JPS5947071B2 - Breathable and waterproof processing method for knitted fabrics, woven fabrics, etc. with excellent wash resistance - Google Patents
Breathable and waterproof processing method for knitted fabrics, woven fabrics, etc. with excellent wash resistanceInfo
- Publication number
- JPS5947071B2 JPS5947071B2 JP9113380A JP9113380A JPS5947071B2 JP S5947071 B2 JPS5947071 B2 JP S5947071B2 JP 9113380 A JP9113380 A JP 9113380A JP 9113380 A JP9113380 A JP 9113380A JP S5947071 B2 JPS5947071 B2 JP S5947071B2
- Authority
- JP
- Japan
- Prior art keywords
- fabrics
- breathable
- processing method
- wash resistance
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 title claims description 21
- 239000002759 woven fabric Substances 0.000 title claims description 3
- 238000003672 processing method Methods 0.000 title description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229920001296 polysiloxane Polymers 0.000 claims description 12
- 230000002940 repellent Effects 0.000 claims description 10
- 239000005871 repellent Substances 0.000 claims description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 8
- 239000011737 fluorine Substances 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 238000004078 waterproofing Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 238000005406 washing Methods 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- 229960000583 acetic acid Drugs 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 239000012362 glacial acetic acid Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000012733 comparative method Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- -1 polysiloxane Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【発明の詳細な説明】
本発明は通気性と防水性に優れ、特に耐洗濯性の優れた
編地、織物等の耐洗濯性の優れた通気性防水加工法に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a breathable waterproofing method for knitted fabrics, woven fabrics, etc., which have excellent breathability and waterproof properties, and particularly have excellent wash resistance.
従来、オムツカバー等のか＼る加工法としては、生地表
面に樹脂加工によるコーティングを施したり、或は各種
タイプのシリコン系撥水剤、例えば水溶性タイプ又は溶
剤処理タイプの単独の処理浴に浸漬処理する方法がとら
れていた。Traditionally, processing methods for diaper covers and the like include applying a resin coating to the surface of the fabric, or immersing the fabric in a separate treatment bath of various types of silicone water repellents, such as water-soluble or solvent-treated. A method was taken to deal with it.
しかし乍ら前者の方法にあっては、編目が樹脂により閉
塞されるため通気性のないむれやすい生地となり、又、
生地自体が硬くなって着用感がきわめて悪くなる欠点が
あり、又、後者の方法にあっては防水性能において劣る
欠点があった。However, in the former method, the stitches are blocked by resin, resulting in a fabric that is not breathable and tends to get stuffy.
The disadvantage is that the fabric itself becomes hard, making it extremely uncomfortable to wear, and the latter method also has the disadvantage of poor waterproof performance.
また上記従来技術とは別に、通気性と防水性を維持しつ
つ、特に染色繊維布の染色摩擦堅牢度の改良を目的とし
、反応型オルガンポリシロキサンとフッ素系撥水剤の特
定組成物を用いて処理するものが特開昭５６−１２３４
７９号として提案されているが、耐洗濯性について非常
に劣るものであった。In addition to the above-mentioned conventional technology, a specific composition of reactive organ polysiloxane and a fluorine-based water repellent is used to improve the color fastness to abrasion of dyed fiber cloth while maintaining breathability and waterproofness. JP-A-56-1234
Although it has been proposed as No. 79, it has very poor washing resistance.
本発明は上記各従来の欠点を解消したもので、天然繊維
、再生繊維、合成繊維を問わず、その単独或いは混合（
交編、混紡糸、交撚糸、引揃えなど）して構成された編
織物例えば一般のメリヤス編生地、タテ編生地等につい
て通気性と防水性に優れ、特に耐洗濯性に優れた加工法
を提供するものであり、本発明の要旨とするところは、
無機あるいは有機の金属塩触媒及び酸の存在下に反応型
オルガンポリシロキサンとフッ素系撥水剤を重量比にお
いて前者に対する後者の割合が５０パ一セント以上とな
る如く混合して成る処理浴を構成し、該処理浴中におい
て被加工布を浸漬処理した後、乾燥及びキユアリング等
の加熱処理をすることによって生地の表面に反応を完結
させたオルガノポリシロキサン、及びフッ素系撥水剤の
混合皮膜を形成付着させる点にある。The present invention eliminates each of the above-mentioned conventional drawbacks, and can be applied to natural fibers, regenerated fibers, and synthetic fibers, either alone or in combination.
