- 235000010413 sodium alginate Nutrition 0.000 description 10
- 239000000661 sodium alginate Substances 0.000 description 10
- 229940005550 sodium alginate Drugs 0.000 description 10
- PYMYPHUHKUWMLA-UHFFFAOYSA-N 2,3,4,5-tetrahydroxypentanal Chemical compound OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 235000010443 alginic acid Nutrition 0.000 description 7
- 229920000615 alginic acid Polymers 0.000 description 7
- 238000005345 coagulation Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 6
- 239000001639 calcium acetate Substances 0.000 description 6
- 229960005147 calcium acetate Drugs 0.000 description 6
- 235000011092 calcium acetate Nutrition 0.000 description 6
- 230000015271 coagulation Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 5
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 5
- 229960001126 alginic acid Drugs 0.000 description 5
- 239000000783 alginic acid Substances 0.000 description 5
- 150000004781 alginic acids Chemical class 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229960005069 calcium Drugs 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 5
- 239000001527 calcium lactate Substances 0.000 description 5
- 235000011086 calcium lactate Nutrition 0.000 description 5
- 229960002401 calcium lactate Drugs 0.000 description 5
- 229920000591 gum Polymers 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000000467 phytic acid Substances 0.000 description 5
- 235000002949 phytic acid Nutrition 0.000 description 5
- 229940068041 phytic acid Drugs 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- 235000005979 Citrus limon Nutrition 0.000 description 4
- 244000131522 Citrus pyriformis Species 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 235000013361 beverage Nutrition 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- 235000011148 calcium chloride Nutrition 0.000 description 4
- 235000012041 food component Nutrition 0.000 description 4
- 239000005417 food ingredient Substances 0.000 description 4
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 240000005893 Pteridium aquilinum Species 0.000 description 3
- 235000009936 Pteridium aquilinum Nutrition 0.000 description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000011975 tartaric acid Substances 0.000 description 3
- 235000002906 tartaric acid Nutrition 0.000 description 3
- 239000004034 viscosity adjusting agent Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 2
- 244000247812 Amorphophallus rivieri Species 0.000 description 2
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 2
- 244000099147 Ananas comosus Species 0.000 description 2
- 235000007119 Ananas comosus Nutrition 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- 229920002752 Konjac Polymers 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 241000199919 Phaeophyceae Species 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 235000006468 Thea sinensis Nutrition 0.000 description 2
- 229940072056 alginate Drugs 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000020279 black tea Nutrition 0.000 description 2
- 235000008429 bread Nutrition 0.000 description 2
- 235000010410 calcium alginate Nutrition 0.000 description 2
- 239000000648 calcium alginate Substances 0.000 description 2
- 229960002681 calcium alginate Drugs 0.000 description 2
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000001112 coagulating effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000252 konjac Substances 0.000 description 2
- 235000010485 konjac Nutrition 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 235000013997 pineapple juice Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 239000003351 stiffener Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 240000000385 Brassica napus var. napus Species 0.000 description 1
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 229920002230 Pectic acid Polymers 0.000 description 1
- 241001310492 Pectis angustifolia Species 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical class [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- -1 calcium Chemical class 0.000 description 1
- 229960002713 calcium chloride Drugs 0.000 description 1
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 238000009924 canning Methods 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Chemical class 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 235000019700 dicalcium phosphate Nutrition 0.000 description 1
- 229940095079 dicalcium phosphate anhydrous Drugs 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000016337 monopotassium tartrate Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015205 orange juice Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- LCLHHZYHLXDRQG-ZNKJPWOQSA-N pectic acid Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)O[C@H](C(O)=O)[C@@H]1OC1[C@H](O)[C@@H](O)[C@@H](OC2[C@@H]([C@@H](O)[C@@H](O)[C@H](O2)C(O)=O)O)[C@@H](C(O)=O)O1 LCLHHZYHLXDRQG-ZNKJPWOQSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000010318 polygalacturonic acid Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- KYKNRZGSIGMXFH-ZVGUSBNCSA-M potassium bitartrate Chemical compound [K+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O KYKNRZGSIGMXFH-ZVGUSBNCSA-M 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229940086065 potassium hydrogentartrate Drugs 0.000 description 1
- 235000004252 protein component Nutrition 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000021055 solid food Nutrition 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 210000005182 tip of the tongue Anatomy 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Dairy Products (AREA)
- Grain Derivatives (AREA)
- Jellies, Jams, And Syrups (AREA)
- Non-Alcoholic Beverages (AREA)
- Tea And Coffee (AREA)
- General Preparation And Processing Of Foods (AREA)
- Seeds, Soups, And Other Foods (AREA)
- Formation And Processing Of Food Products (AREA)
Description
【発明の詳細な説明】
技術水準と発明の目的
本発明は、各種凝固剤を添加した原料食品を得る方法、
この原料食品を気中における各種の成形法によって粒状
の凝固体に成形した後カプセル皮膜により被覆する方法
およびカプセル内において上記凝固体を解凝し流動食品
とする方法を包含し、これらの方法を組合わせてなる流
動体食品内蔵粒状カプセル体の製造方法に関する。[Detailed Description of the Invention] State of the Art and Purpose of the Invention The present invention provides a method for obtaining raw food products to which various coagulants have been added;
These methods include a method in which the raw food is formed into a granular coagulate by various molding methods in the air and then covered with a capsule film, and a method in which the coagulate is deflocculated in a capsule to form a liquid food. The present invention relates to a method for manufacturing a granular capsule containing a liquid food product.
果実、疏菜などの天然固形食品を■アルギン酸ソーダお
よび/または低メトキシペクチン等の造膜剤と、■カル
シウムその他の多価金属塩等の皮膜凝結剤とを反応させ
て得た比較的硬いゲル状カプセル皮膜で被覆したカプセ
ル体は公知である。Relatively hard gel obtained by reacting natural solid foods such as fruits and canola with ■film-forming agents such as sodium alginate and/or low methoxy pectin, and ■film-coagulating agents such as calcium and other polyvalent metal salts. Capsule bodies coated with capsule shells are known.
また、ジュースのような液状食品や比較的低温で溶ける
ゼリー状食品であって、しかもカプセルが日中でつぶれ
ると食品中に含有された成分が日中にひろがるようなカ
プセル食品およびその製造方法も文献上公知である。In addition, capsule foods such as liquid foods such as juice and jelly-like foods that melt at relatively low temperatures, and in which the ingredients contained in the food spread during the day when the capsules are crushed during the day, and methods for producing the same, are also available. It is known in the literature.
上記のような食品をカプセル食品にする方法としては、
食品原料液中にカルシウム等の多価金属の塩すなわち皮
膜凝結剤を加えた流動状のものをアルギン酸ソーダ等の
造膜剤液中に滴下し、その液滴の表面にアルギン酸多価
金属塩のカプセル皮膜を形成さぜる方法や二重管のデボ
ジッターで食品原料液と皮膜凝結剤の液とを同時に滴下
して、カプセル皮膜で被覆された食品を形成させる方法
、すなわち滴下造膜法が知られている。How to make the above foods into capsule foods:
A fluid containing a salt of a polyvalent metal such as calcium or a film coagulant added to a food raw material solution is dropped into a film forming agent solution such as sodium alginate, and the surface of the droplet is coated with a polyvalent metal salt of alginate. A method of forming a capsule film and a method of simultaneously dropping a food raw material liquid and a film coagulant liquid using a double-tube depositor to form a food coated with a capsule film, that is, a dropping film forming method, are known. It is being
けれども、上記のような各種の滴下造膜法によってカプ
セル食品を作ろうとすると、造膜剤液槽中の液表面にお
ける原料液滴の細分小滴化およびこの小滴と滴下された
液滴との相互付着、または造膜剤液中における食品原料
液滴の変形および相互付着などが生じやすい。However, when attempting to make capsule foods using the various dropping film forming methods described above, the raw material droplets are subdivided into small droplets on the liquid surface in the film forming agent liquid tank, and the droplets and the dropped droplets are separated. Mutual adhesion, or deformation and mutual adhesion of food raw material droplets in the film-forming agent solution, etc. are likely to occur.
