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JPS6058012B2 - Molding method of thermoplastic resin foam sheet - Google Patents
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JPS6058012B2 - Molding method of thermoplastic resin foam sheet - Google Patents

Molding method of thermoplastic resin foam sheet

Info

Publication number
JPS6058012B2
JPS6058012B2 JP56001918A JP191881A JPS6058012B2 JP S6058012 B2 JPS6058012 B2 JP S6058012B2 JP 56001918 A JP56001918 A JP 56001918A JP 191881 A JP191881 A JP 191881A JP S6058012 B2 JPS6058012 B2 JP S6058012B2
Authority
JP
Japan
Prior art keywords
mold
foam sheet
sheet
thermoplastic resin
resin foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP56001918A
Other languages
Japanese (ja)
Other versions
JPS57131528A (en
Inventor
正明 高場
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denka Co Ltd
Original Assignee
Denki Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denki Kagaku Kogyo KK filed Critical Denki Kagaku Kogyo KK
Priority to JP56001918A priority Critical patent/JPS6058012B2/en
Publication of JPS57131528A publication Critical patent/JPS57131528A/en
Publication of JPS6058012B2 publication Critical patent/JPS6058012B2/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/04Combined thermoforming and prestretching, e.g. biaxial stretching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Description

【発明の詳細な説明】 本発明は熱可塑性樹脂発泡シートの成型法、特に該発
泡シートを用いて絞り比の大きい容器の熱可塑性樹脂発
泡成型体の製法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for molding a thermoplastic resin foam sheet, and more particularly to a method for manufacturing a thermoplastic resin foam molded article for a container having a large drawing ratio using the foam sheet.

従来から熱可塑性樹脂シートの深絞り成型例えば絞り
比1.2〜15程度のものは非発泡シートの場合は容易
に成型することができるが、発泡シートの場合は容易で
はなかつた。
Conventionally, deep drawing of thermoplastic resin sheets, for example, sheets with a drawing ratio of about 1.2 to 15, can be easily formed in the case of non-foamed sheets, but this has not been easy in the case of foamed sheets.

これは、非発泡シートは、熱によりシートが損われる
までの温度領域巾が広く、絞り比1以上の成型ができる
程度に充分シートを軟化させることができるからであり
、発泡シート、例えばポリスチレンペーパー(以下PS
Pという)は加熱により表面のセルが破壊されやすく、
充分に内部まで軟化させることができないこと、また表
面のスキン層自体が弱いので絞り比0.2〜0.3程度
のものしか得られず、絞り比を上げるために、PSPの
片側を 非発泡シートで裏打ちしたラミネートPSPで
も絞り比0.5程度が限度であつた。
This is because non-foamed sheets have a wide temperature range before they are damaged by heat, and can be softened sufficiently to allow molding with a drawing ratio of 1 or more. (Hereafter P.S.
(referred to as P), the surface cells are easily destroyed by heating.
Since it is not possible to soften the inside sufficiently, and the surface skin layer itself is weak, a drawing ratio of only about 0.2 to 0.3 can be obtained.In order to increase the drawing ratio, one side of the PSP is unfoamed. Even for laminated PSP backed with a sheet, the aperture ratio was limited to about 0.5.