For knitted fabrics such as general stockinette knit fabrics, warp knit fabrics, etc., which are made of knitted fabrics (mixed knits, blended yarns, mixed twisted yarns, aligned yarns, etc.), we have developed a processing method that provides excellent breathability and waterproofness, and particularly excellent washing resistance. The gist of the present invention is to provide the following:
A treatment bath is formed by mixing a reactive organpolysiloxane and a fluorine-based water repellent in the presence of an inorganic or organic metal salt catalyst and an acid such that the ratio of the latter to the former is 50% or more by weight. After the fabric to be processed is immersed in the treatment bath, a mixed film of the reacted organopolysiloxane and a fluorine-based water repellent is applied to the surface of the fabric by heat treatment such as drying and curing. The point is to form and adhere.
以下その詳細について説明する。The details will be explained below.
先ず本発明に用いる処理剤について、
反応型オルガノポリシロキサンとしては例えば次式の如
きものを用いる。First, regarding the processing agent used in the present invention, as the reactive organopolysiloxane, for example, one of the following formula is used.
（１）反応型オルガノポリシロキサンＨタイプを夫々単
独若しくは混合して用いる。(1) Reactive organopolysiloxane H type is used alone or in combination.
又フッ素系撥水剤としては、 フルオロカーボンを主体とする撥水剤を用いる。Also, as a fluorine-based water repellent, Use a water repellent based on fluorocarbons.
又反応型オルガノポリシロキサンの反応触媒として無機
あるいは有機金属塩を用いる。Further, an inorganic or organic metal salt is used as a reaction catalyst for the reactive organopolysiloxane.
これとしては、
無機金属塩・・・錫、ジルコニウム、亜鉛、鉄、鉛等の
塩酸塩、硫酸塩、硝酸塩等
有機金属塩・・・ジブチル錫ジアセテート、オクチル酸
亜鉛、ジブチル錫ジラウレー
ト、オクチル酸錫、ブチルチタネ
ート等を用いる。These include: Inorganic metal salts...organic metal salts such as hydrochlorides, sulfates, and nitrates of tin, zirconium, zinc, iron, lead, etc....dibutyltin diacetate, zinc octylate, dibutyltin dilaurate, octylic acid Tin, butyl titanate, etc. are used.
また浴の安定剤として無機酸、有機酸、例えば塩酸、硫
酸、リン酸、醋酸、氷酸酸、ギ酸等を用いる。Inorganic acids and organic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, glacial acid, and formic acid are used as bath stabilizers.
本発明は上記組成より成る処理浴中に被加工布を浸漬処
理し、所望のピックアップ率にて引出した後、予備乾燥
、ベーキング等の加熱処理を行う。In the present invention, a cloth to be processed is immersed in a treatment bath having the above composition, pulled out at a desired pick-up rate, and then subjected to heat treatment such as preliminary drying and baking.
以下、実施例、比較例及び従来法を挙げて説明する。Examples, comparative examples, and conventional methods will be described below.
下記第１表は処理浴の組成を示したものである。Table 1 below shows the composition of the treatment bath.
上記組成に水を加え全量を１１とした液にポリエステル
２段１両面編地を浸漬し、ピックアップ率９５％とした
後、１００℃で３分間乾燥し、１８０℃で１分間ベーキ
ング処理した。A 2-row, 1-double-sided polyester knitted fabric was immersed in a solution of the above composition with water added to make a total volume of 11 to give a pick-up rate of 95%, dried at 100°C for 3 minutes, and baked at 180°C for 1 minute.
なお、従来法／Ｉ６１は同一素材に塩化ビニル樹脂をコ
ーティングし、乾燥後にキユアリングしたものである。In the conventional method/I61, the same material was coated with vinyl chloride resin and cured after drying.
以上の条件で加工した本発明法加工布を、比較法及び従
来法加工布と比較すると下記第２表に示す通りである。The fabric processed by the present invention processed under the above conditions is compared with the fabric processed by the comparative method and the conventional method as shown in Table 2 below.