そのため、作業能率が劣り、完全な球形カプセル体の収
率も低くて、満足な工業的生産に適しない欠点は解消さ
れず、滴下造膜法についての公知文献は多いが、これら
の文献に示された方法で製造された流動食品を内蔵する
カプセル体は現実に販売されるに至っていない。As a result, the work efficiency is poor and the yield of perfectly spherical capsules is low, making it unsuitable for satisfactory industrial production. Capsules containing liquid food produced by this method have not actually been sold.
そこで、本発明者らは、滴下造膜法に代えて、食品原料
を取扱い容易なカプセル皮膜で被覆された凝固食品とし
た後、これをもとの流動食品にもどすことを着想した。Therefore, instead of using the dropping film forming method, the present inventors came up with the idea of converting a food raw material into a coagulated food coated with an easy-to-handle capsule film, and then returning the product to the original liquid food.
本発明の目的は、上記のような基本構想にもとづき、そ
の具体的な各工程手段およびその結合工程を提供するに
ある。An object of the present invention is to provide specific process means and their combination process based on the basic concept as described above.
本発明者らは、上記目的を達するための方法について研
究を進め、流動状の食品に各種の食品凝固剤を添加して
常温で凝固体となる食品原料を作る方法、この食品原料
を粒状に成形する方法、成形された粒の表面にカプセル
皮膜を形成させつつ、またはカプセル皮膜を形成させた
後に、このカプセル体を熱水に接触させて、カプセル皮
膜を破壊することなく内蔵された凝固食品の凝固を解い
て流動食品とする方法を組合わせた結合工程を開発し、
本発明を完成するに至った。The present inventors have conducted research on methods to achieve the above objectives, and have developed a method of adding various food coagulants to fluid foods to produce food raw materials that become coagulated at room temperature, and a method of producing food raw materials that become coagulated at room temperature. A method of molding, forming a capsule film on the surface of the molded grains, or after forming a capsule film, and then contacting the capsule body with hot water to produce a solidified food containing the capsule without destroying the capsule film. We have developed a binding process that combines methods to uncoagulate food and make it into a liquid food.
The present invention has now been completed.
構成
本発明の方法の特徴は、特許請求の範囲に記載のとおり
であって、これを要するに、流動食品原料中に予め適当
な食品凝固剤を添加するほか、要すれば、この凝固剤に
よる食品の凝固を最終工程で解き解凝後の内蔵食品がゲ
ル化するのを防ぐのに有効な解凝剤を添加して、PHを
0.3以下の酸性値に調整し、気中において降温し成形
した粒状凝固食品原料を用い、この表面に、各種の公知
方法中の適宜の方法により、アルギン酸のカルシウム塩
を主成分とするカプセル皮膜を形成増強させながら、ま
たはカプセル皮膜を形成させた後に、これを熱水と接触
させ少くとも数分間加熱してカプセル内の凝固食品を解
凝させ、カプセル皮膜を弱化させることなく、カプセル
中の凝固食品のみを流動食品に変化させることによって
、流動食品を内蔵した粒状カプセル体にする方法である
。Structure The characteristics of the method of the present invention are as described in the claims, and in short, in addition to adding an appropriate food coagulant to the liquid food raw material in advance, if necessary, the food with this coagulant is added. In the final process, a deflocculant is added that is effective in preventing the defocculated food from gelling, the pH is adjusted to an acidic value of 0.3 or less, and the temperature is lowered in the air. Using the molded granular coagulated food raw material, while enhancing the formation of a capsule film containing calcium salt of alginic acid as a main component, or after forming a capsule film on the surface thereof, by an appropriate method among various known methods, This is brought into contact with hot water and heated for at least several minutes to decongeal the coagulated food inside the capsule, changing only the coagulated food inside the capsule into a liquid food without weakening the capsule membrane, thereby making a liquid food. This is a method of forming a built-in granular capsule.
以下本発明を一層詳細に説明するに先立ち、本明細書中
における用語の意義を明らかにする。Before explaining the present invention in more detail below, the meanings of terms used in this specification will be clarified.
流動食品とは、常温前後の温度のもとて液状ま、たはゼ
リー状を呈する経口摂取可能な物をいう。Liquid foods refer to orally ingestible foods that are liquid or jelly-like at around room temperature.
ゼリー状とは柔かいゲルで舌先での軽い押圧ないし同等
の衝撃によって容易に変形するテクスチャーを有するも
のをいう。The term jelly-like refers to a soft gel with a texture that easily deforms with light pressure from the tip of the tongue or an equivalent impact.
凝固とは、流動食品を常温下の分別、運搬、液面への投
入等の処理によっては変形しないまでに硬くゲル化させ
ること、またはゲル化した状態をいう。Coagulation refers to the process of hardening a liquid food to a gelatinous state without deforming it through processes such as sorting, transporting, and adding it to a liquid surface at room temperature, or to a gelatinized state.
食品凝固剤とは、流動食品に添加することによって流動
食品を凝固させる物質をいう。A food coagulant is a substance that coagulates a liquid food by adding it to the liquid food.
凝固食品とは、流動食品が食品凝固剤により凝固された
状態の物をいう。A coagulated food is a liquid food that has been coagulated by a food coagulant.
解凝剤とは、酸性雰囲気の加熱下において凝固食品中の
食品凝固剤と反応して、食品凝固剤の分解ないし変性を
促進させ凝固棄品を流動食品に変化させて粘度を低下さ
せる物質および/またはその粘度上昇および再凝固を防
止する物質をいう。A deflocculant is a substance that reacts with a food coagulant in a coagulated food under heating in an acidic atmosphere, promotes the decomposition or denaturation of the food coagulant, changes the coagulated waste into a liquid food, and lowers the viscosity. / or a substance that prevents viscosity increase and re-solidification.
造膜剤とは、商品としてのアルギン酸ソーダおよび褐藻
類を処理して得られる可溶性のアルギン酸を含有する天
然抽出成分をいう。The film-forming agent refers to a naturally extracted component containing sodium alginate as a commercial product and soluble alginic acid obtained by processing brown algae.
造膜剤液とは、造膜剤の水溶液をいう。The film-forming agent liquid refers to an aqueous solution of a film-forming agent.
皮膜凝結剤とは、粒状食品の表面を被覆した造膜剤液中
の造膜剤と反応してカプセル皮膜を形成するカルシウム
塩等の多価金属塩であって食品添加可能なものをいう。The film coagulant refers to a polyvalent metal salt such as a calcium salt that forms a capsule film by reacting with a film forming agent in a film forming agent liquid that coats the surface of a granular food, and can be added to foods.
粒状とは、最大さし渡し2cIrLまでの球形その他の
形状をいう。Granular means spherical or other shapes with a maximum width of up to 2 cIrL.
なお、本明細書中の多値は、すべて重量多値である。In addition, all the multivalues in this specification are weight multivalues.
つぎに、本発明を一層詳細に説明する。Next, the present invention will be explained in more detail.
まず、食品原料中の流動食品としては、果汁、コーラ飲
料、紅茶、コーヒー、スープ等の嗜好飲料、乳製品含有
飲料、健康飲料などの液状食品および柔かいゼリー状物
で経口摂取可能な一切のものを用いることができる。First, liquid foods in food ingredients include fruit juices, cola drinks, tea, coffee, and other beverages such as soups, dairy products-containing beverages, health drinks, and other liquid foods and soft jelly-like substances that can be ingested orally. can be used.
食品凝固剤としては、寒天およびファーセレランのよう
に単独で流動食品を凝固させる成分、すなわち、液状の
食品に添加すると高い温度では溶解し常温では中性また
は酸性下において流動食品を凝固させる性質のものが代
表的な1例である。Food coagulants include ingredients that can coagulate liquid foods by themselves, such as agar and farcellan; in other words, they dissolve at high temperatures when added to liquid foods, but have the property of coagulating liquid foods at room temperature under neutral or acidic conditions. is a typical example.
さらに、他の例としては、低メトキシペクチン、コンニ
ャク粉、カルボキシメチルセルローズのナトリウム塩な
どの凝固剤原料と1価ないし多価の金属塩との両者の反
応により生成される食品凝固剤を挙げることができる。Further, other examples include food coagulants produced by the reaction of coagulant raw materials such as low methoxy pectin, konjac flour, and sodium salt of carboxymethyl cellulose with monovalent or polyvalent metal salts. I can do it.
この食品凝固剤は上記凝固剤原料と上記地価金属塩とを
流動食品中に添加して加熱溶解し、両者を反応させるこ
とにより、流動食品中で生成させることができる。This food coagulant can be produced in a liquid food by adding the above-mentioned coagulant raw material and the above-mentioned mineral metal salt into a liquid food, heating and dissolving them, and causing the two to react.
