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JPS6031806B2 - Make-up cosmetics - Google Patents
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JPS6031806B2 - Make-up cosmetics - Google Patents

Make-up cosmetics

Info

Publication number
JPS6031806B2
JPS6031806B2 JP52062994A JP6299477A JPS6031806B2 JP S6031806 B2 JPS6031806 B2 JP S6031806B2 JP 52062994 A JP52062994 A JP 52062994A JP 6299477 A JP6299477 A JP 6299477A JP S6031806 B2 JPS6031806 B2 JP S6031806B2
Authority
JP
Japan
Prior art keywords
cosmetics
makeup
ehec
oil
wax
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP52062994A
Other languages
Japanese (ja)
Other versions
JPS53148547A (en
Inventor
道子 奈良
靖子 秋山
一徳 山崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP52062994A priority Critical patent/JPS6031806B2/en
Publication of JPS53148547A publication Critical patent/JPS53148547A/en
Publication of JPS6031806B2 publication Critical patent/JPS6031806B2/en
Expired legal-status Critical Current

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  • Cosmetics (AREA)

Description

【発明の詳細な説明】 本発明はメイクアップ化粧料特にアィメィクアップ化粧
料に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to make-up cosmetics, particularly eye make-up cosmetics.

従来のメイクアップ化粧料の欠点であった「化粧くずれ
」即ち化粧料に対する汗、涙、皮脂などの人体分泌物の
作用及び雨、雪、プールの水、海水など化粧料使用時の
夫倭、場所の諸条件に起因する水分の作用、併用する他
の化粧料中の諸成分の作用など主に化学的作用によるイ
凶姓くずれ、更にイ劫斑料の使用部位における皮膚の動
き、王或は衣類によるマサッなど主に物理的作用による
化粧くずれ、これ等の種々の「化粧くずれ」を解決し、
衣類も汚染しない化粧もちの良好なメイクアップ化粧料
を得ようとするものである。更に従来のメイクアップ化
粧料には水系、油系、乳化系及び粉末系など多種多様な
処方形態のものがあるが、例えば、水系のものは親水性
物質を多量に含有するため、汗、涙、雨などにより化粧
くずれし易い、即ち耐水性が不良である。
The drawback of conventional makeup cosmetics is "makeup discoloration," which is the effect of human body secretions such as sweat, tears, and sebum on cosmetics, and the effects of rain, snow, pool water, seawater, etc. when using cosmetics. It is mainly caused by chemical effects such as the action of moisture due to the conditions of the place and the action of various ingredients in other cosmetics used together, and also the movement of the skin in the area where the blemish pigment is used, It solves various types of "makeup discoloration" mainly caused by physical effects such as stiffness due to clothing, etc.
The purpose is to obtain a makeup cosmetic with good makeup retention that does not contaminate clothing. Furthermore, conventional makeup cosmetics come in a wide variety of formulations, such as water-based, oil-based, emulsified, and powder-based. , make-up easily fades due to rain, etc., that is, water resistance is poor.

又、油系のものは親油性物質を多量に含有するため皮脂
或は併用する化粧料の油分等により、化粧くずれし易い
、即ち耐油性が不良である。乳化系のものは耐水性、耐
油性のいずれも充分ではない。粉末系のものは耐水性、
耐油性に劣り、更に使用部位における皮膚の動き、手或
は衣類によるマサッにより化粧くずれし易い、即ち、肌
への接着性が不良である。又衣類も汚染し易い。本発明
は上記〆ィクアップ化粧料の欠点を解決すべく、主に油
系、乳化系メイクアツプイQ鮭料を基にして、これに或
種の油溶性セルロース誘導体を配合することにより、目
的を達成し、耐水性、耐油性、接着性に顔れた化粧くず
れのない、化粧もち良好なメイクアップ化粧料を得るも
のである。
In addition, since oil-based products contain a large amount of lipophilic substances, they tend to be easily damaged by sebum or the oil content of cosmetics used in combination, that is, they have poor oil resistance. Emulsion type products do not have sufficient water resistance or oil resistance. Powder type is water resistant,
It has poor oil resistance, and makeup tends to come off due to movement of the skin at the site of use or being massaged by hands or clothing, that is, it has poor adhesion to the skin. Clothes are also easily contaminated. In order to solve the drawbacks of the above-mentioned makeup cosmetics, the present invention achieves the purpose by blending a certain type of oil-soluble cellulose derivative into a makeup product based mainly on oil-based and emulsified makeup makeup Q-salmon ingredients. To obtain a make-up cosmetic that has good water resistance, oil resistance, and adhesive properties, does not cause makeup deterioration, and has good makeup retention.

