JPS605863B2 - Air conditioning equipment - Google Patents
Air conditioning equipmentInfo
- Publication number
- JPS605863B2 JPS605863B2 JP51090922A JP9092276A JPS605863B2 JP S605863 B2 JPS605863 B2 JP S605863B2 JP 51090922 A JP51090922 A JP 51090922A JP 9092276 A JP9092276 A JP 9092276A JP S605863 B2 JPS605863 B2 JP S605863B2
- Authority
- JP
- Japan
- Prior art keywords
- heating
- cooling
- capillary tube
- heat exchanger
- refrigerant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Devices For Blowing Cold Air, Devices For Blowing Warm Air, And Means For Preventing Water Condensation In Air Conditioning Units (AREA)
Description
【発明の詳細な説明】
本発明はヒートポンプ式冷暖房装置の冷房能力を向上さ
せるとともにヒートポンプ暖房運転の室外側熱交換器へ
の除霜ドレーン氷結成長を防止することを目的とするも
のである。DETAILED DESCRIPTION OF THE INVENTION An object of the present invention is to improve the cooling capacity of a heat pump air-conditioning system and to prevent the growth of ice on a defrost drain to an outdoor heat exchanger during heat pump heating operation.
以下本発明の一実施例につき添付図面に沿って詳細に説
明する。An embodiment of the present invention will be described in detail below with reference to the accompanying drawings.
1は室内ユニット、2は室外ユニット、3は冷媒酌管ユ
ニットである。1 is an indoor unit, 2 is an outdoor unit, and 3 is a refrigerant tube unit.
室内ユニット1において、4は圧縮機、5は四方弁、6
は室内側熱交換器、7は室内側熱交換器6を流れる冷媒
を分流させる複数分割回路の各々の一端に設けたガス側
枝管、8は室内側熱交換器6の複数分割回路の各々の他
の一端に直結しかつ絞り抵抗を大きくした冷暖房共用主
キヤピラリチューブ、9はフィル夕、10はアキユムレ
ータ、11はジョイント、12は室内ファンである。室
外ユニット2においては13は室外側熱交換器、14は
室内側熱交換器6と同様に複数分割回路をなす室外側熱
交換器13の各々の一端に設けたガス側枝管、15は室
外側熱交換器13の複数分割回路の各々の一端に直結し
かつ絞り抵抗を小さくした冷暖房共用補助キャピラリチ
ューブ、16はフィル夕、17は逆止弁、18は暖房専
用キャピラリチュープ、19は受液器で、その下方液相
部には暖房専用キャピラリ18の一端を、上方気相部に
は逆止弁17の一端を接続している。20はジョイント
、21は室外ファン、22は過冷却熱交換器である。In the indoor unit 1, 4 is a compressor, 5 is a four-way valve, and 6 is a compressor.
is an indoor heat exchanger, 7 is a gas side branch pipe provided at one end of each of the plurality of divided circuits that divide the refrigerant flowing through the indoor heat exchanger 6, and 8 is a gas side branch pipe provided at one end of each of the plurality of divided circuits of the indoor heat exchanger 6. A main capillary tube for heating and cooling is directly connected to the other end and has a large throttle resistance, 9 is a filter, 10 is an accumulator, 11 is a joint, and 12 is an indoor fan. In the outdoor unit 2, 13 is an outdoor heat exchanger, 14 is a gas side branch pipe provided at one end of each of the outdoor heat exchangers 13 forming a plurality of divided circuits like the indoor heat exchanger 6, and 15 is an outdoor heat exchanger. An auxiliary capillary tube for heating and cooling that is directly connected to one end of each of the plurality of divided circuits of the heat exchanger 13 and has a small throttle resistance, 16 is a filter, 17 is a check valve, 18 is a capillary tube exclusively for heating, and 19 is a liquid receiver. One end of a heating capillary 18 is connected to the lower liquid phase, and one end of a check valve 17 is connected to the upper gas phase. 20 is a joint, 21 is an outdoor fan, and 22 is a subcooling heat exchanger.