その好適例が低メトキシペクチンとカルシウム塩の共添
によって流動食品中に低メトキシペクチンのカルシウム
塩を生成させる例である。A preferred example is the production of a calcium salt of low methoxy pectin in a liquid food by co-adding low methoxy pectin and a calcium salt.
また、別の凝固剤の例としては、ワラビ粉などの澱粉類
がある。Other examples of coagulants include starches such as bracken powder.
さらに、高濃度の砂糖とタマリンドやペクチン酸の共添
なとも食品凝固剤の例としてあげることができる。Furthermore, co-addition of high-concentration sugar with tamarind or pectic acid is another example of a food coagulant.
これらの凝固剤を用いた凝固食品のゲル硬度や凝固食品
を粒状化したときの保形性が多少劣る場合には、寒天や
ファーセレランなどの強固な凝固体を作る物質を少量添
加すればよい。If the gel hardness of the coagulated food using these coagulants or the shape retention when the coagulated food is granulated is somewhat inferior, a small amount of a substance that forms a strong coagulate, such as agar or farcellan, may be added.
以上述べた食品凝固剤のほかに、ゼラチンやカラギーナ
ンのようなゼリー化剤も使用できるが、これらのゼリー
化剤は、食品凝固剤としては冷却しても軟弱すぎて取扱
いにくいなどのことがあるので、寒天やファーセレラン
を加えて保形可能な状態にする。In addition to the food coagulants mentioned above, jelly-forming agents such as gelatin and carrageenan can also be used, but these jelly-forming agents are difficult to handle as they are too soft even when cooled to be used as food coagulants. Therefore, add agar or Farselan to make it possible to retain the shape.
食品凝固剤は、上述した例のいずれか1つを選択しなけ
ればならないものではなく、適宜二種以上の食品凝固剤
を共添して使用することができる。As the food coagulant, it is not necessary to select one of the above-mentioned examples, and two or more food coagulants can be used together as appropriate.
食品凝固剤の全体としての添加量は、調整される食品原
料の種類や組成に応じ、全量に対して0.5係から5.
0係までの範囲内で適宜加減する。The total amount of the food coagulant to be added is from 0.5 to 5.0% of the total amount, depending on the type and composition of the food raw material to be adjusted.
Adjust as appropriate within the range up to 0.
解凝剤は、酸性雰囲気下の80℃以上の加熱により凝固
食品中の凝固剤を分解ないし変性させて粘度を低下させ
、その粘度の上昇および再凝固の作用を防止する物質で
あれば何でもよい。The deflocculant may be any substance that decomposes or denatures the coagulant in the coagulated food by heating at 80°C or higher in an acidic atmosphere, lowers the viscosity, and prevents the increase in viscosity and the effect of re-coagulation. .
解凝剤の例としては、低メトキシペクチンのカルシウム
塩などのような物質すなわち食品凝固剤中に結合して存
在する金属イオンをキレート結合によって取出し、食品
凝固剤による凝固を解いて食品の粘度を低下させるキレ
ート剤がある。Examples of deflocculants include substances such as calcium salts of low methoxy pectin, which take out metal ions bound to food coagulants through chelate binding, loosen the coagulation caused by the food coagulant, and reduce the viscosity of the food. There are chelating agents that lower it.
フィチン酸、リン酸およびその塩類などがキレート剤の
好適な例である。Preferred examples of chelating agents include phytic acid, phosphoric acid, and salts thereof.
また、Li、Mg、Na、に、NH4,804イオンな
どのように、食品凝固剤に対して溶解作用をする水利力
の大きい陽イオンや同様の作用をする陰イオンを電離す
る物質も解凝剤として使用できる。In addition, substances such as Li, Mg, Na, and NH4,804 ions, which have a large water-utilizing power and have a dissolving effect on food coagulants, and substances that ionize anions that have a similar effect, are also decoagulated. Can be used as an agent.
たとえば、NH4Cl、酒石酸水素カリウムなどが好適
な例である。For example, NH4Cl, potassium hydrogen tartrate, etc. are suitable examples.
さらに、食品中の凝固剤を凝集させ、ゲルをゾル化して
粘度を低下させる明パン、KCII、 Back2、M
g804などの電解質物質も肩凝剤として用いることが
できる。Furthermore, Ampang, KCII, Back2, M, which aggregates coagulants in foods and turns gels into sol to reduce viscosity.
Electrolyte materials such as g804 can also be used as shoulder thinners.
これらの肩凝剤は、使用する凝固剤の種類に対応した適
当な物質を適宜選択すればよい。These coagulants may be selected from appropriate substances depending on the type of coagulant used.
たとえば、寒天が食品凝固剤の場合にフィチン酸と硫酸
マグネシウムを添加し、ファーセレランが食品凝固剤で
ある場合に明パンと塩化力11ウムを添加し、ワラビ粉
などの澱粉が食品凝固剤である場合に塩化アンモニウム
とリン酸とを添加し、食品凝固剤がタマリンドガムと砂
糖からなる場合にフィチン酸を添加するなどが適当な例
であるが、その組合せは上記の例に限定されるものでな
いこというまでもない。For example, when agar is a food coagulant, phytic acid and magnesium sulfate are added, when Farcellan is a food coagulant, light bread and 11 um of chloride are added, and starch such as bracken powder is a food coagulant. Suitable examples include adding ammonium chloride and phosphoric acid when the food coagulant consists of tamarind gum and sugar, and adding phytic acid when the food coagulant consists of tamarind gum and sugar, but the combinations are not limited to the above examples. Needless to say.
肩凝剤の添加量は食品原料全量に対して0.05〜5.
0%の範囲で適宜加減するが、通常0.1〜1.0%で
十分である。The amount of shoulder stiffener added is 0.05 to 5.0% based on the total amount of food ingredients.
The amount may be adjusted appropriately within the range of 0%, but usually 0.1 to 1.0% is sufficient.
肩凝剤は、一般に食品凝固剤の食品中における濃度が高
く、たとえば、寒天やファーセレランの濃度が0.7%
以上であるような場合、または、上記未満の濃度ではあ
るが食品の凝固成形が可能な程度の量を用いた場合に、
肩凝速度を速めるために使用する。Generally, the concentration of food coagulants in food is high, for example, the concentration of agar and farcellan is 0.7%.
or above, or when using an amount that is lower than the above concentration but still allows for coagulation and molding of food.
Used to speed up shoulder stiffness.
しかし、本発明の方法によれば、酸性雰囲気下の加熱だ
けでも肩凝は可能であるから、凝固剤の濃度や予定肩凝
時間の如何tこよっては、肩凝剤を使用しなくてもよい
。However, according to the method of the present invention, it is possible to curdle the shoulder simply by heating in an acidic atmosphere, so depending on the concentration of the coagulant and the planned coagulant time, it is possible to curdle the shoulder without using the coagulant. good.
食品原料に加えるpH調整剤としては、クエン酸、酒石
酸、塩酸、リン酸など食品への添加を許可されている有
機酸およびそのナトリウム塩または鉱酸の一種以上を用
いる。As the pH adjuster to be added to the food raw materials, one or more organic acids and their sodium salts or mineral acids that are permitted to be added to foods, such as citric acid, tartaric acid, hydrochloric acid, and phosphoric acid, are used.
pH調整剤によって食品原 。料はpH1,0〜3.0
程度に調整されるのがよい。Food ingredients by pH adjusters. pH 1.0-3.0
It is best to adjust it accordingly.
食品原料への必須の添加剤である食品凝固剤とpH調整
剤とに加えて、必要に応じ各種の粘度調整剤を用いるこ
とができる。In addition to food coagulants and pH adjusters, which are essential additives to food raw materials, various viscosity adjusters can be used as necessary.
その例としては、タマリンドガム、ローカストビーンガ
ム、キサンタン 。Examples include tamarind gum, locust bean gum, and xanthan.
ガム、アラビヤガム、トラガントガム、グアガム、ポリ
アクリル酸ソーダその他の高分子物質がある。There are gum, gum arabic, gum tragacanth, guar gum, sodium polyacrylate, and other polymeric substances.
