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JPS6016899B2 - FRP molding method - Google Patents
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JPS6016899B2 - FRP molding method - Google Patents

FRP molding method

Info

Publication number
JPS6016899B2
JPS6016899B2 JP53084254A JP8425478A JPS6016899B2 JP S6016899 B2 JPS6016899 B2 JP S6016899B2 JP 53084254 A JP53084254 A JP 53084254A JP 8425478 A JP8425478 A JP 8425478A JP S6016899 B2 JPS6016899 B2 JP S6016899B2
Authority
JP
Japan
Prior art keywords
resin
reinforcing fiber
fiber material
frp
molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP53084254A
Other languages
Japanese (ja)
Other versions
JPS5514205A (en
Inventor
良一 松浦
醇一 松井
信則 林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP53084254A priority Critical patent/JPS6016899B2/en
Publication of JPS5514205A publication Critical patent/JPS5514205A/en
Publication of JPS6016899B2 publication Critical patent/JPS6016899B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)
  • Reinforced Plastic Materials (AREA)

Description

【発明の詳細な説明】 本発明は、FRPの成形方法に関するものである。[Detailed description of the invention] The present invention relates to a method for molding FRP.

樹脂を繊維で強化してなるFRP(繊維強化プラスチッ
ク:Fiber ReinmcedPlastics)
は、軽量かつ高強度、高弾性であるという優れた特長を
有しているため、いろいろな産業分野において広く用い
られる。
FRP (Fiber Reinforced Plastics) made by reinforcing resin with fibers
has the excellent features of being lightweight, high strength, and high elasticity, so it is widely used in various industrial fields.

このようなFRPは、従来、たとえばプリプレグ法と呼
ばれる方法や樹脂含浸法と呼ばれる方法によって作られ
ている。
Such FRP has conventionally been produced, for example, by a method called a prepreg method or a method called a resin impregnation method.

すなわち、プリプレグ法は、補強用繊維材料に熱硬化性
樹脂を含浸予備硬化させた、いわゆるプリプレグを用い
、このプリプレグをたとえば金型の中に積み重ね、加熱
加圧して成形する方法である。
That is, the prepreg method is a method in which so-called prepreg, which is a reinforcing fiber material impregnated with a thermosetting resin and precured, is stacked in, for example, a mold, and molded by heating and pressing.

また、樹脂舎浸法は、補強用繊維材料を所望の形状を有
するように裁断した後これに液状の樹脂を含浸し、直ち
に成形する方法である。しかしながら、上述したような
プリプレグ法は、いかなるFRPの種類や形状にも適合
するように、いろいろな種類の熱硬化性樹脂と補強用繊
維材料とからなるプリブレグを、あらかじめ準備してお
く必要があるという欠点があった。また、プリプレグは
熱硬化性樹脂が成形前において完全に硬化してしまわな
いように、冷蔵または冷凍の状態で保管されるが、上述
したように多種類のプリプレグを作っておく必要がある
と、補強用繊維材料込みの状態で保管するため、広い保
管設備が必要であるといいう欠点があった。また、樹脂
舎浸法は、成形直前に補強用繊維材料への液状樹脂の含
浸を行うので、成形工程の作業環境が悪いという欠点が
あった。
The resin soaking method is a method in which a reinforcing fiber material is cut into a desired shape, impregnated with liquid resin, and immediately molded. However, in the prepreg method described above, it is necessary to prepare prepregs made of various types of thermosetting resins and reinforcing fiber materials in advance so as to be compatible with any type and shape of FRP. There was a drawback. In addition, prepreg is stored in a refrigerated or frozen state to prevent the thermosetting resin from completely curing before molding, but as mentioned above, it is necessary to make many different types of prepreg. Since it is stored with the reinforcing fiber material included, it has the disadvantage of requiring a large storage facility. Furthermore, the resin immersion method has the disadvantage that the reinforcing fiber material is impregnated with liquid resin immediately before molding, resulting in a poor working environment during the molding process.

本発明の目的は、従釆のFRPの成形方法の上記欠点を
解決し、樹脂や補強用繊維材料の組み合わせの自由度が
大きく、いろいろな種類の形状のFRPを簡単に成形す
ることができ、しかも成形工程の作業環境が良好であり
、全体としてFRPのコストを低減することができるF
RPの成形方法を提供するにある。
The purpose of the present invention is to solve the above-mentioned drawbacks of conventional FRP molding methods, to have a large degree of freedom in combining resins and reinforcing fiber materials, and to easily mold FRP in various shapes. Furthermore, the working environment in the molding process is good, and the overall cost of FRP can be reduced.
The present invention provides a method for molding RP.

上記目的を達成する本発明は、補強用繊維材料とこの補
強用繊維材料とは別に用意した熱可塑性の樹脂材料また
は半硬化状態の熱硬化性の樹脂材料とを成形時に重ね合
わせ、この重ね合わせの状態のまま加熱加圧して前記補
強用繊維材料に前記樹脂材料の樹脂を合浸し、さらに前
記樹脂を硬化させるFRPの成形方法を特徴とするもの
である。
The present invention achieves the above object by overlapping a reinforcing fiber material and a thermoplastic resin material or a semi-hardened thermosetting resin material prepared separately from the reinforcing fiber material during molding, and The FRP molding method is characterized in that the reinforcing fiber material is soaked with the resin of the resin material by heating and pressurizing the reinforcing fiber material in the above state, and the resin is further cured.

