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JPS60457B2 - synthetic fiber composite yarn - Google Patents
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JPS60457B2 - synthetic fiber composite yarn - Google Patents

synthetic fiber composite yarn

Info

Publication number
JPS60457B2
JPS60457B2 JP13564975A JP13564975A JPS60457B2 JP S60457 B2 JPS60457 B2 JP S60457B2 JP 13564975 A JP13564975 A JP 13564975A JP 13564975 A JP13564975 A JP 13564975A JP S60457 B2 JPS60457 B2 JP S60457B2
Authority
JP
Japan
Prior art keywords
fibers
yarn
weight
synthetic fiber
spun yarn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP13564975A
Other languages
Japanese (ja)
Other versions
JPS5259745A (en
Inventor
明夫 木村
脩 和田
厚夫 橋詰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Ltd filed Critical Teijin Ltd
Priority to JP13564975A priority Critical patent/JPS60457B2/en
Publication of JPS5259745A publication Critical patent/JPS5259745A/en
Publication of JPS60457B2 publication Critical patent/JPS60457B2/en
Expired legal-status Critical Current

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  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Description

【発明の詳細な説明】 本発明は吸湿性、吸汗性、肌ざわりの改良された織編物
を与える合成繊維100%の複合糸に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a 100% synthetic fiber composite yarn that provides a woven or knitted fabric with improved moisture absorption, sweat absorption, and texture.

合成繊維は、その優れた性質から、衣料用素材として、
非常に広範囲に使用されているが、その多くが、疎水性
の重合体よりできているために、吸湿性に乏しく、衣料
として使用する際不快な蒸し暑さ、べとつき等を引き起
こし、特に肌着、夏物衣料などの用途には、不向きとさ
れている。
Synthetic fibers are used as clothing materials due to their excellent properties.
Although they are widely used, most of them are made of hydrophobic polymers, so they have poor moisture absorption properties, causing unpleasant stuffiness and stickiness when used as clothing, especially underwear and summer clothing. It is considered unsuitable for uses such as clothing.

この様な欠点を解決するために、従釆親水性合成繊維の
開発研究、あるいは、疎水性合成繊維の親水化研究が数
多くなされており、例えば、親水性基をポリマー主鏡中
に導入する方法、親水性化合物をポリマー中に練り込む
方法、繊維表面に親水性化合物を塗布する方法等による
親水性合成繊維或いはナイロン4繊維が製造されている
。しかし、この様な親水性合成繊維は吸湿性が得られた
反面、主体ポIJマーの繊維が本来備えていた優れた性
能を低下させたり或いは本釆の性能が悪かったりして、
耐久性に乏しかったり、あるいは織編物として衣料に用
いた場合に風合、肌ざわりが悪かったりする種々の欠点
を有する。この様に今日工業的に製造されている親水性
合成繊維は、紡績糸にしても、捲縮を与えたマルチフィ
ラメントにしても衣料にした場合着心地の面で大きな問
題があり、特に、夏物肌着、中衣に用いると肌ざわりの
面で天然粥繊維に対し著るしい差がある。
In order to solve these drawbacks, a lot of research has been carried out to develop hydrophilic synthetic fibers or to make hydrophobic synthetic fibers hydrophilic.For example, a method of introducing hydrophilic groups into a polymer primary mirror Hydrophilic synthetic fibers or nylon 4 fibers are manufactured by methods such as kneading a hydrophilic compound into a polymer, applying a hydrophilic compound to the fiber surface, and the like. However, although such hydrophilic synthetic fibers have hygroscopic properties, they may reduce the excellent performance originally possessed by the main polymer IJ polymer fibers, or may have poor performance.
It has various drawbacks such as poor durability and poor feel and texture when used in clothing as a woven or knitted fabric. In this way, the hydrophilic synthetic fibers that are industrially produced today, whether they are made into spun yarn or crimped multifilament, have serious problems in terms of comfort when used in clothing, especially for summer clothes. When used for underwear and innerwear, there is a marked difference in texture compared to natural porridge fibers.

以上述べた合成繊維使いにおける種々の欠点を克服すべ
く、本発明者らは衣料における吸湿問題則ち人体から発
散された汗の衣服を通しての移動プロセス、並びにそれ
と関連して肌ざわりの問題を繊密に検討し、研究を重ね
た結果、本発明に到達したものである。
In order to overcome the various drawbacks of using synthetic fibers as described above, the present inventors have carefully investigated the problem of moisture absorption in clothing, that is, the process of transport of sweat emitted from the human body through clothing, and the related problem of texture. As a result of extensive consideration and research, the present invention has been arrived at.

