JPS607000B2 - Composition for chemically treated wiping tools and wiping tools - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention is directed to chemically treated wiping shells.
Ateddus rs: chemical rags) and the cleaning odor composition, for example, furniture/furnishings, fixtures,
It includes electrical appliances and other tools and equipment, as well as various furniture, as well as indoor and outdoor walls, ceilings, floors, pillars, handrails, partitions, etc. of buildings and wheels. It can be used to wipe down articles such as various fittings (collectively referred to as furniture fittings in the present invention), and has excellent cleaning effects, durability of the wiping effect, and an increase in the area to which the wiping effect is imparted. In addition to the advantages, it can simultaneously impart excellent flame retardancy, mildew resistance, disinfection effect, etc. to the surface to be wiped, and there is no risk of odor or coloring, and the surface to be wiped is harmless to humans and animals. The present invention relates to a composition for chemically treated wiping odor that can be imparted, and to a wiping odor obtained by treating a wiping fibrous substrate with such a composition.

More specifically, the present invention provides 0.005 to 0.05 parts by weight of a reverse soap-based disinfectant (disinfectant) {o} ammonia phosphate based on a total of 10 parts by weight of the following: and a flame retardant containing guanidine phosphate 3 to 15 parts by weight N alkylaryl ether type nonionic surfactant
1 to 1 parts by weight Silicone waterproofing (water repellent) agent 1 to 1 parts by weight Aqueous medium
The present invention relates to a composition for chemically treated wiping tools, characterized in that it consists of an aqueous composition containing a residue.

The present invention also relates to a cleaning odor in which the composition is supported on the base material by carrying the cleaning fibrous base material with the aqueous composition.

Traditionally, cleaning has been done for a long time by impregnating a fibrous base material such as a cloth or a mop with water and squeezing it appropriately, but it is different from those types. Therefore, chemically treated wiping tools (chemical wipes) that can be used for wiping without adding moisture are now widely used.

The present invention relates to the latter type of wiping odor and a chemically treated cleaning odor composition used for its production. In addition to being supported on the wiping fibrous substrate, the composition can also be used by applying an appropriate amount to the surface to be wiped, for example, by dropping or spraying, and then wiping and spreading the composition over the surface with a dry cloth. . The latter type of conventional wiping tools (hereinafter sometimes referred to as chemical wiping cloths or chemically treated dusters) have a sufficient wiping cleaning effect and the sustainability of the wiping effect (durability). In addition to the disadvantage that it is not large enough to be satisfactory, the area that can be wiped clean is relatively small, and it is difficult to impart a sufficient cleaning effect to a large area unless the chemical cloth is frequently replaced with a new one. Furthermore,
With conventional chemical cloths, it has not been possible to overcome the above-mentioned drawbacks and provide an improved cleaning effect on the wiped surface, as well as flame retardancy, anti-mold and disinfection effects, etc. Moreover, such an idea had never existed before. The present inventor has developed an improved product that improves the drawbacks and shortcomings of conventional chemical cloths as described above, and also provides flame retardancy, sterilization and disinfection effects, and anti-mold effects to the surface being wiped, which conventional products cannot provide. We conducted research to collaborate.

As a result, an aqueous composition consisting of a combination of specific ingredients and a specific ratio has shown many improved properties as a composition for chemical rags, and has excellent cleaning effect, wiping effect sustainability (durability), and wiping effect. In addition to the improvement benefits such as an increase in the applied area, it can simultaneously impart excellent flame retardancy, mold resistance, sterilization and disinfection effects to the surface to be cleaned, and there is no risk of odor or coloring, making it harmless to humans and animals. We have discovered that it is useful for providing effect-imparting aspects.

According to the research of the present invention, an aqueous composition that satisfies the above-mentioned combinations of ingredients and blending ratios, as will be shown later with comparative examples and examples, has been found to be difficult to clean by wiping with a conventional chemical cloth. It has been found that this material exhibits unique properties that allow it to easily provide a wipe-cleanable surface that combines various improvement effects that would otherwise be impossible to obtain.

Furthermore, the aqueous composition can be used in the form of a chemical cloth made by pre-impregnating or impregnating and drying a wiping fibrous substrate, such as fiber cloth, mop cord, or other substrates, to make it carry a special support. In addition to exhibiting the above-mentioned improvement effects, it can be stored in the form of the aqueous composition and supported on the substrate at the time of use, and used as a chemical cloth on the spot. It has been found that it has the advantage of being useful in a wide range of applications, such as by applying an appropriate amount to the surface and wiping it with a dry cloth.

SUMMARY OF THE INVENTION Accordingly, the object of the present invention is to relate to a cleaning tool and a composition for the cleaning tool having excellent improved properties. The above objects and many other objects and advantages of the present invention will become more apparent from the following description. {i}～'Based on a total of 100 parts by weight of the village,'i} Inverse soap-based disinfectant
0.005 to 0.05 parts by weight Flame retardant containing ammonia phosphate and guanidine phosphate
3 to 15 parts by weight Alkylaryl ether type nonionic surfactant 1 to 1 parts by weight B Silicone waterproofing agent 1 to 1 parts by weight Contains the remainder aqueous medium.

