JPS6033365B2 - Improved nail enamel remover composition - Google Patents
Improved nail enamel remover compositionInfo
- Publication number
- JPS6033365B2 JPS6033365B2 JP4906478A JP4906478A JPS6033365B2 JP S6033365 B2 JPS6033365 B2 JP S6033365B2 JP 4906478 A JP4906478 A JP 4906478A JP 4906478 A JP4906478 A JP 4906478A JP S6033365 B2 JPS6033365 B2 JP S6033365B2
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- weight
- aliphatic
- nail enamel
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 210000003298 dental enamel Anatomy 0.000 title claims description 29
- 239000000203 mixture Substances 0.000 title claims description 28
- 235000019441 ethanol Nutrition 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 13
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims description 11
- 125000001931 aliphatic group Chemical group 0.000 claims description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 9
- -1 3-phenoxypropyl alcohol Chemical compound 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 6
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- OYQUCYCSSADEIC-UHFFFAOYSA-N 4-phenoxybutan-1-ol Chemical compound OCCCCOC1=CC=CC=C1 OYQUCYCSSADEIC-UHFFFAOYSA-N 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229940035429 isobutyl alcohol Drugs 0.000 claims description 2
- OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 claims 2
- 150000007824 aliphatic compounds Chemical class 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 description 15
- 230000001954 sterilising effect Effects 0.000 description 8
- 238000004659 sterilization and disinfection Methods 0.000 description 8
- 238000001035 drying Methods 0.000 description 7
- 230000002087 whitening effect Effects 0.000 description 6
- 239000002932 luster Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 230000000249 desinfective effect Effects 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- LOJHHQNEBFCTQK-UHFFFAOYSA-N 2-phenoxypropan-1-ol Chemical compound OCC(C)OC1=CC=CC=C1 LOJHHQNEBFCTQK-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- PLSHFOBOGMFPAG-UHFFFAOYSA-N C(COCCO)O.[Mo] Chemical compound C(COCCO)O.[Mo] PLSHFOBOGMFPAG-UHFFFAOYSA-N 0.000 description 1
- 235000010650 Hyssopus officinalis Nutrition 0.000 description 1
- 240000001812 Hyssopus officinalis Species 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
【発明の詳細な説明】
本発明は、改良されたネイルエナメルリムーバ−組成物
に関し、詳しくは、使用に際して爪をいためたり、白化
する等の弊害なく、消毒、殺菌効果を発揮しながら、ネ
イルエナメルを迅速、容易に溶解除去して、適度な速度
で乾燥し爪に良好なガラス用の光沢を付与し得る不燃性
のネイルエナメルリムーバー組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an improved nail enamel remover composition, and more specifically, it removes nail enamel while exhibiting disinfecting and sterilizing effects without damaging nails or causing whitening when used. The present invention relates to a nonflammable nail enamel remover composition that can be quickly and easily dissolved and removed, dry at a moderate rate, and impart a good glass gloss to nails.
従来、ネイルエナメルリムーバ−としては、脂肪族の低
級アルコール、低級アルコールのヱステル、低沸点ケト
ン等の低沸点有機溶剤からなるものや、水温和性の低沸
点有機溶剤等と水を有するものが知られている。Conventionally, nail enamel removers include those made of low-boiling point organic solvents such as aliphatic lower alcohols, lower alcohol esters, and low-boiling point ketones, and those containing water and water-friendly low-boiling point organic solvents. It is being
しかしながら、有機溶剤系のＩＪムーバーは、浸透力や
溶解力が強いために、衣類の色素を熔解したり、爪の脂
肪や水分を過度に溶解除去して爪をいためたり、白化す
る他、製造時や使用時に引火、爆発を起しやすい欠点が
ある。However, organic solvent-based IJ movers have strong penetrating and dissolving power, so they can dissolve pigments in clothing, remove excessive fat and water from nails, damage nails, whiten them, and cause other problems. It has the disadvantage of being easily flammable and explosive during use.
一方、低沸点有機溶剤−水系のリムーバーは、引火、爆
発等の危険性が少ない反面、火焔を接近すると燃焼しや
すいか、接触すると燃焼するものが多く、また、爪をい
ためたり、白化しやすい等の欠点も充分改良されていな
い。On the other hand, low boiling point organic solvent-water based removers have less risk of ignition or explosion, but on the other hand, many of them tend to burn when brought close to flames or burn when they come into contact with them, and they also tend to damage nails or whiten them. These shortcomings have not been sufficiently improved.