食品凝固剤として作用する澱粉やCMC−Naなどは、
一面において粘度調整剤としても作用する。Starch, CMC-Na, etc. that act as food coagulants are
In one aspect, it also acts as a viscosity modifier.
これらの粘度調整剤の使用濃度は、食品原料全量 づに
対して0.1〜1.5係程度の範囲内で適宜選択する。The concentration of these viscosity modifiers to be used is appropriately selected within the range of about 0.1 to 1.5 parts based on the total amount of food raw materials.
また、食品凝固剤を食品原料中で生成させるに必要なカ
ルシウム等の金属塩の量が過剰であれば、凝固食品中の
上記金属塩の過剰部分は、粒状に成形された凝固食品を
造膜剤液と接触させたときに、カプセル皮膜形成反応に
関与するはずであるから、同様の効果を狙って、たとえ
ば寒天などのような温度低下のみによって食品を凝固さ
せる物質を食品凝固剤として使用するときにも、後のカ
プセル皮膜形成反応に関与させるため、予め多価金属塩
等の皮膜凝結剤を食品中に添加することができる。In addition, if the amount of metal salts such as calcium required to generate a food coagulant in food raw materials is excessive, the excess portion of the metal salt in the coagulated food can be used to form a film in the coagulated food formed into granules. When it comes into contact with the drug solution, it should be involved in the capsule film formation reaction, so to achieve the same effect, a substance that coagulates food only by lowering the temperature, such as agar, can be used as a food coagulant. Sometimes, a film coagulant such as a polyvalent metal salt can be added to the food in advance in order to participate in the subsequent capsule film forming reaction.
皮膜凝結剤の例としては、カルシウム、アルミ; ニウ
ム、バリウム、銅などの塩があるが、これらのうち食品
添加物であるカルシウム塩が最適である。Examples of film coagulants include salts of calcium, aluminum, barium, copper, etc. Among these, calcium salts, which are food additives, are most suitable.
カルシウム塩の例としては、塩化カルシウム、乳酸カル
シウム、酢酸カルシウム、酸性リン酸カルシウムなどが
あげられるが、これらに限定されないことはもとよりで
ある。Examples of calcium salts include, but are not limited to, calcium chloride, calcium lactate, calcium acetate, and acidic calcium phosphate.
カルシウム塩の添加量はカルシウムとして0.1〜1.
5%位が好適である。The amount of calcium salt added is 0.1 to 1.
Approximately 5% is suitable.
さて、これらの成分を添加して凝固食品原料を作る(こ
は、各種飲料等の成分中に食品凝固剤の必要量を混和し
、90℃以上に加熱して完全に溶解させた後、50℃〜
65℃に液温を降下させ、要すれば肩凝剤を加え、pH
調整剤を添加して、原料液のpHを1.0〜3,0の適
宜の値に調整する。Now, these ingredients are added to make coagulated food raw materials. ℃~
Lower the liquid temperature to 65℃, add a coagulant if necessary, and adjust the pH.
A regulator is added to adjust the pH of the raw material liquid to an appropriate value of 1.0 to 3.0.
このほか、必要に応じ適宜の順序段階で粘度調整剤およ
び/または多価金属塩を添加することができるが、食品
凝固剤は必ず原料を90℃以上に加熱する以前に添加す
べきであり、また、肩凝剤を用いるときは、原料を50
℃〜65℃に降温させてから添加する。In addition, viscosity modifiers and/or polyvalent metal salts can be added at appropriate sequential steps as needed, but food coagulants should always be added before heating the raw materials to 90°C or higher. Also, when using a shoulder thickener, add 50% of the raw material.
Add after cooling to 65°C.
この温度では食品凝固剤を含有していても食品原料は流
動状である。At this temperature, the food material remains fluid even if it contains a food coagulant.
つぎの工程は、気中において上記流動食品を粒状の凝固
食品に成形する工程である。The next step is a step of forming the liquid food into a granular solidified food in air.
この工程には多種の実施態様が考えられる。Many different implementations of this step are possible.
たとえば、50℃以上に加熱されて流動性を保持してい
る各種凝固剤含有食品原料を鋳型に入れ常温力)ら0℃
を超える程度の適当な温度範囲内の気中で降温させて型
に応じた各種寸法形状の粒状凝固食品としたり、上記温
度範囲内lこ降温させて凝固食品のマスを作り、これを
適宜の寸法形状に細断し、またはノズルから押出して押
出成形後に裁断するなどの方法がある。For example, food materials containing various coagulants that have been heated to 50°C or higher to retain their fluidity are placed in a mold from room temperature to 0°C.
The temperature can be lowered in the air within an appropriate temperature range exceeding the above temperature range to produce granular coagulated foods of various sizes and shapes depending on the mold, or the temperature can be lowered within the above temperature range to make a mass of coagulated foods and this can be made into appropriate shapes. There are methods such as cutting into size and shape, or extruding from a nozzle and cutting after extrusion molding.
なお、公知の噴霧造粒法や回転円板造粒法により低温下
に球形に造粒する方法も考えられる。Note that a method of granulating the particles into spherical shapes at low temperatures by a known spray granulation method or rotating disk granulation method is also considered.
つぎに、上述の各種の方法によって得られた粒状の凝固
食品のうち多価金属塩を含有していないものについては
、造膜剤液と接触させるに先立って減圧下でカルシウム
塩などの皮膜凝結剤と接触させ、少くとも表面近く船こ
皮膜凝結剤を塗布浸透させておくことが望ましい。Next, for granular coagulated foods obtained by the various methods described above that do not contain polyvalent metal salts, a film of calcium salts etc. is coagulated under reduced pressure before being brought into contact with the film-forming agent solution. It is desirable to apply and permeate the coating film coagulant at least near the surface.
造膜剤液としては、市販のアルギン酸ソーダの水溶液お
よび/または各種褐藻類から抽出して得た可溶性アルギ
ン酸を含む組成液を用いることができる。As the film-forming agent liquid, a commercially available aqueous solution of sodium alginate and/or a composition liquid containing soluble alginic acid extracted from various brown algae can be used.
造膜剤液中のアルギン酸の濃度は0.2〜3.0%の範
囲内とすることができるが、0.5〜1.5係が好適で
ある。The concentration of alginic acid in the film forming agent liquid can be within the range of 0.2 to 3.0%, but preferably 0.5 to 1.5%.
造膜剤液中には、形成されるカプセル皮膜を強化するた
め、酸性雰囲気中で加熱下に凝固する蛋白質成分を0,
05〜4.0係の範囲で添加することができる。In order to strengthen the capsule film that is formed, the film-forming agent solution contains 0 or 0 protein components that solidify under heating in an acidic atmosphere.
It can be added in the range of 0.05 to 4.0.
カプセル皮膜を柔かくして食感をよくするため(こ各種
の多糖類を若干量添加してもよい。In order to soften the capsule film and improve the texture (a small amount of various polysaccharides may be added).
造膜剤液の温度は、これlこ接触させる食品原料の状態
に応じて5℃から60℃までの範囲tこ保持する。The temperature of the film-forming agent solution is maintained within a range of 5° C. to 60° C. depending on the state of the food raw material with which it comes into contact.
前述した粒状に成形された凝固食品を上記造膜剤液で処
理し上記粒状凝固食品の表面にカプセル皮膜を形成させ
る方法には、いくつかの態様がある。There are several methods for forming a capsule film on the surface of the granular coagulated food by treating the granular coagulated food with the film-forming agent liquid.
すなわち、いずれにしても粒状凝固食品と造膜剤液とを
適宜の方法で接触させればよいのであるが、その方法と
して、たとえば粒状の凝固食品を造膜剤液中に投入浸漬
する方法、粒状の凝固食品に造膜剤液を吹きかける方法
などがある。That is, in any case, the granular coagulated food and the film-forming agent liquid may be brought into contact with each other by an appropriate method, such as a method in which the granular coagulated food is placed in and immersed in the film-forming agent liquid; There are methods such as spraying a film-forming agent solution onto granular coagulated foods.
粒状に成形された凝固食品に多価金属塩を含有ないし塗
布浸透させておいた場合には、造膜剤液中のアルギン酸
等と食品原料中の多価金属イオンとが反応して滴下物の
表面にアルギン酸多価金属塩のカプセル皮膜が形成され
る。When a polyvalent metal salt is contained or applied and permeated into a coagulated food product formed into granules, the alginic acid, etc. in the film-forming agent solution reacts with the polyvalent metal ions in the food raw material, causing the dropped product to react with the polyvalent metal salt. A capsule film of polyvalent metal alginate is formed on the surface.