本発明にいう“半硬イa氏態の熱硬化性の樹脂材料”と
は、液状のように流動性は有しないが、完全には硬化し
ていないような熱硬化性樹脂であって、かつシート状や
テープ状、棒状のような形態を有するものをいう。
In the present invention, the "semi-hard thermosetting resin material in A mode" refers to a thermosetting resin that does not have fluidity like a liquid, but is not completely hardened. It also refers to something that has a sheet-like, tape-like, or rod-like shape.

上記のような半硬イQ伏態の熱硬化性樹脂は、加熱する
ことによって完全に硬化する。次に、本発明のFRPの
成形方法を具体的に説明する。
The above-mentioned semi-hard AQ-lowered thermosetting resin is completely cured by heating. Next, the FRP molding method of the present invention will be specifically explained.

本発明において使用する補強用繊維材料は炭素繊維、ガ
ラス繊維、シリコンカーバイト繊維、ポロン繊維、有機
高弾性繊維、ポリアミド繊維、ポリエステル繊維のよう
な高強度、高弾性繊維を、シート状やテープ状、ホース
状に加工したようなものである。それは、たとえば各種
の織物や編物、すだれ、マット、組みひものようなもの
である。半硬化状態の熱硬化性の樹脂材料を構成する熱
硬化性樹脂は、ェポキシ系樹脂や不飽和ポリエステル系
樹脂、ポリィミド系樹脂、フェノール系樹脂のようなも
のである。
The reinforcing fiber materials used in the present invention are high-strength, high-elastic fibers such as carbon fibers, glass fibers, silicon carbide fibers, poron fibers, organic high-elastic fibers, polyamide fibers, and polyester fibers in the form of sheets or tapes. It looks like it has been processed into a hose shape. Examples include various types of woven and knitted fabrics, blinds, mats, and braids. The thermosetting resin constituting the semi-cured thermosetting resin material includes epoxy resin, unsaturated polyester resin, polyimide resin, and phenol resin.

樹脂材料はまた、ポリアミド系樹脂やアクリルニトリル
、ブタジェン、スチレン系樹脂、ポリプチレンテレフタ
レート系樹脂のような熱可塑性樹脂を、シート状やテー
プ状、棒状に加工したようなものであってもよい。
The resin material may also be one obtained by processing a thermoplastic resin such as polyamide resin, acrylonitrile, butadiene, styrene resin, or polybutylene terephthalate resin into a sheet, tape, or rod shape.

このような熱可塑性の樹脂材料の樹脂は、成形時に加熱
することによって流動性を有するようになり、補強用繊
維材料に含浸される。さて、上述したような補強用繊維
材料と樹脂材料を用いてFRPを成形するには、たとえ
ば次のようにして行う。
The resin of such a thermoplastic resin material becomes fluid when heated during molding, and is impregnated into the reinforcing fiber material. Now, in order to mold FRP using the above-mentioned reinforcing fiber material and resin material, it is carried out, for example, as follows.

すなわち、板状のFRPを成形するような場合には、シ
ート状の補強用繊維材料とシート状の樹脂材料とを用い
、これらの所要複数枚を金型内に交互に重ね合わせて積
み、加熱加圧して補強用繊維材料に樹脂材料の樹脂を含
浸させ、さらに樹脂を硬化させる。
In other words, when molding a plate-shaped FRP, a sheet-shaped reinforcing fiber material and a sheet-shaped resin material are used, and the required number of sheets are stacked alternately in a mold and heated. Pressure is applied to impregnate the reinforcing fiber material with the resin of the resin material, and the resin is further cured.

管状のFRPを成形するような場合には、1枚のシート
状の補強用繊維材料と1枚のシート状の樹脂材料とを重
ね合わせ、樹脂材料が内側になるようにマンドレルに巻
き付け、さらにその上から熱収縮性フィルムを巻き付け
た後オーブン中で加熱して補強用繊維材料に樹脂材料の
樹脂を含浸させ、さらに樹脂を硬化させた後マンドレル
を引き抜く。
When molding tubular FRP, one sheet of reinforcing fiber material and one sheet of resin material are overlapped, wrapped around a mandrel with the resin material on the inside, and then After wrapping a heat-shrinkable film on top, it is heated in an oven to impregnate the reinforcing fiber material with the resin of the resin material, and after the resin is further cured, the mandrel is pulled out.