前記過冷却熱交換器22は高圧で凝縮液化した袷媒を大
幅に過冷却して冷暖房の能力と運転特性の安全を可能に
するもである。すなわち、冷房運転の場合には圧縮機4
、四方弁5からガス側枝管14により複数に分流して室
外側熱交換器13に流入する高圧冷煤ガスは各々分流し
た冷媒回路で室外ファン21により空冷され凝縮液化す
るものであるが、風速の分布および袷煤分流の分布によ
り必らずしも均等に凝縮し過冷却されることがなく室内
外側熱交換器6,13へ袷媒を数回路に分流させて流す
ような場合の大きな問題であった。本発明は以上の点に
立脚し、確実に大幅な過冷却を取るために室外側熱交換
器13から冷暖房共用補助キャピラリチューブ15によ
り各分流回路から出て来た袷煤をフィルター6、逆止弁
17から受液器19に集め、受液器19の下方から冷煤
液を本発明の過冷却熱交換器22へ流して確実に所定の
過冷却度を取るものである。この過冷却熱交換器22は
フィンチューブ式の室外側熱交換器13と同一フィンに
取付けた下段のチューブを用いたもので、したがって、
室外ファン21により過冷却されるのである。過冷却さ
れた冷媒は室内ュニットーに流れてフィル夕3から冷暖
房共用主キャピラリチューブ8にて分流され室内側熱交
換器6で冷房作用を行うものである。この時、過冷却熱
交換器22で充分に過冷却されているため、冷暖房共用
主キャピラリチューブ8には完全な冷媒液が均一に流れ
やすく、したがって、冷煤ガスの混入等による各キャピ
ラリチューブへの流れのばらつき等がなく、運転特性を
安定させるとともに、過冷却度に相応した冷房能力の向
上を保証するものである。以上の様に本発明実施例にお
いては、室内、外側熱交換器6,13の冷媒を数回路に
分流して流しても、室外側熱交換器13では冷煤出口に
設けた冷暖房共用補助キャピラリチューブ15の絞り抵
抗を均一にし又、室内側熱交換器6では冷媒入口に設け
た冷暖房共用主キャピラリチュープ8の絞り抵抗を均一
にすることにより、各分流回路への冷媒流量を同じにす
ることが出来るので、室内、外側熱交換器6,13の各
々の全域を均等に有効利用した熱交換を行い得るのであ
る。The supercooling heat exchanger 22 significantly subcools the liquefied medium that is condensed at high pressure, thereby ensuring safe heating and cooling performance and operating characteristics. In other words, in the case of cooling operation, the compressor 4
The high-pressure cold soot gas that flows from the four-way valve 5 into a plurality of branches through the gas side branch pipes 14 and flows into the outdoor heat exchanger 13 is air-cooled by the outdoor fan 21 in each branched refrigerant circuit, and is condensed and liquefied. This is a big problem when the soot is divided into several circuits to the indoor/outdoor heat exchangers 6 and 13 because it does not necessarily condense evenly and is not supercooled due to the distribution of soot and the distribution of the soot distribution. Met. The present invention is based on the above points, and in order to reliably achieve significant supercooling, the soot coming out of each branch circuit from the outdoor heat exchanger 13 is filtered through the filter 6 and the auxiliary capillary tube 15 for heating and cooling. The cold soot liquid is collected from the valve 17 into a liquid receiver 19 and flows from below the liquid receiver 19 to the supercooling heat exchanger 22 of the present invention to ensure a predetermined degree of supercooling. This subcooling heat exchanger 22 uses a lower tube attached to the same fin as the fin-tube type outdoor heat exchanger 13, and therefore,
It is supercooled by the outdoor fan 21. The supercooled refrigerant flows into the indoor unit, is branched from the filter 3 through the main capillary tube 8 for heating and cooling, and is used for cooling in the indoor heat exchanger 6. At this time, since the subcooling heat exchanger 22 has sufficiently subcooled the refrigerant liquid, it is easy for the complete refrigerant liquid to flow uniformly into the main capillary tube 8 used for cooling and heating, and therefore, the contamination of cold soot gas etc. There is no variation in the flow of air, stabilizing the operating characteristics, and guaranteeing an improvement in cooling capacity commensurate with the degree of supercooling. As described above, in the embodiment of the present invention, even if the refrigerant in the indoor and outdoor heat exchangers 6 and 13 is divided into several circuits and flows, in the outdoor heat exchanger 13, the cooling and heating common auxiliary capillary provided at the cold soot outlet By making the throttling resistance of the tubes 15 uniform and also by making the throttling resistance of the main capillary tube 8 for air conditioning and heating provided at the refrigerant inlet of the indoor heat exchanger 6 uniform, the refrigerant flow rate to each branch circuit can be made the same. Therefore, it is possible to perform heat exchange by effectively utilizing the entire areas of the indoor and outer heat exchangers 6 and 13 evenly.