粒状凝固食品に皮膜凝固剤としての多価金属塩を含有な
いし塗布浸透させていないものを造膜剤液と接触させる
場合も、造膜剤液との接触の方法は前述したと同様であ
るが、この場合には、造膜剤の液槽から取出した粒状の
凝固食品を皮膜凝結剤である多価金属塩含有液に接触さ
せてカプセル皮膜を形成させてから最終の肩凝工程に移
ればよい。When a granular coagulated food containing or not coated with a polyvalent metal salt as a film coagulant is brought into contact with a film forming agent liquid, the method of contacting with the film forming agent liquid is the same as described above. In this case, the granular coagulated food taken out from the film-forming agent liquid tank is brought into contact with a liquid containing a polyvalent metal salt, which is a film-coagulant, to form a capsule film, and then the final curing process is carried out. good.
肩凝工程に用いる加熱水中に多価金属塩を含有させてお
き、粒状体の表面lこカプセル皮膜を形成させ、または
表面に形成ずみのカプセル皮膜を保護補強させつつ肩凝
してもよい。A polyvalent metal salt may be contained in the heated water used in the hardening process to form a capsule film on the surface of the granules, or the hardening may be performed while protecting and reinforcing the capsule film already formed on the surface.
最終工程は、肩凝工程であって、食品原料中に予め食品
凝固剤を添加して酸性雰囲気に保持する原料調整工程と
関連しつつ本発明の主な特徴を示す工程である。The final step is a coagulant step, which is a step that shows the main feature of the present invention in conjunction with the raw material preparation step in which a food coagulant is added in advance to food raw materials and maintained in an acidic atmosphere.
造膜剤液で処理された後に、粒状の凝固食品は少くとも
5〜15分間Qこわたり80℃好ましくは85℃以上に
加熱されることを要する。After being treated with the film-forming agent liquid, the granular coagulated food product needs to be heated to a temperature of 80° C., preferably 85° C. or higher, for at least 5 to 15 minutes.
粒状凝固食品中には多量の水分が含有されており、その
蒸発等による逸出は避けなければならないから、上記の
加熱は、熱水中で行うのが好適であるが、水蒸気を飽和
させないし微小水滴を含むエキゾーストボックスまたは
レトルト等の室中での加熱処理も可能である。Granular coagulated foods contain a large amount of water, and its escape due to evaporation must be avoided, so it is preferable to perform the above heating in hot water, but do not saturate the water vapor. Heat treatment in a room such as an exhaust box or retort containing minute water droplets is also possible.
熱水中には粒状食品のカプセル皮膜の形成、維持補強を
図るためカプセル皮膜中に抱含された造膜剤成分と反応
する多価金属の塩を加えると効果的であることは前述し
た。As mentioned above, it is effective to add a polyvalent metal salt that reacts with the film-forming agent component contained in the capsule film to the hot water in order to form, maintain and reinforce the capsule film of the granular food.
カプセル皮膜内の凝固食品は、水と接触しつつ加熱され
て内部温度が一定温度以上に上昇すると、内部が酸性雰
囲気であるため食品凝固剤成分に肩凝剤成分が作用し、
逐次肩凝作用が進行して流動状態となる。When the coagulated food inside the capsule membrane is heated while in contact with water and the internal temperature rises above a certain temperature, the coagulant component acts on the food coagulant component due to the acidic atmosphere inside.
The stiffness of the shoulder gradually progresses, resulting in a fluid state.
この場合熱水中の加熱による凝固食品の肩凝作用を促進
するため、熱水中にクエン酸や酒石酸などの適宜の酸を
加えて酸性液とすることが適当である。In this case, in order to promote the curdling effect of the coagulated food due to heating in hot water, it is appropriate to add an appropriate acid such as citric acid or tartaric acid to the hot water to make an acidic liquid.
ただし、酸性液中での加熱は粒状食品のカプセル皮膜を
弱化させる原因となる。However, heating in an acidic liquid causes the capsule film of the granular food to weaken.
そこで前述のとおり造膜剤液中に耐酸性のある蛋白また
はセルロース等の補強物質を加えておくのがよい。Therefore, as mentioned above, it is preferable to add a reinforcing substance such as acid-resistant protein or cellulose to the film-forming agent solution.
なお、粒状の凝固食品を内蔵するカプセル体が缶詰とな
るときは、缶詰製造時における相当時間の加熱を最終の
肩凝工程として利用することもできる。In addition, when the capsule containing the granular coagulated food is to be canned, heating for a considerable period of time during canning can also be used as the final stiffening process.
肩凝のため加熱処理を加えられる直前の粒状凝固食品の
粒形および寸法は、凝固成形の工程如何によってさまざ
まである。The particle shape and size of the granular coagulated food just before being subjected to heat treatment for stiffening the shoulders vary depending on the coagulation process.
気中冷却成形や押出裁断などによる成形品は球状でなく
、角柱形や円柱形などを呈している場合が多い。Molded products formed by air cooling molding, extrusion cutting, etc. are not spherical but often have a prismatic or cylindrical shape.
しかし、これらの形状の粒も熱水槽中などで加熱される
ことによって粒の内部の肩凝が進行すると、食品内部の
流動化の傾向が進み、流動液の表面張力等の作用により
次第に球形tこ近づく。However, when grains with these shapes are heated in a hot water bath or the like, and the grains become stiff, the inside of the food tends to fluidize, and due to the surface tension of the fluid, they gradually become spherical. This is getting closer.
それにつれてカプセル皮膜の外観も漸次球形化する。Accordingly, the appearance of the capsule film gradually becomes spherical.
よほど細長い棒状などの凝固食品でない限り、得られた
流動食品を内蔵する粒状カプセル体は概ね球形であり、
径2の位までのものを得ることが容易である。The granular capsule containing the obtained liquid food is generally spherical, unless it is a coagulated food such as a very long and slender rod.
It is easy to obtain a diameter of up to 2 mm.
以上の説明によって本発明の各種の実施態様は明らかで
あり、それから適宜の設計による多くの実施例が引き出
せるが、以下に若干の好適な実施例を掲げる。Various embodiments of the present invention will be clear from the above description, and many embodiments can be derived from the invention with appropriate designs, but some preferred embodiments are listed below.
実施例 1
調製後の原料食品全量に対して、食品凝固剤としてのフ
ァーセレラン1.5%、乳酸カルシウム1.5%にレモ
ンジュース希釈液60係を加え、90℃以上に加熱して
溶解し、このBx12の溶液を50〜65℃に降温させ
てから、0.11%キサンタンガムでエマルジョン化し
た。Example 1 To the total amount of the raw material food after preparation, add 60 parts of lemon juice diluted liquid to 1.5% of Faseleran as a food coagulant, 1.5% of calcium lactate, and dissolve by heating to 90°C or higher. The temperature of this Bx12 solution was lowered to 50 to 65°C, and then emulsified with 0.11% xanthan gum.
、1%レモン油と肩凝剤としての明パンおよび塩化カリ
ウム合計0、2 %および1.o%クエン酸と0.1
%リン酸ソーダの水溶液を加えてpH値を2.2に調整
し、全量をレモンジュースで100%となるよう補正す
る。, 1% lemon oil and light bread as shoulder curd and potassium chloride total 0, 2% and 1. o% citric acid and 0.1
The pH value is adjusted to 2.2 by adding an aqueous solution of % sodium phosphate, and the total volume is corrected to 100% with lemon juice.
60℃に保持された流動食品を容器に注入して1℃〜1
0℃の冷蔵室中で凝固させて得た凝固食品を径51!t
2I!の丸棒状に押出して5朋間隔に裁断し、短円柱状
の粒状凝固食品を得る。Liquid food kept at 60℃ is poured into a container and heated to 1℃~1℃.
The coagulated food obtained by coagulating it in a refrigerator at 0℃ has a diameter of 51! t
2I! The product is extruded into a round bar shape and cut into 5-inch pieces to obtain a short cylindrical granular coagulated food.
この粒状品は軽い抑圧を加えた程度の衝撃力ではつぶれ
ることがないので取扱い容易である。This granular product is easy to handle because it will not be crushed by a slight impact force.