上記の第２表より■金属塩と氷醋酸の使用により、耐水
度の耐洗濯性が著しく向上していることが判る。From Table 2 above, it can be seen that the use of metal salt and glacial acetic acid significantly improves the water resistance and washing resistance.
また■氷醋酸により処理浴（樹脂液）の安定性がよくな
り、Ｐａｄ−Ｎｉｐでのガムアップ（Ｇｕｍｕｐ）が防
止でき、均一な樹脂皮膜が得られる。Moreover, (2) the stability of the treatment bath (resin liquid) is improved by the use of glacial acetic acid, it is possible to prevent gum-up in Pad-Nip, and a uniform resin film can be obtained.
前記ガムアップとは、樹脂液中で樹脂が反応して固形物
となることで、樹脂浴が不安定となる均一な樹脂皮膜が
得られない。The gum-up refers to the reaction of the resin in the resin liquid to form a solid substance, which makes the resin bath unstable and makes it impossible to obtain a uniform resin film.
く第２表の評価法〉
■８通気度は・・・ＵＳ人規格 Ｌｉ２．５１． １９
６８ＡＳＴＭ Ｄ−７３７−６７
フラジール通気性試験
２、耐水度は・・・ＪＩＳＬ１０７９−１９７６６．３
１．１耐水度
３、耐洗濯性は・・・家庭用洗剤にュービーズ）２ｇ／
ｌで家庭用洗濯機により５分間
洗濯、すすぎ後乾燥を１０回、
５０回繰返しにより行なった。Evaluation method in Table 2> ■8 Air permeability is...US standard Li2.51. 19
68ASTM D-737-67 Frazier air permeability test 2, water resistance...JISL1079-19766.3
1.1 Water resistance: 3, washing resistance: household detergent (Ubeads) 2g/
The cloth was washed for 5 minutes in a household washing machine, rinsed, and then dried 10 times and then 50 times.
４、浴安定性は・・・樹脂液をホモミキサーで１０分間
攪拌後、沖過を行なう。4. Bath stability: After stirring the resin liquid with a homomixer for 10 minutes, it is filtered.
沢過後の濾紙上のガムの状況を評価する。Evaluate the condition of the gum on the filter paper after filtration.
下記第３表は、本発明を実施するに当っての最適濃度を
示したものである。Table 3 below shows the optimum concentrations for practicing the present invention.
この表によれば触媒の最適濃度はｉｏ ｇ７ｉ前後、氷
醋酸は最適濃度は２〜５ｇ／ｌが好適である。According to this table, the optimum concentration of the catalyst is approximately io g7i, and the optimum concentration of glacial acetic acid is preferably 2 to 5 g/l.
以上の結果より明らかなように、本発明方法によれば、
従来法に比しては通気性と防水性に優れ、かつ耐洗濯性
にも優れ、また比較例である特開昭５６−１２３４７９
号に比し、特に耐洗濯性において飛躍的に優れたもので
あり、長期的にその性能を持続することができる。As is clear from the above results, according to the method of the present invention,
Compared to the conventional method, it has superior breathability and waterproofing properties, as well as excellent washing resistance.
Compared to No. 2, it is significantly superior in washing resistance, and can maintain its performance over a long period of time.
尚、本発明においてフッ素系撥水剤の用量を重量比にお
いて反応型オルガノポリシロキサンに比し５０重量％以
下とすることは、防水性及び耐洗濯性が低下するので好
ましくない。In the present invention, it is not preferable that the amount of the fluorine-based water repellent be less than 50% by weight compared to the reactive organopolysiloxane, since this reduces waterproofness and washing resistance.
また、本発明で無機あるいは有機の金属塩触媒を用いる
のは、反応型オルガノポリシロキサン（反応性シリコン
）の反応を早める為であり、酸を用いるのはガムアップ
防止、すなわち反応性シリコンの急速な反応を抑えるた
めであり、作用としては前記両者は相反するものである
が、基本的には混合処理浴を生地に付着させる直前の反
応を酸で抑えると共に生地に付着させると同時に加熱に
よって酸を飛ばし、一気に反応を促進して均一な皮膜を
形成するものである。In addition, the reason why an inorganic or organic metal salt catalyst is used in the present invention is to accelerate the reaction of reactive organopolysiloxane (reactive silicone), and the reason why an acid is used is to prevent gum-up, that is, to accelerate the reaction of reactive silicone. The purpose of this is to suppress the reaction, and the above two actions are contradictory, but basically, the reaction just before the mixed treatment bath is applied to the fabric is suppressed with an acid, and at the same time the reaction is applied to the fabric, the acid is applied by heating. , and accelerates the reaction all at once to form a uniform film.