これにより、室外側熱交換器13における凝縮冷媒液の
過冷却度も均一になると共に、分流冷煤を合流した後の
受液器19からの冷媒液を過冷却熱交換器22で過冷却
度を大きくしているので冷房能力の向上も一段と向上す
る効果を得ている。又、室外側熱交換器13に接続した
冷暖房共用補助キャピラリチューブ15の絞り抵抗は冷
暖房共用主キャピラリチューブ8に対して小さくし、室
外側熱交換器13の冷媒分流の均一化を主目的にしてい
るので、冷暖房共用補助キャピラリチューブ16の圧損
による袷煤の蒸発をさげており、冷房時の冷煤の蒸発は
室内側熱交換器6入口の冷暖房共用主キャピラリチュー
ブ8での絞り抵抗の大なる圧損減圧作用により行うので
室内側熱交換器6で性能の良い冷房作用を行うことが出
来る。As a result, the degree of subcooling of the condensed refrigerant liquid in the outdoor heat exchanger 13 becomes uniform, and the degree of subcooling of the refrigerant liquid from the receiver 19 after merging the branched cold soot is transferred to the subcooling heat exchanger 22. By increasing the size of the air conditioner, the cooling capacity is further improved. In addition, the throttling resistance of the auxiliary capillary tube 15 for both air conditioning and heating connected to the outdoor heat exchanger 13 is made smaller than that of the main capillary tube 8 for air conditioning and heating, and the main purpose is to equalize the refrigerant distribution in the outdoor heat exchanger 13. This reduces the evaporation of soot due to pressure loss in the auxiliary capillary tube 16 used for cooling and heating, and the evaporation of cold soot during cooling is caused by the large throttling resistance in the main capillary tube 8 for heating and cooling at the inlet of the indoor heat exchanger 6. Since this is performed by a pressure drop decompression action, the indoor heat exchanger 6 can perform a cooling action with good performance.
他方暖房運転の場合には圧縮機4、四方弁5、ガス側枝
管7から室内側熱交換器6へ流れた高圧冷媒ガスは暖房
作用をして凝縮液化し、冷暖房共用主キャピラリチュー
プ8、フィル夕9、ジョイント11、袷煤配管ユニット
3、ジョイント20から室外ユニット2へ流入する。こ
の時冬期のヒートポンプによる暖房運転で問題になるの
は低外気温時の室外側熱交換器13の着霜と除霜ドレー
ンの氷結による暖房能力の低下である。すなわち除霜ド
レーンが室外熱交換器13のフィンを流れ落ちる時、氷
結してしまい室外熱交換器13の下方より上方へ向けて
、氷が成長してゆき、順次室外熱交換器13がこ氷によ
り囲まれて熱交換器としての作用を大幅に失う問題であ
る。本発明はこの問題に対して、氷結を防止するもので
ある。すなわち、室外側熱交換器13と同一フィンの下
段に過冷却熱交換器22を設けているので、45qC位
から20qC位までに保たれているために、滴下するド
レーンが氷結することがないものである。すなわち室内
側熱交換器6で凝縮した冷媒液は冷暖房共用主キヤピラ
リチューブ8の圧損減圧作用により一部蒸発し気液2相
の状態になり、室外ユニット2に流れ、過冷却熱交換器
22に流入する。過冷却熱交換器22では低外気温およ
び室外側熱交換器13のドレーン水で冷やされ気液2相
の冷媒は再度凝縮液化作用を行い、この凝縮熱により、
過冷却熱交換器22は室内外の運転温度条件により異な
るが45q0位から20oo位を保つことになり、滴下
するドレーンの氷結を防止する役目を行う。過冷却熱交
換器22で再凝縮した冷煤液は、その後、受液器19か
ら暖房専用キャピラリチューフ18、フィル夕16、冷
暖房共用補助キャピラリチューブ15を経て室外側熱交
換器13に分流し、蒸発するものである。したがって室
外側熱交換器13における冷媒の低温蒸発作用に対して
除霜ドレーンの氷結により室外側熱交換器13を囲むこ
となく、効率よく熱交換作用をして蒸発を促進させてい
るので、暖房能力の低下を防止し、また、寒冷地におい
ても運転特性を安定させることができるものである。又
、暖房運転時には、暖房専用キャピラリチューブ18を
設けて、絞り抵抗の小さな冷暖房共用補助キャピラリチ
ューブ15での圧損減圧作用の不足を補完しているので
室外側熱交換器13で冷煤が低温外気から熱を吸収して
完全に蒸発して暖房能力の向上と圧縮機4への未蒸発冷
媒液の流入を防止して圧縮機4での液圧縮による故障を
防ぐものである。On the other hand, in the case of heating operation, the high-pressure refrigerant gas that flows from the compressor 4, four-way valve 5, and gas side branch pipe 7 to the indoor heat exchanger 6 has a heating effect and is condensed and liquefied, and the main capillary tube 8, which is used for heating and cooling, and the filter At 9pm, soot flows into the outdoor unit 2 from the joint 11, the soot piping unit 3, and the joint 20. The problem with heating operation using a heat pump during winter is a reduction in heating capacity due to frost formation on the outdoor heat exchanger 13 and freezing of the