本発明者等は、従来技術の欠点を改良したネィルェナメ
ルリムーバーとして、先に、前記フェノキシアルカノー
ルと脂肪族低級アルコールと水が混和した組成物を提案
し、その多くの効果を確認しているが、更に系統的な研
究を続けた結果、後述の如く脂肪族ケトンを前記組成物
の構成成分と混浴する場合は、そのネイルエナメル除去
効果、乾燥性等を更に向上し得ることを見出し本発明を
完成した。The present inventors have previously proposed a composition in which the above-mentioned phenoxyalkanol, aliphatic lower alcohol, and water are mixed as a nail enamel remover that improves the drawbacks of the prior art, and have confirmed many of its effects. However, as a result of further systematic research, it was discovered that when an aliphatic ketone is mixed with the constituent components of the composition as described below, the nail enamel removal effect, drying properties, etc. can be further improved, and the present invention has been made. completed.
本発明の目的は、使用に際して爪をいためたり、白化す
る等の弊害なく、消毒、殺菌効果を発揮しながらネイル
エナメルを迅速容易に溶解除去して乾燥しやすく、爪に
良好なガラス様の光沢を付与し得る不燃性の新規なネイ
ルエナメルリムーバー組成物を提供することにある。The object of the present invention is to quickly and easily dissolve and remove nail enamel while exhibiting disinfecting and sterilizing effects without damaging the nails or causing whitening when used, and to provide a glass-like luster that is easy to dry and gives the nails a good glass-like luster. An object of the present invention is to provide a new nonflammable nail enamel remover composition that can impart the following properties.
すなわち、本発明は 一般式 （式中で、Ｒは炭素数２〜４のアルキレン基である。That is, the present invention general formula (In the formula, R is an alkylene group having 2 to 4 carbon atoms.
）で表わされるフェノキシアルカノールと脂肪族ケトン
と脂肪族低級アルコールと水が混落していることを特徴
とする改良されたネイルエナメルリムーバ−組成物であ
る。本発明に使用する前記一般式で示されるフェノキシ
アルカノールとしては、例えば、２−フェノキシエチル
アルコール、３−フエノキシプロピルアルコール、２−
フエノキシプロピルアルコール、４−フェノキシブチル
アルコール等を挙げることができる。This is an improved nail enamel remover composition characterized in that it contains a phenoxyalkanol represented by (), an aliphatic ketone, an aliphatic lower alcohol, and water. Examples of the phenoxyalkanol represented by the above general formula used in the present invention include 2-phenoxyethyl alcohol, 3-phenoxypropyl alcohol, and 2-phenoxypropyl alcohol.
Examples include phenoxypropyl alcohol and 4-phenoxybutyl alcohol.
それらの中で２−フェノキシェチルアルコールが最も好
ましい。該フェノキシアルカノールは、一つ、又は二つ
以上組合せて使用される。上記のフェノキシアルカノー
ルは水に鍵溶、アルコールやアセトン等に易溶の軽快な
る芳香を有する粘穂の液体であって、人体に対する刺激
や毒性が無い上に、高度の消毒、殺菌性を有している。
フェノキシアルカノールの適量混和によって、爪を白化
することなく良好なガラス様光沢及び消毒、殺菌効果を
付与することができる。フェノキシアルカノールの使用
量（含有量）は、組成物全量に対して２８〜６頚重量％
、好ましくは３５〜６血董量％である。２母重量％より
も少ないと使用時の爪に対するガラス様光沢の付与効果
及び消毒、殺菌効果の低下や爪の白化をきたしやすく、
６母重量％よりも多くなると不燃性の低下（燃え易くな
る）や感触の劣化をきたしやすい。Among them, 2-phenoxyethyl alcohol is most preferred. The phenoxyalkanol may be used alone or in combination of two or more. The above phenoxyalkanol is a viscous liquid with a light fragrance that is soluble in water and easily soluble in alcohol, acetone, etc., and is non-irritating or toxic to the human body, and has a high degree of disinfection and sterilization properties. ing.