また発泡シートの深絞り成型の困難性は前記した絞り比
だけでなく、成型品の形状特に、第5図に示すように雌
型の傾斜角θが小さい程、また複数取りの型においては
金型の間隔1が小さい程、成型が困難でなる。一般的に
成型品の絞り比は、飲料預器を対象とする場合商品価値
として1〜1.2は必要てあり、又成型品の角度θは、
容量の面や、静置の際”の安定性の面で小さい方が好ま
しい。又金型間隔1が小さい程成型品の収量があがりス
クラップ量が少なくコスト面でも有利である。 次に従
来の成型方法は、第1図に示すように、加熱された発泡
シート4に、まず、雌型11を接触させると同時に、雄
型2で発泡シート4を押圧し、雌型の外部真空孔13及
び内部真空孔12により真空吸引する方法が一般的であ
り、この方法では、発泡シート4が雌型角16でシゴか
れる事と雌型11と接触した瞬間に発泡シート4の表面
が冷却固化して伸びにくくなる。
In addition, the difficulty in deep drawing of foam sheets lies not only in the drawing ratio mentioned above, but also in the shape of the molded product, especially as the inclination angle θ of the female die is smaller, as shown in Figure 5, and in the case of a multi-cavity die. The smaller the mold spacing 1, the more difficult the molding becomes. In general, the drawing ratio of a molded product is required to be 1 to 1.2 for commercial value when targeting beverage storage containers, and the angle θ of the molded product is
Smaller molds are preferable in terms of capacity and stability when left standing.Also, the smaller the mold interval 1, the higher the yield of molded products and the smaller the amount of scrap, which is advantageous in terms of cost. As shown in FIG. 1, the molding method is to first bring a female die 11 into contact with a heated foam sheet 4, and at the same time press the foam sheet 4 with a male die 2 to open the external vacuum holes 13 and the female die. A common method is to apply vacuum suction through internal vacuum holes 12. In this method, the foam sheet 4 is squeezed by the female mold corner 16, and the surface of the foam sheet 4 is cooled and solidified the moment it comes into contact with the female mold 11. It becomes difficult to stretch.

その結果、発泡シート4の伸びムラや亀裂の不良部17
を生じ、絞り比も0.5程度の成型品しか得られず、ま
た、伸びのよいテミネー日ゝPでも、絞り比は0.7程
度、第5図に示す金型の角度θも100以上、又複数個
取りの型においても金型の間隔1は、金型口径Dに対し
て0.4〜0.5と大きく発泡シート原反の約50%前
後はスクラップとして廃棄される現状にある。本発明は
、これらの欠点を解決したもので、従来法では困難とさ
れていた熱可塑性樹脂発泡シートを絞り、比1以上に深
絞り成型すること、また絞り比0.5〜1.0のものに
おいては、従来法より収率を向上させる事、成型品の肉
厚を均一に成型する事、成型品の座屈強度、側圧強度を
向上させる事、成型品の形状において、第5図における
金型角度0を難度の高い小さい角度にする事等を可能と
した熱可塑性樹脂発泡シートの成形方を提供しようとす
るものである。
As a result, the foamed sheet 4 has uneven elongation and cracks in defective areas 17.
, and a molded product with a drawing ratio of only about 0.5 can be obtained.Also, even with Temine day P, which has good elongation, the drawing ratio is about 0.7, and the mold angle θ shown in Fig. 5 is more than 100. In addition, even in a multi-cavity mold, the interval 1 between the molds is 0.4 to 0.5 relative to the mold diameter D, and the current situation is that around 50% of the original foam sheet is discarded as scrap. . The present invention solves these drawbacks, and it is possible to deep-draw a thermoplastic resin foam sheet to a drawing ratio of 1 or more, which was difficult with conventional methods, and to form a thermoplastic resin foam sheet with a drawing ratio of 0.5 to 1.0. For molded products, it is possible to improve the yield compared to the conventional method, to mold the wall thickness of the molded product uniformly, to improve the buckling strength and lateral pressure strength of the molded product, and to improve the shape of the molded product as shown in Figure 5. The purpose of this invention is to provide a method of molding a thermoplastic resin foam sheet that makes it possible to change the mold angle from 0 to a small angle that is highly difficult.