以上のように本発明は無機あるいは有機の金属塩触媒及
び酸の存在下で反応型オルガノポリシロキサンとフッ素
系撥水剤の組合せにより、繊維表面に反応の完結したシ
リコンの強固な皮膜を形成すると共に、更にフッ素系撥
水剤の撥水性能を付加し、前記囲者の相乗作用により従
来にない耐洗濯性に優れた通気性防水加工を可能とした
ものである。As described above, the present invention forms a strong film of fully reacted silicon on the fiber surface by combining a reactive organopolysiloxane and a fluorine-based water repellent in the presence of an inorganic or organic metal salt catalyst and an acid. At the same time, the water repellency of a fluorine-based water repellent is added, and the synergistic effect of the above-mentioned surrounding material enables a breathable waterproof finish with unprecedented washing resistance.
従って素材、編織組織を問わず、かかる性能の要求され
るオムツカバー、レインコート、スポーツウェア、レイ
ンコ−ト、レジャーウェア等広汎に用いることができる
。Therefore, it can be used in a wide variety of diaper covers, raincoats, sportswear, raincoats, leisure wear, etc. that require such performance, regardless of the material or the weaving structure.
又、糸条の段階で該加工を施し、その後、編織等を形成
しても同一機能の発揮は可能である。Furthermore, the same function can be achieved even if the processing is performed at the yarn stage and then knitted or woven products are formed.
Claims (1)
反応型オルガノポリシロキサンとフッ素系撥水剤を重量
比において前者に対する後者の割合が５０パ一セント以
上となる如く混合して処理浴を構成し、該処理浴にて被
処理浴を浸漬処理した後、加熱処理することを特徴とす
る編地、織物等の耐洗濯性の優れた通気性防水加工法。1 In the presence of an inorganic or organic metal salt catalyst and an acid,
A treatment bath was prepared by mixing reactive organopolysiloxane and a fluorine-based water repellent such that the ratio of the latter to the former was 50% or more by weight, and the bath to be treated was immersed in the treatment bath. A breathable waterproofing method for knitted fabrics, woven fabrics, etc. that has excellent wash resistance and is then heat-treated.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9113380A JPS5947071B2 (en) | 1980-07-01 | 1980-07-01 | Breathable and waterproof processing method for knitted fabrics, woven fabrics, etc. with excellent wash resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9113380A JPS5947071B2 (en) | 1980-07-01 | 1980-07-01 | Breathable and waterproof processing method for knitted fabrics, woven fabrics, etc. with excellent wash resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5716975A JPS5716975A (en) | 1982-01-28 |
| JPS5947071B2 true JPS5947071B2 (en) | 1984-11-16 |
Family
ID=14018029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9113380A Expired JPS5947071B2 (en) | 1980-07-01 | 1980-07-01 | Breathable and waterproof processing method for knitted fabrics, woven fabrics, etc. with excellent wash resistance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5947071B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62141519U (en) * | 1986-02-28 | 1987-09-07 | ||
| EP0777009A2 (en) | 1995-11-28 | 1997-06-04 | Dow Corning Toray Silicone Company Ltd. | Compositions for treating fibers and textiles |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58144179A (en) * | 1982-02-23 | 1983-08-27 | 東レ株式会社 | Permanent water repellent fabric and production thereof |
-
1980
- 1980-07-01 JP JP9113380A patent/JPS5947071B2/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62141519U (en) * | 1986-02-28 | 1987-09-07 | ||
| EP0777009A2 (en) | 1995-11-28 | 1997-06-04 | Dow Corning Toray Silicone Company Ltd. | Compositions for treating fibers and textiles |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5716975A (en) | 1982-01-28 |
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