体温調節のため汗腺を通ってきた汗は外界の雰囲気条件
によって、一部は気体、一部は液体として体外に排出さ
れる。この排出された汗の一部は直接衣服を構成してい
る糸或いは繊維の間の空隙を通じて外界へ放散され、一
部は一旦繊維間および繊維の有する吸湿能力に応じて繊
維中に保持されて含有密度勾配に基づく移動プロセスに
より外界へと移動して放散され、それ以上の汗は衣服を
通じて移動できず、皮膚面とそれに対する衣服面との間
に留り、この残留分が着衣時の蒸し暑さ、に関係し、衣
服を構成する布毎の表面構造と相僕つてべとつきの感覚
を与えるものである。一方、発汗量からすると、人間は
、普通安静時でも15夕/従/hd室度の発汗し、運動
時あるいは、高温多湿の環境条件下ではその6倍程度に
も増え、皮膚面と衣服の間の湿度が70〜100%RH
にもなって蒸し暑くべとついた感じを斉らすのである。
Sweat that passes through the sweat glands to regulate body temperature is partially discharged as gas and partially as liquid, depending on the external atmospheric conditions. A part of this discharged sweat is directly dissipated to the outside world through the gaps between the threads or fibers that make up the clothing, and a part is once retained between the fibers and within the fibers depending on their moisture absorption ability. Sweat is transferred to the outside world and dissipated by a migration process based on the content density gradient, and no more sweat is able to move through the clothing, remaining between the skin surface and the clothing surface, and this residual sweat becomes hot and humid when wearing clothes. It is related to the texture and gives a sticky feeling in conjunction with the surface structure of each cloth that makes up the clothing. On the other hand, in terms of the amount of perspiration, humans sweat at a rate of 15 degrees per day even when they are at rest, and when they exercise or in a hot and humid environment, the amount of sweat increases to about six times that amount, and the amount of sweat perspires on the skin and clothing. Humidity between 70-100%RH
It also makes you feel hot, humid, and sticky.

従って、衣服は人体より発散された汗を速やかに吸湿し
外界へ放散する機能を有することが重要であり、例えば
衣服を構成する総総の吸湿性も上記の如く実質的には高
い雰囲気湿度における吸湿性が問題であり、一般的に用
いられている関係湿度65%の吸湿性は実状から外れた
ものとされる。
Therefore, it is important for clothing to have the ability to quickly absorb sweat emitted from the human body and dissipate it to the outside world. Hygroscopicity is a problem, and the commonly used relative humidity of 65% is considered to be out of touch with the actual situation.

そして、蒸し暑さ、べとつき感を与えない衣服として、
高湿度雰囲気での吸湿能力の高い繊維よりなり、繊維間
、糸間に十分抱水し得る空隙を有し、密度勾配に基づく
移動の行われ易い内部構造と蒸発面積の大きい粗な表面
構造を有し、しかも最外表面には乾き易い、即ち吸湿性
の少ない繊維が出ているような構造の布畠から出来てい
ることが理想的と考えられるのである。本発明はこの様
な布幕を作るに通した合成繊維よりなる織編物用の糸を
与えるものであって、合成繊維100%で上述の目的を
達成する意図は合成繊維の有する寸法安定性、防級性、
耐久性等の機能も重視しているためである。本発明の糸
は合成繊維よりなる紡績糸と合成繊維フィラメント捲縮
糸との引揃え、若しくは撚り合わせより成り、紡績糸が
20〜7の重量%、フィラメント捲額糸が80〜3の重
量%の範囲の構成比率にあり、かつ紡績糸を構成する繊
維は20午○、80%RHにおいて平衡水分率3%以下
、フィラメント捲縮糸を構成する繊維は同じく20q0
80%RHで平衡水分率10%以上であることを特徴と
する合成繊維複合糸である。
And, as clothes that do not give you a feeling of heat, humidity, or stickiness,
It is made of fibers with high moisture absorption ability in high humidity environments, has voids between fibers and yarns that can sufficiently hold water, has an internal structure that facilitates movement based on density gradients, and a rough surface structure that has a large evaporation area. Ideally, it should be made of a fabric with a structure in which the outermost surface has fibers that dry easily, that is, have low hygroscopicity. The present invention provides yarns for woven and knitted fabrics made of synthetic fibers that can be used to make such curtains. Class resistance,
This is because functions such as durability are also considered important. The yarn of the present invention is made by aligning or twisting a spun yarn made of synthetic fiber and a crimped synthetic fiber filament yarn, and the spun yarn is 20 to 7% by weight and the filament wrapped yarn is 80 to 3% by weight. The fibers constituting the spun yarn have an equilibrium moisture content of 3% or less at 20 pm and 80% RH, and the fibers constituting the filament crimped yarn have a composition ratio of 20 q0 or less.
It is a synthetic fiber composite yarn characterized by having an equilibrium moisture content of 10% or more at 80% RH.