すなわち本発明は、熱可塑性樹脂発泡シートを加熱した
後、そのシートを上下クランプ枠により挾持しながらそ
のシートに雄型を所定の位置まで押圧すると共に、クラ
ンプ枠、雄型、雄型取付ベースおよび熱可塑性樹脂発泡
シートによつて囲まれた空間部を吸引して真空状態とし
、そのシートを雄型表面に密着させ、次いで雌型と雄型
とをシートを介して密着させた後、雌型側から吸引して
発泡成型品の外型を雌型の形状にセットすることを特徴
とする。
That is, in the present invention, after heating a thermoplastic resin foam sheet, a male mold is pressed onto the sheet to a predetermined position while the sheet is held between upper and lower clamp frames, and the clamp frame, male mold, male mold mounting base, and The space surrounded by the thermoplastic resin foam sheet is vacuumed, the sheet is brought into close contact with the surface of the male mold, the female mold and the male mold are brought into close contact via the sheet, and then the female mold is It is characterized by setting the outer mold of the foam molded product into a female mold shape by suctioning from the side.

以下図面に従つて本発明を説明する。The present invention will be explained below with reference to the drawings.

第1図は従来例の説明図、第2図、第3図、第4図、第
5図は本発明の説明図であつて、第1図は不良の発生状
況を示す断面図、第2図は、発泡シートを雄型により押
圧した断面図、第3図は、発泡シートが雄型に密着した
状態の装置断面図、第4図は、成形完了した状態の装置
の断面図、第5図は複数個取りの金型の断面図を示す。
FIG. 1 is an explanatory diagram of a conventional example, and FIGS. 2, 3, 4, and 5 are explanatory diagrams of the present invention. The figure is a cross-sectional view of the foam sheet pressed by the male mold, Figure 3 is a cross-sectional view of the device with the foam sheet in close contact with the male mold, Figure 4 is a cross-sectional view of the device after molding is completed, and Figure 5 The figure shows a cross-sectional view of a multi-cavity mold.

符号1は、クランプ枠、2は、雄型、3は、雄型取付ベ
ース、4は、発泡シート、5は、空間部、6は、空気逃
げ孔、7は、シール、8,12は、内部真空孔、9,1
3は、外部真空孔、10,15は、ピストン、14は、
雌型取付ベース、16は雌型角、17は、不良部を表わ
す。第2図において加祢された熱可塑性樹脂発泡シート
(以下発泡シートという)牡はクランプ枠1、によつて
上下からはさまれた後、ピストン10に固定された雄型
2、により押圧される。この時雄型取付けベース3、と
クランプ枠1、とが接触する様にし、接触部はシール7
、によつて完全にシールしエアーがもれない構造とする
。その結果、クランプ枠1、雄型2、雄型取付けベース
3、及びシール7、発泡シート牡で囲まれた密閉空間5
を生ずる。この空間は、雄型2に設けられた、内部真空
孔8及び図示されない外部真空ラインに通じる外部真空
孔9、を通じて真空にされる。その結果、発泡シート牡
は第3図に示される如く、雄型2に密着する。この様に
あらかじめ雄型2に発泡シート4を密着させて賦型した
後、第4図の如く雌型取付ベース14に取付けた雌型1
1をピストン15で作動させて成型品の肉厚を規制する
と同時に、内部真空孔12及び外部真空孔13によりコ
ーナー部を吸引し発泡シート4の外型を、雌型11の形
状に完全にセットする。
1 is a clamp frame, 2 is a male mold, 3 is a male mold mounting base, 4 is a foam sheet, 5 is a space, 6 is an air escape hole, 7 is a seal, 8, 12 are Internal vacuum hole, 9,1
3 is an external vacuum hole, 10 and 15 are pistons, 14 is
A female mounting base, 16 a female corner, and 17 a defective part. In FIG. 2, the added thermoplastic resin foam sheet (hereinafter referred to as foam sheet) is sandwiched from above and below by a clamp frame 1, and then pressed by a male mold 2 fixed to a piston 10. . At this time, the male mounting base 3 and the clamp frame 1 should be in contact with each other, and the contact area should be sealed with the seal 7.
, to ensure complete sealing and prevent air leakage. As a result, a closed space 5 surrounded by a clamp frame 1, a male mold 2, a male mold mounting base 3, a seal 7, and a foam sheet
will occur. This space is evacuated through an internal vacuum hole 8 provided in the male mold 2 and an external vacuum hole 9 leading to an external vacuum line, not shown. As a result, the foamed sheet member comes into close contact with the male mold 2, as shown in FIG. After molding the male mold 2 with the foam sheet 4 in close contact with it in advance in this way, the female mold 1 is attached to the female mold mounting base 14 as shown in FIG.
1 with a piston 15 to regulate the wall thickness of the molded product, and at the same time, the inner vacuum hole 12 and the outer vacuum hole 13 suck the corner part to completely set the outer mold of the foam sheet 4 into the shape of the female mold 11. do.