従来の化粧料成分中にはシェラツク、ロジンのような天
然系油溶性樹脂が、又、エチルセルロ*ース、ニトロセ
ルロース、酢酸セルロースなどの油溶性セルロ−ス誘導
体、アルキド樹脂、酢酸ピニル樹脂、ポリエステル樹脂
、アリルスルフオンアミドーホルムアルデヒド樹脂など
が更にその他多種多様の水落性高分子が用いられてきた
が、特に油溶性樹脂の場合、一部溶剤系を除いて、ほと
んど各成分との相溶性も劣り、イ日舞もちが良好である
とは言い難いものである。本発明は皮膜形成能のある油
溶性セルロース誘導体であるエチルハイドロキシェチル
セルロース(以下EHECと略す)を使用することによ
って上記各欠点をなくし、優れたメイクアップ化粧料を
得た。
Conventional cosmetic ingredients include natural oil-soluble resins such as shellac and rosin, oil-soluble cellulose derivatives such as ethylcellulose, nitrocellulose, and cellulose acetate, alkyd resins, pinyl acetate resins, and polyesters. Resins, allylsulfonamide formaldehyde resins, and a wide variety of other water-soluble polymers have been used, but especially in the case of oil-soluble resins, they are not compatible with most of the components except for some solvent-based resins. However, it is difficult to say that the performance is good. The present invention eliminates the above-mentioned drawbacks by using ethyl hydroxyethyl cellulose (hereinafter abbreviated as EHEC), which is an oil-soluble cellulose derivative capable of forming a film, and provides an excellent makeup cosmetic.

このEHECの一般式は、で示され、セルロースの−O
H基中多くのものがェトキシル基又はェトキシェトキシ
ル基で置換されているものであり、置換度nは2.4〜
2.8である。
The general formula of this EHEC is shown as -O of cellulose
Many of the H groups are substituted with ethoxyl groups or ethoxyshethoxyl groups, and the degree of substitution n is 2.4 to 2.4.
It is 2.8.

EHECは極性のあるワックス、オイルに溶解し、無極
性の鎖式炭化水素にも溶解或は膨潤する。
EHEC dissolves in polar waxes and oils, and also dissolves or swells in nonpolar chain hydrocarbons.

熔解しないものにはエタノールやインプロピルアルコー
ルのようなCosolventを加えることにより透明
に溶解する。即ちEHECは種々の物質との相瀞性に優
れている。又、増粘剤、顔料の浮き防止としての効果も
具備している。
Those that do not dissolve can be dissolved transparently by adding a cosolvent such as ethanol or inpropyl alcohol. That is, EHEC has excellent compatibility with various substances. It also has the effect of acting as a thickener and preventing pigments from floating.

このEHECをメイクアップ化粧料成分中1〜15%配
合することにより、目的を蓮せられる。
By incorporating 1 to 15% of this EHEC into makeup cosmetic ingredients, the purpose can be achieved.

即ち、EHECの上記特性が製品特性に顕著に現われ、
耐水性、耐油性、接着性に優れ、化粧くずれのない化粧
もちの良好なメイクアッブイ均鑑料が得られる。次に、
本発明の実施例を示す。%は重量%である。実施例 1
アィシャドゥ 蟹質流動パラフィン 60%ラノリ
ン誘導体 5%セレシンワツク
ス 10%EHEC
5%ピースワックス
5%パール剤
10%青色界羊青
5%防腐剤 適量香 料
適量(製法)ラノリ
ン誘導体、セレシンワツクス及びピースワックスを80
〜90℃で均一に加熱溶解したものに竪質流動パラフィ
ンとEHECを混合溶解したものを添加して縄梓分散す
る。
In other words, the above characteristics of EHEC appear prominently in the product characteristics,
To obtain a make-up uniform agent that has excellent water resistance, oil resistance, and adhesion, and has good makeup retention without smearing the makeup. next,
An example of the present invention is shown. % is by weight. Example 1
Aishadu Crab Liquid Paraffin 60% Lanolin Derivatives 5% Ceresin Wax 10% EHEC
5% peace wax
5% pearl agent
10% blue world sheep blue
5% preservative, appropriate amount fragrance
Appropriate amount (manufacturing method) lanolin derivative, ceresin wax and peace wax 80%
A mixed solution of vertical liquid paraffin and EHEC is added to the solution uniformly heated and dissolved at ~90° C. and dispersed in a rope.