これを0.3 %のアルギン酸ソーダとo、 5%のカ
ゼイン−Naを含有する常温の造膜剤液槽中に投入し攪
拌しつつ短円柱状の凝固食品の表面にアルギン酸カルシ
ウムのカプセル皮膜を形成させ、上記液槽から取出し水
洗した後にクエン酸0.2 %、塩化カルシウム1.0
%を溶解した81℃の熱水中に浸漬し、6〜8分加熱
する。This was placed in a film-forming agent liquid bath at room temperature containing 0.3% sodium alginate, 5% casein-Na, and was stirred to form a capsule film of calcium alginate on the surface of the short cylindrical coagulated food. After forming and taking out from the liquid tank and washing with water, 0.2% citric acid and 1.0% calcium chloride were added.
% in hot water at 81°C and heated for 6 to 8 minutes.
この加熱処理によってカプセル内の凝固食品は肩凝され
て流動食品となり、かつ、カプセル体は概ね球形に変す
る。By this heat treatment, the coagulated food inside the capsule is solidified and becomes a liquid food, and the capsule body changes into a generally spherical shape.
得られたカプセル体は日中で容易につぶれ流動液が口中
にひろがってレモンの香を呈する。The obtained capsule bodies are easily crushed during the day, and the liquid liquid spreads in the mouth, giving it a lemon scent.
このカプセル体を紅茶に添加したものは、飲用に供する
と、江茶の風味とカプセルが口中でつぶれて得られるレ
モンの風味がよく調和した飲料となる。When this capsule body is added to black tea and served for drinking, it becomes a beverage that has a good harmony of the flavor of Echa and the flavor of lemon obtained by crushing the capsule in the mouth.
実施例 2
食品凝固剤、pH調整剤と肩凝剤の種類および添加量は
実施例1と同様であるが、カルシウム等の多価金属塩を
添加することなく、粘度調整剤としてタマリンド0.5
%を添加し、5%の粉乳を加えて実施例1と同様の方
法によりpH値を2.6に調整し1oo%補正をして原
料とする。Example 2 The types and amounts of the food coagulant, pH adjuster, and shoulder coagulant were the same as in Example 1, but without adding polyvalent metal salts such as calcium, tamarind 0.5 was used as the viscosity adjuster.
%, 5% milk powder was added, the pH value was adjusted to 2.6 in the same manner as in Example 1, and the pH value was corrected by 10%, and the raw material was used.
こび・原料をアルミニウム製のトレイ中にハンカム状型
枠を重ねた型中に注入し、最大さし渡し8mm高さ81
1Lnの正六角形に10℃で鋳型成形し、取出した凝固
食品を1.3係乳酸カルシウム水溶液中に真空下で浸漬
し凝固食品中に乳酸カルシウムを浸透させて水洗してか
ら常温の0.5%アルギン酸ソーダ液を十分に吹きかけ
て凝固食品の表面にアルギン酸カルシウムのカプセル皮
膜を形成させる。The raw materials are poured into a mold made of stacked handcam-shaped molds in an aluminum tray, and the maximum width is 8 mm and the height is 81 mm.
The solidified food was molded into a 1 Ln regular hexagon at 10°C, and the taken out solidified food was immersed in a 1.3 calcium lactate aqueous solution under vacuum to allow the calcium lactate to penetrate into the solidified food, washed with water, and then 0.5 cm at room temperature. % sodium alginate solution is sufficiently sprayed to form a capsule film of calcium alginate on the surface of the coagulated food.
次いで、これを実施例1のとおりの塩化カルシウムを含
む81℃の酸性加熱液中に8分間浸漬して加熱するとカ
プセル内蔵凝固食品は完全に流動コロイド液に変□化す
る。Next, when this is immersed in an acidic heating solution containing calcium chloride at 81° C. for 8 minutes and heated as in Example 1, the coagulated food containing capsules is completely transformed into a fluid colloidal liquid.
このミルク入りカプセル体は、コーヒーなどに添加する
とよく調和する。This milk-containing capsule blends well with coffee and other drinks.
実施例 3
食品凝固剤およびその補助剤として寒天1.5係および
キサンタンガム0.1%、酢酸カルシウム0.7%をパ
イナツプルジュースに溶解し、実施例1と同様の処決で
pH2,0に調整して原料とした。Example 3 Agar 1.5, 0.1% xanthan gum, and 0.7% calcium acetate were dissolved in pineapple juice as a food coagulant and its adjuvant, and the pH was adjusted to 2.0 in the same manner as in Example 1. It was adjusted to be the raw material.
この原料は60℃で十分流動性を有する。This raw material has sufficient fluidity at 60°C.
次いで、この原料液を1〜10℃の冷蔵室中で厚さ約6
朋の平板状に凝固させて6mrn角に細断し立方体形の
粒状凝固食品とし、これを0.3 %のアルギン酸ソー
ダと0.7 %のアルブミンを含有する液と直接接触さ
せて径約6關の球形カプセル皮膜で被覆された凝固食品
を得、以下実施例1と同様に処理して流動食品を内蔵す
る球形のカプセル体を得た。Next, this raw material liquid is heated to a thickness of about 6 cm in a refrigerator at 1 to 10°C.
It is coagulated into a flat plate shape and shredded into 6 mrn square pieces to form a cube-shaped granular coagulated food, which is then brought into direct contact with a solution containing 0.3% sodium alginate and 0.7% albumin to form a product with a diameter of about 6 mm. A coagulated food coated with a spherical capsule film was obtained, and then treated in the same manner as in Example 1 to obtain a spherical capsule body containing a liquid food product.
このカプセル体を果汁飲料に添加すると、香りのよい飲
料となる。When this capsule body is added to a fruit juice drink, the drink becomes fragrant.
実施例 4
食品凝固剤生成用成分として2.0係の低メトキシペク
チンと0.7 %の塩化カルシウム、凝固補強剤として
0.3%の寒天のほか、オレンジエツセンス若干を加え
た約10係のオレンジジュース原料を得て、肩凝剤とし
ての0,15%のフィチン酸と0.151%の硫酸マグ
ネシウムを用い実施例1と同様の方法で処理してpH2
,2に調整した。Example 4 Low methoxy pectin of 2.0% and calcium chloride of 0.7% as ingredients for producing a food coagulant, 0.3% agar as a coagulation enhancer, and about 10% of orange essence. An orange juice raw material of
, adjusted to 2.
この60℃で十分流動状の原料を実施例2と同様の方法
で6角柱形の粒状凝固食品とした後0.51%アルギン
酸ソーダと0.7 %のセルロースを含有する造膜剤液
中に投入攪拌して、凝固食品の表面にカプセル皮膜を形
成させてから取出し水洗して以後実施例1のとおり処理
する。This raw material, which was sufficiently fluid at 60°C, was made into a hexagonal prism-shaped granular coagulated food in the same manner as in Example 2, and then added to a film-forming agent solution containing 0.51% sodium alginate and 0.7% cellulose. The coagulated food is charged and stirred to form a capsule film on the surface of the coagulated food, then taken out, washed with water, and then treated as in Example 1.
ただし、酸性液中への保持時間は7〜12分である。However, the retention time in the acidic solution is 7 to 12 minutes.
得られたカプセル体は口中でつぶすと内蔵液が日中にひ
ろがりオレンジの芳香を発する。When the resulting capsule is crushed in the mouth, the internal fluid spreads during the day, emitting an orange aroma.
実施例 5
食品凝固剤生成用成分として1.0係のコンニャク粉と
1.o%の乳酸カルシウムを具部したほか、少量のパイ
ナツプルエツセンスとパイナツプルジュースを添加し、
肩凝剤として0.25%のフィチン酸と0.25%の塩
化バリウムを加え、実施例1と同様の方法で処理してp
i−11,7に調整した約65℃の原料液を実施例2に
記載した方法条件で鋳型成形し、0.5 %アルギン酸
ソーダと0.7 %セルロースを含有する造膜剤液中に
投入浸漬した後、実施例1の方法条件で熱水中で加熱処
理した。Example 5 Konjac flour of 1.0 and 1.0 were used as ingredients for producing a food coagulant. In addition to adding o% of calcium lactate, we also added a small amount of pineapple essence and pineapple juice.
0.25% phytic acid and 0.25% barium chloride were added as shoulder thinners and treated in the same manner as in Example 1.