defrosting drain at low outside temperatures. In other words, when the defrost drain flows down the fins of the outdoor heat exchanger 13, it freezes and the ice grows from the bottom of the outdoor heat exchanger 13 upwards, and the outdoor heat exchanger 13 is gradually damaged by the ice. The problem is that it loses its function as a heat exchanger significantly if it is surrounded. The present invention solves this problem by preventing freezing. In other words, since the subcooling heat exchanger 22 is provided at the lower stage of the same fin as the outdoor heat exchanger 13, the temperature is maintained from about 45 qC to about 20 qC, so the dripping drain does not freeze. It is. In other words, the refrigerant liquid condensed in the indoor heat exchanger 6 is partially evaporated due to the pressure drop and depressurization action of the main capillary tube 8 used for both cooling and heating, becoming a gas-liquid two-phase state, flowing to the outdoor unit 2, and flowing into the subcooling heat exchanger 22. flows into. In the subcooling heat exchanger 22, the gas-liquid two-phase refrigerant cooled by the low outside temperature and the drain water of the outdoor heat exchanger 13 performs condensation and liquefaction again, and with this condensation heat,
The supercooling heat exchanger 22 maintains a temperature of about 45q0 to about 2000, depending on the indoor and outdoor operating temperature conditions, and serves to prevent the dripping drain from freezing. The cold soot liquid recondensed in the supercooling heat exchanger 22 is then diverted from the liquid receiver 19 to the outdoor heat exchanger 13 via the heating capillary tube 18, the filter 16, and the auxiliary cooling/heating common capillary tube 15. , which evaporates. Therefore, in response to the low-temperature evaporation action of the refrigerant in the outdoor heat exchanger 13, the defrosting drain does not surround the outdoor heat exchanger 13 due to freezing, and the evaporation is promoted by efficiently exchanging heat. This prevents the performance from decreasing and also stabilizes the operating characteristics even in cold regions. In addition, during heating operation, the heating-only capillary tube 18 is provided to compensate for the lack of pressure loss and depressurization in the cooling/heating auxiliary capillary tube 15 with low throttling resistance. By absorbing heat from the refrigerant and completely evaporating it, heating capacity is improved and unevaporated refrigerant liquid is prevented from flowing into the compressor 4, thereby preventing malfunctions due to liquid compression in the compressor 4.
本発明はヒートポンプ式冷暖房装置、特に比較的能力の
大きなパッケージエアコン等の様に室内外側熱交換器を
複数冷媒分割回路で構成した装置の冷暖房能力を向上さ
せると共に、ヒートポンプ暖房運転時の室外側熱交換器
への除霜ドレーン氷結成長を防止するものであって下記
の様な効果を有するものである。The present invention improves the cooling and heating capacity of a heat pump type air-conditioning device, especially a device in which an indoor-outdoor heat exchanger is configured with a plurality of refrigerant division circuits, such as a relatively large-capacity package air conditioner. This prevents the growth of ice on the defrost drain to the exchanger, and has the following effects.