本発明の複合糸における紡績糸は毛細管現象に基づく強
い吸水能力と、フィラメントに比して乱れた繊維配向が
与える方向性の少ない導水能力と〜毛羽の存在による粗
な表面構造および大なる蒸発面積とに関与し、フィラメ
ント捲縮糸と引揃え若しくは撚り合わせて一体とするこ
とにより引き伸ばされて空隙の無くなり易いフィラメン
ト格縮糸の空隙を安定に維持せしめる役割も果す。
The spun yarn in the composite yarn of the present invention has a strong water absorption ability based on capillary phenomenon, a less directional water conduction ability due to the disordered fiber orientation compared to filaments, and a rough surface structure and large evaporation area due to the presence of fluff. It also plays a role in stably maintaining the voids in the filament crimped yarn, which tend to disappear when stretched, by aligning or twisting them together with the filament crimped yarn.

そしてこの紡績糸に吸湿性の少し、、即ち20oo、8
0%RH平衡水分率3%以下と云う合成繊維ステープル
を用いることにより、最外表面は乾き易い、吸湿性の少
ない繊維毛羽で構成されることとなるのである。また合
成繊維フィラメント捲縮糸はその嵩高性による大きな繊
維間空隙と構成繊維が20℃、80%RHで平衡水分率
10%以上の吸湿性繊維であることによる吸水性で大な
る抱水能力を与える。ここで繊維の平衡水分率が10%
より低いと早い吸水能力が得られなくなると云う問題が
起る。そして紡績糸とフィラメント捲縦糸の複合割合は
紡績糸が20〜7の重量%好ましくは30〜5の重量%
を占めることが必要であり、2の重量%より少なくなる
とフィラメントによって紡績糸毛羽が押さえられること
もあってフィラメント表面が支配的となり、紡績糸毛羽
による槌面タッチ、乾いたタッチが失われることになる
。また紡績糸が7の重量%を超すと抱水空隙が減少し、
吸湿性繊維による早い吃水能力が失われると云う結果を
招来する。本発明における紡績糸に用いられる繊維とし
てはポリエステル系繊維、ポリアクリロニトリル系繊維
そしてポリビニルアルコール系繊維等が挙げられる。ま
たフィラメント捲縮糸に用いられる繊維としては20o
o、80%RHの平衡水分率が10%以上のナイロン4
繊維、アクリル酸、メタアクリル、マレィン酸、スチレ
ンスルホン酸、アクリルアミド等親水性基を有し重合可
能な二重結合を有する親水性モノマーを公知の電離性イ
オン化照射による方法、過酸化物による方法、オゾン或
いは紫外線を用いる方法等によってグラフト重合したポ
リァミド系繊維、ポリビニルァルコール系繊維、或いは
ポリエステル繊維を炭酸ソーダなどの弱アルカリを用い
てアルカリ金属塩に転換した繊維などが挙げられる。そ
して、この吸湿性フィラメント糸に捲縮を付与する方法
としては仮撚「押込、等公知の捲縦加工方法またはコン
ジュゲート繊維による方法等が挙げられる。紡績糸とフ
ィラメント捲縮糸を複合する方法は前述の通り、引揃え
ても撚り合わせでもよいが、紡績糸を表面に多く露出せ
しめることからフィラメント捲縮糸よりもオーバーフィ
ードして紡績糸をフィラメント捲縮糸の周囲にかべ撚り
状に巻き付ける方法が特に好ましいとされる。本発明の
複合糸を織編物に用いると肌着、スポーツ衣、シャツ、
ブラウス等に好適な布尾が得られる。
And this spun yarn has a little bit of hygroscopicity, namely 20oo, 8
By using a synthetic fiber staple with a 0% RH equilibrium moisture content of 3% or less, the outermost surface is composed of fiber fuzz that dries easily and has low hygroscopicity. In addition, the synthetic fiber filament crimped yarn has large inter-fiber voids due to its bulk and water absorption due to the fact that the constituent fibers are hygroscopic fibers with an equilibrium moisture content of 10% or more at 20°C and 80%RH, and have a large water-holding capacity. give. Here, the equilibrium moisture content of the fiber is 10%
If it is lower, a problem arises in that fast water absorption ability cannot be obtained. The composite proportion of the spun yarn and the filament-wound warp is 20 to 7% by weight, preferably 30 to 5% by weight.
If it is less than 2% by weight, the spun yarn fluff may be suppressed by the filament, and the filament surface becomes dominant, and the hammered surface touch and dry touch due to the spun yarn fluff will be lost. Become. In addition, when the spun yarn exceeds 7% by weight, the water-holding voids decrease,
This results in a loss of the quick wicking ability of the hygroscopic fibers. Examples of the fibers used in the spun yarn in the present invention include polyester fibers, polyacrylonitrile fibers, and polyvinyl alcohol fibers. In addition, the fiber used for the filament crimped yarn is 20o
o, Nylon 4 with an equilibrium moisture content of 10% or more at 80%RH
fibers, acrylic acid, methacrylic acid, maleic acid, styrene sulfonic acid, acrylamide, and other hydrophilic monomers having a hydrophilic group and a polymerizable double bond, using known ionizing irradiation methods, peroxide methods, Examples include polyamide fibers graft-polymerized by methods using ozone or ultraviolet rays, polyvinyl alcohol fibers, and fibers obtained by converting polyester fibers into alkali metal salts using a weak alkali such as soda carbonate. Methods for imparting crimps to this hygroscopic filament yarn include known longitudinal winding methods such as false twisting and pressing, or methods using conjugate fibers. A method of combining spun yarn and filament crimped yarn. As mentioned above, the spun yarn may be aligned or twisted together, but in order to expose more of the spun yarn on the surface, overfeeding the filament crimped yarn will cause the spun yarn to be twisted around the filament crimped yarn in a wall-twisted manner. The winding method is said to be particularly preferable.When the composite yarn of the present invention is used in woven or knitted fabrics, it can be used for underwear, sports clothing, shirts,
A cloth tail suitable for blouses etc. can be obtained.