その後パール剤、青色弟羊青、防腐剤及び香料を添加す
ればブルーのクリームアィシャドウが得られる。実施例
2 マスカラ 竪質流動パラフィン 50%ピース
ワックス 13力ルナウバワツ
クス 3EHEC
IOラ/リン誘導体
5ソルビタンモノステアレート
2イオン交換水
15カーボンブラック 2防
腐剤 適量香 料
適量(製法)ピースワック
ス、力ルナウバワツクス、ラノリン誘導体及びソルビタ
ンモノステアレートを80〜90℃で均一に加熱熔解し
たものに軽質流動パラフィンにEHECを70qoで混
合溶解したものを添加して額梓分散後、カーボンブラッ
クを混合して、イオン交換水、防腐剤及び香料を添加す
ればブラックのクリームマスカラが得られる。
Then, by adding a pearl agent, blue violet blue, a preservative, and a fragrance, a blue cream eye shadow can be obtained. Example 2 Mascara Vertical Liquid Paraffin 50% Peace Wax 13 Power Lunauba Wax 3EHEC
IO La/Lin derivative
5 Sorbitan monostearate
2 ion exchange water
15 Carbon black 2 Preservatives Appropriate amount fragrance
Appropriate amount (manufacturing method) Peace wax, Lunauba wax, lanolin derivative, and sorbitan monostearate are heated and melted uniformly at 80 to 90°C, and a mixture of light liquid paraffin and EHEC at 70 qo is added and dispersed. A black cream mascara can be obtained by mixing carbon black and adding ion-exchanged water, preservatives and perfume.

実施例 3 クリームファンデーション イソパラフイン 50%炭化
水素ワックス 5ラノリン議導
体 5EHEC
′ 3酸化鉄
3二酸化チタン
12タルク
20有機変性モンモリロナイト
2香 料 適量(製
法)ィソパラフィンに炭化水素ワックス、ラノリン誘導
体、EHEC、有機変性モンモリロナィトを添加して加
熱溶解分散させたものに酸化鉄、二酸化チタン、タルク
を添加し、縄梓分散後、香料を添加混合して冷却すれば
クリームファンデーションが得られる。
Example 3 Cream foundation Isoparaffin 50% hydrocarbon wax 5 Lanolin conductor 5EHEC
' Iron trioxide
titanium dioxide
12 talc
20 Organically modified montmorillonite
2 Fragrance Appropriate amount (manufacturing method) Hydrocarbon wax, lanolin derivative, EHEC, and organically modified montmorillonite are added to isoparaffin, heated and dissolved and dispersed, iron oxide, titanium dioxide, and talc are added, and after the rope is dispersed, the fragrance is added. A cream foundation can be obtained by adding, mixing, and cooling.

実施例 4 液状口紅 イソパラフイン 49%炭化
水素ワックス 10流動パラフィ
ン 8ラノリン誘導体
5EHEC
15アルミニウムステアレート
1赤色201号
3赤色202号
4パール剤 5香 料
適量(製法)ィソパラ
フィンに炭化水素ワックス、流動パラフィン、ラノリン
誘導体、EHEC、アルミニウムステアレートを添加し
て加熱溶解分散させたものに赤色201号、赤色202
号、パール剤を添加し、縄梓分散後、香料を添加混合し
て冷却すれば液状口紅が得られる。
Example 4 Liquid lipstick isoparaffin 49% hydrocarbon wax 10 Liquid paraffin 8 Lanolin derivative
5EHEC
15 aluminum stearate
1 Red No. 201
3 Red No. 202
4 Pearl agent 5 Fragrance
Appropriate amount (manufacturing method) Hydrocarbon wax, liquid paraffin, lanolin derivative, EHEC, and aluminum stearate are added to isoparaffin and dissolved and dispersed by heating to produce Red No. 201 and Red No. 202.
A liquid lipstick can be obtained by adding a pearl agent, dispersing the powder, adding a fragrance, and cooling the mixture.

次に本発明のメイクアップイQ鮭料である実施例2のク
リームマスカラ処方中EHECの配合量を2.5〜15
.0%配合したクリームマスカラとEHECの配合され
ていないクリームマスカラ(従来品)との耐油性.耐水
性についての比較データを第1図に示す。
Next, the amount of EHEC in the cream mascara formulation of Example 2, which is the Makeup Q salmon ingredient of the present invention, was adjusted to 2.5 to 15%.
.. Oil resistance between cream mascara containing 0% and cream mascara (conventional product) containing no EHEC. Comparative data regarding water resistance is shown in Figure 1.