この後雄型2と雌型11をピストン10及び15で開き
、成型品が取出される。以上の様な成型方法より、第1
図に示すように雄型により突き出されたシートが雌型の
角でシゴかれ、発泡シートの無理な突き出しや、発泡シ
ートの局部冷却が解消された結果、発泡シートが均一に
伸ばされる様になり、かつ、不良品の発生がなくなるの
で、従来の方法では、実用的に実現できなかつた、絞り
比1以上、場合によつては1.5に近い深絞り発泡成型
品の成型が可能となつた。
Thereafter, the male mold 2 and female mold 11 are opened by pistons 10 and 15, and the molded product is taken out. From the above molding methods, the first
As shown in the figure, the sheet ejected by the male mold is squeezed by the corner of the female mold, eliminating forced ejection of the foam sheet and local cooling of the foam sheet, allowing the foam sheet to be stretched uniformly. Moreover, since the occurrence of defective products is eliminated, it becomes possible to mold deep-drawn foam molded products with a drawing ratio of 1 or more, and in some cases close to 1.5, which could not be practically achieved using conventional methods. Ta.

ここで、熱可塑性樹脂発泡シートとは、シート中に気泡
を含み、加熱により軟化する発泡シートで、素材として
は、ポリエチレンを始め、ABSlポリプロピレン、ポ
リエチレン、塩化ビニル、ナイロン樹脂等が好適である
Here, the thermoplastic resin foam sheet is a foam sheet that contains air bubbles in the sheet and softens when heated, and suitable materials include polyethylene, ABSl polypropylene, polyethylene, vinyl chloride, nylon resin, etc.

以下実施例について述べるが、これにのみ限定されるも
のではない。
Examples will be described below, but the present invention is not limited thereto.

実施例1 雌型口径83Tm深さ83TnIn(絞り比1.0)角
度θ=7型、金型間隔1=45T!r!n(うちクラン
プ枠W=579りで9ケ配列した型を用い、又発泡シー
トとしては、1皓発泡厚み2.5順のPSPに0.15
−の耐衝撃スチレン樹脂シートをラミネーションしたラ
ミネートPSPを用い、本発明による成型方法で成型し
た。
Example 1 Female mold diameter 83Tm depth 83TnIn (drawing ratio 1.0) angle θ = 7 molds, mold spacing 1 = 45T! r! n (including 9 molds arranged with clamp frame W = 579 mm, and as a foam sheet, 1 mm foam thickness is 0.15 to PSP in order of 2.5 mm)
A laminate PSP obtained by laminating impact-resistant styrene resin sheets of - was molded by the molding method of the present invention.

その結果上肉厚1.8WrIn1下部肉厚1.6Trr
!n1底部肉厚1.5waの成型品が得られた。この場
合の成型品の原反に対する重量収率は55%以上であつ
た。一方従来法による成型方法では、底部より10〜・
20Tn上方の部分から穴があき成型不能であつた。実
施例2雌型口径837wt深さ77wt(絞り比0.9
3)、角度θ=100、金型間隔30T!Rln(うち
クランプ枠幅W=3Tfn)で9ケ配列した金型を用い
、発泡シートとしてユーパール(株)製ラミネートPs
pr商品名#L7O8Jを用いて成型した。
As a result, the upper wall thickness is 1.8WrIn1, the lower wall thickness is 1.6Trr.
! A molded product with an n1 bottom wall thickness of 1.5 wa was obtained. In this case, the weight yield of the molded product based on the original fabric was 55% or more. On the other hand, in the conventional molding method, from the bottom
A hole formed from the upper part of the 20Tn, making it impossible to mold. Example 2 Female diameter 837wt depth 77wt (aperture ratio 0.9
3), angle θ=100, mold spacing 30T! Using a mold in which 9 molds were arranged with Rln (of which the clamp frame width W = 3Tfn), a laminate Ps manufactured by U-Pearl Co., Ltd. was used as a foam sheet.
It was molded using pr trade name #L7O8J.