以下「本発明の実施例を示す。Hereinafter, "Examples of the present invention will be shown."

実施例 1 雰囲気温度20qo、相対湿度80%RHの条件下で平
衡水分率が0.8重量%のポリヱステル短繊維(1.9
e×38脚)から成る40′/一紡績糸と同じ雰囲気条
件下での平衡水分率がla重量%のナイロン4フィラメ
ントから成る仮撚糸(IONe/24fil)を交燃し
、丸編機により編成した。
Example 1 Polyester short fibers (1.9
A false twisted yarn (IONe/24fil) consisting of 4 filaments of nylon with an equilibrium moisture content of 1% by weight under the same atmospheric conditions as a 40'/spun yarn consisting of 38 legs) was exchanged and knitted using a circular knitting machine. did.

この緑地でスポーツ、シャツを縫製し、20名の男子に
着せ着用試験を行った結果、第1表に示す結果が得られ
た。
Sports shirts were sewn in this green area and tested on 20 men.The results shown in Table 1 were obtained.

ここでは着用時に吸汗性、むし暑さ、べとつき感の3項
目に着目して各項目につき5点満点で験者に回答しても
らった平均値で比較している。第 1 表 実施例 2 雰囲気温度2000、相対湿度80%RHの条件下で平
衡水分率が0.8重量%の三角断面ポリエステル短繊維
から成る40/一紡績糸と同一の条件下での平衡水分率
が15重量%のアクリル酸をグラフトしあと炭酸ソーダ
でナトリウム塩としたナイロン・6の長繊維から成る仮
撚糸(15のe/4がd)を交燃した複合糸を用いて、
平織物を得た。
Here, we focused on three items: sweat absorption, heat, and sticky feeling when worn, and compared the average values obtained from testers who answered each item on a 5-point scale. Table 1 Example 2 Equilibrium moisture under the same conditions as a 40/1 spun yarn made of triangular cross-section polyester short fibers with an equilibrium moisture content of 0.8% by weight under the conditions of an ambient temperature of 2000℃ and a relative humidity of 80% RH. Using a composite yarn in which false twisted yarn (15 e/4 is d) consisting of long fibers of nylon 6 grafted with 15% by weight of acrylic acid and then sodium salted with sodium carbonate,
A plain woven fabric was obtained.