又、標準の耐油性及び耐水性の試験方法は次のとおりで
ある。
In addition, the standard oil resistance and water resistance test methods are as follows.

耐油性及び耐水性:クリームマスカラを塗布乾燥した板
を試験紙(試験液:○/W型乳液を定量滴下)上に、一
定回数(50回接触させ、試験紙上への転写の度合を比
較する。
Oil resistance and water resistance: A plate coated with cream mascara and dried is brought into contact with a test paper (test liquid: ○/W type emulsion is dropped in fixed amounts) a certain number of times (50 times), and the degree of transfer onto the test paper is compared. .

この試験を2回繰り返した。(0/W型乳液の処方) 流動パラフィン 2の重量%ラノリ
ン 5ピースワックス
15グリセリンモノステアレート(自己乳化
型)7水(イオン交換水) 53
香 料 適量防腐剤
適量第1図において、EH
ECの配合されていないクリームマスカラ(従来品)と
各EHECの配合量2.5〜15.0%の本発明品クリ
ームマスカラの比較から明らかに耐油性、耐水性に優れ
ていることが確認された。
This test was repeated twice. (Formulation of 0/W type emulsion) Liquid paraffin 2% by weight Lanolin 5 piece wax
15 Glycerin monostearate (self-emulsifying type) 7 Water (ion exchange water) 53
Fragrance Appropriate amount of preservative
Appropriate amount In Figure 1, EH
A comparison of the cream mascara containing no EC (conventional product) and the cream mascara of the present invention containing 2.5 to 15.0% of each EHEC revealed that it clearly has excellent oil resistance and water resistance. Ta.

即ち試験紙上への転写の度合が薄くなる程耐油性、耐水
性が良好である。本発明はその他のファンデーション類
、アィブロウ、アイシャドウ、アィライナ−、マスカラ
等のアィメイクアップ化粧料類、ボディペイント、ネイ
ルエナメル、口紅、毛髪用着色料及びレッグメイクアッ
プ化粧料等の皮層イ劫姓料や頭髪化粧料に広く応用され
るものである。
That is, the thinner the degree of transfer onto the test paper, the better the oil resistance and water resistance. The present invention is applicable to other foundations, eye make-up cosmetics such as eyebrows, eye shadows, eyeliners, and mascaras, body paints, nail enamels, lipsticks, hair colorants, and leg make-up cosmetics that affect the skin layer. It is widely applied to cosmetics and hair cosmetics.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はクリームマスカラにおけるEHECの配合効果
による耐油性及び耐水性の効果を図面に示したものであ
る。 第1図
FIG. 1 is a diagram showing the effect of oil resistance and water resistance due to the blending effect of EHEC in cream mascara. Figure 1

Claims (1)

【特許請求の範囲】 1 一般式 ▲数式、化学式、表等があります▼ (セルロースの3個の−OH基中多くのものがエトキ
シル基又はエトキシエトキシル基で置換され、置換度2
.4〜2.8)で示されるエチルハイドロキシエチルセ
ルローズを1〜15%配合することを特徴とするメイク
アツプ化粧料。
[Claims] 1 General formula ▲ Numerical formula, chemical formula, table, etc.
.. A makeup cosmetic comprising 1 to 15% of ethyl hydroxyethyl cellulose represented by 4 to 2.8).
JP52062994A 1977-05-30 1977-05-30 Make-up cosmetics Expired JPS6031806B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP52062994A JPS6031806B2 (en) 1977-05-30 1977-05-30 Make-up cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP52062994A JPS6031806B2 (en) 1977-05-30 1977-05-30 Make-up cosmetics

Publications (2)

Publication Number Publication Date
JPS53148547A JPS53148547A (en) 1978-12-25
JPS6031806B2 true JPS6031806B2 (en) 1985-07-24

Family

ID=13216422

Family Applications (1)

Application Number Title Priority Date Filing Date
JP52062994A Expired JPS6031806B2 (en) 1977-05-30 1977-05-30 Make-up cosmetics

Country Status (1)

Country Link
JP (1) JPS6031806B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5962514A (en) * 1982-10-04 1984-04-10 Shiseido Co Ltd Cosmetic
JPH0759488B2 (en) * 1984-05-31 1995-06-28 ポーラ化成工業株式会社 Makeup cosmetics
JP2537779Y2 (en) * 1992-06-08 1997-06-04 株式会社伊藤電気製作所 Waterproof wiring box

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
THE CHEMISTRY AND MANUFACTURE OF COSMETICS=1962 *

Also Published As

Publication number Publication date
JPS53148547A (en) 1978-12-25

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