A raw material solution at about 65°C adjusted to i-11.7 was molded into a mold under the method conditions described in Example 2, and poured into a film-forming agent solution containing 0.5% sodium alginate and 0.7% cellulose. After immersion, it was heat-treated in hot water under the method conditions of Example 1.
熱水中での保持時間は7〜12分である。Retention time in hot water is 7-12 minutes.
得られたカプセル体の内蔵食品は完全な流動食品に変化
しており、パイナツプルの芳香を発する。The internal food of the resulting capsule body has been transformed into a complete liquid food, which emits the aroma of pineapple.
実施例 6
1、0 %の低メトキシペクチン、0.2%の寒天、1
、o%の酢酸カルシウム、20係の砂糖を添加した溶液
を実施例1と同様の方法で処理してpH1,5に調整し
60℃に降温させてから1〜10℃の冷蔵室中で冷却し
て凝固体とし、これを実施例1のとおり押出し截断して
径5mTl@度の短円柱状の粒状凝固食品とし、以後は
実施例4と同一の条件でカプセル皮膜を形成させて熱水
中で加熱処理した。Example 6 1.0% low methoxy pectin, 0.2% agar, 1
A solution containing 0% calcium acetate and 20% sugar was treated in the same manner as in Example 1, adjusted to pH 1.5, cooled to 60°C, and then cooled in a refrigerator at 1 to 10°C. This was extruded and cut as in Example 1 to obtain a short cylindrical granular coagulated food with a diameter of 5 mTl@degrees. Thereafter, a capsule film was formed under the same conditions as in Example 4, and the product was soaked in hot water. heat treated.
得られたカプセル体は球形であり、その内部は完全に流
動食品に変化している。The obtained capsule body is spherical, and the inside thereof is completely transformed into a liquid food.
このカプセル体はコーラ飲料とよく調和する。This capsule blends well with cola drinks.
実施例 7
食品凝固剤としてのタマリンドガム1.o%、高メトキ
シペクチン1.5 %、砂糖55係およびファーセレラ
ン0.3%と0.8%の酢酸カルシウムを紅茶に添加し
て、実施例1と同一の方法で処理してpH2,0に調整
した溶液を実施例2のとおりの方法で鋳型成形して粒状
の凝固食品を得、以後は実施例1のとおり処理した。Example 7 Tamarind gum as a food coagulant1. 0%, high methoxy pectin 1.5%, sugar 55% and furcerelan 0.3% and 0.8% calcium acetate were added to black tea and treated in the same manner as in Example 1 to pH 2.0. The prepared solution was molded in the same manner as in Example 2 to obtain a granular coagulated food, and thereafter treated as in Example 1.
ただし熱酸性液中での加熱時間は10〜13分である。However, the heating time in the hot acidic liquid is 10 to 13 minutes.
得られたカプセル体の内部は、肩凝剤を用いなくても完
全に流動体となっている。The inside of the obtained capsule body is completely fluid even without the use of a coagulant.
実施例 8
食品凝固剤として1.5 %のタマリンドガムおよび5
5係の砂糖、寒天0.2%、肩凝剤として0.3係のフ
ィチン酸のはか1.o%の第2リン酸カルシウムを添加
し加熱して得た水溶液を1係の酒石酸と0.3 %の塩
酸を用いてpH1,5に調整し、以後これを実施例4の
とおりに処理した。Example 8 1.5% Tamarind Gum and 5% as Food Coagulant
5 parts sugar, 0.2% agar, and 0.3 parts phytic acid as a stiffener. An aqueous solution obtained by adding and heating 0% dibasic calcium phosphate was adjusted to pH 1.5 using Part 1 tartaric acid and 0.3% hydrochloric acid, and then treated as in Example 4.
加熱処理によってカプセル体は球状となり内部の凝固食
品は完全に流動食品に変化している。Due to the heat treatment, the capsule becomes spherical and the coagulated food inside is completely transformed into a liquid food.
この製品は糖濃度が非常に高いが、適宜の飲料中に添加
すると浸透圧によりカプセル皮膜を通じてカプセル内外
液が平衡化するので、それほど糖濃度を問題にする必要
はない。Although this product has a very high sugar concentration, when added to an appropriate beverage, the fluids inside and outside the capsule are equilibrated through the capsule membrane due to osmotic pressure, so there is no need to worry about the sugar concentration that much.
実施例 9
ワラビ粉2.0%に酢酸カルシウムo、 s %を加え
95℃以上の温度で加熱溶解し、5o°〜65℃に降温
してから塩化アンモニウム0.1 %とリン酸を加えて
レモンジュースで100%補正したpH2,0の液を得
、これを実施例1のとおり、丸棒状に押出し截断して粒
状凝固食品としてから造膜剤液中で処理し、得られた粒
状凝固食品内蔵カプセル体を酢酸カルシウム1.o%、
クエン酸0.3係を含む95℃以上の沸騰水で10〜1
3分間処理して製品とした。Example 9 Add 2.0% calcium acetate to 2.0% bracken powder, dissolve by heating at a temperature of 95°C or above, cool down to 5°C to 65°C, then add 0.1% ammonium chloride and phosphoric acid. A liquid with a pH of 2.0 that was 100% corrected with lemon juice was obtained, and as in Example 1, this was extruded and cut into round rods to produce a granular coagulated food, which was then treated in a film-forming agent solution to obtain a granular coagulated food. 1. Calcium acetate built-in capsule body. o%,
10 to 1 with boiling water above 95℃ containing 0.3 parts of citric acid
The product was processed for 3 minutes.
カプセル体は球状となり内蔵食品は完全に解凝されて流
動状となっていた。The capsule body became spherical, and the internal food was completely thawed and became fluid.
以上若干の具体的実施例を掲げたが、本発明には上述の
説明と実施例とから当業者に自明な他の多くの変更例が
あることを知られるであろう。Although some specific embodiments have been described above, it will be appreciated that the present invention has many other modifications that will be obvious to those skilled in the art from the foregoing description and examples.
原料としての食品酸性液の各種の組成と粒状の凝固食品
を成形する各種の方法と造膜剤の組成および造膜剤液に
よる処理方法と水の存在下における加熱肩凝工程の種々
の態様は、相互に独立した工程と考えることができる。Various compositions of food acidic liquids as raw materials, various methods for forming granular coagulated foods, compositions of film-forming agents, treatment methods with film-forming agent liquids, and various aspects of the heating shoulder curd process in the presence of water. , can be considered as mutually independent processes.
したがって、たとえば、前述の1つの実施例における特
定の段階の工程方法と他の実施例における別個の段階の
工程方法とを各種の組合せにより相互置換することがで
きる。Therefore, for example, the process method of a particular step in one embodiment described above and the process method of a separate step in another embodiment can be replaced with each other by various combinations.
要するに、本発明は、当初の食品原料に、これを常温で
は凝固体に保持しているが酸性雰囲気下の加熱により変
化変質して解凝するような凝固剤を添加しておき、造膜
剤液による処理中は食品原料を粒状の固体として扱い、
その後に熱水と接触させて加熱することにより、凝固剤
を解凝してカプセル内部の凝固食品のみを流動食品に変
化させる方法の一種であって、このような方法は未だ知
られていないと考える。In short, the present invention adds a coagulating agent to the original food raw material that maintains it in a coagulated form at room temperature, but changes its quality and deagglomerates when heated in an acidic atmosphere, and During liquid processing, food ingredients are treated as granular solids,
It is a type of method in which only the coagulated food inside the capsule is transformed into a liquid food by thawing the coagulant by contacting it with hot water and heating it, and this method is still unknown. think.
効果
本発明の効果は上述したところから自明と思われるが、
これを摘記するとつぎのとおりである。Effects The effects of the present invention seem obvious from the above, but
This can be summarized as follows.
すなわち、本発明方法によれば、アルギン酸ソーダを含
む造膜剤液中に原料食品を粒状の固体として投入するの
で1食品原料の取扱いが容易であり、滴下造粒法の工程
途上における種々の不利益を解消することができ、した
がってカプセル体の収率も大きく工業生産に適する。That is, according to the method of the present invention, the raw food material is added as a granular solid to the film-forming agent solution containing sodium alginate, so handling of one food raw material is easy, and various defects during the process of the drop granulation method can be avoided. It is possible to eliminate the profit, and therefore the yield of capsules is high, making it suitable for industrial production.