The above-mentioned reverse soap-based disinfectant is an enteric ion active agent that has cationic activity, whereas ordinary soap has anionic activity, and has excellent disinfectant action and is safe in terms of toxicity. You can use whatever you choose.

Preferred examples of such inverse soap-based disinfectants include the use of known inverse soap-based disinfectants of the quaternary ammonium salt type, such as penzalkonium chloride and penzethonium chloride. The amount to be used is 0.005 to 0.005 parts in total of 100 parts by weight of the above.
0.05 parts by weight, preferably 0.01 to 0.0 parts by weight.

If the amount used is too small, it will be difficult to achieve satisfactory antifungal and disinfectant effects, and if it is too large, the chemical may adhere to the skin and cause irritation for some people, so it is recommended to use the amount within the above range. good. Further, as the ammonia phosphate used in any of the flame retardants containing ammonium phosphate and guanidine phosphate, diammonium phosphate is preferable, but monoammonium phosphate and triammonium phosphate can also be used.

Preferred examples of such flame retardants include, for example, ammonium phosphate and guanidine phosphate disclosed in Japanese Patent Publication No. 52-4 Matara No. 57 (Japanese Patent No. 914191), as well as magnesium chloride and/or calcium chloride. Examples of flame retardant compositions containing the above can be given. The amount used is 3 to 15 parts by weight, preferably 5 to 15 parts by weight, out of the total 100 parts by weight of the above-mentioned substances.

If the amount used is too small, it will be difficult to provide a satisfactory flame retardant effect, and if it is used too much, sticky residue will remain after wiping, so the amount is used within the above range. Further, as the alkylaryl ether type nonionic surfactant, polyoxyethylene higher alkyl phenyl ether such as polyoxyethylene nonyl phenyl ether, polyoxyethylene octylphenyl ether, etc. Among them, it is particularly preferable to use oily polyoxyethylene octylphenyl ether having a specific gravity of 1.03 to 1.0 degrees Celsius (at 20° C.).

These are easily available on the market. The amount used is 1 to 1 part by weight, preferably 1.5 to 10 parts by weight, out of the total 100 parts by weight of the above-mentioned Kawa to T Village.

If the amount used is too small, the appearance of dust after wiping will be weak, and the dust adsorption power and cleaning effect will be poor. or,
If the amount is too large, the surface to be wiped will become sticky and will be delayed in drying forever, so it is used in the amount within the above range. Furthermore, as the silicone waterproofing agent of Q above, commercially available silicone waterproofing agents can be used, and for example, a silicone waterproofing agent containing an acrylic resin component, olon MF40; a product of Shin-Etsu Chemical Co., Ltd. is preferably exemplified. I can do it.

The amount used is, out of the total 100 parts by weight of the above
The amount is 1 to 10 parts by weight, preferably 2 to 1 parts by weight.

If the amount used is too small, the waterproof effect will be weak, and even if it is used in an excessive amount, it will not be possible to see any further increase in the effect, so it is used in the amount within the above range. The chemically treated wiping odor composition of the present invention is composed of an aqueous composition containing the above-mentioned [i} to iii. In addition to various effects such as increasing the surface area for wiping and wiping, it also provides excellent flame retardancy, mildew resistance, and disinfection effects to the surface to be wiped, and there is no risk of odor or coloring. A cleaning effect imparting surface that is harmless to humans and animals can be imparted to the cleaning surface to be wiped.

For example, above [. }, Components 1 and 8 exhibit a cooperative effect with each other, exhibiting an excellent cleaning effect on the surface to be wiped, its sustainability, the effect of increasing the area to which it is applied, and the effect of imparting flame retardancy,
The surface to be cleaned is strong and flexible, forming a water-resistant film that prevents re-contamination, and at the same time imparts flame retardancy, and the coexistence of the above-mentioned ingredients provides anti-mold and disinfection effects. It is presumed that it also provides the above-mentioned film-forming effect and helps to effectively provide the above-mentioned excellent effects. Although the details of the origin of the cooperative interaction between these essential components are not necessarily clear, as will be shown later with examples and comparative examples, the bonding requirements specified in the present invention can be understood. If it deviates from the above, it becomes difficult to achieve the combination of the above-mentioned improvement effects, so it can be inferred that these essential components cooperate with each other to exert a cooperative and reciprocal effect.

The wiping odor of the present invention can be provided by applying the composition as described above to, for example, fiber cloth, mop strings, or any other fibrous substrate for wiping odor.