By mixing an appropriate amount of phenoxyalkanol, it is possible to impart a good glass-like luster and a disinfecting and sterilizing effect without whitening the nails. The amount (content) of phenoxyalkanol used is 28 to 6% by weight based on the total amount of the composition.
, preferably 35-6%. If it is less than 2% by weight, the effect of imparting a glass-like luster to the nails, the disinfection and sterilization effects during use, and the whitening of the nails are likely to occur.
If the amount exceeds 6% by weight, the non-flammability may decrease (it becomes easier to burn) and the feel may deteriorate.
フェノキシアルカノールは前記の如く水に鍵熔で親水性
が低いけれども、脂肪族低級アルコールと脂肪族ケトン
の共存によって、比較的多量のフェノキシアルカノール
を安定に混溶して均一系を保持し得る。本発明に使用さ
れる脂肪族ケトンとしては、例えばアセトン、メチルエ
チルケトン、ジアセトンアルコール、アセチルアセトン
等が挙げられ、一つ又は二つ以上組合せて使用される。Although phenoxyalkanol is soluble in water and has low hydrophilicity as described above, the coexistence of aliphatic lower alcohol and aliphatic ketone makes it possible to stably mix and maintain a relatively large amount of phenoxyalkanol and maintain a homogeneous system. Examples of the aliphatic ketones used in the present invention include acetone, methyl ethyl ketone, diacetone alcohol, acetylacetone, etc., and one or more of them may be used in combination.
脂肪族ケトンの適量混和によって、フェノキシアルカノ
ールー脂肪族低級アルコール−水系組成物のネイルヱナ
メルの除去効果、乾燥性等を著しく向上せしめることが
でき、しかも前記組成物の特性を何等阻害することがな
い。By incorporating an appropriate amount of aliphatic ketone, the nail enamel removal effect, drying properties, etc. of the phenoxyalkanol-aliphatic lower alcohol-water composition can be significantly improved, and the properties of the composition are not impaired in any way. .
脂肪族ケトンの使用量（含有量）は、５〜１５重量％、
好ましくは７〜ｌａ重量％である。The amount (content) of aliphatic ketone used is 5 to 15% by weight,
Preferably it is 7 to 1% by weight.
５重量％よりも少なくなるとネイルエナメルの除去効果
及び乾燥速度を低下しやすく、また不均一系を形成しや
すい。When the amount is less than 5% by weight, the nail enamel removal effect and drying rate tend to decrease, and a non-uniform system tends to be formed.
１５重量％よりも多くなると、燃えやすく、爪が白化し
やすくなる。If it exceeds 15% by weight, it will easily burn and cause nails to turn white.
脂肪族低級アルコ−ルとしては、例えばエチルアルコー
ル、ｎ−フ。Examples of aliphatic lower alcohols include ethyl alcohol and n-ph.
ロピルアルコール、イソプ。ピルアルコール、ｎ−ブチ
ルアルコール、イソブチルアルコール等を挙げることが
でき、一つ又は二つ以上組合せて使用される。その使用
量（含有量）は組成物重量に対して５〜２５重量％、好
ましくは７〜２の重量％である。５重量％よりも少なく
なると不均一系を形成しやすく、２５重量％よりも多く
なると燃えやすく、使用時に爪が白化しやすい。Lopyl alcohol, isop. Examples include pyrual alcohol, n-butyl alcohol, and isobutyl alcohol, which may be used singly or in combination of two or more. The amount used (content) is 5 to 25% by weight, preferably 7 to 2% by weight, based on the weight of the composition. When the amount is less than 5% by weight, a heterogeneous system tends to be formed, and when it is more than 25% by weight, it is easy to burn and the nails tend to whiten during use.
水の使用量は、組成物全量に対して１０〜４の重量％、
好ましくは１５〜３５重量％である。The amount of water used is 10 to 4% by weight based on the total amount of the composition,
Preferably it is 15 to 35% by weight.
１の重量％よりも少なくなると燃えやすくなり、４の重
量％よりも多くなるとネイルエナメルの溶解性が低下し
、また組成物が不均一系を形成しやすい。When the content is less than 1% by weight, it becomes easily flammable, and when it is more than 4% by weight, the solubility of the nail enamel decreases and the composition tends to form a heterogeneous system.