■ 室外側熱交換器には絞り抵抗の小さな冷暖房共用補
助キャピラリチューブ、室内側熱交換器には冷暖房共用
主キャピラリチューブを複数冷媒分割回路の各々に設け
ているので、冷暖房運転時共に室内側熱交換器における
冷媒の分流を熱交換器全域にわたって均一にすることが
出釆、熱交換器を有効に使った冷暖房能力の向上が得ら
れる。■ The outdoor heat exchanger is equipped with an auxiliary capillary tube for both air conditioning and heating, which has low throttling resistance, and the indoor heat exchanger is equipped with a main capillary tube for air conditioning and heating, in each of the multiple refrigerant division circuits, so that the indoor heat can be transferred during both air conditioning and heating operation. It is possible to make the division of refrigerant in the exchanger uniform over the entire area of the heat exchanger, and it is possible to improve the heating and cooling capacity by effectively using the heat exchanger.
■ 室外側熱交換器に冷暖房共用補助キャピラリチュー
ブを設けているにもかかわらず絞り抵抗を小さくしてい
るので、冷煤の蒸発は冷暖房共用主キャピラリチュープ
による室内側熱交換器のみで行うので冷房能力を低下さ
せることがない。■ Even though the outdoor heat exchanger is equipped with an auxiliary capillary tube for both heating and cooling, the throttling resistance is kept small, so the evaporation of cold soot is carried out only in the indoor heat exchanger with the main capillary tube for heating and cooling. No reduction in performance.
又、暖房運転時には、室外側熱交換器に設けた冷暖房共
用補助キャピラリチューブでの減圧作用の不足を暖房専
用キャピラリチューブを設けて補完しているので、室外
側熱交換器での袷煤の蒸発を完全に行い、空気からの熱
の吸収を良くして暖房能力の向上を行うと共に圧縮機へ
の液バックを防止する効果を得ている。■ 暖簾運転時
の室外側熱交換器への除霜ドレーンの氷結防止は、冷暖
房共用主キャピラリチューブによる冷煤液の部分的蒸発
した気液2相を過冷却熱交換器に流入させて再凝縮作用
に伴う凝縮熱で、室外側熱交換器の下部の保温をしてい
るので、ドレーンの氷結を完全に防ぐことが出来る。In addition, during heating operation, the lack of pressure reducing effect in the auxiliary capillary tube for heating and cooling installed in the outdoor heat exchanger is compensated for by installing a dedicated capillary tube for heating, which reduces the evaporation of soot in the outdoor heat exchanger. This has been done perfectly, improving the absorption of heat from the air and improving heating capacity, as well as preventing liquid backflow into the compressor. ■ To prevent freezing of the defrosting drain to the outdoor heat exchanger during noren operation, the partially evaporated gas-liquid phase of the cold soot liquid is flowed into the supercooling heat exchanger using the main capillary tube used for heating and cooling, and is recondensed. The condensation heat generated by the action keeps the lower part of the outdoor heat exchanger warm, completely preventing the drain from freezing.
図は本発明の一実施例における冷暖房装置の冷媒回路図
である。
1・・・・・・室内ユニット、2・…・・室外ユニット
、3・・…・冷媒配管ユニット、4・・・・・・圧縮機
、5・・・・・・四方弁、6・・・・・・室内側熱交換
器、8…・・・冷暖房共用主キャピラリチューブ、15
・・・・・・冷暖房共用補助キヤピラリチューブ、17
・・・・・・逆止弁、18・・・・・・暖房専用キャピ
ラリチューブ、19・・・・・・受液器、22・…・・
過冷却熱交換器。The figure is a refrigerant circuit diagram of a heating and cooling system according to an embodiment of the present invention. 1...Indoor unit, 2...Outdoor unit, 3...Refrigerant piping unit, 4...Compressor, 5...Four-way valve, 6... ...Indoor heat exchanger, 8...Main capillary tube for air conditioning and heating, 15
・・・・・・Auxiliary capillary tube for heating and cooling, 17
...Check valve, 18...Capillary tube for heating, 19...Liquid receiver, 22...
Supercooling heat exchanger.