このとき、樹脂材料が補強用繊維材料の外側になるよう
に巻き付けることができるが、特に薄肉の管状FRPを
成形する場合は、上述したように樹脂材料が内側になる
ように巻き付けるほうが、成形時のポィドが少なくなる
ので好ましい。なお、このような成形方法を採る場合、
シート状の補強用繊維材料を挟むようにその両側にシー
ト状の樹脂材料を重ね合わせて用いてもよいし、それぞ
れの複数枚を交互に重ね合せて用いてもよい。以上説明
したように、本発明のFRPの成形方法は、補強用繊維
材料とこの補強用繊維材料とは別に用意した熱可塑性の
樹脂材料または半硬イひ伏態の熱硬化性の樹脂材料とを
成形時に重ね合わせて成形するので、補強用繊維材料と
樹脂との組み合わせの自由度が大きく、いろいろな種類
や形状のFRPを簡単に成形することができる。
At this time, it is possible to wrap the resin material on the outside of the reinforcing fiber material, but especially when molding thin-walled tubular FRP, it is better to wrap it so that the resin material is on the inside as described above. This is preferable because it reduces the number of pods. In addition, when adopting such a molding method,
A sheet-like reinforcing fiber material may be sandwiched with sheet-like resin materials stacked on both sides thereof, or a plurality of sheets of each resin material may be stacked alternately. As explained above, the FRP molding method of the present invention uses a reinforcing fiber material and a thermoplastic resin material or semi-rigid thermosetting resin material prepared separately from the reinforcing fiber material. Since these are overlapped during molding, there is a large degree of freedom in combining the reinforcing fiber material and resin, and various types and shapes of FRP can be easily molded.

また、従来のプリプレグ法のように、補強用繊維材料に
樹脂を含浸した状態のまま冷蔵または冷凍保管する必要
がなく、樹脂材料のみを補強用繊維材料とは別に保管す
ることができるので、広い冷蔵または冷凍保管設備を必
要としない。
In addition, unlike the conventional prepreg method, there is no need to refrigerate or freeze the reinforcing fiber material impregnated with resin, and the resin material can be stored separately from the reinforcing fiber material. Does not require refrigeration or frozen storage facilities.

さらに、従来の樹脂含浸法のように、成形時に補強用繊
維材料に液状の樹脂を含浸する必要がないので、成形工
程の作業環境が良好である。
Furthermore, unlike conventional resin impregnation methods, there is no need to impregnate the reinforcing fiber material with liquid resin during molding, resulting in a favorable working environment during the molding process.

Claims (1)

【特許請求の範囲】[Claims] 1 補強用繊維材料とこの補強用繊維材料とは別に用意
した熱可塑性の樹脂材料または半硬化状態の熱硬化性の
樹脂材料とを成形時に重ね合わせ、この重ね合わせの状
態のまま加熱加圧して前記補強用繊維材料に前記樹脂材
料の樹脂を含浸し、さらに前記樹脂を硬化させることを
特徴とするFRPの成形方法。
1. A reinforcing fiber material and a thermoplastic resin material or a semi-hardened thermosetting resin material prepared separately from the reinforcing fiber material are overlapped during molding, and heated and pressurized while in this overlapping state. A method for molding FRP, comprising impregnating the reinforcing fiber material with a resin of the resin material, and further curing the resin.
JP53084254A 1978-07-11 1978-07-11 FRP molding method Expired JPS6016899B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP53084254A JPS6016899B2 (en) 1978-07-11 1978-07-11 FRP molding method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP53084254A JPS6016899B2 (en) 1978-07-11 1978-07-11 FRP molding method

Publications (2)

Publication Number Publication Date
JPS5514205A JPS5514205A (en) 1980-01-31
JPS6016899B2 true JPS6016899B2 (en) 1985-04-30

Family

ID=13825316

Family Applications (1)

Application Number Title Priority Date Filing Date
JP53084254A Expired JPS6016899B2 (en) 1978-07-11 1978-07-11 FRP molding method

Country Status (1)

Country Link
JP (1) JPS6016899B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01212898A (en) * 1987-10-09 1989-08-25 Kontron Holding Ag Sighting system

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56106817A (en) * 1980-01-31 1981-08-25 Shin Kobe Electric Mach Co Ltd Press molding method for thermoplastic resin sheet
EP0040492A3 (en) * 1980-05-21 1984-07-11 Mitsubishi Rayon Co., Ltd. Moulding material for fibre reinforced plastic tubes
JPS60256024A (en) * 1984-06-01 1985-12-17 Nikkiso Co Ltd Force plate for walking anaysis system
JPS63264637A (en) * 1987-04-21 1988-11-01 Nisshinbo Ind Inc Electroconductive fiber membranous structural material
US7842378B2 (en) 2004-01-06 2010-11-30 Kabushiki Kaisha Toyota Jidoshokki Energy absorber and method for manufacturing the same
WO2020157895A1 (en) * 2019-01-31 2020-08-06 株式会社サングード Laminated composite material, and method for manufacturing laminated composite material

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS493969A (en) * 1972-04-25 1974-01-14
JPS5210908A (en) * 1975-07-15 1977-01-27 Hitachi Ltd Operation method for oil-cooled positive-displacement rotary compresso r

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01212898A (en) * 1987-10-09 1989-08-25 Kontron Holding Ag Sighting system

Also Published As

Publication number Publication date
JPS5514205A (en) 1980-01-31

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