この場合成型品の肉厚は上部1.9Tn!R下部1.8
7m底部1.777rmであつた。
In this case, the thickness of the molded product is 1.9Tn at the top! R lower part 1.8
It was 1.777rm at the bottom of 7m.

又DOwnspeed2−/分の条件での座屈強度は1
5〜20k9を示し又成型品側面を10順ひずませるに
要する側圧強度も0.8〜1.2kgあり実用上充分に
使用可能であつた。この場合の成型品の重量収率は6%
以上であつた。一方従来の方法て成型した成型品の肉厚
は上部2.1順下部0.5醜、底部1.3顛と偏肉が大
きく、座屈強度は、4〜7k9、側圧強度は0.2〜1
.3k9で実用に向かないものであつた。実施例3 雌型口径7『深さ105鶏(絞り比1.5)角度θ=8
.5径、金型間隔45W!E(うちクランプ枠W=3T
!r!n)で9ケ配列した金型を用い発泡シートとして
1.5倍発泡、厚み2瓢のポリプロピレン樹脂を用い、
本発明による方法及び装置て成型した。
Also, the buckling strength under the condition of DOwnspeed 2-/min is 1
5 to 20k9, and the lateral pressure strength required to distort the side surface of the molded product in a 10-order order was 0.8 to 1.2 kg, which was sufficient for practical use. In this case, the weight yield of the molded product is 6%
That's all. On the other hand, the wall thickness of the molded product molded using the conventional method is 2.1 mm at the top, 0.5 mm at the bottom, and 1.3 mm at the bottom.The buckling strength is 4 to 7k9, and the lateral pressure strength is 0.2. ~1
.. It was 3k9 and not suitable for practical use. Example 3 Female mold diameter 7, depth 105 (drawing ratio 1.5) angle θ = 8
.. 5 diameter, mold spacing 45W! E (including clamp frame W = 3T
! r! Using a mold with 9 pieces arranged in n), a polypropylene resin with 1.5 times the foam and a thickness of 2 gourds was used as a foam sheet.
Molding was carried out using the method and apparatus according to the invention.

その結果、成型品収率は50%であつた。又多少強度面
で難はあるが、一応絞り比1.5の成型品が得られた。
実施例4 雌型口径83T!n1、深さ10.8(絞り比1.3)
角度0=100の1ケ取り金型を用い、発泡シートとし
てユーパール(株)製ラミネートPspr商品名#L7
O8Jを真空成型した。
As a result, the molded product yield was 50%. Also, although there were some difficulties in terms of strength, a molded product with a drawing ratio of 1.5 was obtained.
Example 4 Female diameter 83T! n1, depth 10.8 (aperture ratio 1.3)
Using a single-cavity mold with an angle of 0=100, we used Laminate Pspr manufactured by U-Pearl Co., Ltd., product name #L7, as a foam sheet.
O8J was vacuum formed.