本発明のエナメルリムーバー組成物には、必要に応じて
、香料、染料等の着色剤、紫外線吸収剤等を添加使用す
ることができる。本発明のエナメルリムーバー組成物は
、前記構成成分のフェノキシアルカノールと脂肪族ケト
ンと脂肪族低級アルコールと水を又は必要に応じて香料
、着色剤、紫外線、吸収剤等の慣用添加物を濃伴下に適
宜順序で添加、混合することによって製造される。The enamel remover composition of the present invention may contain fragrances, colorants such as dyes, ultraviolet absorbers, and the like, if necessary. The enamel remover composition of the present invention contains the above-mentioned components phenoxyalkanol, aliphatic ketone, aliphatic lower alcohol, and water, or if necessary, conventional additives such as fragrances, colorants, ultraviolet rays, and absorbers. It is manufactured by adding and mixing in an appropriate order.
本発明のエナメルリムーバー組成物は、前記構成の四成
分が混溶している新規な組成物であって、実質的に、均
一な不燃性の液体で、かつ、乾燥速度や、脱脂力が適度
であるため使用時に爪をいためたり白化する等の弊害や
異和感がなく、消毒殺菌効果を発揮しながら、ネイルエ
ナメルを迅速容易に溶解、除去して、同時にガラス様の
良好な光沢を付与することができる。The enamel remover composition of the present invention is a novel composition in which the four components described above are mixed, and is a substantially uniform nonflammable liquid with moderate drying speed and degreasing power. Therefore, there is no harm or discomfort such as damaging or whitening the nails during use, and while exhibiting a disinfecting and sterilizing effect, it dissolves and removes nail enamel quickly and easily, and at the same time imparts a good glass-like gloss. can do.
就中、脂肪族低級アルコールや脂肪族ケトンは水温和性
の低いフェノキシアルカノールを均一安定に湯落し、そ
のフヱノキシアルカノールは有機溶媒系リムーバーや、
水混和性有機溶媒−水系リムーバーには見られない高度
の消毒、殺菌効果及び良好なガラス様光沢を爪に付与し
、そして共存する脂肪族ケトンによって除去効果や乾燥
性が顕著に向上される作用効果の特異性は著しい。In particular, aliphatic lower alcohols and aliphatic ketones can be used to uniformly and stably remove phenoxyalkanols, which have low water miscibility, and the phenoxyalkanols can be used in organic solvent removers,
Water-miscible organic solvent - gives nails a high degree of disinfection and sterilization effect not found in water-based removers and a good glass-like gloss, and the coexisting aliphatic ketone significantly improves the removal effect and drying properties. The specificity of the effect is remarkable.
以下、本発明の実施例について詳説する。実施例に示す
部とは重量部を、％とは重量％を意味する。Examples of the present invention will be described in detail below. In the examples, parts mean parts by weight, and % means weight %.
ネイルエナメルリムーバ−試料の性能試験は、特定のネ
イルエナメル（ニトロセルローズ１峠部、エチルアルコ
ール５部、エチルアセテート２礎都、ブチルアセテート
１５部、ジブチルフタレート５部、アルキッド樹脂１碇
郭、トルェン３５部、染料（赤色２１３号）０．００３
部からなるネイルエナメル）を使用（２回塗り）して行
ない女性２０人をパネラーとして毎日３週間行なった結
果及び専門技術者３人が毎日３週間行なった結果を示し
た。エナメルリムーバーの燃焼性は、リムーバーを時計
皿に入れた後、ライターの火稲（火稲長一定）をリムー
バーに直接接触して、燃えたものは燃焼、燃えなかった
ものは不燃とした。ネイルエナメル溶解性試験は、前記
のネイルエナメルの塗膜を、アプリケーターを用いて０
．２柳の厚さで（製膜板の上に）形成し、乾燥後、生成
したネイルエナメルの皮膜を剥離して、５肌×５肋の大
きさに細断し、この皮膜を２０の国／分の速度でプロペ
ラ縄拝しているリムーバー試料（５０ｃｃ）の中に投入
して、１０分後の溶解状態をしらべ、リムーバー効果の
一尺度とした。Nail enamel remover - The performance test of the sample was conducted using a specific nail enamel (1 part of nitrocellulose, 5 parts of ethyl alcohol, 2 parts of ethyl acetate, 15 parts of butyl acetate, 5 parts of dibutyl phthalate, 1 part of alkyd resin, 35 parts of toluene) part, dye (red No. 213) 0.003
This paper shows the results of 20 female panelists performing the test every day for 3 weeks, and 3 professional technicians performing the test every day for 3 weeks. The flammability of the enamel remover was determined by placing the remover in a watch glass and directly contacting the remover with the flame of a lighter (fixed flame length).Those that burned were considered combustible, and those that did not burn were considered non-flammable. In the nail enamel solubility test, the above nail enamel coating was applied using an applicator.