Claims (1)
室内側熱交換器を構成する複数冷媒分割回路の各一端に
直結しかつ絞り抵抗を大きくした冷暖房共用主キヤピラ
リチユーブと室外側熱交換器を構成する複数冷媒分割回
路の各一端に直結しかつ絞り抵抗を小さくした冷暖房共
用補助キヤピラリチユーブをそれぞれ接続し、前記冷暖
房共用補助キヤピラリチユーブと冷暖房共用主キヤピラ
リチユーブとの間に逆止弁と受液器と適冷却熱交換器と
を順次直列に接続し、前記冷暖房共用補助キヤピラリチ
ユーブと逆止弁との間に他端を接続した暖房専用キヤピ
ラリチユーブの一端を受液器の下方液相部に接続し、前
記過冷却熱交換器は室外側熱交換器の下端部に配設し、
暖房運転時には前記冷暖房共用主キヤピラリチユーブか
ら暖房専用キヤピラリチユーブ、冷暖房共用補助キヤピ
ラリチユーブへの3段階の減圧機構とし、冷房運転時に
は冷暖房共用補助キヤピラリチユーブから冷暖房共用主
キヤピラリチユーブへの2段階の減圧機構とした冷暖房
装置。1. In the refrigerant circuit that makes up the heat pump air conditioning system,
A common main capillary tube for heating and cooling that is directly connected to one end of each of the plurality of refrigerant division circuits that constitute the indoor heat exchanger and has a large throttling resistance, and a main capillary tube that is directly connected to one end of each of the plurality of refrigerant division circuits that constitute the outdoor heat exchanger and has a large throttling resistance. Auxiliary cooling/heating capillary tubes with reduced throttling resistance are connected to each other, and a check valve, a liquid receiver, and an appropriate cooling heat exchanger are sequentially installed between the cooling/heating/common auxiliary capillary tube and the cooling/heating/common main capillary tube. One end of a heating capillary tube connected in series, the other end of which was connected between the cooling/heating common auxiliary capillary tube and the check valve, is connected to the lower liquid phase part of the liquid receiver, and the supercooling heat exchange The container is placed at the lower end of the outdoor heat exchanger,
During heating operation, a three-stage pressure reduction mechanism is used from the main capillary tube used for cooling and heating, to a dedicated capillary tube for heating, and to an auxiliary capillary tube used for cooling and heating, and during cooling operation, from the auxiliary capillary tube used for cooling and heating to the main capillary tube used for cooling and heating. A heating and cooling system with a two-stage pressure reduction mechanism.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51090922A JPS605863B2 (en) | 1976-07-29 | 1976-07-29 | Air conditioning equipment |
| AU27404/77A AU496673B1 (en) | 1976-07-29 | 1977-07-28 | Heat pump including auxiliary outdoor heat exchanger acting as defroster and sub cooler |
| US05/820,003 US4171622A (en) | 1976-07-29 | 1977-07-28 | Heat pump including auxiliary outdoor heat exchanger acting as defroster and sub-cooler |
| ES461192A ES461192A1 (en) | 1976-07-29 | 1977-07-28 | A HEAT PUMP. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51090922A JPS605863B2 (en) | 1976-07-29 | 1976-07-29 | Air conditioning equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5316945A JPS5316945A (en) | 1978-02-16 |
| JPS605863B2 true JPS605863B2 (en) | 1985-02-14 |
Family
ID=14011910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51090922A Expired JPS605863B2 (en) | 1976-07-29 | 1976-07-29 | Air conditioning equipment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS605863B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01115560U (en) * | 1988-01-30 | 1989-08-03 | ||
| US10959933B1 (en) | 2020-06-01 | 2021-03-30 | The Procter & Gamble Company | Low pH skin care composition and methods of using the same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5121361Y2 (en) * | 1971-07-29 | 1976-06-03 | ||
| JPS4941955A (en) * | 1972-08-17 | 1974-04-19 | ||
| JPS5111726U (en) * | 1974-07-12 | 1976-01-28 |
-
1976
- 1976-07-29 JP JP51090922A patent/JPS605863B2/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01115560U (en) * | 1988-01-30 | 1989-08-03 | ||
| US10959933B1 (en) | 2020-06-01 | 2021-03-30 | The Procter & Gamble Company | Low pH skin care composition and methods of using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5316945A (en) | 1978-02-16 |
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