また、前記実施例1の食品原料と凝固剤を用い同実施例
の肩凝工程を経たカプセル体を2′−5°Cに冷蔵保存
して内蔵流動食品の粘度(センチポアズ)の経時変化を
測定した結果は、各種成形法の如何にかかわらず、第」
表1こ示すとおりである。In addition, the capsule body that had undergone the coagulation process of Example 1 using the food raw materials and coagulant of Example 1 was stored refrigerated at 2'-5°C, and the change over time in the viscosity (centipoise) of the built-in liquid food was measured. The results are the same regardless of the various molding methods.
As shown in Table 1.
この表によって、本発明方法により製造されたカプセル
体の内蔵食品は長期にわたって良好な流動状態を維持し
再凝固現象を生じないことが判る。From this table, it can be seen that the food contained in the capsule body produced by the method of the present invention maintains a good fluid state over a long period of time and does not cause the re-solidification phenomenon.
Claims (1)
液を食品凝固剤が凝固せず又酸によって分解しない範囲
内の温度に降温させた後pi−13,0以下に調整し、
さらに気中における冷却成形工程を経て粒状に成形され
た凝固食品とし、次いで造膜剤液との接触工程を経た後
、上記粒状の凝固食品を酸による解装反応が進行する温
度の水と接触させ加熱することによって解凝し、カプセ
ル皮膜内の凝固食品を流動食品に変化させることを特徴
とする流動食品内蔵粒状カプセル体の製造方法。 2 流動食品と食品凝固剤とを含有する加熱溶解液を6
5℃以下に降温させ、必要に応じ解凝剤を添加してpH
3,0以下(こ調整し、この液を40℃未満の気中にお
ける降温工程を経て粒状の凝固食品とし、次いで、上記
粒状の凝固食品にカプセル皮膜を形成させるための造膜
剤液との接触工程を経過させた後、80℃以上の水と接
触させ、粒状の凝固食品を解凝させて流動食品に変化さ
せることを特徴とする特許請求の範囲第1項の流動食品
内蔵カプセル体の製造方法。 3 食品凝固剤として、加熱すると溶解し降温すると凝
固体となる食品凝固剤を添加することを特徴とする特許
請求の範囲第1項記載の流動食品内蔵粒状カプセル体の
製造方法。 41価ないし多価の金属塩とこの金属イオンと結合して
凝固する成分とを流動食品中に共添することにより食品
凝固剤含有食品原料を得ることを特徴とする特許請求の
範囲第1項記載の流動食品内蔵粒状カプセル体の製造方
法。 5 食品原料中に添加する食品凝固剤がタマリンドガム
類および高濃度の砂糖からなることを特徴とする特許請
求の範囲第1項記載の流動食品内蔵カプセル体の製造方
法。 6 食品原料中に添加する食品凝固剤が澱粉類であるこ
とを特徴とする特許請求の範囲第1項記載の流動食品内
蔵カプセル体の製造方法。 7 カプセル皮膜形成前の粒状凝固食品中に食品添加可
能なカルシウム塩を含有させることを特徴とする特許請
求の範囲第1項記載の流動食品内蔵粒状カプセル体の製
造方法。 8 冷気中の型成形により粒状の凝固食品を得ることを
特徴とする特許請求の範囲第1項記載の流動食品内蔵粒
状カプセル体の製造方法。 9 冷気中で板状ないし塊状に凝固させた凝固食品を裁
断して粒状の凝固食品とすることを特徴とする特許請求
の範囲第1項記載の流動食品内蔵粒状カプセル体の製造
方法。 10凝固させた凝固食品をノズルから押出して適宜寸法
に裁断し粒状lこ成形することを特徴とする特許請求の
範囲第1項記載の流動食品内蔵粒状カプセル体の製造方
法。 11 粒状の凝固食品をカプセル皮膜で被覆した後に、
カルシウム塩を含有するp)I 4. 、&以下の酸性
熱水と接触させて加熱し凝固食品を流動食品とすること
を特徴とする特許請求の範囲第1項記載の流動食品内蔵
粒状カプセル体の製造方法。 12粒状の凝固食品をカプセル皮膜で被覆した後に、蒸
熱室中で加熱し凝固食品を流動食品に変化させることを
特徴とする特許請求の範囲第1項記載の流動食品内蔵粒
状カプセル体の製造方法。 13粒状の凝固食品をカプセル皮膜で被覆した後に、カ
ルシウム塩を含有する80℃以上の熱水に浸漬して加熱
し凝固食品を流動食品に変化させることを特徴とする特
許請求の範囲第1項記載の流動食品内蔵粒状カプセル体
の製造方法。[Scope of Claims] 1 After cooling a heated solution containing a liquid food and a food coagulant to a temperature within a range where the food coagulant does not coagulate or decompose by acid, pi-13.0 or less Adjust to
Furthermore, the solidified food is formed into granules through a cooling molding process in air, and after a contact process with a film-forming agent, the granular solidified food is brought into contact with water at a temperature at which the decomposition reaction with acid proceeds. 1. A method for producing a granular capsule containing a liquid food, characterized by decoagulating the solidified food within the capsule film into a liquid food by heating the capsule. 2 A heating solution containing a liquid food and a food coagulant is heated to 6
Lower the temperature to 5℃ or less, add a defocculant if necessary, and adjust the pH.
3.0 or less (adjust this, make this liquid into a granular coagulated food through a cooling process in the air below 40 ° C., and then combine with a film-forming agent solution to form a capsule film on the granular coagulated food). After the contact step, the capsule containing a liquid food according to claim 1 is brought into contact with water at 80° C. or higher to deagglomerate the granular coagulated food and transform it into a liquid food. Manufacturing method. 3. A method for manufacturing a granular capsule containing a liquid food according to claim 1, characterized in that a food coagulant that dissolves when heated and becomes a coagulate when the temperature cools is added as a food coagulant. 41 Claim 1, characterized in that a food raw material containing a food coagulant is obtained by co-adding a valent or polyvalent metal salt and a component that coagulates by binding with the metal ion to a liquid food. 5. The liquid food capsule according to claim 1, wherein the food coagulant added to the food raw material comprises tamarind gum and high concentration sugar. 6. A method for producing a capsule containing a liquid food according to claim 1, characterized in that the food coagulant added to the food raw material is starch. 7. A granule before forming a capsule film. A method for producing a granular capsule containing a liquid food according to claim 1, characterized in that a calcium salt that can be added to the food is contained in the coagulated food. 8. Obtaining a granular coagulated food by molding in cold air. A method for manufacturing a granular capsule containing a liquid food according to claim 1, characterized in that: 9. Cutting a coagulated food solidified into a plate or block shape in cold air to produce a granular coagulated food. A method for manufacturing a granular capsule containing a liquid food according to claim 1.10 A claim characterized in that the coagulated food is extruded from a nozzle, cut into appropriate sizes, and formed into granules. A method for manufacturing a granular capsule containing a liquid food according to item 1. 11. After covering a granular coagulated food with a capsule film,
p)I containing calcium salts 4. , & The method for producing a granular capsule containing a liquid food according to claim 1, characterized in that the coagulated food is made into a liquid food by contacting and heating the coagulated food with acidic hot water as follows. 12. A method for producing a granular capsule containing a liquid food according to claim 1, which comprises coating a granular coagulated food with a capsule film and then heating the coagulated food in a steam chamber to transform the coagulated food into a liquid food. . Claim 1, characterized in that the coagulated food in the form of 13 particles is coated with a capsule film and then immersed in hot water of 80° C. or higher containing calcium salts and heated to transform the coagulated food into a liquid food. The method for manufacturing the granular capsule body containing a liquid food product as described above.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56160246A JPS5945352B2 (en) | 1981-10-09 | 1981-10-09 | Method for producing granular capsules containing liquid food |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56160246A JPS5945352B2 (en) | 1981-10-09 | 1981-10-09 | Method for producing granular capsules containing liquid food |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5860959A JPS5860959A (en) | 1983-04-11 |
| JPS5945352B2 true JPS5945352B2 (en) | 1984-11-06 |
Family
ID=15710852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56160246A Expired JPS5945352B2 (en) | 1981-10-09 | 1981-10-09 | Method for producing granular capsules containing liquid food |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5945352B2 (en) |
-
1981
- 1981-10-09 JP JP56160246A patent/JPS5945352B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5860959A (en) | 1983-04-11 |
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