．． After drying, the resulting nail enamel film was peeled off and cut into pieces of 5 skins x 5 ribs, and this film was used in 20 countries. The solution was poured into a remover sample (50 cc) that was being moved by a propeller at a speed of 1/2 min, and the state of dissolution after 10 minutes was examined, which was used as a measure of the remover's effectiveness.
尚、溶解性試験の判定基準は、次の通りである。The criteria for the solubility test are as follows.
Ａ・・・・・・溶解
Ｂ・・・・・・分散（一部溶解）
Ｃ・・…・軟化（膨潤）
Ｄ・・・・・・不顔
実施例 １
第１表に示す各ネイルエナメルリムーバーの構成成分を
所要量、混合機に容れ、３び分間蝿梓混合して各リムー
バーを製造した。A: Dissolution B: Dispersion (partial dissolution) C: Softening (swelling) D: Faceless Example 1 Each nail enamel shown in Table 1 Required amounts of the components of the remover were placed in a mixer and mixed for 3 minutes to produce each remover.
第１表
得られた（第１表）の各リムーバーの外観、消毒殺菌効
果、ネイルエナメルの熔解性を専門技術者がしらべた結
果及び女性２０人（パネラー）が行なった実用テストの
結果を第２表に示した。Table 1 presents the results of an examination by expert technicians of the appearance, disinfection and sterilization effect, and solubility of nail enamel of each remover obtained (Table 1), as well as the results of a practical test conducted by 20 women (panelists). It is shown in Table 2.
第２表（実用テスト）
使用後の感触が良好 １５人 １３
人 １１人 ６へ ３人 １０人〃 普
通 ４ ５ ６ ８
７ ５〃 不良 １
２ ３ ６ １０ ５除去効
果が良好 １６ １１
８ １１ １７ ０〃 普通
４ ８ ７
７ ３ ０〃 不良
０ １ ５ ２
０ ２０乾きが良好 １６
１０ １０ １６ １７ ０〃 普
通 ４ ５ ４
４ ３ ２〃 不良
０ ５ ６ ０ ０ １
８爪表面が異状に白くをる ０ ０
２ １８ ２０ １〃 を認
めない ２０ ２０ １８ ２
０ １９良好をガラス様光沢が付いた
１５ １５ ２ １ ０
８ガラス様ではをいが光沢が付いた ４
４ １ １ ０ ８光
沢が付かなかった １ １
１７ １８ ２０ ４以上の
如く、本発明のリムーバーは、比較例の各リムーバ−の
難点をすべて改良している。Table 2 (practical test) Good feel after use 15 people 13
People 11 people Go to 6 3 people 10 people Normal 4 5 6 8
7 5〃 Defective 1
2 3 6 10 5 Good removal effect 16 11
8 11 17 0〃 Normal
4 8 7
7 3 0〃 Defective
0 1 5 2
0 20 Good drying 16
10 10 16 17 0 Normal 4 5 4
4 3 2〃 Defective
0 5 6 0 0 1
8 The nail surface is abnormally white 0 0
2 18 20 1 20 20 18 2
0 19 Good with glass-like luster
15 15 2 1 0
8 Glass-like and has a glossy finish 4
4 1 1 0 8 Not shiny 1 1
17 18 20 4 As described above, the remover of the present invention has improved all the drawbacks of the removers of the comparative examples.