この結果、実施例1と同様の偏肉のない発泡成型品を得
た。
As a result, a foamed molded product with no thickness deviation similar to that of Example 1 was obtained.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、従来例の説明図、第2図、第3図、第4図、
第5図は本発明の説明図であつて、第1図は、不良の発
生状況を示す断面図、第2図は発泡シートを雄型により
押圧した断面図、第3図は、発泡シートが雄型に密着し
た状態の装置断面図、第4図は、成型完了した状態の装
置の断面図、第5図は複数個取りの金型の断面図を表わ
す。 符号、1・・・・・・クランプ枠、2・・・・・・雄型
、3・・・・雄型取付ベース、4・・・・・・発泡シー
ト、5・・・・・・空間部、6・・・・・・空気逃げ孔
、7・・・・・・シール、8,12・・内部真空孔、9
,13・・・・・外部真空孔、10,15・・・・・・
ピストン、14・・・・・・雌型取付ベース、16・・
・・・・雌型角、17・・・・・・不良部。
Fig. 1 is an explanatory diagram of a conventional example, Fig. 2, Fig. 3, Fig. 4,
Fig. 5 is an explanatory diagram of the present invention, in which Fig. 1 is a sectional view showing the occurrence of defects, Fig. 2 is a sectional view of the foam sheet pressed by a male mold, and Fig. 3 is a sectional view of the foam sheet pressed by a male mold. FIG. 4 is a cross-sectional view of the device in a state where it is in close contact with a male mold, FIG. 4 is a cross-sectional view of the device in a state where molding is completed, and FIG. 5 is a cross-sectional view of a multi-cavity mold. Code, 1... Clamp frame, 2... Male type, 3... Male type mounting base, 4... Foam sheet, 5... Space Part, 6... Air escape hole, 7... Seal, 8, 12... Internal vacuum hole, 9
, 13... External vacuum hole, 10, 15...
Piston, 14...Female mounting base, 16...
...Female corner, 17...Defective part.

Claims (1)

【特許請求の範囲】[Claims] 1 熱可塑性樹脂発泡シートを加熱した後、そのシート
を上下クランプ枠により挾持しながらそのシートに雄型
を所定の位置まで押圧すると共に、クランプ枠、雄型、
雄型取付ベースおよび熱可塑性樹脂発泡シートによつて
囲まれた空間部を吸引して真空状態とし、そのシートを
雄型表面に密着させ、次いで雌型と雄型とをシートを介
して密着させた後、雌型側から吸引して発泡成形品の外
型を雌型の形状にセットすることを特徴とする熱可塑性
樹脂発泡シートの成形法。
1. After heating the thermoplastic resin foam sheet, press the male die onto the sheet to a predetermined position while holding the sheet between the upper and lower clamp frames, and press the male die onto the sheet to a predetermined position.
The space surrounded by the male mold mounting base and the thermoplastic resin foam sheet is vacuumed, the sheet is brought into close contact with the surface of the male mold, and then the female mold and the male mold are brought into close contact with each other via the sheet. 1. A method for molding a thermoplastic resin foam sheet, characterized in that the outer mold of the foamed molded product is set in the shape of the female mold by suction from the female mold side.
JP56001918A 1981-01-09 1981-01-09 Molding method of thermoplastic resin foam sheet Expired JPS6058012B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56001918A JPS6058012B2 (en) 1981-01-09 1981-01-09 Molding method of thermoplastic resin foam sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56001918A JPS6058012B2 (en) 1981-01-09 1981-01-09 Molding method of thermoplastic resin foam sheet

Publications (2)

Publication Number Publication Date
JPS57131528A JPS57131528A (en) 1982-08-14
JPS6058012B2 true JPS6058012B2 (en) 1985-12-18

Family

ID=11514961

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56001918A Expired JPS6058012B2 (en) 1981-01-09 1981-01-09 Molding method of thermoplastic resin foam sheet

Country Status (1)

Country Link
JP (1) JPS6058012B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6388114U (en) * 1986-11-27 1988-06-08
JPH01136707A (en) * 1987-11-25 1989-05-30 Yamazaki Kagaku Kogyo Kk Manufacture of light-accumulating rubber molded object

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990002645A1 (en) * 1988-09-16 1990-03-22 Garwood Limited Improved packaging

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6388114U (en) * 1986-11-27 1988-06-08
JPH01136707A (en) * 1987-11-25 1989-05-30 Yamazaki Kagaku Kogyo Kk Manufacture of light-accumulating rubber molded object

Also Published As

Publication number Publication date
JPS57131528A (en) 1982-08-14

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