The supporting treatment itself can be performed by any known means, such as pre-impregnating the fibrous base material for wiping odor, spraying, squeezing after soaking, and if necessary, drying after the supporting treatment. It can be done by means. The shape of the wiping tool can also be selected as appropriate; for example, in addition to the shapes of cloth rags, blackboard wipes, mops, etc., it can also be shaped like a special rag, such as a glove shape. Furthermore, the chemically treated cleaning odor composition of the present invention comprises the aqueous composition (
It can also be stored in the form of an emulsion composition (emulsion composition), and at the time of use, an appropriate amount can be supported on a base material such as the one described above, and used on the spot in the form of a chemical cloth. It can be used in a wide variety of ways, such as by wiping it with a dry cloth. The amount of the composition of the present invention supported on the wiping fibrous substrate (take-up) can be appropriately selected.

The amount may be arbitrarily selected as long as the amount is not so excessive that the composition drips after completion of the supporting treatment. For example, as an aqueous composition, approximately 25%
Loading amounts such as 0 to about 35% by weight may be exemplified. Next, a numerical sequence of several aspects of the present invention will be explained in more detail by way of examples, along with comparative examples.

In addition, in the following, the test method and evaluation for determining the effectiveness are based on the following tests and evaluations. Vertical x Width: approx. 40 x 2 & weight: approx. 35 yen cotton terry cloth cloth, carrying amount (take up)
Up) A chemical cloth carrying a chemical composition for 80 minutes is used.

(i' Cleaning effect test: - [i' Fly ash (average particle size of about 2 pieces) was placed on a white painted iron plate (painted with melamine white baking paint).
Spread it evenly at an amount of 0.1 ml per coat, and gently wipe it off with a hand towel using a sample chemical cloth.

It is expressed as the area that could be wiped off without fly ash scattering (the occurrence of a condition in which ash once attached to the cloth falls off).

The larger the area, the better. ‘.

Apply lipstick to the area that has been immersed and purified in the test of ``Joyakui'' for about 5 minutes.
Draw an arc and perform the wiping operation once in the same manner as above using an untreated cotton cloth rag (the sample rag that has not been treated with chemicals).

The results are observed with the naked eye and evaluated according to the following criteria. A:
Lipstick circles will no longer be recognized.

B: More than half of the lipstick circles are not recognized, but less than half are faintly recognized.

C: A portion of the lipstick circle is no longer recognized, but more than half is faintly recognized.

D: Partially pale, but the entire lipstick circle is visible.

(ii) Durability test: - Approximately half of the matte melamine board (woodgrain pattern) is hand-wiped with the chemical rag under test, and the other half is left untreated.

The sample is suspended in an open shed, and the period of time until the gloss of the treated area becomes indistinguishable from the untreated area is shown. The longer the period, the better. (iii) Effect test for increasing effect imparting area: - The test chemical cloth used in the river in the previous (i) is used for the test after sieving by hand to remove any ash that may fall off.

Perform the same test as the river and show similar area. The larger the area, the better. ``W Flame retardancy test: - Planned cedar wood 4 pieces of wood (thickness 5 willow, vertical and horizontal 2
Wipe the front and back of the 0x10 arc) with a sample chemical cloth.

Samples were prepared by manually wiping a plurality of pieces of wood a different number of times, and the residual dust time was tested according to JISL-1004, and the number of times the sample was wiped at which the residual dust time became 0 seconds is indicated. The fewer times, the better. Examples 1 to 5 and Comparative Examples 1 to 4 Aqueous compositions containing '-0 in the amounts shown in Table 1 below were prepared using the following components.

... Penzalkonium chloride (reverse soap-based disinfectant).

[o} Fujiporca (Flame retardant containing ammonia phosphate and guanidine phosphate) [■ Fujimasu Chemical Research Institute product (Patent No. 914191 product)] ether-type nonionic surfactant) [Newcol 865:
Nippon Emulsifier ■Product], A Silicone waterproofing agent containing acrylic resin component (Silicone waterproofing agent) [PolonM
F40; Shin-Etsu Chemical ■products], water removal remains.

Using the prepared composition, a test chemical cloth was made,
Tests of (i) to (iV) were conducted.

The results are shown in Table 1 below. Table 1

Claims (1)

[Claims] 1. Based on a total of 100 parts by weight of the following (a) to (e),
(a) 0.005 to 0.05 parts by weight of inverse soap-based disinfectant (
b) 3 to 15 parts by weight of a flame retardant containing ammonia phosphate and guanidine phosphate (c) 1 to 10 parts by weight of an alkylaryl ether type nonionic surfactant (d) 1 to 10 parts by weight of a silicone waterproofing agent ) A composition for a cleaning tool for chemically treating furniture and fittings, characterized by comprising an aqueous composition containing a residual aqueous medium. 2 Wipe the fibrous base material with the following (a) to (e) total 1
Based on 0.00 parts by weight, (a) 0.00 inverse soap-based disinfectant
5 to 0.05 parts by weight (b) 3 to 15 parts by weight of a flame retardant containing ammonium phosphate and guanidine phosphate (c) 1 to 10 parts by weight of an alkylaryl ether type nonionic surfactant (d) Silicone waterproofing A wiping tool for furniture and fittings, which is supported on an aqueous composition containing 1 to 10 parts by weight of an aqueous medium.