尚、比較例２で使用しているジェチレングリコールモ／
フェニルェーテルは、本発明のフェノキシアルカノール
とは類縁の化合物であり、両者の作用効果に著しい差異
が認められる。実施例 ２
２−フエノキシエチルアルコールを５碇邦、エチルアル
コールの代りにィソプロピルアルコ−ルを２碇部、アセ
トンの代りにメチルエチルケトンを１０部、水を２館部
使用する他は実施例１と同様に蝿梓下に混合して均一透
明な本発明のリムーバーを得た。Furthermore, the diethylene glycol molybdenum used in Comparative Example 2
Phenyl ether is a compound related to the phenoxyalkanol of the present invention, and there is a significant difference in the effects of the two. Example 2 The same procedure was carried out except that 5 parts of 2-phenoxyethyl alcohol, 2 parts of isopropyl alcohol instead of ethyl alcohol, 10 parts of methyl ethyl ketone instead of acetone, and 2 parts of water were used. In the same manner as in Example 1, a uniformly transparent remover of the present invention was obtained by mixing with a powder.
このリムーバーについて、専門技術者３人が実施した実
用テストの結果は、不燃性で、使用時に爪をいためたり
、白化することがなく、市販品（アセトン７の部、エチ
ルアルコール１碇郡、水２０部からなるリムーバー）（
以下同じ）には見られない良好なガラス様光沢が付与さ
れること、ネイルエナメルの除去効果は良好であること
を認めている。The results of a practical test conducted by three professional engineers on this remover revealed that it is non-flammable, does not damage or whiten nails when used, and is found to be non-flammable, does not damage or whiten nails when used, and is compatible with commercially available products (7 parts of acetone, 1 part of ethyl alcohol, and 1 part of water). Remover consisting of 20 parts) (
It has been recognized that a good glass-like gloss is imparted that is not seen in other products (the same applies hereinafter), and that the nail enamel removal effect is good.
実施例 ３
３ーフェノキシプロピルアルコール４５部、ｎ−プロピ
ルアルコール１８部、アセチルアセトン１２部、水２５
部を使用し、実施例１と同様に蝿梓下に混合して均一透
明な本発明のリムーバーを得た。Example 3 45 parts of 3-phenoxypropyl alcohol, 18 parts of n-propyl alcohol, 12 parts of acetylacetone, 25 parts of water
A homogeneous and transparent remover of the present invention was obtained by mixing under the same method as in Example 1.
このリムーバ−について、専門技術者３人が実施した実
用テストの結果は不燃性で、使用時に爪をいためたり、
白化することがなく、前記市販品に見られない良好なガ
ラス様光沢が付与されること、ネイルエナメルの除去効
果は良好であることを認めている。実施例 ４
４−フエノキシブチルアルコール５碇郡、ｎ−フチルア
ルコール１８部、ジアセトンアルコール１２部、水２碇
部使用し、実施例１と同様に灘梓下に混合して均一透明
な本発明のリムーバーを得た。The results of a practical test conducted by three professional engineers on this remover revealed that it is non-flammable and will not damage your nails when used.
It has been recognized that it does not cause whitening, provides a good glass-like gloss not found in the commercially available products, and has a good nail enamel removal effect. Example 4 5 parts of 4-phenoxybutyl alcohol, 18 parts of n-phthyl alcohol, 12 parts of diacetone alcohol, and 2 parts of water were used and mixed under Nada Azusa in the same manner as in Example 1 to make it uniformly transparent. The remover of the present invention was obtained.
このリムーバーについて、専門技術者３人が実施した実
用テストの結果は、不燃性で使用時に爪をいためたり白
化することがなく、前記市販品に見られない良好なガラ
ス様光沢が付与されること、ネイルエナメルの除去効果
は良好であることを認めている。実施例 ５
構成成分の組成を第３表の通りにする他は、実施例１と
同様にして、本発明（Ｎｏ．１〜Ｎｏ．１０）及び比較
例（Ｎｏ．１１〜Ｎｏ．１８）のりムーバーを製造した
。The results of a practical test conducted by three expert engineers on this remover showed that it is nonflammable, does not damage or whiten nails when used, and provides a good glass-like gloss that is not found in the commercially available products. , admitted that the nail enamel removal effect is good. Example 5 The present invention (No. 1 to No. 10) and comparative example (No. 11 to No. 18) glues were prepared in the same manner as in Example 1, except that the composition of the constituent components was as shown in Table 3. Manufactured a mover.