該織物よりブラウスを縫製し、20名の女子に着せ着用
試験を行った。実施例1と同様の方法で、纏めた結果は
第2表の通りである。第 2 表 実施例 3 雰囲気温度2000、相対湿度80%RHの条件下で平
衡水分率が0.8重量%のポリエステル短繊維(1.母
e×38柳)から成る80ノーS紡績糸を同じ雰囲気条
件下で平衡水分率が5.鷲重量%のナイロン6の長繊維
から成る仮撚糸(15のe/4ail)の2本引揃えに
対し50%のオーバーフイードで撚り合わせて複合糸と
した。
Blouses were sewn from the fabric and tested on 20 women. The results were summarized using the same method as in Example 1 and are shown in Table 2. Table 2 Example 3 80 No S spun yarn made of polyester short fibers (1. Matrix e x 38 willow) with an equilibrium moisture content of 0.8% by weight under the conditions of an ambient temperature of 2000 and a relative humidity of 80% RH. Equilibrium moisture content under atmospheric conditions is 5. Two false twisted yarns (15 e/4 ail) made of long fibers of nylon 6 with a weight ratio of 20% by weight were aligned and twisted together with an overfeed of 50% to obtain a composite yarn.

この複合糸を用いて編物を作り「 これをメタアクリル
酸および過硫酸アンモンに浸潰した後ポリエチレンフィ
ルムで包んで9000で1時間放置してから水で抽出し
、次いで炭酸ソーダの水溶液の処理を行なった。この編
物を分解し、ナイロン6とポリエステルとを別々に分析
した処、ポリエステルにはグラフトしておらず、ナイロ
ン6がメタアクリル酸のグラフト重合した平衡水分率l
a重量%の繊維になっていることを確認した。この編物
をスポーツシャツに縫製し、20名の女子に着せ着用試
験結果は第3表の通りである。第 3 表
A knitted fabric is made using this composite yarn, which is soaked in methacrylic acid and ammonium persulfate, wrapped in polyethylene film, left at 9000 for 1 hour, extracted with water, and then treated with an aqueous solution of soda carbonate. When this knitted fabric was disassembled and nylon 6 and polyester were analyzed separately, it was found that nylon 6 was not grafted to polyester, but had an equilibrium moisture content l in which nylon 6 was grafted with methacrylic acid.
It was confirmed that the fibers were 1% by weight. This knitted fabric was sewn into sports shirts and worn by 20 women, and the test results are shown in Table 3. Table 3

Claims (1)

【特許請求の範囲】[Claims] 1 合成繊維よりなる紡績糸と合成繊維のフイラメント
捲縮糸との引揃え若しくは撚り合わせより成り、紡績糸
が20〜70重量%、フイラメント捲縮糸が80〜30
重量%の範囲の構成比率にあり、かつ紡績糸を構成する
繊維は20℃、80%RHにおいて平衡水分率3%以下
であり、フイラメント糸を構成する繊維は同じく20℃
、80%RHで平衡水分率が10重量%以上であること
を特徴とする合成繊維複合糸。
1 Consisting of a spun yarn made of synthetic fiber and a filament crimped yarn of synthetic fiber, which are aligned or twisted together, with the spun yarn being 20 to 70% by weight and the filament crimped yarn being 80 to 30% by weight.
The fibers constituting the spun yarn have an equilibrium moisture content of 3% or less at 20°C and 80% RH, and the fibers constituting the filament yarn have a composition ratio within the range of 20°C by weight.
, a synthetic fiber composite yarn having an equilibrium moisture content of 10% by weight or more at 80% RH.
JP13564975A 1975-11-13 1975-11-13 synthetic fiber composite yarn Expired JPS60457B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13564975A JPS60457B2 (en) 1975-11-13 1975-11-13 synthetic fiber composite yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13564975A JPS60457B2 (en) 1975-11-13 1975-11-13 synthetic fiber composite yarn

Publications (2)

Publication Number Publication Date
JPS5259745A JPS5259745A (en) 1977-05-17
JPS60457B2 true JPS60457B2 (en) 1985-01-08

Family

ID=15156722

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13564975A Expired JPS60457B2 (en) 1975-11-13 1975-11-13 synthetic fiber composite yarn

Country Status (1)

Country Link
JP (1) JPS60457B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9609396A (en) * 1995-06-07 1999-06-15 Allied Signal Inc Carpet products made of synthetic fibers and yarns combined

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JPS5259745A (en) 1977-05-17

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