専門技術３名が実施した性能テストの結果を第３表に示
した。尚、第３表の中に記載しているＰＥＡは２−フエ
ノキシエチルアルコール、ＥＡはエチルアルコール、Ａ
Ｃはアセトンである。第 ３ 表この結果から明らかな
ように、本発明のネイルエナメルリムーバー組成物にお
いては、フェノキシアルカノール２８〜６頚重量％、脂
肪族低級アルコール５〜２５重量％、脂肪族ケトン５〜
１５重量％、水１０〜４匹重量％の範囲が適している。Table 3 shows the results of a performance test conducted by three experts. In addition, PEA listed in Table 3 is 2-phenoxyethyl alcohol, EA is ethyl alcohol, and A
C is acetone. Table 3 As is clear from the results, the nail enamel remover composition of the present invention contains 28 to 6% by weight of phenoxyalkanol, 5 to 25% by weight of aliphatic lower alcohol, and 5 to 5% by weight of aliphatic ketone.
A range of 15% by weight and 10 to 4% water by weight is suitable.
Claims (1)
わされるフエノキシアルカノールと脂肪族ケトンと脂肪
族低級アルコールと水が混溶していることを特徴とする
改良されたネイルエナメルリムーバー組成物。 ２ フエノキシアルカノールが、２−フエノキシエチル
アルコール、３−フエノキシプロピルアルコール、２−
フエノキシプロピルアルコール、４−フエノキシブチル
アルコールあるいはそれらの組合せである特許請求の範
囲第１項記載の組成物。 ３ フエノキシアルカノールが、２８〜６８重量％混溶
している特許請求の範囲第１項記載の組成物。 ４ 脂肪族ケトンが、アセトン、メチルエチルケトン、
ジアセトンアルコール、アセチルアセトン、アセトニル
アセトンあるいはそれらの組合せである特許請求の範囲
第１項記載の組成物。 ５ 脂肪族ケトンが、５〜１５重量％混溶している特許
請求の範囲第１項記載の組成物。 ６ 脂肪族低級アルコールが、エチルアルコール、ｎ−
プロピルアルコール、イソプピルアルコール、ｎ−ブチ
ルアルコール、イソブチルアルコールあるいはそれらの
組合せである特許請求の範囲第１項記載の組成物。 ７ 脂肪族低級アルコールが、２〜２５重量％混溶して
いる特許請求の範囲第１項記載の組成物。 ８ 水が１０〜４０重量％混溶している特許請求の範囲
第１項記載の組成物。[Claims] 1. A phenoxyalkanol, an aliphatic ketone, and an aliphatic compound represented by the general formula ▲ Numerical formula, chemical formula, table, etc. ▼ (in the formula, R is an alkylene group having 2 to 4 carbon atoms) An improved nail enamel remover composition characterized by containing a mixed solution of lower alcohol and water. 2 Phenoxyalkanol is 2-phenoxyethyl alcohol, 3-phenoxypropyl alcohol, 2-
The composition according to claim 1, which is phenoxypropyl alcohol, 4-phenoxybutyl alcohol, or a combination thereof. 3. The composition according to claim 1, wherein the phenoxyalkanol is mixed in an amount of 28 to 68% by weight. 4 The aliphatic ketone is acetone, methyl ethyl ketone,
The composition according to claim 1, which is diacetone alcohol, acetylacetone, acetonylacetone or a combination thereof. 5. The composition according to claim 1, wherein the aliphatic ketone is mixed in an amount of 5 to 15% by weight. 6 The aliphatic lower alcohol is ethyl alcohol, n-
The composition of claim 1 which is propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol or a combination thereof. 7. The composition according to claim 1, wherein the aliphatic lower alcohol is mixed in an amount of 2 to 25% by weight. 8. The composition according to claim 1, which contains 10 to 40% by weight of water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4906478A JPS6033365B2 (en) | 1978-04-24 | 1978-04-24 | Improved nail enamel remover composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4906478A JPS6033365B2 (en) | 1978-04-24 | 1978-04-24 | Improved nail enamel remover composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54140741A JPS54140741A (en) | 1979-11-01 |
| JPS6033365B2 true JPS6033365B2 (en) | 1985-08-02 |
Family
ID=12820644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4906478A Expired JPS6033365B2 (en) | 1978-04-24 | 1978-04-24 | Improved nail enamel remover composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6033365B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2265055A1 (en) * | 1998-03-11 | 1999-09-11 | Chester P. Jarema | Solvent mixtures suited for use with wiping cloth on auto bodies |
-
1978
- 1978-04-24 JP JP4906478A patent/JPS6033365B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54140741A (en) | 1979-11-01 |
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